201002885 九、發明說明 【發明所屬之技術領域】 本發明係關於紗及含有尼龍短纖維及高韌度人造纖維 素短纖維之織物’及由彼製成之類似衣物、寢具或布套的 物品’且特別與具有尚耐磨性同時保持高舒適度之織物有 關。 【先前技術】 某些形式之工作服’包括那些用於高磨損狀況者，已 發現是極快速地磨損。對於企圖用在多沙狀況中之工作服 ’此情形是特別真實的。已知：纖維素纖維諸如棉、黏膠 嫘縈或來瑟（Loycell)可以製成具有高度舒適性之衣物。 這是因爲該等衣物吸收水分且具有涼爽舒適的觸感。然而 ，純纖維素衣物不具有極高度之耐磨性。 織物及衣物的耐磨性係藉Martindale測試來測量，且 在本專利申請案中總是給予直至2線斷裂之摩擦數。這是 一種標準織物測試，其細節在A S T M D 4 9 6 6 - 9 8及在IS Ο 1 2 9 4 7中列出。 50%/50%棉/聚酯織物具有良好舒適度，但依照例如織 物構造、重量等，具有20,000至50,000摩擦的耐磨性。但 即使這是不足以應付極端要求之狀況，諸如沙漠。亦知道 :含棉之織物的耐磨性可以藉製造棉/尼龍織物而增加。 由美國軍隊爲沙漠僞裝制服所用之織物是已知爲NyCo之 50%/50%棉/尼龍織物，其具有大於8〇,0〇〇摩擦的 201002885201002885 IX. INSTRUCTIONS OF THE INVENTION [Technical Fields of the Invention] The present invention relates to yarns and fabrics comprising nylon staple fibers and high tenacity man-made cellulosic staple fibers, and articles made of similar clothes, bedding or cloth sleeves made of the same 'In particular, it is related to fabrics that have wear resistance while maintaining high comfort. [Prior Art] Some forms of workwear, including those used for high wear conditions, have been found to wear very quickly. This situation is especially true for workwear that is intended to be used in a sandy situation. It is known that cellulose fibers such as cotton, viscose or Loycell can be made into a garment having a high degree of comfort. This is because the clothes absorb moisture and have a cool and comfortable touch. However, pure cellulose garments do not have extremely high abrasion resistance. The abrasion resistance of fabrics and garments is measured by the Martindale test, and the number of rubs up to the 2-line break is always given in this patent application. This is a standard fabric test, the details of which are listed in A S T M D 4 9 6 6 - 9 8 and in IS Ο 1 2 9 4 7. The 50%/50% cotton/polyester fabric has good comfort, but has a wear resistance of 20,000 to 50,000 rubbing in accordance with, for example, fabric construction, weight, and the like. But even this is not enough to cope with extreme demands, such as the desert. It is also known that the abrasion resistance of cotton-containing fabrics can be increased by the manufacture of cotton/nylon fabrics. The fabric used by the US Army for desert camouflage uniforms is a 50%/50% cotton/nylon fabric known as NyCo, which has a friction of more than 8 inches, 0〇〇 201002885
Martindale耐磨性。 此外，織物需要具有適合之撕裂強度。 特殊條件下開始或持續織物中之撕裂所需的 測試的細節列於ASTM D-226 1、ASTM D-IS Ο 1 3 93 7 中。 藉所需之效能而定出規格。例如’對於 的2x 1斜紋織物之聚酯/棉之戰服而言’需要 度於經紗中及20 N之撕裂強度於緯紗中。 ripstop)織物可以具有不同之要求’例如25 緯紗。 來瑟是人造纖維素纖維的通稱’其係在 製造··不從纖維素於含水有機化合物（正 啉-N-氧化物（NMMO))所成之溶液中形成 遠比通常之黏膠纖維具有更高之韌度。雖然 之來瑟正常顯出約37 cN/tex之破裂點的韌度 在相同條件下顯出低於2 5之破裂點的韌度， 照個別製造方法而定。 比較用之尼龍-6.6具有約56 cN/tex之破 且棉具有約25 cN/tex。 除了美國軍隊所用之棉及尼龍織物之< 來瑟織物已在實驗基礎上被製造。這些尼f 藉織造來瑟經紗於連續尼龍纖絲緯紗中而製 瑟被製造成短纖維且紡成紗以使其可被織造 衣物，但此舉不適於尼龍。很多尼龍被製成 撕裂強度是在 力。撕裂強度 2262 及 BS EN 依照U.K.規格 2 8 N之撕裂強 所謂之防裂（ N經紗及6 0 N 以下狀況下被 常是N-甲基嗎 衍生物。來瑟 在調節狀態下 ’正規的黏膠 但卻強烈地依 裂點的韌度， 卞’某些尼龍/ 隱/來瑟織物已 造。雖然’來 或針織而形成 連續纖絲材料 -6- 201002885 而構成緯紗。緯紗有效地是一組線，其在製造開始前被纏 繞在圓柱體上且置於織布機上。常使用梭，使緯紗線往返 經經紗。在織造可開始前經紗需被製造，且連續尼龍纖絲 經紗是可得的。藉由將作爲緯紗之來瑟線織造經連續尼龍 纖絲經線，而製造實驗性的織物。此種織物尙未在商業上 以任何規模被使用且純粹被製造以作爲實驗物。尼龍短纖 維（亦即在擠出後切成限定長度且紡成紗之纖維）從未供 此種應用之用。 除了來瑟之外的另一人造纖維素纖維是莫代爾（ modal )，其係藉經改良之黏膠方法來製造。莫代爾也是 高韌度人造纖維素纖維，因爲其在調節狀態下顯出約3 5 cN/tex之破裂點的韌度。依BISFA之定義，莫代爾纖維是 具有高的破裂力及高的濕模數的纖維素纖維。在調節狀態 下之莫代爾的破裂力（Be)是Be(cN)2 1.3 WT + 2T。在潮濕 狀態下使莫代爾纖維有5%伸長度所需的力（Bm )是 Bm(cN) ^0.5* VT。