EP2139837A1 - Procédé de production d'acide formique - Google Patents

Procédé de production d'acide formique

Info

Publication number
EP2139837A1
EP2139837A1 EP08717979A EP08717979A EP2139837A1 EP 2139837 A1 EP2139837 A1 EP 2139837A1 EP 08717979 A EP08717979 A EP 08717979A EP 08717979 A EP08717979 A EP 08717979A EP 2139837 A1 EP2139837 A1 EP 2139837A1
Authority
EP
European Patent Office
Prior art keywords
formic acid
radicals
hydrogenation
catalyst
amine
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP08717979A
Other languages
German (de)
English (en)
Inventor
Nina Challand
Xavier Sava
Michael Röper
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Priority to EP08717979A priority Critical patent/EP2139837A1/fr
Publication of EP2139837A1 publication Critical patent/EP2139837A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/02—Preparation of carboxylic acids or their salts, halides or anhydrides from salts of carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C53/00—Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen
    • C07C53/02—Formic acid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/62—Reductions in general of inorganic substrates, e.g. formal hydrogenation, e.g. of N2
    • B01J2231/625—Reductions in general of inorganic substrates, e.g. formal hydrogenation, e.g. of N2 of CO2
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0202—Alcohols or phenols
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0237—Amines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0271—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds also containing elements or functional groups covered by B01J31/0201 - B01J31/0231
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring

Abstract

L'invention concerne un procédé de production d'acide formique, suivant lequel on produit le formiate d'ammonium correspondant par hydrogénation catalytique de dioxyde de carbone avec de l'hydrogène sur un catalyseur qui contient un métal des groupes 8 à 10 de la classification périodique, en présence d'une amine primaire, secondaire et/ou tertiaire, et l'on sépare le formiate d'ammonium par chauffage en acide formique et en amine. L'invention est caractérisée en ce que l'amine primaire, secondaire ou tertiaire est choisie parmi les amines de formule I ou leurs mélanges, où R<SUB>1</SUB> à R<SUB>3</SUB> sont identiques ou différents et signifient hydrogène, des restes alkyle linéaires ou ramifiés ayant 1 à 18 atomes de carbone, des restes cycloaliphatiques ayant 5 à 7 atomes de carbone, des restes aryle et/ou des restes arylalkyle et au moins l'un des restes R<SUB>1 </SUB>à R<SUB>3 </SUB>porte un groupe hydroxyle, et l'on réalise l'hydrogénation dans un solvant qui présente un point d'ébullition = 105 °C à la pression normale, et l'on obtient l'acide formique dans le mélange réactionnel de l'hydrogénation, contenant le solvant à point d'ébullition élevé, par clivage thermique du formiate d'ammonium et séparation de l'acide formique par distillation.
EP08717979A 2007-03-23 2008-03-18 Procédé de production d'acide formique Withdrawn EP2139837A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP08717979A EP2139837A1 (fr) 2007-03-23 2008-03-18 Procédé de production d'acide formique

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP07104745 2007-03-23
PCT/EP2008/053248 WO2008116799A1 (fr) 2007-03-23 2008-03-18 Procédé de production d'acide formique
EP08717979A EP2139837A1 (fr) 2007-03-23 2008-03-18 Procédé de production d'acide formique

Publications (1)

Publication Number Publication Date
EP2139837A1 true EP2139837A1 (fr) 2010-01-06

Family

ID=39469940

Family Applications (1)

Application Number Title Priority Date Filing Date
EP08717979A Withdrawn EP2139837A1 (fr) 2007-03-23 2008-03-18 Procédé de production d'acide formique

Country Status (10)

Country Link
US (1) US20100063320A1 (fr)
EP (1) EP2139837A1 (fr)
JP (1) JP2010521533A (fr)
KR (1) KR20090123972A (fr)
CN (1) CN101663259A (fr)
AR (1) AR065807A1 (fr)
BR (1) BRPI0809156A2 (fr)
CA (1) CA2681508A1 (fr)
NO (1) NO20093037L (fr)
WO (1) WO2008116799A1 (fr)

