EP1917337A1 - Compositions contenant des alcoxylates d'alcools gras - Google Patents

Compositions contenant des alcoxylates d'alcools gras

Info

Publication number
EP1917337A1
EP1917337A1 EP06776640A EP06776640A EP1917337A1 EP 1917337 A1 EP1917337 A1 EP 1917337A1 EP 06776640 A EP06776640 A EP 06776640A EP 06776640 A EP06776640 A EP 06776640A EP 1917337 A1 EP1917337 A1 EP 1917337A1
Authority
EP
European Patent Office
Prior art keywords
fatty alcohol
alcohol alkoxylates
formula
composition according
particularly preferably
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP06776640A
Other languages
German (de)
English (en)
Inventor
Franz-Xaver Scherl
Christian Sowa
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Clariant Produkte Deutschland GmbH
Original Assignee
Clariant Produkte Deutschland GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Clariant Produkte Deutschland GmbH filed Critical Clariant Produkte Deutschland GmbH
Publication of EP1917337A1 publication Critical patent/EP1917337A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/825—Mixtures of compounds all of which are non-ionic
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D19/00—Degasification of liquids
    • B01D19/02—Foam dispersion or prevention
    • B01D19/04—Foam dispersion or prevention by addition of chemical substances
    • B01D19/0404—Foam dispersion or prevention by addition of chemical substances characterised by the nature of the chemical substance
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
    • C09K23/017—Mixtures of compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/40—Monoamines or polyamines; Salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/835—Mixtures of non-ionic with cationic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/42—Amino alcohols or amino ethers
    • C11D1/44—Ethers of polyoxyalkylenes with amino alcohols; Condensation products of epoxyalkanes with amines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/722—Ethers of polyoxyalkylene glycols having mixed oxyalkylene groups; Polyalkoxylated fatty alcohols or polyalkoxylated alkylaryl alcohols with mixed oxyalkylele groups