T是平均線性密度，其單位是分特（ d e c i t e X ) 〇 來瑟及莫代爾之混合物在市面上也是已知的，但迄今 比尙未大量販售。 【發明內容】 本發明之目的是要提供一種織物，其在穿著此織物製 之衣物者的舒適性與良好耐磨性及耐撕裂性之間有良好的 平衡。獲得良好程度之舒適性或獲得耐磨性及耐撕裂性之 -7- 201002885 任一者是容易達成的事。然而，甚難在織物中獲得二者， 因爲對於獲得良好舒適性所需之織物性質及對於獲得良好 耐磨及耐撕裂性所需之織物性質常是互相排斥的。 另一較佳目的是要製造一種織物，其可以被均勻地染 色，特別是用在軍隊制服染色中所常用之染料來染色，其 中此種染料具有紅外線（IR )反射比特性，此特性可被整 理以具有適用於制服之僞裝本質。 已知的FR油劑（finish )經常明顯地降低含纖維素纖 維之織物的機械性。因此，另一較佳目的是要製造一種織 物，其可用阻火（“ F R ”）油劑（例如P r 〇 b a η ® )來處理， 卻不損失太多強度及耐磨性。 本發明之另一目的是要提供一種紗，其可被用來製造 具有上述性質之織物。 藉本發明，提供一種由尼龍短纖維及高韌度人造纖維 素短纖維之緊密摻合物所形成之紗。較佳地’高韌度人造 纖維素短纖維在調節狀態下顯出多於32 cN/tex之破裂點的 韌度。 此紗可以含有1 0至7 5 %尼龍，且此織物可以含有1 〇 % 至5 0%之尼龍。較佳地，在每一情況中’其餘者是高韌度 人造纖維素纖維，但無論如何，由此紗所製成之織物必須 含有至少50%之高韌度人造纖維素纖維。 如本文中所用之尼龍一詞係指已知爲聚醯胺類之塑膠 族類。尼龍典型是具有醯胺基（CONH) ’且涵蓋多種材 料範圍，諸如尼龍4,6 ;尼龍6 ;尼龍6,6 :尼龍1 2 ;尼龍 -8- 201002885 6, 12。全部都是適合的，但以尼龍6及尼龍6,6爲較佳。 另外較佳地，尼龍及高韌度人造纖維素纖維皆具有相 同或極類似之單位爲分特（dtex)的平均線性密度（“纖度 ，，）。例如’ l^dtex或1.4dtex之來瑟纖維可以與1.7dtex或 2. Odtex之尼龍纖維摻合。通常，類似之平均線性密度義爲 在二纖維間差異不超過5 0%。 尼龍及高韌度人造纖維素纖維之短纖維長度也是相同 或極類似的。例如，38毫米之來瑟短纖維可以與35至40毫 米之尼龍短纖維摻合，更佳是與38毫米之尼龍短纖維）摻 合。通常，類似之纖維長度義爲二纖維間長度差異不超過 1 5 〇/〇。 高韌度人造纖維素纖維較佳是來瑟短纖維、莫代爾短 纖維或其混合物。 來瑟及莫代爾相較於其他纖維素（包括棉），具有較 高之破裂韌度。它們也具有高的潮濕強度。因此，可以預 期對織物之耐撕裂性有明顯影響。但因爲尼龍還有更高之 破裂韌度，技師會預期：含有尼龍及高韌度人造纖維素纖 維二者的織物的耐撕裂性會降低，若尼龍之量降低。因此 ’技師會僅合倂對穿著者有足夠舒適性所需之量的纖維素 纖維。 但令人驚訝地，已發現：藉合倂增量之高韌度人造纖 維素纖維’所得織物之耐撕裂性增加。因此，由摻合高韌 度人造纖維素短纖維及尼龍短纖維之紗所形成的織物具有 高的抗張強度且從尼龍纖維及高韌度人造纖維素纖維二者 -9- 201002885 獲得強度。 另外，已發現：爲獲得此優點，必須使用尼龍短纖維 及高韌度人造纖維素短纖維二者以製造紗。 當高韌度人造纖維素纖維與尼龍摻合時，超過20%之 尼龍無法有優點。耐磨性、抗張強度及撕裂強度已極接近 地達到一種適於高效能應用的程度。 高韌度人造纖維素纖維可以是一種無光（dull )纖維 ，意即含有消光劑（matting agent，例如Ti〇2)之人造纖 維素。這可有某些優點，類似在沙漠地區所用之經增強的 防曬者。 高韌度人造纖維素纖維可以是亮纖維，意即不含消光 劑之高韌度人造纖維素纖維。 藉本發明也提供一種含有如上述之紗的織物。 另外，藉本發明也提供一種織物，其含有由尼龍短纖 維及高韌度人造纖維素短纖維之緊密摻合物所形成之紗。 依本發明之織物可以含有1 〇%至5 〇 %尼龍。較佳地，該織 物是織造織物且含有該紗於經紗及緯紗二者之中。 織物可以具有在1〇〇至500克/平方公尺範圍內之基礎 重量，較佳地在120至300克/平方公尺之基礎重量，另外 較佳地在180至25〇克/平方公尺之基礎重量。 織物可以是斜紋織物且可以是2 X 1斜紋織物。彼也可 以有其他構造’例如平紋構造。 較佳地，織物具有至少60,〇〇〇 摩擦的Martindale耐磨 性，較佳至少1 00,00〇 摩擦的Martindale耐磨性’及至少 -10- 201002885 2 0牛頓的抗撕裂性，較佳至少3 0牛頓的抗撕裂性。 因爲依本發明之織物主要適用於軍隊應用及工作服， 它們可以用數種油劑，印染用染料、F R油劑或IR反射比油 劑來處理。依照一般之經驗，那些油劑可以影響纖維或紗 之原初性質。但例如’若Pro ban® FR油劑被應用在依本發 明之織物上方，強度極其良好地被保留。抗張強度及撕裂 強度下降約1 〇 -1 5 %，但耐磨性保持在1 〇 〇, 〇 〇 〇以上。Martindale wear resistance. In addition, the fabric needs to have a suitable tear strength. Details of the tests required to initiate or continue tearing in the fabric under special conditions are listed in ASTM D-226 1, ASTM D-IS Ο 1 3 93 7 . The specifications are determined by the required performance. For example, 'for a 2x 1 twill polyester/cotton suit' needs to be in the warp and 20 N tear strength in the weft. The ripstop) fabric can have different requirements, such as 25 weft yarns. Reneser is a generic term for man-made cellulosic fibers. It is manufactured in a solution that does not form from a solution of cellulose in an aqueous organic compound (normal porphyrin-N-oxide (NMMO)). Higher toughness. Although the toughness of the fracture point of about 37 cN/tex was normally exhibited by the singularity, the toughness of the fracture point below 25 was exhibited under the same conditions, depending on the individual manufacturing method. The comparative nylon-6.6 had a break of about 56 cN/tex and the cotton had about 25 cN/tex. In addition to the cotton and nylon fabrics used by the US military, the fabrics have been manufactured on an experimental basis. These yarns are