EP1816234B1 - Wässrige Reaktionslösung und Verfahren zur Passivierung von Zink- und Zinklegierungen - Google Patents
Wässrige Reaktionslösung und Verfahren zur Passivierung von Zink- und Zinklegierungen Download PDFInfo
- Publication number
- EP1816234B1 EP1816234B1 EP06001930A EP06001930A EP1816234B1 EP 1816234 B1 EP1816234 B1 EP 1816234B1 EP 06001930 A EP06001930 A EP 06001930A EP 06001930 A EP06001930 A EP 06001930A EP 1816234 B1 EP1816234 B1 EP 1816234B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- reaction solution
- zinc
- aqueous reaction
- acid
- workpieces
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000011701 zinc Substances 0.000 title claims abstract description 37
- 229910052725 zinc Inorganic materials 0.000 title claims abstract description 33
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 title claims abstract description 30
- 238000000034 method Methods 0.000 title claims abstract description 29
- 229910001297 Zn alloy Inorganic materials 0.000 title claims abstract description 21
- 239000008199 coating composition Substances 0.000 title 1
- 238000006243 chemical reaction Methods 0.000 claims abstract description 62
- PVNIIMVLHYAWGP-UHFFFAOYSA-N Niacin Chemical compound OC(=O)C1=CC=CN=C1 PVNIIMVLHYAWGP-UHFFFAOYSA-N 0.000 claims abstract description 30
- 150000003839 salts Chemical class 0.000 claims abstract description 17
- 229960003512 nicotinic acid Drugs 0.000 claims abstract description 14
- 235000001968 nicotinic acid Nutrition 0.000 claims abstract description 14
- 239000011664 nicotinic acid Substances 0.000 claims abstract description 14
- 229910001430 chromium ion Inorganic materials 0.000 claims abstract description 7
- 239000000243 solution Substances 0.000 claims description 71
- -1 halide ion Chemical class 0.000 claims description 19
- 239000011651 chromium Substances 0.000 claims description 14
- 239000002253 acid Substances 0.000 claims description 13
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 9
- 229910052742 iron Inorganic materials 0.000 claims description 9
- 229910052782 aluminium Inorganic materials 0.000 claims description 7
- 150000001875 compounds Chemical class 0.000 claims description 7
- 229910017604 nitric acid Inorganic materials 0.000 claims description 7
- XLJKHNWPARRRJB-UHFFFAOYSA-N cobalt(2+) Chemical compound [Co+2] XLJKHNWPARRRJB-UHFFFAOYSA-N 0.000 claims description 6
- 238000007654 immersion Methods 0.000 claims description 5
- 229910052759 nickel Inorganic materials 0.000 claims description 5
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims description 4
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 4
- 229910021645 metal ion Inorganic materials 0.000 claims description 4
- 229910052804 chromium Inorganic materials 0.000 claims description 3
- 229910052747 lanthanoid Inorganic materials 0.000 claims description 3
- 150000002602 lanthanoids Chemical class 0.000 claims description 3
- 229910052750 molybdenum Inorganic materials 0.000 claims description 3
- 159000000000 sodium salts Chemical class 0.000 claims description 3
- 239000007864 aqueous solution Substances 0.000 claims description 2
- 229910052802 copper Inorganic materials 0.000 claims description 2
- 239000010949 copper Substances 0.000 claims description 2
- 229910052733 gallium Inorganic materials 0.000 claims description 2
- 229910052735 hafnium Inorganic materials 0.000 claims description 2
- 229910052738 indium Inorganic materials 0.000 claims description 2
- 229910052758 niobium Inorganic materials 0.000 claims description 2
- 229910052706 scandium Inorganic materials 0.000 claims description 2
- 229910052715 tantalum Inorganic materials 0.000 claims description 2
- 229910052719 titanium Inorganic materials 0.000 claims description 2
- 229910052721 tungsten Inorganic materials 0.000 claims description 2
- 229910052720 vanadium Inorganic materials 0.000 claims description 2
- 229910052727 yttrium Inorganic materials 0.000 claims description 2
- 229910052726 zirconium Inorganic materials 0.000 claims description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims 1
- 229910052748 manganese Inorganic materials 0.000 claims 1
- 239000011572 manganese Substances 0.000 claims 1
- 239000001117 sulphuric acid Substances 0.000 claims 1
- 235000011149 sulphuric acid Nutrition 0.000 claims 1
- 239000010410 layer Substances 0.000 description 48
- 230000007797 corrosion Effects 0.000 description 29
- 238000005260 corrosion Methods 0.000 description 29
- 238000002161 passivation Methods 0.000 description 29
- 238000004532 chromating Methods 0.000 description 19
