EP1825055B1 - Glanzpapier - Google Patents

Glanzpapier Download PDF

Info

Publication number
EP1825055B1
EP1825055B1 EP05824442.7A EP05824442A EP1825055B1 EP 1825055 B1 EP1825055 B1 EP 1825055B1 EP 05824442 A EP05824442 A EP 05824442A EP 1825055 B1 EP1825055 B1 EP 1825055B1
Authority
EP
European Patent Office
Prior art keywords
paper
glossy
scintillating
microbeads
microplatelets
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Not-in-force
Application number
EP05824442.7A
Other languages
English (en)
French (fr)
Other versions
EP1825055A1 (de
Inventor
André Honnorat
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Honnorat Recherches and Services
Original Assignee
Honnorat Recherches and Services
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Honnorat Recherches and Services filed Critical Honnorat Recherches and Services
Publication of EP1825055A1 publication Critical patent/EP1825055A1/de
Application granted granted Critical
Publication of EP1825055B1 publication Critical patent/EP1825055B1/de
Not-in-force legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/66—Coatings characterised by a special visual effect, e.g. patterned, textured
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/38—Coatings with pigments characterised by the pigments
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H23/00—Processes or apparatus for adding material to the pulp or to the paper
    • D21H23/02—Processes or apparatus for adding material to the pulp or to the paper characterised by the manner in which substances are added
    • D21H23/22—Addition to the formed paper
    • D21H23/24—Addition to the formed paper during paper manufacture

