JP6117928B2 - アルコキシレート組成物および農業アジュバントとしてのそれらの使用 - Google Patents
アルコキシレート組成物および農業アジュバントとしてのそれらの使用 Download PDFInfo
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- JP6117928B2 JP6117928B2 JP2015533404A JP2015533404A JP6117928B2 JP 6117928 B2 JP6117928 B2 JP 6117928B2 JP 2015533404 A JP2015533404 A JP 2015533404A JP 2015533404 A JP2015533404 A JP 2015533404A JP 6117928 B2 JP6117928 B2 JP 6117928B2
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- 239000000203 mixture Substances 0.000 title claims description 86
- 239000002671 adjuvant Substances 0.000 title claims description 11
- 239000004094 surface-active agent Substances 0.000 claims description 40
- 238000009472 formulation Methods 0.000 claims description 28
- 239000004480 active ingredient Substances 0.000 claims description 26
- -1 propyleneoxy Chemical group 0.000 claims description 23
- 241000196324 Embryophyta Species 0.000 claims description 17
- 239000004546 suspension concentrate Substances 0.000 claims description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 16
- 238000000034 method Methods 0.000 claims description 12
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 11
- 125000000217 alkyl group Chemical group 0.000 claims description 10
- 239000004530 micro-emulsion Substances 0.000 claims description 7
- 239000007787 solid Substances 0.000 claims description 7
- 239000007788 liquid Substances 0.000 claims description 6
- 239000007764 o/w emulsion Substances 0.000 claims description 6
- 239000004562 water dispersible granule Substances 0.000 claims description 5
- 239000000080 wetting agent Substances 0.000 claims description 5
- 241000238631 Hexapoda Species 0.000 claims description 4
- 201000010099 disease Diseases 0.000 claims description 4
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 claims description 4
- 239000000417 fungicide Substances 0.000 claims description 4
- 239000004009 herbicide Substances 0.000 claims description 4
- 239000002518 antifoaming agent Substances 0.000 claims description 3
- 239000002270 dispersing agent Substances 0.000 claims description 3
- 235000013399 edible fruits Nutrition 0.000 claims description 3
- 239000003995 emulsifying agent Substances 0.000 claims description 3
- 230000000855 fungicidal effect Effects 0.000 claims description 3
- 239000001963 growth medium Substances 0.000 claims description 3
- 230000002363 herbicidal effect Effects 0.000 claims description 3
- 239000002917 insecticide Substances 0.000 claims description 3
- 239000003002 pH adjusting agent Substances 0.000 claims description 3
- 239000002689 soil Substances 0.000 claims description 3
- 239000002562 thickening agent Substances 0.000 claims description 3
- 238000009736 wetting Methods 0.000 description 8
- 239000003905 agrochemical Substances 0.000 description 7
- 239000000725 suspension Substances 0.000 description 7
- 239000003054 catalyst Substances 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 5
- 239000003090 pesticide formulation Substances 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical class [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- 239000004495 emulsifiable concentrate Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000000575 pesticide Substances 0.000 description 4
