EP3069647B1 - Cellulose tissu eponge avec des proprietes abrasives - Google Patents
Cellulose tissu eponge avec des proprietes abrasives Download PDFInfo
- Publication number
- EP3069647B1 EP3069647B1 EP16160849.2A EP16160849A EP3069647B1 EP 3069647 B1 EP3069647 B1 EP 3069647B1 EP 16160849 A EP16160849 A EP 16160849A EP 3069647 B1 EP3069647 B1 EP 3069647B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- sponge cloth
- adhesive
- abrasive
- fibres
- cloth according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000004744 fabric Substances 0.000 title claims description 71
- 239000000835 fiber Substances 0.000 claims description 54
- 239000000853 adhesive Substances 0.000 claims description 51
- 230000001070 adhesive effect Effects 0.000 claims description 51
- 238000000034 method Methods 0.000 claims description 11
- 229920000297 Rayon Polymers 0.000 claims description 10
- 239000002245 particle Substances 0.000 claims description 8
- 239000004831 Hot glue Substances 0.000 claims description 7
- 239000004952 Polyamide Substances 0.000 claims description 7
- 229920002647 polyamide Polymers 0.000 claims description 7
- 239000006185 dispersion Substances 0.000 claims description 4
- 239000004627 regenerated cellulose Substances 0.000 claims description 4
- 238000007650 screen-printing Methods 0.000 claims description 4
- 229920002678 cellulose Polymers 0.000 claims description 3
- 239000001913 cellulose Substances 0.000 claims description 3
- 229920000728 polyester Polymers 0.000 claims description 3
- 230000035515 penetration Effects 0.000 claims description 2
- 229920002635 polyurethane Polymers 0.000 claims description 2
- 239000004814 polyurethane Substances 0.000 claims description 2
- 229920002994 synthetic fiber Polymers 0.000 claims 2
- 238000006243 chemical reaction Methods 0.000 claims 1
- 244000144992 flock Species 0.000 description 28
- 239000000463 material Substances 0.000 description 13
- 230000000694 effects Effects 0.000 description 12
- 239000000758 substrate Substances 0.000 description 10
- 238000000576 coating method Methods 0.000 description 9
- 238000004140 cleaning Methods 0.000 description 8
- 239000011248 coating agent Substances 0.000 description 8
- 229910052593 corundum Inorganic materials 0.000 description 7
- 239000010431 corundum Substances 0.000 description 7
- 239000007788 liquid Substances 0.000 description 7
- 239000003082 abrasive agent Substances 0.000 description 6
- 239000000428 dust Substances 0.000 description 5
- 230000005686 electrostatic field Effects 0.000 description 5
- 238000001035 drying Methods 0.000 description 4
- 239000010410 layer Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 229920000742 Cotton Polymers 0.000 description 3
- 230000001680 brushing effect Effects 0.000 description 3
- 230000005684 electric field Effects 0.000 description 3
- 239000008187 granular material Substances 0.000 description 3
- 239000003973 paint Substances 0.000 description 3
- 238000007639 printing Methods 0.000 description 3
- 230000005855 radiation Effects 0.000 description 3
- 230000002787 reinforcement Effects 0.000 description 3
- 229910052582 BN Inorganic materials 0.000 description 2
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 description 2
- 229920001410 Microfiber Polymers 0.000 description 2
- 208000002352 blister Diseases 0.000 description 2
- 238000007664 blowing Methods 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 239000003658 microfiber Substances 0.000 description 2
- 239000010446 mirabilite Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000005498 polishing Methods 0.000 description 2
- 239000004848 polyfunctional curative Substances 0.000 description 2
- -1 polypropylene Polymers 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000010453 quartz Substances 0.000 description 2
- 238000007788 roughening Methods 0.000 description 2
- 238000010079 rubber tapping Methods 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- RSIJVJUOQBWMIM-UHFFFAOYSA-L sodium sulfate decahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.[Na+].[Na+].[O-]S([O-])(=O)=O RSIJVJUOQBWMIM-UHFFFAOYSA-L 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000012790 adhesive layer Substances 0.000 description 1
- 239000004760 aramid Substances 0.000 description 1
- 229920003235 aromatic polyamide Polymers 0.000 description 1
- 238000000889 atomisation Methods 0.000 description 1
