EP2013384A1 - Fil de polymère et matériau non tissé - Google Patents
Fil de polymère et matériau non tisséInfo
- Publication number
- EP2013384A1 EP2013384A1 EP07724352A EP07724352A EP2013384A1 EP 2013384 A1 EP2013384 A1 EP 2013384A1 EP 07724352 A EP07724352 A EP 07724352A EP 07724352 A EP07724352 A EP 07724352A EP 2013384 A1 EP2013384 A1 EP 2013384A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- polymer
- filler
- filament
- weight
- polymer thread
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920005594 polymer fiber Polymers 0.000 title abstract description 3
- 229920000642 polymer Polymers 0.000 claims abstract description 72
- 239000000945 filler Substances 0.000 claims abstract description 55
- 239000000203 mixture Substances 0.000 claims abstract description 35
- 239000002245 particle Substances 0.000 claims abstract description 32
- 238000000034 method Methods 0.000 claims abstract description 21
- 239000004753 textile Substances 0.000 claims abstract description 14
- 229920001169 thermoplastic Polymers 0.000 claims abstract description 6
- 239000008187 granular material Substances 0.000 claims abstract description 5
- 230000002040 relaxant effect Effects 0.000 claims abstract description 5
- 239000011256 inorganic filler Substances 0.000 claims abstract description 4
- 229910003475 inorganic filler Inorganic materials 0.000 claims abstract description 4
- 238000002360 preparation method Methods 0.000 claims abstract 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 66
- 239000004745 nonwoven fabric Substances 0.000 claims description 47
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 33
- 239000004743 Polypropylene Substances 0.000 claims description 31
- 229920001155 polypropylene Polymers 0.000 claims description 30
- 239000000835 fiber Substances 0.000 claims description 26
- -1 polyethylene Polymers 0.000 claims description 18
- 239000004744 fabric Substances 0.000 claims description 15
- 238000004519 manufacturing process Methods 0.000 claims description 13
- 230000008569 process Effects 0.000 claims description 13
- 229920000098 polyolefin Polymers 0.000 claims description 10
- 239000004698 Polyethylene Substances 0.000 claims description 8
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 7
- 229920000728 polyester Polymers 0.000 claims description 6
- 229920000573 polyethylene Polymers 0.000 claims description 6
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 claims description 4
- 239000004952 Polyamide Substances 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 4
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 claims description 4
- 229920002647 polyamide Polymers 0.000 claims description 4
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 3
- 239000004734 Polyphenylene sulfide Substances 0.000 claims description 3
- 229910052736 halogen Inorganic materials 0.000 claims description 3
- 150000002367 halogens Chemical class 0.000 claims description 3
- 229920000069 polyphenylene sulfide Polymers 0.000 claims description 3
- 239000005062 Polybutadiene Substances 0.000 claims description 2
- 229920002367 Polyisobutene Polymers 0.000 claims description 2
- 239000000443 aerosol Substances 0.000 claims description 2
- 238000004140 cleaning Methods 0.000 claims description 2
- 239000002537 cosmetic Substances 0.000 claims description 2
- 238000000151 deposition Methods 0.000 claims description 2
- 239000007789 gas Substances 0.000 claims description 2
- 239000011810 insulating material Substances 0.000 claims description 2
- 229920002857 polybutadiene Polymers 0.000 claims description 2
- 229920001195 polyisoprene Polymers 0.000 claims description 2
- 239000004408 titanium dioxide Substances 0.000 claims description 2
- 235000013311 vegetables Nutrition 0.000 claims description 2
- 238000004804 winding Methods 0.000 claims description 2
- 230000008021 deposition Effects 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 9
- 238000009987 spinning Methods 0.000 abstract description 2
- 238000005096 rolling process Methods 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 238000007792 addition Methods 0.000 description 8
- 238000002074 melt spinning Methods 0.000 description 6
- 230000035699 permeability Effects 0.000 description 6
- 238000012360 testing method Methods 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 230000035515 penetration Effects 0.000 description 4
- 239000011148 porous material Substances 0.000 description 4
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 3
- 229910010413 TiO 2 Inorganic materials 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000007596 consolidation process Methods 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 238000001125 extrusion Methods 0.000 description 3
- 239000012764 mineral filler Substances 0.000 description 3
- 229920000747 poly(lactic acid) Polymers 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- 239000002033 PVDF binder Substances 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 230000004888 barrier function Effects 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 235000013980 iron oxide Nutrition 0.000 description 2
- 229920002521 macromolecule Polymers 0.000 description 2
- 239000000395 magnesium oxide Substances 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 2
- 239000010445 mica Substances 0.000 description 2
- 229910052618 mica group Inorganic materials 0.000 description 2
- 229920002492 poly(sulfone) Polymers 0.000 description 2
- 229920001707 polybutylene terephthalate Polymers 0.000 description 2
- 229920000515 polycarbonate Polymers 0.000 description 2
- 239000004417 polycarbonate Substances 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 239000004626 polylactic acid Substances 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 2
- 239000004810 polytetrafluoroethylene Substances 0.000 description 2
- 229920002215 polytrimethylene terephthalate Polymers 0.000 description 2
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 2
- 239000000454 talc Substances 0.000 description 2
- 229910052623 talc Inorganic materials 0.000 description 2
- 244000198134 Agave sisalana Species 0.000 description 1
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 description 1
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 description 1
- 102000011045 Chloride Channels Human genes 0.000 description 1
- 108010062745 Chloride Channels Proteins 0.000 description 1
- 240000000491 Corchorus aestuans Species 0.000 description 1
- 235000011777 Corchorus aestuans Nutrition 0.000 description 1
- 235000010862 Corchorus capsularis Nutrition 0.000 description 1
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 208000002430 Multiple chemical sensitivity Diseases 0.000 description 1
- 244000061176 Nicotiana tabacum Species 0.000 description 1
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 1
- 108091034117 Oligonucleotide Proteins 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 229930040373 Paraformaldehyde Natural products 0.000 description 1
- 239000004642 Polyimide Substances 0.000 description 1
- 229920002396 Polyurea Polymers 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 239000004708 Very-low-density polyethylene Substances 0.000 description 1
- 238000006653 Ziegler-Natta catalysis Methods 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical class [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
- AYJRCSIUFZENHW-UHFFFAOYSA-L barium carbonate Chemical compound [Ba+2].[O-]C([O-])=O AYJRCSIUFZENHW-UHFFFAOYSA-L 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000007767 bonding agent Substances 0.000 description 1
- 238000003490 calendering Methods 0.000 description 1
- 235000009120 camo Nutrition 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 150000001244 carboxylic acid anhydrides Chemical class 0.000 description 1
- 238000009960 carding Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 235000005607 chanvre indien Nutrition 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000005352 clarification Methods 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000010041 electrostatic spinning Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000007380 fibre production Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000011487 hemp Substances 0.000 description 1
- 229920001903 high density polyethylene Polymers 0.000 description 1
- 239000004700 high-density polyethylene Substances 0.000 description 1
- 238000003898 horticulture Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical class [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 229920000092 linear low density polyethylene Polymers 0.000 description 1
