EP1778883A4 - Verfahren zur gewinnung von nickel und cobalt aus lateriterzen durch kombination von auslaugung unter normaldruck und moderatem druck - Google Patents

Verfahren zur gewinnung von nickel und cobalt aus lateriterzen durch kombination von auslaugung unter normaldruck und moderatem druck

Info

Publication number
EP1778883A4
EP1778883A4 EP05761684A EP05761684A EP1778883A4 EP 1778883 A4 EP1778883 A4 EP 1778883A4 EP 05761684 A EP05761684 A EP 05761684A EP 05761684 A EP05761684 A EP 05761684A EP 1778883 A4 EP1778883 A4 EP 1778883A4
Authority
EP
European Patent Office
Prior art keywords
leach
nickel
ore
recited
iron
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP05761684A
Other languages
English (en)
French (fr)
Other versions
EP1778883A1 (de
Inventor
David Neudorf
David A Huggins
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SKYE RESOURCES Inc
Original Assignee
SKYE RESOURCES Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SKYE RESOURCES Inc filed Critical SKYE RESOURCES Inc
Publication of EP1778883A1 publication Critical patent/EP1778883A1/de
Publication of EP1778883A4 publication Critical patent/EP1778883A4/de
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B23/00—Obtaining nickel or cobalt
    • C22B23/04—Obtaining nickel or cobalt by wet processes
    • C22B23/0407—Leaching processes
    • C22B23/0415—Leaching processes with acids or salt solutions except ammonium salts solutions
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B23/00—Obtaining nickel or cobalt
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B23/00—Obtaining nickel or cobalt
    • C22B23/04—Obtaining nickel or cobalt by wet processes
    • C22B23/0407—Leaching processes
    • C22B23/0415—Leaching processes with acids or salt solutions except ammonium salts solutions
    • C22B23/043—Sulfurated acids or salts thereof
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B23/00—Obtaining nickel or cobalt
    • C22B23/04—Obtaining nickel or cobalt by wet processes
    • C22B23/0453—Treatment or purification of solutions, e.g. obtained by leaching
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B23/00—Obtaining nickel or cobalt
    • C22B23/04—Obtaining nickel or cobalt by wet processes
    • C22B23/0453—Treatment or purification of solutions, e.g. obtained by leaching
    • C22B23/0461—Treatment or purification of solutions, e.g. obtained by leaching by chemical methods
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/20—Recycling