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 15
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical compound [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 15
- 239000000203 mixture Substances 0.000 description 15
- JOPOVCBBYLSVDA-UHFFFAOYSA-N chromium(6+) Chemical compound [Cr+6] JOPOVCBBYLSVDA-UHFFFAOYSA-N 0.000 description 14
- 230000004224 protection Effects 0.000 description 13
- BFGKITSFLPAWGI-UHFFFAOYSA-N chromium(3+) Chemical compound [Cr+3] BFGKITSFLPAWGI-UHFFFAOYSA-N 0.000 description 11
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 8
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 150000002500 ions Chemical class 0.000 description 7
- 150000004760 silicates Chemical class 0.000 description 7
- 229910052684 Cerium Inorganic materials 0.000 description 6
- 240000007817 Olea europaea Species 0.000 description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 6
- PHFQLYPOURZARY-UHFFFAOYSA-N chromium trinitrate Chemical compound [Cr+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O PHFQLYPOURZARY-UHFFFAOYSA-N 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 239000007800 oxidant agent Substances 0.000 description 6
- 239000007921 spray Substances 0.000 description 6
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Natural products OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 4
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 4
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 description 4
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- 150000002390 heteroarenes Chemical class 0.000 description 4
- 229910052500 inorganic mineral Chemical class 0.000 description 4
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- 150000007513 acids Chemical class 0.000 description 3
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 3
- 239000010953 base metal Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 229910017052 cobalt Inorganic materials 0.000 description 3
- 239000010941 cobalt Substances 0.000 description 3
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 3
- UFMZWBIQTDUYBN-UHFFFAOYSA-N cobalt dinitrate Chemical class [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 description 3
- 229910001429 cobalt ion Inorganic materials 0.000 description 3
- 238000007598 dipping method Methods 0.000 description 3
- 238000005246 galvanizing Methods 0.000 description 3
- 229910052761 rare earth metal Inorganic materials 0.000 description 3
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Natural products OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- WLJVNTCWHIRURA-UHFFFAOYSA-N Heptanedioic acid Natural products OC(=O)CCCCCC(O)=O WLJVNTCWHIRURA-UHFFFAOYSA-N 0.000 description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 2
- BDJRBEYXGGNYIS-UHFFFAOYSA-N Nonanedioid acid Natural products OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 2
- 229910004298 SiO 2 Inorganic materials 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- TYFQFVWCELRYAO-UHFFFAOYSA-N Suberic acid Natural products OC(=O)CCCCCCC(O)=O TYFQFVWCELRYAO-UHFFFAOYSA-N 0.000 description 2
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 2
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N benzene-dicarboxylic acid Natural products OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- XQTIWNLDFPPCIU-UHFFFAOYSA-N cerium(3+) Chemical compound [Ce+3] XQTIWNLDFPPCIU-UHFFFAOYSA-N 0.000 description 2
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- 239000011248 coating agent Substances 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
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- 238000002474 experimental method Methods 0.000 description 2
- 150000004820 halides Chemical class 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N hexanedioic acid Natural products OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052746 lanthanum Inorganic materials 0.000 description 2
- 239000003446 ligand Substances 0.000 description 2
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 2
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- 239000011733 molybdenum Substances 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N n-Decanedioic acid Natural products OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N o-dicarboxybenzene Natural products OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
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- PUZPDOWCWNUUKD-UHFFFAOYSA-M sodium fluoride Chemical compound [F-].[Na+] PUZPDOWCWNUUKD-UHFFFAOYSA-M 0.000 description 2
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- 231100000331 toxic Toxicity 0.000 description 2
