EP2254423B1 - Improved confectionery aroma containing products - Google Patents

Improved confectionery aroma containing products Download PDF

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Publication number
EP2254423B1
EP2254423B1 EP09712484.6A EP09712484A EP2254423B1 EP 2254423 B1 EP2254423 B1 EP 2254423B1 EP 09712484 A EP09712484 A EP 09712484A EP 2254423 B1 EP2254423 B1 EP 2254423B1
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EP
European Patent Office
Prior art keywords
isomalt
product
weight
component
coating
Prior art date
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Active
Application number
EP09712484.6A
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German (de)
English (en)
French (fr)
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EP2254423A1 (en
Inventor
Jörg Kowalczyk
Ingrid Willibald-Ettle
Margit Arenz
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Suedzucker AG
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Suedzucker AG
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Publication date
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Publication of EP2254423A1 publication Critical patent/EP2254423A1/en
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Classifications

    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G1/00—Cocoa; Cocoa products, e.g. chocolate; Substitutes therefor
    • A23G1/30—Cocoa products, e.g. chocolate; Substitutes therefor
    • A23G1/32—Cocoa products, e.g. chocolate; Substitutes therefor characterised by the composition containing organic or inorganic compounds
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G1/00—Cocoa; Cocoa products, e.g. chocolate; Substitutes therefor
    • A23G1/30—Cocoa products, e.g. chocolate; Substitutes therefor
    • A23G1/32—Cocoa products, e.g. chocolate; Substitutes therefor characterised by the composition containing organic or inorganic compounds
    • A23G1/36—Cocoa products, e.g. chocolate; Substitutes therefor characterised by the composition containing organic or inorganic compounds characterised by the fats used
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G4/00—Chewing gum
    • A23G4/06—Chewing gum characterised by the composition containing organic or inorganic compounds
    • A23G4/068—Chewing gum characterised by the composition containing organic or inorganic compounds containing plants or parts thereof, e.g. fruits, seeds, extracts
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G9/00—Frozen sweets, e.g. ice confectionery, ice-cream; Mixtures therefor
    • A23G9/32—Frozen sweets, e.g. ice confectionery, ice-cream; Mixtures therefor characterised by the composition containing organic or inorganic compounds

