EP2222909A2 - Garne, stoffe mit hoher verschleissfestigkeit und daraus hergestellte objekte - Google Patents

Garne, stoffe mit hoher verschleissfestigkeit und daraus hergestellte objekte

Info

Publication number
EP2222909A2
EP2222909A2 EP20080864155 EP08864155A EP2222909A2 EP 2222909 A2 EP2222909 A2 EP 2222909A2 EP 20080864155 EP20080864155 EP 20080864155 EP 08864155 A EP08864155 A EP 08864155A EP 2222909 A2 EP2222909 A2 EP 2222909A2
Authority
EP
European Patent Office
Prior art keywords
fabric
nylon
staple fibre
yarn
tenacity
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP20080864155
Other languages
English (en)
French (fr)
Other versions
EP2222909B1 (de
Inventor
Marina Crnoja-Cosic
James Martin Taylor
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Lenzing AG
Original Assignee
Lenzing AG
Chemiefaser Lenzing AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lenzing AG, Chemiefaser Lenzing AG filed Critical Lenzing AG
Publication of EP2222909A2 publication Critical patent/EP2222909A2/de
Application granted granted Critical
Publication of EP2222909B1 publication Critical patent/EP2222909B1/de
Not-in-force legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
    • D02G3/04—Blended or other yarns or threads containing components made from different materials
    • D02G3/045—Blended or other yarns or threads containing components made from different materials all components being made from artificial or synthetic material
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F2/00—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/12—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyamide as constituent
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/44—Yarns or threads characterised by the purpose for which they are designed
    • D02G3/442—Cut or abrasion resistant yarns or threads
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/44—Yarns or threads characterised by the purpose for which they are designed
    • D02G3/446—Yarns or threads for use in automotive applications
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D1/00—Woven fabrics designed to make specified articles
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D1/00—Woven fabrics designed to make specified articles
    • D03D1/0035—Protective fabrics
    • D03D1/0041—Cut or abrasion resistant
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D13/00—Woven fabrics characterised by the special disposition of the warp or weft threads, e.g. with curved weft threads, with discontinuous warp threads, with diagonal warp or weft
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/20—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
    • D03D15/208—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads cellulose-based
    • D03D15/225—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads cellulose-based artificial, e.g. viscose
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/20—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
    • D03D15/283—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads synthetic polymer-based, e.g. polyamide or polyester fibres
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/40—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads
    • D03D15/47—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads multicomponent, e.g. blended yarns or threads
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/50—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
    • D03D15/573—Tensile strength
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04B—KNITTING
    • D04B1/00—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
    • D04B1/14—Other fabrics or articles characterised primarily by the use of particular thread materials
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00—Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/01—Natural vegetable fibres
    • D10B2201/02—Cotton
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00—Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/20—Cellulose-derived artificial fibres
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00—Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/20—Cellulose-derived artificial fibres
    • D10B2201/22—Cellulose-derived artificial fibres made from cellulose solutions
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00—Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/20—Cellulose-derived artificial fibres
    • D10B2201/22—Cellulose-derived artificial fibres made from cellulose solutions
    • D10B2201/24—Viscose
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/02—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00—Physical properties
    • D10B2401/06—Load-responsive characteristics
    • D10B2401/063—Load-responsive characteristics high strength
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2501/00—Wearing apparel
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2501/00—Wearing apparel
    • D10B2501/04—Outerwear; Protective garments
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2503/00—Domestic or personal
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2503/00—Domestic or personal
    • D10B2503/06—Bed linen
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2503/00—Domestic or personal
    • D10B2503/06—Bed linen
    • D10B2503/062—Fitted bedsheets
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2505/00—Industrial
    • D10B2505/08—Upholstery, mattresses
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2505/00—Industrial
    • D10B2505/12—Vehicles
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/249921—Web or sheet containing structurally defined element or component
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2631—Coating or impregnation provides heat or fire protection
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/30—Woven fabric [i.e., woven strand or strip material]
    • Y10T442/3065—Including strand which is of specific structural definition
    • Y10T442/313—Strand material formed of individual filaments having different chemical compositions
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/30—Woven fabric [i.e., woven strand or strip material]
    • Y10T442/3976—Including strand which is stated to have specific attributes [e.g., heat or fire resistance, chemical or solvent resistance, high absorption for aqueous composition, water solubility, heat shrinkability, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/40—Knit fabric [i.e., knit strand or strip material]
    • Y10T442/425—Including strand which is of specific structural definition
    • Y10T442/438—Strand material formed of individual filaments having different chemical compositions

