WO2004108108A1 - Preparation cosmetique contenant un colorant non soluble produisant des effets de fluorescence - Google Patents

Preparation cosmetique contenant un colorant non soluble produisant des effets de fluorescence Download PDF

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Publication number
WO2004108108A1
WO2004108108A1 PCT/EP2004/006055 EP2004006055W WO2004108108A1 WO 2004108108 A1 WO2004108108 A1 WO 2004108108A1 EP 2004006055 W EP2004006055 W EP 2004006055W WO 2004108108 A1 WO2004108108 A1 WO 2004108108A1
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WO
WIPO (PCT)
Prior art keywords
preparation according
oil
preparation
powder
mixtures
Prior art date
Application number
PCT/EP2004/006055
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German (de)
English (en)
Inventor
Klaus-Dieter SCHRÖDER
Werner Brüchert
Willy Weiss
Original Assignee
Schwan-Stabilo Cosmetics Gmbh & Co. Kg
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Filing date
Publication date
Priority claimed from DE20308712U external-priority patent/DE20308712U1/de
Priority claimed from DE20308748U external-priority patent/DE20308748U1/de
Priority claimed from DE20309463U external-priority patent/DE20309463U1/de
Application filed by Schwan-Stabilo Cosmetics Gmbh & Co. Kg filed Critical Schwan-Stabilo Cosmetics Gmbh & Co. Kg
Publication of WO2004108108A1 publication Critical patent/WO2004108108A1/fr

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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/12—Face or body powders for grooming, adorning or absorbing
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • A61K8/466—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfonic acid derivatives; Salts
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
    • A61K8/4906—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom
    • A61K8/4926—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom having six membered rings
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
    • A61K8/4973—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with oxygen as the only hetero atom
    • A61K8/498—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with oxygen as the only hetero atom having 6-membered rings or their condensed derivatives, e.g. coumarin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/85—Polyesters
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/88—Polyamides
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • A61K8/927—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of insects, e.g. shellac
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02—Preparations containing skin colorants, e.g. pigments
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02—Preparations containing skin colorants, e.g. pigments
    • A61Q1/04—Preparations containing skin colorants, e.g. pigments for lips
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02—Preparations containing skin colorants, e.g. pigments
    • A61Q1/04—Preparations containing skin colorants, e.g. pigments for lips
    • A61Q1/06—Lipsticks
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02—Preparations containing skin colorants, e.g. pigments
    • A61Q1/10—Preparations containing skin colorants, e.g. pigments for eyes, e.g. eyeliner, mascara
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/10—Preparations for permanently dyeing the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/42—Colour properties
    • A61K2800/43—Pigments; Dyes
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/42—Colour properties
    • A61K2800/43—Pigments; Dyes
    • A61K2800/434—Luminescent, Fluorescent; Optical brighteners; Photosensitizers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/57—Compounds covalently linked to a(n inert) carrier molecule, e.g. conjugates, pro-fragrances
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
    • A61K2800/87—Application Devices; Containers; Packaging
    • A61K2800/872—Pencils; Crayons; Felt-tip pens