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- HFVMEOPYDLEHBR-UHFFFAOYSA-N (2-fluorophenyl)-phenylmethanol Chemical compound C=1C=CC=C(F)C=1C(O)C1=CC=CC=C1 HFVMEOPYDLEHBR-UHFFFAOYSA-N 0.000 description 1
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 1
- FFRBMBIXVSCUFS-UHFFFAOYSA-N 2,4-dinitro-1-naphthol Chemical compound C1=CC=C2C(O)=C([N+]([O-])=O)C=C([N+]([O-])=O)C2=C1 FFRBMBIXVSCUFS-UHFFFAOYSA-N 0.000 description 1
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- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 1
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- LDDQLRUQCUTJBB-UHFFFAOYSA-O azanium;hydrofluoride Chemical compound [NH4+].F LDDQLRUQCUTJBB-UHFFFAOYSA-O 0.000 description 1
- YOUGRGFIHBUKRS-UHFFFAOYSA-N benzyl(trimethyl)azanium Chemical compound C[N+](C)(C)CC1=CC=CC=C1 YOUGRGFIHBUKRS-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
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- QSWDMMVNRMROPK-UHFFFAOYSA-K chromium(3+) trichloride Chemical compound [Cl-].[Cl-].[Cl-].[Cr+3] QSWDMMVNRMROPK-UHFFFAOYSA-K 0.000 description 1
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- 230000000087 stabilizing effect Effects 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000012756 surface treatment agent Substances 0.000 description 1
- 238000010189 synthetic method Methods 0.000 description 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- APSPVJKFJYTCTN-UHFFFAOYSA-N tetramethylazanium;silicate Chemical compound C[N+](C)(C)C.C[N+](C)(C)C.C[N+](C)(C)C.C[N+](C)(C)C.[O-][Si]([O-])([O-])[O-] APSPVJKFJYTCTN-UHFFFAOYSA-N 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 150000003628 tricarboxylic acids Chemical class 0.000 description 1
- ZNEOHLHCKGUAEB-UHFFFAOYSA-N trimethylphenylammonium Chemical compound C[N+](C)(C)C1=CC=CC=C1 ZNEOHLHCKGUAEB-UHFFFAOYSA-N 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 208000029257 vision disease Diseases 0.000 description 1
- 230000004393 visual impairment Effects 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 1
- GTLDTDOJJJZVBW-UHFFFAOYSA-N zinc cyanide Chemical compound [Zn+2].N#[C-].N#[C-] GTLDTDOJJJZVBW-UHFFFAOYSA-N 0.000 description 1
- XLOMVQKBTHCTTD-UHFFFAOYSA-N zinc oxide Inorganic materials [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/82—After-treatment
- C23C22/84—Dyeing
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/07—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
- C23C22/08—Orthophosphates
- C23C22/12—Orthophosphates containing zinc cations
- C23C22/17—Orthophosphates containing zinc cations containing also organic acids
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/34—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/48—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 not containing phosphates, hexavalent chromium compounds, fluorides or complex fluorides, molybdates, tungstates, vanadates or oxalates
- C23C22/53—Treatment of zinc or alloys based thereon
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2222/00—Aspects relating to chemical surface treatment of metallic material by reaction of the surface with a reactive medium
- C23C2222/10—Use of solutions containing trivalent chromium but free of hexavalent chromium
Definitions
- Metallic materials are galvanized or cemented to protect them from corrosive environmental influences.
- the corrosion protection of zinc is based on the fact that it is still less noble than the base metal and therefore initially attracts only the corrosive attack, it acts as a sacrificial layer.
- the base metal of the galvanized component in question remains intact while it is still completely covered with zinc, and the mechanical functionality is retained for longer periods of time than with non-galvanized parts.
- thick zinc coatings provide a higher level of corrosion protection than thin layers - the corrosive removal of thick layers takes even longer.
- GB-A-2 097 024 the treatment of metal surfaces to improve corrosion protection on zinc and zinc alloy surfaces with an aqueous acidic solution comprising an oxidizing agent and at least one metal selected from the group consisting of iron, cobalt, nickel, molybdenum, manganese, aluminum, lanthanum, lanthanide mixtures or cerium ions or mixtures thereof and in particular iron and cobalt ions.
- an aqueous acidic solution comprising an oxidizing agent and at least one metal selected from the group consisting of iron, cobalt, nickel, molybdenum, manganese, aluminum, lanthanum, lanthanide mixtures or cerium ions or mixtures thereof and in particular iron and cobalt ions.