Definitions

  • the present invention relates to confectionery products comprising an isomalt component, a geraniol containing aroma component and at least one product additive as well as processes to obtain them.
  • US 2003/129143 discloses confectionery compositions which provide enhanced oral malodour benefits comprising specified metal cations, water and confectionery carrier.
  • Geraniol can be used as essential oil having anti-bacterial properties.
  • US 2004/253189 discloses breath freshening and oral cleansing product using geraniol.
  • the oral products of this invention are chewing gums, confections, mouthwashes, mouth sprays and edible thin film products.
  • geraniol is delivered in an oral product for convenient oral cleansing and breath freshening benefits.
  • Geraniol also called rhodinol, is a monoterpenoid and an alcohol. It is the primary part of oil-of-rose, palmarosa oil and citronella oil. It also occurs in small quantities in geranium, lemon and many other essential oils. It appears as a clear to pale-yellow oil, which is insoluble in water, but soluble in most common organic solvents. It has a rose-like odour, for which it is commonly used in perfumes. Further-more, research has shown geraniol to be an effective plant based insect repellent.
  • the technical problem underlying the present invention is to provide confectionery products, which not only fulfil organoleptical demands of the consumer, but further harbour at least one further additional beneficial effect which increases the consumers' acceptance.
  • the present invention solves the underlying technical problem by the provision of a confectionery product, which comprises an isomalt component, a geraniol containing aroma component and at least one product additive.
  • the present invention solves the above-identified technical problem by providing a confectionery product comprising a mixture of an isomalt component, a geraniol containing aroma component and at least one product additive, wherein the confectionery product comprises 1.0 to 99.8 weight-% of the isomalt component, 0.1 to 5.0 weight-%, preferably 0.2 to 4.0 weight-%, most preferably 0.5 to 2.0 weight-% of the geraniol containing aroma component and 0.1 to 98.0 weight-% of at least one product additive (each based on total weight of confectionery product and all constituents adding up to 100.0% of dry matter of the confectionery product).
  • the combination of the isomalt component with the geraniol containing aroma component surprisingly leads in confectionery products, in particular in chewing gums, coated chewing gums, soft caramels, tablets and hard caramels, to a very favourable aroma release profile, in particular a continuous, long lasting and constant release and exhalation from the skin of the consumer which in addition very rapidly starts after consumption of the product. Furthermore, it could be shown that the isomalt component increases the storage stability of the aroma component in the confectionery product.
  • the isomalt component acts as an odour release elevator.
  • the isomalt component within the confectionery product of the present invention has the advantage to mask the unpleasant taste of the geraniol.
  • the geraniol containing aroma component exhibits in combination with the isomalt component a homogenous distribution, especially when used in hard caramels. In chewing gums and soft candies an improved, in particular longer lasting chewability was observed.
  • the term “isomalt component” preferably encompasses isomalt, isomalt ST, isomalt GS, an isomalt variant or component thereof.
  • the isomalt component is selected from the group consisting of 1,1-GPS (1-O- ⁇ -D-glucopyranosyl-D-sorbitol), 1,1-GPM (1-O- ⁇ -D-glucopyranosyl-D-mannitol), 1,6-GPS (6-O- ⁇ -D-glucopyranosyl-D-sorbitol), isomalt, isomalt ST and isomalt GS.
  • isomalt is a mixture of 1,6-GPS and 1,1-GPM
  • isomalt ST is a mixture of 53 to 47%-1,6-GPS and 47 to 53% 1,1-GPM
  • Isomalt GS is a mixture of 71 to 79% 1,6-GPS and 29 to 21% 1,1-GPM, preferably 75% 1,6-GPS to 25% 1,1-GPM (values given in weight-% on dry matter).
  • isomalt variants are for instance mixtures of 10 to 50% 1,6-GPS, 2 to 20% 1,1-GPS and 30 to 70% 1,1-GPM or mixtures of 5 to 10% 1,6-GPS, 30 to 40% 1,1-GPS and 45 to 60% 1,1-GPM.
  • Isomalt variants may also be in form of 1,6-GPS enriched mixtures.
  • 1,6-GPS enriched mixtures have an 1,6-GPS amount of 58 to 99 % and an 1,1-GPM amount of 42 to 1 %.
  • 1,1-GPM enriched mixtures have an 1,6-GPS amount of 1 to 42 % and an 1,1-GPM amount of 58 to 99 %.
  • the isomalt component used is a milled and agglomerated isomalt, in particular a milled and agglomerated isomalt, wherein the milled isomalt particles have a diameter of less than 100 ⁇ m, preferably less than 50 ⁇ m.