Definitions

  • the invention relates to the field of glossy or glittering papers used for the production of magazines, brochures, advertising documents, art papers or papers for printing and writing.
  • Glossy papers are generally obtained by means of a calendering or supercalendering operation of coated papers with an essentially inorganic coating, said calendering operation makes it possible to smooth the surface thoroughly.
  • the gloss is obtained on the coated and calendered paper by the uniform reflection of the light on the extremely smooth and homogeneous surface.
  • the method does not in any way to obtain a textured paper or relief since the method consists in completely leveling the surface.
  • embossed papers correspond, in a non exclusive way, to the papers of the categories printing and writing, texts and covers and fine arts, for which a particular texture of paper is often sought.
  • Paper texture must include papers with watermarks, particular colors, orchards, various markings such as those produced with grain markers or markers, etc ...
  • Another means for producing glossy papers and more particularly said embossed papers is to coat a gloss varnish during a processing operation, out of the paper machine.
  • the gloss is obtained by a high quantity deposit of a glossy polymer.
  • a process similar to that of the varnishing can be performed on a coater with a formulation similar to that of a varnish.
  • Another technique is to laminate the finished paper with a polymer film.
  • the laminating operation carried out outside the paper machine, when the paper is manufactured, is also expensive and corresponds to an application different from that of the invention, rather from the field of the transformation of the printed paper than that of the production. .
  • This composition is coated on a support paper with a coating system equipped with an equalizer air knife.
  • This type of coating system does not equip paper machines. As a result, coating with this coating system is not performed on the paper machine.
  • no component a) to f) of the coating composition comprises microplates or reflective microbeads smaller than 300 microns, integrating at least one optically transparent material in their structure.
  • the invention therefore aims to solve these major difficulties, that is to say manufacture a glossy or scintillating paper economically without calendering or varnishing operation on all paper machines, with or without built-in coater, and with all possible supports, especially colored or textured.
  • the glossy or scintillating paper according to the invention has a roughness greater than 30 ml / min measured according to the ISO 8791-2 standard, it is manufactured completely on a paper machine, and it is characterized by the fact that it comprises microplates or reflective microbeads smaller than 300 ⁇ m integrating at least one optically transparent material into their structure, generally a compound classified in the general family of glasses, for example a borosilicate.
  • the advantages of the paper according to the invention are both economical, since it is possible to manufacture a glossy or scintillating paper without calendering, coating or processing, and at the same time technical because glossy papers as proposed allow to obtain particular optical effects and in particular a remarkable gloss on textured or colored papers with full maintenance of the mechanical characteristics of the paper, in particular as regards rigidity and resistance to bursting.
  • Another remarkable effect of the invention is that the optical rendering of the paper according to the invention is variable according to the ambient lighting at the moment of observation.
  • lighting is important, in the sense of the light reaching the paper, the treatment leads to a uniform gloss effect whereas when the lighting is low scintillated individual points are perceptible on the surface of said paper.
  • the glossy or scintillating treated paper retains all its physical and mechanical characteristics as well as its appearance and touch characteristics, which is decisive in the case of textured papers for which a relief is desired and for which it is often required a pleasant touch, this is more particularly the case for papers incorporating cotton linters in their fibrous composition.
  • Coating, coating or varnishing treatments result in the loss of these appearance properties which are particularly appreciated for fine art papers and most papers used in printing and writing.
  • coated paper any paper having on its surface a coating comprising at least one polymeric binder and optionally inorganic or organic fillers, the operation being carried out on or off the machine. using a coating tool to maintain the layer deposited on the surface of the paper, that is to say that said layer does not penetrate more than 20%, and generally less than 10% of the paper thickness.
  • Uncoated paper is to be understood as a raw paper having either no surface treatment or impregnation or coating by means of various, preferably rolled, devices which force the penetration of the treating composition into the entire sheet thickness or at least 30% of said thickness.
  • a varnished paper is a paper on which is deposited a glossy transparent layer, penetrating very little into the paper, that is to say in less than 20% of its thickness, generally consisting essentially of a glossy polymer without additional charge and with a dry matter deposition of at least 2 g / m 2 and preferably more than 5 g / m 2 .
  • the varnishing operation being performed outside the paper machine on a specific material, a coating machine, or by means of a coating apparatus.
  • the gloss or flicker of the paper within the meaning of the invention is defined by the visual effect produced at observation at a variable angle between 20 and 80 °.
