EP1872426A1 - Element galvanique - Google Patents

Element galvanique

Info

Publication number
EP1872426A1
EP1872426A1 EP06724078A EP06724078A EP1872426A1 EP 1872426 A1 EP1872426 A1 EP 1872426A1 EP 06724078 A EP06724078 A EP 06724078A EP 06724078 A EP06724078 A EP 06724078A EP 1872426 A1 EP1872426 A1 EP 1872426A1
Authority
EP
European Patent Office
Prior art keywords
substrate
galvanic element
electrodes
element according
electrolyte
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP06724078A
Other languages
German (de)
English (en)
Inventor
Konrad Holl
Martin Krebs
Hartmut Weidenbacher
Bernd Kreidler
Hermann LÖFFELMANN
Dejan Ilic
Magnus Berggren
Staffan Nordlinder
Linda Andersson
Lars-Olof Hennerdal
Anurak Sawatdee
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
VARTA Microbattery GmbH
Original Assignee
VARTA Microbattery GmbH
Acreo AB
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by VARTA Microbattery GmbH, Acreo AB filed Critical VARTA Microbattery GmbH
Publication of EP1872426A1 publication Critical patent/EP1872426A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/04Processes of manufacture in general
    • H01M4/0402Methods of deposition of the material
    • H01M4/0404Methods of deposition of the material by coating on electrode collectors
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/04Construction or manufacture in general
    • H01M10/0436Small-sized flat cells or batteries for portable equipment
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/04Processes of manufacture in general
    • H01M4/0402Methods of deposition of the material
    • H01M4/0414Methods of deposition of the material by screen printing
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10Primary casings; Jackets or wrappings
    • H01M50/102Primary casings; Jackets or wrappings characterised by their shape or physical structure
    • H01M50/103Primary casings; Jackets or wrappings characterised by their shape or physical structure prismatic or rectangular
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M6/00Primary cells; Manufacture thereof
    • H01M6/04Cells with aqueous electrolyte
    • H01M6/06Dry cells, i.e. cells wherein the electrolyte is rendered non-fluid
    • H01M6/12Dry cells, i.e. cells wherein the electrolyte is rendered non-fluid with flat electrodes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M6/00Primary cells; Manufacture thereof
    • H01M6/40Printed batteries, e.g. thin film batteries
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M6/00Primary cells; Manufacture thereof
    • H01M6/42Grouping of primary cells into batteries
    • H01M6/46Grouping of primary cells into batteries of flat cells
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T29/00Metal working
    • Y10T29/49Method of mechanical manufacture
    • Y10T29/49002Electrical device making
    • Y10T29/49108Electric battery cell making
    • Y10T29/49115Electric battery cell making including coating or impregnating