made into staple fibers by weaving the warp yarns in continuous nylon filament weft yarns and spun into yarns to make them woven, but this is not suitable for nylon. A lot of nylon is made and the tear strength is in force. Tear strength 2262 and BS EN according to the UK specification 2 8 N tear strong so-called anti-cracking (N warp yarns and N 0 -methyl derivatives are often used under conditions of 60 N or less. The adhesive but strongly depends on the toughness of the crack, 卞 'Some nylon / hidden / lais fabric has been made. Although 'coming or knitting to form continuous filament material -6- 201002885 and constitute the weft. Weft effective Is a set of threads that are wrapped around a cylinder and placed on a looper before the start of manufacture. Shuttles are often used to make the weft yarns warp the warp yarns. The warp yarns need to be made before weaving can begin, and continuous nylon filaments Warp yarns are available. Experimental fabrics are produced by weaving a continuous nylon filament through a thread as a weft yarn. Such fabrics are not commercially used on any scale and are manufactured purely as Experiments. Nylon staple fibers (i.e., fibers that are cut to length and spun into yarn after extrusion) have never been used for this application. Another man-made cellulosic fiber other than Joseph is modal. , which is based on improved viscose Made in mod. Modal is also a high-toughness man-made cellulosic fiber because it exhibits a toughness at a breaking point of about 35 cN/tex under conditioning. According to the definition of BISFA, modal fiber has high breaking force and high Wet modulus cellulose fiber. The rupture force (Be) of the modal in the adjusted state is Be(cN)2 1.3 WT + 2T. The force required to make the modal fiber have 5% elongation in the wet state (Bm) It is Bm(cN) ^0.5* VT. T is the average linear density, and its unit is decitex. The mixture of 〇 瑟 and modal is also known in the market, but it has not been sold in large quantities so far. Disclosure of the Invention An object of the present invention is to provide a fabric which has a good balance between the comfort of a person wearing the fabric and the good wear resistance and tear resistance. A good degree of comfort or gain is obtained. -7-201002885 abrasion resistance and tear resistance are easy to achieve. However, it is very difficult to obtain both in the fabric because of the fabric properties required for good comfort and for good wear resistance. And the weaving required for tear resistance The nature of the material is often mutually exclusive. Another preferred object is to create a fabric that can be dyed uniformly, especially dyes commonly used in the dyeing of military uniforms, where the dye has infrared (IR) Reflectance characteristics, which can be tailored to have a camouflage nature suitable for uniforms. Known FR finishes often significantly reduce the mechanical properties of fabrics containing cellulose fibers. Therefore, another preferred objective is to A fabric is produced which can be treated with a fire retardant ("FR") oil agent (e.g., Pr 〇ba η ® ) without losing much strength and wear resistance. Another object of the present invention is to provide a yarn which can be used to make a fabric having the above properties. According to the present invention, there is