Definitions

  • U.S. Pat. No. 4,097,575 describes an improvement to the HPAL process which constitutes roasting saprolite ore below about 820 0 C in order to render the ore more reactive with sulfuric acid and then using the roaster calcine to neutralize excess acid in the discharge of an autoclave wherein pressure leaching of limonite ore occurs. Nickel contained in the saprolite ore is largely dissolved during this neutralization.
  • an iron-bearing "seed" material is added to the leach slurry at the start of the saprolite pressure leach stage to accelerate the precipitation of dissolved ferric iron and the extraction of remaining nickel and cobalt from the solid phases.
  • FIG. 2 is a flow sheet showing another embodiment of the process of the present invention in which some of the leach residue is recycled in order to provide seed for iron precipitation.
  • a reductant is added to the limonite leach slurry in order to enhance the dissolution of nickel, and particularly cobalt, from the ore.
  • Most of the cobalt and a smaller proportion of the nickel present in limonite ore is contained typically in a variety of oxidized manganese minerals, referred to collectively as "manganese wad.”
  • Manganese is typically in the tetravalent or trivalent state in these minerals and is refractory to acid leaching unless a reductant is added to cause the manganese to dissolve in the divalent form. The dissolution of manganese is necessary to allow the contained cobalt and nickel to dissolve as well, as will be apparent to those skilled in the art.
  • Suitable reductants include sulfur dioxide (SO 2 ), either as a gas or aqueous solution of SO 2 and ferrous iron, as a soluble salt, e.g. ferrous sulfate, although many other reducing species will also react with oxidized manganese compounds.
  • SO 2 sulfur dioxide
  • ferrous iron as a soluble salt, e.g. ferrous sulfate, although many other reducing species will also react with oxidized manganese compounds.
  • the resulting limonite leach slurry is injected into an autoclave along with the saprolite ore.
  • the saprolite ore typically will be prepared by crushing, grinding and screening or cycloning of the run-of-mine saprolite ore to achieve a particle size that allows the saprolite ore particles to be suspended in the autoclave reactor during the leaching process.
  • the resulting slurry is heated to the desired reaction temperature, for example in the range of 120 to 160 0 C, by any appropriate means, for example by direct injection of intermediate pressure steam into the autoclave, or by direct or indirect steam heating of the leach slurry prior to injection into the autoclave.
  • the autoclave retention time is sufficient to allow most of the iron in solution after the limonite atmospheric leach to hydrolyze and precipitate, and the acid regenerated by iron hydrolysis to react with the saprolite ore, thus extracting most of the contained nickel and cobalt, as well as magnesium and other impurity metals.
  • the saprolite was wet ground to -100 mesh and filtered to produce a filtercake. 262 g (dry basis) of this filtercake was added to the limonite leach slurry, which was then transferred to an autoclave. The autoclave was sealed and heated to 150 0 C, at which temperature leaching was allowed to continue for an additional hour before rapidly cooling the autoclave. The slurry was sampled at the completion of the additional one- hour leach period. The saprolite to limonite ratio was 1.1 and the sulfuric acid addition was 650 kg H 2 SO4 per tonne of ore in this test.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacture And Refinement Of Metals (AREA)
EP05761684A 2004-08-02 2005-06-23 Verfahren zur gewinnung von nickel und cobalt aus lateriterzen durch kombination von auslaugung unter normaldruck und moderatem druck Withdrawn EP1778883A4 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US59237504P 2004-08-02 2004-08-02
PCT/CA2005/000988 WO2006029499A1 (en) 2004-08-02 2005-06-23 Method for nickel and cobalt recovery from laterite ores by combination of atmospheric and moderate pressure leaching

Publications (2)

Publication Number Publication Date
EP1778883A1 EP1778883A1 (de) 2007-05-02
EP1778883A4 true EP1778883A4 (de) 2007-08-29

Family

ID=36059658

Family Applications (1)

Application Number Title Priority Date Filing Date
EP05761684A Withdrawn EP1778883A4 (de) 2004-08-02 2005-06-23 Verfahren zur gewinnung von nickel und cobalt aus lateriterzen durch kombination von auslaugung unter normaldruck und moderatem druck

Country Status (12)

Country Link
US (1) US20060024224A1 (de)
EP (1) EP1778883A4 (de)
JP (1) JP2008508428A (de)
KR (1) KR20070041770A (de)
CN (1) CN100402679C (de)
AU (1) AU2005284620A1 (de)
BR (1) BRPI0513652A (de)
CA (1) CA2572420A1 (de)
GT (1) GT200600110A (de)
TW (1) TW200607867A (de)
WO (1) WO2006029499A1 (de)
ZA (1) ZA200701848B (de)