- 239000004550 soluble concentrate Substances 0.000 description 4
- PXMNMQRDXWABCY-UHFFFAOYSA-N 1-(4-chlorophenyl)-4,4-dimethyl-3-(1H-1,2,4-triazol-1-ylmethyl)pentan-3-ol Chemical group C1=NC=NN1CC(O)(C(C)(C)C)CCC1=CC=C(Cl)C=C1 PXMNMQRDXWABCY-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000005839 Tebuconazole Substances 0.000 description 3
- 125000002947 alkylene group Chemical group 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 239000008187 granular material Substances 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- WQDUMFSSJAZKTM-UHFFFAOYSA-N Sodium methoxide Chemical compound [Na+].[O-]C WQDUMFSSJAZKTM-UHFFFAOYSA-N 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000012669 liquid formulation Substances 0.000 description 2
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 235000011118 potassium hydroxide Nutrition 0.000 description 2
- 235000011121 sodium hydroxide Nutrition 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- 239000004563 wettable powder Substances 0.000 description 2
- QNBTYORWCCMPQP-JXAWBTAJSA-N (Z)-dimethomorph Chemical compound C1=C(OC)C(OC)=CC=C1C(\C=1C=CC(Cl)=CC=1)=C/C(=O)N1CCOCC1 QNBTYORWCCMPQP-JXAWBTAJSA-N 0.000 description 1
- ZOCSXAVNDGMNBV-UHFFFAOYSA-N 5-amino-1-[2,6-dichloro-4-(trifluoromethyl)phenyl]-4-[(trifluoromethyl)sulfinyl]-1H-pyrazole-3-carbonitrile Chemical compound NC1=C(S(=O)C(F)(F)F)C(C#N)=NN1C1=C(Cl)C=C(C(F)(F)F)C=C1Cl ZOCSXAVNDGMNBV-UHFFFAOYSA-N 0.000 description 1
- 239000005730 Azoxystrobin Substances 0.000 description 1
- TWFZGCMQGLPBSX-UHFFFAOYSA-N Carbendazim Natural products C1=CC=C2NC(NC(=O)OC)=NC2=C1 TWFZGCMQGLPBSX-UHFFFAOYSA-N 0.000 description 1
- 239000005747 Chlorothalonil Substances 0.000 description 1
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 description 1
- 239000005761 Dimethomorph Substances 0.000 description 1
- 239000005894 Emamectin Substances 0.000 description 1
- 239000005899 Fipronil Substances 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000005906 Imidacloprid Substances 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 1
- 239000005843 Thiram Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 239000003125 aqueous solvent Substances 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- 239000003849 aromatic solvent Substances 0.000 description 1
- MXWJVTOOROXGIU-UHFFFAOYSA-N atrazine Chemical compound CCNC1=NC(Cl)=NC(NC(C)C)=N1 MXWJVTOOROXGIU-UHFFFAOYSA-N 0.000 description 1
- WFDXOXNFNRHQEC-GHRIWEEISA-N azoxystrobin Chemical compound CO\C=C(\C(=O)OC)C1=CC=CC=C1OC1=CC(OC=2C(=CC=CC=2)C#N)=NC=N1 WFDXOXNFNRHQEC-GHRIWEEISA-N 0.000 description 1
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 1
- 239000006013 carbendazim Substances 0.000 description 1
- JNPZQRQPIHJYNM-UHFFFAOYSA-N carbendazim Chemical compound C1=C[CH]C2=NC(NC(=O)OC)=NC2=C1 JNPZQRQPIHJYNM-UHFFFAOYSA-N 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- CRQQGFGUEAVUIL-UHFFFAOYSA-N chlorothalonil Chemical compound ClC1=C(Cl)C(C#N)=C(Cl)C(C#N)=C1Cl CRQQGFGUEAVUIL-UHFFFAOYSA-N 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000005343 cylinder glass Substances 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- CXEGAUYXQAKHKJ-NSBHKLITSA-N emamectin B1a Chemical compound C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](NC)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 CXEGAUYXQAKHKJ-NSBHKLITSA-N 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 229940013764 fipronil Drugs 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000005337 ground glass Substances 0.000 description 1
