EP2043596A1 - Crayon cosmétique - Google Patents

Crayon cosmétique

Info

Publication number
EP2043596A1
EP2043596A1 EP07787112A EP07787112A EP2043596A1 EP 2043596 A1 EP2043596 A1 EP 2043596A1 EP 07787112 A EP07787112 A EP 07787112A EP 07787112 A EP07787112 A EP 07787112A EP 2043596 A1 EP2043596 A1 EP 2043596A1
Authority
EP
European Patent Office
Prior art keywords
preparation
wax
waxes
form according
stick form
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
EP07787112A
Other languages
German (de)
English (en)
Inventor
Heidi Riedel
Kirsten Schneider
Frank Schwanke
Lynn Viehmeyer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Beiersdorf AG
Original Assignee
Beiersdorf AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Beiersdorf AG filed Critical Beiersdorf AG
Publication of EP2043596A1 publication Critical patent/EP2043596A1/fr
Ceased legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02—Preparations containing skin colorants, e.g. pigments
    • A61Q1/04—Preparations containing skin colorants, e.g. pigments for lips
    • A61Q1/06—Lipsticks
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0216—Solid or semisolid forms
    • A61K8/0229—Sticks
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/31—Hydrocarbons
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A61K8/342—Alcohols having more than seven atoms in an unbroken chain
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37—Esters of carboxylic acids
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37—Esters of carboxylic acids
    • A61K8/375—Esters of carboxylic acids the alcohol moiety containing more than one hydroxy group
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8105—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • A61K8/8111—Homopolymers or copolymers of aliphatic olefines, e.g. polyethylene, polyisobutene; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin

