EP2454038B1 - Procédé de blocage d une fausse barre dans une installation de coulée continue et installation de coulée continue présentant ladite fausse barre - Google Patents

Procédé de blocage d une fausse barre dans une installation de coulée continue et installation de coulée continue présentant ladite fausse barre Download PDF

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Publication number
EP2454038B1
EP2454038B1 EP10728647.8A EP10728647A EP2454038B1 EP 2454038 B1 EP2454038 B1 EP 2454038B1 EP 10728647 A EP10728647 A EP 10728647A EP 2454038 B1 EP2454038 B1 EP 2454038B1
Authority
EP
European Patent Office
Prior art keywords
strand
locking device
continuous casting
strand guide
casting installation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Not-in-force
Application number
EP10728647.8A
Other languages
German (de)
English (en)
Other versions
EP2454038A1 (fr
Inventor
Kurt Fellinger
Paul Pennerstorfer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Primetals Technologies Austria GmbH
Original Assignee
SIEMENS VAI METALS TECHNOLOGIES GmbH
Siemens VAI Metals Technologies GmbH Austria
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SIEMENS VAI METALS TECHNOLOGIES GmbH, Siemens VAI Metals Technologies GmbH Austria filed Critical SIEMENS VAI METALS TECHNOLOGIES GmbH
Publication of EP2454038A1 publication Critical patent/EP2454038A1/fr
Application granted granted Critical
Publication of EP2454038B1 publication Critical patent/EP2454038B1/fr
Not-in-force legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/08Accessories for starting the casting procedure
    • B22D11/081Starter bars
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/08Accessories for starting the casting procedure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/08Accessories for starting the casting procedure
    • B22D11/085Means for storing or introducing the starter bars in the moulds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/14Plants for continuous casting
    • B22D11/148Safety arrangements

