EP1829956A1 - Pièce à laver à l'aide de détergents synthétiques - Google Patents

Pièce à laver à l'aide de détergents synthétiques Download PDF

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Publication number
EP1829956A1
EP1829956A1 EP07003951A EP07003951A EP1829956A1 EP 1829956 A1 EP1829956 A1 EP 1829956A1 EP 07003951 A EP07003951 A EP 07003951A EP 07003951 A EP07003951 A EP 07003951A EP 1829956 A1 EP1829956 A1 EP 1829956A1
Authority
EP
European Patent Office
Prior art keywords
washing piece
weight
piece according
washing
fatty alcohol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP07003951A
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German (de)
English (en)
Other versions
EP1829956B1 (fr
Inventor
Joachim Dr. Gottfreund
Thomas Dipl.-Ing. Meyer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sebapharma & Co GmbH
Original Assignee
Sebapharma & Co GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sebapharma & Co GmbH filed Critical Sebapharma & Co GmbH
Publication of EP1829956A1 publication Critical patent/EP1829956A1/fr
Application granted granted Critical
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Active legal-status Critical Current
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2006—Monohydric alcohols
    • C11D3/201—Monohydric alcohols linear
    • C11D3/2013—Monohydric alcohols linear fatty or with at least 8 carbon atoms in the alkyl chain
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/37—Mixtures of compounds all of which are anionic
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0047—Detergents in the form of bars or tablets
    • C11D17/006—Detergents in the form of bars or tablets containing mainly surfactants, but no builders, e.g. syndet bar
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2093—Esters; Carbonates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/384—Animal products
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/04—Carboxylic acids or salts thereof
    • C11D1/10—Amino carboxylic acids; Imino carboxylic acids; Fatty acid condensates thereof