Definitions

  • This invention relates to yarns and fabrics containing nylon staple fibre and high-tenacity man-made cellulosic staple fibre, and objects like garments, beddings or upholstery made therefrom, and has particular reference to fabrics having a high resistance to wear whilst retaining a high comfort level.
  • Certain forms of workwear including that for use in conditions of high abrasion, have been found to wear very quickly. This is particularly true for workwear intended for use in sandy conditions. It is known that cellulosic fibres such as cotton, viscose rayon or Lyocell can be made into garments which have a high level of comfort. This is because the garments absorb moisture and have a cool comfortable touch. However cellulosic pure garments do not have a very high level of abrasion resistance.
  • Abrasion resistance in fabrics and garments is measured by the Martindale test and in this patent application always the number of rubs until 2 threads break is given. This is a standard fabric test details of which are set out in ASTM D4966-98 and in ISO 12947.
  • the specification is set by the required performance. For example for a 2x1 twill polyester/cotton battledress according to U.K. specifications a tear strength of 28 N in the warp and 20 N in the weft is required.
  • the so called ripstop fabrics can have different requirements, e. g. 25 N warp and 60 N weft.
  • Lyocell is the generic name for a man-made cellulosic fibre produced without the formation of a derivative from a solution of cellulose in an aqueous organic compound, normally N-methylmorpholine-N-oxide (NMMO). Lyocell has a much higher tenacity than regular viscose. While Lyocell in the conditioned state normally shows a tenacity at break of about 37 cN/tex, regular viscose under the same conditions shows a tenacity at break lower than 25, but strongly depending on the individual production process.
  • NMMO N-methylmorpholine-N-oxide
  • Nylon-6.6 for comparison, has a break tenacity of about 56 cN/tex and cotton of about 25cN/tex.
  • nylon/Lyocell fabrics have been produced on an experimental basis. These nylon/Lyocell fabrics have been produced by weaving a Lyocell weft into a continuous filament nylon warp.
  • Lyocell is produced as a staple fibre, and spun into yarns to enable it to be woven or knitted to form garments, this is not the case for nylon.
  • Much nylon is made as continuous filament material which is made up into warps. A warp is effectively a set of threads which are wound round a cylinder and placed on a loom before weaving begins. The weft thread is passed backwards and forwards though the warp often using a shuttle.
  • Warps require to be made up before weaving can begin and warps of continuous nylon filaments were available.
  • the experimental fabrics were made by weaving a Lyocell tread as a weft through the continuous filament nylon warps. Such fabrics have not been commercially used on any scale and were made purely as an experiment.
  • Nylon staple fibres i. e. fibres cut to a definite length after extrusion and spun to yarns, were never used for this application.
  • Modal Another man-made cellulosic fibre besides Lyocell is Modal, which is produced by a modified viscose process.
  • Modal is a high-tenacity man-made cellulosic fibre, too, as it shows a tenacity at break of about 35 cN/tex in the conditioned state.
  • BISFA Modal fibres are cellulose fibres having a high breaking force and a high wet modulus.
  • the breaking force (B c ) of a Modal fibre in the conditioned state is B c (cN) > 1 ,3 ⁇ /T+2T.
  • the force (B m ) required to produce an elongation of 5 % in the wet state of a Modal fibre is B m (cN) ⁇ 0,5*VT.
  • T is the mean linear density in decitex
  • IR infra red
  • a further object of the invention is to provide a yarn which can be used to produce a fabric with the above mentioned properties.
  • the high-tenacity man-made cellulosic staple fibre shows a tenacity at break in conditioned state of more than 32 cN/tex.
  • the yarn may contain 10 to 75% nylon and the fabric may contain from 10% to 50% nylon.
  • the balance in each case is high-tenacity man- made cellulosic fibre but in any event the fabric made from the yarn must contain at least 50% high-tenacity man-made cellulosic fibre.
  • nylon refers to the group of plastics known as polyamides.
  • Nylons are typified by amide groups (CONH) and encompass a range of material types e.g. Nylon 4,6; Nylon 6; Nylon 6,6; Nylon 12 ;Nylon 6,12. All are suitable but nylon 6 and nylon 6,6 are preferred.