Definitions

  • the invention relates to compositions containing
  • fatty alcohol alkoxylates, end-capped fatty alcohol alkoxylates and alkoxylates based on synthetic starting alcohols or on alcohols of native origin are to be described uniformly under the term "fatty alcohol alkoxylates".
  • fatty alcohol alkoxylates and alkoxylates based on synthetic starting alcohols as nonionic surfactant, foam suppressant, wetting and dispersing agents is known.
  • this class of substance is widely used as an effective agent in agrochemical formulations, as described in DE 101 18 076.
  • a particular group of fatty alcohol alkoxylates are the end-capped fatty alcohol alkoxylates.
  • the terminal hydroxy group of the fatty alcohol alkoxylates is reacted with alkylating agents such as dimethyl sulfate or methyl chloride or other alkyl esters or alkyl halides, thereby masking the OH function.
  • alkylating agents such as dimethyl sulfate or methyl chloride or other alkyl esters or alkyl halides
  • formulations containing fatty alcohol alkoxylates or end-capped fatty alcohol alkoxylates may be limited in their stability, so that efforts are made to reduce the pH values of fatty alcohol alkoxylates or end-capped fatty alcohol alkoxylates or of formulations containing fatty alcohol alkoxylates or end-capped fatty alcohol alkoxylates by prolonged storage in a temperature range of from -20 0 C to +50 0 C to prevent.
  • the invention relates to compositions containing
  • R 1 represents a linear or branched, saturated or unsaturated alkyl group having 6 to 30 and preferably 8 to 22 carbon atoms or a cyclic alkyl radical having 5 to 6 carbon atoms
  • OA 1 , OA 2 and OA 3 each independently represent an alkyleneoxy group, preferably an ethyleneoxy (EO), propyleneoxy (PO) or butyleneoxy group (BO), and in the event that the grouping is - (OA 1 ) ⁇ (OA 2 ) y (OA 3 ) z - consists of different alkyleneoxy groups, preferably of EO and PO groups, the alkyleneoxy groups can be arranged block-wise or randomly distributed,
  • the indices x, y and z each independently of one another represent a number from 0 to 50, preferably from 0 to 25 and particularly preferably from 0 to 15,
  • the sum x + y + z is a number from 1 to 150, preferably from 2 to 75 and more preferably from 3 to 30, and
  • R 2 is hydrogen -H or an alkyl group having 1 to 8 carbon atoms, preferably methyl, ethyl, n-propyl, n-butyl, n-pentyl, n-hexyl, n-heptyl or n-octyl, for an alkenyl group 2 to 8 carbon atoms, preferably AIIyI, or an alkylaryl group having 6 to 10 carbon atoms, preferably an alkylaryl group having 7 or 8 carbon atoms and more preferably benzyl, and
  • R a, R b and R c which may be identical or different, are hydrogen -H, for niethyl, "vo7zügiller 8 to 22 and particularly preferably 8 to 18 carbon atoms, a linear or branched alkenyl radical having 2 to 30, preferably 8 to 22 and particularly preferably 8 to 18 carbon atoms, for an aryl group, preferably phenyl or naphthyl, or an alkylaryl group, preferably benzyl,
  • OA a , OA b and A C O each independently represent an alkyleneoxy group, preferably an ethyleneoxy (EO), propyleneoxy (PO) or
  • Butylenoxy distru (BO), or for a group consisting of EO and PO groups and in which the Alkylenoxy phenomenon may be arranged block-wise or randomly distributed, stand,
  • indices a, b and c are each independently a number from 0 to 50, preferably from 0 to 25 and more preferably from 0 to 15, and
  • the sum a + b + c is a number from 0 to 150, preferably from 0 to 75 and more preferably from 0 to 30.
  • compositions of the invention comprise one or more fatty alcohol alkoxylates or end-capped fatty alcohol alkoxylates of formula (I) wherein R 1 is derived
  • alcohols of native origin having 6 to 22, preferably 8 to 22 and particularly preferably 12 to 22 carbon atoms, and particularly preferably derived from lauryl, coconut, palm oil, palm kernel, stearyl, oleyl, capron, capryl , Caprine, myristyl, cetyl, elaidyl, petroselinyl, arachyl, gadoleyl, behenyl, erucyl or brassidyl alcohol or
  • compositions according to the invention comprise one or more fatty alcohol alkoxylates or End-capped fatty alcohol alkoxylates of the formula (I) in which R 1 is derived from technical mixtures which are obtained, for example, in high pressure hydrogenations of technical methyl esters based on fats and oils or aldehydes from Roelen's oxosynthesis and as monomer fraction in the dimerization of unsaturated fatty alcohols.
  • compositions according to the invention contain one or more fatty alcohol alkoxylates or end-capped fatty alcohol alkoxylates of the formula (I) in which R 2 is -H or methyl and preferably methyl.