Definitions

  • the present invention relates to a cosmetic stick.
  • Lipsticks usually consist of a wax matrix in which low-concentration liquid and semi-solid oils and pigments and fillers are incorporated. They are in solid pen form.
  • Lip Gloss contains predominantly liquid oils that leave a moist, moisturizing "oil film" on the skin.Lip Gloss is available in liquid or viscous form at room temperature.
  • the decorative most effective effects in the lip area can be achieved in particular by a combination of colored lipstick and lip gloss.
  • the color emphasizes the mouth area, the moist-shining lip-gloss gives the lips a healthy lush appearance, because lip-gloss leaves the lips fuller (voluminous) act.
  • the usually female user of decorative lip cosmetics usually proceeds by first using a lipstick to dye the lips and then "paint" them with lip-gloss, which is a two-stage make-up process using two different cosmetics (colored lipstick and lip gloss) are used.
  • a disadvantage of the prior art is the fact that it has not been possible to develop moist gloss lip gloss lipsticks.
  • conventional lipsticks if the amount of oil increases, the pins quickly lose their strength and produce viscous, non-malleable masses. If you increase the amount of wax in lip-gloss formulations, the preparations lose their shine very quickly before they even reach the desired pen consistency.
  • a cosmetic preparation in stick form comprising a) a combination of one or more natural waxes, one or more microcrystalline waxes, one or more synthetic waxes, wherein the total amount of all waxes in the preparation is 9 to 15% by weight, based on the total weight of the preparation, b) several oils c) one or more lipids having a melting point of 30-40 ° C in a total amount of 5-15 wt .-%, based on the total weight of the preparation.
  • the preparations according to the invention are distinguished by high pen strength, a slight abrasion when applied to the lips and an exceptionally high wet gloss.
  • the term "stick-shaped preparation” is understood to mean a preparation which has the consistency of a conventional lipstick at room temperature (20 ° C.) In particular, it is firm and dimensionally stable on the one hand and easily spread on the lips on the other hand.
  • the melting points and melting ranges according to the invention can be determined according to the invention according to DIN 51803.
  • the total amount of all waxes in the preparation is 10 to 12% by weight, based on the total weight of the preparation.
  • lipids with a melting point of 30-40 ° C in a total amount of up to 8-12 wt .-%, based on the total weight of the preparation in this are included.
  • the preparation contains pigments in an amount of 0.05-8 wt .-%, based on the total weight of the preparation.
  • the preparation according to the invention contains pigments in an amount of up to 1-5% by weight or 2-4% by weight, based on the total weight of the preparation.
  • the preparation according to the invention in stick form is characterized in that the pigments have an average size of 2 to 5 ⁇ m.
  • the average size of the particles can be determined as follows: Measuring instrument: Grindometer; Measuring range: 0-25 ⁇ m; The sample is filled into the lower end (at 25 ⁇ m) of the grindometer without air bubbles. Subsequently, the sample is spread evenly with a scraper to the other end of the grindometer. After the sample has been spread, the particle size is determined by observing the surface of the grindometer against the light. At the depth where the particles leave marks on the surface of the grindometer, the value is read.
  • Pigments of the invention may be of organic and inorganic origin, such as azo-type organic, indigoidene, triphenylmethane-type, anthraquinones, and xanthine dyes known as D & C and FD & C blues, browns, greens, oranges, reds, yellows.
  • Inorganic pigments consist of insoluble salts of certified dyes called lakes or iron oxides. For example, barium lakes, calcium lakes, aluminum lakes, titanium dioxides, mica and iron oxides can be used.
  • Al salts include Red 3 Aluminum Lake, Red 21 Aluminum Lake, Red 27 Aluminum Lake, Red 28 Aluminum Lake, Red 33 Aluminum Lake, Yellow 5 Aluminum Lake, Yellow 6 Aluminum Lake, Yellow 10 Aluminum Lake, Orange 5 Aluminum Lake , Blue 1 Aluminum Lake and combinations.
  • iron oxides or oxide hydrates e.g. cosmetic yellow oxide C33- (sunchemical), cosmetic brown oxide C33-115 (Sun Chemical), cosmetic iron oxide red C33-2199 (Sun Chemical), cosmetic russet oxide C33-8075 (Sun Chemical), cosmetic iron oxide black C33-5000 (Sunchemical), as Titanium Dioxide eg Kronos 1 171 (Kronos), C47-051 Cosmetic White (Sunchemical) is known and, if appropriate, beneficial.
  • these preparations have a content of inorganic pigments selected from the group of metal oxides and / or other sparingly water-soluble or insoluble metal compounds, preferably oxides of titanium (TiO 2 ), zinc (ZnO), iron (eg. Fe 2 O 3 ), zirconium (ZrO 2 ), silicon (SiO 2 ), manganese (eg MnO), aluminum (Al 2 O 3 ), cerium (eg Ce 2 O 3 ), mixed oxides of the corresponding Metals and mixtures of such oxides and the sulfate of barium (BaSO 4 ) have.