  • the nylon and high-tenacity man-made cellulosic fibres are both of the same or closely similar mean linear density ("titre") in decitex (dtex). For example a 1.7 dtex or 1.4 dtex Lyocell fibre can be blended with a 1.7 or 2.0 dtex nylon fibre.
  • similar mean linear densities mean a difference of not more than 50% between the two fibres.
  • the staple fibre length of the nylon and the high-tenacity man-made cellulosic fibres is also the same or very similar.
  • a 38 mm staple Lyocell fibres can be blended with 35 to 40 mm nylon staple fibres, more preferably with 38mm nylon staple fibres.
  • similar fibre lengths mean a difference of not more than 15% in length between the two fibres.
  • the high-tenacity man-made cellulosic fibre preferably is a Lyocell staple fibre, a Modal staple fibre or a mixture thereof.
  • Lyocell as well as Modal have a higher break tenacity than other cellulosics including cotton. They also have a high wet strength. Therefore a significant effect on the tear resistance of the fabric can be expected. But as nylon has a still higher break tenacity the artisan would expect that the tear resistance of a fibric containing both nylon and a high-tenacity man-made cellulosic fibre will decrease if the amount of nylon decreases. Therefore the artisan would incorporate only as much cellulosic fibre as is needed to create enough comfort to the wearer.
  • the high-tenacity man-made cellulosic fibre can be a dull fibre, that is to say man-made cellulosic containing a matting agent, for example TiO 2 . This may give certain advantages like enhanced sun protection for the use in desert areas.
  • the high-tenacity man-made cellulosic fibre may be a bright fibre, that is to say a high-tenacity man-made cellulosic fibre not containing a matting agent.
  • a fabric which contains a yarn formed of an intimate blend of nylon staple fibre and high-tenacity man-made cellulosic staple fibre.
  • the fabric according to the invention may contain from 10% to 50% nylon.
  • Preferably said fabric is a woven fabric and contains said yarn in both the warp and the weft.
  • the fabric may have a basis weight in the region of 100 to 500 g/m 2 preferably 120 to 300 g/m 2 , further preferably 180 to 250 g/m 2 .
  • the fabric may be a twill fabric and may be a 2x1 twill. It could also be of another construction, e. g. plain.
  • the fabric has a Martindale abrasion resistance of at least 60,000 rubs, preferably at least 100,000 rubs, and a tear resistance of at least 20 newtons, preferably at least 30 newtons.
  • the fabrics according to the invention are mainly used for military applications and workwear, they may be treated by several finishes, like print dyes, FR finishes or IR reflectance finishes. According to general experience those finishes may affect the original properties of the fibres or yarns. But for example if a Proban® FR finish is applied on top of the fabric according to the invention, the strengths are pretty much maintained. Both tensile and tear strength drop by about 10-15% but abrasion remains above 100,000.
  • the Proban® process is based on the application of THPC (Tetra- kishydroxymethylphosphonium chloride) with urea to generate a pre-condensate.
  • THPC Tetra- kishydroxymethylphosphonium chloride
  • urea Tetra- kishydroxymethylphosphonium chloride
  • This pre-condensate is padded onto the fabric and the fabric dried to ⁇ 15% moisture content.
  • the fabric is then exposed to ammonia vapours in a special reaction chamber, followed by oxidation with hydrogen peroxide. This process is well known to the expert. Chemicals and instructions are available from Rhodia.
  • Pyrovatex® finish is also known to be applicable to cellulosic fibres such as Modal or Lyocell.
  • Pyrovatex® is a durable phosphorus containing finish created by the use of N-methylol dimethylphosphonopropionamide in combination with trimethylolmelamine and phosphoric acid as catalyst in a pad-dry-cure process. Chemicals and instructions are available from Huntsman.
  • the yarns according to the invention may also be used in knits.
  • the resulting knitted fabrics show a very high burst strength combined with superior wear comfort.
  • the abrasion resistance of knitted fabrics shows the same dependence from the mixture ratio cellulosic/nylon than in woven fabrics. Because the construction of a knitted fabric is more open, the abrasion resistance as can be measured by the Martindale test in general is lower compared to woven fabrics. Nevertheless for many applications a knitted construction is needed, especially when the demand for wear comfort and elasticity is high but has to be combined with certain durability requirements, for example for corporate wear. For those applications an abrasion resistance of at least 25.000 rubs would be sufficient