  • a milled and agglomerated isomalt is isomalt DC.
  • the confectionery product comprises the isomalt component in form of particles, wherein 90% of said particles have a diameter of less than 100 ⁇ m, preferably less than 50 ⁇ m.
  • Particle size as described herein is measured by scanning electron microscopy (SEM) or other optical or scanning techniques, for example using a coulter counter.
  • the isomalt component is a mixture of isomalt and maltitol, preferably of isomalt GS or isomalt ST and maltitol, further preferred isomalt and maltitol syrup or of isomalt GS or isomalt ST and maltitol syrup.
  • the mixture comprises 60 to 80%, in particular 70% isomalt, preferably isomalt ST or GS, and 40 to 20%, in particular 30 % maltitol (values given in weight-% on dry matter).
  • the geraniol containing aroma component is a geraniol containing oil.
  • the geraniol containing oil comprises 5 to 90, preferably 10 to 80, most preferred 10 to 20 weight-% (based on the total weight of oil) geraniol.
  • the geraniol containing oil is an oil from geranium, lemon, coriander, bay leaves, nutmeg, tobacco and rose. In a preferred embodiment it is an oil-of-rose, palmarosa oil or citronella oil, in particular of the java type.
  • the confectionery product is sugar-free, in particular free of sucrose, free of glucose, free of lactose and/or free of fructose or free of combinations of at least two of these sugars.
  • the confectionery product is tooth-friendly.
  • the confectionery product is selected from the group consisting of filled chewing gums, non-filled chewing gums, hard caramels, also called hard candies, soft caramels, also called soft candies, toffee, pastilles, tablets, gum, jellies, marshmallows, nougat, lozenges, fudge, fondant or chocolate products.
  • the mixture of the isomalt component and the geraniol containing aroma component provides hard candies showing a very high transparency, which are shiny and exhibit a very constant and highly efficient release of aroma. Furthermore, the hard candies of the present invention show a very homogenous distribution of the geraniol containing aroma component and improved sucking behaviour and a well-balanced aroma and sweetness impression, while simultaneously showing extraordinarily good storage stability, namely no visible crystallisation or the like.
  • coated chewing gums of the present invention also show a very good storage stability, a constant and good release of aroma, a well balanced aroma and sweetness impression and a constant and homogenous distribution of the geraniol containing aroma component.
  • the tablets or compressed products of the present invention show an improved and high storage stability, a well balanced aroma and sweetness impression as well as a homogenous and even distribution of the geraniol containing component.
  • Soft caramels or soft candies of the present invention show a well-balanced aroma and sweetness impression, a highly efficient constant release of aroma, a very good and even distribution of the geraniol containing component, a high storage stability and an improved prolonged chewability.
  • the confectionery product is a coated product.
  • the coated product is a coated filled or non-filled chewing gum, a coated jelly, a coated tablet, a coated soft caramel or a coated chocolate product.
  • the geraniol containing aroma component is located in the preferred coated confectionery product of the present invention solely in the coating.
  • the geraniol containing aroma component is located in the confectionery product according to the present invention solely in the centre of the confectionery product and not in the coating.
  • at least part of the isomalt component is associated with the geraniol containing aroma component, namely in case the geraniol containing component is located solely in the coating, at least part of the isomalt component is also contained in the coating.
  • at least part of the isomalt component is also contained in the centre.
  • the geraniol containing component together with the isomalt component is located both in the coating and in the centre of the preferred coated confectionery products of the present invention.
  • the coated product comprises 15 to 70, preferably 25 to 45, weight-% product coating (based on dry weight of the overall coated product).
  • the coated product comprises 30 to 85, preferably 55 to 75 weight-% product core (based on the dry weight of the overall coated product).
  • the product coating may comprise 1, 2 or more, for instance 50 to 100 layers of product coating material.
  • said layers may be of the same or different compositions.