Definitions

  • the invention relates to a method for securing a starter strand in a strand guide of a continuous casting plant and a continuous casting plant with a starter strand.
  • the invention relates to a continuous casting with a mold and a subsequent strand in the conveying direction strand guide, and with a Anfahrstrang that closes the mold at the start of casting exit and can be held and moved in the strand guide of engagable and driven strand guide rollers, the strand guide rollers a transport path for form the Anfahrstrang.
  • the mold Before the start of a casting process, the mold is closed on the output side with the head of a starter strand.
  • the Anfahrstrang is either promoted from below in an upward movement along the strand guide mostly with engagable and driven strand guide rollers to the mold and held in this starting position of the strand guide rollers or starting from the Casting platform conveyed from above through the mold and then held in the strand guide in turn by the engagable and drivable strand guide rollers in the starting position.
  • An operator error or failure in one - the adjusable and drivable strand guide rollers - means of electrical, hydraulic, pneumatic or communication, can lead to a sudden onset, constantly accelerating downward movement of the heavy Anfahrstrangs in the strand guide, with this movement, the so-called Crash, typically over a long distance (eg over several strand guide segments and / or traction roller scaffolding).
  • This risk is particularly high in vertical casters, as this type of plant has a vertical strand guide.
  • the crash of the starter train can lead to personal injury as well as damage to individual plant components. For safety reasons, operating personnel are therefore not allowed to stay in hazardous areas during this phase of operation.
  • Another object of the invention is that the Anfahrstrang can be secured both during threading, while holding in the starting position and after the start of pouring. Furthermore, the securing of the Anfahrstrangs should be independent of the weight starter strand and in particular work well even with very heavy Anfahrstrfiten.
  • the Anfahrstrang is transported during the threading of drivable strand guide rollers in the strand guide in the direction of mold and then held before the casting start in a mold on the output side closing starting position of engagable strand guide rollers.
  • the Anfahrstrang when threading and holding at least one in Strang adoptcardi downstream locking device secured, ie the movement of the Anfahrstrangs in the strand conveying direction is blocked by at least one locking device.
  • the Anfahrstrang is secured both during threading, while holding and during Ausfiln against an uncontrolled crash.
  • a plurality of locking devices are distributed in the strand guide (e.g., comprising one or more strand guide segments or traction roller frames) which are sequentially secured as the dummy strand is threaded and sequentially released after casting commencement.
  • sequential unlocking of the locking devices proceeds undisturbed by securing the starter strand.
  • the securing of the starter strand by a plurality of distributed in the strand guide, locking is largely independent of the length of the Anfahrstrangs, whereby the backup of very short Anfahrstrnature is possible.
  • the plurality of locking devices further reduces the distance in the event of a crash until the starting line is intercepted in the strand guide, which increases safety.
  • an arresting device automatically secures the startup line in the event of a failure of a device of electrical, hydraulic, pneumatic or communication. This increases the safety when threading, holding and unthreading the dummy bar.
  • the automatic securing of the starter strand without external, i. from outside the locking device, energy. This further increases the safety during threading, holding and unthreading of the dummy bar
  • At least one locking device for the Anfahrstrang is arranged in the strand guide, which lies from a lying outside the transport path release position in a transport path the Anfahrstrangs locking catch position is formed displaced back and forth.
  • Anfahrstrang is designed as a link chain or rigid, or has a straight or curved shape.
  • a locking device on a front side of a Strand guide segment or a drive roller frame or between two, adjacent in the strand conveying direction, strand guide rollers, preferably driven strand guide rollers arranged.