- 229920005601 base polymer Polymers 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 229910001651 emery Inorganic materials 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 229920001821 foam rubber Polymers 0.000 description 1
- 239000002223 garnet Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000011019 hematite Substances 0.000 description 1
- 229910052595 hematite Inorganic materials 0.000 description 1
- 239000012510 hollow fiber Substances 0.000 description 1
- 239000012943 hotmelt Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- LIKBJVNGSGBSGK-UHFFFAOYSA-N iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Fe+3].[Fe+3] LIKBJVNGSGBSGK-UHFFFAOYSA-N 0.000 description 1
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920001228 polyisocyanate Polymers 0.000 description 1
- 239000005056 polyisocyanate Substances 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 230000037452 priming Effects 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 239000012783 reinforcing fiber Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 238000000518 rheometry Methods 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000006748 scratching Methods 0.000 description 1
- 230000002393 scratching effect Effects 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
Images
Classifications
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47L—DOMESTIC WASHING OR CLEANING; SUCTION CLEANERS IN GENERAL
- A47L13/00—Implements for cleaning floors, carpets, furniture, walls, or wall coverings
- A47L13/10—Scrubbing; Scouring; Cleaning; Polishing
- A47L13/16—Cloths; Pads; Sponges
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47L—DOMESTIC WASHING OR CLEANING; SUCTION CLEANERS IN GENERAL
- A47L13/00—Implements for cleaning floors, carpets, furniture, walls, or wall coverings
- A47L13/02—Scraping
- A47L13/06—Scraping with wire brushes or wire meshes
Definitions
- the sponge body has a weight of 35 to 55 kg / m 3 .
- an at least partially agglomerated, preferably rice-grain-shaped pore-forming agent made from Glauber's salt is added to the viscose solution.
- Cotton fibers can also be added as reinforcement.
- the sponge body can also be provided with an abrasive layer.
- the abrasive layer can consist of a binder and abrasive particles of organic or inorganic origin.
- a polishing material which comprises a carrier layer made of foam, rubber or similar material and a layer made of microfibers thereon.
- the carrier is preferably made of a closed-cell foam rubber.
- the microfibers have an average length of at least 50 mm and an average thickness of less than 1 denier.
- the relatively long and thin fibers have only a slight abrasive effect.
- the material can only absorb relatively little water.
- the object was therefore to create a sponge cloth which, in addition to absorbing liquid, also has an abrasive effect. In this way, even dried-on impurities can be loosened on a surface with liquid in a single operation and then removed mechanically and abrasively without damaging the surface.
- the abrasive sponge cloth should also be able to clean sensitive surfaces, e.g. those made of plastic material, without scratching them.
- the cellulose-based sponge cloth is generally produced by the viscose process using Glauber's salt as a pore-forming agent. As mechanical reinforcement, it preferably contains a network and / or three-dimensionally distributed fibers in its interior. The reinforcing fibers are usually cotton fibers.
- the sponge cloth In the dry state, the sponge cloth generally has a density of 0.085 to 0.15 g / cm 3 , preferably 0.10 to 0.12 g / cm 3 .
- the thickness of the dry sponge cloth (before applying the glue and flock fibers or hard material particles) is generally 0.8 to 8.0 mm, preferably 1.0 to 3.0 mm.
- the flocked areas are arranged in such a way that no streaks occur when the sponge cloth is wiped over a surface to be cleaned, regardless of the direction of the wiping movement.
- FIG. 1 shows a sponge cloth flocked with polyamide flock, 44 dtex, 0.5 mm fiber length, according to the present invention.
- the dark circles represent the flocked areas.
- the function, look and feel of a flocking depend on the fiber thickness and length, whereby the fiber thickness is measured in dtex (grams per 10,000 meters of length) and the fiber length in millimeters.
- the thickness is between 0.5 dtex and 200 dtex, preferably between 1.0 and 100 dtex, and for the fiber length between 0.2 mm and 4.0 mm, preferably 0.4 to 2.0 mm.