- YWTYJOPNNQFBPC-UHFFFAOYSA-N imidacloprid Chemical compound [O-][N+](=O)\N=C1/NCCN1CC1=CC=C(Cl)N=C1 YWTYJOPNNQFBPC-UHFFFAOYSA-N 0.000 description 1
- 229940056881 imidacloprid Drugs 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- RPDAUEIUDPHABB-UHFFFAOYSA-N potassium ethoxide Chemical compound [K+].CC[O-] RPDAUEIUDPHABB-UHFFFAOYSA-N 0.000 description 1
- BDAWXSQJJCIFIK-UHFFFAOYSA-N potassium methoxide Chemical compound [K+].[O-]C BDAWXSQJJCIFIK-UHFFFAOYSA-N 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- QDRKDTQENPPHOJ-UHFFFAOYSA-N sodium ethoxide Chemical compound [Na+].CC[O-] QDRKDTQENPPHOJ-UHFFFAOYSA-N 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000002459 sustained effect Effects 0.000 description 1
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 description 1
- 229960002447 thiram Drugs 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/10—Aromatic or araliphatic carboxylic acids, or thio analogues thereof; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/34—Nitriles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/50—1,3-Diazoles; Hydrogenated 1,3-diazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/50—1,3-Diazoles; Hydrogenated 1,3-diazoles
- A01N43/52—1,3-Diazoles; Hydrogenated 1,3-diazoles condensed with carbocyclic rings, e.g. benzimidazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/66—1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms
- A01N43/68—1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms with two or three nitrogen atoms directly attached to ring carbon atoms
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/84—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,4
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/24—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing the groups, or; Thio analogues thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/32—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing >N—CO—N< or >N—CS—N< groups directly attached to a cycloaliphatic ring
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Dentistry (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Catching Or Destruction (AREA)
Description
(a)式Iのアルコキシレートであって、
R1O−(AO)x−(EO)y−H (I)
式中、AOが、プロピレンオキシまたはブチレンオキシであり、EOが、エチレンオキシであり、R1が、直鎖状または分岐状C4〜C10アルキルであり、xが、1〜11の実数であり、yが、1〜20の実数である、式Iのアルコキシレートと、
(b)式IIのアルコキシレートであって、
R2O−(EO)r−(PO)p−(EO)q−H (II)
式中、EOが、エチレンオキシであり、POが、プロピレンオキシであり、R2が、H、または直鎖状または分岐状C1〜C6アルキルであり、rが、1〜40の実数であり、pが、1〜60の実数であり、qが、1〜50の実数である、式IIのアルコキシレートと、を含む。
R1O−(AO)x−(EO)y−H (I)
式中、AOは、プロピレンオキシまたはブチレンオキシであり、EOは、エチレンオキシであり、R1は、直鎖状または分岐状C4〜C10アルキルであり、xは、1〜11の実数であり、yは、1〜20の実数である。
R2O−(EO)r−(PO)p−(EO)q−H (II)
式中、EOは、エチレンオキシであり、POは、プロピレンオキシであり、R2は、H、または直鎖状または分岐状C1〜C6アルキルであり、rは、1〜40の実数であり、pは、1〜60の実数であり、qは、1〜50の実数である。
流動点法。界面活性剤の重要な性能測定基準は、湿潤性能である。湿潤性能を評価するために、流動点法と称される方法が農薬実践者によって広く用いられている。この方法のプロセスは、1)2g、5g等のある特定の量の農業活性成分を調製し、2)5%界面活性剤水溶液を調製し、3)この界面活性剤溶液を活性成分に滴加すると同時に、ガラス棒で活性成分を撹拌および製粉し、4)湿潤性能が良好である場合、活性成分が液体のようにガラス棒から自由に落下する。活性成分を液体のように流動させ得る界面活性剤溶液の量を、この種の界面活性剤の流動点と定義する。界面活性剤が活性成分を効果的に湿潤させることができない場合、流動点は現れない。