  • the force for securing or intercepting the Anfahrstrangs is introduced via the locking device in an advantageous manner in the strand guide segment or in the drive roller frame.
  • a locking device can also be arranged in a separate support structure. By means of this embodiment, it is possible to assemble or disassemble the locking device independently of strand guide segments or driving roller stands.
  • a simple embodiment is to form a locking device as a displaceable or pivotable bolt, wherein the bolt is designed to be displaceable by a Betuschistsvorrichung. It is particularly advantageous to use the bolt and the actuating device in an assembly, e.g. As a cassette, form so that this module can be easily and quickly assembled or disassembled.
  • a further embodiment is to form a locking device as a displaceable, inclined plate or a displaceable, obliquely located bolt, wherein the weight of the locking device defines the basic position of the locking device and the locking device is displaceable via an actuating device in the release position. This ensures that the locking device automatically secures the Anfahrstrang in case of failure of the actuator.
  • a further embodiment consists in that the actuating device comprises a, for example pneumatic or hydraulic, pressure accumulator, wherein the pressure accumulator formed by means of a pressure medium cylinder Actuator defines the basic position of the locking device. This ensures that the locking device automatically secures the Anfahrstrang in case of failure of the actuator.
  • a further embodiment consists in that the actuating device comprises a spring, wherein the spring force defines the basic position of the locking device. This ensures that the locking device automatically secures the Anfahrstrang in case of failure of the actuator.
  • the Anfahrstrang a transverse to the transport path recess, preferably a slot or a U-shaped recess, and on the Anfahrstrang on, engaging in the recess, displaceable bolt, is secured.
  • a locking device is designed as a displaceable or pivotable plate, wherein the plate is designed to be displaceable by an actuating device.
  • Fig. 1 is a vertical caster in a longitudinal section with the essential components of the invention shown schematically. It comprises a mold 1, in which a cast strand of molten steel is formed during the casting process, and an adjoining vertical strand guide 2, in which the cast strand is continuously cooled, guided and supported.
  • the strand guide is formed by a series of strand guide segments, of which four strand guide segments 3a, 3b, 3c, 3d are shown as representative.
  • the transport path 6 for the dummy bar 4 and the cast strand through the strand guide 2 is formed by two rows of strand guide rollers 7a and 7b, which are grouped together and stored in the strand guide segments 3a to 3d.
  • a series of strand guide rollers 7a are fixedly supported on the outside of the strand guide segment and the second series of strand guide rollers 7b are arranged on the inside of the strand guide segment so as to be movable relative to the first series of strand guide rollers.
  • This relative mobility allows, for example, the adjustment to a desired strand thickness or a reduction in thickness in a cast strand with, for example, still liquid core.
  • the outer and the inner strand guide rollers 7a and 7b are rotatably supported in a support frame.
  • strand guide rollers 7a, 7b are designed as drivable strand guide rollers 7c and / or as engageable strand guide rollers 7d and determine the speed of the casting strand or the withdrawal speed of the starter strand 4.
  • a starter strand 4th from below into the Threaded strand guide 2.
  • the strand guide segments 3b to 3d each have a locking device 8a to 8c.
  • the different phases of threading are in FIG. 1 marked with the numbers 1 to 4.
  • phase 1 the continuous casting plant is shown at the beginning of the threading process.
  • all locking devices 8a, 8b, 8c are opened, the dummy bar 4 is threaded from below into the strand guide segment 3d and moved by means of drivable and / or adjustable strand guide rollers 7c, 7d against the strand transport direction R.
  • phase 2 the Anfahrstrang 4 has already passed the strand guide segment 3d and the locking device 8c has been closed, whereby the Anfahrstrang is secured against falling. Subsequently, the Anfahrstrang is in turn moved by means of drivable and / or engageable strand guide rollers 7c, 7d and secured by means of the locking device 8b in phase 3 and 8a in phase 4.