  • the optical effect produced is situated between a scintillating effect, such as that produced by snow in the sun for example, that is to say shiny points distributed from random way reflecting light, and between a uniform shiny effect without individualized scintillating points.
  • optical effects obtained in the invention are not only variable according to the angle of observation of the treated paper but also according to the ambient lighting, the visual effect is changing depending on the lighting is low, in these conditions glittering points individualized are more particularly visible, or strong, and in these conditions the brilliant effect is homogeneous and very intense. These effects are very different from those obtained in coated calendered papers or varnished papers which never have a scintillating appearance and whose gloss is relatively independent of the lighting conditions.
  • the roughness of the paper is usually measured by means of different devices such as "Bekk”, “Bendtsen” or “Sheffield” apparatus, said roughness measurement is standardized and reference is made here more particularly to the ISO8791-2 standard allowing express the roughness of the paper in ml / min with the "Bendtsen” device.
  • the papers according to the invention have a roughness of at least 30 ml / min and preferably more than 100 ml / min which in the traditional classification of papermakers corresponds to raw papers or very slightly calendered but in no way to papers traditional glosses whose roughness values measured in Bendtsen are at values below 30 ml / min and more generally below 10 ml / min.
  • the textured papers for which the treatment is of particular interest have roughnesses greater than 300 ml / min and generally above 1000 ml / min when texturing using markers or engraved presses is employed.
  • the treatment composition according to the invention is applicable to all types of paper, textured or colored in particular, by means of a tool arranged inside the paper machine, preferably a gluing press, a multiple roller device known as “gate roll” or “massey”, an impregnator, a roller device having pre-dosages for the coating formulation such as for example that called “blade metering size press” (“BMSP”), or any other device comprising at least one roll in contact with the paper.
  • a tool arranged inside the paper machine preferably a gluing press, a multiple roller device known as “gate roll” or “massey”, an impregnator, a roller device having pre-dosages for the coating formulation such as for example that called “blade metering size press” (“BMSP”), or any other device comprising at least one roll in contact with the paper.
  • BMSP blade metering size press
  • Traditional coating tools arranged inside the paper machine can be used, such as for example towing or barbed coatings.
  • the treatment composition according to the invention employs reflective particles in the form of platelets or microbeads incorporating their structure at least one optically transparent material, in general a compound classified in the general family of glasses, for example a borosilicate.
  • the dimensions of the particles are less than 300 ⁇ m and preferably between 50 and 250 ⁇ m so that the reflective effect is optimal. Too fine particles, that is to say the size of the usual coating pigments, typically less than 30 microns, penetrate too much into the paper support during the application of the treatment composition and their shiny or scintillating effect finds it very weak.
  • the reflective effect of the platelets or balls is created by the combination of an optically transparent material and a light reflecting material, the manufacture of such particles in the form of platelets or beads is known per se and carried out in particular by Merck, which has developed technologies to obtain particles with different materials in successive layers.
  • the products used in the context of the invention are remarkable in that they can be used in extremely reduced doses on all types of supports and more particularly on supports of notable roughness as defined above, and in the fact that they are applicable by conventional means present on all paper machines and not only sleeping tools.
  • the roughness of the finished paper is greater than 100 ml / min according to ISO 8791-2 and the microplates or reflective microbeads are incorporated at least 0.05% and preferably at least 0.15%. in dry weight compared to finished paper.
  • the treatment composition according to the invention comprises at least one class of particles in the form of microplates or reflective microbeads incorporating at least one optically transparent material in their structure, and at least one binder for fixing said particles in and on the surface of the paper.
  • Reflective microplates of dimensions between 20 and 200 microns, quite suitable are for example marketed by Merck under the name MIRAVAL® and under the reference 5411 Magic White.
  • the binder can be conventionally a starch, a polyvinyl alcohol, a latex or any other polymer that can be used in a known manner in paper industry.
  • the quantity and nature of said binder is chosen according to the coating means and factors related to the subsequent use of the paper such as, for example, the printing medium employed.
  • binders that can enhance the gloss of the reflective particles are, for example, and without limitation, the polymers selected from the families of polyvinyl alcohols, acrylic latices, polyvinylipyrrolidones.
  • the glossy or scintillating paper which comprises microplates or reflecting microbeads in a proportion of at least 0.05% by dry weight relative to the paper, and preferably at least 0.15%, also contains a polymeric binder at a rate of at least 0.1% by dry weight and preferably more than 1% by weight of paper.
  • the level of binder inside the treatment composition must be sufficiently high, it has been found particularly advantageous to put at least the same amount of binder, in dry weight. incorporated, as reflective particles, and preferably at least twice as much.
