EP2192202B2 - Aluminiumband für lithographische Druckplattenträger mit hoher Biegewechselbeständigkeit - Google Patents
Aluminiumband für lithographische Druckplattenträger mit hoher Biegewechselbeständigkeit Download PDFInfo
- Publication number
- EP2192202B2 EP2192202B2 EP08105850.5A EP08105850A EP2192202B2 EP 2192202 B2 EP2192202 B2 EP 2192202B2 EP 08105850 A EP08105850 A EP 08105850A EP 2192202 B2 EP2192202 B2 EP 2192202B2
- Authority
- EP
- European Patent Office
- Prior art keywords
- printing plate
- aluminum
- weight
- lithographic printing
- plate supports
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title claims description 33
- 229910052782 aluminium Inorganic materials 0.000 title claims description 33
- 239000004411 aluminium Substances 0.000 title claims 2
- 238000005452 bending Methods 0.000 title description 18
- 229910000838 Al alloy Inorganic materials 0.000 claims description 49
- 238000005096 rolling process Methods 0.000 claims description 33
- 238000000034 method Methods 0.000 claims description 22
- 229910045601 alloy Inorganic materials 0.000 claims description 18
- 239000000956 alloy Substances 0.000 claims description 18
- 238000000137 annealing Methods 0.000 claims description 16
- 238000004519 manufacturing process Methods 0.000 claims description 16
- 229910052748 manganese Inorganic materials 0.000 claims description 4
- 229910052802 copper Inorganic materials 0.000 claims description 3
- 239000012535 impurity Substances 0.000 claims description 3
- 229910052719 titanium Inorganic materials 0.000 claims description 3
- 229910052725 zinc Inorganic materials 0.000 claims description 3
- 229910052804 chromium Inorganic materials 0.000 claims description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 29
- 239000011777 magnesium Substances 0.000 description 26
- 229910052742 iron Inorganic materials 0.000 description 13
- 238000007788 roughening Methods 0.000 description 13
- 229910052749 magnesium Inorganic materials 0.000 description 11
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 9
- 239000011572 manganese Substances 0.000 description 8
- 239000011651 chromium Substances 0.000 description 7
- 239000011701 zinc Substances 0.000 description 7
- 239000010949 copper Substances 0.000 description 6
- 239000010936 titanium Substances 0.000 description 5
- 238000009661 fatigue test Methods 0.000 description 4
- 238000005097 cold rolling Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 238000007373 indentation Methods 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
- C22C21/06—Alloys based on aluminium with magnesium as the next major constituent
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41N—PRINTING PLATES OR FOILS; MATERIALS FOR SURFACES USED IN PRINTING MACHINES FOR PRINTING, INKING, DAMPING, OR THE LIKE; PREPARING SUCH SURFACES FOR USE AND CONSERVING THEM
- B41N1/00—Printing plates or foils; Materials therefor
- B41N1/04—Printing plates or foils; Materials therefor metallic
- B41N1/08—Printing plates or foils; Materials therefor metallic for lithographic printing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41N—PRINTING PLATES OR FOILS; MATERIALS FOR SURFACES USED IN PRINTING MACHINES FOR PRINTING, INKING, DAMPING, OR THE LIKE; PREPARING SUCH SURFACES FOR USE AND CONSERVING THEM
- B41N1/00—Printing plates or foils; Materials therefor
- B41N1/04—Printing plates or foils; Materials therefor metallic
- B41N1/08—Printing plates or foils; Materials therefor metallic for lithographic printing
- B41N1/083—Printing plates or foils; Materials therefor metallic for lithographic printing made of aluminium or aluminium alloys or having such surface layers
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/04—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/04—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
- C22F1/047—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon of alloys with magnesium as the next major constituent
Definitions
- the invention relates to a method for producing an aluminum strip.