provided a yarn formed from an intimate blend of nylon staple fibers and high tenacity rayon staple fibers. Preferably, the 'high tenacity man-made cellulosic staple fiber exhibits a toughness of more than 32 cN/tex at the point of failure in the adjusted state. The yarn may contain from 10 to 75% nylon and the fabric may contain from 1% to 50% nylon. Preferably, in each case the remainder is a high tenacity man-made cellulosic fiber, but in any event, the fabric made from the yarn must contain at least 50% high tenacity man-made cellulosic fibers. The term nylon as used herein refers to a family of plastics known as polyamipenes. Nylon typically has a guanamine group (CONH)' and covers a wide range of materials, such as nylon 4,6; nylon 6; nylon 6,6: nylon 12; nylon-8-201002885 6, 12. All are suitable, but nylon 6 and nylon 6,6 are preferred. Further preferably, both nylon and high tenacity man-made cellulosic fibers have the same or very similar average linear density ("denier,") in units of dtex. For example, 'l^dtex or 1.4 dtex The fibers can be blended with 1.7 dtex or 2.0 Odtex nylon fibers. Typically, a similar average linear density means no more than 50% difference between the two fibers. Nylon and high tenacity man-made cellulose fibers have the same length of staple fibers. Or very similar. For example, a 38 mm rayon staple fiber can be blended with a 35 to 40 mm nylon staple fiber, more preferably a 38 mm nylon staple fiber. Typically, a similar fiber length is two. The difference in length between fibers is not more than 15 〇 / 〇. The high-toughness man-made cellulose fiber is preferably short fiber, modal short fiber or a mixture thereof. The lai and modal are compared with other cellulose (including cotton). Higher fracture toughness. They also have high wet strength. Therefore, it is expected to have a significant effect on the tear resistance of the fabric. However, because nylon has a higher fracture toughness, the technician would expect: The tear resistance of the fabrics of both high-toughness man-made cellulosic fibers is reduced, and if the amount of nylon is reduced, the technician will only combine the amount of cellulose fibers required for the wearer to have sufficient comfort. Surprisingly, it has been found that the tear resistance of the resulting fabric is increased by the combination of high toughness man-made cellulose fibers. Therefore, yarns blended with high-toughness man-made cellulosic staple fibers and nylon staple fibers are used. The resulting fabric has high tensile strength and strength is obtained from both nylon fibers and high tenacity man-made cellulose fibers - 9 - 201002885. In addition, it has been found that in order to achieve this advantage, nylon staple fibers and high toughness must be used. Both man-made cellulosic staple fibers are used to make yarns. When high-toughness man-made cellulosic fibers are blended with nylon, more than 20% of nylon cannot have advantages. Wear resistance, tensile strength and tear strength have reached very close A degree suitable for high-performance applications. The high-toughness man-made cellulose fiber may be a dull fiber, that is, an artificial cellulose containing a matting agent such as Ti〇2. These advantages are similar to those of enhanced sunscreens used in desert areas. High tenacity man-made