  • phase 4 of the Anfahrstrang has reached the starting position for the casting start, whereby the head of the Anfahrstrangs 4 closes the mold 1 on the output side.
  • the Anfahrstrang can also be threaded from above, ie from the casting platform, through the mold in the strand guide (eng., Top feeding ) .
  • the Anfahrstrang is usually introduced by a movable on the casting platform Anfahrstrangwagen or a crane through the mold and lowered to a locked locking device. Afterwards the crane is suspended from the starting line, so that any incorrect operation is excluded. Furthermore, the drivable and / or engageable strand guide rollers are turned on and the Anfahrstrang accurately positioned in the strand guide and the locking device again locked. Also in this embodiment, it is advantageous, depending on the length of the Anfahrstrangs at least one locking device to keep closed during threading and so to secure the Anfahrstrang.
  • Fig. 2 is holding the Anfahrstrangs 4 and the extraction of the Anfahrstrangs 4 with the casting 5 from the mold 1 shown.
  • the starting line is held by the drivable and / or engageable strand guide rollers and secured by the locking device 8a.
  • the locking device 8a is unlocked, ie unlocked, and the starter strand 4 with the forming cast strand 5 from the mold 1 in the strand conveying direction R pulled out.
  • the locking devices 8a to 8c of the successive strand guide segments 3b, 3c, 3d are subsequently sequentially unlocked, whereby the starting and the casting strand are secured even when pulling out.
  • a strand guide segment 3 a strand guide a vertical caster is shown.
  • the strand guide segment consists essentially of a support frame 12, the outer and inner strand guide rollers 7a, 7b, and the locking device 8, which comprises a displaceable on the upper end face 9 of the strand guide segment 3 executed plate 9 and a, designed as a pressure cylinder actuation device 11.
  • the outer, arranged in strand transport direction R bottom, strand guide roller 7c is designed as a drivable strand guide roller.
  • the also arranged below, but internal strand guide roller 7d is designed as a, by means of an adjusting device 13 designed as a hydraulic cylinder, as engageable strand guide roller.
  • the strand guide rollers 7b, 7d in the support frame 12 are designed to be movable relative to the strand guide rollers 7a, 7c, making it possible to adjust to the starting or casting strand or to reduce the thickness of the cast strand.
  • the plate 10 is the Arretier Hughes 8 moved by means of the actuator 11 from a lying outside the transport path 6 release position in a transport path blocking catchment position.
  • the pressure cylinder of the actuator operates against a - the starting position of the plate over the transport path 6 defining position - not shown spring, so that the plate in case of failure of a hydraulic, electrical or communication device automatically in the starting position, ie via the transport path 6, is moved.
  • Fig. 4 is a schematic representation of the threading of a starter strand 4 in a formed from a driving pulley frame strand guide 2 shown.
  • phase 1 is the - launched either by means of a crane through the mold 1 in the strand guide 2 ( top feeding ), or from below by means of engagable and driven strand guide rollers 7c, 7d introduced dummy bar 4 on the locked, designed as a bolt , Arretier sympathy 8c on.
  • the engageable and drivable strand guide rollers 7c, 7d employed, possibly suspended the crane, the locking device 8c unlocked and the Anfahrstrang 4 accurately positioned.
  • the launch line has the target position, cf. reached the start position above, and executed as a bolt locking device 8c is displaced by means of an actuating device, not shown in a slot of the Anfahrstrangs.
  • phase 4 therefore, the starting line is completely secured in the starting position.
  • Fig. 5 is a part of the strand guide a vertical caster shown.
  • the threaded starter strand 4 is held by engageable and drivable strand guide rollers 7c, 7d and, as soon as the starter strand has reached the starting position, is secured by a locking device 8 designed as a bolt in cassette construction.
  • the actuator for the locking device 8 is as hydraulic Pressure medium cylinder executed, whereby the Anfahrstrang is automatically secured by the area ratio of the pressure medium cylinder in conjunction with a hydraulic pressure accumulator, not shown. Due to the design of the locking device in cassette construction also a quick assembly and disassembly is possible.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Continuous Casting (AREA)

