EP2219820B1 - Article de nettoyage - Google Patents
Article de nettoyage Download PDFInfo
- Publication number
- EP2219820B1 EP2219820B1 EP08841998.1A EP08841998A EP2219820B1 EP 2219820 B1 EP2219820 B1 EP 2219820B1 EP 08841998 A EP08841998 A EP 08841998A EP 2219820 B1 EP2219820 B1 EP 2219820B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- abrasive layer
- base body
- cleaning article
- cleaning
- scouring
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000004140 cleaning Methods 0.000 title claims description 28
- 238000009991 scouring Methods 0.000 claims description 11
- 239000011230 binding agent Substances 0.000 claims description 9
- 239000002562 thickening agent Substances 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 8
- 239000002245 particle Substances 0.000 claims description 8
- 229920000742 Cotton Polymers 0.000 claims description 6
- 239000004627 regenerated cellulose Substances 0.000 claims description 6
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 4
- 239000011707 mineral Substances 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims 4
- 239000002585 base Substances 0.000 description 13
- 239000003082 abrasive agent Substances 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 5
- 229920002678 cellulose Polymers 0.000 description 5
- 239000001913 cellulose Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 239000007788 liquid Substances 0.000 description 4
- 230000009974 thixotropic effect Effects 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 229920000058 polyacrylate Polymers 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- -1 for example Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 235000010755 mineral Nutrition 0.000 description 2
- 239000005011 phenolic resin Substances 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 235000011121 sodium hydroxide Nutrition 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
- 229920003043 Cellulose fiber Polymers 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- 208000032912 Local swelling Diseases 0.000 description 1
- 239000004640 Melamine resin Substances 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 229920000459 Nitrile rubber Polymers 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 229920002319 Poly(methyl acrylate) Polymers 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 239000010431 corundum Substances 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- ZOOODBUHSVUZEM-UHFFFAOYSA-N ethoxymethanedithioic acid Chemical compound CCOC(S)=S ZOOODBUHSVUZEM-UHFFFAOYSA-N 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 239000010446 mirabilite Substances 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 239000000985 reactive dye Substances 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- RSIJVJUOQBWMIM-UHFFFAOYSA-L sodium sulfate decahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.[Na+].[Na+].[O-]S([O-])(=O)=O RSIJVJUOQBWMIM-UHFFFAOYSA-L 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000012991 xanthate Substances 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24D—TOOLS FOR GRINDING, BUFFING OR SHARPENING
- B24D3/00—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents
- B24D3/001—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as supporting member
- B24D3/002—Flexible supporting members, e.g. paper, woven, plastic materials
- B24D3/004—Flexible supporting members, e.g. paper, woven, plastic materials with special coatings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24D—TOOLS FOR GRINDING, BUFFING OR SHARPENING
- B24D11/00—Constructional features of flexible abrasive materials; Special features in the manufacture of such materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24D—TOOLS FOR GRINDING, BUFFING OR SHARPENING
- B24D11/00—Constructional features of flexible abrasive materials; Special features in the manufacture of such materials
- B24D11/02—Backings, e.g. foils, webs, mesh fabrics
Definitions
- the invention relates to a cleaning article, according to the preamble of patent claim 1 and a method for its preparation.
- the US 3,073,716 describes a sponge body provided with an abrasive layer.
- the DE 103 39 113 A1 shows a sponge cloth based on regenerated cellulose, which is colored with at least one reactive dye.
- From the WO 94/04738 A1 is a nonwoven fabric with an abrasive layer known.
- Such cleaning articles are known from DE 103 39113 A1 known.
- the previously known cleaning articles are produced by the cellulose xanthate method. To produce cotton fibers are wetted with alkali and kneaded with viscose. Then Glauber's salt and colorants are added as needed and the mixture is then kneaded.
- the invention has for its object to improve the cleaning performance of the cleaning article described above against firmly adhering dirt.
- the base body is provided at least on one side with an abrasive layer.
- the abrasive layer improves the cleaning performance of the cleaning article against firmly adhering soiling.