cellulosic fibers can be bright fibers, meaning high toughness man-made cellulosic fibers that do not contain a matting agent. A fabric of the above yarn. In addition, the present invention also provides a fabric comprising a yarn formed of an intimate blend of nylon staple fibers and high tenacity man-made cellulosic staple fibers. The fabric according to the present invention may contain 1 inch. % to 5% nylon. Preferably, the fabric is a woven fabric and contains the yarn in both warp and weft. The fabric may have a basis weight in the range of from 1 Torr to 500 g/m2. Preferably, the basis weight is from 120 to 300 grams per square meter, and more preferably from 180 to 25 grams per square meter. The fabric may be a twill weave and may be a 2 X 1 twill fabric. He may also have other configurations, such as plain weave construction. Preferably, the fabric has a Martindale abrasion resistance of at least 60, rubbing friction, preferably a Martindale abrasion resistance of at least 100,00 rubs, and a tear resistance of at least -10-201002885 2 Newtons. Good resistance to tearing of at least 30 Newtons. Since the fabrics according to the invention are mainly suitable for military applications and overalls, they can be treated with several oils, dyes for printing, F R oils or IR reflections. According to general experience, those oils can affect the original properties of the fiber or yarn. However, for example, if Pro ban® FR oil is applied over the fabric according to the invention, the strength is extremely well preserved. The tensile strength and tear strength decreased by about 1 〇 -1 5 %, but the abrasion resistance was maintained at 1 〇 〇, 〇 〇 〇 or more.
Proban®方法是基於THPC (氯化四羥基甲基鱗）與尿 素之應用’以產生預縮合物。此預縮合物被壓染在織物上 且織物乾燥至約1 5 %之水含量。織物而後曝於特殊反應器 內之氨蒸氣中，接著是過氧化氫之氧化作用。此方法對專 家而言是習知的。化學品及指示可從Rhodi a獲得。 類似之適合的FR油劑是Pyrovatex®油劑，其也已知是 適用於纖維素纖維，諸如莫代爾或來瑟。Pyrovatex®油劑 是一種耐用的含磷油劑，其係藉由結合使用N -羥甲基二甲 基亞磷羧基丙醯胺與三羥甲基三聚氰醯胺及作爲觸媒之磷 酸於壓染-乾燥一固化方法中所生成。化學品及指示可從 Huntsman獲得 ° 因所欲之用途，依本發明之紗也可以用在針織物中。 所得之針織織物顯出極高之猝發（burst )強度與優越之穿 著舒適性。針織織物的耐磨性顯出與在織造織物中者相同 之與纖維素/尼龍混合比例的關係。因爲針織織物之構造 更疏’ Martindale測試可測量之耐磨性通常比織造織物更 低。然而’對很多應用而言，需要針織構造，特別是當高 -11 - 201002885 度需要穿著舒適性及彈性’但必須結合某些耐用性需求（ 例如供團體衣服）時。對於那些應用而言’至少25，00 0摩 擦之耐磨性會是足夠的。 依本發明之織物可以用於製造工作服、團體衣服或制 服。因彼之良好的耐磨性，它們也可以用於製造家具、辦 公用椅或運輸工具（例如汽車、公車、火車或飛機）內座 椅的布套織物。FR油劑也適用於依本發明之布套織物上。 對於此種用途而言，專家所習知之非耐用的FR化學品’諸 如硼酸及硼砂或強酸（特別是磷酸）之銨鹽（諸如磷酸二 銨或胺基磺酸銨或溴化銨）的混合物，也是適合的。依本 發明之另外的使用領域是醫院及旅館之寢具的製造’特別 是在使用工業洗衣法被用來洗衣時。 進一步增加依本發明之產物的正面性質的可能性是使 用經合倂脫乙醯殼多醣之來瑟纖維，其也已從WO 2004/007818 及 Austrian utility model AT 008 388 U2中獲知。這會使織 物有抗菌功能以及經增強之皮膚友善性。 經合倂脫乙醯殼多醣之來瑟纖維與如上述之油劑之# 合，特別是與類似Proban®或Pyrovatex®之FR油劑之結合 也是可能的。這特別是在織物應有該二項有利性質的應用 中被實施。 然而，本發明之另一目的是一種含有如上述之織物的 衣物。此種衣物較佳是一種工作服、團體衣服或制服，但 也可以是任何其他形式之衣物，而對該等衣物而言，該織 物之典型性質是有利的。 -12- 201002885 本發明之另一目的是含有此織物之布套或寢具，以及 含該布套之家具。 【實施方式】 本發明現在將藉實例來說明。這些實例決不限制本發 明範圍。 實例1至6 商業上可獲得之具有2.〇dtex纖度及38毫米切斷長度的 PA-6.6短纖維以在表1中所述之比例與商業上可獲得之具 有1.4dtex纖度及38毫米切斷長度且紡成Nm l/26(Ne 1/15 )之紗的TENCEL®短纖維混合。 藉織造成具有249克/平方公尺重量及32端及24緯紗之 斜紋織物而將紗進一步加工。織造織物而後被燒毛、去膠 、洗淨、乾燥、在205 °C下熱固化、印染以符合軍隊之IR 反射比規格且用FC排水劑來後處理。這些方法對精於此技 藝之任何人而言是習知的。 經紗方向以及緯紗方向之撕裂強度被測量且對每一如 此後處理之織物進行Martindale測試。 -13- 201002885 表1 實例 Tencel/ PA 6.6比率 [w/wl 紗韌度 [cN/tex] 經紗之撕 裂強度[N] 緯紗之撕 裂強度[N] Martindale [摩擦] 1 100/0 25.4 18 30 20,000 2 90/10 24.0 25 32 65,000 3 80/20 23.3 26 42 >100,000 4 70/30 22.0 28 40 >100,000 5 60/40 20.9 28 42 >100,000 6 50/50 20.4 29 45 >100,000 由表1可清楚地推知：當織物尼龍含量從〇增加至20% 時，顯出織物機械性之最大改良。