Definitions

  • a corresponding protection or a corresponding stabilization can also be realized in another way, for example by applying a film or a corresponding layer over the plane of the electrolyte, preferably imprinting it.
  • This layer is usually also made of plastic, d. H. is at least polymer-based.
  • FIG. 1 shows the schematic structure of a galvanic element according to the invention as a single cell with adjacent electrodes.
  • FIG. 2 shows the schematic structure of a galvanic element according to the invention with three individual cells
  • FIG. 3 shows the schematic structure of a galvanic element according to the invention with four individual cells (connected in series and in parallel)
  • FIG. 4 shows a schematic section of the production process for the construction of individual cells on an endless belt serving as a substrate.
  • Fig. 1 shows an inventive galvanic element in the form of a so-called single cell.
  • so-called collectors / arresters 3, 4 are applied to a flat substrate 1 in the form of an electrically non-conductive, thin plastic film 2.
  • These were applied to the substrate 1 in the form of electrically conductive pastes (preferably silver, copper, nickel, aluminum, indium, bismuth or graphite) and then dried.
  • electrically conductive pastes preferably silver, copper, nickel, aluminum, indium, bismuth or graphite
  • Such pastes may usually contain binders in the form of polymers, which may be thermally or chemically solidified, for example.
  • the application of the collectors / arresters 3, 4 is not limited to the application of electrically conductive pastes.
  • the collectors / arresters 3, 4 may be thin electrically conductive foils (metal foils, plastic foils filled with conductive materials). The connection of these films with the substrate 1 is preferably carried out by cold or hot bonding.
  • the collectors / arresters 3, 4 can also be represented by conventional metallization processes (vacuum deposition, sputtering, electrodeposition).
  • the cathode 5 ie, the corresponding electrode material
  • This application is preferably carried out with the aid of a printable paste.
  • the anode 6 ie the corresponding electrode material
  • Both the cathode 5 and the anode 6 are electrically contacted with the collectors / arresters 3, 4.
  • the electrodes there is a gel-like electrolyte 7, which is fixed with a net structure or a fleece 8.
  • the electrolyte 7 with the nonwoven 8 covers the active electrode material of the cathode 5 and the anode 6.
  • the substrate 1 and the plastic film 2 form a tightly closing housing for the functional components located between the substrate 1 and the plastic film 2, namely the actual electrodes (5, 3, 6, 4).
  • FIG. 2 shows the schematic structure of a galvanic element (battery) in which three individual cells with electrodes lying side by side in pairs (ie, three individual cells according to FIG. 1) are connected to one another via electrically conductive paths (printed conductors 9). Thereby higher voltages can be realized.
  • Such series circuits can lead to galvanic elements with voltages of 30 V and higher, which can be produced according to the invention particularly inexpensive and easy.
  • FIG. 3 the schematic structure of a galvanic element (battery) is shown in four individual cells (see FIG. 1) with electrodes lying side by side in pairs. These four single cells are connected both in series and in parallel. Through this construction, different total voltages and capacities or load capacities can be achieved.
  • Fig. 4 shows schematically a section of the production process according to the invention.
  • the galvanic elements according to the invention can be produced endlessly (as shown) on a substrate 12 (carrier tape) in the form of an endless belt or even in multiple rows (not shown).
  • the conductor tracks 10 and 11 serving as collectors / arresters are already applied to the substrate 12 prior to the actual production process of the single cell.
  • the actual electrodes or the corresponding electrode material are applied to the printed conductors 10 and 11 at the locations provided for this purpose.
  • the application of the electrolyte which is stabilized as a gel-like electrolyte with a nonwoven takes place. Due to the reference to FIG.
  • both the substrate 12 and the cover sheet 13 can be made of self-adhesive films. This facilitates, on the one hand, the application of the cover film to the single cell which has been completed in each case. On the other hand, it is possible, if appropriate after separation of the individual cells produced, to mount the substrate 12 directly by gluing on, for example, a printed circuit board without additional adhesive.
  • plastic films with low gas and water vapor diffusion rate are preferred, d. H. in particular made of PET, PP or PE. If it is intended to heat-seal these films together later, the provided base films can be laminated with a low-melting additional material. Here it can be z. B. to act a hot melt adhesive from a copolymer based on PE.
  • the electrolyte is applied in a further process step.
  • the electrolyte is preferably a gelatinous paste. This consists, for example, of an aqueous solution of zinc chloride, it being possible for this solution to be completely or partially predried.
  • the application of the electrolyte is also preferably carried out by a printing process.
  • the electrolyte covers (as shown in Fig. 1) both electrodes over the entire surface.
  • the electrolyte may be reinforced and stabilized by a non-woven or net-like material.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Connection Of Batteries Or Terminals (AREA)
  • Primary Cells (AREA)
  • Sealing Battery Cases Or Jackets (AREA)
  • Secondary Cells (AREA)

Abstract

L'invention concerne un élément galvanique comportant au moins une électrode positive et une électrode négative (5, 6) disposées l'une à côté de l'autre sur un substrat isolant plat (1), et connectées par un électrolyte conduisant les ions. Des cellules individuelles peuvent être branchées mutuellement du fait qu'une pluralité d'électrodes positives et d'électrodes négatives sont disposées les unes à côté des autres par paires sur le substrat.
EP06724078A 2005-04-08 2006-04-06 Element galvanique Withdrawn EP1872426A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102005017682A DE102005017682A1 (de) 2005-04-08 2005-04-08 Galvanisches Element
PCT/EP2006/003132 WO2006105966A1 (fr) 2005-04-08 2006-04-06 Element galvanique

Publications (1)

Publication Number Publication Date
EP1872426A1 true EP1872426A1 (fr) 2008-01-02

Family

ID=36607544

Family Applications (1)

Application Number Title Priority Date Filing Date
EP06724078A Withdrawn EP1872426A1 (fr) 2005-04-08 2006-04-06 Element galvanique

Country Status (6)

Country Link
US (1) US20100081049A1 (fr)
EP (1) EP1872426A1 (fr)
JP (1) JP2008535194A (fr)
CN (2) CN101194385B (fr)
DE (1) DE102005017682A1 (fr)
WO (1) WO2006105966A1 (fr)

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Also Published As

Publication number Publication date
CN101194385A (zh) 2008-06-04
CN101194385B (zh) 2013-04-17
WO2006105966A1 (fr) 2006-10-12
CN103000914A (zh) 2013-03-27
DE102005017682A1 (de) 2006-10-12
JP2008535194A (ja) 2008-08-28
US20100081049A1 (en) 2010-04-01

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