EP2121150A1 - Matériau composite en fibres et noyau de planche de glisse constitué d'un matériau composite en fibres à base de mat de fibres de bois, en particulier pour des skis ou des planches à neige - Google Patents

Matériau composite en fibres et noyau de planche de glisse constitué d'un matériau composite en fibres à base de mat de fibres de bois, en particulier pour des skis ou des planches à neige

Info

Publication number
EP2121150A1
EP2121150A1 EP08707627A EP08707627A EP2121150A1 EP 2121150 A1 EP2121150 A1 EP 2121150A1 EP 08707627 A EP08707627 A EP 08707627A EP 08707627 A EP08707627 A EP 08707627A EP 2121150 A1 EP2121150 A1 EP 2121150A1
Authority
EP
European Patent Office
Prior art keywords
wood
fiber
wood fiber
mats
composite material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP08707627A
Other languages
German (de)
English (en)
Other versions
EP2121150B1 (fr
Inventor
Michael Theurl
Michael Oberlojer
Rudolf Müller
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
THEURL LEIMHOLZBAU GmbH
Original Assignee
THEURL LEIMHOLZBAU GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by THEURL LEIMHOLZBAU GmbH filed Critical THEURL LEIMHOLZBAU GmbH
Publication of EP2121150A1 publication Critical patent/EP2121150A1/fr
Application granted granted Critical
Publication of EP2121150B1 publication Critical patent/EP2121150B1/fr
Not-in-force legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • AHUMAN NECESSITIES
    • A63SPORTS; GAMES; AMUSEMENTS
    • A63CSKATES; SKIS; ROLLER SKATES; DESIGN OR LAYOUT OF COURTS, RINKS OR THE LIKE
    • A63C5/00Skis or snowboards
    • A63C5/12Making thereof; Selection of particular materials
    • AHUMAN NECESSITIES
    • A63SPORTS; GAMES; AMUSEMENTS
    • A63CSKATES; SKIS; ROLLER SKATES; DESIGN OR LAYOUT OF COURTS, RINKS OR THE LIKE
    • A63C5/00Skis or snowboards
    • A63C5/12Making thereof; Selection of particular materials
    • A63C5/126Structure of the core
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24058Structurally defined web or sheet [e.g., overall dimension, etc.] including grain, strips, or filamentary elements in respective layers or components in angular relation
    • Y10T428/24124Fibers
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31971Of carbohydrate
    • Y10T428/31989Of wood