- Lithographic printing plate supports are primarily made from aluminum alloys, with typical thicknesses of the printing plate supports being between 0.15 and 0.5 mm. Increasingly high technical demands are being placed on lithographic printing plate supports. These result from the fact that ever larger numbers of prints must be achievable with printing presses. Furthermore, the printing plate support must be as large as possible in order to maximize the printing area per print. Since the printing plate supports are made of aluminum strips, their width is naturally limited to something less than the width of the aluminum strip. For this reason, the clamping of the printing plate supports in printing presses is increasingly carried out transversely to the rolling direction, so that the flexural fatigue strength of the printing plate supports transverse to the rolling direction is becoming increasingly important.
- the printing plate support must have a high level of stability in the printing device in order to enable the greatest possible number of prints.
- a printing plate support must therefore have sufficient reverse bending strength so that plate tearing due to mechanical overloading of the printing plate support is ruled out.
- the flexural fatigue strength transverse to the rolling direction is becoming increasingly important, since many printing plate supports are clamped perpendicular to the rolling direction and bending does not occur longitudinally but transversely to the rolling direction.
- an aluminum alloy for the production of lithographic printing plate supports which has a relatively high iron content of 0.4% by weight to 1% by weight and a relatively high manganese content of up to 0.3% by weight. % allows.
- This aluminum alloy was improved in particular with regard to its strength properties after a baking process.
- Mg contents greater than 0.3% by weight cause problems in the electrochemical roughening of the aluminum strip.
- the pamphlet concerns EP 0 272 528 A2 also an aluminum alloy for lithographic printing plate supports, which, in addition to Fe, Mg, Si, Mn and Ti, contains in particular up to 0.20% by weight copper, up to 0.25% by weight zinc, up to 0.10% by weight Cr and up to 0.025 wt% vanadium.
- the present invention is based on the object of specifying a production method for an aluminum strip which is particularly well suited for the production of lithographic printing plate supports.
- the aluminum alloy provides increased flexural fatigue resistance with constant tensile strength values after a baking process transverse to the rolling direction.
- the flexural fatigue strength transverse to the rolling direction can be increased by more than 40% with the aluminum alloy compared to the aluminum alloys previously used. It is assumed that the combination of relatively high proportions of magnesium and iron in the aluminum alloy is responsible for the improved flexural fatigue strength.
- silicon causes a large number of sufficiently deep indentations to occur during electrochemical etching, so that optimal absorption of the photosensitive lacquer is ensured.
- Copper should be limited to a maximum of 0.04% by weight in order to avoid inhomogeneous structures during roughening. Titanium is only introduced for grain refinement and leads to problems with roughening at higher contents than 0.1% by weight. Manganese, on the other hand, can interact with iron Improving the properties of an aluminum strip made from the aluminum alloy after a baking process, provided the proportion does not exceed 0.25% by weight. Above 0.25 wt%, coarse precipitates are expected to degrade roughening properties.
- Aluminum alloys with the iron contents mentioned showed, in addition to an increase in the flexural fatigue strength from the as-rolled state to the state after a baking process transverse to the rolling direction, a very process-reliable roughenability.
- Mg contents lead to improved mechanical properties, especially after a stoving process. This effect becomes clear with Mg contents of at least 0.4% by weight.
- An upper limit of 0.65 wt. Mg contents above 1% by weight favor the formation of streaks when the aluminum strip is roughened.
- tests showed no signs of problematic roughening properties at Mg contents between 0.4% by weight and 0.65% by weight.
- Magnesium contents of between 0.65% by weight and 1% by weight also result in outstanding properties in terms of flexural fatigue strength transverse to the rolling direction, but the roughening process can become more difficult due to the increasing tendency to form streaks.
- the structure of the aluminum alloy can be further improved in that the aluminum alloy has the following alloy components in percent by weight: Ti ⁇ 0.05%.
- the aluminum alloy preferably has a Mn content of at most 0.1% by weight, preferably at most 0.05% by weight. Due to the high Mg and Fe contents of the aluminum alloy, manganese only makes an insignificant contribution to improving the tensile strength values after a baking process in the aluminum alloy and can therefore be reduced to a minimum.
- the aluminum ribbon for producing lithographic printing plate supports made of the aluminum alloy has a thickness of 0.15 mm to 0.5 mm.