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
UA104324C2 (ru) * 2009-06-26 2014-01-27 Басф Се Способ получения муравьиной кислоты
CA2765430A1 (fr) * 2009-06-26 2010-12-29 Basf Se Procede de preparation d'acide formique
US8877965B2 (en) 2010-06-29 2014-11-04 Basf Se Process for preparing formic acid by reaction of carbon dioxide with hydrogen
BR112012012033A2 (pt) * 2010-06-29 2016-05-17 Basf Se processo para preparar ácido fórmico
BR112012032211A2 (pt) 2010-06-29 2016-11-29 Basf Se "processo para obter ácido fórmico".
US8791297B2 (en) 2010-06-29 2014-07-29 Basf Se Process for preparing formic acid by reaction of carbon dioxide with hydrogen
PL2588439T3 (pl) 2010-06-29 2014-09-30 Basf Se Sposób wytwarzania kwasu mrówkowego drogą reakcji ditlenku węgla z wodorem
US8901350B2 (en) 2010-06-29 2014-12-02 Basf Se Process for the preparation of formic acid
WO2012034991A1 (fr) * 2010-09-17 2012-03-22 Basf Se Procédé de préparation de formamides
JP2014508119A (ja) * 2010-12-21 2014-04-03 ビーエーエスエフ ソシエタス・ヨーロピア 二酸化炭素と水素との反応によってギ酸を製造するための方法
DE102011000077A1 (de) * 2011-01-11 2012-07-12 Rheinisch-Westfälische Technische Hochschule Aachen CO2-Hydrierungsverfahren zu Ameisensäure
WO2012168396A1 (fr) * 2011-06-09 2012-12-13 Basf Se Procédé de préparation d'acide formique
WO2012168905A1 (fr) * 2011-06-09 2012-12-13 Basf Se Procédé de préparation d'acide formique
KR20140044891A (ko) * 2011-07-07 2014-04-15 바스프 에스이 이산화탄소와 수소의 반응에 의한 포름산의 제조 방법
RU2014118032A (ru) * 2011-10-07 2015-11-20 Басф Се Способ получения муравьиной кислоты путем превращения диоксида углерода с водородом
WO2013068389A1 (fr) * 2011-11-10 2013-05-16 Basf Se Procédé de préparation d'acide formique par réaction de dioxyde de carbone avec de l'hydrogène
US8889905B2 (en) 2011-12-20 2014-11-18 Basf Se Process for preparing formic acid
BR112014015187A8 (pt) * 2011-12-20 2017-07-04 Basf Se processo para à obtenção de ácido fórmico
US8835683B2 (en) 2011-12-20 2014-09-16 Basf Se Process for preparing formic acid
CA2856959A1 (fr) 2011-12-20 2013-06-27 Basf Se Procede de preparation d'acide formique
DE102013201246A1 (de) * 2013-01-25 2014-07-31 Technische Universität Bergakademie Freiberg Verfahren zur in-situ Umsetzung von chemisch fixiertem Kohlendioxid in niedermolekulare Kohlenwasserstoffe
JP6289310B2 (ja) * 2014-08-27 2018-03-07 一般財団法人電力中央研究所 触媒又はその前駆体並びにこれらを利用した二酸化炭素の水素化方法及びギ酸塩の製造方法
CN105367404B (zh) * 2015-10-13 2018-04-10 大连理工大学 一种二氧化碳催化加氢制备甲酸盐的方法
CN108424359B (zh) * 2018-03-21 2020-11-13 大连理工大学 一种水相中钌配合物催化co2加氢还原制备甲酸盐/甲酸的方法
EP3936498A4 (fr) * 2019-03-08 2022-12-14 Nitto Denko Corporation Procédé de production d'acide formique
JP7405594B2 (ja) 2019-03-08 2023-12-26 日東電工株式会社 ギ酸の製造方法

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4474959A (en) * 1982-05-22 1984-10-02 Bp Chemicals Limited Production of formate salts from carbon dioxide, hydrogen and amines
DE68920933T2 (de) * 1988-08-20 1995-05-24 Bp Chem Int Ltd Produktion von Formiat-Salzen von Stickstoffbasen.
DE4211141A1 (de) * 1992-04-03 1993-10-07 Basf Ag Verfahren zur Herstellung von Ameisensäure durch thermische Spaltung von quartären Ammoniumformiaten

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO2008116799A1 *

Also Published As

Publication number Publication date
JP2010521533A (ja) 2010-06-24
CA2681508A1 (fr) 2008-10-02
KR20090123972A (ko) 2009-12-02
WO2008116799A1 (fr) 2008-10-02
AR065807A1 (es) 2009-07-01
US20100063320A1 (en) 2010-03-11
BRPI0809156A2 (pt) 2014-09-16
CN101663259A (zh) 2010-03-03
NO20093037L (no) 2009-10-19

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