Definitions

  • Fiber composite based on wood fiber mats especially for skis or snowboards
  • the invention relates to a fiber composite.
  • the invention further relates to a sliding board core made of a fiber composite material, which is particularly suitable for installation in skis or snowboards.
  • the invention further relates to a sliding board.
  • the invention relates to a method for producing a fiber composite material, in particular a Gleitbrettkerns.
  • wood is still a virtually predestined material for the production of the entire cores or parts thereof, because it has some mechanical properties which are excellent in relation to its comparatively low density Naturally optimized microscopic structure from predominantly elongated fiber cells with pore-shaped cell cavities are due. Professionals always emphasize the benefits of wooden core skis and snowboards and always place this product in the high-end market segment.
  • Wood with a comparatively low mass, has high tensile and flexural strengths, good vibration damping and high fracture toughness, and exhibits excellent fatigue strengths, both in the case of static fatigue life and in a very high number of alternating deformations.
  • wood As a natural raw material, however, it also shows a typically broad distribution of its properties within the same wood species different growth due to temporally and spatially varying environmental and site conditions (variability of wood properties). This leads to strongly scattering technical values. Thus, for example, the bulk density, which is a significant factor influencing all strength and elasticity values, shows great differences even within the same wooden board and between different production batches.
  • wood has different properties as a function of the action transversely or longitudinally to the fiber direction or radially or tangentially to the growth rings (anisotropy of the wood properties).
  • there is a pronounced hydrophilic behavior of the wood polymers which causes moisture fluctuations even under careful drying and storage of the dried wood under constant climatic conditions.
  • thermosetting plastics in particular those made of polyurethane
  • high-strength RIM foams Reactive Injection Molding
  • rigid integral foams with densities of between 0.4 and 0.6 g / cm 3 only Bending strengths of 20-35 MPa and bending moduli of elasticity between 700-1,100 MPa.
  • spruce wood with a common moisture content of 12% shows a density of approx. 0.47 g / cm 3 and with stress gradients parallel to the fiber an average bending strength of 70 MPa, bending modulus of elasticity of 10,000 MPa.
  • Another known disadvantage of plastics is their fast compared to wood material fatigue and insufficient vibration damping.
  • inorganic fibers - in connection with gliding board cores - has to be considered.
  • glass, carbon or aramid fibers have very high levels
  • thermoplastics used in addition to the previously mentioned thermosets show a number of well-known disadvantages for sliding board cores with respect to creep behavior, plastic deformability, temperature-dependent variability and high density. These also remain in combination with fibers and can not be prevented by the fiber component.
  • DE 744347 discloses a ski, in particular of plastics, wherein the insert or inserts between the outsole and the ski upper side consist of lightweight panels. Such a ski may have at the location of the ski bag another deposit made of wood, which allows a screwing of the binding parts.
  • GB 833721 discloses improvements in and for a ski used in
  • Laminierbauweise is formed with an elongated core, and having a plurality of bonded laminate layers.
  • EP 1,319,503 discloses a composite part of a core layer, on both sides of the core layer arranged with polyurethane resin impregnated fiber layers, a cover layer with Class A surface quality on the a fiber layer and optionally a decorative layer on the second fiber layer.
  • the object of the invention is to provide a producible with reasonable effort fiber composite material with favorable material properties.
  • a fiber composite material is provided, which is produced on the basis of wood fiber mats from mutually entangled wood fibers, are introduced into the thermosetting and / or elastomeric plastics.
  • a sliding board core which has a
  • a gliding board in particular a ski or snowboard, which includes a gliding board core having the features described above.
  • thermosetting plastics also called thermosets
  • plastics can be considered that can not be deformed after their curing.
  • plastics in particular dimensionally stable, but elastically deformable plastics can be considered.
  • the plastics can deform under tensile and compressive load, but then return to their original, undeformed shape.
  • the solid or hard tissue of the shoot axes (trunk, branches, twigs) of trees can be regarded as wood.
  • wood can be considered as a material that stores lignin in the cell wall.
  • a lignified (woody) plant tissue may be referred to as wood in particular.
  • physical structures which can be used for sliding on a solid or liquid surface or for sliding through a fluid (for example gas, liquid) can be considered as a gliding board.
  • the outstanding properties of the naturally optimized fiber composite wood can be combined with the advantages of plastics that can be produced in desired shapes in one operation and the above-mentioned disadvantages regarding the inhomogeneities on the wood and the low mechanical properties of the plastics are excluded , Where the mechanical properties of the fiber composite approached as far as possible those of the wood, but can also be selectively changed and still the lowest possible weight is achieved.
  • a sliding board core is created from a fiber composite material, which is particularly suitable for installation in skis or snowboards.
  • This fiber composite material contains a sufficiently high proportion of
