EP1749918B1 - Procédé et dispositif d'imprégnation d'un matériaux fibreux - Google Patents
Procédé et dispositif d'imprégnation d'un matériaux fibreux Download PDFInfo
- Publication number
- EP1749918B1 EP1749918B1 EP05013783A EP05013783A EP1749918B1 EP 1749918 B1 EP1749918 B1 EP 1749918B1 EP 05013783 A EP05013783 A EP 05013783A EP 05013783 A EP05013783 A EP 05013783A EP 1749918 B1 EP1749918 B1 EP 1749918B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- fibre material
- mixing
- working chamber
- mixing heads
- impregnating agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Not-in-force
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Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B3/00—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
- D06B3/02—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fibres, slivers or rovings
Definitions
- the invention relates to a method and a device for impregnating a fiber material with an impregnating agent containing as a solution or an emulsion at least one additive.
- Such methods are used to impregnate any fibrous materials, which may be synthetic or natural fibers, with additives which serve to formulate certain performance characteristics of the fibrous material.
- additives are used to make the fibers of the fiber material flame resistant or to protect against fungal or bacterial attack.
- dip impregnation the mats are flooded with the liquid impregnating agent. Natural fibers especially absorb the liquid. The mats must therefore be subsequently dried consuming to ensure storage stability. This method is therefore uneconomical.
- the object of the invention is to provide a method and an apparatus for impregnating a fiber material with an impregnating agent, in which a substantially homogeneously distributed impregnation of the fibers is achieved.
- the guided past the mixing heads and this at least partially surrounding fiber material with the help of the mixing heads in a region around the mixing heads around loosened locally and treated with the impregnating agent by the impregnating agent is introduced by means of the mixing heads via one or more nozzles in the locally loosened fiber material whereby the impregnating agent is distributed substantially homogeneously over the fibers of the fibrous material; and applying the impregnating agent
- an apparatus for impregnating a fibrous material with an impregnating agent containing as a solution or an emulsion at least one additive having a dissolving means for pre-dissolving the fibrous material, a continuous mixing system for treating the fibrous material to be impregnated the impregnating agent and a metering device upstream of the continuous mixing system for the metered feeding of the continuous mixing system with the previously dissolved fiber material, and wherein in the continuous mixing system, a working space for receiving the introduced via the metering fiber material is formed in the working space a conveying and mixing device is arranged with the introduced fiber material can be conveyed from an inlet of the working space along a conveying path to an outlet of the working space, and mixing heads are arranged in the working space are with which the along the conveyor line on the mixing heads conveyed over fiber material loosened locally and with which the impregnating agent can be introduced via one or more nozzles in the locally loosened fiber
- the impregnating agent is preferably applied with a pressure for dispensing, so that the impregnating agent is sprayed.
- the impregnating agent is distributed to save material and evenly over the fibers to be impregnated. This is achieved in particular by the fact that the fiber material is dissolved prior to introduction into the working space, which is preferably carried out to the separation of the fiber material, and with the help of the mixing heads a local loosening of the fiber material is performed, so that a felting of the fiber material is avoided , In this way, the introduced impregnating material meets a loosened fiber material, in which hardly any shadow effect of fibers compared to other fibers occurs.
- the impregnating agent is introduced directly into the loosened fiber material. Losses that occur when impregnating is not introduced into the fiber material, but for example on the inner wall of the working space, are avoided. This also ensures that as little additive as possible must be used to impregnate the fiber material. In this way, the method contributes to cost savings.
- the avoidance of the unintentional distribution of impregnating agent on the inner regions of the working space further contributes to the fact that the wear of the system is reduced because less contamination of the components occurs in the working space. Therefore, the cleaning intervals can be extended.
- the deposition of impregnating agent on such components may also cause damage to these components, for example due to the chemically aggressive effect of the additive.
- An expedient embodiment of the invention provides that the impregnating agent as a highly concentrated solution / emulsion of the at least one additive on the one or all nozzles is introduced.
- the impregnating agent as a highly concentrated solution / emulsion of the at least one additive on the one or all nozzles is introduced.