而後，獲得實際重要的 値且進一步增加之尼龍僅導致些微的改良。當達到 1 0 0，0 0 0摩擦的程度時，M a rt i n d a 1 e測試會應經濟因素而停 止。 對實例1、3、4及5之織物進行G A T S測試，此測試給 予一個關於汗水從穿著者身體除去速率的紀錄。曲線圖顯 示於圖1中。要指出之趨勢是··隨著TENCEL含量逐漸變高 ，水之吸收越快（曲線圖之斜率），且可以保持之體積越 大（曲線圖之高度）。速度是關鍵。 實例7至9 從含有依實例 iiTencei/PA-6·6 70%/30%(w/w)混 合纖維之N e 1 /1 5紗製成2 X 1斜紋織物。重量及油劑係按照 表2來改變，但方法步驟則同於實例1至6。在實例8中’則 在之後進行一般之Proban®處理。在實例9中’製成不同之 -14- 201002885 織物構造’但使用與實例7中相同之紗。 表2 實例 構造 [端/緯紗] 織物重量 [克/平方公尺] 經紗撕裂 強度[N] 緯紗撕裂 強度[N] Martindale [摩擦] 附記 7 39/22 205 35 27 >100,000 兩 8 39/22 205 27 21 >100,000 Proban FR 油劑 9 30/20 179 36 31 >100,000 較輕之重量 可見到：依本發明之三種織物皆符合2 8 c N (經紗） 、20 CN (緯紗）及4 5,00 0Martindale摩擦之U.K·軍隊規格 。實例8之織物也通過εν 5 3 2之耐火測試。 實例1 0 : 從實例4之70/3 0紗，但用3 5 0 f/136尼龍纖絲防裂線作 爲每個第9條線，製成具有30端/22緯紗及180克/m2之2x1之 防裂斜紋織物。表3顯示U.K.軍隊規格與防裂織物的比較 表3 實例 經紗撕裂 強度[NJ 緯紗撕裂 強度[N] Martindale [摩擦] 滲氣性 fl/m2sl 規格 25 60 30,000 200 10 39 >50 不能撕裂 >100,000 415 -15- 201002885 實例1 1至1 3 : 使用含有與實例2至6中所用者相同之纖維但有表4中 所列之多種組成之環紗N m 5 0 / 1 ’針織出單一澤西衣料（ jersey )。針織織物用慣用之反應性染料來染色。 表4 實例 Tencel/PA 6.6 比例[w/w] Martindale [摩擦] 11 100/0 13,000 12 95/5 18,000 13 90/10 28,500 如同在織造織物中者’藉添加少量尼龍’觀察到耐磨 性之強烈的增加。 實例1 4 如實例3中者製造紗’但使用丨.4 dtex之含脫乙醯殻多 醣之來瑟纖維（由Lenzing AG製之“Tencel C”’其含有 0.5% ( w/w )脫乙醯殻多醣於纖維中）’而非常規之 T e n c e 1 纖維。T e n c e 1 C : P A 6 _ 6 比例是 8 0 % / 2 0 %。此紗被加 工成具有203克/平方公尺重量之2x1斜紋織物。所測量之 性質列於表5中。 實例1 5 : 如實例3中者製造紗’但使用由L e n z 1 n g A G所製之1 · 4 dtex的莫代爾纖維而非常規之Tencel纖維。莫代爾：PA6·6 -16' 201002885 比例是80%/20%。此紗被加工成具有212克/平方公尺重量 之2x 1斜紋織物。所測量之性質列於表5中。 表5 實例 經紗撕裂 強度[N] 緯紗撕裂 強度[N] Martindale [摩擦] 滲氣性 [l/m2sl 14 45 45 84.000 326 15 39 30 75.000 352 【圖式簡單說明】 圖1顯示實例1、3、4及5之織物的GATS測試結果。 -17-The Proban® method is based on the application of THPC (tetrahydroxymethyl chlorinated chloride) to urea to produce a precondensate. This precondensate was dyed onto the fabric and the fabric was dried to a water content of about 15%. The fabric is then exposed to ammonia vapor in a special reactor followed by oxidation of hydrogen peroxide. This method is well known to experts. Chemicals and instructions are available from Rhodi a. A similarly suitable FR oil is a Pyrovatex® oil which is also known to be suitable for use in cellulosic fibers such as Modal or Joseph. Pyrovatex® oil is a durable phosphorus-containing oil by combining N-hydroxymethyl dimethylphosphonium carboxy propylamine with trishydroxymethyl melamine and phosphoric acid as a catalyst. It is produced by a dye-drying-solidification method. Chemicals and instructions are available from Huntsman ° Yarns according to the invention may also be used in knitwear. The resulting knit fabric exhibits a very high burst strength and superior wearing comfort. The abrasion resistance of the knitted fabric showed the same relationship with the cellulose/nylon mixing ratio as in the woven fabric. Because knit fabrics are more sturdy, the measurable wear resistance of the Martindale test is usually lower than that of woven fabrics. However, for many applications, knit construction is required, especially when high -11 - 201002885 degrees require wearing comfort and flexibility' but must be combined with certain durability requirements (eg for group clothes). For those applications, a wear resistance of at least 2,500 ounces would be sufficient. The fabric according to the invention can be used