EP2281905A1 - Augmentation de la rigidité de l'iridium, du rhodium et de leurs alliages - Google Patents
Augmentation de la rigidité de l'iridium, du rhodium et de leurs alliages Download PDFInfo
- Publication number
- EP2281905A1 EP2281905A1 EP20100005962 EP10005962A EP2281905A1 EP 2281905 A1 EP2281905 A1 EP 2281905A1 EP 20100005962 EP20100005962 EP 20100005962 EP 10005962 A EP10005962 A EP 10005962A EP 2281905 A1 EP2281905 A1 EP 2281905A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- iridium
- alloys
- rhodium
- calcium
- boron
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C5/00—Alloys based on noble metals
- C22C5/04—Alloys based on a platinum group metal
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/14—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of noble metals or alloys based thereon
Definitions
- the invention relates to iridium and its Zr and Hf-free alloys and rhodium and its Zr and Hf-free alloys with high creep rupture strength at high temperatures.
- Iridium as one of the platinum group metals is used, for example, in crucibles for growing single crystals of refractory oxide melts, e.g. from Nd: YAG laser crystals, or used in components for the glass industry.
- crucibles for growing single crystals of refractory oxide melts, e.g. from Nd: YAG laser crystals, or used in components for the glass industry.
- a high creep and creep rupture strength of the iridium at high temperatures is of crucial importance.
- tungsten and / or zirconium-containing iridium alloys are described for high temperature applications which additionally contain from 0.01 to 0.5% by weight of further elements such as molybdenum and hafnium and optionally ruthenium at from 0.01 to 10% by weight.
- JP 56-81646 A Platinum-based jewelery alloys containing calcium boride or boron for increasing strength, especially hardness, after high temperature treatment such as brazing, are described.
- the object of the present invention is the creep rupture strength of iridium at high Temperature while maintaining the ductility and processability of the material to increase, without using the said elements. It is accordingly advantageous if the material in question is also free of titanium.
- the creep strength of the iridium doped in this way increases by 20 to 30% at a temperature of 1800 ° C. in comparison to undoped iridium by the addition of calcium and boron in the range of a few ppm. It is expected that this will also be achieved for iridium alloys as well as rhodium and its alloys.
- the service lives are in a range of 1403.7 h (about 58.5 days) at 6.7 MPa to 0.73 h at 25 MPa and decrease with increasing voltage. As the strain rate increases with increasing stress, the elongations at break do not show a significant tendency.
- Table 2 Values from the creep rupture curve of the undoped lr batch Lifetime [h] Creep rupture strength [MPa] Strain rate [s -1 ] 10 16.9 6.5 ⁇ 10 -6 100 11.0 5.6 x 10 -7 1000 7.2 4.9 ⁇ 10 -8
- the iridium ingot was then forged analogously to the undoped iridium batch in the comparative example and rolled to a final thickness of 1 mm.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Turbine Rotor Nozzle Sealing (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Materials For Medical Uses (AREA)
- Investigating Strength Of Materials By Application Of Mechanical Stress (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102009031168A DE102009031168A1 (de) | 2009-06-29 | 2009-06-29 | Festigkeitserhöhung von Iridium, Rhodium und ihren Legierungen |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2281905A1 true EP2281905A1 (fr) | 2011-02-09 |
EP2281905B1 EP2281905B1 (fr) | 2015-08-12 |
Family
ID=42790582
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP10005962.5A Active EP2281905B1 (fr) | 2009-06-29 | 2010-06-10 | Augmentation de la rigidité de l'iridium |
Country Status (4)
Country | Link |
---|---|
US (1) | US8613788B2 (fr) |
EP (1) | EP2281905B1 (fr) |
JP (1) | JP2011006791A (fr) |