  • Wood fibers which are interlinked in the form of mats with or are present without preferred orientation of the fibers, and are introduced into the thermosetting or elastomeric plastics. Due to the definable high and above all uniform wood fiber density of the mats, a homogeneous material with uniform mechanical properties is achieved, but which can also be selectively changed at different points in the core.
  • the sliding board core has a
  • the plastic polymer takes over the function of the forming binder.
  • mats offer the advantage of a specifically definable and especially uniform wood fiber density, which can be introduced on desired zone sections of the core and the highest possible proportion of wood fibers.
  • the mechanical properties of the core in terms of flexural elasticity, vibration damping and fatigue resistance are as far as possible approximated to those of the wood and, above all, the dosing problems of the injection process at the thinning points to the longitudinal ends are avoided.
  • the mechanical properties can be selectively changed as required at different locations in the core, as is necessary, for example, in the center of the core and at the core ends. This is achieved by local stacking of the
  • Mats and compaction or loosening of the mat structure places higher or lower density and rigidity are created or in that the mats have a preferred fiber orientation, wherein a plurality of such mats can be placed crosswise one above the other.
  • Particularly advantageous in this context is the aforementioned anatomical structure of the wood fiber from cell walls and cell cavities, since thereby the goal of weight reduction compared to heavy inorganic synthetic fibers can be maintained even at high fiber proportions.
  • any thermosetting or elastomeric plastic comes into question, wherein it is particularly advantageous if such polymers are introduced into the wood fiber mats, which foam in the course of curing and thus transmit the pore structure of the wood fibers in the plastic matrix.
  • the mat with the defined homogeneous fiber structure pre-defines the foamable gaps and thus guarantees foaming with evenly distributed pores of homogeneous size in the plastic.
  • the insertion of inserts for receiving the binding screws or a non-adhesive connection with previously inserted into the mold laminates for upper and lower chords or the like in one operation with the Inserting the wood fiber mats is possible.
  • the mentioned wood fibers are obtained, for example, in thermomechanical pulping processes, as they have been tried and tested in the fiber board industry for decades. They are reasonably priced as well as easy and safe to supply.
  • the wood fiber mats can be produced therefrom with specifically determinable density and constant entanglement, with or without reinforcement by plastic threads, with or without prior impregnation by synthetic resins.
  • the wood fiber mats are after cutting into hollow molds, which correspond to the geometry of the finished Gleitbrettkernes inserted, the impregnation with the thermosetting or elastomeric plastic component can be done before loading or only then in the form.
  • the disclosed in the context of this application embodiments of the fiber composite also apply to the Gleitbrettkern, the sliding board and for the process.
  • the disclosed in the context of this application embodiments of Gleitbrettkerns also apply to the fiber composite, the sliding board and for the process.
  • the location of the wood fibers in the wood fiber mat may be free of a preferred direction, i. isotropic, be.
  • the wood fibers can have a statistical distribution in terms of their orientation in the fiber composite, resulting in uniform mechanical properties in all directions.
  • the location of the wood fibers in the wood fiber mat may have a preferred direction, i. anisotropic.
  • the wood fibers may have an ordered distribution in orientation in the fiber composite, resulting in different mechanical properties in different directions.
  • a composite material based on wood fiber mats and foamed (or foaming) elastomeric or thermosetting polymers and a process for its production is provided.
  • Embodiments of the invention relate to a mats-based composite with wooden fibers from the woody plant trunk / thermomechanical pulping processes into which foamable (or foaming) elastomeric or thermosetting polymers are incorporated, and to a process for its production ,
  • a process for producing a composite formed with wood fibers from the woody plant / thermomechanical pulping process and foamed elastomeric or thermosetting polymers the density values being that of industrially useful coniferous or hardwoods should be sought and the highest possible proportion of wood fibers (for example, at least 30 percent by weight or at least 50 weight percent) should be present, which enter into a predictable uniform distribution of a compound with the foam structure of the polymer.
  • a foamable elastomeric or thermosetting polymer for example polyurethane, can be introduced into previously provided wood fiber mats.
  • the proportion of wood fibers in the composite material is to be kept as high as possible and, moreover, the wood fibers are to be embedded in the plastic matrix in a predeterminable uniform distribution, a suitable process can be found for the reasons described above by introducing the polymer into wood fiber mats.
  • wood fibers can be used in particular from the thermo-mechanical refining process.
  • the log can first be crushed and then fed to a digestion process, for example the thermo-mechanical refining process.
  • the wood fibers can be dried. Since the wood fibers constantly interlock with each other and can not be scattered loose, they can be brought by needling in a spatially matted structure, which usually even small parts by weight of synthetic fibers to reinforce the mat structure are introduced. In this form, the mats can then easily manipulated, cut in shape, stacked, transported and stored.