  • inorganic pigments selected from the group of metal oxides and / or other sparingly water-soluble or insoluble metal compounds, preferably oxides of titanium (TiO 2 ), zinc (ZnO), iron (eg. Fe 2 O 3 ), zirconium (ZrO 2 ), silicon (SiO 2 ), manganese (eg MnO), aluminum (Al 2 O 3 ), cerium
  • the inorganic pigments can advantageously be used in the context of the present invention also in the form of commercially available oily or aqueous predispersions. Dispersants and / or solubilizers may advantageously be added to these predispersions.
  • the pigments may advantageously be surface-treated ("coated"), whereby, for example, a hydrophilic, amphiphilic or hydrophobic character is to be formed or retained.This surface treatment may consist in using a thin hydrophilic and hydrophilic pigment according to methods known per se or hydrophobic inorganic and / or organic layer
  • the various surface coatings may also contain water for the purposes of the present invention.
  • Inorganic surface coatings for the purposes of the present invention may consist of aluminum oxide (Al 2 O 3 ), aluminum hydroxide Al (OH) 3 , or aluminum oxide hydrate (also: alumina, CAS No .: 1333-84-2), sodium hexametaphosphate (NaPO 3 ). 6, sodium metaphosphate (NaPOs) n , silicon dioxide (SiO 2 ) (also: silica, CAS No .: 7631-86-9), or iron oxide (Fe 2 Os). These inorganic surface coatings may be present alone, in combination and / or in combination with organic coating materials.
  • Organic surface coatings for the purposes of the present invention may consist of vegetable or animal aluminum stearate, vegetable or animal stearic acid, lauric acid, dimethylpolysiloxane (also: dimethicone), methylpolysiloxane (methicone), simethicone (a mixture of dimethylpolysiloxane with an average chain length of 200 to 350 Dimethylsiloxane units and silica gel) or alginic acid. These organic surface coatings may be present alone, in combination and / or in combination with inorganic coating materials.
  • the process according to the invention also includes the incorporation of color pigments into the preparations according to the invention.
  • the color pigments are first predispersed in a cosmetic oil before this dispersion is incorporated into the preparation.
  • Oils which are advantageous according to the invention for the preparation of the dispersion of the dyes are, above all, polar oils, in particular castor oil, coconut glycerides, octyldodecanol, diisostearyl fumarate.
  • polar oils in particular castor oil, coconut glycerides, octyldodecanol, diisostearyl fumarate.
  • excellent dispersing results and a very narrow particle size spectrum are obtained after a very short time.
  • the mean particle size is around 2-5 microns.
  • Pigments can also act as a light filter and thus protect the lips from damage by UV radiation.
  • the cosmetic preparation according to the invention is characterized in that the preparation after application to the skin produces a gloss value of greater than or equal to 10 after a time of 5 minutes. According to the invention, preparations which produce a gloss value of greater than 12 after a time of 5 minutes are preferred. Particular preference is given to preparations which produce a gloss value of greater than 14 after a time of 5 minutes.
  • the gloss value according to the invention is determined by the following method: To determine the skin gloss, a reflectance spectrometer (measuring instrument: tenth gloss meter ZGM 1020 60 °) is used. Using a light guidance technique and a special measuring head, white light is applied to the skin surface at an entrance angle of 60 °. The light reflected or mirrored at the exit angle of likewise 60 ° is supplied to the detector and quantified. Characteristic: Gloss value according to DIN EN ISO 2813 The measurement takes place on the untreated area, as well as after 5 minutes and 15 minutes of application.
  • the preparation according to the invention advantageously contains 0-5% by weight pearlescent pigments.
  • pearlescent pigment types based on mica / metal oxide are also advantageous, for example, are the following pearlescent pigment types based on mica / metal oxide:
  • the pigments of the companies Costenoble (cloisonne type, flamenco type, Low Luster type), Merck (Colorona types, Microna type, Timiron type, Colorona, Ronasphere), Les Colornats Wacker (Covapure, Vert oxyde de Chrome), Cadre (Colorona, Sicopearl), BASF (Sicopearl, Sicovit), Rona (Colorona).
  • pearlescent pigments which are prepared using SiO 2 , for example those obtainable from Merck under the name Xirona.
  • Such pigments which may also have additional gonichromatic effects are, for. B. under the trade name Sicopearl Fantastico available from BASF.
  • Pigments based on synthetic mica (synthetic fluorophlogopite) from Sunchemical can be advantageously used. These are available under the name SunShine.
  • the weight ratio of microcrystalline wax to synthetic wax is 45:55 or the proportion of microcrystalline wax is greater. According to the invention, this weight ratio is preferably 50:50.