- the aluminum strip is characterized by excellent flexural fatigue strength transverse to the rolling direction, especially after a burn-in process.
- the aluminum strip is characterized by excellent flexural fatigue strength transverse to the rolling direction, especially after a burn-in process.
- the aluminum strip in the as-rolled condition has a tensile strength Rm of less than 200 MPa in the rolling direction and, after a baking process at a temperature of 280°C and a duration of 4 minutes, a tensile strength Rm of more than 140 MPa and a Bending fatigue resistance transverse to the rolling direction of at least 2000 cycles in the bending fatigue test, the aluminum strip can be used particularly advantageously for the production of oversized lithographic printing plate supports.
- the printing plate supports are then particularly easy to handle both in the as-rolled condition and after a baking process. In particular, the printing plate supports produced therefrom have an improved service life.
- a use of the aluminum strip for the production of printing plate supports is described, because these can be reliably processed in larger dimensions and clamped in large printing devices.
- these printing plate supports have an improved service life due to the increased flexural fatigue resistance transverse to the rolling direction and do not tend to plate tears.
- the object indicated above is achieved by a method for producing an aluminum strip for lithographic printing plate supports consisting of the aluminum alloy, in which a rolling ingot is cast, the rolling ingot is optionally homogenized at a temperature of 450° C. to 610° C. the slab is hot rolled to a thickness of 2 to 9 mm and the hot strip is cold rolled to a final thickness of 0.15 mm to 0.5 mm with intermediate annealing.
- the intermediate annealing is carried out in such a way that the desired final strength of the aluminum strip in the as-rolled condition is set by the subsequent cold-rolling process to the final thickness. According to the invention, as already stated, this is just below 200 MPa.
- the intermediate annealing is carried out at an intermediate thickness of 0.5 mm to 2.8 mm, the intermediate annealing taking place in a coil or in a continuous furnace at a temperature of 230°C to 470°C.
- the final strength of the aluminum strip can be adjusted.
- the use of the aluminum alloy to produce a strip for lithographic printing plate supports significantly improves the resistance to alternating bending transversely to the rolling direction of the aluminum strip compared to the previously known aluminum alloys and the aluminum strips produced from them. Overall, there is an increase in the flexural fatigue strength test of more than 40%.
- Table 1 shows the alloy compositions of two aluminum alloys C1, C2, which, as comparative examples, have compositions of aluminum alloys previously used for printing plate supports.
- the aluminum alloys I1 to I4 have significantly higher magnesium and iron values.
- Rolling ingots were cast from alloys V1 to I4. The rolling ingot was then homogenized at a temperature of 450°C to 610°C and hot-rolled to a thickness of 4 mm. This was followed by cold rolling to a final thickness of 0.28 mm.
- Comparison alloy V2 was not subjected to any intermediate annealing during cold rolling, whereas comparison alloy VI and aluminum alloys I1 to I4 were produced with intermediate annealing.
- the intermediate annealing of the strips of comparison alloy V1 took place at an intermediate thickness of 2.2 mm. Intermediate annealing was carried out on the aluminum alloys I1 to I4 at a thickness of 1.1 mm. Table 1 shows the alloy components of the aluminum alloys V1 to I4 in percent by weight.
- the strips produced from the aluminum alloys V1 to I4 were examined with regard to their roughenability. It was found that all the aluminum strips produced had good roughenability.
- Table 2 not only shows the roughenability of the aluminum alloys V1 to I4, but also the number of bending cycles that samples from the various aluminum alloys achieved in a reverse bending test. The reverse bending tests were carried out with an in 1 Schematically shown experimental setup carried out. Alternating bending tests were carried out both with as-rolled aluminum strips and with aluminum strips after a baking process at 280°C for 4 minutes, lengthwise and crosswise to the rolling direction.
- Fig. 1a shows the flexural fatigue test device 1 used in a schematic sectional view.
- samples 2 are fastened in the flexural fatigue test device 1 to a movable segment 3 and a stationary segment 4 .