- 239000004707 linear low-density polyethylene Substances 0.000 description 1
- 229920001684 low density polyethylene Polymers 0.000 description 1
- 239000004702 low-density polyethylene Substances 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical class [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 235000011160 magnesium carbonates Nutrition 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000006224 matting agent Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000010297 mechanical methods and process Methods 0.000 description 1
- 230000005226 mechanical processes and functions Effects 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 239000011112 polyethylene naphthalate Substances 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 239000005033 polyvinylidene chloride Substances 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 239000001038 titanium pigment Substances 0.000 description 1
- 229920001866 very low density polyethylene Polymers 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- 150000007934 α,β-unsaturated carboxylic acids Chemical class 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/02—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D01F6/04—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyolefins
- D01F6/06—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyolefins from polypropylene
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/4382—Stretched reticular film fibres; Composite fibres; Mixed fibres; Ultrafine fibres; Fibres for artificial leather
- D04H1/43825—Composite fibres
- D04H1/43828—Composite fibres sheath-core
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/4282—Addition polymers
- D04H1/4291—Olefin series
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/4326—Condensation or reaction polymers
- D04H1/4334—Polyamides
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/4326—Condensation or reaction polymers
- D04H1/435—Polyesters
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/4382—Stretched reticular film fibres; Composite fibres; Mixed fibres; Ultrafine fibres; Fibres for artificial leather
- D04H1/43825—Composite fibres
- D04H1/43832—Composite fibres side-by-side
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/4391—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece characterised by the shape of the fibres
- D04H1/43912—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece characterised by the shape of the fibres fibres with noncircular cross-sections
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/4391—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece characterised by the shape of the fibres
- D04H1/43914—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece characterised by the shape of the fibres hollow fibres
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
- D04H3/005—Synthetic yarns or filaments
- D04H3/007—Addition polymers
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
- D04H3/02—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of forming fleeces or layers, e.g. reorientation of yarns or filaments
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
- D04H3/08—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating
- D04H3/16—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between thermoplastic filaments produced in association with filament formation, e.g. immediately following extrusion
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2927—Rod, strand, filament or fiber including structurally defined particulate matter
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
- Y10T442/637—Including strand or fiber material which is a monofilament composed of two or more polymeric materials in physically distinct relationship [e.g., sheath-core, side-by-side, islands-in-sea, fibrils-in-matrix, etc.] or composed of physical blend of chemically different polymeric materials or a physical blend of a polymeric material and a filler material
- Y10T442/642—Strand or fiber material is a blend of polymeric material and a filler material
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
- Y10T442/699—Including particulate material other than strand or fiber material
Definitions
- the invention relates to a polymer thread containing a thermoplastic polymer and an inorganic filler.
- the polymer thread is for the production of textile
- Sheets in particular provided by nonwovens.
- No. 6,797,377 B1 describes a process for producing a fabric from a polymer or polymer mixture having a cloth-like structure which has a mineral filler content of up to 10% to ensure the softness of the fabric as it increases
- a mineral filler content of up to 10% to ensure the softness of the fabric as it increases
- TiO 2 in particular prevents the increasing stiffening of the fabric at higher filler contents Therefore, according to the teaching of US 6,797,377, only a mixture of TiO 2 and a further mineral filler is used.
- the particle size of the filler a size of 10 to 150 ⁇ m is provided in US Pat. No. 6,797,377.
- the object of the invention is to provide a polymer thread with a higher
- Filler content wherein a produced from the polymer thread nonwoven fabric, in comparison to a polymer thread with a filler content ⁇ 10% by weight, should have substantially unchanged properties.
- the invention teaches a polymer thread containing a thermoplastic polymer and an inorganic filler, which is characterized in that the filler content, based on the polymer thread, more than 10% by weight, and the average particle size (D 5 o) of Filler is less than or equal to 6 microns.
- the core idea of the invention is the recognition that, when the filler content is significantly increased, the particle size of the filler plays a decisive role in ensuring the constancy of the properties of the polymer thread or of the nonwovens produced therefrom.
- the inventors have recognized that with increased filler content especially the uniform dispersion of the filler in the polymer matrix ensures the consistency of the material properties and they have recognized that the uniformity of the dispersion is essentially dependent on the size and shape of the particles of the filler.
- the range of the appropriate average particle size was determined. This is at a filler content of more than 10% by weight at ⁇ 6 microns (D 50 ).
- a “thread” in the sense of the invention is a line-shaped structure which forms the basic element of a textile fabric, and thus the term “thread” is to be understood as a common generic term for the terms “filament” and “fiber”.
- a “fiber” differs conceptually from a “filament” by its finite length. Thus, “filaments” are to be understood inter alia as endless fibers.
- Polymers are macromolecular substances that are composed of simple molecules (monomers) by polymerization, polycondensation or polyaddition.
- “Filament-forming polymers” in the sense of the invention are polymers which have properties which fulfill the conditions of spinnability in their melt or solution The conditions for the spinnability of polymers were described by Nitschman and Schrade (HeIV Chem. Acta 31 (1948). 297) and by Hirai (Rheol Acta 1 (1958) 213) and by Ziabicki and Taskerman-Krozer (Colloid Z. 198 (1964) 60).
- a "filler" within the meaning of the invention relates to particles and other forms of materials which are the polymer
- Extrusion mixture can be added, wherein the particles do not affect the polymer and distribute evenly in the extrusion mixture.
- the filler can be made of different materials, with variations in the shape and size of the particles.
- Texttile fabrics in the context of this description are woven, knitted, knitted or non-woven fabrics. “Nonwovens” are thus a subspecies of textile fabrics. They consist of nonwoven fabrics, which are e.g. by mechanical
- the filler of the polymer thread according to the invention consists of an alkaline earth carbonate, in particular of calcium carbonate.
- Calcium carbonate is an ideal filler, inter alia, by the following of JT Lutz, and RF Grossman (Eds.), "Polymer Modifiers and Additives", Marcel Dekker, Inc. 2001, page 125 et seq., Characteristics characterized: chemically inert to the polymer or other additives; low specific gravity, desired refractive index and color, low cost.
- calcium carbonate is normally derived from natural chalk deposits and that local geological conditions determine the level of additional minerals in the chalk.
- additional minerals e.g., in the chalk, among other alkaline earth carbonates, e.g. also metal oxides such as e.g. Be contained iron oxide.
- the filler consists of at least 90% by weight, preferably 95% by weight, in particular 97% by weight of calcium carbonate.