- a homogeneous distribution of the impregnating agent on the fibers to be impregnated is supported in a development of the invention in that the impregnating agent is introduced as a mist, for example as a spray or spray.
- a targeted and material-saving use of the additive is achieved in one embodiment of the invention in that an amount of sprayed with the impregnating at least one additive in dependence on a solids content of the metered amounts of introduced in the working space dissolved fiber material is determined.
- the procedure is preferably such that the weight of the solid of the fiber material is determined on the basis of a weighing and then the amount of additive is determined which is necessary to achieve a desired impregnation of the fiber material.
- Such a process design in turn supports an efficient use of the at least one additive.
- any additives can be distributed substantially homogeneously over the fibers to be impregnated with the aid of the method.
- the invention can be provided that are introduced along the conveying path via the mixing heads impregnating agent with various additives. In this way, a successively carried out impregnation of the fiber material with different additives is possible.
- the fiber material in a first section of the conveyor line the fiber material can be impregnated, for example, with a flame retardant.
- a mold protection agent is additionally sprayed in.
- the material-saving and efficient use of the at least one additive is supported in one embodiment of the invention in that the mixing heads during the introduction of one or all impregnating continuously surrounded by the funded from the inlet to the outlet of the working space fiber material substantially.
- the sensor device for example, an optical sensor can be used.
- the fiber material surrounding the mixing heads is locally loosened up with a rotating loosening device formed on the mixing heads in the area around the mixing heads.
- the rotary loosening device on the mixing heads is preferably formed by means of a rotating member having a circumferential length which is greater than an elongated length of the longest fibers covered by the fiber material to be impregnated.
- the local loosening of the fiber material for spraying the impregnating agent is preferably achieved in that the rotating loosening device rotates at high speed at the mixing heads at a speed of about 500 to 3000 revolutions per minute, preferably at a speed of about 1,000 to 3,000 revolutions per minute, more preferably at a speed of about 1,500 to 3,000 revolutions per minute.
- an embodiment of the invention provides that the introduced fiber material in the working space along the conveying path conveyed by means of entrainment tools encompassed by the conveying and mixing device mounted on a shaft disposed in the working space and rotated with the shaft to convey the introduced fiber material from the inlet to the outlet.
- a shaft having a circumferential length which is greater than a stretched length of the longest of the fiber material to be impregnated fibers This prevents that the fibers of the fiber material to be impregnated wrap around the shaft or there is an increased entanglement of the fiber material.
- the method can be used to provide artificial fibers or natural fibers, in particular fibers of renewable raw materials such as annual plants with a substantially homogeneously distributed impregnation.
- fibers of renewable raw materials such as annual plants
- substantially homogeneously distributed impregnation Compared to known methods, the advantages in particular in the impregnation of a long fiber material with fibers having a length of about 30mm to about 200mm unfold.
- Embodiments of the invention may provide that prior to introduction of the dissolved fiber material by means of a moisture analysis, a basic moisture of the Fiber material and / or after the application of the treated fiber material by means of a further moisture analysis, a total moisture content of the treated fiber material is determined. Based on the information about the determined ground moisture of the metered fiber material, the amount of solvents can be determined, which is introduced via the mixing heads, so that the treated fiber material then has a predetermined total moisture. Compliance with the predetermined total moisture can be checked with the help of further moisture analysis. In addition, the information about the total moisture of the discharged fiber material can be used to decide on an optional, the impregnation downstream drying of the discharged fiber material. In particular, it can be determined whether and, if appropriate, to what extent post-drying is necessary.
- the treated fiber material is applied with a total moisture content of less than about 25% from the working space. This has the advantage that the discharged fiber material can be processed without further drying, for example for producing an insulating material.
- the most homogeneous possible distribution of the impregnating agent on the fiber material to be treated is supported in an expedient embodiment of the invention in that the one or all nozzles for discharging the impregnating agent are designed as a rotary nozzle.
- the use of rotary nozzles also has the advantage that, after stopping the supply of impregnating agent to the rotary nozzle, residues of the impregnating agent escape from the rotary nozzle due to the centrifugal force in a very short time, so that later dripping out of the nozzle is prevented.
- One or more rotary nozzles may be formed on the mixing heads as separately rotatable nozzles.