Definitions

  • the invention relates to a preparation, in particular cosmetic preparation for decorative cosmetics for coloring and beautifying the skin, lips, eyelids, hair, eyelashes and eyebrows.
  • Preparations in particular cosmetic preparations, come in various forms.
  • the form of loose or pressed powder or cast powder in the form of a stick or in the form of extruded leads, which can be produced from an extrudable mass and have been dried by dehydration, are well suited for the field of decorative cosmetics.
  • Examples of products to be considered according to the invention include: make-up, in particular the so-called party effect make-up, theater make-up, contour pencils, for example lip liner and eyeliner, lip coloring agents such as lip powder, cheek blush, eye shadow, mascara, Hair masks, eyelash coloring agents, semi-permanent tattoos and the like.
  • Preparations for coloring and beautifying skin and hair can also be produced from anhydrous lipid compositions which contain at least one oil which is liquid at room temperature, at least one wax and at least one powdery phase, the powdery phase consisting of at least one pigment which is insoluble in the preparation mentioned.
  • Preparations for coloring and beautifying skin and hair can also be produced from smooth pastes based on suitable fats, waxes and oils or in the form of W / O or O / W emulsions.
  • Coloring agents are generally used to color the above-mentioned preparations, which are neither soluble in polar nor in non-polar solvents and therefore remain at the place of application and also do not bleed out.
  • a sufficient number of recipe examples can be found in the standard cosmetic works, e.g. by K. Rothemann, "The Great Recipe Book for Skin and Personal Care Products", 1st ed. 1949, GA Nowak, "The Cosmetic Preparations", 3rd ed., 1984 or H.
  • Titanium dioxide alone or optical brighteners such as disodium distyryldiphenyl disulfonate or the like , essentially only result in light blue fluorescent colors and therefore only little variation in the range from yellow to red fluorescent colors - an overall unsatisfactory condition.
  • preparations such as make-up, e.g. the so-called party effect make-up, theater make-up, contour pencils, e.g. Lip liner and eyeliner, lip dye, lip powder, cheek blush, eyeshadow, mascara, hair mascara, eyelash dye, semi-permanent tattoos and the like are colored by colorants that are insoluble in the preparation so that they provide unusual and interesting effects, e.g. under UV light, so-called black light, intense and interesting colors and fluorescence on the applied areas, e.g.
  • Another object is to provide preparations which, under normal light conditions, in particular in daylight, using the colorants, if appropriate in addition to the aforementioned colorants, impart more intense color impressions by the fact that colorants which can be excited by means of UV light to fluoresce through daylight are caused by UV light -Share be stimulated to emit fluorescent light.
  • colorants which are suitable not only for lipid-containing preparations but also for gel-like and emulsion-like preparations, but also for powdered preparations and those in anhydrous form.
  • a preparation in particular a cosmetic preparation for the field of decorative cosmetics for coloring and beautifying the skin, lips, eyelids, hair, eyelashes and eyebrows, which is characterized in that it contains at least one colorant contains, which is insoluble in polar and non-polar solvents and gives fluorescence effects under UV light.
  • a preparation is thus made available with which cosmetics can be colored without being limited to special dyes.
  • insoluble or insolubilized coloring agents as coloring agents for the above-mentioned preparations, which, by way of salt formation, by the formation of a neutral salt - or by way of a real covalent bond - from a matrix of a polymer material with at least one functional group in the side chain and a soluble dye having at least one functional group.
  • reaction products of polymers with at least one functional group and a dye with at least one group which is reactive with the functional group of the polymer are thus used as colorants. This makes it possible to provide dyes that cannot otherwise be used for cosmetics, for cosmetic products with special effects.
  • either coloring agents can be used, for example by reacting polyesters which are also insoluble in the preparation and which contain at least one primary, secondary or tertiary amino group in the side chain, with anionic dyes or polyesters which contain at least one acid residue the side chain included, are made with cationic dyes. It is also conceivable to react polyacrylates or polymethacrylates or polyurethanes which have at least one of the abovementioned amino groups or at least one acid group in the side chain with dyes with oppositely charged functional groups.
  • the colorants to be selected are stable to hydrolysis under in vivo conditions, which can be done by a simple test - namely by storing the colorant in a 1% aqueous solution of an organic hydroxy acid, such as lactic acid or citric acid, buffered to pH 5.5 over 24 hours at 37 ° C - easy to determine.
  • an organic hydroxy acid such as lactic acid or citric acid
  • Commercially available are, for example, colorants which consist of a polyester matrix obtained by the reaction of ethylene glycol, cyclohexanedimethanol, terephthalic acid, isophthalic acid and norbornanediamine and dyes which are derived from fluoresceins, quinoline dyes, triphenylmethane dyes and anthraquinone dyes.
  • polyester-3 A suitable polyester matrix is also known to the person skilled in the relevant art as “polyester-3”. Dyes such as Cl-No are mentioned here. 45,380 (tetrabromofluorescein), Cl-No. 45.370: 1 (mixture of dibromo, tribromo and tetrabromofluorescein), Cl-No. 47,000 (quinophthalone, not for use on mucous membranes), Cl-No. 47.005 (quinophthalone disulfonic acid), Cl-No. 42,090 (triphenylmethane dye), Cl-No. 60.730 (anthraquinone dye, not for use on mucous membranes), Cl-No. 61,570 (anthraquinone dye).
  • pigments are titanium dioxide, zinc oxide, iron oxides, chromium oxide, chromium oxide hydrate, ultramarine, manganese violet, ferric blue, micaceous mica, mica coated with titanium dioxide, colored mica coated with metal oxides, bismuth oxychloride, bismuth oxychloride coated with metal oxides, platelet-shaped metal powder from Aluminum, brass, bronze, copper, silver or gold, carmine and its various salts with metals, as well as varnishing of organic colorants with aluminum, barium, calcium, strontium or zirconium. This list is only exemplary and not exhaustive. The quantities used depend on the desired effects and are limited by the maximum quantities regulated in the respective national legislation.
  • the proportions of colorant are usually in a range from 0.1 to 50% by weight, preferably in a range from 5 to 35% by weight and particularly preferably in a range from 10 to 25% by weight. These quantities for the colorants are provided with the proviso that the sum of all the ingredients of the aforementioned preparation, in particular cosmetic preparation, is added to 100% by weight.
  • the average particle size of the aforementioned colorants varies depending on the area of application and is generally in a size range from 0.1 to 10 ⁇ m, in particular 0.5 to 10 ⁇ m, in the case of the plate-shaped colorants, such as the mica, the bismuth oxychlorides and the metal powders, the average particle size can also be are in a range from 5 to 150 ⁇ m.