  • product additives may be present in the confectionery product or its coating.
  • a product additive is any substance which may be added into the preparation process to easily influence the preparation process itself and/or influence product characteristics, which may either be relevant for the process or for the finally obtained product, for instance its organoleptic, sensoric, physiological, storage or optical behaviour.
  • the confectionery product comprises at maximum 98 weight-%, namely 0.1 to 98 weight-%, preferably 0.1 to 90 weight-%, preferably 10 to 85 weight-%, most preferably 1 to 75 weight-% of such product additives.
  • the product additive is selected from the group consisting of sugars, preferably tooth-friendly sugars, sugar alcohols, intense sweeteners, hydrocolloid, gum base, plastifiers, lubricant, emulsifiers, protein components, milk components, dairy ingredients, fat and fat substitutes, vegetable fat, vitamins, minerals, pharmaceutically active ingredients, preservatives, further aroma, flavourings, such as peppermint, menthol, fruit, strawberry flavour, colours, TiO 2 , edible acids, such as citric acid, and dietary fibres.
  • sugars preferably tooth-friendly sugars, sugar alcohols, intense sweeteners, hydrocolloid, gum base, plastifiers, lubricant, emulsifiers, protein components, milk components, dairy ingredients, fat and fat substitutes, vegetable fat, vitamins, minerals, pharmaceutically active ingredients, preservatives, further aroma, flavourings, such as peppermint, menthol, fruit, strawberry flavour, colours, TiO 2 , edible acids, such as citric acid, and dietary fibres.
  • the tooth-friendly sugar is selected from the group consisting of isomaltulose, nutriose, leukrose and polydextrose.
  • the sugar is isomaltulose.
  • the amount of non-tooth-friendly ingredients is at maximum 1 weight-% (on total weight of the confectionery product).
  • the sugar alcohol is selected from the group of xylitol, mannitol, maltitol, erythritol, lactitol or sorbitol.
  • the isomalt component is the only sweetening agent present in the confectionery product of the present invention.
  • the isomalt component is the only sugar alcohol present in the confectionery product of the present invention.
  • the isomalt component is the only sweetening agent providing a body to the confectionery product of the present invention.
  • an intense sweetener may also be present in the confectionery product.
  • the intense sweetener is selected from the group of cyclamate, saccharin, aspartame, glycyrrhicine, neohesperidine-dihydrochalcone, steveoside, thaumatin, monellin, acesulfame, alitame, sucralose or a mixture thereof.
  • It is a further object of the present invention to provide a process for the preparation of a hard caramel mass comprising 1 to 99.8 weight-% of an isomalt component, 0.1 to 5.0 weight-%, preferably 0.2 to 4.0 weight-%, most preferably 0.5 to 2.0 weight-% of a geraniol containing aroma component and 0.1 to 98 weight-% of at least one product additive, wherein the process comprises a) dissolving the isomalt component in an aqueous medium, b) boiling the obtained solution to evaporate the aqueous medium, c) cooling the obtained mass, d) adding and distributing the at least one product additive to obtain a hard caramel mass, wherein the geraniol containing aroma component is added and homogenously distributed in the boiled sweetener at the end of step b) or in step c) or d).
  • the end of step b) is reached once substantially all of the aqueous medium has been evaporated so as to leave a highly viscous
  • the boiling in step b) is done under vacuum.
  • a preferred embodiment of the present invention relates to a process for the preparation of a hard caramel mass comprising 1 to 99.8 weight-% of an isomalt component, 0.1 to 5.0 weight-%, preferably 0.2 to 4.0 weight-%, most preferably 0.5 to 2.0 weight-% of a geraniol containing aroma component and 0.1 to 98 weight-% of at least one product additive, wherein the process comprises a') melting the isomalt component, b') cooling the obtained hard caramel mass, c') adding and distributing the at least one product additive to obtain a hard caramel mass, wherein the geraniol containing aroma component is added and homogenously distributed in step a') or step b') or c').
  • the hard caramel mass as obtained according to the above boiling or melting process is shaped into a hard caramel.