  • the process is characterized in that the paper support can be colored, textured, watermarked, laid, marked with markers, engraved presses or any other device known to give a relief or heterogeneity to the paper by any method to inside the paper machine, before the treatment formulation is applied to its surface.
  • the process for obtaining a glossy or scintillating paper is also characterized in that the microplates or reflective microbeads are incorporated in the paper together with the polymeric binder in a treatment composition applied by means of a coating device comprising at least one roll, conventionally a gluing press.
  • the method is particularly well suited for obtaining glossy or glittering colored papers without calendering or coating operation.
  • a treatment composition comprising reflective microplates incorporating at least one optically transparent material in their structure is applied to the gluing press on a paper of 150 g / m 2 textured by means of marker pens. .
  • the treatment composition consists of a solution comprising, by weight relative to the total weight of the formulation: 2% of a polyvinyl alcohol of high viscosity, Mowiol® 28-99 marketed by the company SEPPIC and 0.5% of MIRAVAL® 5411 Magic White from Merck.
  • the carrier of the preceding solution to the sizing press is 35% by weight relative to the paper, which represents a weight of reflective microplates incorporated in the paper of 0.175% and a weight of polymeric binder of 0.7%.
  • Said binder is in quantity four times greater than the amount of reflective microplates in the composition.
  • the brilliant effect obtained is variable depending on the lighting conditions.
  • the gloss effect is homogeneous and very intense.
  • the paper is observed in a poorly lit place it appears essentially sparkling points.
  • the glossy white paper thus obtained has a roughness measured according to the ISO 8791-2 standard of 1500 ml / min.
  • a glossy colored paper and laid paper is obtained by producing a colored paper of 100 g / m 2 laid on the table of the paper machine and colored in its mass in a conventional manner.
  • the colored and textured sheet is coated with the size press with a composition comprising, by weight relative to the total weight of the formulation: 1% of a polyvinyl alcohol of high viscosity, Mowiol® 28-99 sold by the company SEPPIC, 5% by dry weight of a styrene butadiene latex DL 955 marketed by the company DOW CHEMICAL and 2% of MIRAVAL® 5411 Magic White from Merck.
  • a composition comprising, by weight relative to the total weight of the formulation: 1% of a polyvinyl alcohol of high viscosity, Mowiol® 28-99 sold by the company SEPPIC, 5% by dry weight of a styrene butadiene latex DL 955 marketed by the company DOW CHEMICAL and 2% of MIRAVAL® 5411 Magic White from Merck.
  • the treatment composition penetrates the entire thickness of the paper and a load of 40% is found.
  • the reflective microplates are incorporated at a rate of 0.8% by dry weight relative to the weight of paper
  • the polymeric binder represented by the polyvinyl alcohol and the latex is incorporated at the rate of three times the amount of reflective microplates and at a rate of 2.4% based on the weight of paper.
  • the finished paper still has its original color and texture before treatment, the roughness is measured at 1000 ml / min, the gloss of the paper is very strong under a lot of light, producing a particular optical rendering but with the classic characteristics touch and relief provided by the shepherds.
  • the previous solution is applied by means of a gluing press on the base paper in a proportion of at least 30 liters of treatment composition per 100 kg of paper, which taking into account this paper represents approximately 30% of the thickness treated. and a hydrophilic binder amount of 1.8% based on the weight of paper. Reflective microplates are incorporated at a rate of 0.9% dry product over finished paper.
  • the paper thus coated is dried post-drying and the finished product is wound without calendering so as to preserve the texture formed with the engraved presses.
  • the product has the texture of watercolor paper with high gloss and high printability.
  • Such paper can be used for art reproduction on large format inkjet printers or as a support for photo printing in desktop printers. There is no equivalent on the market of such paper that is both textured, glossy and ink-jet-ready, even if produced by a different technique.
  • the fibers used to make the paper may be cellulosic and / or cotton linters, wholly or partly, in association or not with synthetic fibers or fibers of other kinds. All additives traditionally used in paper industry such as additional fillers (talc, kaolin, calcium carbonate, etc.), bonding agents, retention agents, colorants, brighteners, etc. can be used without departing from the scope of the invention.
  • the texture of the product may be strong or non-existent, the paper may be watermarked or not, high or low weight, without departing from the scope of the invention which is to bring a gloss effect to non-calendered and unvarnished papers while retaining their usual appearance properties including roughness and touch.
  • one of the advantages of the invention is that it is possible to produce a paper treated differently on its two sides, directly in the paper-making process, and thus to obtain finally a paper having two different glosses on both sides, which represents a strong commercial advantage.
  • the treatment composition may in particular be added various additives such as co-binders, rheology modifiers, defoamers, antifungals, optical brighteners, dyes and various other compounds traditionally known in paper making without departing from the scope of the invention.