Families Citing this family (47)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007092994A1 (en) * 2006-02-15 2007-08-23 Andreazza Consulting Pty Ltd Processing of laterite ore
CA2641919A1 (en) * 2006-02-24 2007-08-30 Murrin Murrin Operations Pty Ltd. Hematite precipitation at elevated temperature and pressure
BRPI0612374B1 (pt) * 2006-11-10 2015-08-11 Vale Sa Processo de recuperação de níquel e cobalto a partir de minérios lateríticos empregando resina de troca iônica e produto contendo níquel ou cobalto
EP2152631B1 (de) * 2007-05-02 2014-12-31 Drinkard Metalox, Inc. Nickel-laterit-verfahren
EP2171108A4 (de) * 2007-05-03 2011-03-30 Drinkard Metalox Inc Verfahren zur rückgewinnung von metallwerten aus erzen
WO2008138039A1 (en) * 2007-05-14 2008-11-20 Bhp Billiton Ssm Development Pty Ltd Nickel recovery from a high ferrous content laterite ore
WO2008138038A1 (en) * 2007-05-14 2008-11-20 Bhp Billiton Ssm Development Pty Ltd LOW Eh LEACH WITH SULFUR RECYCLE
US20090056502A1 (en) * 2007-08-29 2009-03-05 Vale Inco Limited Hydrometallurgical process for recovery of nickel and cobalt
AU2008299386B2 (en) 2007-09-14 2012-01-12 Barrick Gold Corporation Process for recovering platinum group metals using reductants
EP2200943A4 (de) * 2007-09-21 2012-06-20 Res Inst Ind Science & Tech Verfahren zur herstellung von fe- und ni-haltigem material und co-haltigem material unter verwendung von rezyklierungsrückstand von verbrauchtem katalysator und verfahren zur herstellung von ausgangsstoff für nichtrostenden stahl unter verwendung des fe- und ni-haltigen materials und verfahren zur herstellung von fe-ni-legierung
CN101270417B (zh) * 2008-04-30 2010-11-03 江西稀有稀土金属钨业集团有限公司 一种提取镍和/或钴的方法
JP5332418B2 (ja) * 2008-09-04 2013-11-06 住友金属鉱山株式会社 オートクレーブの圧力調整方法
EP2370607A1 (de) * 2008-11-28 2011-10-05 BHP Billiton SSM Development Pty Ltd Verfahren zum trennen von limonit und saprolit
TWI401213B (zh) * 2010-02-02 2013-07-11 廢加氫脫硫觸媒中鎳鈷精礦資源化回收方法
FI123646B (fi) 2010-02-25 2013-08-30 Outotec Oyj Menetelmä kiintoaine-neste-erotuksen tehostamiseksi lateriittien liuotuksen yhteydessä
CN101805828B (zh) * 2010-04-19 2012-01-18 中南大学 一种低成本处理红土镍矿的方法
CN101974685B (zh) * 2010-11-05 2013-02-27 吉林吉恩镍业股份有限公司 用矿浆树脂吸附技术从红土矿中提取镍钴工艺
CN102010993B (zh) * 2010-11-10 2012-07-04 吉林吉恩镍业股份有限公司 用矿浆萃取技术从红土矿中提取镍钴
KR101172897B1 (ko) * 2010-12-13 2012-08-10 재단법인 포항산업과학연구원 니켈 함유 원료로부터 니켈을 회수하는 방법
KR101191042B1 (ko) 2011-12-27 2012-10-15 강호길 니켈정광, 니켈매트로부터 고순도 황산니켈을 제조하는 방법
JP5704410B2 (ja) * 2012-03-21 2015-04-22 住友金属鉱山株式会社 製鉄用ヘマタイトの製造方法
CN102676806A (zh) * 2012-04-18 2012-09-19 赣州腾远钴业有限公司 一种利用二氧化硫还原浸出含钴物料的方法
CA2870199A1 (en) 2012-05-01 2013-11-07 Dow Global Technologies Llc Nickel and cobalt recovery using continuous ion exchange