  • compositions according to the invention comprise one or more fatty alcohol alkoxylates or end-capped fatty alcohol alkoxylates of the formula (I) in which
  • R 1 is n-hexyl, n-heptyl, n-octyl, n-nonyl, n-decyl, n-undecyl, n-dodecyl, n-tridecyl, n-tetradecyl, n-pentadecyl, n-hexadecyl, n-octadecyl , i-hexyl, i-heptyl, i-octyl, i-nonyl, i-decyl, i-undecyl, i-dodecyl, i-tridecyl, i-tetradecyl, i-pentadecyl, i-hexadecyl or i-octadecyl,
  • OA 1 , OA 2 and OA 3 are ethyleneoxy or propyleneoxy groups, preferably ethyleneoxy groups,
  • the indices x, y and z are each, independently of one another, a number from 0 to 25, preferably 0 to 20 and particularly preferably 0 to 15,
  • the sum x + y + z is a number from 1 to 30, preferably from 4 to 20 and particularly preferably from 6 to 15, and
  • R 2 is -H 1 methyl, ethyl, propyl or -butyl, preferably -H or methyl and most preferably methyl.
  • the compositions according to the invention comprise one or more fatty alcohol alkoxylates or end-capped fatty alcohol alkoxylates of the formula (I) in which R 1 is a radical derived from isotridecyl alcohol of synthetic origin.
  • R 2 is preferably -H or methyl, and more preferably methyl.
  • compositions one or more fatty alcohol alkoxylates or end-capped fatty alcohol alkoxylates of the formula (I) wherein
  • OA 1 is ethyleneoxy
  • OA 2 is propyleneoxy
  • x and y are each independently a number from 0 to 25, preferably from 0 to 20 and particularly preferably from 0 to 15, z is the number 0 and the sum x + y + z is a number from 1 to 30, preferably from 4 to 20, and more preferably from 6 to 15.
  • compositions according to the invention comprise one or more fatty alcohol alkoxylates or end-capped fatty alcohol alkoxylates of the formula (I) embedded image in which
  • OA 1 is ethyleneoxy
  • x is a number from 1 to 25, preferably 4 to 20, and particularly preferably
  • compositions according to the invention contain one or more tertiary amines of the formula (II) in which
  • -RVR- and -R c which may be either or both of which are -H, n-hexyl, n-heptyl, n-octyl, n-nonyl, n-decyl, n-undecyl, n-dodecyl, n-tridecyl, n-tetradecyl, n-pentadecyl, n-hexadecyl, n-octadecyl, i-hexyl, i-heptyl, i-octyl, i-nonyl, i-decyl, i-undecyl, i-dodecyl, i-tridecyl, i-tetradecyl, i-pentadecyl, i-hexadecyl or i-octadecyl,
  • OA a , OA b and A C O represent ethyleneoxy or propyleneoxy groups, preferably ethyleneoxy groups
  • indices a, b and c are each a number from 0 to 10, and preferably from 0 to 6, and
  • a + b + c is a number from 0 to 30 and preferably 0 to 15.
  • compositions according to the invention comprise one or more tertiary amines of the formula (II) selected from tri-i-octylamine, tri-n-octylamine, tri-n-decylamine, tri- (n-octyl / n-decyl) amine, tri (i-octyl / n-decyl) amine and tri (n-octyl / i-octyl) amine.
  • tertiary amines of the formula (II) selected from tri-i-octylamine, tri-n-octylamine, tri-n-decylamine, tri- (n-octyl / n-decyl) amine, tri (i-octyl / n-decyl) amine and tri (n-octyl / i-octyl) amine.
  • compositions according to the invention contain one or more tertiary amines of the formula (II) selected from tri-i-octylamine, tri-n-octylamine, tri-n-decylamine and tri- (n-octyl / n-decyl) amine.
  • tri- (n-octyl / n-decyl) -amine denotes tertiary amines which contain both n-octyl and n-decyl bound to the nitrogen and wherein the nitrogen of the tertiary amine contains no residues other than n-octyl.
  • Octyl and n-decyl are bonded.
  • compositions according to the invention comprise one or more fatty alcohol alkoxylates or end-capped fatty alcohol alkoxylates of the formula (I) in which R 1 is isotridecyl, OA 1 -for -ethyleneoxy ppax for a number from 1 to 25, preferably 4 to 20 and especially prefers
  • R a , R b and R c are selected from n-octyl, i-octyl and n-decyl.
  • compositions according to the invention comprise from 95 to 99.9% by weight of one or more fatty alcohol alkoxylates or end-capped fatty alcohol alkoxylates of the formula (I) and from 0.1 to 5% by weight of one or more tertiary amines of the formula ( II), preferably from 98 to 99.9 wt .-% of one or more fatty alcohol alkoxylates or end-capped fatty alcohol alkoxylates of the formula (I) and from 0.1 to 2 wt .-% of one or more tertiary amines of the formula (II), particularly preferably from 98.5 to 99.75% by weight of one or more fatty alcohol alkoxylates or end-capped fatty alcohol alkoxylates of the formula (I) and from 0.25 to 1.5% by weight of one or more tertiary amines of the formula (II) and in particular preferably from 99 to 99.5% by weight of one or more fatty alcohol alkoxylates or