Landscapes

  • Paper (AREA)

Claims (10)

  1. Glanz- oder Glimmerpapier mit einer gemessenen Rauheit von mehr als 30 ml/min gemäß Norm ISO 8791-2, vollständig mittels Papiermaschine hergestellt, dadurch gekennzeichnet, dass es reflektierende Mikroplättchen oder Mikrokügelchen mit einer Größe von weniger als 300 µm aufweist, die mindestens ein optisch transparentes Material in ihrer Struktur enthalten, im Allgemeinen eine der allgemeinen Familie der Gläser zugeordnete Verbindung, zum Beispiel Borosilikat.
  2. Glanz- oder Glimmerpapier nach Anspruch 1, bei dem die Rauheit mehr als 100 ml/min gemäß Norm ISO 8791-2 beträgt und die reflektierenden Mikroplättchen oder Mikrokügelchen zu mindestens 0,05 % des Trockengewichts und vorzugsweise zu mindestens 0,15 % bezogen auf das fertige Papier eingearbeitet sind.
  3. Glanz- oder Glimmerpapier nach Anspruch 1, gewonnen durch Beschichtung mit einer Behandlungszusammensetzung, die reflektierende Mikroplättchen oder Mikrokügelchen sowie mindestens ein polymeres Bindemittel enthält, wobei diese Behandlungszusammensetzung die Einarbeitung besagter Mikroplättchen oder Mikrokügelchen zu mindestens 0,05 % des Trockengewichts und vorzugsweise zu mindestens 0,15 % bezogen auf das fertige Papier sowie des besagten polymeren Bindemittels zu mindestens 0,1 % des Trockengewichts und vorzugsweise zu mehr als 1 % bezogen auf das Papiergewicht ermöglicht.
  4. Glanz- oder Glimmerpapier nach Anspruch 3, gewonnen durch Beschichtung mit einer Behandlungszusammensetzung, die ein Trockengewicht an Bindemittel aufweist, das mindestens so viel wie das Gewicht an reflektierenden Mikroplättchen oder Mikrokügelchen beträgt.
  5. Glanz- oder Glimmerpapier nach Anspruch 4, wobei das verwendete Bindemittel aus der Familie der Polyvinylalkohole, der Acryllatexe oder der Polyvinylpyrrolidone ausgewählt wird.
  6. Glanz- oder Glimmerpapier nach Anspruch 3, wobei die
    Behandlungszusammensetzung mittels eines Gerätes aufgetragen wird, das mindestens eine Rolle besitzt, zum Beispiel nach Art einer Leimpresse, "Massey", "Gate-Roll", "BMSP".
  7. Glanz- oder Glimmerpapier nach Anspruch 3, dadurch gekennzeichnet, dass es mit Filzen, Gravurpressen gefärbt, texturiert, mit Wasserzeichen versehen, gerippt, markiert werden kann, um dem Papier ein Relief oder eine Heterogenität im Innern der Papiermaschine zu geben, bevor die Behandlungsformulierung auf seine Oberfläche aufgetragen wird.
  8. Verfahren zur Gewinnung eines Glanz- oder Glimmerpapiers mit einer gemessenen Rauheit von mehr als 30 ml/min gemäß Norm ISO 8791-2, in einem einzigen Schritt mittels Papiermaschine hergestellt, das durch die Abfolge der folgenden Phasen gekennzeichnet ist:
    • Erstellung eines Papierträgers,
    • Auftragen auf besagten Träger einer Behandlungszusammensetzung bestehend aus reflektierenden Mikroplättchen oder Mikrokügelchen mit einer Größe von weniger als 300 µm, die mindestens ein optisch transparentes Material in ihrer Struktur enthalten, und bestehend aus mindestens einem polymeren Bindemittel, dessen Trockenmenge mindestens jener der besagten Mikroplättchen oder Mikrokügelchen entspricht,
    • Trocknung der besagten Zusammensetzung und Aufspulen des fertigen Papiers.
  9. Verfahren zur Gewinnung eines Glanz- oder Glimmerpapiers nach Anspruch 8, dadurch gekennzeichnet, dass der Träger mit Filzen, Gravurpressen gefärbt, texturiert, mit Wasserzeichen versehen, gerippt, markiert werden kann, um dem Papier ein Relief oder eine Heterogenität im Innern der Papiermaschine zu geben, bevor die Behandlungsformulierung auf seine Oberfläche aufgetragen wird.
  10. Verfahren zur Gewinnung eines Glanz- oder Glimmerpapiers nach Anspruch 8, dadurch gekennzeichnet, dass die Behandlungszusammensetzung mittels einer Beschichtungsvorrichtung aufgetragen wird, die mindestens eine Rolle aufweist, zum Beispiel nach Art einer Leimpresse, "Massey", "Gate-Roll", "BMSP", wodurch es möglich ist, in das Papier eine Menge von mindestens 0,05 % des Trockengewichts und vorzugsweise von mindestens 0,15 % der besagten Mikroplättchen oder Mikrokügelchen bezogen auf das fertige Papier sowie mindestens ein polymeres Bindemittel zu mindestens 0,5 % des Trockengewichts und vorzugsweise zu mehr als 1 % bezogen auf das Papiergewicht einzuarbeiten.
EP05824442.7A 2004-12-15 2005-12-01 Glanzpapier Not-in-force EP1825055B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0413319A FR2879225B1 (fr) 2004-12-15 2004-12-15 Papier brillant
PCT/FR2005/003011 WO2006064101A1 (fr) 2004-12-15 2005-12-01 Papier brillant