in the manufacture of workwear, group clothing or garments. Because of their good wear resistance, they can also be used to make upholstery fabrics for furniture, communal chairs or seats in transport vehicles such as cars, buses, trains or airplanes. FR oils are also suitable for use on the fabric of the present invention. For such use, a mixture of non-durable FR chemicals known to the expert, such as ammonium salts of boric acid and borax or strong acids (especially phosphoric acid), such as diammonium phosphate or ammonium amine sulfonate or ammonium bromide It is also suitable. Another area of use in accordance with the present invention is the manufacture of bedding in hospitals and hotels', particularly when used in industrial laundry methods for laundry. The possibility of further increasing the positive properties of the products according to the invention is the use of conjugated bismuth quercetin, which is also known from WO 2004/007818 and Austrian utility model AT 008 388 U2. This gives the fabric an antibacterial function and enhanced skin friendliness. It is also possible to combine the lysine fiber of the lycopene saponin with the oil agent as described above, especially with FR oils like Proban® or Pyrovatex®. This is especially the case where the fabric should have these two advantageous properties. However, another object of the invention is a garment comprising a fabric as described above. Such garments are preferably work clothes, group clothes or uniforms, but may be any other form of clothing for which the typical properties of the fabric are advantageous. -12- 201002885 Another object of the present invention is a cloth cover or bedding containing the fabric, and furniture containing the same. [Embodiment] The present invention will now be described by way of examples. These examples in no way limit the scope of the invention. Examples 1 to 6 Commercially available PA-6.6 staple fibers having a 〇dtex denier and a 38 mm cut length were commercially available in the ratios described in Table 1 with a 1.4 dtex denier and a 38 mm cut. TENCEL® short fiber blend of length and spun into Nm l/26 (Ne 1/15 ) yarn. The yarn was further processed by weaving a twill fabric having a weight of 249 g/m 2 and a length of 32 and 24 wefts. The fabric is woven, then singeed, degummed, washed, dried, heat cured at 205 ° C, printed and dyed to meet the Army's IR reflectance specifications and post treated with FC drainage. These methods are well known to anyone skilled in the art. The tear strength in the warp direction and the weft direction was measured and the Martindale test was performed on each of the fabrics treated thereafter. -13- 201002885 Table 1 Example Tencel/PA 6.6 ratio [w/wl yarn toughness [cN/tex] warp tear strength [N] weft tear strength [N] Martindale [friction] 1 100/0 25.4 18 30 20,000 2 90/10 24.0 25 32 65,000 3 80/20 23.3 26 42 >100,000 4 70/30 22.0 28 40 >100,000 5 60/40 20.9 28 42 >100,000 6 50/50 20.4 29 45 >100,000 It is clearly inferred from Table 1 that the maximum mechanical improvement of the fabric is exhibited when the nylon content of the fabric is increased from 〇 to 20%. Then, obtaining a practically important 値 and further increasing the nylon only led to a slight improvement. When the degree of friction of 1 0 0,0 0 0 is reached, the test of M a rt