  • an automatically foaming polyurethane can be used, which brings the advantage of a long experience in combination with wood.
  • the chemical affinity for the free hydroxyl groups of the cellulosic, hemicellulosic and ligninous molecules is also good.
  • Fiber mats may be provided, for example, with thicknesses between 2 mm and 30 mm (or higher: 50 mm or more). Thus, a defined space is given for the subsequent plastic matrix into which it can penetrate. According to one embodiment of the invention, a
  • Composite of natural / wood fiber and foamed elastomeric or thermosetting polymers be provided. Such a composite material may have at least 40% share of wood fibers.
  • a composite may contain a combination of mats of different density / thickness.
  • Self-foaming polyurethane can be used for such a composite material.
  • Composite material can be configured as a continuous process.
  • a corresponding method for producing a composite material may alternatively be designed as a discontinuous process.
  • fiber cells in all land plants form the supporting and guiding tissue, which is why they are rather elongated and have stronger cell walls.
  • the cell walls of the fiber cells in the trunk of woody plants differ substantially from those of the remaining fiber plants with one or only a few years of growth times, that at the molecular level between the formed as elongated strands macromolecular polysaccharides, ie the cellulose and the hemicelluloses, of which completely different and amorphous lignin, the 'woody' material, is present in a high proportion of about 20 to 30 and more percent by weight and in the way that it forms a matrix in which the cellulosic fibrils are embedded.
  • the lignin content is in the one-digit percentage range, with hemp, for example, between about 2 and 5 percent by weight. Due to the high proportion of amorphous lignin, the digested, ie isolated wood fibers are much more brittle than those of the other non or less woody fiber plants, whose cell walls are composed almost exclusively of the string-shaped cellulosic framework substances.
  • a decisive advantage of the refiner wood fibers, however, is their consistent quality, which is due to the fact that the fiber cells were formed in the trunk wood from a decades-long centuries active mantle cambium by cell division in constantly the same design.
  • the fiber cells of woody plants with thickness growth are thus firmly in a comprehensive association of more or less the same or similar Cells are involved, wherein the elongated fiber cells of the softwoods are very similar and have a length of typically less than 5 mm.
  • the quality of the fibers from the non-woody plants with one or a few years' rotation is strongly dependent on the growth conditions in the one or more concerned
  • Fiber production The fiber cell in the wood is firmly bound into an extensive bandage of similar cells and so builds the trunk wood with known large diameters and heights, while above-described bast or leaf fibers occur in the form of easily isolatable fiber bundles. Therefore, the industrial processes for the development and above all the fiber products are completely different.
  • thermo-mechanical refining technology As part of the thermo-mechanical refining technology, it is first crushed and the wood parts then boiled under steam and under pressure. Since the pectins, the "fiber adhesive", which binds the individual cells together, dissolve and plasticize the amorphous lignin, the material can
  • a fiber composite or a Gleitbrettkern according to an embodiment of the invention may be used as the basis for a ski (for example, an alpine ski or a cross-country ski or a mono-ski), a snowboard, a surfboard, car covers, aircraft panels, furniture parts, panels and others
  • Covering elements for indoor and outdoor use, etc. may be provided. Other applications are possible.
  • Fig. 1 shows a sliding board core with recessed insert for later receiving screws for a binding region of a ski according to an exemplary embodiment of the invention.
  • Fig. 2 shows a sliding board core with locally compressed areas according to another exemplary embodiment of the invention.
  • FIGS. 3 to 7 show various combinations of wood fiber mats of the same or different densities according to exemplary embodiments of the invention.
  • Figures 8 and 9 show images of raw wood fiber mats, for example, as the basis for sliding board cores according to exemplary embodiments of the invention.
  • 10 shows an insert inserted into a fiber composite according to an exemplary embodiment of the invention.
  • 11 to 13 show a fiber composite, as it is particularly suitable for sliding board cores, according to an exemplary embodiment of the invention.
  • FIG. 1 shows a cross section of a gliding board core 100 according to an exemplary embodiment of the invention.
  • the Gleitbrettkern 100 is made of a fiber composite, which is formed on the basis of a wood fiber mat of mutually matted wood fibers 102, in which a thermosetting or elastomeric plastics is introduced. This is, as indicated by reference numeral 104, provided in intermediate spaces between the entangled wood fibers 102.
  • the gliding board core 100 may be provided as a base for a ski and is characterized in that the entangled wood fibers 102 have a preferred direction, namely parallel or substantially parallel to the horizontal dimension of the gliding board core 100 according to FIG. 1.
  • an insert 106 is formed with a screw thread, which can be firmly connected by means of a screw or other fastener, for example, with a ski binding or another element to be coupled.
  • FIG. 2 shows a cross section of a gliding board core 150 according to another exemplary embodiment of the invention.
  • the gluing board core 150 has different densities and wood fiber portions at different sliding board core zones. More specifically, an area 152 of the gliding board core 150 is one with a smaller one Density is provided as an area 154 of the higher density boarding board core 150. This can be achieved, for example, by applying pressure to the area 154 of the sliding board core 150.