  • microcrystalline waxes of the invention have a melting range of 60-90 ° C. According to the invention preferably have a melting range of 80 to 90 ° C.
  • the synthetic waxes according to the invention have a melting range of 60-90 ° C. According to the invention preferably have a melting range of 70-85 ° C.
  • natural waxes are understood to mean compounds which fall under the term “natural waxes” according to the standard works (for example Römpp-Chemie-Lexikon).
  • hydrogenated waxes of natural origin i.e., a natural wax which has been hydrogenated also fall under this definition.
  • the natural waxes are selected from the group of the compounds candelilla wax, carnauba wax, beeswax, shellac wax, berry wax, hydrogenated jojoba wax, wool wax, sugarcane wax, rice germ wax.
  • the use of the natural waxes candelilla wax, carnauba wax and shellac wax according to the invention is particularly preferred.
  • microcrystalline waxes are understood to mean compounds which fall under the term “microcrystalline waxes” according to the standard works (for example Römpp-Chemie-Lexikon).
  • microcrystalline waxes are selected from the group of products Micro-La, Paracera, Micro Care from Paramelt, Kahlwachs / microwax, special wax from Kahl Permulgin from Koster Keunen and / or Microcrystalline Wax type SP from Company Strahl & Pitch, which are freely available in the trade.
  • synthetic waxes are understood to mean compounds which fall under the term “synthetic waxes” in accordance with the standard works (eg Römpp-Chemie-Lexikon).
  • the synthetic waxes are selected from the group of compounds of straight-chain polyethylene waxes, Fischer-Tropsch waxes, fatty alcohols (C30-50) which have a melting point of 60-90 ° C.
  • the use of synthetic waxes polyethylene waxes, Fischer-Tropsch waxes according to the invention is particularly preferred.
  • lipids are understood to mean compounds which fall under the term “lipids” according to the standard works (for example Römpp-Chemie-Lexikon), with the exception of the compounds which belong to the waxes or to the oils.
  • the lipids with a melting point of 30-40 ° C. are selected from the group of the compounds shea butter, myristyl lactate.
  • oils are understood as meaning compounds which fall under the terms of the standard works (for example Römpp-Chemie-Lexikon) under "oils”.
  • oils a mixture of the components
  • Pentaerytrityl ester diisostearyl malate, caprylic / capric triglyceride, isododecylstearyl stearate in an amount of 10-25% by weight,
  • the preparation according to the invention may advantageously contain further constituents according to the invention.
  • the preparation according to the invention contains as further constituents one or more compounds selected from the group of preservatives, UV light protection filters, dyes, film formers, vitamin A palmitate, vitamin E acetate, allantoin, panthenol, ⁇ - Bisabolol, lecithin, ceramides, collagene contains.
  • the preservatives used are parabens and in particular propylparabens.
  • the preparation according to the invention advantageously contains the preservatives according to the invention in a total concentration of 0.01 to 0.5% by weight, based on the total weight of the preparation.
  • UV light protection filters butyl methoxybenzoylmethane, octyl Methoxycinnamate, bis-ethylhexyloxyphenol methoxyphenyl triazines.
  • the inventive composition contains the UV light protection filter according to the invention advantageously in a total concentration of 0.1 to 3% by weight, based on the total weight of the preparation.
  • VP / eicosene copolymer PVP hexadecene copolymer
  • sucrose acetate isobutyrate sucrose acetate isobutyrate
  • the preparation according to the invention advantageously contains the film-forming agents according to the invention in a total concentration of 0.5 to 5% by weight, based on the total weight of the preparation.
  • the active compounds according to the invention vitamin A palmitate, vitamin E acetate, allantoin, panthenol, ⁇ -bisabolol, lecithin, ceramides, collagens can advantageously be used according to the invention in a single concentration of 0.01 to 5% by weight, based on the total weight of the preparation be included in this.
  • Also according to the invention is a lipstick envelope containing the preparation according to the invention.
  • the use of the preparation according to the invention as a lipstick is possible.
  • a reflectance spectrometer (measuring instrument: Tenth Glossmeter ZGM 1020 60 °) is used. Using a light guidance technique and a special measuring head, white light is applied to the skin surface at an entrance angle of 60 °. The light reflected or mirrored at the exit angle of likewise 60 ° is supplied to the detector and quantified. Characteristic: Gloss value according to DIN EN ISO 2813 The measurement takes place on the untreated area, as well as after 5 minutes and 15 minutes of application. For results see example formulations
  • phase A is melted with constant stirring at 90 ° C.
  • phase B is added and stirred.
  • the cosmetic preparation is poured into a suitable mold, cooled and demolded.