Claims (13)

  1. Procédé de blocage d'une fausse barre (4) dans un guidage de barre (2) comprenant plusieurs rouleaux de guidage de barre (7a, 7b) d'une installation de coulée continue, dans lequel
    - lors de l'introduction, la fausse barre (4) est transportée par des rouleaux de guidage de barre entraînables (7c) ;
    - avant le début de la coulée, la fausse barre (4) est maintenue dans une position de départ, fermant une lingotière (1) côté sortie, par des rouleaux de guidage de barre resserrables (7d); et
    - la fausse barre (4) et une barre de coulée (5) se formant après le début de la coulée sont extraites par des rouleaux de guidage de barre entraînables (7c) ;
    - la fausse barre (4), lors de l'introduction et du maintien, étant bloquée par au moins un dispositif d'arrêt (8, 8a, 8b, 8c) monté en aval dans le sens de transport (R) de la barre ; et
    - le blocage et le déblocage de la fausse barre (4) au moyen du dispositif d'arrêt (8, 8a, 8b, 8c) s'effectuant par une fermeture et une libération d'une voie de transport (6) formée par les rouleaux de guidage de barre (7a, 7b, 7c, 7d) ;
    caractérisé en ce que
    plusieurs dispositifs d'arrêt (8, 8a, 8b, 8c) sont répartis dans le guidage de barre (2), lesquels dispositifs sont bloqués de manière séquentielle lors de l'introduction de la fausse barre (4) et débloqués de manière séquentielle après le début de la coulée.
  2. Procédé selon l'une des revendications précédentes, caractérisé en ce qu'un dispositif d'arrêt (8, 8a, 8b, 8c) bloque automatiquement la fausse barre (4) lors d'une défaillance d'un dispositif électrique, hydraulique, pneumatique ou de communication, par exemple par une plaque (10) ou une tige positionnée en biais, le poids propre du dispositif d'arrêt définissant une position de réception du dispositif d'arrêt, et le dispositif d'arrêt pouvant passer dans une position de libération par l'intermédiaire d'un dispositif d'actionnement (11).
  3. Procédé selon l'une des revendications précédentes, caractérisé en ce que lors d'un brusque détachement et d'une chute de la fausse barre (4), celle-ci est interceptée, et empêchée de poursuivre sa descente, par au moins un dispositif d'arrêt (8, 8a, 8b, 8c) monté en aval dans le sens de transport (R) de la barre.
  4. Installation de coulée continue avec une lingotière (1) suivie, dans le sens de transport de la barre, d'un guidage de barre (2) comprenant plusieurs rouleaux de guidage de barre (7a, 7b), et avec une fausse barre (4) qui ferme la lingotière (1) côté sortie au début de la coulée et qui peut être maintenue et déplacée dans le guidage de barre (2) par des rouleaux de guidage de barre entraînables et resserrables (7c, 7d), les rouleaux de guidage de barre (7a, 7b) formant un chemin de transport (6) pour la fausse barre (4), caractérisée en ce que plusieurs dispositif d'arrêt (8, 8a, 8b, 8c) pour la fausse barre (4) sont répartis dans le guidage de barre (2), lesquels dispositifs sont conçus chacun pour passer, en un mouvement vers l'avant et vers l'arrière, d'une position de libération, située à l'extérieur du chemin de transport (6), dans une position de réception bloquant le chemin de transport (6) de la fausse barre (4).
  5. Installation de coulée continue selon la revendication 4, caractérisée en ce que l'installation de coulée continue est conçue comme installation de coulée continue verticale.
  6. Installation de coulée continue selon la revendication 4, caractérisée en ce que l'installation de coulée continue est conçue comme installation de coulée continue courbe.
  7. Installation de coulée continue selon l'une des revendications 4 à 6, caractérisée en ce qu'un dispositif d'arrêt (8, 8a, 8b, 8c) est disposé sur une face d'extrémité (9) d'un segment de guidage de barre (3, 3a, 3b, 3c) ou d'une cage de rouleaux d'entraînement ou entre deux rouleaux de guidage de barre (7a, 7b) voisins dans le sens de transport (R) de la barre.
  8. Installation de coulée continue selon l'une des revendications 4 à 7, caractérisée en ce qu'un dispositif d'arrêt (8, 8a, 8b, 8c) est disposé dans une structure de support séparée.
  9. Installation de coulée continue selon l'une des revendications 4 à 8, caractérisée en ce qu'un dispositif d'arrêt (8, 8a, 8b, 8c) est réalisé sous la forme d'une tige coulissante ou pivotante, ladite tige étant conçue pour être déplacée par un dispositif d'actionnement (11).
  10. Installation de coulée continue selon l'une des revendications 4 à 9, caractérisée en ce qu'un dispositif d'arrêt (8, 8a, 8b, 8c) est réalisé sous la forme d'une plaque (10) ou d'une tige positionnée en biais et coulissante, le poids propre du dispositif d'arrêt définissant la position de réception du dispositif d'arrêt (8, 8a, 8b, 8c), et le dispositif d'arrêt pouvant passer dans une position de libération par l'intermédiaire d'un dispositif d'actionnement (11).
  11. Installation de coulée continue selon l'une des revendications 4 à 10, caractérisée en ce que le dispositif d'actionnement (11) comprend un accumulateur de pression, ledit accumulateur de pression définissant la position de réception du dispositif d'arrêt (8, 8a, 8b, 8c) au moyen d'un dispositif d'actionnement (11) se présentant sous forme de vérin à fluide sous pression.
  12. Installation de coulée continue selon l'une des revendications 4 à 10, caractérisée en ce que le dispositif d'actionnement (11) comprend un ressort, la force de ressort définissant la position de réception du dispositif d'arrêt (8, 8a, 8b, 8c).
  13. Installation de coulée continue selon l'une des revendications 4 à 12, caractérisée en ce qu'un dispositif d'arrêt (8, 8a, 8b, 8c) est réalisé sous la forme d'une plaque (10) coulissante ou pivotante, ladite plaque étant conçue pour être déplacée par un dispositif d'actionnement (11).
EP10728647.8A 2009-07-17 2010-06-25 Procédé de blocage d une fausse barre dans une installation de coulée continue et installation de coulée continue présentant ladite fausse barre Not-in-force EP2454038B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
ATA1128/2009A AT508517B1 (de) 2009-07-17 2009-07-17 Verfahren zum sichern eines anfahrstranges in einer stranggiessanlage und stranggiessanlage mit anfahrstrang
PCT/EP2010/059051 WO2011006748A1 (fr) 2009-07-17 2010-06-25 Procédé de blocage d’une fausse barre dans une installation de coulée continue et installation de coulée continue présentant ladite fausse barre