- fillers include iron oxides, alumina (Al 2 O 3 ) or silica (SiO 2 ) or calcium oxide (CaO) or magnesium oxide (MgO) or barium sulfate (BaSO 4 ) or magnesium sulfate (MgSO 4 ) or aluminum sulfates (AlSO 4 ) or aluminum hydroxide (AlOH 3 ).
- iron oxides iron oxides, alumina (Al 2 O 3 ) or silica (SiO 2 ) or calcium oxide (CaO) or magnesium oxide (MgO) or barium sulfate (BaSO 4 ) or magnesium sulfate (MgSO 4 ) or aluminum sulfates (AlSO 4 ) or aluminum hydroxide (AlOH 3 ).
- alumina kaolin
- zeolites kieselguhr
- talc mica or carbon black.
- Titanium dioxide (TiO 2 ) is also a common filler which can in principle also be used in connection with the invention.
- TiO 2 is also a common filler which can in principle also be used in connection with the invention.
- the filler content is between 15 and 25 percent by weight, based on the weight of the polymer thread.
- the preferred range of the fillers used according to the invention is ⁇ 6 ⁇ m. This preferably corresponds to a top-cut (D 98 ) of
- Filler particles of ⁇ 10 ⁇ m The value in this case indicates that only 2% of the filler particles are> 10 ⁇ m.
- the particle size is 2-6 microns.
- the mentioned lower limit makes no statement on the feasibility of the invention with even smaller particle sizes, but characterizes the range of those particle sizes which ensure a uniform dispersion and at the same time are available at favorable cost prices.
- spherical eg glass or silicate spheres
- cube-shaped eg calcium carbonate
- cuboid eg barium sulfate or silica
- platelet-shaped eg talc or mica
- cylindrical particles e.g talc or mica
- the important thread-forming, spinnable thermoplastic polymers are polyolefins, polyesters, polyamides or halogen-containing polymers.
- the class of polyolefins includes i.a. Polyethylene (HDPE, LDPE, LLDPE, VLDPE, ÜLDPE, UHMW-PE), polypropylene (PP), poly (butobene), polyisobutylene, poly (1-pentene), poly (4-methylpent-1-ene), polybutadiene , Polyisoprene, as well as various
- Olefin copolymers Besides these, heterophasic blends are also among the polyolefins.
- polyolefins in particular polypropylene or polyethylene, graft copolymers or copolymers of polyolefins and ⁇ , ⁇ -unsaturated carboxylic acids or carboxylic anhydrides, polyesters,
- Polycarbonate, polysulfone, polyphenylene sulfide, polystyrene, polyamides or a mixture of two or more of said compounds can be used.
- polyesters are i.a. Polyethylene terephthalate (PET), polytrimethylene terephthalate (PTT), polybutylene terephthalate (PBT), polyethylene naphthalate (PEN), but also degradable polyesters such as polylactic acid (polylactide, PLA) counted.
- PET Polyethylene terephthalate
- PTT polytrimethylene terephthalate
- PBT polybutylene terephthalate
- PEN polyethylene naphthalate
- degradable polyesters such as polylactic acid (polylactide, PLA) counted.
- the halogen-containing fiber-forming polymers include, for example, polyvinyl chloride (PVC), polyvinylidene chloride (PVDC), polyvinylidene fluoride (PVDF) and polytetrafluoroethylene (PTFE).
- PVC polyvinyl chloride
- PVDC polyvinylidene chloride
- PVDF polyvinylidene fluoride
- PTFE polytetrafluoroethylene
- Polymers there are other polymers, such as polyacrylates, Polyvinyl acetate, polyvinyl alcohol, polycarbonate, polyurethane, polystyrene, polyphenylene sulfide, polysulfone, polyoxymethylene, polyimide or polyurea, which come as a component of the polymer thread of the invention in question.
- polyacrylates Polyvinyl acetate, polyvinyl alcohol, polycarbonate, polyurethane, polystyrene, polyphenylene sulfide, polysulfone, polyoxymethylene, polyimide or polyurea, which come as a component of the polymer thread of the invention in question.
- the polymer thread according to the invention may be formed as a mono- or as a multicomponent filament.
- the polymer composition of the individual components does not have to be uniform, but is variable within wide limits.
- the weight fraction of the filler-containing component, based on the total weight of the multicomponent filament is greater than 50%.
- bicomponent filaments When using bicomponent filaments, various shapes are available, e.g. Core / coat or side-to-side. Bicomponent filaments of various polyolefins, particularly polypropylene and polyethylene, are particularly preferred.
- the polymer threads of the invention can be prepared by methods known per se.
- the filler content based on the polymer thread,> 10% by weight, and the average particle size (D 5 o) of the filler is ⁇ 6 microns.
- the macromolecules are arranged in the filaments, wherein the filament receives its physical properties (strength, fineness, shrinkage properties). After stretching, the filaments are placed on a tray for further consolidation to a nonwoven fabric or cut to the desired length for the spinning fiber production (in the
- Literature sometimes becomes filaments after stretching as fibers although the filaments have not been cut to length).
- the consolidation of the filaments in melt spinning can be carried out in a manner known to the person skilled in the art by mechanical processes (mainly needling or hydroentanglement), by heat (welding by application of pressure with simultaneous heating) or by means of chemical methods (bonding agent).
- a method for nonwoven production in addition to the preferred melt spinning for example, the carding process, the meltblown process, the wet-laid process, the electrostatic spinning or aerodynamic nonwoven production process can be used.
- the fabrics according to the invention in particular nonwovens, can likewise be produced by the abovementioned processes.
- the addition of the filler takes place in the stated amount and particle size.
- the following steps are used: i mixing polymer granules with the particles of a filler, ii extruding the mixture through one or more
- the filler content based on the polymer thread, is> 10% by weight, and the average particle size (D 50 ) of the filler is ⁇ 6 ⁇ m.
- textile fabrics of polyolefin fibers in particular of polypropylene fibers and / or polypropylene-polyethylene bicomponent fibers, in particular core sheath fibers with PP core and PE sheath.
- these products are characterized by high stability against chemically aggressive environments.
- the textile fabrics of polyolefin fibers in particular of polypropylene fibers and / or polypropylene-polyethylene bicomponent fibers, in particular core sheath fibers with PP core and PE sheath.
- these products are characterized by high stability against chemically aggressive environments.
- the textile fabrics of polyolefin fibers in particular of polypropylene fibers and / or polypropylene-polyethylene bicomponent fibers, in particular core sheath fibers with PP core and PE sheath.
- Sheet of a mixture of a polymeric thread with a uniform or several different natural fiber Hemp, jute, sisal and tobacco leaves are used as natural fibers.
- nonwoven fabric according to the invention in its solidification, e.g. By varying temperatures and pressures during thermal consolidation during calendering, it can certainly help to vary the properties of the calcium carbonate filled nonwoven fabrics beyond the scope given herein.