  • a preferred embodiment of the present invention relates to a process for the preparation of a coated confectionery product, which comprises a product core or product centre and a product coating, the product coating comprising at least the coating ingredients at least an isomalt component, a geraniol containing aroma component and at least one product additive, preferably according to the above, which process comprises a) applying a coating medium comprising at least partially the coating ingredients to said product core and b) drying the coated product so as to obtain a product coating, which coating comprises 1 to 99.8 weight-% isomalt component, 0.1 to 5.0 weight-%, preferably 0.2 to 4.0 weight-%, most preferably 0.5 to 2.0 weight-% of a geraniol containing aroma component and 0.1 to 98 weight-% (each based on dry weight of product coating) of at least one product additive. If in one preferred embodiment only a part of the coating ingredients is added into the coating medium, then the other part is applied in a dusting or drying step thereafter.
  • drying of the coated core with a dry and powdered ingredient is also called dusting.
  • the coating medium is an aqueous medium, particularly water.
  • the drying of step b) is done by subjecting the coated product to air, in particular an air stream, having a temperature of 20°C to 80°C, preferably 30°C to 80°C.
  • the drying step b) is done by adding at least a part of the coating ingredients in dry and powdered form to the coated products during step b).
  • the coating medium is a coating solution or coating suspension.
  • step a) and before step b) the coated products are subjected to a distribution step, wherein the coated products are agitated to allow a homogenous distribution of the coating medium on the product core.
  • step a) all coating ingredients are applied in form of a coating medium, in particular a coating suspension.
  • a part of the coating ingredients is applied in the coating medium and a further part is applied in dry and powdered from, both of them in step a).
  • step b all of the geraniol containing aroma component of the product coating is added in step b).
  • all of the geraniol containing aroma components of the product coating is added in form of the oil and part of the isomalt component is added in dry and powdered form, both of them in step b).
  • step b At least a part if the isomalt component is added in dry and powdered from in step b).
  • steps a) and b) are repeated one or more times, preferably 8 to 120 times.
  • steps a) and b) are repeated 3 to 10 times.
  • the coating ingredients applied in powder form represent 30 to 75% by weight, preferably 40 to 75% by weight of the overall amount of the coating ingredients (each based on dry weight of the product coating).
  • the process of the present invention is carried out in at least two phases, wherein in a first phase of the process, the coating medium comprising a part of the coating ingredient is applied in step a) and the drying is done in step b) by adding part of the coating ingredients in dry and powdered form to the coated products one or more repeated times and wherein in a second phase of the process the coating medium is applied to the coated products in step a) and dried in step b) by subjecting the coated products to air without addition of dry and powdered coating ingredients one or more repeated times.
  • step b) the drying of step b) is done both by subjecting the coated products to air having a temperature of 20 to 80°C and by adding part of the coating ingredients in dry and powdered form to the coated products during step b).
  • steps a) and b) are repeated 3 to 50 times.
  • step b) in a first phase of the repetitions of steps a) and b) the drying of step b) is done by adding part of the coating ingredients in dry and powdered form to the coated products and wherein in a second phase of the repetitions only the coating medium is applied and the drying of step b) is done by subjecting the coated product to air having a temperature of 20 to 80°C.
  • Very storage-stable tablets were obtained with favourable organoleptic and sensoric properties, which provide a pleasant and long-lasting, continuously released rose-like odour by exhalation from the skin.
  • Isomalt ST and water are mixed in a pan followed by heating to dissolve the isomalt and boiling this mixture at a temperature from 155 to 160°C.
  • a 5 minute vacuum was applied so as to obtain a highly viscous caramel mass and after cooling of the mass to 110°C to 115°C the citric acid, the aroma, acesulfam K and the geraniol oil are added and are homogenously distributed.
  • the so prepared hard caramel mass was moulded to form hard candies.
  • the above-identified recipe without water has also been processed directly to a hard caramel in a melt extrusion process by simultaneously extruding the ingredients and forming hard caramels therefrom.