Publications (2)

Publication Number Publication Date
EP1825055A1 EP1825055A1 (de) 2007-08-29
EP1825055B1 true EP1825055B1 (de) 2013-10-23

Family

ID=34952592

Family Applications (1)

Application Number Title Priority Date Filing Date
EP05824442.7A Not-in-force EP1825055B1 (de) 2004-12-15 2005-12-01 Glanzpapier

Country Status (6)

Country Link
US (1) US20090294080A1 (de)
EP (1) EP1825055B1 (de)
ES (1) ES2440475T3 (de)
FR (1) FR2879225B1 (de)
WO (1) WO2006064101A1 (de)
ZA (1) ZA200705697B (de)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8668965B2 (en) 2010-10-22 2014-03-11 Hewlett-Packard Development Company, L.P. Printed article with metallic appearance
FI123459B (fi) * 2011-05-05 2013-05-15 Teknologian Tutkimuskeskus Vtt Menetelmä kohteen pinnan muokkaamiseksi
US8715812B2 (en) 2011-09-30 2014-05-06 Hewlett-Packard Development Company, L.P. Metallic luster printed medium and method of preparing same
JP6466260B2 (ja) * 2014-06-11 2019-02-06 特種東海製紙株式会社 印刷用紙
WO2016021721A1 (ja) * 2014-08-08 2016-02-11 株式会社ニコン 情報処理装置、およびプログラム