Definitions

  • the invention relates to a Syndetwasch Division Multiple Access (SBA) Program.
  • Syndetwasch Division Multiple Access (MEC) Program with cleansing and skin care property based on at least one or more synthetic surfactants as detergent ingredients.
  • Syndetasch Such Syndetasch conductede have long been known.
  • the term "syndet” is derived from “synthetic detergent”. This is understood to mean soap-like pieces, which are mostly used for body cleansing or cleansing of the skin.
  • anionic, amphoteric or non-ionic surfactants are usually used, wherein the dermatological properties of a Syndetasch publishedes also depend substantially on the particular surfactant used.
  • the wash should have virtually no tendency to undesirable changes in the external appearance such as color changes or crystallization of constituents and thus have a high long-term stability even in the presence of moisture.
  • microcrystalline waxes and / or paraffin waxes have been used variously, but these have only an inadequate skin compatibility.
  • the washing piece in the washing process should have a certain water absorption and adapted dissolving properties, so that during the usual washing process, a sufficient amount of syndet is dissolved by the water and unfolds its washing action.
  • "shrinkage" of the wash piece which is the property of the laundry is understood that in contact with water (eg when stored in the soap dish), the outer areas in a soft, swollen state, which no longer Cleaning can be used and represents an undesirable abrasion.
  • the swollen (mop) surface layer can then be removed manually or mechanically easily from the unswollen core of a syndet piece.
  • the invention has for its object to provide a Syndusch Faculty which solves the above objects, in particular has a high long-term stability even in the presence of moisture and very good Versumpfungseigenschaften and at the same time has a very good skin compatibility and very pleasant handling properties, is particularly tolerated by the skin and washing is perceived by the consumer as pleasant.
  • a washing piece according to claim 1 which contains constituents which form a homogeneous wax melt with a melting point of 50-60 °, or by a washing piece containing such homogeneous wax.
  • the wax forming the melt can also be homogeneous and long-term stable at room temperature.
  • Beeswax, fatty acid esters c) and fatty alcohols d), to which the above statements apply, may be provided as constituents which form a homogeneous wax melt.
  • the presence of such homogeneous wax melts is furthermore particularly advantageous since it is then possible to dispense as far as possible or completely with the presence of paraffins or paraffin waxes and / or of microcrystalline waxes in the composition.
  • the skin compatibility is thereby significantly improved.
  • the wash contains ⁇ 2-5 wt .-% and / or ⁇ 2-5 wt .-% microcrystalline waxes, or the total content of paraffin and microcrystalline waxes ⁇ 2-5 wt. % based on the weight of the washing piece or the Syndetgrundmasse.
  • Microcrystalline waxes are paraffin waxes having a melting point of between 60 and 90 ° C, predominantly iso-paraffins and naphtha-substituted aromatics, and are finely crystalline at room temperature.
  • compositions with homogeneous wax melts having a melting point of 50-60 ° C have proven to be particularly effective, it may happen that certain constituents of the wax melt crystallize out in certain compositions. This can lead to an undesirable roughness of the washing pieces, wherein the crystallized components can be partially visible even by visual inspection. It has therefore proved to be particularly advantageous for certain compositions to add crystallization inhibitors which suppress crystallization of constituents of the homogeneous wax melt. Surprisingly, it has turned out that in the presence of such crystallization inhibitors and the seeding properties of the wash can be significantly improved. Surprisingly, the Versumpfungseigenschaften already significantly improved, even if no crystallization by visual inspection is perceptible. This may be due to the fact that the formation of crystal nuclei or microcrystals is prevented by the crystallization inhibitors and so the swelling properties of the wash on a microscopic basis but also significantly improved overall.
  • crystallization inhibitors here are inulin and / or alkali metal fatty alcohol glutamates, in particular those having a C8 to C22 or to C30 fatty alcohol, more preferably a C10 to C16 or C12 to C14 fatty alcohol, most preferably a coconut oil fatty alcohol, in particular can be present in combination.
  • the alkali metal salts may in each case in particular be sodium salts, if appropriate also potassium salts.