- the movable segment 3 is moved back and forth on the stationary segment 4 by means of a rolling movement, so that the specimen 2 is exposed to bending perpendicular to the extension of the specimen 2 .
- the specimens simply have to be cut out transversely to the rolling direction and clamped in the device. The same applies to samples cut out in the direction of rolling.
- the radius of the bending segments 3, 4 is 30 mm.
- the aluminum alloys I1 to I4 also show the tensile strength values required for the handling of the printing plate supports, in particular when using oversized printing plate supports clamped transversely to the rolling direction.
- the aluminum strips I1 to I4 have tensile strengths Rm measured according to DIN of less than 200 MPa, so that a coil set can be easily removed.
- the tensile strength Rm of the aluminum strips I1 to I4 is still more than 140 MPa in order to make it easier to clamp large printing plate supports in printing devices. This also applies to the yield strength Rp0.2 measured according to DIN, which is less than 195 MPa in the as-rolled condition and more than 130 MPa after the curing process at 280°C for 4 minutes.
- the values for the tensile strength and yield point of the aluminum strips depend on the process parameters during the production of the aluminum strips.
- the aluminum alloys allow the preferred values to be achieved in a simple manner, for example with intermediate annealing at 1.1 mm, and still provide outstanding flexural fatigue strength properties with very good strength values.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Printing Plates And Materials Therefor (AREA)
Priority Applications (8)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP08105850.5A EP2192202B2 (de) | 2008-11-21 | 2008-11-21 | Aluminiumband für lithographische Druckplattenträger mit hoher Biegewechselbeständigkeit |
ES08105850.5T ES2587024T3 (es) | 2008-11-21 | 2008-11-21 | Banda de aluminio para soportes de plancha de impresión litográfica con alta resistencia a la flexión alternante |
PCT/EP2009/065508 WO2010057959A1 (de) | 2008-11-21 | 2009-11-19 | Aluminiumband für lithographische druckplattenträger mit hoher biegewechselbeständigkeit |
CN200980146724.4A CN102308011B (zh) | 2008-11-21 | 2009-11-19 | 具有高交变弯曲耐受性的用于平版印刷的印版载体的铝带 |
KR1020117014333A KR20110094317A (ko) | 2008-11-21 | 2009-11-19 | 휨 피로 강도가 높은 리소그래프 인쇄판 지지체용 알루미늄 스트립 |
BRPI0922063A BRPI0922063B8 (pt) | 2008-11-21 | 2009-11-19 | Tira de alumínio para produção de suportes de chapas de impressão litográfica de uma liga de alumínio, uso da tira e processo para a produção de uma tira |
JP2011536870A JP2012509404A (ja) | 2008-11-21 | 2009-11-19 | リソグラフ印刷プレート支持体用の高い曲げ疲労強度を有するアルミニウムストリップ |
US13/112,588 US10927437B2 (en) | 2008-11-21 | 2011-05-20 | Aluminium strip for lithographic printing plate supports with high flexural fatigue strength |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP08105850.5A EP2192202B2 (de) | 2008-11-21 | 2008-11-21 | Aluminiumband für lithographische Druckplattenträger mit hoher Biegewechselbeständigkeit |
Publications (4)
Publication Number | Publication Date |
---|---|
EP2192202A1 EP2192202A1 (de) | 2010-06-02 |
EP2192202B1 EP2192202B1 (de) | 2016-07-06 |
EP2192202B9 EP2192202B9 (de) | 2016-11-30 |
EP2192202B2 true EP2192202B2 (de) | 2022-01-12 |
Family
ID=40445590
