Classifications

• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
  • C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
  • C11D1/88—Ampholytes; Electroneutral compounds
  • C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
  • C11D3/16—Organic compounds
  • C11D3/37—Polymers
  • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
  • C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
  • C11D3/3773—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines in liquid compositions
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
  • C11D3/16—Organic compounds
  • C11D3/38—Products with no well-defined composition, e.g. natural products

Definitions

• the agent according to the invention is intended to be used for cleaning hard surfaces and in particular for manual dishwashing.
• a further subject of this application is therefore the use of a liquid aqueous agent with a surfactant combination containing at least one anionic surfactant and optionally one or more nonionic and / or amphoteric surfactants, and further one or more skin care agents for cleaning hard surfaces and especially as hand dishwashing detergents.
• the quaternary polymers used according to the invention may be synthetic or natural or modified natural polymers.
• So quaternized protein hydrolysates or -Partialhydrolysate as the quaternized offered under the trade name Gluadin® ® WQ from Cognis can be wheat protein hydrolyzate (INCI Laurdimonium hydroxypropyl hydrolyzed wheat protein) used to improve the skin feel, for example.
• skin-affine moisturizing agents are, for example, nourishing wax dispersions.
• all wax dispersions used in cosmetic preparations for skin and hair care / conditioning can be used. Representing be mentioned here that available under the trade name lamesoft ® TM Benz by Cognis dispersion of (INCI) Glycol Distearate, coco-glucoside, glyceryl oleate and glyceryl stearate.
• a mixture of alkylpolyglycoside and fatty acid partial esters of glycerol such as the cheap rate offered by the company Cognis Plantatex ® LLE, the invention can be used.
• more care and conditioning agents used in cosmetic products can be used in the invention, such as that sold by Degussa under the trade name of Amilan ® 40 GST conditioning agent, which is a mixture of a C 12-14 fatty alcohol polyglycol ethers (having 3 ethylene oxide EO) units (INCI: Laureth-3) and a mixed ester of fatty acids and diacetyltartaric acid with glycerol (INCI: DATEM, for diacetyl tartrate esters of monoglycerides).
• Suitable skin affine refatting active ingredients are mixtures of long-chain alcohols and ethers, for example that available under the trade name Cetiol ® LDO from Cognis mixture of dicapryl ether, and lauryl alcohol.
• Polymers such as that sold under the trade name Aristoflex ® PEA / PEA 70 from Clariant polypropylene terephthalate, or long chain glycols, such as the polyglycol 35000S Clariant, a polyethylene glycol (INCI PEG-800), may also be used for the purposes of this invention as sensory agents.
• Preferably used plant extracts are preferably selected from the group comprising marigold extract ( Calendula officinalis ), green tea extract, almond extract, arnica extract ( Arnica montana ), hops extract ( Humulus lupulus ), balm extract ( Melissa officinalis ), gentian extract ( Gentiana lutea ), chamomile extract ( Matricaria chamomilla ) , Henna extract ( Lawsonia inermis ) and mixtures thereof.
• This marigold and green tea extract especially anti-inflammatory and able to calm the skin, the almond extract also has a smoothing and regenerating effect, the arnica extract, the anti-inflammatory effect is used, and the other plant extracts mentioned are able to soothe the skin in general and protect.
• Other usable skin-care extracts include, for example, aloe vera, witch hazel extract or algae extracts. However, most preferred are the extracts of marigold and green tea.
• the plant extracts in amounts of from 0 to 20 wt .-%, particularly preferably 0.01 to 5 wt .-% are used.
• the anionic surfactants are usually in situ as alkali metal, alkaline earth metal and / or mono-, di- or Trialkanolammoniumsalz and / or in the form of their with the corresponding alkali metal hydroxide, alkaline earth metal hydroxide and / or mono-, di- or trialkanolamine neutralizing corresponding acid used.
• Particularly preferred are the sodium salts.
• composition according to the invention comprises a surfactant combination comprising at least one alkyl ether sulfate and at least one secondary alkanesulfonate.