  • non-coloring pigments and other fillers, such as silicon dioxide, talc, kaolin, metal salts of fatty acids, such as Al, Mg, Ca, Zn or Sr stearate, palmitate or myristate, Boron nitride, starch, organically modified starch, nylon powder, polytetrafluoroethylene powder or mixtures thereof.
  • the preparations can also be customary and of the respective Approved antioxidants and preservatives can be added to cosmetics legislation.
  • the preparation according to the invention contains the ingredients customarily used for such preparations.
  • the colorants provided according to the invention can be used for a wide variety of preparations which can be prepared in a manner known per se.
  • powder-like preparations are produced by homogeneously mixing their finely pulverized constituents and, if necessary, grinding them again and filling them loosely into suitable sales containers or using an oil binder or an emulsion binder to bring them into a form suitable for compacting and the resulting mixture under pressure into small sheet metal parts, so-called godets.
  • godets so-called godets.
  • godets so-called godets.
  • gypsum to the base, to soak it with water and then to extrude it into mines or to pour it into suitable sales containers and let it harden.
  • an aqueous solution of a cellulose derivative such as e.g.
  • Carboxymethyl cellulose or ethyl cellulose can be used, the product obtained then being subjected to a drying process.
  • a drying process it is also known to mix the powder with a volatile silicone oil, e.g. a cyclomethicone, and pour it into suitable moldings, then dry the filled moldings at elevated temperature and then recover the evaporating solvent from a cooled water bath as a cold trap.
  • a volatile silicone oil e.g. a cyclomethicone
  • oils which are approved for the manufacture of cosmetics and which are customary in cosmetics and are volatile and / or non-volatile at room temperature, of vegetable, mineral or synthetic origin - organosilicon compounds such as dimethicone are mentioned here , Phenyltrimethicones, diphenyldimethicones or volatile oils, such as, for example, volatile short-chain dimethicones such as hexamethyldisiloxane, cyclomethicones such as hexamethyltricyclosiloxane, octamethyltetracyclosiloxane, decamethylpentacyclosiloxane, dodedamethylhexa-cyclosaffarine mixture, such as 12-cyclosaffarine mixture, such as in-parosaffarine mixture / cyclosaffarine mixture, such as in-parosaffarine mixture, such as in-parosafarine mixture / cycl
  • Mineral oil and paraffin oil as well as vegetable oils such as sesame oil, castor oil, may also be mentioned.
  • Sunflower oil peanut oil, rapeseed oil, mango seed oil (Magnifera Indica), Meadowfoam Seed Oil (Limnantes Alba), Macadamia Nut Oil (Macadamia Ternifolia Nut Oil), octyldodecanol, isopropyl myristate, isopropyl palmitate, Butyl stearate, isopropyl isostearate, isostearyl isostearate, Caprylic / Capric Triglyceride, Propylene Glycol Dicaprylate / Dicaprate and others.
  • Vegetable, animal or synthetic waxes may also be mentioned, e.g. Beeswax, Japanese wax (Rhus Succedanea), camauba wax, candelilla wax, sugar cane wax, jojoba oil (Buxus Chinensis) or hydrogenated jojoba oil, silicone waxes.
  • Paraffin waxes, montan waxes, microcrystalline waxes or waxes obtained from the Fischer-Tropsch synthesis or petroleum jelly or mixtures of the waxes mentioned can be used.
  • the preparation may also contain triglycerides, in particular triglycerides which are solid at room temperature, which have been obtained by hydrogenating vegetable oils, such as e.g. hydrogenated vegetable oils such as Hydrogenated Cottonseed Oil, Hydrogenated Vegetable Oil, Hydrogenated Rapeseed Oil, Hydrogenated Castor Oil, Hydrogenated Coco Glycerides or Mango Seed Oil (Magnifera Indica), Meadowfoam Seed Oil (Limnantes Alba), Shea Butter (Butyrospermum Parkii), Macadamia Nut Oil (Macadamia Temifolia Nut Oil) or their mixtures.
  • hydrogenated vegetable oils such as Hydrogenated Cottonseed Oil, Hydrogenated Vegetable Oil, Hydrogenated Rapeseed Oil, Hydrogenated Castor Oil, Hydrogenated Coco Glycerides or Mango Seed Oil (Magnifera Indica), Meadowfoam Seed Oil (Limnantes Alba), Shea Butter (Butyrospermum Parkii), Macadamia Nut Oil
  • the preparations according to the invention can also be in the form of water-based suspensions with solids without any addition of lipids or in the form of suspensions which additionally contain finely dispersed lipid bodies or in the form of colored emulsions.
  • Emulsions can be produced using oils, fats and waxes known and approved for the production of cosmetics, such as dimethicone, phenyltrimethicone, diphenyldimethicone, silicone wax or volatile cyclomethicone and the like.
  • Animal or vegetable waxes may also be mentioned, such as, for example, beeswax, Japanese wax (Rhus succedanea), camamauba wax, candelilla wax, sugar cane wax, jojoba oil (Buxus Chinensis) or hydrogenated jojoba oil, hydrogenated vegetable oils such as Hydrogenated Cottonseed Oil, Hydrogenated Vegetable Oil, Hydrogenated Rapeseed Oil, Hydrogenated Castor Oil, Hydrogenated Coco Glycerides or Mango Seed Oil (Magnifera Indica), Meadowfoam Seed Oil (Limnantes Alba), Shea Butter (Butyrospermum Parkii), Macadamia Nut Oil (Macadamia Ternifolia Nut Oil) or mixtures thereof.
  • Raw materials derived from petroleum such as volatile isoparaffins, mineral oil, petroleum jelly, paraffin waxes, montan waxes, microcrystalline waxes or waxes obtained from the Fischer-Tropsch synthesis can also be used.
  • the preparation can contain water as well as humectants, e.g. Glycerin, diglycerin, triglycerin, propylene glycol, butylene glycols, hexylene glycols, lactic acid or its salts, pyrrolidone carboxylic acid or its salts or mixtures of the substances mentioned and caring additives of medicinal plant extracts, which are available in sufficient numbers commercially.
  • humectants e.g. Glycerin, diglycerin, triglycerin, propylene glycol, butylene glycols, hexylene glycols, lactic acid or its salts, pyrrolidone carboxylic acid or its salts or mixtures of the substances mentioned and caring additives of medicinal plant extracts, which are available in sufficient numbers commercially.
  • humectants e.g. Glycerin, diglycerin, triglycerin, propylene glycol, butylene glycols, hexy
  • the preparations can also contain vegetable, animal or synthetic thickeners, such as gum tragacanth, xanthan gum, carrageenan, locust bean gum, agar agar, alginates, pectin, gelatin, starch derivatives and modified starches, cellulose derivatives such as carboxymethyl cellulose, methylhydroxyethyl cellulose, methyl hydroxypropyl cellulose, methyl hydroxypropyl cellulose Carboxymethylhydroxyethylcellulose and the like or synthetic thickeners such as acrylate polymers and acrylate copolymers, which are known to the person skilled in the art under the INCI name Carbomer, and also mixtures of the substances mentioned.
  • vegetable, animal or synthetic thickeners such as gum tragacanth, xanthan gum, carrageenan, locust bean gum, agar agar, alginates, pectin, gelatin, starch derivatives and modified starches, cellulose derivatives such as carboxymethyl cellulose, methylhydroxyeth
  • Preparations for coloring and beautifying skin and hair can also be prepared from anhydrous lipid compositions which contain at least one oil which is liquid at room temperature, at least one wax and at least one powdery phase, the powdery phase comprising at least one pigment which is insoluble in the preparation mentioned, for Achievement of special fluorescence effects an insoluble fluorescent pigment.