- the penetration depth into the adhesive is generally 0.1 mm to 0.5 mm. The fibers must not completely penetrate the adhesive.
- the fibers are generally arranged at an angle of 70 to 110 ° with respect to the surface normal, so they are essentially at right angles to the surface of the sponge cloth.
- the orientation of the fibers is crucial for the abrasive effect.
- Fibers can be used for flocking.
- polyester and viscose acrylic flock, rayon flock, carbon flock, cotton flock, aramid flock and polypropylene flock are used for special applications.
- the use of the fibers depends heavily on the area of application. So are z. B. show polyester fibers ideal for outdoor applications but weakness in buckling stability.
- Fibers based on polyamide have very good abrasive properties.
- the polyamide that is most commonly used technically in this application is PA 6.6, also known as nylon. This fiber melts at 255 to 260 ° C and is mainly used in the titer range 0.9 dtex to 100 dtex depending on the application. The length varies from 0.3 mm to 4.0 mm.
- Polyamide flock has a high abrasion resistance and very good resilience after pressure load (kink resistance). The UV stability is sufficient in most cases.
- the fibers can have different shapes.
- hollow fibers such as core / sheath fibers, side-by-side fibers or island-in-sea fibers, or fibers with a non-round cross-sectional shape, can also be used. for example with a square, star-shaped or other cross-sectional shape.
- fibers that contain fillers with abrasive properties can also be used for flocking.
- One method of making a sponge cloth abrasive is, for example, the flocking technique.
- the flocking technique surface flocking (for full-surface flocking of one or both sides) and design flocking (patterns, logos, lettering, etc. using a template or a sieve) are possible for the sponge cloth.
- the flocking is done either manually, semi-automatically or fully automatically in the electrostatic field.
- the electrically conductive adhesive is applied using various printing processes (pad, screen or letterpress in surface or rotary form), but it can also be done by spraying, brushing, dipping or rolling.
- the adhesive-specific properties such as viscosity and thixotropy, rheology (flow behavior), open time, pot life and atomization must be taken into account. It has proven to be expedient to apply the adhesive in an amount of from 0.01 to 0.30 grams, preferably from 0.02 to 0.20 grams, per square centimeter of the surface of the sponge cloth to be flocked.
- the adhesive can be solvent-based or dispersion-based consisting of 1 or 2 components, polyurethane-based, a hot-melt adhesive or chemically covalently react with the surface of the substrate, e.g. B. polyisocyanate with a sponge cloth.
- pretreatment of the substrate before application of the adhesive such as roughening, grinding, treating with primers, priming with plasma or treating by corona discharge, can also be useful.
- the adhesive When cured, the adhesive should be sufficiently flexible and, in addition to being washable up to 95 ° C, also be resistant to UV radiation. The adhesive should also be able to be colored according to the color of the flock.
- the area that is not to be flocked is masked so that no adhesive can be applied there, as the flock fibers can only anchor themselves firmly in the adhesive.
- the flock fibers to which an electric charge is applied are aligned in an electric field perpendicular to the substrates, so that the fibers are still longitudinally in the area applied to the substrate Dip the wet adhesive. It is important to ensure that the adhesive layer is applied in sufficient thickness so that the flock fibers can optimally anchor themselves in the adhesive bed. Only when the fibers are fixed in the adhesive at approximately right angles to the surface of the sponge cloth can they develop the desired abrasive effect.
- All fibers must have sufficient electrostatic chargeability. This can be achieved by appropriately preparing the fiber (e.g. by coating it with salts). A certain humidity and temperature must be maintained during flocking so that the conductivity of the fiber is guaranteed.
- filaments e.g. viscose fibers, which contain carbides, in particular silicon or boron carbides, on their surface. These are completely abrasive, so there is no need to align such fibers in the adhesive. The fiber must just not be completely immersed in the adhesive. The same applies to fibers equipped with corundum or boron nitride.
- the solvent or dispersion based 1- or 2-component adhesive or the printing ink has cured, dirt particles can be detached from the surface to be cleaned during the cleaning process by moving back and forth while exerting pressure on the part of the sponge cloth coated with adhesive or paint, or they remain on the edges of the three-dimensional adhesive or paint hang and can be completely picked up with the clean back of the sponge cloth.