- the nonwoven fabric produced according to the invention is more precisely determined by the following parameters within the specified limits:
- Basis weight of 7 and 500 g / m 2 , preferably between 10 and 200 g / m 2 .
- Filament surface hydrophilized has penetration times after EDANA ERT 150 values of less than 5 seconds.
- Filament titer in the range of 1 to 5 dtex, preferably 2 to 3.5 dtex.
- nonwoven fabric In the context of the invention are also the many uses of the nonwoven fabric.
- the most important possible uses for the nonwovens according to the invention are the production of interlining materials, body hygiene articles (diapers, sanitary napkins, cosmetic pads), cleaning wipes and mop cloths, as well as filters for gases, aerosols and liquids, wound dressings, wound compresses.
- the production of insulating materials, acoustic nonwovens and roof underlays is conceivable.
- geo-tile is, according to the breadth of the preamble, very comprehensive.
- geo-tiles are used in the attachment of dykes, as a layer in a green roof construction, as a layer of a landfill cover for the separation of earth layers and bulk solids or as an intermediate layer below the ballast bed of a road surface.
- nonwovens are useful as covers for the field and vegetable economy.
- Example 1 Nonwovens Consisting of Monofilaments PP spunbonds with a different content of calcium carbonate and different weight per unit area were produced on a conventional spunbond pilot plant (Reicofil 3).
- the calcium carbonate used (Omyalene 102M-OG) is a granulated calcium carbonate, which can be obtained from Omya AG.
- ZN-PP Moplen HP560R, manufacturer Basell
- the method presented being not limited to this type of PP, Rather, other suitable for fiber, filament or nonwoven fabric forming plastics, such as metallocene PP, random and heterophasic propylene copolymers, polyolefin block and copolymers, polyethylenes, polyesters, polyamides, etc. are also suitable.
- Table 1 summarizes the composition of the nonwoven fabrics produced as well as selected characteristic properties.
- nonwoven fabric samples 12.1, 17.1 and 20.1 made by melt spinning and made of pure PP monofilaments.
- melt-spun nonwoven samples 12.2, 17.2 and 20.2 were made from monofilaments consisting of a mixture of 90% PP and 10% calcium carbonate.
- melt-spun nonwoven samples 12.3, 17.3 and 20.3 were made from monofilaments consisting of a mixture of 85% PP and 15% calcium carbonate.
- melt-spun nonwoven samples 12.4 and 20.4 were made from monofilaments consisting of a blend of 75% PP and 25% calcium carbonate. Table 1. Composition, process conditions, and characteristics of monofilament nonwovens.
- Extruder head 0 C 230 230 230 230 230 230 230 230 230 230 230 230 230 230 230 230
- Nonwoven thickness ⁇ m 216.C 279.0 312.5 216.5 270.5 303.0 204.5 269.0 303.5
- multicomponent fibers were also spun for the production of nonwovens, in which the calcium carbonate is not distributed throughout the fiber, but only in individual fiber components.
- nonwovens were made from core / sheath bicomponent fibers.
- Table 2 summarizes the composition and its characteristics.
- the nonwoven fabric samples 12. IB and 20. IB produced by melt spinning are made of pure PP bicomponent filaments with a core / sheath ratio of 50/50 and are intended as a reference.
- the melt-spun nonwoven samples 12.2B and 20.2B consist of PP bicomponent filaments in which the core of the filaments consists of a blend of 90% PP and 10% calcium carbonate and the sheath of pure PP.
- the core / shell ratio was 75/25. Based on the total fiber, the content of calcium carbonate is about 7.5%.
- the melt-spun nonwoven samples 12.3B and 20.3B are made of PP bicomponent filaments in which both the core and the sheath of the filaments are a mixture of 90% PP and 10% calcium carbonate.
- the Core / shell ratio was 50/50. Based on the total fiber, the content of calcium carbonate is about 5%.
- the melt-spun nonwoven fabric sample 20.4B consists of PP bicomponent filaments in which the core of the filaments consists of a mixture of 75% PP and 25% calcium carbonate and the sheath of pure PP.
- the core / shell ratio was 50/50. Based on the total fiber, the content of calcium carbonate is about 12.5%.
- the melt-spun nonwoven fabric sample 20.5B consists of PP bicomponent filaments in which the core of the filaments consists of a blend of 75% PP and 25% calcium carbonate and the sheath of pure PP.
- the core / shell ratio was 75/25. Based on the total fiber, the content of calcium carbonate is about 18.75%.
- blends for producing the nonwoven fabrics may contain, in addition to the specified formulations, other additives or blends, in particular titanium dioxide or pigments.
- Table 2 Composition, process conditions, and characteristics of nonwovens made from bicomponent fibers.
- Extruder 1st zone 0 C 180 180 180 180 180 180 180 180 180 180 180 180 180 180 180 180 180 180 180 180 180 180
- Extruder head 0 C 230 230 230 230 230 230 230 230 230 230 230 230 230 230 230
- Nonwovens used for personal care products are typically rendered hydrophilic.
- the hydrophilizing agent Nuwet 237 from GE SILOCONES can be used for this purpose.
- both pure PP nonwovens and those with a calcium carbonate content of 10% and a basis weight of 12 g / m 2 and 20 g / m 2 were admixed by a formulation consisting of 7.5%.
- the basis weight determination was carried out according to DIN EN 29073-1 on 10 x 10 cm specimens.
- the nonwoven fabric thickness was measured as the distance between two plane-parallel measuring surfaces of a certain size, between which the nonwovens are below a predetermined measuring pressure.
- the method was carried out analogously to DIN EN ISO 9073-2.
- the average pore size of the nonwovens was determined by means of a capillary flow porometer (PMI Capillary Flow Porometer CFP-34RUF8A-3-X-M2T). In the process, a sample saturated with a special liquid in the porometer becomes one continuously increasing air pressure, the dependence of air pressure and air flow is measured.
- the measurement of the air permeability was carried out according to DIN EN ISO 9237.
- the surface of the measuring head was 20 cm 2 , the applied test pressure 200 Pa.
- the mechanical properties of the nonwovens were determined according to DIN EN 29073-3. Clamping length: 100mm, sample width 50mm, feed 200mm / min. "Maximum tensile force” is the maximum force reached when passing through the force-strain curve, “Maximum tensile strain” is the strain in the force-strain curve associated with the maximum tensile force.