i n d a 1 e will stop due to economic factors. The fabrics of Examples 1, 3, 4 and 5 were subjected to a G A T S test which gave a record of the rate of removal of sweat from the wearer's body. The graph is shown in Figure 1. The trend to be pointed out is that as the TENCEL content becomes higher, the water absorption is faster (the slope of the graph), and the larger the volume (the height of the graph) can be maintained. Speed is the key. Examples 7 to 9 2 X 1 twill fabrics were prepared from N e 1 /15 yarns containing 70%/30% (w/w) of the mixed fibers according to Example iiTencei/PA-6·6. The weight and oil regimen were varied according to Table 2, but the method steps were the same as in Examples 1 to 6. In Example 8, 'there is then a general Proban® treatment. In Example 9, 'different -14-201002885 fabric construction' was made but the same yarn as in Example 7 was used. Table 2 Example construction [end/weft] Fabric weight [g/m2] Warp tear strength [N] Weft tear strength [N] Martindale [Friction] Supplementary note 7 39/22 205 35 27 >100,000 Two 8 39 /22 205 27 21 >100,000 Proban FR Oil 9 30/20 179 36 31 >100,000 The lighter weight can be seen: the three fabrics according to the invention all comply with 2 8 c N (warp), 20 CN (weft) And 4 5,00 0 Martindale Friction UK · Army specifications. The fabric of Example 8 was also tested for fire resistance by εν 5 3 2 . Example 10: From the 70/30 yarn of Example 4, but using a 3 5 0 f/136 nylon filament anti-crack line as each of the 9th lines, made with 30 ends / 22 weft yarns and 180 grams / m2 2x1 crack-proof twill fabric. Table 3 shows a comparison of UK military specifications and crack-resistant fabrics. Table 3 Example warp tear strength [NJ weft tear strength [N] Martindale [friction] gas permeability fl/m2sl size 25 60 30,000 200 10 39 >50 cannot tear Splitting>100,000 415 -15- 201002885 Example 1 1 to 1 3 : Knitting N m 5 0 / 1 ' knitting using the same fiber as those used in Examples 2 to 6 but having various compositions listed in Table 4 A single Jersey dress ( jersey ). Knitted fabrics are dyed with conventional reactive dyes. Table 4 Example Tencel/PA 6.6 Proportion [w/w] Martindale [Friction] 11 100/0 13,000 12 95/5 18,000 13 90/10 28,500 As in the woven fabric, the wear resistance was observed by adding a small amount of nylon. A strong increase. Example 1 4 As in Example 3, the yarn was produced 'but the 丨.4 dtex containing quercetin-containing lysine fiber ("Tencel C" manufactured by Lenzing AG" containing 0.5% (w/w) Clam shell polysaccharide in fiber) 'is not a conventional Ten ence 1 fiber. T e n c e 1 C : P A 6 _ 6 The ratio is 80% / 20%. This yarn was processed into a 2x1 twill fabric having a weight of 203 g/m2. The properties measured are listed in Table 5. Example 1 5: The yarn was made as in Example 3, but a 4.9 dtex modal fiber made of L e n z 1 n g A G was used instead of the conventional Tencel fiber. Modal: PA6·6 -16' 201002885 The ratio is 80%/20%. This yarn was processed into a 2 x 1 twill fabric having a weight of 212 g/m2. The properties measured are listed in Table 5. Table 5 Example warp tear strength [N] Weft tear strength [N] Martindale [Friction] Gas permeability [l/m2sl 14 45 45 84.000 326 15 39 30 75.000 352 [Simple diagram] Figure 1 shows example 1. GATS test results for fabrics 3, 4 and 5. -17-