  • preparations are usually prepared by bringing the wax and oil to a temperature above the melting point of the wax, adding the powdery phase and mixing the whole thing, and then using a colloid mill, corundum disc mill or a three-roll mill to process them sufficiently to destroy agglomerates and to homogenize them ,
  • the preparation is then extruded and cut into mines, which can be processed into pencils with a sharpenable coating using the methods known from pencil production.
  • the leads can also be inserted into suitable rotating mechanisms.
  • suitable methods for further processing consist in heating the preparation above its melting point and pouring it in liquid form directly into sleeves made of a sharpenable material such as wood or plastic.
  • preparations for decorative cosmetics are water-free pastes based on suitable fats, waxes and oils or in the form of W / O or O / W emulsions.
  • preparations in the form of a liquid, a gel or an emulagor-free “Pickering emulsion” are also known for cosmetic applications. Soluble dyes are often used for liquid formulations.
  • Preparations according to the invention which are in the form of soft pastes, preferably have a dynamic viscosity in the range from 50 to 3000 mPa.s, the dynamic viscosity using a Bohlin CVOR 200 rotary viscometer at shear rates of 10 "4 / s to 10 3 / s below Using a plate cone or plate / plate measuring device. The measurements take place with increasing and falling shear again.
  • the preparations according to the invention in the form of pastes generally have a viscosity profile in the form of a hysteresis curve, which indicates thixotropic properties of the preparations.
  • the "white" powder components are mixed with cooling and then the preservatives and the perfume oil are added. Then the iron oxide and the fluorescent colors are added and the mixture is mixed intensively. The mixture is then ground using a ring gear mill or using a vibrating sieve the loose powder is preferably applied to the skin with a tassel receives a light, reddish-brown, very grippy powder with good adhesion to the skin that shows orange to magenta fluorescence in long-wave UV light. By varying the amounts of red iron oxide and titanium dioxide, a lighter or darker shade of the powder can be achieved.
  • D&C Red 7 (C.l.-No. 15,850: 1) 3,300 red iron oxide (C.l.-No. 77,491) 3,500 yellow iron oxide (C.I.- -No. 77,492) 1,500
  • Example 3 Effect Makeup (Cast)
  • Gum arabic is poured over the ethanol in a suitable container.
  • the water is heated to 80 ° C and poured onto the gum arabic, after which it is allowed to swell.
  • Dowicil 200, the carboxymethyl cellulose and the carrageenan are then added with stirring. Allow to swell, stir the mixture free of kiumpen and then add the binder to the powder mixture and process everything into a thick paste. Possibly. a little water can be added.
  • the mixture is poured into suitable, rustproof sheet metal parts, shaken if necessary and dried to constant weight at 50-60 ° C.
  • Polyester-3 Yellow 10,000 Polyester-3, Blue 1 2,000
  • the oil binder is made by heating the oil phase slightly and dissolving the preservatives in it. It can be used immediately and is also storable.
  • the powder components are placed down to the mica and mixed intensively with cooling. About 60% by weight of the oil binder is then sprayed in or added in portions. Then the mica is added and then the remaining oil binder in portions.
  • the batch is sieved using a vibrating sieve and then compacted into small metal parts (Godets) using a suitable press. A pearlescent, blue-green compact powder with good adhesion is obtained, which shows a bright, yellowish fluorescence under long-wave UV light.
  • Guar gum and PVP are dissolved in about 10-15 parts of water while heating.
  • a mixing plant e.g. a suitable kneader
  • the powder components are mixed well - first without adding the mica - then the mica is added.
  • the aqueous solution of the binders is added and the mixture is kneaded until a homogeneous, very pasty mass has formed.
  • This is shaped by means of an extruder into leads of, for example, 8 mm or 10 mm in diameter, which are cut to length and preferably dried at a somewhat elevated temperature.
  • the leads can be made of a sharpenable material - e.g. Plastic wrappings or in a known manner from pencil production in wood - are introduced.
  • the leads can also be encased in a hose made of a thermoplastic, shrinkable material in a known manner before further processing. But they can also be used in a turning mechanism.
  • the example above results in a lead that gives a light blue, pearlescent line that glows light blue in long-wave UV light.
  • Polyester-3 Red 22 6,000
  • Example 5 The production is carried out analogously to Example 5.
  • the finished mass is extruded into mines with a thickness of approximately 4 mm, which are then further processed in the manner described.
  • a lead with a strong red streak is obtained, which shows a strong yellowish-magenta fluorescence in the long-wave UV light.
  • the preparation is carried out analogously to Examples 5 and 6 above.
  • the mass is extruded into leads with a diameter of approximately 4 mm.
  • the preparation is expediently prepared in small portions so that it can be extruded within a few minutes.
  • the mines are dried at a somewhat elevated temperature and processed further in the manner previously described.
  • a lead is obtained with a strong dark blue streak which fluoresces blue under long-wave UV light. With this preparation, too, further shades of color can easily be produced by simply varying the pigment mixture.
  • Polyester-3 Red 28 20,000
  • the waxes are melted in a vacuum stirred kettle at about 70 ° C., then the nylon powder and the pigment are added and incorporated homogeneously with stirring. Then the preservatives and the antioxidant are added. The kettle is now vented a little and about half the amount of isoparaffin is sucked in. If the mixture shows a homogeneous structure, the rest of the isoparaffin is sucked in and the mixture is homogenized.
  • One omits Cool with moderate stirring using the anchor stirrer to about 35 ° C, deaerate by applying a vacuum (water jet pump), cool down to room temperature and discharge the mass into the storage container.
  • An intensely margarine-colored mascara mass is obtained which shows an intense red-violet fluorescence under long-wave UV light. It has a viscosity of around 18-20 Pas.
  • the mass is ideally suited to be applied to the eyelash tips using a "conventional" mascara.
  • the pigments used can be replaced by other luminescent pigments in variations:
  • a green hair-effect mask is obtained which shows a clear yellow-green fluorescence under long-wave UV light.
  • a medium-blue hair effect mascara is obtained which shows a very clear light-blue fluorescence under long-wave UV light.
  • Polyester-3 Yellow 10 4,500
  • Polyester-3 Red 22 0.750
  • the fat components - except Cyclomethicone D-5 - are melted in a suitable vacuum stirred kettle, then the pigments - apart from the coated mica - are added and the liquid mass is homogenized. After that, the preservatives and the antioxidant are added and it gets short stirred. Then the coated mica and cyclomethicone D-5 are added, the mixture is briefly homogenized again and the mixture is slowly stirred cold. A light, blue-green pearlescent paste is obtained which shows an orange-colored fluorescence under long-wave UV light. The viscosity is 18 Pas.