- GB-A-2 097 024 the use of trivalent chromium ions and iron ions in combination with an additional metal selected from the group consisting of the abovementioned ions or cerium ions, but mainly describes combinations of chromium (III) in combination with an
- the present invention has for its object to provide a solution and a method for producing chromium (III) -containing and chromium (VI) -free yellow passivation layers that are color intensive and long-term stability.
- These metal ions may be added to the reaction solution as soluble salts, preferably as nitrates, sulfates or halides.
- cobalt (II) ions are contained in a concentration of at least about 0.1 g / L. Their concentration may preferably reach up to 5 g / l.
- reaction solution can also be used to treat workpieces in accordance with the invention in which, in addition to the zinc or zinc alloy surfaces, surfaces which are not zinc or a zinc alloy, for example iron-containing surfaces such as steel surfaces, are also exposed. These other surfaces can be passivated together with the zinc or zinc alloy surfaces.
- the reaction solution of the invention also for the passage of aluminum, aluminum alloy surfaces and surfaces made of cadmium.
Priority Applications (10)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL06001930T PL1816234T3 (pl) | 2006-01-31 | 2006-01-31 | Reakcyjny roztwór wodny oraz metoda pasywacji cynku i stopów cynku |
| EP06001930A EP1816234B1 (de) | 2006-01-31 | 2006-01-31 | Wässrige Reaktionslösung und Verfahren zur Passivierung von Zink- und Zinklegierungen |
| AT06001930T ATE431442T1 (de) | 2006-01-31 | 2006-01-31 | Wässrige reaktionslösung und verfahren zur passivierung von zink- und zinklegierungen |
| DE502006003710T DE502006003710D1 (de) | 2006-01-31 | 2006-01-31 | Wässrige Reaktionslösung und Verfahren zur Passivierung von Zink- und Zinklegierungen |
| CN2007800013029A CN101356301B (zh) | 2006-01-31 | 2007-01-23 | 钝化具有锌或锌合金表面的加工件的含水反应溶液和方法 |
| JP2008551736A JP5130226B2 (ja) | 2006-01-31 | 2007-01-23 | 亜鉛または亜鉛合金表面を有する加工部品を不動態化するための水性反応溶液及び方法 |
| US12/086,796 US8262811B2 (en) | 2006-01-31 | 2007-01-23 | Aqueous reaction solution and method of passivating workpieces having zinc or zinc alloy surfaces and use of a heteroaromatic compound |
| CA2624215A CA2624215C (en) | 2006-01-31 | 2007-01-23 | Aqueous reaction solution and method of passivating workpieces having zinc or zinc alloy surfaces |
| EP07703155A EP1979507A1 (en) | 2006-01-31 | 2007-01-23 | Aqueous reaction solution and method of passivating workpieces having zinc or zinc alloy surfaces |
| PCT/EP2007/000805 WO2007088030A1 (en) | 2006-01-31 | 2007-01-23 | Aqueous reaction solution and method of passivating workpieces having zinc or zinc alloy surfaces |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP06001930A EP1816234B1 (de) | 2006-01-31 | 2006-01-31 | Wässrige Reaktionslösung und Verfahren zur Passivierung von Zink- und Zinklegierungen |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP1816234A1 EP1816234A1 (de) | 2007-08-08 |
| EP1816234B1 true EP1816234B1 (de) | 2009-05-13 |
Family
ID=36602528
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP06001930A Active EP1816234B1 (de) | 2006-01-31 | 2006-01-31 | Wässrige Reaktionslösung und Verfahren zur Passivierung von Zink- und Zinklegierungen |