  • inulin instead of inulin, other D-fructose containing polysaccharides or other predominantly or exclusively beta (1,2) -glykosidisch linked polysaccharides can be used, even if inulin has been found to be particularly preferred.
  • inulin and / or alkali metal fatty alcohol glutamates in particular sodium cocoyl glutamate, very effectively reduces the crystallization of constituents of said composition which contains homogeneously melting waxes in the temperature range from 50 ° C. to 60 ° C., which at the same time leads to very pleasant washing properties.
  • the alkali metal fatty alcohol glutamate may each be esterified with the fatty alcohol at the carboxyl group of the C1 or C4 atom.
  • beeswax is part of these waxes.
  • an ethoxylated alkali metal fatty alcohol glutamate may be contained in the composition.
  • the weight fraction of ethoxylated fatty alcohol glutamates ⁇ 50 wt .-% or ⁇ 10-20 wt .-% than that of the nonethoxylated glutamates or these are not present.
  • inulin is present in a proportion of 0.1-10% by weight, preferably 0.2-5% by weight, based on the total weight of the wash piece or the syndet base.
  • the content of inulin may in particular also be 0.2-2% by weight, particularly preferably 0.5-2% by weight.
  • the content of alkali metal fatty alcohol glutamates may, based on the total weight of the wash piece or the Syndetgrundmasse 0.1-5 wt .-%, preferably 0.5-4 wt .-% or 1-3 wt .-% amount.
  • the washing piece preferably contains beeswax, particularly preferably in combination with one or more fatty acid esters c) and / or at least one or more fatty alcohols d).
  • the fatty acid ester c) and / or the fatty alcohol d) is contained in a higher proportion of weight percent in the wash piece or the Syndet groundmasse than the beeswax.
  • the wash has significantly improved Versumpfungseigenschaften and at the same time a very good skin compatibility. This is also surprising insofar as beeswax is often described as disadvantageous in terms of skin tolerance.
  • the washing piece can be virtually free of paraffin and / or microcrystalline waxes, which further improves the skin compatibility.
  • beeswax is a wax having a melting point of 61-68 ° C, which consists essentially of a mixture of complex wax esters (usually about 65-75 wt .-%, usually about 70% by weight of the beeswax), normal fatty acids and hydroxyfatty acids (usually about 12-15% by weight, usually about 13-14% by weight) and also hydrocarbons (usually about 5-15% by weight). %, usually about 10-14 wt .-%) exists.
  • the wax esters may be esters of C 16 to C 36 acids, in particular palmitic and cerotic acids, it being possible for a total of about 50 to 70 different esters or more to be present.
  • the alcohol component may consist of a mixture of C24 to C36 alcohols and in particular also contain 1-triacontanol.
  • wax esters of hydroxyfatty acids especially cerylhydroxypalmitate (optionally also stearate) may be present (usually about 6-11% by weight, usually about 8-9% by weight).
  • 14-Hydroxypalmitin as well as 16-Hydroxy- and 17-Hydroxystearinklare are mostly also components of beeswax.
  • lignocerin, cerotinic and melicic acid can occur as free wax acids.
  • beeswax as a natural raw material is subject to fluctuations in its composition and, if appropriate, that some of the constituents can be outside the above-mentioned ranges without substantially changing the properties of the beeswax as a whole.
  • Synthetic beeswax may also be used instead of or in addition to natural beeswax if this has a comparable melting point and comparable composition, in particular as defined above, and results in comparable or identical properties of the washing piece, in particular with regard to the skin feel and hardness thereof and with respect to the dulness.
  • the fatty acid esters used according to the invention may in particular be glycol fatty acid esters and / or glycerol fatty acid esters or esters of higher alcohols, in particular the alcohol may also have unesterified hydroxy groups.
  • the fatty acid ester may in particular be a glycol mono- or diester or a mono- or diglyceride, if appropriate also a triglyceride.
  • the ester may each be a mixed ester.
  • the Syndetwasch Published fatty acid ester c) in addition to fatty alcohols d).
  • the fatty acid ester c) and the fatty alcohol d) are preferably present in a higher proportion in percent by weight in the wash piece or in the basic mass thereof than beeswax.
  • the weight fraction of beeswax is lower than that of the fatty acid ester c).
  • the proportion of fatty alcohol d) in the wash piece or the basic mass thereof is preferably lower than the proportion of the fatty acid ester c) in percent by weight.