Family Cites Families (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR694861A (fr) * 1930-05-02 1930-12-09 Procédé de fabrication de feuilles à effets nacrés
GB752374A (en) * 1954-03-26 1956-07-11 Walter Roberts Improvements in or relating to transfers
SE313492B (de) * 1965-04-02 1969-08-11 Mo Och Domsjoe Ab
FR1474425A (fr) * 1965-04-02 1967-03-24 Mo Och Domsjoe Ab Composition d'enduisage
US3485658A (en) * 1965-07-22 1969-12-23 Du Pont Plural monolayer coated article and process of making
FR2192153A1 (en) * 1972-07-11 1974-02-08 Rhone Poulenc Sa Coating compsn for paper and card - giving good brightness, and suitable for printing
US3873390A (en) * 1972-09-27 1975-03-25 Richard K Cornell Phosphorescent, fluorescent and reflective coated sheets or films and compositions and method for making the same
US4317849A (en) * 1979-11-06 1982-03-02 Mitsubishi Paper Mills, Ltd. Process for producing high-gloss coated paper
US5118533A (en) * 1988-09-14 1992-06-02 Kanazaki Paper Mfg. Co., Ltd. Method of manufacturing coated paper
US5125996A (en) * 1990-08-27 1992-06-30 Eastman Kodak Company Three dimensional imaging paper
US5372878A (en) * 1992-06-23 1994-12-13 Yamasa Momi Kikaku Co., Ltd. Slackened or creased fibrous sheet
US6977025B2 (en) * 1996-08-01 2005-12-20 Loctite (R&D) Limited Method of forming a monolayer of particles having at least two different sizes, and products formed thereby
DE19745082A1 (de) * 1997-10-11 1999-04-15 Haindl Papier Gmbh Gestrichenes Rollendruckpapier mit Coldset-Eignung
FR2791368B1 (fr) * 1999-03-26 2001-06-01 Arjo Wiggins Sa Feuille avec un toucher "peau" imprimable a des cadences elevees et son procede de fabrication et emballage la comportant
EP1777255A3 (de) * 1999-06-11 2007-07-11 Sydney Hyman Bildformungsmaterial
US6820975B2 (en) * 2000-09-01 2004-11-23 Konica Corporation Inkjet recording apparatus and inkjet recording method
US6565770B1 (en) * 2000-11-17 2003-05-20 Flex Products, Inc. Color-shifting pigments and foils with luminescent coatings
FI117870B (fi) * 2001-04-24 2011-06-27 M Real Oyj Päällystetty kuiturata ja menetelmä sen valmistamiseksi
FI110800B (fi) * 2001-06-25 2003-03-31 M Real Oyj Menetelmä päällystetyn kuiturainan valmistamiseksi
CA2477956A1 (en) * 2002-03-14 2003-09-18 Katsuto Nakatsuka Coated powder, coating composition, and coated article
US7758690B2 (en) * 2002-05-03 2010-07-20 Imerys Minerals, Ltd. Paper coating pigments
KR100990793B1 (ko) * 2002-12-25 2010-10-29 제이에스알 가부시끼가이샤 비접촉형 도공용 공중합체 라텍스 및 이를 포함하는 조성물및 도공지 및 그의 제조 방법
US7361399B2 (en) * 2004-05-24 2008-04-22 International Paper Company Gloss coated multifunctional printing paper
JP5614986B2 (ja) * 2006-09-12 2014-10-29 ミードウエストベコ・コーポレーション マイクロプレートレットセルロース粒子を含有する板紙
DE602007005101D1 (de) * 2007-04-05 2010-04-15 Eckart Gmbh Kosmetische Zusammensetzungen enthaltend Perlglanzpigmente
DE602007001237D1 (de) * 2007-04-05 2009-07-16 Eckart Gmbh Effektpigmente mit einem Substrat aus Glasplättchen
JP2009166478A (ja) * 2007-12-17 2009-07-30 Pilot Ink Co Ltd 変色性積層体
DE102008020442A1 (de) * 2008-04-23 2009-10-29 Merck Patent Gmbh Pigmentpräparationen

Also Published As

Publication number Publication date
ES2440475T3 (es) 2014-01-29
FR2879225B1 (fr) 2007-02-16
FR2879225A1 (fr) 2006-06-16
US20090294080A1 (en) 2009-12-03
WO2006064101A1 (fr) 2006-06-22
EP1825055A1 (de) 2007-08-29
ZA200705697B (en) 2009-01-28

Similar Documents

Publication Publication Date Title
EP1319104B1 (de) Sicherheitsblatt, das eine durchsichtige oder transluzente schicht enthält
CA2564505C (fr) Procede de fabrication de papier decoratif et stratifie decoratif comportant un tel papier decoratif
EP0514455B1 (de) Blatt für sicherheitsdokumente mit einer hohen bedruckbarkeit und einer hohen verschleissfestigkeit
EP0656443A1 (de) Papiervlies für abriebfeste Schichtstoffplatten
EP1761672B1 (de) Offset druckverfahren
EP1825055B1 (de) Glanzpapier
EP2914776B1 (de) Dekorpapier für schichtprodukte
EP2576904A1 (de) Feines schichtpapier mit angenehmer haptik
EP1987197A2 (de) Filmmaterial mit mindestens einem wasserzeichen mit farbiger nuance
EP3577273B1 (de) Dekorpapier für laminate
EP1583870B1 (de) Folie mit iridisierender optik und deren herstellung
JP6507539B2 (ja) 塗工白板紙
JP6503666B2 (ja) 塗工白板紙
EP1135556B1 (de) Nicht beschichtetes papier mit einem nachgeahmten wasserzeichen, und verfahren zu seiner herstellung
CA2099871C (fr) Feuille imprimable marquee couchee et son procede de fabrication
WO2015040090A1 (fr) Papier comportant au moins une face ultra-brillante et procédé de fabrication dudit papier
WO2014097146A1 (fr) Support d'information destine a l'impression sur presses offset
WO2015181686A1 (fr) Substrat pour document securise