- the penetration times of the hydrophilized nonwovens were measured according to EDANA ERT 150.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Nonwoven Fabrics (AREA)
- Artificial Filaments (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
- Woven Fabrics (AREA)
- Filtering Materials (AREA)
- Multicomponent Fibers (AREA)
- Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
- Absorbent Articles And Supports Therefor (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL07724352T PL2013384T5 (pl) | 2006-04-28 | 2007-04-19 | Włóknina |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102006020488.3A DE102006020488B4 (de) | 2006-04-28 | 2006-04-28 | Vliesstoff, Verfahren zu dessen Herstellung und dessen Verwendung |
| PCT/EP2007/003415 WO2007124866A1 (fr) | 2006-04-28 | 2007-04-19 | Fil de polymère et matériau non tissé |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| EP2013384A1 true EP2013384A1 (fr) | 2009-01-14 |
| EP2013384B1 EP2013384B1 (fr) | 2010-03-03 |
| EP2013384B2 EP2013384B2 (fr) | 2014-01-15 |
Family
ID=38294020
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP07724352.5A Active EP2013384B2 (fr) | 2006-04-28 | 2007-04-19 | Matériau non tissé |
Country Status (13)
| Country | Link |
|---|---|
| US (2) | US8987152B2 (fr) |
| EP (1) | EP2013384B2 (fr) |
| JP (1) | JP2009534549A (fr) |
| CN (1) | CN101432472A (fr) |
| AT (1) | ATE459736T1 (fr) |
| BR (1) | BRPI0710984B1 (fr) |
| DE (2) | DE102006020488B4 (fr) |
| ES (1) | ES2340815T5 (fr) |
| MX (1) | MX2008013609A (fr) |
| PL (1) | PL2013384T5 (fr) |
| RU (2) | RU2408745C2 (fr) |
| UA (1) | UA98457C2 (fr) |
| WO (1) | WO2007124866A1 (fr) |
Families Citing this family (40)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8921244B2 (en) | 2005-08-22 | 2014-12-30 | The Procter & Gamble Company | Hydroxyl polymer fiber fibrous structures and processes for making same |
| DE102006020488B4 (de) | 2006-04-28 | 2017-03-23 | Fitesa Germany Gmbh | Vliesstoff, Verfahren zu dessen Herstellung und dessen Verwendung |
| DE102006044496A1 (de) | 2006-09-21 | 2008-04-17 | Fiberweb Corovin Gmbh | Leichtgewichtiges Spinnvlies mit besonderen mechanischen Eigenschaften |
| US20100184348A1 (en) * | 2006-12-20 | 2010-07-22 | Imerys Pigments, Inc. | Spunlaid Fibers Comprising Coated Calcium Carbonate, Processes For Their Production, and Nonwoven Products |
| EP2633964B1 (fr) | 2007-06-03 | 2018-10-24 | Imerys Pigments, Inc. | Produits non tissés et leurs procédés de production |
| US20090022983A1 (en) | 2007-07-17 | 2009-01-22 | David William Cabell | Fibrous structures |
| US8852474B2 (en) | 2007-07-17 | 2014-10-07 | The Procter & Gamble Company | Process for making fibrous structures |
| US7972986B2 (en) | 2007-07-17 | 2011-07-05 | The Procter & Gamble Company | Fibrous structures and methods for making same |
| US10024000B2 (en) | 2007-07-17 | 2018-07-17 | The Procter & Gamble Company | Fibrous structures and methods for making same |
| BRPI0906807B1 (pt) * | 2008-01-21 | 2019-02-19 | Imerys Pigments, Inc. | Fibra monofilamentar |
| FI20095800A0 (fi) | 2009-07-20 | 2009-07-20 | Ahlstroem Oy | Nonwoven komposiittituote, jolla on korkea selluloosapitoisuus |
| JP5292517B2 (ja) | 2009-11-02 | 2013-09-18 | ザ プロクター アンド ギャンブル カンパニー | 繊維性構造体及びその作製方法 |
| BR112012010003A2 (pt) | 2009-11-02 | 2016-03-01 | Procter & Gamble | elementos fibrosos e estruturas fibrosas que empregam os mesmos |
| CN102652007B (zh) * | 2009-12-10 | 2014-09-17 | Sca卫生用品公司 | 作为碳降低物的吸收制品 |
| KR101684906B1 (ko) * | 2009-12-29 | 2016-12-09 | 코오롱글로텍주식회사 | 위생용품용 폴리올레핀계 단섬유, 부직포, 및 이들의 제조방법 |
| MX346871B (es) | 2010-03-31 | 2017-03-24 | Procter & Gamble | Estructuras fibrosas y métodos para elaborarlas. |
| LV14446B (lv) * | 2011-07-29 | 2012-04-20 | Jlu Technologies, Sia | Dzintara kompozītpavedieni |
| US20140018758A1 (en) * | 2012-07-13 | 2014-01-16 | The Procter & Gamble Company | Stretchable laminates for absorbent articles and methods for making the same |
| EP2749679B1 (fr) * | 2012-12-28 | 2017-03-22 | Omya International AG | CaCO3 en polyester pour non-tissé et fibres |
| US9861533B2 (en) | 2013-05-08 | 2018-01-09 | The Procter & Gamble Company | Apertured nonwoven materials and methods for forming the same |
| EP3008231B1 (fr) * | 2013-06-12 | 2019-05-08 | Kimberly-Clark Worldwide, Inc. | Étoffe multifonctionnelle |
| JP2016532019A (ja) * | 2013-09-03 | 2016-10-13 | トーレ・アドバンスド・マテリアルズ・コリア・インコーポレーテッドＴｏｒａｙ Ａｄｖａｎｃｅｄ Ｍａｔｅｒｉａｌｓ Ｋｏｒｅａ Ｉｎｃｏｒｐｏｒａｔｅｄ | 炭酸カルシウムを含むポリオレフィン系不織布及びその製造方法 |
| US9580845B2 (en) | 2014-06-09 | 2017-02-28 | The Procter & Gamble Company | Nonwoven substrate comprising fibers comprising an engineering thermoplastic polymer |
| TR201810896T4 (tr) | 2014-07-01 | 2018-08-27 | Omya Int Ag | Çok filamentli polyester elyaflar. |
| MX2017005908A (es) | 2014-11-06 | 2017-06-27 | Procter & Gamble | Articulos absorbentes que comprenden laminados orientados hacia la prenda. |
| WO2016073724A1 (fr) | 2014-11-06 | 2016-05-12 | The Procter & Gamble Company | Bandes/stratifiés de non-tissé filé-lié à fibres frisées |
| CN107106380A (zh) | 2014-11-06 | 2017-08-29 | 宝洁公司 | 具有色彩效果的吸收制品 |
| AU2016368453B2 (en) * | 2015-12-11 | 2021-10-28 | Kimberly-Clark Worldwide, Inc. | Method for forming porous fibers |
| JP2019507641A (ja) | 2016-03-09 | 2019-03-22 | ザ プロクター アンド ギャンブル カンパニー | 吸収性物品 |
| EP3480352B1 (fr) * | 2016-03-10 | 2020-02-12 | Reifenhäuser GmbH & Co. KG Maschinenfabrik | Emballage |
| US20170258645A1 (en) | 2016-03-11 | 2017-09-14 | The Procter & Gamble Company | Three-dimensional materials having apertures |
| CN106192215A (zh) * | 2016-07-12 | 2016-12-07 | 纺粘无纺布(深圳)有限公司 | 一种皮革抹布及其制备方法 |
| DE112018000617T5 (de) | 2017-01-31 | 2019-11-07 | The Procter & Gamble Company | Geformte Vliesstoffe und diese enthaltende Artikel |
| EP4335420A3 (fr) | 2017-02-16 | 2024-05-29 | The Procter & Gamble Company | Articles absorbants avec substrats ayant des motifs répétitifs d'ouvertures comprenant une pluralité d'unités récurrentes |
| KR102455776B1 (ko) * | 2017-11-01 | 2022-10-18 | 도레이 카부시키가이샤 | 스펀본드 부직포 |
| US11266544B2 (en) | 2018-09-19 | 2022-03-08 | The Procter & Gamble Company | Method and apparatus for making patterned apertured substrates |