  • Example 12 The preparation is carried out analogously to Example 12. A red paste with a viscosity of 25 Pas is obtained which shows a red-violet fluorescence under long-wave UV light.
  • the aforementioned emulsion-based products can be easily removed by washing the hair with a shampoo.
  • the mascara preparations can be easily removed from the eyelashes again using a make-up remover.
  • the theatrical make-up can be removed well using a make-up remover based on low-viscosity paraffin oil, petroleum jelly and a proportion of a non-ionic emulsifier, eg cetylstearyl ethoxylate, and washed off without residue by washing with a mild fine soap or washing lotion.
  • a non-ionic emulsifier eg cetylstearyl ethoxylate
  • the water heated to 75 ° C., is placed in a vacuum stirred kettle, in which the xanthan gum and the acrylate polymer are dissolved. Then the magnesium aluminum silicate is added and the mixture is thoroughly mixed using a toothed lock washer (the boiler must be closed).
  • Propylene glycol is placed in a separate vessel and heated to about 55 ° C. Methyl paraben, propyl paraben and tocopherol acetate are dissolved therein. Thereafter, oleyl alcohol, isostearic acid and oleyl alcohol are dissolved in it. This mixture is then added while stirring the amount of water in the kettle, after which the batch is thoroughly mixed again with the toothed lock washer.
  • the colorant is added to the mixture and worked in well using a toothed lock washer. This mixture is then deaerated by applying a vacuum, cooled and filled into storage containers. An intensely magenta lipliner with a dynamic viscosity of 500 to 700 mPas is obtained, which shows an intense red-violet fluorescence under long-wave UV light.
  • the water, heated to 75 ° C., is placed in a vacuum stirred kettle, and the acrylate copolymer is added and incorporated using a toothed lock washer. Then carrageenan, cellulose and hectorite are added and incorporated using a toothed lock washer (with the boiler closed).
  • the fat components are melted in a separate vessel at about 75 ° C and mixed with the sodium lauroyl sarcosinate.
  • the mixture is then added to the water phase and processed into an emulsion using a toothed lock washer (with the boiler closed).
  • Diglycerin and phenoxyethanol submitted and dissolved methylparaben, propylparaben and tocopherol acetates with gentle warming.
  • the mixture in the kettle is cooled to about 45 ° C, then the preservation mixture is added.
  • the pigments are then sprinkled in and worked in using a toothed lock washer (with the boiler closed) with intensive stirring.
  • the fragrance is then added, the mixture is cooled to room temperature and discharged into a storage container.
  • a dark, almost black preparation with a dynamic viscosity of about 1,000 to 1,200 mPas is obtained, which shows a yellow-red fluorescence in long-wave UV light. It is particularly suitable for painting water-resistant but washable patterns on the skin.
  • the mixture in the kettle is cooled to about 40 ° C, then the last mixture is added, and the whole is briefly mixed again using a toothed disk. It is then vented by applying a vacuum and the mixture is filled into suitable storage containers at room temperature. A red lip color is obtained which shows a strong yellowish-magenta fluorescence in the long-wave UV light.
  • the mixture has a dynamic viscosity of 300-400 mPas.
  • luminous colors such as e.g. Polyester-3, Blue 1 or Polyester-3, Yellow 10, or Polyester-3, Yellow 11 or mixtures thereof, if necessary also using suitable optical brighteners, e.g. Produce disodium distyryldiphenyl disulfonate effective body paintings that show little tendency to migrate on the skin and that show very attractive fluorescence under long-wave UV light.
  • suitable optical brighteners e.g. Produce disodium distyryldiphenyl disulfonate effective body paintings that show little tendency to migrate on the skin and that show very attractive fluorescence under long-wave UV light.
  • These mixtures are also suitable for application to the hair.
  • the application can be carried out by means of suitable brushes or suitable foam applicators, which are customary in the trade.
  • Polyester-3 Red 28 20,000
  • Polyester-3 Yellow 10 8,500
  • the mixture is placed on a three-roll mill and passed twice.
  • the mixture is then pressed and extruded into a strand with a diameter of approximately 8-10 mm and cut to length.
  • the mines obtained are glued into wooden boards in a known manner and processed into sharpenable pencils. An intensely red lipstick with bright red fluorescence in long-wave UV light is obtained.
  • UV light gives a light blue fluorescent smear.
  • Polyester-3 Yellow 10 12,000
  • the lipid components are heated and melted to 80 ° C. in a suitable vacuum kettle with a stirrer and gear ring mixer, then the powder components are added and the mixture is homogenized. Finally the preservatives and the antioxidant are added.
  • the preparation can now be poured directly into sleeves made of a sharpenable material and processed into effect lip liners with a lead with a diameter of approximately 4 mm. Alternatively, as already described above, the preparation can also be poured directly into the holding part of a suitable rotating mechanism. A pen with an intensely red lead is obtained, the smear of which shows a bright red fluorescence in the long-wave UV light.
  • Example 20 Effect eyeshadow pencil, cast
  • Titanated Mica 25,000
  • Polyester-3 Yellow 10 4,500 Disodium Distyryldiphenyl Disulfonate 0.200
  • the lipid components are heated and melted to 80 ° C. in a suitable stirred tank with a stirrer and gear mixer, then the powder components are added and the mixture is homogenized, after which the preservatives and the antioxidant are added. The mixture is then deaerated by applying a vacuum, then the volatile oils are added and the mixture is thoroughly mixed again.
  • the preparation is then poured into sleeves made of a sharpenable material with an inner diameter of approximately 8-10 mm using a suitable system processed into eyeshadow pencils. Alternatively, the preparation can of course also be poured into flat pans that have to be inserted in airtight cassettes. A blue-green effect eyeshadow is obtained which shows a bright, blue-green fluorescence under long-wave UV light.
  • Example 21 Effect Body Painting, Cast (Body Painting Pen)
  • Polyester-3 Red 22 13,500
  • Polyester-3 Yellow 10 12,500
  • the preparation is carried out in a known manner by melting the lipid components at about 80 ° C. in a suitable vacuum stirred tank with a stirrer and gear rim mixer and then adding and homogenizing the powder components with the exception of the coated mica.
  • the preservatives, the antioxidant and the coated mica are then added, the batch mixed thoroughly with the stirrer alone and vented by applying a vacuum.
  • the preparation is not poured into sleeves made of a sharpenable material, which is also possible in principle, but in rotating mechanisms with a rotating spindle, as are known in principle from deodorant sticks. A bright orange lead is obtained, which fluoresces intensely red-orange in the long-wave UV light.
  • Polyester-3 Blue 1 19,500
  • the preparation is carried out in the manner described above, essentially analogously to Example 21.
  • the preparation is not poured into sleeves made of a sharpenable material, which is also possible in principle, but in rotating mechanisms with a rotating spindle, as are known in principle from deodorant sticks , A medium blue lead is obtained, which fluoresces intensely light blue in the long-wave UV light.