  • the geraniol oil has been added after boiling of the isomalt ST solution into the highly viscous, but still liquid hard caramel mass, which thereafter is transferred on a cooling belt and further processed by moulding and cooling in order to obtain the final hard caramels.
  • Hard caramels were obtained with favourable organoleptic, a high transparency and improved sensoric properties, which provide a pleasant long-lasting and continuously released rose-like odour by exhalation from the skin.
  • the hard caramels shown an excellent storage stability.
  • chewing base Nostic TWA 1400 g isomalt ST 2200 g sorbitol syrup (70% dry substance) 600 g geraniol oil 40 g glycerol 150 g menthol 150 g flavour (spearmint) 100 g aspartam 2.5 g acesulfam K 2.5 g
  • the chewing gum base is heated at approximately 55°C in a heating oven, before it is placed in a kneader; subsequently, the chewing gum base is kneaded for 1-2 minutes.
  • the powdery additives isomalt ST (1:1 mixture of 1,6-GPS and 1,1-GPM), geraniol oil, sweetener, menthol
  • flavour, sorbitol syrup and glycerol are added.
  • the kneading continues until the mass is homogenous (end temperature approximately 45°C). The mass is taken from the kneader and divided into portions which weigh approximately 1 kg.
  • the chewing gum mass divided into portions is placed in intermediate storage for approximately 15 to 20 min on a talc-strewn substrate, extruded with a suitable extruder, and further processed as usual.
  • Very storage-stable chewing gums were obtained with prolonged chewability, favourable organoleptic and sensoric properties, which provide a pleasant, long-lasting and continuously released rose-like odour by exhalation from the skin.
  • a coating solution comprising as coating ingredients 5500 g isomalt GS, 410 g of a 50% gum arabic solution (205 g gum arabic, dry matter) and 3980 g water was prepared. Chewing gum cushions with a weight of 1,018 g/pc are provided. In a coating drum, the coating solution is applied to the chewing gum cushions at 60°C, wherein during said coating a mixture of isomalt GS/PA (powder, 90% of the particles ⁇ 50 ⁇ m) and 0.1 % SiO 2 is sequentially added as powdery dry charges in a first phase of 2 x 160 g, in a second phase of 7 x 150 g and in a third phase of 4 x 170 g.
  • the applied coating layers are dried after each cycle with a constant air stream with a temperature ranging from 23 to 28°C. Afterwards, the geraniol oil is added to the coating solution and the coating solution is applied in a fourth phase in 5 cycles, in a fifth phase in 5 cycles and in a sixth phase in 3 cycles. The applied coating layers are dried after each cycle with a constant air stream.
  • a coated product is prepared comprising 33 weight-% coating and about 67 weight-% (each based on dry weight of final product) chewing gum centre.
  • a coated chewing gum was obtained with favourable organoleptic and sensoric properties, which provides a constant and continuously released pleasant rose-like odour by exhalation from the skin.
  • the coating showed a very good storage stability.
  • a coated chewing gum was obtained with favourable organoleptic and sensoric properties, which provides a constant and continuously released pleasant rose-like odour by exhalation from the skin.
  • the coating showed a very good storage stability.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • Botany (AREA)
  • Confectionery (AREA)
EP09712484.6A 2008-02-19 2009-02-05 Improved confectionery aroma containing products Active EP2254423B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US12/033,451 US20090208602A1 (en) 2008-02-19 2008-02-19 Confectionery aroma containing products
PCT/EP2009/000788 WO2009103428A1 (en) 2008-02-19 2009-02-05 Improved confectionery aroma containing products

Publications (2)

Publication Number Publication Date
EP2254423A1 EP2254423A1 (en) 2010-12-01
EP2254423B1 true EP2254423B1 (en) 2014-04-09

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Country Status (8)

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US (2) US20090208602A1 (ja)
EP (1) EP2254423B1 (ja)
JP (1) JP2011512131A (ja)
CN (1) CN101969785A (ja)
BR (1) BRPI0908095A8 (ja)
EA (1) EA018096B1 (ja)
ES (1) ES2467669T3 (ja)
WO (1) WO2009103428A1 (ja)

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US20060088574A1 (en) * 2004-10-25 2006-04-27 Manning Paul B Nutritional supplements

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BRPI0908095A2 (pt) 2015-08-25
BRPI0908095A8 (pt) 2016-06-28
ES2467669T3 (es) 2014-06-12
US20100316760A1 (en) 2010-12-16
EA018096B1 (ru) 2013-05-30
WO2009103428A8 (en) 2009-10-29
CN101969785A (zh) 2011-02-09
EP2254423A1 (en) 2010-12-01
JP2011512131A (ja) 2011-04-21
EA201070967A1 (ru) 2011-02-28
US20090208602A1 (en) 2009-08-20

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