  • the fatty acid ester c) used according to the invention can contain, if appropriate exclusively, C14- to C22- or else C24- fatty acids, preferably C14- to C20-fatty acids, more preferably C16- to C18-fatty acids.
  • the fatty acids are preferably each saturated and may be linear or optionally also branched fatty acids.
  • the ester may be a stearic acid ester, preferably a pure stearic acid ester.
  • the ester is in each case a glyceride, in particular a mono- or diglyceride or optionally also triglyceride of said fatty acids.
  • the fatty acid ester may also be a mixed ester.
  • the syndiate sponge may contain one or more different fatty acid esters.
  • the ester may also be a fatty acid ester of a more than trihydric alcohol.
  • the at least one fatty alcohol d) may in particular be a C12 to C22 or a C16 to C20 or C16 to C18 fatty alcohol.
  • the fatty alcohol may contain cetyl alcohol and / or stearyl alcohol.
  • the fatty alcohol is preferably saturated.
  • the fatty alcohol can be linear or branched.
  • the fatty alcohol may be cetearyl alcohol (also called cetylstearyl alcohol), i. H. a mixture of about equal parts of cetyl and stearyl alcohol.
  • the fatty alcohol d) may also partially contain other fatty alcohols, optionally only those mentioned above.
  • the composition may also be practically of fatty alcohol sulfates.
  • the constituents beeswax, fatty acid ester c) and fatty alcohol d) may in particular in a proportion of 10 to 20 wt .-%, optionally 12 to 16 wt .-% based on the weight the wash piece or the Syndetgrundmasse present.
  • the wash piece may in particular contain anionic, nonionic and / or amphoteric surfactants.
  • the wash can be ⁇ 10 wt% or ⁇ 5 wt% or ⁇ 2-3 wt% or ⁇ 1 wt% soaps, i. Salts - especially alkali metal salts - of fatty acids, contained or at least substantially or completely free of these.
  • Anionic surfactants may contain, for example, carboxylate, sulfate or sulfonate groups as functional groups.
  • suitable anionic surfactants are alkyl ether carboxylates, alkyl benzene sulfonates, alkyl ether sulfates and phosphates, alkane sulfonates, alkyl ether sulfonates, glycerol ether sulfonates, alpha-methyl ester sulfonates, sulfo fatty acids, alkyl sulfates, fatty alcohol sulfates, glycerol ether sulfates, fatty acid ether sulfates, hydroxy mixed ether sulfates, ether carboxylic acids, sulfotriglycerides, fatty acid amides, ether sulfates, mono- and dialkyl sulfosuccinates , Mono- and dialkylsulfos
  • Nonionic surfactants may be especially those with polyether chains.
  • Nonionic surfactants may in particular be polyglycol ethers, such as fatty alcohol polyglycol ethers, alkylphenol polyglycol ethers, fatty acid amide polyglycol ethers, alkoxylated triglycerides, mixed ethers and mixed formals, fatty alcohol or fatty acid oxethylates, fatty acid N-alkylglucamides, protein hydrolysates, polyol fatty acid esters, sorbitan esters, polysorbates, amine oxides, fatty acid amides, etc.
  • polyglycol ethers such as fatty alcohol polyglycol ethers, alkylphenol polyglycol ethers, fatty acid amide polyglycol ethers, alkoxylated triglycerides, mixed ethers and mixed formals, fatty alcohol or fatty acid oxethylates, fatty acid N-alkyl
  • the wash piece of the invention may also contain amphoteric surfactants such as, for example, betaines, acyl / dialkylethylenediamine, for example sodium acylamphoacetate, sodium acylamphopropyonate, corresponding disodium salts, sodium acylamphohydroxypropylsulfonate and the like, or N-alkylamino acids, e.g. Alkylaminopropionic acid, aminopropylalkylglutamide, sodium alkylimidodiproprionate, carboxyglucinates and the like.
  • amphoteric surfactants such as, for example, betaines, acyl / dialkylethylenediamine, for example sodium acylamphoacetate, sodium acylamphopropyonate, corresponding disodium salts, sodium acylamphohydroxypropylsulfonate and the like, or N-alkylamino acids, e.g. Alkylaminopropionic acid, aminopropyl
  • the washing piece according to the invention may also contain cationic surfactants but also be substantially or completely free of them.
  • the washing piece may further contain at least one or more organic acids, in particular carboxylic acids including hydroxycarboxylic acids, which may each have one or more carboxyl groups, for example citric acid, lactic acid, malic acid or else formic acid.
  • organic acids in particular carboxylic acids including hydroxycarboxylic acids, which may each have one or more carboxyl groups, for example citric acid, lactic acid, malic acid or else formic acid.
  • the aqueous solution of Syndetwasch Publishedes may have a pH of 5-6.5, in particular a pH of 5.0 to 6.0.