WO2014047672A1 (en) * 2012-09-28 2014-04-03 Direct Nickel Pty Ltd Method for the recovery of metals from nickel bearing ores and concentrates
CN103936080B (zh) * 2013-03-20 2015-10-07 江苏理工学院 一种黄钾铁矾的制备方法
CN103614571A (zh) * 2013-10-09 2014-03-05 北京矿冶研究总院 一种红土镍矿联合浸出的工艺
US10030286B1 (en) 2013-11-13 2018-07-24 Ii-Vi Incorporated Method of direct solvent extraction of rare earth metals from an aqueous acid-leached ore slurry
CN103757261B (zh) * 2013-12-05 2016-07-06 中国科学院过程工程研究所 一种红土镍矿盐酸常压浸出过程铁与镍、钴、硅分离与综合利用的清洁生产方法
CN103757239A (zh) * 2013-12-29 2014-04-30 四川师范大学 镍氢废电池正负极混合材料的浸出方法
CN104630505A (zh) * 2014-12-31 2015-05-20 金川集团股份有限公司 一种通过联合浸出工艺从低品位红土镍矿中回收镍、钴、铁和硅的方法
CN104789766A (zh) * 2014-12-31 2015-07-22 金川集团股份有限公司 通过联合浸出工艺从红土镍矿中回收镍、铁和硅的方法
CN104630502A (zh) * 2014-12-31 2015-05-20 金川集团股份有限公司 一种通过联合浸出工艺从褐铁矿中回收镍、钴、铁和硅的方法
CN104651609A (zh) * 2014-12-31 2015-05-27 金川集团股份有限公司 一种从红土镍矿中回收镍、钴和铁的方法
CN104611579A (zh) * 2014-12-31 2015-05-13 金川集团股份有限公司 一种从低品位红土镍矿中回收镍的方法
CN104611582A (zh) * 2014-12-31 2015-05-13 金川集团股份有限公司 一种通过联合浸出工艺从低品位红土镍矿中回收镍、钴、铁和硅的方法
CN104611581A (zh) * 2014-12-31 2015-05-13 金川集团股份有限公司 一种从低品位红土镍矿中提取镍的方法
CN104611580A (zh) * 2014-12-31 2015-05-13 金川集团股份有限公司 一种处理低品位红土镍矿的方法
CN104805283A (zh) * 2014-12-31 2015-07-29 金川集团股份有限公司 常压酸浸和中等压力浸出相结合处理红土镍矿的方法
US10933410B2 (en) 2015-10-30 2021-03-02 Ii-Vi Delaware, Inc. Composite extractant-enhanced polymer resin, method of making the same, and its usage for extraction of valuable metal(s)
US10808296B2 (en) 2015-10-30 2020-10-20 Ii-Vi Delaware, Inc. Selective recovery of rare earth metals from an acidic slurry or acidic solution
CN106929672B8 (zh) * 2017-04-07 2019-01-11 中南大学 一种利用晶种诱导除铁促进黄铜矿生物浸出的方法
CN107312930B (zh) * 2017-07-07 2018-08-28 金川集团股份有限公司 一种低镍锍硝酸浸出液热解除铁的方法
US11473170B2 (en) 2017-09-25 2022-10-18 Mohammad Asadrokht Treatment of non-sulfidic nickeliferous resources and recovery of metal values therefrom
CN114555539A (zh) 2019-08-13 2022-05-27 加州理工学院 由含钙岩石和矿物生产氧化钙或普通波特兰水泥的工艺
CN111100985B (zh) * 2019-12-30 2021-05-18 荆门市格林美新材料有限公司 一种含钠铵废液应用于红土镍矿的综合处理方法
CN113373315A (zh) * 2021-05-18 2021-09-10 厦门嘉鹭金属工业有限公司 一种高效回收钨渣中钴镍的方法
CN115180661B (zh) * 2022-07-22 2024-02-13 余姚市鑫和电池材料有限公司 一种从铁铝废渣中回收镍钴铜混合硫酸盐的方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3804613A (en) * 1971-09-16 1974-04-16 American Metal Climax Inc Ore conditioning process for the efficient recovery of nickel from relatively high magnesium containing oxidic nickel ores
US6379636B2 (en) * 1999-11-03 2002-04-30 Bhp Minerals International, Inc. Method for leaching nickeliferous laterite ores
WO2003093517A1 (en) * 2002-04-29 2003-11-13 Qni Technology Pty Ltd Atmospheric pressure leach process for lateritic nickel ore
US6680035B2 (en) * 1999-11-03 2004-01-20 Bhp Minerals International Inc. Atmospheric leach process for the recovery of nickel and cobalt from limonite and saprolite ores