- the abrasiveness can be adjusted by the hardness of the adhesive or color to be used. There is also the option of coloring the adhesive.
- hotmelt adhesives also known as hot melt adhesives, hot melt adhesives or hotmelts
- Hot-melt adhesives are solvent-free products that are more or less solid at room temperature. They are applied to the adhesive surface when they are hot and create a firm bond with the substrate when they cool down.
- the greater part of the flock fibers protrudes essentially perpendicularly from the plane of the sponge cloth and is responsible for the abrasive effect.
- the ingredients of the hot melt adhesives are based on base polymers, resins, stabilizers, wax and nucleating agents and are selected according to their adhesion to the substrate, processing temperature, heat resistance, chemical resistance and hardness.
- the sponge cloth with abrasive flock fibers is particularly suitable for gently removing stubborn dirt from surfaces, whereby the surfaces remain as undamaged as possible.
- abrasive sponge cloth e.g. roughening, removing material or polishing
- other requirements are placed on the abrasive coating of the sponge cloth:
- the abrasive coating In order for the material to be removed quickly and sustainably (long service life), the abrasive coating must be very hard and tough.
- hard material grains also called abrasives and abrasives, usually consist of corundum on a natural or synthetic basis (aluminum oxide; fine corundum, semi-precious corundum, normal corundum, etc.), silicon carbide, diamond, boron nitride, quartz, metal powder, glass granulate / glass powder, garnet, emery (Mixture of corundum, magnetite, hematite and quartz) and many others.
- the structure or manufacture of a material-removing, abrasive sponge cloth that is not according to the invention is largely the same as the coating process with flock and is therefore only roughly described:
- the surface coating for a full-surface coating on one or both sides
- the design coating patterns, logos, lettering, etc. using a template or a sieve
- Electrically conductive adhesive is applied to the clean sponge cloth (substrate).
- the primarily solvent-based adhesive is applied to the sponge cloth as described above.
- the hard material grains are anchored more firmly in solvent-based one- or two-component adhesive than in a water-based adhesive.
- the hard material grains to which an electrical charge is applied are aligned perpendicular to the substrates in an electrical field, so that the grains are immersed in the still wet adhesive applied to the substrate.
- the sponge cloth is vibrated by shaking it so that the hard material grains penetrate deeper into the adhesive and are thus more firmly (more permanently) enclosed by the adhesive.
Landscapes
- Cleaning Implements For Floors, Carpets, Furniture, Walls, And The Like (AREA)
- Polishing Bodies And Polishing Tools (AREA)
Claims (13)
- Tissu éponge à effet abrasif à base de cellulose régénérée, qui est renforcé avec un filet se trouvant à l'intérieur ou des fibres réparties de manière essentiellement homogène, caractérisé en ce qu'il présente des fibres à effet abrasif sur sa surface, qui sont agencées de manière essentiellement perpendiculaire par rapport au plan de la surface de tissu éponge.
- Tissu éponge selon la revendication 1, caractérisé en ce qu'il présente des particules à effet abrasif supplémentaires sur sa surface.
- Tissu éponge selon la revendication 1 ou 2, caractérisé en ce qu'il présente des fibres à effet abrasif et/ou des particules à effet abrasif seulement sur un seul côté.
- Tissu éponge selon l'une quelconque ou plusieurs des revendications 1 à 3, caractérisé en ce que la proportion de la surface, qui présente des fibres à effet abrasif et/ou des particules à effet abrasif, est de 1 à 100 %, de préférence de 3 à 50 %, le plus préférentiellement de 5 à 30 %, respectivement en se référant à la surface totale.
- Tissu éponge selon l'une quelconque ou plusieurs des revendications 1 à 4, caractérisé en ce que l'épaisseur des fibres synthétiques est de 0,5 dtex à 200 dtex, de préférence de 1,0 à 100 dtex.
- Tissu éponge selon l'une quelconque ou plusieurs des revendications 1 à 5, caractérisé en ce que la longueur de fibre est de 0,2 mm à 4,0 mm, de préférence de 0,4 à 2,0 mm.