  • the fabrics according to the invention can be used for the manufacture of workwear, corporate wear or uniforms. Due to their good abrasion resistance they can also be used for the manufacture of upholstery fabric for furniture, office chairs or seats in transportation vehicles like cars, coaches, trains or planes. On upholstery fabrics according to the invention also FR finishes are applicable. For such purposes also non-durable FR chemicals, which are well-known by the expert, such as a mixture of boric acid and borax or ammonium salts of strong acids, especially phosporic acid, such as diammonium phosphate or ammonium sulfamate or ammonium bromide are applicable.
  • a further field of use for the fabrics according to the invention is the manufacture of beddings for hospital and hotels, especially where industrial laundries are used for the laundering.
  • Lyocell fibres with incorporated Chitosan which is already known from WO 2004/007818 and Austrian utility model AT 008 388 U2. This will give to the fabrics an anti-bacterial function as well as enhanced skin friendliness.
  • Chitosan-incorporated Lyocell fibres with finishes as described above, especially with FR finishes like Proban® or Pyrovatex®. It will perform especially in applications where a fabric should have both advantageous properties.
  • Yet another object of the present invention is a garment, containing a fabric as described above.
  • a garment preferably is a workwear, corporate wear or a uniform, but can also be any other type of garment, for which the typical properties of said fabric are advantageous.
  • Another object of the present invention is upholstery or bedding, containing this fabric as well as a furniture containing said upholstery.
  • PA-6.6 staple fibres with a titer of 2.0 dtex and 38 mm cut length were mixed in the ratios described in table 1 with commercially available TENCEL® staple fibres with a titer of 1.4 dtex and 38 mm cut length and spun to a yarn of Nm 1/26 (Ne 1/15).
  • the yarns were further processed by weaving a 2x1 twill with a weight of 249 g/m 2 and 32 ends and 24 picks.
  • the woven fabrics were then singed, desized, scoured, dried, heat set at 205 0 C, printed to meet the IR reflectance specifications from military and finished with an FC water repellent.
  • example 8 a conventional Proban® treatment was applied afterwards.
  • example 9 a different fabric construction was made, but by using the same yarns as in example 7.
  • Example 10 A 2x1 ripstop twill with 30 ends/22 picks and 180 g/ m 2 was made from the 70/30 yarn of example 4 but with a 350f/136 nylon filament ripstop thread as every ninth pick. Table 3 shows the comparison with the U.K. military specification for ripstop fabric.
  • Examples 11 to 13 A single jersey was knitted using a ring yarn Nm50/1 containing the same fibres as used in examples 2 to 6 with the various compositions listed in Table 4. The knitted fabrics were dyed with a common reactive dyestuff.
  • a yarn was made as in example 3, but using a 1 ,4 dtex chitosan-containing Lyocell fibre (Tencel C" by Lenzing AG 1 containing 0,5 % (w/w) Chitosan in the fibre) instead of the regular Tencel fibre.
  • the ratio Tencel C : PA 6.6 was 80%/20% (w/w).
  • This yarn was processed into a 2x1 twill with a weight of 203 g/m 2 .
  • the measured properties are listed in table 5.
  • a yarn was made as in example 3, but using a 1 ,4 dtex Modal fibre produced by Lenzing AG instead of the Tencel fibre.
  • the ratio Modal : PA 6.6 was 80%/20% (w/w).
  • This yarn was processed into a 2x1 twill with a weight of 212 g/m 2 .
  • the measured properties are listed in table 5.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Woven Fabrics (AREA)
  • Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
  • Professional, Industrial, Or Sporting Protective Garments (AREA)
  • Mattresses And Other Support Structures For Chairs And Beds (AREA)
  • Knitting Of Fabric (AREA)
  • Artificial Filaments (AREA)
EP20080864155 2007-12-20 2008-12-10 Garne, stoffe mit hoher verschleissfestigkeit und daraus hergestellte objekte Not-in-force EP2222909B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
AT0208907A AT506241B1 (de) 2007-12-20 2007-12-20 Garne, flächengebilde mit hoher abnutzungsbeständigkeit und daraus hergestellte artikel
PCT/AT2008/000440 WO2009079674A2 (en) 2007-12-20 2008-12-10 Yarns, high wear resistance fabrics and objects made therefrom