DE (1) | DE102009031168A1 (fr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3216883A1 (fr) | 2016-03-07 | 2017-09-13 | Heraeus Deutschland GmbH & Co. KG | Alliage iridium-platine et article usiné constitué de celui-ci |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3766997A1 (fr) * | 2019-07-18 | 2021-01-20 | The Swatch Group Research and Development Ltd | Procédé de fabrication d'alliages de métaux précieux et alliages de métaux précieux ainsi obtenus |
CN115319424B (zh) * | 2022-09-16 | 2024-02-06 | 咸阳三毅有岩科技有限公司 | 一种薄壁铱坩埚的加工方法及薄壁铱坩埚 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3970450A (en) * | 1975-07-16 | 1976-07-20 | The United States Of America As Represented By The United States Energy Research And Development Administration | Modified iridium-tungsten alloy |
JPS5681646A (en) | 1979-12-08 | 1981-07-03 | Tanaka Kikinzoku Kogyo Kk | Platinum alloy for accessory |
WO2004007782A1 (fr) | 2002-07-13 | 2004-01-22 | Johnson Matthey Public Limited Company | Alliage |
DE102005032591A1 (de) | 2005-07-11 | 2007-04-05 | W.C. Heraeus Gmbh | Dotiertes Iridium mit verbesserten Hochtemperatureigenschaften |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE157709C (fr) | 1904-02-22 | |||
US3918965A (en) * | 1974-04-26 | 1975-11-11 | Us Energy | Iridium-hafnium alloy |
US4014692A (en) * | 1976-01-09 | 1977-03-29 | Owens-Corning Fiberglas Corporation | Platinum-rhodium alloys having low creep rates |
US4123263A (en) * | 1977-11-02 | 1978-10-31 | Owens-Corning Fiberglas Corporation | Platinum-rhodium alloys |
DD157709A1 (de) * | 1981-03-31 | 1982-12-01 | Klaus Schwarz | Platinmetallegierung |
US4444728A (en) * | 1982-01-21 | 1984-04-24 | Engelhard Corporation | Iridium-rhenium crucible |
JPH07258767A (ja) | 1994-03-18 | 1995-10-09 | Tanaka Kikinzoku Kogyo Kk | 硬質Pt金属又は硬質Pt合金の製造方法 |
JP3135224B2 (ja) | 1996-05-10 | 2001-02-13 | 株式会社フルヤ金属 | イリジウム基合金 |
JP3413488B2 (ja) | 2000-04-20 | 2003-06-03 | 独立行政法人物質・材料研究機構 | イリジウム基超合金 |
JP4722576B2 (ja) | 2004-06-16 | 2011-07-13 | 新日鉄マテリアルズ株式会社 | 半導体実装用ボンディングワイヤの製造方法 |
WO2007091576A1 (fr) | 2006-02-09 | 2007-08-16 | Japan Science And Technology Agency | Alliage à base d'iridium ayant une résistance à la chaleur élevée et une résistance élevée et procédé servant à produire celui-ci |
JP2008019487A (ja) | 2006-07-14 | 2008-01-31 | Ishifuku Metal Ind Co Ltd | Rh基合金 |
KR100831578B1 (ko) * | 2006-12-05 | 2008-05-21 | 한국원자력연구원 | 원자력용 우수한 내식성을 갖는 지르코늄 합금 조성물 및이의 제조방법 |
-
2009
- 2009-06-29 DE DE102009031168A patent/DE102009031168A1/de not_active Withdrawn
-
2010
- 2010-06-10 EP EP10005962.5A patent/EP2281905B1/fr active Active
- 2010-06-28 US US12/824,398 patent/US8613788B2/en active Active
- 2010-06-29 JP JP2010147186A patent/JP2011006791A/ja active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3970450A (en) * | 1975-07-16 | 1976-07-20 | The United States Of America As Represented By The United States Energy Research And Development Administration | Modified iridium-tungsten alloy |
JPS5681646A (en) | 1979-12-08 | 1981-07-03 | Tanaka Kikinzoku Kogyo Kk | Platinum alloy for accessory |
WO2004007782A1 (fr) | 2002-07-13 | 2004-01-22 | Johnson Matthey Public Limited Company | Alliage |
DE102005032591A1 (de) | 2005-07-11 | 2007-04-05 | W.C. Heraeus Gmbh | Dotiertes Iridium mit verbesserten Hochtemperatureigenschaften |
Non-Patent Citations (2)
Title |
---|
E.K. OHRINER: "Purification of Iridium by Electron Beam Melting", JOURNAL OF ALLOYS AND COMPOUNDS, no. 461, 26 July 2007 (2007-07-26), USA, pages 633 - 640, XP002603403 * |
Y.F. GU ET AL: "Microstructures and Fracture behaviours of B-Free and B-Doped Ir3Nb (L1) Intermetallic Compounds", MATERIALS SCIENCE AND ENGINEERING, 1 January 2002 (2002-01-01), XP002603404 * |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3216883A1 (fr) | 2016-03-07 | 2017-09-13 | Heraeus Deutschland GmbH & Co. KG | Alliage iridium-platine et article usiné constitué de celui-ci |
WO2017153264A1 (fr) | 2016-03-07 | 2017-09-14 | Heraeus Deutschland GmbH & Co. KG | Alliage iridium-platine et article usiné fabriqué à partir de celui-ci |
Also Published As
Publication number | Publication date |
---|---|
JP2011006791A (ja) | 2011-01-13 |
EP2281905B1 (fr) | 2015-08-12 |
US20100329922A1 (en) | 2010-12-30 |
DE102009031168A1 (de) | 2010-12-30 |
US8613788B2 (en) | 2013-12-24 |
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