- Tissu éponge selon l'une quelconque ou plusieurs des revendications 1 à 6, caractérisé en ce que les fibres synthétiques sont ancrées sur le tissu éponge à l'aide d'un adhésif à base de solvant ou de dispersion composé de 1 ou 2 composants, d'un adhésif à base de polyuréthane, d'un adhésif thermofusible ou d'un adhésif chimiquement covalent réagissant avec la cellulose à la surface du tissu éponge.
- Tissu éponge selon l'une quelconque ou plusieurs des revendications 1 à 7, caractérisé en ce que la profondeur de pénétration des fibres dans l'adhésif se situe de 0,1 mm à 0,5 mm.
- Tissu éponge selon l'une quelconque ou plusieurs des revendications 1 à 8, caractérisé en ce que les fibres sont agencées selon un angle par rapport à la normale à la surface dans la plage de 70 à 110°.
- Tissu éponge selon l'une quelconque ou plusieurs des revendications 1 à 9, caractérisé en ce que les plages floquées forment un motif graphique.
- Tissu éponge selon l'une quelconque ou plusieurs des revendications 1 à 10, caractérisé en ce qu'il est floqué avec des fibres de polyamide, de polyester et/ou de viscose.
- Tissu éponge selon l'une quelconque ou plusieurs des revendications 1 à 11, caractérisé en ce que les fibres à effet abrasif et/ou les particules à effet abrasif sont mélangées avec un adhésif ou une couleur et sont appliquées de manière partielle ou totale sur la surface du tissu éponge dans un procédé de sérigraphie.
- Tissu éponge selon la revendication 12, caractérisé en ce que le milieu abrasif ne présente pas de direction préférentielle.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PL16160849T PL3069647T3 (pl) | 2015-03-17 | 2016-03-17 | Celulozowa ścierka gąbczasta o właściwościach abrazyjnych |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE201520101364 DE202015101364U1 (de) | 2015-03-17 | 2015-03-17 | Cellulose-Schwammtuch mit abrasiven Eigenschaften |
Publications (2)
Publication Number | Publication Date |
---|---|
EP3069647A1 EP3069647A1 (fr) | 2016-09-21 |
EP3069647B1 true EP3069647B1 (fr) | 2021-05-12 |
Family
ID=52812325
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP16160849.2A Active EP3069647B1 (fr) | 2015-03-17 | 2016-03-17 | Cellulose tissu eponge avec des proprietes abrasives |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP3069647B1 (fr) |
CY (1) | CY1124268T1 (fr) |
DE (1) | DE202015101364U1 (fr) |
ES (1) | ES2874002T3 (fr) |
PL (1) | PL3069647T3 (fr) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BR112018017027A2 (pt) | 2016-02-26 | 2018-12-26 | 3M Innovative Properties Co | artigo de esfregamento e método para produção de um artigo de esfregamento |
DE102020126904A1 (de) | 2020-10-13 | 2022-04-14 | a&n&a GmbH & Co. KG | Reinigungsschwamm und verfahren zu seiner herstellung |
CN115246101A (zh) * | 2021-04-25 | 2022-10-28 | 苏州三鼎纺织科技有限公司 | 光学玻璃抛光用磨皮及其制备方法 |
Citations (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2540906A (en) | 1947-06-05 | 1951-02-06 | Burgess Cellulose Company | Artificial chamois skin and method of making the same |
US2671743A (en) | 1952-04-23 | 1954-03-09 | Celloplast Ab | Artificial sponge cloth |
US3197327A (en) | 1961-09-27 | 1965-07-27 | Du Pont | Manufacture of rot resistant sponges |
EP0632990A1 (fr) | 1993-07-09 | 1995-01-11 | CORONET-Werke Gesellschaft mit beschränkter Haftung | Produit de nettoyage et traitement de surfaces et procédé de fabrication |