| WO2020219414A1 (fr) | 2019-04-24 | 2020-10-29 | The Procter & Gamble Company | Bandes non tissées hautement extensibles et articles absorbants présentant de telles bandes |
| US20220195645A1 (en) * | 2020-12-21 | 2022-06-23 | O&M Halyard, Inc. | Higher Strength Calcium Carbonate Filled Fiber Spunbond and SMS Nonwoven Material |
| CN114250541B (zh) * | 2021-12-30 | 2023-04-25 | 匹克（中国）有限公司 | 吸湿速干抗菌面料及其制备方法 |
| CN117211008B (zh) * | 2023-11-09 | 2024-01-30 | 龙帛生物科技有限公司 | 一种可降解无纺布材料及其制备方法 |
Family Cites Families (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1950669C3 (de) | 1969-10-08 | 1982-05-13 | Metallgesellschaft Ag, 6000 Frankfurt | Verfahren zur Vliesherstellung |
| GB1328090A (en) * | 1969-12-29 | 1973-08-30 | Shell Int Research | Filler-containing film fibres and process for the manufacture thereof |
| JPS5148782B2 (fr) * | 1974-07-20 | 1976-12-22 | ||
| DE3713861A1 (de) | 1987-04-25 | 1988-11-10 | Reifenhaeuser Masch | Verfahren und spinnvliesanlage zur herstellung eines spinnvlieses aus synthetischem endlosfilament |
| GB8716243D0 (en) * | 1987-07-10 | 1987-08-19 | Courtaulds Plc | Yarns |
| JPH0261120A (ja) * | 1988-08-24 | 1990-03-01 | Asahi Chem Ind Co Ltd | 保温性繊維製品用複合混繊糸 |
| TW224494B (fr) * | 1991-07-25 | 1994-06-01 | Kuraray Co | |
| US5506041A (en) * | 1991-09-26 | 1996-04-09 | Unitika Ltd. | Biodegradable nonwoven fabrics |
| WO2002063087A1 (fr) | 2001-02-05 | 2002-08-15 | Ason Engineering, Ltd. | Appareil et procede de production de bandes non tissees avec une vitesse de filament elevee |
| US5626960A (en) * | 1995-09-07 | 1997-05-06 | E. I. Du Pont De Nemours And Company | Spandex containing a huntite and hydromagnesite additive |
| TW324031B (en) * | 1996-02-12 | 1998-01-01 | Danaklon As | Fiber or filament suitable for producing non-woven fabric, a non-woven fabric and process of producing non-woven fabric the invention relates to a fiber or filament suitable for producing non-woven fabric, in which the fiber or filament comprises a polymer and 0.01-20 wt% of inorganic particles. |
| CN1079452C (zh) * | 1996-02-12 | 2002-02-20 | 菲伯维森斯公司 | 适于制作非织造布的纤维或长丝及制备非织造布的方法 |
| US20040097158A1 (en) * | 1996-06-07 | 2004-05-20 | Rudisill Edgar N. | Nonwoven fibrous sheet structures |
| JPH1059754A (ja) * | 1996-08-19 | 1998-03-03 | Daiwabo Co Ltd | セメント補強用ポリプロピレン繊維およびセメント成型体 |
| JP3949172B2 (ja) † | 1996-10-11 | 2007-07-25 | チッソ株式会社 | 長繊維不織布とその製造方法及びこれを用いた吸収性物品 |
| JPH10140420A (ja) * | 1996-11-07 | 1998-05-26 | Japan Exlan Co Ltd | 無機微粒子含有繊維とその製造方法 |
| US5904982A (en) * | 1997-01-10 | 1999-05-18 | Basf Corporation | Hollow bicomponent filaments and methods of making same |
| US6797377B1 (en) * | 1998-06-30 | 2004-09-28 | Kimberly-Clark Worldwide, Inc. | Cloth-like nonwoven webs made from thermoplastic polymers |
| JP2002069742A (ja) * | 2000-08-29 | 2002-03-08 | Toyobo Co Ltd | 高比重糸 |
| US6855422B2 (en) * | 2000-09-21 | 2005-02-15 | Monte C. Magill | Multi-component fibers having enhanced reversible thermal properties and methods of manufacturing thereof |
| WO2003038174A1 (fr) | 2001-09-26 | 2003-05-08 | Bba Nonwovens Simpsonville, Inc. | Appareil et procede de production d'un toile de filaments non tisses |
| US20030203695A1 (en) * | 2002-04-30 | 2003-10-30 | Polanco Braulio Arturo | Splittable multicomponent fiber and fabrics therefrom |
| US20040116018A1 (en) * | 2002-12-17 | 2004-06-17 | Kimberly-Clark Worldwide, Inc. | Method of making fibers, nonwoven fabrics, porous films and foams that include skin treatment additives |
| US20040242105A1 (en) * | 2003-05-30 | 2004-12-02 | Mcguire Sheri L. | High loft nonwoven having balanced properties and a method of making same |
| US7172814B2 (en) * | 2003-06-03 | 2007-02-06 | Bio-Tec Biologische Naturverpackungen Gmbh & Co | Fibrous sheets coated or impregnated with biodegradable polymers or polymers blends |
| JP3883007B2 (ja) * | 2003-06-19 | 2007-02-21 | 住友金属鉱山株式会社 | ホウ化物微粒子含有繊維およびこれを用いた繊維製品 |
| US20050215155A1 (en) * | 2004-03-23 | 2005-09-29 | The Procter & Gamble Company | Absorbent article with improved opacity |
| US7338916B2 (en) * | 2004-03-31 | 2008-03-04 | E.I. Du Pont De Nemours And Company | Flash spun sheet material having improved breathability |
| US20070122614A1 (en) * | 2005-11-30 | 2007-05-31 | The Dow Chemical Company | Surface modified bi-component polymeric fiber |
| DE102006020488B4 (de) | 2006-04-28 | 2017-03-23 | Fitesa Germany Gmbh | Vliesstoff, Verfahren zu dessen Herstellung und dessen Verwendung |
| DE102006044495A1 (de) * | 2006-09-21 | 2008-04-17 | Fiberweb Corovin Gmbh | Leichtgewichtiges Spinnvlies mit besonderen Sperreigenschaften |
-
2006
- 2006-04-28 DE DE102006020488.3A patent/DE102006020488B4/de not_active Expired - Fee Related
-
2007
- 2007-04-19 RU RU2008147001A patent/RU2408745C2/ru active
- 2007-04-19 UA UAA200812524A patent/UA98457C2/ru unknown
- 2007-04-19 MX MX2008013609A patent/MX2008013609A/es active IP Right Grant
- 2007-04-19 RU RU2010132636/05A patent/RU2570872C2/ru active
- 2007-04-19 DE DE200750003010 patent/DE502007003010D1/de active Active
- 2007-04-19 PL PL07724352T patent/PL2013384T5/pl unknown
- 2007-04-19 EP EP07724352.5A patent/EP2013384B2/fr active Active
- 2007-04-19 BR BRPI0710984-9A patent/BRPI0710984B1/pt active IP Right Grant
- 2007-04-19 ES ES07724352T patent/ES2340815T5/es active Active
- 2007-04-19 CN CNA2007800151067A patent/CN101432472A/zh active Pending
- 2007-04-19 WO PCT/EP2007/003415 patent/WO2007124866A1/fr active Application Filing
- 2007-04-19 JP JP2009506953A patent/JP2009534549A/ja active Pending
- 2007-04-19 AT AT07724352T patent/ATE459736T1/de active
-
2008
- 2008-10-27 US US12/258,811 patent/US8987152B2/en active Active
-
2015
- 2015-03-18 US US14/661,147 patent/US10087555B2/en active Active
Non-Patent Citations (1)
| Title |
|---|
| See references of WO2007124866A1 * |
Also Published As
| Publication number | Publication date |
|---|---|
| US8987152B2 (en) | 2015-03-24 |
| EP2013384B1 (fr) | 2010-03-03 |
| RU2010132636A (ru) | 2012-02-10 |
| ES2340815T5 (es) | 2014-04-30 |
| ES2340815T3 (es) | 2010-06-09 |
| EP2013384B2 (fr) | 2014-01-15 |
| PL2013384T3 (pl) | 2010-07-30 |
| US10087555B2 (en) | 2018-10-02 |
| ATE459736T1 (de) | 2010-03-15 |
| US20090104831A1 (en) | 2009-04-23 |