  • Fig. 2 thus shows a gliding board core 150 in which zones 152, 154 of different densities are created by compacting the originally homogeneous and constantly dense wood fiber mat at local locations in the gliding board 150, such as those raised to create the typical three-dimensional shape together with the gliding board ends Tips is necessary.
  • An important point in the design of the density zones in the board is the fact that even when using an originally homogeneous wood fiber mat with originally constant density zones 152, 154 different density arise when the typical three-dimensional shape of Gleitbrettkernes 150 (8 mm in the middle of the board strong, at the ends only 3 mm) is created by pure compression at the board ends.
  • FIG. 2 therefore illustrates the creation of zones 152, 154 of differing density by local densification of the original homogeneous constant density wood fiber mats, for example, in the longitudinal direction toward the ends of the gliding board core 150. Also due to the fact that the Gleitbrettkern 150 tapers towards the tips and thus forms a three-dimensional shape. In Fig. 2, an increase of the core shape is shown on the Gleitbrettspitzen (thicknesses shown in excess compared to length).
  • FIGS. 3 to 7 show various possible combinations of wood fiber mats of different densities with a plastic that may be used, for example, for a fiber composite according to exemplary embodiments of the invention.
  • the wood fiber mat may have a relatively low density of For example, 0.05 g / cm 3 to 0.15 g / cm 3 (in which case the plastic 104 is not included).
  • FIG. 4 shows a wood fiber mat based fiber composite 300 according to another exemplary embodiment of the invention.
  • felted wood fibers 102 are embedded, which are embedded in a plastic matrix 104.
  • the wood fiber mat is provided with a higher density than shown in FIG. 2, for example, about 0.20 g / cm 3 .
  • Fig. 5 shows a wood fiber mat based
  • Fiber composite 400 according to another exemplary embodiment of the invention. This is shaped by two fiber composite panels 200 based on wood fiber mats of the same density 200 arranged one above the other in the manner of a height layer model and connected to one another, for example by gluing. It is on the one hand possible to connect the two fiber composite panels 200 only after curing of the respective plastics 104 with each other, for example, to glue or screw. On the other hand, it is possible to apply two wood fiber mats of the same density to each other and to work together to form a fiber composite by inserting and curing a plastic 104 in both wood fiber mats after application, thereby forming the fiber composite sheets 200 and simultaneously bonding them together.
  • FIG. 6 shows a fiber composite 500 according to another embodiment of the invention, in which a fiber composite mat 200 based on a first density wood fiber mat with another fiber composite mat 300 based on a second density wood fiber mat (greater than the first density) are connected.
  • a combination of types of mats of different densities for the formation of the fiber composite material 500 in the manner of a height layer model be used.
  • Different wood fiber mat densities in different areas of the fiber composite material 500 can serve, for example, to fulfill different stability and / or flexibility requirements depending on the location. It is on the one hand possible to connect the two fiber composite panels 200, 300 only after curing of the respective plastics 104 with each other, for example, to glue or screw.
  • Fig. 7 shows a fiber composite 600 according to an exemplary embodiment of the invention.
  • a fibrous composite panel 200 based on a first density wood fiber mat and another fibrous composite panel 300 based on a second density (which is greater than the first density) wood fiber mat are laterally bonded together.
  • a fiber composite panel 200 and a first density wood fiber mat are laterally bonded together.
  • Composite fiber plate 300 laterally to each other or arranged side by side and bonded together on a narrow side / side surface, so that the broad sides / main surfaces of the fiber composite panels 200, 300 do not touch.
  • Different wood fiber mat densities in different regions of the fiber composite material 600 can serve, for example, to fulfill different stability and / or flexibility requirements depending on the location. It is on the one hand possible to connect the two fiber composite panels 200, 300 only after curing of the respective plastics 104 with each other, for example, to glue or screw.
  • mat types of different densities in the longitudinal direction of the fiber composite 600 may be combined, for example, to produce a higher density and stiffness at pointed zones.
  • FIG. 8 shows an overhead view 700 of a wood fiber mat as a base for a gliding board core in accordance with an exemplary embodiment of the invention.
  • Fig. 9 shows another image 800 of the wood fiber mat of Fig. 8.
  • Fig. 10 shows with an image 900 how an insert element (e.g.
  • a connecting device for connecting a fiber composite plate with an element to be coupled is inserted into a wood fiber mat.
  • the insert element can either be cast into the wood fiber mat by potting the wood fiber mat with the integrated insert element by means of a plastic after adding the insert element.
  • the insert element may alternatively be formed after incorporation and curing of plastic into the wood fiber mat in the resulting fiber composite panel, for example, by inserting the insert member into a bore of the fiber composite panel and bonded thereto (eg, bonded).
  • FIG. 11 shows a fiber composite material 1000 according to an exemplary embodiment of the invention, in which inserts previously pressed into the mat and subsequently formed with foamed-in inserts are formed.
  • FIG. 12 shows another fiber composite material 1100 according to an exemplary embodiment of the invention.