  • compositions according to the invention consist of one or more fatty alcohol alkoxylates or end-capped fatty alcohol alkoxylates of the formula (I) and one or more tertiary amines of the formula (II).
  • compositions according to the invention consist of one or more fatty alcohol alkoxylates or end-capped fatty alcohol alkoxylates of the formula (I) and one or more tertiary amines of the formula (II).
  • compositions according to the invention are advantageously suitable for use as surface-active agents, as foam-suppressing agents or as wetting and dispersing agents.
  • a further subject of the present invention is therefore the use of the compositions according to the invention as surface-active agents, as foam-suppressing agents or as wetting and dispersing agents.
  • compositions according to the invention can advantageously be used in detergents and cleaners, in particular as surface-active agents, as foam-suppressing agents or as wetting and dispersing agents.
  • compositions according to the invention in detergents and cleaners, in particular as surface-active agents, as foam-suppressing agents or as wetting and dispersing agents:
  • compositions according to the invention are advantageously suitable as effect enhancers in agrochemical formulations.
  • compositions according to the invention are therefore the use of the compositions according to the invention as effect enhancers in agrochemical formulations.
  • Fatty alcohol alkoxylates can be prepared by known methods by ethoxylation and / or propoxylation and / or butoxylation of the corresponding alcohols.
  • the fatty alcohol or oxo alcohol is presented, alkalized with 50 wt .-% NaOH, dried and then optionally alkoxylated at about 130 to 190 0 C sequentially.
  • End-capped fatty alcohol alkoxylates can also be prepared by known methods by alkalizing fatty alcohol alkoxylates with solid NaOH and then equimolar amounts of alkyl chloride are added at about 70 0 C. The course of the reaction can be checked by OH number.
  • fatty alcohol alkoxylates or end-capped fatty alcohol alkoxylates it is preferred to add from 0.1 to 5% by weight, particularly preferably from 0.1 to 2% by weight, of tertiary amine.
  • the fatty alcohol alkoxylate and the end-capped fatty alcohol alkoxylate to 30 to 7O 0 C, preferably at 50 ° C, and heated to a 30 ° to 70 ° C, preferably at 5O 0 C, warmed amine were added with stirring until the pH a 1 wt .-% solution in a 1: 1 mixture of ethanol / water to 8 to 9 is set.
  • the amine may also be added in the form of a solution, in particular in the form of alcoholic or aromatic solutions, and WZZOJIrrUlovJnM.r. ⁇ ,. _. f . __ ⁇ "
  • the preparation is carried out analogously to the preparation of Genapol 4739 from Genapol X 150. Since Genapol X 150 at room temperature solid, the filling is carried out of the autoclave at about 6O 0 C.
  • Genapol to 4739 warmed to 50 0 C, about 1 wt .-% Hostarex 327 are added with stirring.
  • the pH of the Genapol 4739 / Hostarex 327 blend in a 1 wt% solution in a 1: 1 mixture of ethanol / water is pH 8.5.
  • Genapol XM 150 heated to 50 0 C, about 1 wt .-% Hostarex 324 are added with stirring.
  • the pH of the Genapol XM 150 / Hostarex 324 mixture in a 1 wt.% Solution in a 1: 1 mixture of ethanol / water is pH 8.4.
  • Genapol X 060 isotridecyl alcohol polyglycol ether (6 EO)
  • Genapol 4739 isotridecyl alcohol polyglycol ⁇ -methyl ether (6 EO)
  • Genapol X 150 isotridecyl alcohol polyglycol ether (15 EO)
  • Genapol XM 150 isotridecyl alcohol polyglycol ⁇ -methyl ether (15 EO)
  • the pH is determined according to DIN EN 1262 with 1% by weight of active substance in a 1: 1 mixture of ethanol / water and a 3 point calibration with standard buffer solutions at pH 4.0, 7.0 and 9.0.
  • the specified measurement error is 0.2 pH units.
  • Tables 1 and 2 show the pH values of fatty alcohol ethoxylates with and without the addition of tertiary amine as a function of time.
  • Table 1 pH stability of fatty alcohol alkoxylates without and with tertiary amine at room temperature
  • Table 2 pH stability of fatty alcohol alkoxylates without and with tertiary amine at 50 0 C.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Dispersion Chemistry (AREA)
  • Environmental Sciences (AREA)
  • Materials Engineering (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Dentistry (AREA)
  • Zoology (AREA)
  • Agronomy & Crop Science (AREA)
  • Detergent Compositions (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Cosmetics (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)