Publications (2)

Publication Number Publication Date
EP2222909A2 true EP2222909A2 (de) 2010-09-01
EP2222909B1 EP2222909B1 (de) 2013-09-04

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EP20080864155 Not-in-force EP2222909B1 (de) 2007-12-20 2008-12-10 Garne, stoffe mit hoher verschleissfestigkeit und daraus hergestellte objekte

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US (1) US20100330351A1 (de)
EP (1) EP2222909B1 (de)
JP (1) JP5732653B2 (de)
KR (3) KR101916444B1 (de)
CN (1) CN101903580B (de)
AT (1) AT506241B1 (de)
BR (1) BRPI0821341A2 (de)
ES (1) ES2436719T3 (de)
TW (1) TWI471465B (de)
WO (1) WO2009079674A2 (de)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8932965B1 (en) * 2008-07-30 2015-01-13 International Textile Group, Inc. Camouflage pattern with extended infrared reflectance separation
GB2472070A (en) * 2009-07-23 2011-01-26 Dyson Technology Ltd A flexible hose
GB2472069A (en) * 2009-07-23 2011-01-26 Dyson Technology Ltd A flexible hose made of rip-stop fabric
EP2513371B1 (de) * 2010-01-05 2015-06-24 Manikam Ramaswami Herstellungsverfahren eines flammbeständigen baumwollstoffes mit hoher reissfestigkeit
US20110223398A1 (en) * 2010-03-09 2011-09-15 Valley Forge Fabrics, Inc. Upholstery and Wall Panel Weight Woven Fabrics
AT510909B1 (de) * 2010-12-20 2013-04-15 Chemiefaser Lenzing Ag Flammgehemmte cellulosische man-made-fasern
US8776490B2 (en) * 2012-11-09 2014-07-15 Coreleader Biotech Co., Ltd. Natural polymeric yarn and its fabrication method as well as application
EP2767180B1 (de) * 2013-02-18 2017-01-04 W.L. Gore & Associates GmbH Flammschützende Gewebestruktur
CN103637405A (zh) * 2013-11-28 2014-03-19 苏州工业园区友顺制衣厂 一种易染色织物面料
MX2017004867A (es) * 2014-10-15 2017-12-04 Invista Textiles Uk Ltd Fibras de nylon con alta tenacidad o alto soporte de carga e hilos y tejidos de las mismas.
TWI571491B (zh) * 2015-10-19 2017-02-21 財團法人紡織產業綜合研究所 耐磨纖維的母粒及其製造方法以及使用其所製成的耐磨纖維
US20170159214A1 (en) * 2015-12-02 2017-06-08 L.S. Mills Limited Lyocell-Polyester Fabric and Methods of Manufacture
CN105544053A (zh) * 2015-12-15 2016-05-04 桐乡市亿源鞋业有限公司 高耐磨性面料
EP3467174A1 (de) * 2017-10-06 2019-04-10 Lenzing Aktiengesellschaft Gewirktes endlosfilamentlyocellgewebe
CN109930228B (zh) 2017-12-18 2022-04-29 财团法人纺织产业综合研究所 锦纶66改质纤维
PT3623509T (pt) * 2018-09-13 2021-07-09 Chemiefaser Lenzing Ag Tecido feito de fios retorcidos entrelaçados uns com os outros