| EP07703155A Withdrawn EP1979507A1 (en) | 2006-01-31 | 2007-01-23 | Aqueous reaction solution and method of passivating workpieces having zinc or zinc alloy surfaces |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP07703155A Withdrawn EP1979507A1 (en) | 2006-01-31 | 2007-01-23 | Aqueous reaction solution and method of passivating workpieces having zinc or zinc alloy surfaces |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US8262811B2 (zh) |
| EP (2) | EP1816234B1 (zh) |
| JP (1) | JP5130226B2 (zh) |
| CN (1) | CN101356301B (zh) |
| AT (1) | ATE431442T1 (zh) |
| CA (1) | CA2624215C (zh) |
| DE (1) | DE502006003710D1 (zh) |
| PL (1) | PL1816234T3 (zh) |
| WO (1) | WO2007088030A1 (zh) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3889318A1 (en) | 2020-04-03 | 2021-10-06 | ATOTECH Deutschland GmbH | Method for forming a black-passivation layer on a zinc-iron alloy and black-passivation composition |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007100135A1 (ja) * | 2006-03-03 | 2007-09-07 | Dipsol Chemicals Co., Ltd. | 亜鉛又は亜鉛合金上に黒色の３価クロム化成皮膜を形成するための処理水溶液及び黒色３価クロム化成皮膜の形成方法 |
| DE102008044143B4 (de) * | 2008-11-27 | 2011-01-13 | Atotech Deutschland Gmbh | Wässrige Behandlungslösung und Verfahren zur Erzeugung von Konversionsschichten für zinkhaltige Oberflächen |
| CN101665935B (zh) * | 2009-09-27 | 2012-04-11 | 大连三达奥克化学股份有限公司 | 钢铁工件电泳涂装前常温皮膜钝化剂及其制备方法 |
| DE102010001686A1 (de) * | 2010-02-09 | 2011-08-11 | Henkel AG & Co. KGaA, 40589 | Zusammensetzung für die alkalische Passivierung von Zinkoberflächen |
| CN102560467A (zh) * | 2012-02-14 | 2012-07-11 | 济南德锡科技有限公司 | 一种高耐蚀镀锌黑色钝化剂及其配制方法 |
| US10005104B2 (en) * | 2013-08-28 | 2018-06-26 | Honda Motor Co., Ltd. | Black coating film-forming vehicle component and/or fastening component, and manufacturing method thereof |
| CN103789758B (zh) * | 2014-02-17 | 2016-09-07 | 默克新科技发展（天津）有限公司 | 一种镀锌层的金黄色钝化剂及其制备方法和钝化处理方法 |
| CN103866307A (zh) * | 2014-03-13 | 2014-06-18 | 沈阳市环东电镀厂 | 环保型一剂双色镀锌三价铬钝化剂及其制备和使用方法 |
| CN104451645A (zh) * | 2014-12-05 | 2015-03-25 | 上海奎鸣工程技术有限公司 | 一种三价铬钝化表面处理剂 |
| CN107109659B (zh) * | 2014-12-26 | 2020-05-05 | 迪普索股份公司 | 锌或锌合金基材用3价铬化成处理液和化成被膜 |
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| US3993548A (en) | 1975-05-21 | 1976-11-23 | Oxy Metal Industries Corporation | Zinc electrodeposition process and bath for use therein |
| US4384902A (en) | 1981-06-15 | 1983-05-24 | Occidental Chemical Corporation | Trivalent chromium passivate composition and process |
| CA1228000A (en) | 1981-04-16 | 1987-10-13 | David E. Crotty | Chromium appearance passivate solution and process |
| US4359348A (en) | 1981-06-17 | 1982-11-16 | Occidental Chemical Corporation | Stabilized trivalent chromium passivate composition and process |
| US4578122A (en) * | 1984-11-14 | 1986-03-25 | Omi International Corporation | Non-peroxide trivalent chromium passivate composition and process |
| DE4135524C2 (de) | 1991-10-28 | 1995-01-26 | Gc Galvano Consult Gmbh | Verfahren und Mittel zum Chromatieren von Oberflächen aus Zink oder Cadmium oder Legierungen davon |
| US5328526A (en) * | 1992-04-03 | 1994-07-12 | Nippon Paint Co., Ltd. | Method for zinc-phosphating metal surface |
| US6068711A (en) * | 1994-10-07 | 2000-05-30 | Mcmaster University | Method of increasing corrosion resistance of metals and alloys by treatment with rare earth elements |