1)農薬製剤安定性を標準の方法(CIPAC MT39.3、MT46.3)に従って試験する。農薬試料を54℃で2週間、および0℃で1週間保存する。保存後、この製剤を明らかな外観変化および/または活性成分分解について観察する。
2)持続性発泡体積をCIPAC MT 47に従って評価する。この試験は、農薬試料の発泡特性を評価する。値を試験するために、250mLの限度容量で栓をした目盛り付きシリンダーガラスを用いる。0マークと250mLマークとの間の距離は、20〜21.5cmであり、250mLマークと栓の底面との間の距離は、約4〜6cmである。約180mLの標準水および1gの試料を受け皿付き天秤(top pan balance)上に位置する250mLの計量用シリンダーに注ぐ。表面とすりガラス接合部の底面との間の距離が9.0±0.1cmになるまで標準水で満たす。シリンダーに栓をし、30回反転させる。栓をしたシリンダーをベンチに直立に設置し、即座にストップウオッチを起動させる。生成された発泡体の体積と1分後に残留している体積を読み取る。
3)懸濁度をCIPAC MT161、MT 184に従って評価する。懸濁度とは、水中に希釈した後の農薬製剤試料の懸濁能力を評価するためのものである。値を試験するために、0.5±0.0002gの農薬製剤試料を、250mLの目盛り付きシリンダー中の100mLの標準水(約342ppmのCa2+およびMg2+を含有する)に30±2℃で添加する。250mLマークに達するまで標準水(342ppm)で満たす。このシリンダーを1分以内に30回反転させる。シリンダーを30±2℃の水基剤中に30分間静置する。上の9/10の懸濁液を除去する。残りの1/10懸濁液の水を蒸発させた後、残留物を秤量し、懸濁度を計算する。
4)pH値をCIPAC MT 75.3に従って試験する。pH値を試験するために、1gの農薬製剤試料を100mLの脱イオン水で希釈する。
以下の物質を以下の実施例で用いる:
アルコキシレート1:2−エチルヘキシル−O−(CH2CH(CH3)−O)5.5−(CH2CH2O)6−H
アルコキシレート2:ブチル−O−(EO)3.2−(PO)37.5−(EO)33.6−H
TERSPERSE(商標)4896:Huntsman社の湿潤および分散アジュバント
AEO−5:5EO単位を含有する第1級C10〜16アルコールエトキシレート
がって、0℃および54℃で保存した後の比較実施例7の懸濁率85.90%および51
.83%は、基準を満たさない。
本開示は以下も包含する。
[1]
界面活性剤ブレンドであって、
(a)式Iのアルコキシレートであって、
R 1 O−(AO) x −(EO) y −H (I)
式中、AOが、プロピレンオキシまたはブチレンオキシであり、EOが、エチレンオキシであり、R 1 が、直鎖状または分岐状C 4 〜C 10 アルキルであり、xが、1〜11の実数であり、yが、1〜20の実数である、式Iのアルコキシレートと、
(b)式IIのアルコキシレートであって、
R 2 O−(EO) r −(PO) p −(EO) q −H (II)
式中、EOが、エチレンオキシであり、POが、プロピレンオキシであり、R 2 が、H、または直鎖状または分岐状C 1 〜C 6 アルキルであり、rが、1〜40の実数であり、pが、1〜60の実数であり、qが、1〜50の実数である、式IIのアルコキシレートと、を含む、界面活性剤ブレンド。
[2]
R 1 が、直鎖状または分岐状C 6 〜C 10 アルキルである、上記態様1に記載の界面活性剤ブレンド。
[3]
R 1 が、2−エチルヘキシルまたは2−プロピルヘプチルである、上記態様1または2に記載の界面活性剤ブレンド。
[4]
R 2 が、直鎖状または分岐状C 2 〜C 4 アルキルである、上記態様1〜3のいずれかに記載の界面活性剤ブレンド。
[5]
式Iのアルコキシレートと式IIのアルコキシレートの重量比が、9:1〜1:9である、上記態様1〜4のいずれかに記載の界面活性剤ブレンド。
[6]
農業組成物であって、
アジュバントとして上記態様1〜5のいずれかに記載の界面活性剤ブレンドと、
農業活性成分と、
水と、を含む、農業組成物。
[7]
前記農業活性成分が、除草剤、殺虫剤、殺菌剤、またはこれらの2つ以上の混合物である、上記態様6に記載の農業組成物。
[8]
懸濁濃縮物、水中油型エマルジョン、マイクロエマルジョン、または水分散性顆粒である、上記態様6〜7のいずれかに記載の農業組成物。
[9]
湿潤剤、分散剤、乳化剤、増粘剤、消泡剤、およびpH調節剤の1つ以上をさらに含む、上記態様6〜8のいずれかに記載の農業組成物。
[10]
昆虫、植物病害、または雑草を制御する方法であって、上記態様8〜11のいずれかに記載の農業組成物を含む製剤を提供することと、前記製剤を、植物、植物の葉、花、幹、果実、前記植物に隣接した領域、土壌、種子、発芽種子、根、液体および固体成長培地、ならびに水耕成長溶液の少なくとも1つに適用することと、を含む、方法。
Claims (9)
- 界面活性剤ブレンドであって、
(a)式Iのアルコキシレートであって、
R1O−(AO)x−(EO)y−H (I)
式中、AOが、プロピレンオキシまたはブチレンオキシであり、EOが、エチレンオキシであり、R1が、直鎖状または分岐状C4〜C10アルキルであり、xが、1〜11の実数であり、yが、1〜20の実数である、式Iのアルコキシレートと、
(b)式IIのアルコキシレートであって、
R2O−(EO)r−(PO)p−(EO)q−H (II)
式中、EOが、エチレンオキシであり、POが、プロピレンオキシであり、R2が、直鎖状または分岐状C1〜C6アルキルであり、rが、1〜40の実数であり、pが、1〜60の実数であり、qが、1〜50の実数である、式IIのアルコキシレートと、を含み、
式Iのアルコキシレートと式IIのアルコキシレートの重量比が、9:1〜1:9である、界面活性剤ブレンド。 - R1が、直鎖状または分岐状C6〜C10アルキルである、請求項1に記載の界面活性剤ブレンド。
- R1が、2−エチルヘキシルまたは2−プロピルヘプチルである、請求項1または2に記載の界面活性剤ブレンド。
- R2が、直鎖状または分岐状C2〜C4アルキルである、請求項1〜3のいずれか一項に記載の界面活性剤ブレンド。
- 農業組成物であって、
アジュバントとして請求項1〜4のいずれか一項に記載の界面活性剤ブレンドと、
農業活性成分と、
水と、を含む、農業組成物。 - 前記農業活性成分が、除草剤、殺虫剤、殺菌剤、またはこれらの2つ以上の混合物である、請求項5に記載の農業組成物。
- 懸濁濃縮物、水中油型エマルジョン、マイクロエマルジョン、または水分散性顆粒である、請求項5または6に記載の農業組成物。
- 湿潤剤、分散剤、乳化剤、増粘剤、消泡剤、およびpH調節剤の1つ以上をさらに含む、請求項5〜7のいずれか一項に記載の農業組成物。
- 昆虫、植物病害、または雑草を制御する方法であって、請求項5〜8のいずれか一項に記載の農業組成物を含む製剤を提供することと、前記製剤を、植物、植物の葉、花、幹、果実、前記植物に隣接した領域、土壌、種子、発芽種子、根、液体および固体成長培地、ならびに水耕成長溶液の少なくとも1つに適用することと、を含む、方法。
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