WO1999027835A1 (fr) | 1997-12-03 | 1999-06-10 | Kalle Nalo Gmbh & Co. Kg | Tissu eponge a base de cellulose et son procede de fabrication |
US20060123573A1 (en) | 2002-09-05 | 2006-06-15 | Rivera Maria Del Carmen M | Flocked substrates for use as scouring materials |
EP1693407A2 (fr) | 2005-02-17 | 2006-08-23 | Kalle GmbH | Eponge, son procédé de préparation et son utilisation |
DE102006005984A1 (de) | 2006-02-08 | 2007-08-09 | Carl Freudenberg Kg | Reinigungstuch |
DE102007050902A1 (de) | 2007-10-23 | 2009-04-30 | Carl Freudenberg Kg | Reinigungsartikel |
US20090178223A1 (en) | 2006-02-28 | 2009-07-16 | Carmen Martin Rivera | Wear indicator for a flocked scouring material |
EP2363024A2 (fr) | 2010-03-02 | 2011-09-07 | Kalle GmbH | Feuilles, éponges et tissus éponges revêtus antimicrobiens |
DE102012004331A1 (de) | 2012-03-07 | 2013-09-12 | Carl Freudenberg Kg | Reinigungsgerät mit Schaumstoff |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2005035187A2 (fr) | 2003-09-22 | 2005-04-21 | Meguiar's, Inc. | Tampon polisseur et lustreur |
DE102009013515A1 (de) | 2009-03-19 | 2010-09-23 | Carl Freudenberg Kg | Verfahren zur kontinuierlichen Herstellung von Schwammkörpern aus regenerierter Cellulose und ein Schwammkörper |
DE102010054009B4 (de) | 2010-12-09 | 2014-03-06 | Carl Freudenberg Kg | Reinigungseinrichtung |
-
2015
- 2015-03-17 DE DE201520101364 patent/DE202015101364U1/de active Active
-
2016
- 2016-03-17 ES ES16160849T patent/ES2874002T3/es active Active
- 2016-03-17 PL PL16160849T patent/PL3069647T3/pl unknown
- 2016-03-17 EP EP16160849.2A patent/EP3069647B1/fr active Active
-
2021
- 2021-06-24 CY CY20211100567T patent/CY1124268T1/el unknown
Patent Citations (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2540906A (en) | 1947-06-05 | 1951-02-06 | Burgess Cellulose Company | Artificial chamois skin and method of making the same |
US2671743A (en) | 1952-04-23 | 1954-03-09 | Celloplast Ab | Artificial sponge cloth |
US3197327A (en) | 1961-09-27 | 1965-07-27 | Du Pont | Manufacture of rot resistant sponges |
EP0632990A1 (fr) | 1993-07-09 | 1995-01-11 | CORONET-Werke Gesellschaft mit beschränkter Haftung | Produit de nettoyage et traitement de surfaces et procédé de fabrication |
WO1999027835A1 (fr) | 1997-12-03 | 1999-06-10 | Kalle Nalo Gmbh & Co. Kg | Tissu eponge a base de cellulose et son procede de fabrication |
US20060123573A1 (en) | 2002-09-05 | 2006-06-15 | Rivera Maria Del Carmen M | Flocked substrates for use as scouring materials |
EP1693407A2 (fr) | 2005-02-17 | 2006-08-23 | Kalle GmbH | Eponge, son procédé de préparation et son utilisation |
DE102006005984A1 (de) | 2006-02-08 | 2007-08-09 | Carl Freudenberg Kg | Reinigungstuch |
US20090178223A1 (en) | 2006-02-28 | 2009-07-16 | Carmen Martin Rivera | Wear indicator for a flocked scouring material |
DE102007050902A1 (de) | 2007-10-23 | 2009-04-30 | Carl Freudenberg Kg | Reinigungsartikel |
EP2363024A2 (fr) | 2010-03-02 | 2011-09-07 | Kalle GmbH | Feuilles, éponges et tissus éponges revêtus antimicrobiens |
DE102012004331A1 (de) | 2012-03-07 | 2013-09-12 | Carl Freudenberg Kg | Reinigungsgerät mit Schaumstoff |
Also Published As
Publication number | Publication date |
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ES2874002T3 (es) | 2021-11-04 |
PL3069647T3 (pl) | 2021-11-29 |
DE202015101364U1 (de) | 2015-03-20 |
CY1124268T1 (el) | 2022-07-22 |
EP3069647A1 (fr) | 2016-09-21 |
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