Abstract

L'invention concerne des compositions qui contiennent a) un ou plusieurs alcoxylates d'alcools gras ou alcoxylates d'alcools gras à groupe terminal bloqué de formule (I), ainsi que b) une ou plusieurs amines tertiaires de formule (II). Les compositions selon l'invention peuvent être utilisées de manière avantageuse en tant qu'agents tensioactifs.
EP06776640A 2005-08-11 2006-08-05 Compositions contenant des alcoxylates d'alcools gras Withdrawn EP1917337A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102005037971A DE102005037971A1 (de) 2005-08-11 2005-08-11 Zusammensetzungen enthaltend Fettalkoholalkoxylate
PCT/EP2006/007775 WO2007017217A1 (fr) 2005-08-11 2006-08-05 Compositions contenant des alcoxylates d'alcools gras

Publications (1)

Publication Number Publication Date
EP1917337A1 true EP1917337A1 (fr) 2008-05-07

Family

ID=37198881

Family Applications (1)

Application Number Title Priority Date Filing Date
EP06776640A Withdrawn EP1917337A1 (fr) 2005-08-11 2006-08-05 Compositions contenant des alcoxylates d'alcools gras

Country Status (11)

Country Link
US (1) US20090286684A1 (fr)
EP (1) EP1917337A1 (fr)
JP (1) JP2009504818A (fr)
KR (1) KR20080041244A (fr)
CN (1) CN101263219A (fr)
BR (1) BRPI0615010A2 (fr)
CA (1) CA2618637A1 (fr)
DE (1) DE102005037971A1 (fr)
IL (1) IL189255A0 (fr)
MX (1) MX2008001938A (fr)
WO (1) WO2007017217A1 (fr)

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WO2011113786A2 (fr) 2010-03-17 2011-09-22 Basf Se Composition comprenant un pesticide et un alcoxylate d'isononylamine
US9258996B2 (en) 2010-03-17 2016-02-16 Basf Se Composition comprising a pesticide and an alkoxylate of iso-nonylamine
EA022869B1 (ru) 2011-02-28 2016-03-31 Басф Се Композиция, содержащая пестицид, сурфактант и алкоксилат 2-пропилгептиламина
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MX2015013026A (es) * 2013-03-15 2016-01-22 Croda Inc Alquileteres de alcoholes grasos alcoxilados y productos que los contienen.
WO2016060915A1 (fr) * 2014-10-16 2016-04-21 Dow Global Technologies Llc Éthoxylate d'amine grasse dans des huiles de moteur à base de glycol de polyalkylène
US10130092B2 (en) 2014-12-02 2018-11-20 Dow Global Technologies Llc Solid adjuvant defoamer
JP2018535819A (ja) 2015-10-07 2018-12-06 エレメンティス スペシャルティーズ，インコーポレイテッド．， 湿潤及び消泡剤
WO2017201752A1 (fr) * 2016-05-27 2017-11-30 Dow Global Technologies Llc Agent anti-moussage et compositions à base de celui-ci
CN106076190B (zh) * 2016-06-03 2018-10-09 山东转化科技有限公司 双子烷基胺醚琥珀磺酸盐表面活性剂及其制备方法
JP6807957B2 (ja) * 2016-06-16 2021-01-06 ダウ グローバル テクノロジーズ エルエルシー 斑点防止界面活性剤を含む自動食器洗浄組成物
JP7042684B2 (ja) * 2018-05-08 2022-03-28 日本化薬株式会社 インクセット及びインクジェット記録方法
EP3821709A4 (fr) * 2018-07-05 2022-04-13 Kao Corporation Composition herbicide
CN110699189B (zh) * 2019-11-06 2021-04-27 3M中国有限公司 车用洗涤组合物以及洗涤车辆的方法

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CN101263219A (zh) 2008-09-10
KR20080041244A (ko) 2008-05-09
BRPI0615010A2 (pt) 2011-05-03
JP2009504818A (ja) 2009-02-05
MX2008001938A (es) 2008-03-26
CA2618637A1 (fr) 2007-02-15
US20090286684A1 (en) 2009-11-19
WO2007017217A1 (fr) 2007-02-15
DE102005037971A1 (de) 2007-02-15
IL189255A0 (en) 2008-08-07

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