Publications (2)

Publication Number Publication Date
EP2454038A1 EP2454038A1 (fr) 2012-05-23
EP2454038B1 true EP2454038B1 (fr) 2015-03-18

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Application Number Title Priority Date Filing Date
EP10728647.8A Not-in-force EP2454038B1 (fr) 2009-07-17 2010-06-25 Procédé de blocage d une fausse barre dans une installation de coulée continue et installation de coulée continue présentant ladite fausse barre

Country Status (8)

Country Link
EP (1) EP2454038B1 (fr)
KR (1) KR101757634B1 (fr)
CN (1) CN102470428B (fr)
AT (1) AT508517B1 (fr)
BR (1) BR112012001068A2 (fr)
ES (1) ES2537232T3 (fr)
RU (1) RU2527568C2 (fr)
WO (1) WO2011006748A1 (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113305278B (zh) * 2021-05-07 2022-07-22 中国重型机械研究院股份公司 一种引锭杆起步下拉无下滑的控制装置及方法
CN117380916B (zh) * 2023-12-08 2024-02-23 成都利华强磁浮连铸科技有限责任公司 一种磁悬浮连铸系统及磁悬浮连铸方法

Family Cites Families (11)

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Publication number Priority date Publication date Assignee Title
BE626696A (fr) * 1962-01-12
DE1953094A1 (de) * 1969-10-22 1971-04-29 Schloemann Ag Sicherheitsvorrichtung fuer Stranggiessanlagen und Verfahren zur Betaetigung derselben
JPS5938063B2 (ja) * 1981-05-29 1984-09-13 新日本製鐵株式会社 連続鋳造設備におけるダミ−バ
JPS5952017B2 (ja) * 1981-06-20 1984-12-17 新日本製鐵株式会社 ダミ−バ−の連結確認装置
AT376156B (de) * 1983-03-03 1984-10-25 Voest Alpine Ag Einrichtung zum hochfoerdern eines anfahrstranges in einer stranggiessanlage
DE3525969A1 (de) * 1985-07-20 1987-01-29 Schloemann Siemag Ag Distanzhaltevorrichtung fuer anfahrstraenge in einer stranggiessanlage
DE10049445A1 (de) * 2000-10-06 2002-04-18 Sms Demag Ag Vorrichtung zum Stranggießen von Metallen, insbesondere von Stahl für das Solidified-Bending-Verfahren
JP4135351B2 (ja) * 2001-10-12 2008-08-20 株式会社日立製作所 多列圧延機及びその使用方法並びに圧延設備
KR101016447B1 (ko) * 2003-06-09 2011-02-21 주식회사 포스코 더미바 추락 방지용 디바이스
AT506835B1 (de) * 2008-05-16 2010-09-15 Siemens Vai Metals Tech Gmbh Verfahren zum sichern eines anfahrstranges in einer stranggiessanlage und stranggiessanlage mit einem anfahrstrang
CN201313163Y (zh) * 2008-12-12 2009-09-23 鞍钢股份有限公司 一种板坯连铸机引锭头的封堵结构

Also Published As

Publication number Publication date
KR101757634B1 (ko) 2017-07-14
CN102470428B (zh) 2014-06-18
EP2454038A1 (fr) 2012-05-23
ES2537232T3 (es) 2015-06-03
AT508517A1 (de) 2011-02-15
CN102470428A (zh) 2012-05-23
RU2527568C2 (ru) 2014-09-10
AT508517B1 (de) 2013-05-15
BR112012001068A2 (pt) 2016-03-29
KR20120037994A (ko) 2012-04-20
WO2011006748A1 (fr) 2011-01-20
RU2012105534A (ru) 2013-08-27

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