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  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
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  • Insects & Arthropods (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
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  • Cosmetics (AREA)

Abstract

L'invention concerne une préparation, en particulier une préparation cosmétique, destinée à être utilisée dans le domaine de la cosmétique décorative pour colorer et embellir la peau, les lèvres, les cils et les sourcils. Cette préparation contient au moins un colorant qui est non soluble dans la préparation et produit, en présence d'une lumière ultraviolette, des effets de fluorescence.
PCT/EP2004/006055 2003-06-04 2004-06-04 Preparation cosmetique contenant un colorant non soluble produisant des effets de fluorescence WO2004108108A1 (fr)

Applications Claiming Priority (8)

Application Number Priority Date Filing Date Title
DE20308712U DE20308712U1 (de) 2003-06-04 2003-06-04 Zubereitung, insbesondere Kosmetikzubereitung
DE20308712.7 2003-06-04
DE20308748.8 2003-06-05
DE20308748U DE20308748U1 (de) 2003-06-05 2003-06-05 Zubereitung, insbesondere Kosmetikzubereitung
DE20309463.8 2003-06-20
DE20309463U DE20309463U1 (de) 2003-06-20 2003-06-20 Zubereitung, insbesondere Kosmetikzubereitung
DE20314464.3 2003-09-18
DE20314464U DE20314464U1 (de) 2003-06-04 2003-09-18 Zubereitung, insbesondere Kosmetikzubereitung