Landscapes

  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Emergency Medicine (AREA)
  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Cosmetics (AREA)

Abstract

Préparation cosmétique sous forme de crayon contenant a) une combinaison d'une ou plusieurs cires naturelles, d'une ou plusieurs cires microcristallines, d'une ou plusieurs cires synthétiques, la quantité totale de toutes les cires dans la préparation correspondant à 9 à 15 % en poids par rapport au poids total de la préparation, b) plusieurs huiles, c) un ou plusieurs lipides avec un point de fusion de 30 à 40 °C dans une quantité totale de 5 à 15 % en poids par rapport au poids total de la préparation.
EP07787112A 2006-07-17 2007-07-05 Crayon cosmétique Ceased EP2043596A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE200610034026 DE102006034026A1 (de) 2006-07-17 2006-07-17 Kosmetischer Stift
PCT/EP2007/056822 WO2008009562A1 (fr) 2006-07-17 2007-07-05 Crayon cosmétique

Publications (1)

Publication Number Publication Date
EP2043596A1 true EP2043596A1 (fr) 2009-04-08

Family

ID=38582124

Family Applications (1)

Application Number Title Priority Date Filing Date
EP07787112A Ceased EP2043596A1 (fr) 2006-07-17 2007-07-05 Crayon cosmétique

Country Status (3)

Country Link
EP (1) EP2043596A1 (fr)
DE (1) DE102006034026A1 (fr)
WO (1) WO2008009562A1 (fr)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102011086439B4 (de) 2011-11-16 2021-03-25 Beiersdorf Ag Stabile kosmetische Zubereitung
PT3142641T (pt) 2014-05-13 2021-03-02 Dendropharm Gmbh Formulações para o tratamento de hipertiroidismo
DE102017201947A1 (de) * 2017-02-08 2018-08-09 Beiersdorf Ag Kosmetischer Sonnenschutzstift

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1243248A2 (fr) * 2001-03-21 2002-09-25 Shiseido Company Limited Produit cosmétique solide

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5108737A (en) * 1991-06-28 1992-04-28 Elizabeth Arden Co., Division Of Conopco, Inc. Colored cosmetic sticks
US5667770A (en) * 1996-03-25 1997-09-16 Elizabeth Arden Company, Division Of Conopco, Inc. Long wearing lipstick
US6937976B2 (en) * 2001-07-09 2005-08-30 Hewlett-Packard Development Company, L.P. Method and system for temporary network identity
DE10161170A1 (de) * 2001-12-13 2003-06-18 Beiersdorf Ag Lippenstift
DE10226353A1 (de) * 2002-06-13 2003-12-24 Beiersdorf Ag Kosmetische und dermatologische Lichtschutzzubereitungen enthaltend eine synergistische Kombination aus UV-Absorbern, anorganischen Pigmenten und organischen Farbstoffen
WO2004108108A1 (fr) * 2003-06-04 2004-12-16 Schwan-Stabilo Cosmetics Gmbh & Co. Kg Preparation cosmetique contenant un colorant non soluble produisant des effets de fluorescence
DE20309463U1 (de) * 2003-06-20 2003-09-04 Schwan Stabilo Cosmetics Gmbh Zubereitung, insbesondere Kosmetikzubereitung

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1243248A2 (fr) * 2001-03-21 2002-09-25 Shiseido Company Limited Produit cosmétique solide

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of WO2008009562A1 *

Also Published As

Publication number Publication date
WO2008009562A1 (fr) 2008-01-24
DE102006034026A1 (de) 2008-01-24

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