  • FIG. 13 shows a cross-section of a fiber composite panel 1200 according to an exemplary embodiment of the invention.
  • Gliding board cores may, for example, be fiber mats manufactured by Faurecia (mats of softwood refiner fibers, basis weight 1,200 g / m 2 to 1,800 g / m 2 ; density at 8 mm thickness: 0,15 g / cm 3 and 0,22 g / cm 3, respectively ) and the manufacturer BO-Systems (mats of softwood refiner fibers with basis weight 1,800 g / m 2 ).
  • a metal sleeve with internal thread can be used, which may be provided on the base this round or hexagonal spanning and may have a plastic sheath. This can make a composite with a total density in the area lighter
  • Deciduous or coniferous trees are prepared. However, it is also possible to produce lighter composite materials, for example with a density of 0.35 g / cm 3 .
  • the composite is technologically in competition with solid wood cores, which can be made, for example, of poplar, paulownia (bluebell tree from East Asia, a very light wood), beech, etc. laminated and a density throughout the laminated cross section of, for example, about 0, 43 g / cm 3 may have.
  • Pure PUR cores polyurethane
  • pure PUR cores polyurethane
  • the core has an effect on the board properties of a gliding board core made therefrom.
  • the requirements are therefore to be made with regard to the material properties, so that above all a desired bending stiffness and a desired bending elasticity can be achieved.
  • the tear strength of the inserted insert which can accommodate the later binding screws to certain Adjust requirements for gliding boards.
  • a standard requirement for such sliding boards may be 4,500 Newtons.
  • Wood fiber mats offer the advantage that the inserts can be pressed into the mat before foaming and thus be foamed up when the polyurethane (polyurethane foam) is applied. As a result, a good insert tear resistance can be achieved, and the standard value of 4,500 Newton can be achieved or even exceeded.
  • a manufacturing method will be described in detail.
  • Modipur 541 can be used.
  • Modipur US 541/22 from Hexcel Composites can be used as a CFC-free polyurethane system (4,4'-diphenylmethane diisocyanate + polyol + low percentage of amines as activator).
  • the viscosity of the mixed system can be kept below 2,000 mPa.s.
  • the field of application is the ski industry, especially for PUR cores produced by injection molding. Up to the beginning of the foaming, the open time can be about 30 seconds, whereby the setting time can be about 1 minute.
  • fiber mat foaming can be performed without form. The fiber mat can be acted upon on both sides with a certain amount of PUR, and the exiting or foamed at the mat surface PUR be removed again.
  • the fiber mat foam can be carried out in the form.
  • the remaining amount of PUR can be mixed.
  • a part (for example, half) thereof may first be filled in a mold become. Then a mat can be inserted. Another part (for example, the other half) can be painted on the mat.
  • the mold can be closed, for example mechanically, hydraulically or pneumatically.
  • Said form can also serve in an industrial manufacturing process for receiving the upper and lower surfaces of the sliding board core applied upper and lower straps (for example, Glasmaschineverstärkungsvlies), which can be glued simultaneously in the course of PUR-introduction firmly with the Gleitbrettkern, and the typical pretend three-dimensional shape of the Gleitbrettkernes.
  • upper and lower straps for example, Glasmaschineverstärkungsvlies
  • an optimization can be carried out via a PUR system.
  • Modipur US 23 isocyanate
  • Modipur US 566 mod.5 polyol
  • Wood fiber mat with a specified ratio of, for example, 1 part by weight of wood fiber mat (with about 8 mm thickness and about 0.20 g / cm 3 ) to 1 part by weight of mixed PUR can be further improved. This has proven to be more advantageous than heating both components (isocyanate and polyol). Although in the latter case the viscosity continues to decrease, the starting time tends to be a non-preferred value.
  • a pressurization can be provided, which makes it possible to better convey the PUR into the center of the mat by means of higher pressures.
  • uncompressed wood fiber mats which have a thickness of, for example, 35 mm and thus a density of only about 0.05 g / cm 3 at the same weight per unit area of 1,800 g / m 2 , can be used.
  • the PUR after applying the PUR, to place the mat under compressive pressure so that it is compressed below the desired final thickness and the PUR is thus uniform to the middle of the mat is encouraged.
  • the pressure is removed again and the mold is reduced to the final thickness to be achieved, whereby the mat is relaxed again and is also returned in the course of foaming by the foam pressure from the inside to the final thickness.
  • An example of the dimensioning of a gliding board is a thickness decreasing in the longitudinal direction from the gliding board center to the tips of about 8 mm to about 3 mm, a width of about 24 cm to about 29 cm and a length of about 155 cm.
  • the wood fiber content of the total mass of the composite can for
  • Example be greater than 50%, or even 30% or more.
  • a suitable range for the mass fraction of the wood fiber is between 20% and 70%, in particular between 40% to 60%.
  • Suitable density zones are at a Gleitbrettkern at about 0.35 g / cm 3 to 0.45 g / cm 3 . In higher densities, however, densities of about 0.65 g / cm 3 and more are possible. In addition to a high stability but also a light weight is desirable, so that a preferred range of values between 0.30 g / cm 3 and 0.65 g / cm 3 , in particular between 0.35 g / cm 3 and 0.45 g / cm 3 . Wood fiber mats have significant advantages over other natural fiber mats for the invention. These include the consistent quality of the wood fibers due to the biological relationships described above compared to the grades of natural fibers from 1 year or less growth, which fluctuate greatly from crop to harvest year.