| RU2408745C2 (ru) | 2011-01-10 |
| BRPI0710984A2 (pt) | 2011-05-31 |
| RU2570872C2 (ru) | 2015-12-10 |
| PL2013384T5 (pl) | 2014-06-30 |
| MX2008013609A (es) | 2009-02-12 |
| DE102006020488B4 (de) | 2017-03-23 |
| DE502007003010D1 (de) | 2010-04-15 |
| CN101432472A (zh) | 2009-05-13 |
| DE102006020488A1 (de) | 2007-10-31 |
| JP2009534549A (ja) | 2009-09-24 |
| BRPI0710984B1 (pt) | 2018-05-02 |
| RU2008147001A (ru) | 2010-06-10 |
| WO2007124866A1 (fr) | 2007-11-08 |
| UA98457C2 (ru) | 2012-05-25 |
| US20150191853A1 (en) | 2015-07-09 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP2013384B1 (fr) | Matériau non tissé | |
| DE112011100474B4 (de) | Hochfunktionelles Spinnvlies aus partikelhaltigen Fasern sowie Verfahren zur Erzeugung | |
| WO2008034613A2 (fr) | Non-tissé léger à propriétés mécaniques spéciales | |
| DE69026298T2 (de) | Starke nicht-gewebte Stoffe aus entwickelten Fasern mit mehreren Bestandteilen | |
| EP2197952B1 (fr) | Mélange de polypropylènes | |
| WO2008034612A2 (fr) | Non-tissé léger à propriétés de barrière spéciales | |
| DE3782724T2 (de) | Verfahren zur herstellung von vliesstoffen. | |
| EP3523472B1 (fr) | Procédé de fabrication d'une structure textile plissable dotée de fibres à charge électrostatique, et structure textile plissable | |
| EP1733088B1 (fr) | Non-tisse file-lie, a base de fibres polymeres et son utilisation | |
| EP3424700A1 (fr) | Non-tissé microfibre | |
| EP3108052A1 (fr) | Chiffon de nettoyage | |
| DE60123094T2 (de) | Meltblown-vliesstoffbahn | |
| DE112019004567T5 (de) | Fasern für vliesstoffe mit mischungen aus polymeren mit hoher und niedriger schmelzflussrate | |
| WO2017032778A1 (fr) | Textile de nettoyage | |
| EP2758580A1 (fr) | Non-tissé pourvu d'une matrice contenant des filaments élémentaires | |
| DE10005454B4 (de) | Einlagiges, beidseitig abrasives Vlies und Verfahren zu dessen Herstellung |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
| 17P | Request for examination filed |
Effective date: 20080809 |
|
| AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LT LU LV MC MT NL PL PT RO SE SI SK TR |
|
| AX | Request for extension of the european patent |
Extension state: AL BA HR MK RS |
|
| 17Q | First examination report despatched |
Effective date: 20090324 |
|
| GRAP | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOSNIGR1 |
|
| RTI1 | Title (correction) |
Free format text: NONWOVEN |
|
| RTI1 | Title (correction) |
Free format text: NONWOVEN |
|
| DAX | Request for extension of the european patent (deleted) | ||
| GRAS | Grant fee paid |
Free format text: ORIGINAL CODE: EPIDOSNIGR3 |
|
| GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
| AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LT LU LV MC MT NL PL PT RO SE SI SK TR |
|
| REG | Reference to a national code |
Ref country code: GB Ref legal event code: FG4D Free format text: NOT ENGLISH |
|
| REG | Reference to a national code |
Ref country code: CH Ref legal event code: EP |
|
| REG | Reference to a national code |
Ref country code: IE Ref legal event code: FG4D |
|
| REF | Corresponds to: |
Ref document number: 502007003010 Country of ref document: DE Date of ref document: 20100415 Kind code of ref document: P |
|
| REG | Reference to a national code |
Ref country code: SE Ref legal event code: TRGR |
|
| REG | Reference to a national code |
Ref country code: NL Ref legal event code: T3 Ref country code: ES Ref legal event code: FG2A Ref document number: 2340815 Country of ref document: ES Kind code of ref document: T3 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20100303 |
|
| REG | Reference to a national code |
Ref country code: PL Ref legal event code: T3 |
|
| LTIE | Lt: invalidation of european patent or patent extension |
Effective date: 20100303 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LV Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20100303 Ref country code: SI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20100303 Ref country code: FI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20100303 |
|
| REG | Reference to a national code |
Ref country code: IE Ref legal event code: FD4D |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: RO Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20100303 Ref country code: EE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20100303 Ref country code: IE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20100303 Ref country code: GR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20100604 Ref country code: CY Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20100303 |
|
| BERE | Be: lapsed |
Owner name: FIBERWEB COROVIN G.M.B.H. Effective date: 20100430 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20100303 Ref country code: MC Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20100430 Ref country code: BG Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20100603 Ref country code: IS Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20100703 |
|
| PLBI | Opposition filed |
Free format text: ORIGINAL CODE: 0009260 |
|
| PLAX | Notice of opposition and request to file observation + time limit sent |
Free format text: ORIGINAL CODE: EPIDOSNOBS2 |
|
| 26 | Opposition filed |
Opponent name: IMERYS MINERALS LIMITED Effective date: 20101203 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: PT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20100705 Ref country code: DK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20100303 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: BE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20100430 Ref country code: IT Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20100419 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20100303 |
|
| PLAF | Information modified related to communication of a notice of opposition and request to file observations + time limit |
Free format text: ORIGINAL CODE: EPIDOSCOBS2 |
|
| PLBB | Reply of patent proprietor to notice(s) of opposition received |
Free format text: ORIGINAL CODE: EPIDOSNOBS3 |
|
| REG | Reference to a national code |