- the firmly adhering dirt is released by the abrasive layer of the surface to be cleaned and absorbed in the cleaning liquid, which is bound in the cleaning article, and thereby removed from the surface to be cleaned. Due to the large amount of water that can be absorbed by the cellulose-based cleaning article, a gentle cleaning even of sensitive surfaces.
- the abrasive layer consists of a binder and scouring particles.
- a binder In principle, it is difficult to attach scouring particles to a cellulose-based base body, since the cellulose, for example, can not be locally melted to improve adhesion.
- the scouring particles are firmly bound by a binder.
- Possible binders are based on phenol resin, acrylate-based or consist of a mixture of phenol and acrylate. Such binders are present in an aqueous solution, some of which are in the Body penetrates causes a local swelling of the cellulose and firmly anchored after curing on the cellulose fibers.
- Other conceivable binders may consist of latex, melamine resin, nitrile rubber or polyurethane or of mixtures of the abovementioned.
- the scouring particles are formed by mineral and organic scouring particles.
- mineral abrasives for example, quartz, silicon carbide, aluminum oxide, corundum, glass can be used.
- Other conceivable abrasives consist of lime, chalk, silica, nut shells or Kunststoffstaffgranulate based on polyurethane, polymethylacrylate, polyacrylate, polycarbonate or rubber.
- Polyacrylate is particularly suitable for the abrasive cleaning of sensitive surfaces
- the abrasive layer comprises a thickener.
- the thickener prevents the liquid constituents of the abrasive layer from penetrating into the base body too quickly when applied to the base body due to its high water absorption capacity, and before hardening.
- Thickeners which give thixotropic properties to the solution on which the abrasive layer is based are particularly advantageous. Such thixotropic properties can be processed particularly advantageously in the spray process.
- the solution is liquid by the action of shear forces in the spray apparatus and solidifies immediately after emergence, so that the solution has a high viscosity when hitting the base body, which limits the penetration depth of the solution. As a result, an abrasive layer having a significant thickness can be obtained.
- Methacrylic acid-based thickeners have such advantageous thixotropic properties.
- the abrasive layer can be made to be water-permeable so that the water absorbed in the cleaning article can reach the surface to be cleaned through the abrasive layer.
- a base body consisting of a base of regenerated cellulose reinforced with cotton fibers is provided and provided with an abrasive layer.
- the abrasive layer can be sprayed on or printed on.
- the spraying is particularly easy to integrate into the manufacturing process and it is a high area performance possible.
- Application rates of the abrasive layer of 200 to 300 g / m 2 are conceivable.
- a printing paste is provided which contains a binder and a thickener, wherein the thickener is dosed in accordance with the printing process.
- the abrasives are evenly distributed in the printing paste. It is also possible to provide a printing paste without abrasives. These first print on the surface of the body and then spread on the wet printing paste abrasives, which are thus mainly bound to the surface of the printing paste.
- FIG. 1 shows a cleaning article 1, which consists of a base body 2.
- This basic body 2 in turn consists of a base of regenerated cellulose and reinforced with cotton fibers.
- the main body is on one side 4 over its entire surface with an abrasive layer 3.
- the abrasive layer 3 consists of a binder 5 based on phenolic resin or acrylate provided with abrasives 6 based on glass particles or polyacrylate.
- a base body 2 is composed of a base of regenerated cellulose, reinforced with cotton fibers, and provided with an abrasive layer provided.
- the abrasive layer 3 can be applied to the base body 2 by means of spraying or printing.
- the application of the abrasive layer 3 preferably takes place by means of spraying, the solution forming the abrasive layer 3 comprising a thickener based on methacrylate, so that the solution has thixotropic properties, ie can be sprayed easily and only penetrates into the base body 2 to a limited extent.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Cleaning Implements For Floors, Carpets, Furniture, Walls, And The Like (AREA)
Claims (5)
- Article de nettoyage (1) comprenant un corps de base (2), constitué d'une base de cellulose régénérée, qui est renforcé avec des fibres de coton, le corps de base (2) étant muni au moins d'un côté d'une couche abrasive (3), caractérisé en ce que la couche abrasive (3) se compose d'un liant (5) et de moyens abrasifs (6), la couche abrasive (3) comprenant un épaississant et les moyens abrasifs (6) étant formés par des particules abrasives minérales et organiques.