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WO2004108108A1 true WO2004108108A1 (fr) 2004-12-16

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Cited By (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005107684A1 (fr) * 2004-04-30 2005-11-17 The Procter & Gamble Company Compositions cosmetiques longue duree a brillance amelioree
WO2006082102A2 (fr) * 2005-02-04 2006-08-10 Schwan-Stabilo Cosmetics Gmbh & Co. Kg Preparation, notamment preparation cosmetique, production et utilisation de ladite preparation
FR2885520A1 (fr) * 2005-05-10 2006-11-17 Oreal Composition cosmetique
WO2007007287A2 (fr) * 2005-07-13 2007-01-18 L'oreal Procede de maquillage et/ou de soin cosmetique
WO2007007290A1 (fr) * 2005-07-13 2007-01-18 L'oreal Maquillage et/ou procede de soins
WO2007007296A1 (fr) * 2005-07-13 2007-01-18 L'oreal Traitement cosmetique de maquillage et/ou de soins
WO2007007289A2 (fr) * 2005-07-13 2007-01-18 L'oreal Composition cosmetique a effets de couleurs et/ou optiques
FR2888500A1 (fr) * 2005-07-13 2007-01-19 Oreal Procede de maquillage et/ou de soin cosmetique
WO2007031139A1 (fr) 2005-07-14 2007-03-22 Schwan-Stabilo Cosmetics Gmbh & Co. Kg Préparation, en particulier préparation cosmétique, procédé de production de ladite préparation et applications
WO2007048472A1 (fr) * 2005-10-28 2007-05-03 Henkel Kommanditgesellschaft Auf Aktien Procede de traitement des cheveux caracterise par une efficacite de soin amelioree et produit pour mettre en oeuvre ce procede
WO2008009562A1 (fr) * 2006-07-17 2008-01-24 Beiersdorf Ag Crayon cosmétique
WO2008056688A1 (fr) * 2006-11-08 2008-05-15 Shiseido Company Ltd. Colorant pour préparation cosmétique et cosmétique de maquillage
DE102007005645A1 (de) 2007-01-31 2008-08-07 Henkel Ag & Co. Kgaa Mit Polymerpartikeln beschichtete Lichteffektpigmente
DE102007005646A1 (de) 2007-01-31 2008-08-07 Henkel Ag & Co. Kgaa Färbemittel, enthaltend durch sichtbares Licht anregbare Lumineszenzpigmente
DE102007039335A1 (de) 2007-08-20 2009-02-26 Henkel Ag & Co. Kgaa Lumineszierende Kompositmaterialien
FR2968971A1 (fr) * 2010-12-20 2012-06-22 Oreal Composition comprenant un colorant naturel, un silicate insoluble, un compose aromatique et un solvant aliphatique hydroxyle
JP5801503B1 (ja) * 2015-01-21 2015-10-28 株式会社 資生堂 メーキャップ化粧料
US10272026B2 (en) 2017-07-31 2019-04-30 L'oreal Water-in-oil emulsion compositions suitable for altering the color of hair
WO2019141959A1 (fr) * 2018-01-19 2019-07-25 Perachem Limited Procédé et composition pour colorer un sourcil comprenant un acide organique
CN113476381A (zh) * 2021-07-13 2021-10-08 杭州毛戈平科技有限公司 一种持久滋润口红及其制备工艺

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GB820111A (en) * 1955-03-23 1959-09-16 Thomas Kerfoot & Co Ltd Improvements in lipstick and nail varnish or polish
US4657363A (en) * 1985-08-26 1987-04-14 Neefe Charles W Fluorescent corneal color change device
EP0370470A2 (fr) * 1988-11-23 1990-05-30 Estee Lauder Inc. Compositions cosmétiques fluorescentes
JPH05117127A (ja) * 1991-10-02 1993-05-14 Shiseido Co Ltd 蛍光化粧料
US5336307A (en) * 1992-05-19 1994-08-09 Schwan-Stabilo Schwanhaeusser Gmbh & Co. Marker pencil
US6169185B1 (en) * 1999-02-25 2001-01-02 Day-Glo Color Corp. Ink jet printing inks
EP1099437A1 (fr) * 1999-11-12 2001-05-16 L'oreal Composition comprenant une substance fluorescente et une charge particuliere, utilisations
WO2002061003A1 (fr) * 2001-01-30 2002-08-08 Schwan-Stabilo Schwanhäusser Gmbh & Co. Liquide de marquage

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Publication number Priority date Publication date Assignee Title
GB820111A (en) * 1955-03-23 1959-09-16 Thomas Kerfoot & Co Ltd Improvements in lipstick and nail varnish or polish
US4657363A (en) * 1985-08-26 1987-04-14 Neefe Charles W Fluorescent corneal color change device
EP0370470A2 (fr) * 1988-11-23 1990-05-30 Estee Lauder Inc. Compositions cosmétiques fluorescentes
JPH05117127A (ja) * 1991-10-02 1993-05-14 Shiseido Co Ltd 蛍光化粧料
US5336307A (en) * 1992-05-19 1994-08-09 Schwan-Stabilo Schwanhaeusser Gmbh & Co. Marker pencil
US6169185B1 (en) * 1999-02-25 2001-01-02 Day-Glo Color Corp. Ink jet printing inks
EP1099437A1 (fr) * 1999-11-12 2001-05-16 L'oreal Composition comprenant une substance fluorescente et une charge particuliere, utilisations
WO2002061003A1 (fr) * 2001-01-30 2002-08-08 Schwan-Stabilo Schwanhäusser Gmbh & Co. Liquide de marquage