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3772422A (en) * 1971-09-07 1973-11-13 M Taylor Process for the selective recovery of chromium from chromium containing materials and solutions
US3793432A (en) * 1972-01-27 1974-02-19 D Weston Hydrometallurgical treatment of nickel group ores
US4097575A (en) * 1976-11-05 1978-06-27 Amax Inc. Roast-neutralization-leach technique for the treatment of laterite ore
US4548794A (en) * 1983-07-22 1985-10-22 California Nickel Corporation Method of recovering nickel from laterite ores
US5571308A (en) * 1995-07-17 1996-11-05 Bhp Minerals International Inc. Method for recovering nickel from high magnesium-containing Ni-Fe-Mg lateritic ore

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3804613A (en) * 1971-09-16 1974-04-16 American Metal Climax Inc Ore conditioning process for the efficient recovery of nickel from relatively high magnesium containing oxidic nickel ores
US6379636B2 (en) * 1999-11-03 2002-04-30 Bhp Minerals International, Inc. Method for leaching nickeliferous laterite ores
US6680035B2 (en) * 1999-11-03 2004-01-20 Bhp Minerals International Inc. Atmospheric leach process for the recovery of nickel and cobalt from limonite and saprolite ores
WO2003093517A1 (en) * 2002-04-29 2003-11-13 Qni Technology Pty Ltd Atmospheric pressure leach process for lateritic nickel ore

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
BOLT J.R. JR.: "The Winning of Nickel, its Geology, Mining, and Extractive Metallurgy", 1967, LONGMANS CANADA LTD. *

Also Published As

Publication number Publication date
CN101001964A (zh) 2007-07-18
ZA200701848B (en) 2008-04-30
BRPI0513652A (pt) 2008-05-13
US20060024224A1 (en) 2006-02-02
GT200600110A (es) 2006-04-26
WO2006029499A1 (en) 2006-03-23
EP1778883A1 (de) 2007-05-02
AU2005284620A1 (en) 2006-03-23
JP2008508428A (ja) 2008-03-21
CA2572420A1 (en) 2006-03-23
TW200607867A (en) 2006-03-01
CN100402679C (zh) 2008-07-16
KR20070041770A (ko) 2007-04-19

Similar Documents

Publication Publication Date Title
US20060024224A1 (en) Method for nickel and cobalt recovery from laterite ores by combination of atmospheric and moderate pressure leaching
US20060002835A1 (en) Method for nickel and cobalt recovery from laterite ores by reaction with concentrated acid and water leaching
US4410498A (en) Acid leaching of nickel from serpentinic laterite ores
AU705253B2 (en) Method for recovering nickel from high magnesium-containing Ni-Fe-Mg lateritic ore
US20080271571A1 (en) Process for Leaching Lateritic Ore at Atmospheric Pressure
CA2484134A1 (en) Atmospheric pressure leach process for lateritic nickel ore
EP2722408A2 (de) Verfahren zur Rückgewinnung von Metallwerten aus nickelhaltigen Erzen
CA2521817A1 (en) Process for leaching lateric ore at atmospheric pressure
EP2814992A1 (de) Herstellung eines hochwertigen nickelprodukts
US8361191B2 (en) Low acid leaching of nickel and cobalt from lean iron-containing nickel ores
AU2011235562A1 (en) Low acid leaching of nickel and cobalt from lean iron-containing nickel ores
EP2553129A1 (de) Geringe säurelaugung von nickel und kobalt aus nickelerzen mit geringem eisengehalt
AU2008341033B2 (en) Selectively leaching cobalt from lateritic ores
AU2008341034B2 (en) Laterite heap leaching with ferrous lixiviants
GB2086872A (en) Acid Leaching of Lateritic Nickel Ores
AU2003209829B2 (en) Atmospheric pressure leach process for lateritic nickel ore
ZA200507870B (en) Process for leaching lateritic ore at atmospheric pressure
KR20080058458A (ko) 대기압에서의 라테라이트 광석 침출 방법

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 20070131

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LT LU MC NL PL PT RO SE SI SK TR

A4 Supplementary search report drawn up and despatched

Effective date: 20070726

DAX Request for extension of the european patent (deleted)
RIN1 Information on inventor provided before grant (corrected)

Inventor name: NEUDORF, DAVID

Inventor name: HUGGINS, DAVID, A.

17Q First examination report despatched

Effective date: 20080103

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN

18D Application deemed to be withdrawn

Effective date: 20100106