• aliphatic sulfates such as fatty alcohol sulfates, monoglyceride sulfates and ester sulfonates (sulfo fatty acid esters), lignosulfonates, alkylbenzenesulfonates, fatty acid cyanamides, anionic Sulfosuccinic acid surfactants, fatty acid isethionates, acylaminoalkanesulfonates (fatty acid taurides), fatty acid sarcosinates, ether carboxylic acids and alkyl (ether) phosphates.
• anionic surfactants are anionic gemini surfactants having a diphenyl oxide basic structure, 2 sulfonate groups and an alkyl radical on one or both benzene rings according to the formula O 3 S (C 6 H 3 R) O (C 6 H 3 R ') SO 3 -, in which R is an alkyl radical having, for example, 6, 10, 12 or 16 carbon atoms and R 'is R or H (Dowfax ® Dry hydrotropes Powder with C 16 alkyl radical (s); INCI Sodium Hexyldiphenyl ether sulfonates, Disodium decyl phenyl ether disulfonates, Disodium lauryl phenyl ether disulfonates, Disodium Cetyl phenyl ether disulfonates) and fluorinated anionic surfactants, in particular perfluorinated alkylsulfonates such as ammonium C 9/10 -Perfluoroalkylsulfonat
• Alkyl ether sulfates are products of sulfation reactions on alkoxylated alcohols.
• the person skilled in the art generally understands, under alkoxylated alcohols, the reaction products of alkylene oxide, preferably ethylene oxide, with alcohols, in the context of the present invention preferably with longer-chain alcohols, ie with aliphatic straight-chain or one or more branched, acyclic or cyclic, saturated or mono- or polyunsaturated, preferably straight-chain, acyclic, saturated, alcohols having 6 to 22, preferably 8 to 18, in particular 10 to 16 and particularly preferably 12 to 14 carbon atoms.
• a complex mixture of addition products of different degrees of ethoxylation is the use of mixtures of the alkylene oxides, preferably the mixture of ethylene oxide and propylene oxide.
• Very particularly preferred for the purposes of the present invention are low-ethoxylated fatty alcohols having 1 to 4 ethylene oxide units (EO), in particular 1 to 2 EO, for example 2 EO, such as Na-C 12-14 fatty alcohol + 2EO sulfate.
• the agent according to the invention comprises one or more alkyl ether sulfates in an amount of from 5 to 40% by weight, preferably from 8 to 35% by weight, in particular from 10 to 30% by weight.
• alkyl sulfonates usually have an aliphatic straight-chain or mono- or poly-branched, acyclic or cyclic, saturated or mono- or polyunsaturated, preferably branched, acyclic, saturated, alkyl radical having 6 to 22, preferably 9 to 20, in particular 11 to 18 and particularly preferably 14 to 17 carbon atoms.
• Suitable alkylsulfonates are accordingly the saturated alkanesulfonates, the unsaturated olefin sulfonates and the - formally based on the alkyl ether sulfates underlying alkoxylated Alcohol-diverting ether sulfonates comprising terminal ether sulfonates (n-ether sulfonates) having a sulfonate function attached to the polyether chain and internal ether sulfonates (i-ether sulfonates) having the sulfonate-linked alkyl group.
• alkanesulfonates in particular alkanesulfonates having a branched, preferably secondary, alkyl radical, for example the secondary alkanesulfonate sec. Na C 13-17 alkanesulfonate (INCI Sodium C14-17 Alkyl Sec Sulfonate).
• the agent according to the invention contains one or more sec. Alkyl sulfonates in an amount of up to 30 wt .-%, preferably 3 to 15 wt .-%, in particular 4 to 10 wt .-%.
• alkylbenzenesulfonates ABS for short, especially linear alkylbenzenesulfonates (LAS). These usually have the benzene ring in addition to a sulfonic acid or sulfonate also an aliphatic straight-chain or mono- or multi-branched, acyclic, saturated or mono- or polyunsaturated, alkyl side chain with 6 to 22, preferably 8 to 20, especially 10 to 16 and especially preferably 12 to 14 carbon atoms.
• LAS linear alkylbenzenesulfonates
• the salts are preferably alkali metal salts, ammonium salts and mono-, di- or.
• Trialkanolammoniumsalze for example mono-, di- or Triethanolammoniumsalze, in particular lithium, sodium, potassium or ammonium salts, more preferably sodium or ammonium salts, most preferably sodium salts.
• one or both carboxyl groups of the sulfosuccinic acid is preferably with one or two identical or different unbranched or branched, saturated or unsaturated, acyclic or cyclic, optionally alkoxylated alcohols having 4 to 22, preferably 6 to 20, in particular 8 to 18 , more preferably 10 to 16, most preferably 12 to 14 carbon atoms esterified.
• one or both form carboxyl groups of the sulfosuccinic acid preferably with a primary or secondary amine having one or two identical or different, unbranched or branched, saturated or unsaturated, acyclic or cyclic, optionally alkoxylated alkyl radicals having 4 to 22 , preferably 6 to 20, in particular 8 to 18, more preferably 10 to 16, most preferably 12 to 14 carbon atoms carries, a carboxylic acid amide.