| EP0902103B1 (en) * | 1996-02-05 | 2004-12-29 | Nippon Steel Corporation | Surface-treated metallic material with corrosion resistance and surface treatment used therefor |
| US6190780B1 (en) * | 1996-02-05 | 2001-02-20 | Nippon Steel Corporation | Surface treated metal material and surface treating agent |
| JPH1161429A (ja) * | 1997-08-28 | 1999-03-05 | Nippon Steel Corp | 表面処理金属材料 |
| US7314671B1 (en) | 1996-04-19 | 2008-01-01 | Surtec International Gmbh | Chromium(VI)-free conversion layer and method for producing it |
| DE19615664A1 (de) | 1996-04-19 | 1997-10-23 | Surtec Produkte Und Systeme Fu | Chrom(VI)freie Chromatschicht sowie Verfahren zu ihrer Herstellung |
| WO1998048075A1 (fr) * | 1997-04-24 | 1998-10-29 | Nippon Steel Corporation | Tole enduite et fluide de traitement de surface pour metaux |
| JP2001279462A (ja) * | 2000-03-30 | 2001-10-10 | Boshin Ro | 亜鉛又は亜鉛合金の表面処理剤及び表面処理方法 |
| US7294211B2 (en) * | 2002-01-04 | 2007-11-13 | University Of Dayton | Non-toxic corrosion-protection conversion coats based on cobalt |
| US7029541B2 (en) * | 2002-01-24 | 2006-04-18 | Pavco, Inc. | Trivalent chromate conversion coating |
| DE10305449A1 (de) | 2003-02-11 | 2004-08-26 | Walter Hillebrand Gmbh & Co. | Pigmenthaltiges Stoffgemisch zur Erzeugung farbiger Passivierungsschichten |
| JP2006022364A (ja) * | 2004-07-07 | 2006-01-26 | Nippon Hyomen Kagaku Kk | 金属の保護皮膜形成処理剤と形成方法 |
| JP4429214B2 (ja) * | 2005-06-07 | 2010-03-10 | 株式会社ムラタ | 表面処理液及び化成皮膜の形成方法 |
| JP2005327741A (ja) * | 2005-07-13 | 2005-11-24 | Ngk Spark Plug Co Ltd | スパークプラグ用ガスケット及びそれを備えたスパークプラグ |
-
2006
- 2006-01-31 DE DE502006003710T patent/DE502006003710D1/de active Active
- 2006-01-31 AT AT06001930T patent/ATE431442T1/de not_active IP Right Cessation
- 2006-01-31 PL PL06001930T patent/PL1816234T3/pl unknown
- 2006-01-31 EP EP06001930A patent/EP1816234B1/de active Active
-
2007
- 2007-01-23 JP JP2008551736A patent/JP5130226B2/ja active Active
- 2007-01-23 CA CA2624215A patent/CA2624215C/en active Active
- 2007-01-23 WO PCT/EP2007/000805 patent/WO2007088030A1/en active Application Filing
- 2007-01-23 EP EP07703155A patent/EP1979507A1/en not_active Withdrawn
- 2007-01-23 US US12/086,796 patent/US8262811B2/en active Active
- 2007-01-23 CN CN2007800013029A patent/CN101356301B/zh active Active
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3889318A1 (en) | 2020-04-03 | 2021-10-06 | ATOTECH Deutschland GmbH | Method for forming a black-passivation layer on a zinc-iron alloy and black-passivation composition |
| WO2021198429A1 (en) | 2020-04-03 | 2021-10-07 | Atotech Deutschland Gmbh | Method for forming a black-passivation layer on a zinc-iron alloy and black-passivation composition |
Also Published As
| Publication number | Publication date |
|---|---|
| ATE431442T1 (de) | 2009-05-15 |
| US8262811B2 (en) | 2012-09-11 |
| CN101356301B (zh) | 2011-12-28 |
| CN101356301A (zh) | 2009-01-28 |
| CA2624215A1 (en) | 2007-08-09 |
| WO2007088030A1 (en) | 2007-08-09 |
| EP1816234A1 (de) | 2007-08-08 |
| EP1979507A1 (en) | 2008-10-15 |
| JP2009525398A (ja) | 2009-07-09 |
| CA2624215C (en) | 2013-07-02 |
| US20090032146A1 (en) | 2009-02-05 |
| PL1816234T3 (pl) | 2009-10-30 |
| DE502006003710D1 (de) | 2009-06-25 |
| JP5130226B2 (ja) | 2013-01-30 |
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