- the one or all nozzles of a mixing head in the rotating component are formed, which in turn is part of the loosening device.
- the one or all nozzles are formed as a respective opening on the loosening device, which is supplied via a feed channel with the impregnating agent to be applied.
- the impregnating agent can be subjected to a pressure.
- the application of the impregnating agent can also take place as a result of the centrifugal force acting upon rotation of the rotary nozzle.
- Fig. 1 shows a schematic representation of an apparatus for impregnating a fiber material with an impregnating agent containing as a solution or an emulsion one or more additives.
- the impregnating agent is atomized as a liquid.
- a flame retardant and / or a mold protection for the impregnated fibers are formed.
- the fiber material to be impregnated is exposed to the treatment with the liquid impregnating agent, the fiber material is separated by means of a dissolving device 1.
- the dissolved fiber material is then using a Metering device 2 in metered quantities fed to an inlet 3 of a continuous mixing system 4, preferably continuously.
- Fig. 2 shows a schematic representation of the opening device 1 and the metering device 2 in detail. According to Fig. 2 the dissolved fiber material is weighed by means of a balance 2a and fed via a conveyor belt 5 to the inlet 3 in metered quantities.
- the fiber material In order to determine the solids content of the fiber material to be impregnated, the fiber material is subjected to a moisture analysis in dissolved, optionally isolated, or unresolved state, so that a basic moisture of the fiber material to be impregnated is determined. Using the information about the basic moisture and the weight of a metered amount of the fiber material, the solids content of the metered amount can be determined. This information is used to determine an amount of additive which is sprayed after introduction of the metered amount via the inlet 3 for impregnating the introduced amount of fiber material with the liquid impregnating agent.
- the information about the basic moisture of the introduced fiber material can also be used to determine an amount of solvent of the impregnating agent, which ensures the maintenance of a maximum value for the basic moisture of the treated fiber material for the treated fiber material.
- Table 1 shows examples of the determination of the additive to be added and / or the solvent to be used, depending on a certain solids content.
- Fig. 1 enters the introduced through the inlet 3 in metered quantities of fiber material in a working space 6, which is formed in a mixing drum 7.
- a shaft 8 is arranged centrally, are mounted on the driving tools 9, which are rotated by means of the shaft 8.
- a mixing and conveying device 10 is formed to promote the introduced via the inlet 3 fiber material from the inlet along a conveying path 11 to an outlet 12.
- the number and contour of the driving tools 9 is matched to the properties of the fiber material to be impregnated.
- the type of fiber and the length of the fibers play a role here essential role.
- the entrainment tools 9 are arranged offset on the shaft 8, it is ensured that the fibers are conveyed without entanglement along the conveyor line 11 to the outlet 12.
- the diameter of the mixing drum 7 and its length are specifically tailored to a desired throughput of fiber material and the properties of the fiber material.
- the throughput is influenced by the speed of the shaft 8.
- the mixing heads 13 each have a rotating component 14 and a nozzle 15, which is integrated into the rotating component 14.
- the nozzle 15 is formed in the rotating member 14 as an opening with a feed channel behind it, through which the impregnating agent to be applied is supplied.
- the fibrous material to be impregnated is conveyed past the mixing heads 13 during conveyance along the conveying path 11 and conveyed to the outlet 12. Characterized in that the fiber material to be impregnated on its way along the conveyor section 11 is guided past the mixing heads 13, there is a local loosening of the fiber material around the mixing heads 13, namely with the aid of the respective rotating member 14, which acts as a loosening device.
- Each of the mixing heads 13 may have one or more nozzles.
- the rotating components 14 are rotated at high speed at a speed of about 500 to 3000 revolutions per minute, preferably at a speed of about 1,000 to 3,000 revolutions per minute, more preferably at a speed of about 1,500 to 3,000 revolutions per minute.
- the desired speed is in Depending on the diameter of the rotating member 14 and the fiber material set.
- a circumferential length of the rotary member 14 is larger than an elongated fiber length of the longest fibers included in the fiber material to be impregnated, so that the fibers do not wind around the rotary member 14.