  • composition of the synthezzle may also contain one or more of the following ingredients: tri-C 12 -C 13 alkyl citrate, Cetearylethylhexanoate, acrylate or acrylamide polymers, for example, acrylate / octylacrylamide copolymer, ethylenedistearamide, rice bran wax, oils such as sunflower oil and olive oil and other natural oils, hydrogenated oils such as hydrogenated olive oil, unsaponifiable natural oils such as unsaponifiable olive oil, cetyl palmitate, cetyl stearate, sorbitan esters such as sorbitan palmitate and Sorbitan stearate, sorbitan derivative, fatty acid esters such as stearic acid and palmitic acid with C6 to C10 alcohols, for example stearylheptanoate, glycerol sorbitanate, especially unsaturated glycerol sorbitanate, stearyl and palmityl caprylate, phytosphingos
  • the composition may also contain one or more of the waxes Oryzasativa Bran wax, candelilla wax, ceresin / ceresin, carnauba wax and / or Japan wax, which waxes may be contained individually or in their entirety in lower proportions by weight in the composition than beeswax (especially natural Beeswax), or in each case or in total less than 50% or less than 10-20% by weight of beeswax or in each case in the composition except for unavoidable traces.
  • the components mentioned here in their entirety may each be part of the homogeneous wax having a melting point of 50-60 ° C.
  • the washing piece may have further constituents.
  • the constituents of binders, fillers and additives mentioned are well known and can the respective Be adapted to requirements.
  • the additives may be deodorants, processing aids, preservatives, perfume oils, fragrances, dyes or the like.
  • a binder for example, starch can be used.
  • composition of the washing piece may contain 5-50% by weight of starch, preferably 10-50% by weight or 20-50% by weight, in particular about 30% by weight.
  • the composition may also be starch free.
  • the inventive washing pieces may contain less than 20% by weight of water-soluble alkali metal salts of isetonic acid esters and / or a content of ⁇ 3% by weight of alkali metal salts of alkylsulfoacetates.
  • fillers for example, titanium dioxide, silicates, carbonates or the like can be used.
  • washes In contrast to emulsions, washes have a significantly lower water content and a higher surfactant content.
  • the water content of the washes is generally ⁇ 20% by weight, preferably ⁇ 15% by weight or ⁇ 10% by weight.
  • the content of washing-active substances is generally ⁇ 20% by weight, more preferably ⁇ 25% by weight or ⁇ 30% by weight, in each case based on the total weight of the composition.
  • NTP the shrinkage under defined standard conditions NTP is to be determined.
  • the washing piece a defined size and shape (eg cuboid wash piece with about 15 g weight and edge lengths 35 mm x 25 mm x 12 mm) in a 30 ° C warm water (eg deionized water) and 22 hours in the water to hang freely (without Tempering the water). The pieces are then removed and the swollen soft layer is rubbed off manually.
  • the pieces are smoothed with a cloth and dried at 60 ° C for 45 min, then cooled to room temperature and weighed. Dumping is determined as a percentage of weight loss as indicated above.
  • the used washing pieces of a test series should have the same size and shape.
  • the inventive wash pieces can generally under the conditions defined above (size and shape of the specimens, swelling of 22 hours in water at 30 ° C, abrasion of the swollen layer to the unswollen core, drying for 45 min at 60 ° C) a shrinkage of ⁇ 60%, in particular ⁇ 55% or particularly preferably ⁇ 50%. Damping may be ⁇ 30% or ⁇ 40% under the conditions mentioned.
  • Soap pieces were pressed and their respective properties were investigated on the basis of the compositions or formulations mentioned below.
  • composition 1 here is a comparative example not according to the invention.
  • the calcination values are determined as indicated as weight percent of the abrasion in grams relative to the weight of the wash before swelling in grams (expressed in weight percent). With regard to the further conditions, reference is made to the above.
  • the inventive washing pieces have significantly lower impregnation values than the comparative example. At the same time the washes are perceived as comfortable and not too hard to handle.
  • the ingredients inulin and sodium cocoylglutamate, especially in combination with each other not only prevent crystallization of wax components and give "smooth" washes with a particularly comfortable feel, but also excellent seeding properties.
EP07003951A 2006-03-03 2007-02-27 savon aux détergents synthétiques Active EP1829956B1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE102006010408A DE102006010408A1 (de) 2006-03-03 2006-03-03 Syndetwaschstück