Ref country code: CH Ref legal event code: PL |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LI Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20110430 Ref country code: CH Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20110430 |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: NL Payment date: 20120413 Year of fee payment: 6 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: HU Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20100904 Ref country code: LU Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20100419 |
|
| REG | Reference to a national code |
Ref country code: DE Ref legal event code: R082 Ref document number: 502007003010 Country of ref document: DE Representative=s name: PATENTANWAELTE MAXTON LANGMAACK & PARTNER, DE |
|
| REG | Reference to a national code |
Ref country code: DE Ref legal event code: R082 Ref document number: 502007003010 Country of ref document: DE Representative=s name: PATENTANWAELTE MAXTON LANGMAACK & PARTNER, DE Effective date: 20121218 Ref country code: DE Ref legal event code: R081 Ref document number: 502007003010 Country of ref document: DE Owner name: FITESA GERMANY GMBH, DE Free format text: FORMER OWNER: FIBERWEB COROVIN GMBH, 31224 PEINE, DE Effective date: 20121218 Ref country code: DE Ref legal event code: R082 Ref document number: 502007003010 Country of ref document: DE Representative=s name: VON KREISLER SELTING WERNER - PARTNERSCHAFT VO, DE Effective date: 20121218 Ref country code: DE Ref legal event code: R082 Ref document number: 502007003010 Country of ref document: DE Representative=s name: DOMPATENT VON KREISLER SELTING WERNER - PARTNE, DE Effective date: 20121218 |
|
| REG | Reference to a national code |
Ref country code: AT Ref legal event code: MM01 Ref document number: 459736 Country of ref document: AT Kind code of ref document: T Effective date: 20120419 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: AT Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20120419 |
|
| REG | Reference to a national code |
Ref country code: NL Ref legal event code: V1 Effective date: 20131101 |
|
| PUAH | Patent maintained in amended form |
Free format text: ORIGINAL CODE: 0009272 |
|
| STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: PATENT MAINTAINED AS AMENDED |
|
| 27A | Patent maintained in amended form |
Effective date: 20140115 |
|
| AK | Designated contracting states |
Kind code of ref document: B2 Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LT LU LV MC MT NL PL PT RO SE SI SK TR |
|
| REG | Reference to a national code |
Ref country code: DE Ref legal event code: R102 Ref document number: 502007003010 Country of ref document: DE |
|
| REG | Reference to a national code |
Ref country code: DE Ref legal event code: R102 Ref document number: 502007003010 Country of ref document: DE Effective date: 20140115 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: NL Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20131101 |
|
| REG | Reference to a national code |
Ref country code: SE Ref legal event code: RPEO |
|
| REG | Reference to a national code |
Ref country code: ES Ref legal event code: DC2A Ref document number: 2340815 Country of ref document: ES Kind code of ref document: T5 Effective date: 20140430 |
|
| REG | Reference to a national code |
Ref country code: FR Ref legal event code: CD Owner name: FIBERWEB COROVIN GMBH, DE Effective date: 20140414 |
|
| REG | Reference to a national code |
Ref country code: ES Ref legal event code: PC2A Owner name: FITESA GERMANY GMBH Effective date: 20140523 |
|
| REG | Reference to a national code |
Ref country code: PL Ref legal event code: T5 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LV Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20140115 |
|
| REG | Reference to a national code |
Ref country code: DE Ref legal event code: R082 Ref document number: 502007003010 Country of ref document: DE Representative=s name: VON KREISLER SELTING WERNER - PARTNERSCHAFT VO, DE Ref country code: DE Ref legal event code: R082 Ref document number: 502007003010 Country of ref document: DE Representative=s name: DOMPATENT VON KREISLER SELTING WERNER - PARTNE, DE |
|
| REG | Reference to a national code |
Ref country code: FR Ref legal event code: PLFP Year of fee payment: 10 |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: GB Payment date: 20160413 Year of fee payment: 10 |
|
| REG | Reference to a national code |
Ref country code: FR Ref legal event code: PLFP Year of fee payment: 11 |
|
| GBPC | Gb: european patent ceased through non-payment of renewal fee |
Effective date: 20170419 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: GB Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20170419 |
|
| REG | Reference to a national code |
Ref country code: FR Ref legal event code: PLFP Year of fee payment: 12 |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: SE Payment date: 20220310 Year of fee payment: 16 Ref country code: PL Payment date: 20220315 Year of fee payment: 16 Ref country code: FR Payment date: 20220308 Year of fee payment: 16 Ref country code: CZ Payment date: 20220325 Year of fee payment: 16 |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: ES Payment date: 20220506 Year of fee payment: 16 Ref country code: DE Payment date: 20220430 Year of fee payment: 16 |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: TR Payment date: 20220418 Year of fee payment: 16 |
|
| P01 | Opt-out of the competence of the unified patent court (upc) registered |
Effective date: 20230525 |
|
| REG | Reference to a national code |
Ref country code: DE Ref legal event code: R119 Ref document number: 502007003010 Country of ref document: DE |
|
| REG | Reference to a national code |
Ref country code: SE Ref legal event code: EUG |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20230420 Ref country code: FR Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20230430 Ref country code: DE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20231103 Ref country code: CZ Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20230419 |
|
| REG | Reference to a national code |
Ref country code: ES Ref legal event code: FD2A Effective date: 20240530 |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: IT Payment date: 20240313 Year of fee payment: 18 |