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3657773A (en) * 1966-07-15 1972-04-25 Warner Swasey Co Apparatus for blending fibers
US3641638A (en) * 1970-04-07 1972-02-15 Us Army Nonwoven fibrous felt ballistic armor material
US3765837A (en) * 1971-09-03 1973-10-16 Burlington Industries Inc Flame retardant finish for polyester/cotton blends
US4698956A (en) * 1986-05-29 1987-10-13 Gentex Corporation Composite yarn and method for making the same
JPH1025632A (ja) * 1996-07-09 1998-01-27 Asahi Chem Ind Co Ltd 熱可塑性合成繊維とセルロース繊維との混用糸
JPH1088432A (ja) * 1996-09-09 1998-04-07 Toa Boshoku Kk ウール等と酵素処理溶剤紡糸セルロース繊維との混紡織・編物とその製造法
US6250060B1 (en) * 1997-04-18 2001-06-26 Wellman, Inc. Method of producing improved knit fabrics from blended fibers
JPH11335935A (ja) * 1998-05-26 1999-12-07 Kaihara Kk デニム用混紡糸およびデニム用織編物
GB0101815D0 (en) * 2001-01-24 2001-03-07 Tencel Ltd Dyed lyocell fabric
US20020193030A1 (en) * 2001-04-20 2002-12-19 Li Yao Functional fibers and fibrous materials
JP2003055832A (ja) * 2001-08-17 2003-02-26 Toyobo Co Ltd 溶剤紡糸セルロース繊維の製造方法
JP2003105673A (ja) * 2001-09-28 2003-04-09 Nisshinbo Ind Inc 涼感性を有するセルロース系繊維織編物及びその製造方法
US6805957B1 (en) * 2001-11-07 2004-10-19 The United States Of America As Represented By The Secretary Of The Navy Camouflage U.S. Marine corps utility uniform: pattern, fabric, and design
AT411769B (de) * 2002-07-12 2004-05-25 Chemiefaser Lenzing Ag Verfahren zur herstellung cellulosischer formkörper
JP2004218117A (ja) * 2003-01-10 2004-08-05 Unitika Textiles Ltd 吸湿発熱性セルロース系繊維及び織編物
CN1302165C (zh) * 2003-06-24 2007-02-28 上海第十七棉纺织总厂 罗地亚尼龙66短纤混纺纱的生产工艺
AT501327B1 (de) * 2003-07-21 2007-01-15 Chemiefaser Lenzing Ag Verwendung einer cellulosischen stapelfaser der gattung lyocell
US20060035555A1 (en) * 2004-06-22 2006-02-16 Vasanthakumar Narayanan Durable and fire resistant nonwoven composite fabric based military combat uniform garment
WO2006049188A1 (ja) * 2004-11-01 2006-05-11 Teijin Techno Products Limited パラ型芳香族ポリアミド短繊維

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO2009079674A2 *

Also Published As

Publication number Publication date
KR20180095954A (ko) 2018-08-28
CN101903580B (zh) 2014-11-19
JP5732653B2 (ja) 2015-06-10
JP2011509353A (ja) 2011-03-24
EP2222909B1 (de) 2013-09-04
BRPI0821341A2 (pt) 2015-06-16
TWI471465B (zh) 2015-02-01
ES2436719T3 (es) 2014-01-03
CN101903580A (zh) 2010-12-01
TW201002885A (en) 2010-01-16
KR101916444B1 (ko) 2018-11-08
KR20100099305A (ko) 2010-09-10
AT506241B1 (de) 2011-01-15
KR20150139637A (ko) 2015-12-11
WO2009079674A2 (en) 2009-07-02
WO2009079674A3 (en) 2009-09-11
AT506241A1 (de) 2009-07-15
US20100330351A1 (en) 2010-12-30

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