• Particular preference is given to unbranched and / or saturated and / or acyclic alkyl radicals, in particular unbranched, saturated fatty alkyl radicals.
• Preferred anionic sulfosuccinic are imidosuccinate, mono-Na-sulfosuccinic acid diisobutyl ester (Monawet MB ® 45), mono-Na-sulfosuccinic acid di-octyl ester (Monawef ® MO-84 R2W, Rewopol SB ® DO 75), mono-Na sulfosuccinic acid di-tridecyl (Monawet ® MT 70) Fettalkoholpolyglykolsulfosuccinat-Na-NH 4 salt (sulfosuccinate S-2), di-Na-sulfosuccinic acid mono-C 12/14 3EO ester (Texapon ® SB-3) , Natriumsulfobernsteinkladiisooctylester (Texin DOS 75 ®) and di-sodium sulfosuccinic acid mono-C 12/18 ester
• betaines are the carbo-betaines, in particular the carbo-betaines of the formula (Ia) and (Ib), most preferably the alkylamido-betaines of the formula (Ib).
• suitable betaines and sulfobetaines are the following compounds designated as INCI: almondamidopropyl betaines, apricotamidopropyl betaines, avocadamidopropyl betaines, babassuamidopropyl betaines, behenamidopropyl betaines, behenyl betaines, betaines, canolamidopropyl betaines, caprylic / capramidopropyl betaines, carnitines, cetyl betaines, cocamidoethyl betaines, cocamidopropyl Betaines, cocamidopropyl hydroxysultaines, coco-betaines, coco-hydroxysultaines, coco / oleamido
• amphoteric surfactants (amphoteric surfactants, zwitterionic surfactants) which can be used according to the invention include alkylamidoalkylamines, alkyl-substituted amino acids, acylated amino acids or biosurfactants, of which the betaines are preferred within the scope of the teaching according to the invention.
• R 9 -CO-NH- (CH 2 ) 2 -N (R 11 ) -CH 2 CH 2 O-CH 2 -COOM (IIIa) R 9 is -CO-NH- (CH 2 ) 2 -N (R 11 ) -CH 2 CH 2 O-CH 2 CH 2 -COOM v R 9 -CO-NH- (CH 2 ) 2 -N (R 11 ) -CH 2 CH 2 O-CH 2 CH (OH) CH 2 -SO 3 M (IIIc) R 9 -CO-NH- (CH 2 ) 2 -N (R 11 ) -CH 2 CH 2 O-CH 2 CH (OH) CH 2 -OPO 3 HM (IIId) in which R 11 and M have the same meaning as in formula (III).
• capsules or pearls visible to the naked eye can also be produced.
• active ingredients incorporated in the hand dishwashing detergent according to the invention, an additional visual appeal when the capsules are suspended stable distributed on average, which can be realized by the selection of suitable surfactants and thickening agents and the setting of a suitable viscosity.
• the agent according to the invention may contain one or more additives from the group of surfactants, polymers and builders (builders), usually in an amount of 0.001 to 5% by weight, preferably 0, 01 to 4 wt .-%, in particular 0.1 to 3 wt .-%, particularly preferably 0.2 to 2 wt .-%, most preferably 0.5 to 1.5 wt .-%, for example 1 part by weight. %.
• Surfactants suitable as additives are certain of the amphoteric surfactants already described above, further anionic surfactants, nonionic surfactants and cationic surfactants, which are repeated at this point.
• the content of surface-active additives is preferably to be selected such that the total surfactant content is in the quantitative ranges set out above.
• composition according to the invention can be prepared by stirring the individual components together in any order.
• the order of attachment is not critical to the preparation of the agent.
• water, surfactants, active ingredients and optionally further of the aforementioned ingredients are stirred together. If perfume and / or dye are used, then their addition to the resulting solution. Subsequently, the pH is adjusted as described above.
• composition according to the invention can be used for cleaning hard surfaces, in particular for manual cleaning of dishes.
• active ingredients contained not only the items to be cleaned of stains, but also exerted a nourishing effect on the skin of the user.

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• Chemical & Material Sciences (AREA)
• Life Sciences & Earth Sciences (AREA)
• Engineering & Computer Science (AREA)
• Chemical Kinetics & Catalysis (AREA)
• Oil, Petroleum & Natural Gas (AREA)
• Wood Science & Technology (AREA)
• Organic Chemistry (AREA)
• Cosmetics (AREA)
• Detergent Compositions (AREA)

Applications Claiming Priority (2)

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• 2005
  • 2005-09-07 DE DE200510042603 patent/DE102005042603A1/de not_active Ceased
• 2006
  • 2006-09-05 WO PCT/EP2006/008639 patent/WO2007028571A1/de active Application Filing
  • 2006-09-05 ES ES06805649.8T patent/ES2454251T3/es active Active
  • 2006-09-05 EP EP06805649.8A patent/EP1941020B1/de not_active Not-in-force

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