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 20070423

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LT LU LV MC NL PL PT RO SE SI SK TR

DAX Request for extension of the european patent (deleted)
17Q First examination report despatched

Effective date: 20091015

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

INTG Intention to grant announced

Effective date: 20130325

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

INTG Intention to grant announced

Effective date: 20130527

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LT LU LV MC NL PL PT RO SE SI SK TR

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

Free format text: NOT ENGLISH

REG Reference to a national code

Ref country code: CH

Ref legal event code: EP

REG Reference to a national code

Ref country code: AT

Ref legal event code: REF

Ref document number: 637686

Country of ref document: AT

Kind code of ref document: T

Effective date: 20131115

REG Reference to a national code

Ref country code: IE

Ref legal event code: FG4D

Free format text: LANGUAGE OF EP DOCUMENT: FRENCH

REG Reference to a national code

Ref country code: DE

Ref legal event code: R096

Ref document number: 602005041658

Country of ref document: DE

Effective date: 20131219

REG Reference to a national code

Ref country code: ES

Ref legal event code: FG2A

Ref document number: 2440475

Country of ref document: ES

Kind code of ref document: T3

Effective date: 20140129

REG Reference to a national code

Ref country code: NL

Ref legal event code: VDEP

Effective date: 20131023

REG Reference to a national code

Ref country code: AT

Ref legal event code: MK05

Ref document number: 637686

Country of ref document: AT

Kind code of ref document: T

Effective date: 20131023

REG Reference to a national code

Ref country code: LT

Ref legal event code: MG4D

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20140223

Ref country code: NL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20131023

Ref country code: LT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20131023

Ref country code: FI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20131023

Ref country code: SE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20131023

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: AT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20131023

Ref country code: LV

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20131023

Ref country code: CY

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20131023

BERE Be: lapsed

Owner name: HONNORAT RECHERCHES & SERVICES

Effective date: 20131231

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: PT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20140224

REG Reference to a national code

Ref country code: DE

Ref legal event code: R097

Ref document number: 602005041658

Country of ref document: DE

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: EE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20131023

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CZ

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20131023

Ref country code: MC

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20131023

Ref country code: SK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20131023

Ref country code: LU

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20131201

Ref country code: PL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20131023

Ref country code: RO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20131023

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

REG Reference to a national code

Ref country code: IE

Ref legal event code: MM4A

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20131023

26N No opposition filed

Effective date: 20140724

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: BE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20131231

Ref country code: IE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20131201

REG Reference to a national code

Ref country code: DE

Ref legal event code: R097

Ref document number: 602005041658

Country of ref document: DE

Effective date: 20140724

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GB

Payment date: 20141218

Year of fee payment: 10

Ref country code: CH

Payment date: 20141215

Year of fee payment: 10

Ref country code: ES

Payment date: 20141224

Year of fee payment: 10

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20131023

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 20141211

Year of fee payment: 10

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: TR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20131023

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: HU

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT; INVALID AB INITIO

Effective date: 20051201

Ref country code: BG

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20131023

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20131023

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 11

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20140124

REG Reference to a national code

Ref country code: DE

Ref legal event code: R119

Ref document number: 602005041658

Country of ref document: DE

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 20151201

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20160701

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20151231

Ref country code: GB

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20151201

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20151231

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 12

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: ES

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20151202

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 13

REG Reference to a national code

Ref country code: ES

Ref legal event code: FD2A

Effective date: 20180706

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 14

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: IT

Payment date: 20181210

Year of fee payment: 14

Ref country code: FR

Payment date: 20181030

Year of fee payment: 14

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: FR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20191231

Ref country code: IT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20191201