Publications (2)

Publication Number Publication Date
EP1829956A1 true EP1829956A1 (fr) 2007-09-05
EP1829956B1 EP1829956B1 (fr) 2009-12-16

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ID=38078220

Family Applications (1)

Application Number Title Priority Date Filing Date
EP07003951A Active EP1829956B1 (fr) 2006-03-03 2007-02-27 savon aux détergents synthétiques

Country Status (4)

Country Link
EP (1) EP1829956B1 (fr)
AT (1) ATE452177T1 (fr)
DE (2) DE102006010408A1 (fr)
ES (1) ES2337932T3 (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3073142A1 (fr) * 2017-11-07 2019-05-10 Gallinee Formulation cosmetique
CN111363631A (zh) * 2018-12-26 2020-07-03 上海新阳半导体材料股份有限公司 可用于去毛刺的去胶剂及其制备方法和应用

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DE1792029A1 (de) 1968-07-13 1971-10-21 Huels Chemische Werke Ag Stueckfoermige synthetische Reinigungsmittel
US3766097A (en) 1971-08-09 1973-10-16 P Rosmarin Detergent (soap) compositions
DE3011813A1 (de) 1980-03-27 1981-10-22 Zschimmer & Schwarz Gmbh & Co Chemische Fabriken, 5420 Lahnstein Verfahren zur verbesserung der gebrauchseigenschaften von stueckfoermigen reinigungsmitteln
WO1992013060A2 (fr) 1991-01-28 1992-08-06 The Procter & Gamble Company Systemes de liants utilises dans des savons en barres
GB2317396A (en) 1996-08-21 1998-03-25 Cussons Int Ltd Personal cleansing bar
WO2001072947A1 (fr) 2000-03-25 2001-10-04 Cognis Deutschland Gmbh Savons au detergent synthetique

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US5510050A (en) * 1993-11-08 1996-04-23 The Procter & Gamble Company Improved acyl isethionate skin cleansing bar containing liquid polyols and magnesium soap
DE19846429A1 (de) * 1998-10-08 2000-04-13 Cognis Deutschland Gmbh Stückseifen
JP2002543302A (ja) * 1999-04-27 2002-12-17 ザ、プロクター、エンド、ギャンブル、カンパニー 多糖類を含む処理組成物
DE19937295C2 (de) * 1999-08-06 2002-11-21 Cognis Deutschland Gmbh Syndetseifen
DE10035208A1 (de) * 2000-07-20 2002-01-31 Beiersdorf Ag Geformtes Seifenprodukt, enthaltend Talkum, eine oder mehrere Fettsäuren in Form ihrer Alkaliseifen und ein oder mehrere anionische Tenside bei gleichzeitiger Abwesenheit von Alkyl-(oligo)-glycosiden
EP1552815A1 (fr) * 2004-01-12 2005-07-13 JOHNSON & JOHNSON GmbH Barre de nettoyage contenant une cire

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1792029A1 (de) 1968-07-13 1971-10-21 Huels Chemische Werke Ag Stueckfoermige synthetische Reinigungsmittel
US3766097A (en) 1971-08-09 1973-10-16 P Rosmarin Detergent (soap) compositions
DE3011813A1 (de) 1980-03-27 1981-10-22 Zschimmer & Schwarz Gmbh & Co Chemische Fabriken, 5420 Lahnstein Verfahren zur verbesserung der gebrauchseigenschaften von stueckfoermigen reinigungsmitteln
WO1992013060A2 (fr) 1991-01-28 1992-08-06 The Procter & Gamble Company Systemes de liants utilises dans des savons en barres
GB2317396A (en) 1996-08-21 1998-03-25 Cussons Int Ltd Personal cleansing bar
WO2001072947A1 (fr) 2000-03-25 2001-10-04 Cognis Deutschland Gmbh Savons au detergent synthetique

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3073142A1 (fr) * 2017-11-07 2019-05-10 Gallinee Formulation cosmetique
WO2019092060A1 (fr) * 2017-11-07 2019-05-16 Gallinee Formulation cosmetique
CN111363631A (zh) * 2018-12-26 2020-07-03 上海新阳半导体材料股份有限公司 可用于去毛刺的去胶剂及其制备方法和应用

Also Published As

Publication number Publication date
ATE452177T1 (de) 2010-01-15
EP1829956B1 (fr) 2009-12-16
DE102006010408A1 (de) 2007-09-06
DE502007002303D1 (de) 2010-01-28
ES2337932T3 (es) 2010-04-30

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