- the circumferential length of the shaft 8 is tuned depending on the fiber length to prevent wrapping of the shaft 8 with the fibers.
- this total moisture is less than 25%.
- a drying device (not shown), in which the treated fibers are dried to further reduce the total moisture content.
- Fig. 3 shows a schematic representation of the mixing drum 7 in the filled state. In this way it is ensured that the mixing head 13 is surrounded by the fiber material, so that the liquid impregnating agent is injected directly into the fiber material.
- both artificial fibers and natural fibers can be provided with a homogeneously distributed impregnation. Fiber impregnated in this manner can subsequently be further processed for any desired application.
- the homogeneously impregnated fibers are preferably used for the production of insulating materials, for example in the form of mats.
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatment Of Fiber Materials (AREA)
- Preliminary Treatment Of Fibers (AREA)
Claims (29)
- Procédé pour imprégner un matériau fibreux avec un agent d'imprégnation qui contient au moins un additif sous forme de solution ou d'émulsion, selon lequel :- le matériau fibreux à imprégner est préalablement ouvert à l'aide d'un dispositif d'ouverture (1) ;- le matériau fibreux préalablement ouvert est introduit en quantités dosées à l'aide d'un dispositif de dosage (2) à travers une entrée (3) dans une chambre de travail (6) d'un système de mélange continu (4) ;- le matériau fibreux introduit dans la chambre de travail (6) du système de mélange continu (4) est transporté à l'aide d'un dispositif de transport et de mélange (10) devant des têtes mélangeuses (13) et, en entourant au moins partiellement les têtes mélangeuses (13), de l'entrée (3) vers une sortie (12) le long d'un parcours de transport (11) ;- le matériau fibreux guidé devant les têtes mélangeuses (13) et le matériau fibreux entourant celles-ci au moins partiellement est localement démêlé à l'aide des têtes mélangeuses (13) dans une zone autour des têtes mélangeuses (13) et traité avec l'agent d'imprégnation par introduction de celui-ci au moyen des têtes mélangeuses (13), par l'intermédiaire d'une ou plusieurs buses (15), dans le matériau fibreux localement démêlé, de manière à répartir de façon essentiellement homogène l'agent d'imprégnation sur les fibres du matériau fibreux ; et- le matériau fibreux traité avec l'agent d'imprégnation est évacué de la chambre de travail (6) à travers la sortie (12).
- Procédé selon la revendication 1, caractérisé en ce que l'agent d'imprégnation est introduit par l'intermédiaire de la ou de toutes les buses (15) sous forme de solution / émulsion hautement concentrée dudit au moins un additif.
- Procédé selon la revendication 1 ou 2, caractérisé en ce que l'agent d'imprégnation est introduit sous forme de brouillard.
- Procédé selon l'une des revendications précédentes, caractérisé en ce qu'une quantité dudit au moins un additif introduit avec l'agent d'imprégnation est déterminée en fonction d'une teneur en matières solides des quantités dosées du matériau fibreux ouvert introduit dans la chambre de travail (6).
- Procédé selon l'une des revendications précédentes, caractérisé en ce qu'un agent ignifuge est introduit en tant que ledit au moins un additif avec l'agent d'imprégnation.
- Procédé selon l'une des revendications précédentes, caractérisé en ce qu'un fongicide est introduit en tant qu'additif supplémentaire avec l'agent d'imprégnation.
- Procédé selon l'une des revendications précédentes, caractérisé en ce que des agents d'imprégnation avec différents additifs sont introduits le long du parcours de transport (11) par l'intermédiaire des têtes mélangeuses (13).
- Procédé selon l'une des revendications précédentes, caractérisé en ce que les têtes mélangeuses (13) sont entourées en permanence au moins partiellement par le matériau fibreux transporté de l'entrée (3) vers la sortie (12) de la chambre de travail (6) lors de l'introduction du ou de tous les agents d'imprégnation.
- Procédé selon l'une des revendications précédentes, caractérisé en ce que le matériau fibreux entourant au moins partiellement les têtes mélangeuses (13) est localement démêlé dans la zone autour des têtes mélangeuses (13) au moyen d'un dispositif de démêlage (14) rotatif formé sur les têtes mélangeuses (13).