- Article de nettoyage selon la revendication 1, caractérisé en ce qu'au moins un côté (4) du corps de base (2) est muni sur toute sa surface de la couche abrasive (3).
- Procédé de fabrication d'un article de nettoyage (1) selon l'une quelconque des revendications précédentes, dans lequel un corps de base (2), constitué d'une base de cellulose régénérée, qui est renforcé avec des fibres de coton, est préparé et est muni d'une couche abrasive (3), qui se compose d'un liant et de moyens abrasifs et qui comprend un épaississant, les moyens abrasifs étant formés par des particules abrasives minérales et organiques.
- Procédé selon la revendication 3, caractérisé en ce que la couche abrasive (3) est pulvérisée sur le corps de base (2).
- Procédé selon la revendication 3, caractérisé en ce que la couche abrasive (3) est pressée sur le corps de base (2).
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102007050902A DE102007050902A1 (de) | 2007-10-23 | 2007-10-23 | Reinigungsartikel |
PCT/EP2008/008857 WO2009053013A1 (fr) | 2007-10-23 | 2008-10-20 | Article de nettoyage |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2219820A1 EP2219820A1 (fr) | 2010-08-25 |
EP2219820B1 true EP2219820B1 (fr) | 2014-06-04 |
Family
ID=40380570
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP08841998.1A Active EP2219820B1 (fr) | 2007-10-23 | 2008-10-20 | Article de nettoyage |
Country Status (3)
Country | Link |
---|---|
EP (1) | EP2219820B1 (fr) |
DE (1) | DE102007050902A1 (fr) |
WO (1) | WO2009053013A1 (fr) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE202015101364U1 (de) | 2015-03-17 | 2015-03-20 | Kalle Gmbh | Cellulose-Schwammtuch mit abrasiven Eigenschaften |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2804728A (en) * | 1954-11-18 | 1957-09-03 | Politzer Alfred | Abrasive article |
US3073716A (en) * | 1957-11-08 | 1963-01-15 | Truly Magic Products Inc | Method of making a cleaning pad |
CH422247A (de) * | 1962-08-28 | 1966-10-15 | Minnesota Mining & Mfg | Reinigungs- und Scheuerkörper |
DE69304925T2 (de) * | 1992-08-24 | 1997-01-30 | Minnesota Mining & Mfg | Schmelzverbundene gegenstände aus vliesstoff und verfahren zu ihrer herstellung |
DE29809476U1 (de) * | 1998-05-27 | 1998-10-01 | J. Dittrich & Söhne Vliesstoffwerk GmbH, 66877 Ramstein-Miesenbach | Reinigungskissen |
DE10339113A1 (de) | 2003-08-22 | 2005-03-10 | Kalle Gmbh & Co Kg | Eingefärbtes Schwammtuch und Verfahren zu dessen Herstellung |
-
2007
- 2007-10-23 DE DE102007050902A patent/DE102007050902A1/de not_active Withdrawn
-
2008
- 2008-10-20 WO PCT/EP2008/008857 patent/WO2009053013A1/fr active Application Filing
- 2008-10-20 EP EP08841998.1A patent/EP2219820B1/fr active Active
Also Published As
Publication number | Publication date |
---|---|
DE102007050902A1 (de) | 2009-04-30 |
WO2009053013A1 (fr) | 2009-04-30 |
EP2219820A1 (fr) | 2010-08-25 |
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Inventor name: SCHINDLER, THOMAS Inventor name: LEHNHARDT, PETER Inventor name: HAUSDORF, JOERG Inventor name: DUDA, STEFAN Inventor name: NOWOTTNICK, HEIKE |
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