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Abstract

L'invention concerne un matériau composite en fibres, en particulier pour la construction de skis ou de planches à neige. Ce matériau composite en fibres est constitué d'une part la plus élevée possible de fibres de bois, interconnectées les unes avec les autres sous forme de mat avec ou sans orientation préférée des fibres, et dans lesquels des matières plastiques dures ou élastomères sont incorporées. Grâce à la densité élevée et surtout régulière, pouvant être définie, des fibres de bois des mats, on obtient un matériau homogène ayant des propriétés mécaniques régulières, mais qui peuvent aussi être modifiées de manière ciblée à différents emplacements du noyau.
EP20080707627 2007-02-09 2008-02-08 Matériau composite en fibres et noyau de planche de glisse constitué d'un matériau composite en fibres à base de mat de fibres de bois, en particulier pour des skis ou des planches à neige Not-in-force EP2121150B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
AT0021407A AT504841B1 (de) 2007-02-09 2007-02-09 Gleitbrettkern für schi oder snowboards
PCT/EP2008/000982 WO2008095725A1 (fr) 2007-02-09 2008-02-08 Matériau composite en fibres et noyau de planche de glisse constitué d'un matériau composite en fibres à base de mat de fibres de bois, en particulier pour des skis ou des planches à neige

Publications (2)

Publication Number Publication Date
EP2121150A1 true EP2121150A1 (fr) 2009-11-25
EP2121150B1 EP2121150B1 (fr) 2013-04-03

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EP20080707627 Not-in-force EP2121150B1 (fr) 2007-02-09 2008-02-08 Matériau composite en fibres et noyau de planche de glisse constitué d'un matériau composite en fibres à base de mat de fibres de bois, en particulier pour des skis ou des planches à neige

Country Status (5)

Country Link
US (1) US20100086728A1 (fr)
EP (1) EP2121150B1 (fr)
JP (1) JP2010518203A (fr)
AT (1) AT504841B1 (fr)
WO (1) WO2008095725A1 (fr)

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Also Published As

Publication number Publication date
AT504841A1 (de) 2008-08-15
EP2121150B1 (fr) 2013-04-03
AT504841B1 (de) 2009-03-15
WO2008095725A1 (fr) 2008-08-14
JP2010518203A (ja) 2010-05-27
US20100086728A1 (en) 2010-04-08

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