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP08105850.5A Active EP2192202B2 (de) | 2008-11-21 | 2008-11-21 | Aluminiumband für lithographische Druckplattenträger mit hoher Biegewechselbeständigkeit |
Country Status (8)
Country | Link |
---|---|
US (1) | US10927437B2 (pt) |
EP (1) | EP2192202B2 (pt) |
JP (1) | JP2012509404A (pt) |
KR (1) | KR20110094317A (pt) |
CN (1) | CN102308011B (pt) |
BR (1) | BRPI0922063B8 (pt) |
ES (1) | ES2587024T3 (pt) |
WO (1) | WO2010057959A1 (pt) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR102090529B1 (ko) * | 2012-05-11 | 2020-03-18 | 가부시키가이샤 유에이씨제이 | 알루미늄 합금호일 및 그 제조 방법, 성형 포장체 재료, 이차전지, 의약품 포장 용기 |
CN103667819B (zh) * | 2013-11-22 | 2015-09-16 | 中铝瑞闽股份有限公司 | Ctp版基及其制作方法 |
BR112018070957B1 (pt) * | 2016-04-20 | 2022-08-30 | Hydro Aluminium Rolled Products Gmbh | Método para produção de uma faixa de alumínio para suportes de placa de impressão litográfica de uma liga de alumínio |
US10695450B2 (en) | 2016-07-26 | 2020-06-30 | Laboratoires Cyclopharma | Synthesis of a radioactive agent composition |
CN107868887A (zh) * | 2016-09-23 | 2018-04-03 | 镇江龙源铝业有限公司 | 一种led灯具用铝带新材料 |
CN109652689A (zh) * | 2019-02-26 | 2019-04-19 | 国际铝业(厦门)有限公司 | 一种具有高抗弯强度的铝合金型材及其制备方法 |
JP2023515242A (ja) * | 2020-03-26 | 2023-04-12 | スペイラ ゲゼルシャフト ミット ベシュレンクテル ハフツング | 平坦なトポグラフィーを有するリソストリップおよびそれから製作される印刷版 |
RU2749101C1 (ru) * | 2020-08-07 | 2021-06-04 | Федеральное государственное бюджетное учреждение науки Самарский федеральный исследовательский центр Российской академии наук (СамНЦ РАН) | СПОСОБ ХОЛОДНОЙ МНОГОПРОХОДНОЙ ПРОКАТКИ ТОНКИХ ЛЕНТ ИЗ АЛЮМИНИЕВЫХ СПЛАВОВ Al-Mg |
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JPS62181190A (ja) † | 1986-02-06 | 1987-08-08 | Furukawa Alum Co Ltd | 平版印刷版用アルミニウム合金支持体の製造方法 |
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US4818300A (en) † | 1986-12-08 | 1989-04-04 | Aluminum Company Of America | Method for making lithoplate |
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WO2007045676A1 (de) † | 2005-10-19 | 2007-04-26 | Hydro Aluminium Deutschland Gmbh | Aluminiumband für lithographische druckplattenträger |
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2008
- 2008-11-21 EP EP08105850.5A patent/EP2192202B2/de active Active
- 2008-11-21 ES ES08105850.5T patent/ES2587024T3/es active Active
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2009
- 2009-11-19 WO PCT/EP2009/065508 patent/WO2010057959A1/de active Application Filing
- 2009-11-19 BR BRPI0922063A patent/BRPI0922063B8/pt active IP Right Grant
- 2009-11-19 KR KR1020117014333A patent/KR20110094317A/ko active Search and Examination
- 2009-11-19 JP JP2011536870A patent/JP2012509404A/ja active Pending
- 2009-11-19 CN CN200980146724.4A patent/CN102308011B/zh active Active
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2011
- 2011-05-20 US US13/112,588 patent/US10927437B2/en active Active
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ES2587024T3 (es) | 2016-10-20 |
KR20110094317A (ko) | 2011-08-23 |
BRPI0922063A2 (pt) | 2015-12-15 |
BRPI0922063B8 (pt) | 2023-01-10 |
US10927437B2 (en) | 2021-02-23 |
BRPI0922063B1 (pt) | 2021-05-04 |
EP2192202B9 (de) | 2016-11-30 |
JP2012509404A (ja) | 2012-04-19 |
US20110290381A1 (en) | 2011-12-01 |
EP2192202A1 (de) | 2010-06-02 |
CN102308011A (zh) | 2012-01-04 |
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EP2192202B1 (de) | 2016-07-06 |
CN102308011B (zh) | 2015-11-25 |
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