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PATENT ABSTRACTS OF JAPAN vol. 0174, no. 75 (C - 1103) 30 August 1993 (1993-08-30) *

Cited By (32)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005107684A1 (fr) * 2004-04-30 2005-11-17 The Procter & Gamble Company Compositions cosmetiques longue duree a brillance amelioree
US8318187B2 (en) 2004-04-30 2012-11-27 The Procter & Gamble Company Long-wearing cosmetic compositions with improved shine
WO2006082102A2 (fr) * 2005-02-04 2006-08-10 Schwan-Stabilo Cosmetics Gmbh & Co. Kg Preparation, notamment preparation cosmetique, production et utilisation de ladite preparation
WO2006082102A3 (fr) * 2005-02-04 2007-01-18 Schwan Stabilo Cosmetics Gmbh Preparation, notamment preparation cosmetique, production et utilisation de ladite preparation
FR2885520A1 (fr) * 2005-05-10 2006-11-17 Oreal Composition cosmetique
EP1723988A1 (fr) * 2005-05-10 2006-11-22 L'oreal Composition cosmétique
WO2007007289A2 (fr) * 2005-07-13 2007-01-18 L'oreal Composition cosmetique a effets de couleurs et/ou optiques
WO2007007296A1 (fr) * 2005-07-13 2007-01-18 L'oreal Traitement cosmetique de maquillage et/ou de soins
WO2007007290A1 (fr) * 2005-07-13 2007-01-18 L'oreal Maquillage et/ou procede de soins
FR2888503A1 (fr) * 2005-07-13 2007-01-19 Oreal Composition cosmetique a effets coloriels et/ou optiques
FR2888500A1 (fr) * 2005-07-13 2007-01-19 Oreal Procede de maquillage et/ou de soin cosmetique
FR2888496A1 (fr) * 2005-07-13 2007-01-19 Oreal Procede de maquillage et/ou de soin cosmetique
FR2888497A1 (fr) * 2005-07-13 2007-01-19 Oreal Procede de maquillage et/ou de soin cosmetique
WO2007007287A3 (fr) * 2005-07-13 2007-03-29 Oreal Procede de maquillage et/ou de soin cosmetique
WO2007007289A3 (fr) * 2005-07-13 2007-05-10 Oreal Composition cosmetique a effets de couleurs et/ou optiques
WO2007007287A2 (fr) * 2005-07-13 2007-01-18 L'oreal Procede de maquillage et/ou de soin cosmetique
WO2007031139A1 (fr) 2005-07-14 2007-03-22 Schwan-Stabilo Cosmetics Gmbh & Co. Kg Préparation, en particulier préparation cosmétique, procédé de production de ladite préparation et applications
WO2007048472A1 (fr) * 2005-10-28 2007-05-03 Henkel Kommanditgesellschaft Auf Aktien Procede de traitement des cheveux caracterise par une efficacite de soin amelioree et produit pour mettre en oeuvre ce procede
WO2008009562A1 (fr) * 2006-07-17 2008-01-24 Beiersdorf Ag Crayon cosmétique
JP2008120687A (ja) * 2006-11-08 2008-05-29 Shiseido Co Ltd 化粧料用色材およびメーキャップ化粧料
WO2008056688A1 (fr) * 2006-11-08 2008-05-15 Shiseido Company Ltd. Colorant pour préparation cosmétique et cosmétique de maquillage
DE102007005645A1 (de) 2007-01-31 2008-08-07 Henkel Ag & Co. Kgaa Mit Polymerpartikeln beschichtete Lichteffektpigmente
DE102007005646A1 (de) 2007-01-31 2008-08-07 Henkel Ag & Co. Kgaa Färbemittel, enthaltend durch sichtbares Licht anregbare Lumineszenzpigmente
DE102007039335A1 (de) 2007-08-20 2009-02-26 Henkel Ag & Co. Kgaa Lumineszierende Kompositmaterialien
FR2968971A1 (fr) * 2010-12-20 2012-06-22 Oreal Composition comprenant un colorant naturel, un silicate insoluble, un compose aromatique et un solvant aliphatique hydroxyle
JP5801503B1 (ja) * 2015-01-21 2015-10-28 株式会社 資生堂 メーキャップ化粧料
JP2016132650A (ja) * 2015-01-21 2016-07-25 株式会社 資生堂 メーキャップ化粧料
WO2016117637A1 (fr) * 2015-01-21 2016-07-28 株式会社 資生堂 Produit cosmétique de maquillage
US10272026B2 (en) 2017-07-31 2019-04-30 L'oreal Water-in-oil emulsion compositions suitable for altering the color of hair
WO2019141959A1 (fr) * 2018-01-19 2019-07-25 Perachem Limited Procédé et composition pour colorer un sourcil comprenant un acide organique
US11648191B2 (en) 2018-01-19 2023-05-16 Perachtm Limited Method and composition for colouring an eyebrow comprising an organic acid
CN113476381A (zh) * 2021-07-13 2021-10-08 杭州毛戈平科技有限公司 一种持久滋润口红及其制备工艺

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