- Procédé selon la revendication 9, caractérisé en ce que l'on utilise comme dispositif de démêlage rotatif sur les têtes mélangeuses (13) un composant rotatif (14) ayant une longueur circonférentielle qui est plus grande que la longueur étirée des plus longues fibres comprises par le matériau fibreux à imprégner.
- Procédé selon la revendication 9 ou 10, caractérisé en ce que le dispositif de démêlage rotatif (14) sur les têtes mélangeuses (13) tourne à grande vitesse à une vitesse de rotation d'environ 500 à 3 000 tours par minute, de préférence à une vitesse de rotation d'environ 1 000 à 3 000 tours par minute, plus préférablement à une vitesse de rotation d'environ 1 500 à 3 000 tours par minute.
- Procédé selon l'une des revendications précédentes, caractérisé en ce que le matériau fibreux introduit dans la chambre de travail (6) est transporté le long du parcours de transport (11) au moyen d'outils d'entraînement (9) compris par le dispositif de transport et de mélange (10), qui sont montés sur un arbre (8) disposé dans la chambre de travail (6) et qui tournent avec l'arbre (8) pour transporter le matériau fibreux introduit de l'entrée (3) vers la sortie (12).
- Procédé selon la revendication 12, caractérisé en ce que l'on utilise comme arbre (8) un arbre ayant une longueur circonférentielle qui est plus grande que la longueur étirée des plus longues fibres comprises par le matériau fibreux à imprégner.
- Procédé selon l'une des revendications précédentes, caractérisé en ce que le matériau fibreux est imprégné en tant que matériau à fibres longues composé de fibres ayant une longueur d'environ 30 mm à environ 200 mm.
- Procédé selon l'une des revendications précédentes, caractérisé en ce qu'une humidité de base du matériau fibreux est déterminée au moyen d'une analyse d'humidité avant l'introduction du matériau fibreux ouvert.
- Procédé selon l'une des revendications précédentes, caractérisé en ce qu'une humidité totale du matériau fibreux traité est déterminée au moyen d'une analyse d'humidité supplémentaire après la sortie du matériau fibreux traité.
- Procédé selon l'une des revendications précédentes, caractérisé en ce que le matériau fibreux traité sort de la chambre de travail (6) avec une humidité totale inférieure à environ 25 %.
- Procédé selon l'une des revendications précédentes, caractérisé en ce que le matériau fibreux traité est séché après la sortie de la chambre de travail (6).
- Dispositif pour imprégner un matériau fibreux avec un agent d'imprégnation qui contient au moins un additif sous forme de solution ou d'émulsion, comprenant :- un dispositif d'ouverture (1) pour ouvrir préalablement le matériau fibreux ;- un système de mélange continu (4) pour traiter le matériau fibreux à imprégner avec l'agent d'imprégnation ; et- un dispositif de dosage (2) placé en amont du système de mélange continu (4) pour charger de manière dosée le système de mélange continu (4) avec le matériau fibreux préalablement ouvert ;dans lequel- une chambre de travail (6) destinée à recevoir le matériau fibreux introduit par l'intermédiaire du dispositif de dosage (2) est formée dans le système de mélange continu (4) ;- dans la chambre de travail (6) est disposé un dispositif de transport et de dosage (10) au moyen duquel le matériau fibreux introduit peut être transporté le long d'un parcours de transport (11) d'une entrée (3) de la chambre de travail (6) vers une sortie (12) de la chambre de travail (6) ; et- dans la chambre de travail (6) sont disposées des têtes mélangeuses (13) au moyen desquelles le matériau fibreux transporté devant les têtes mélangeuses (13) le long du parcours de transport (11) est localement démêlé et au moyen desquelles l'agent d'imprégnation peut être introduit par l'intermédiaire d'une ou plusieurs buses (15) dans le matériau fibreux localement démêlé.
- Dispositif selon la revendication 19, caractérisé en ce que les têtes mélangeuses (13) sont disposées les unes derrières les autres le long du parcours de transport (11).
- Dispositif selon la revendication 19 ou 20, caractérisé en ce que la ou toutes les buses (15) sont formées sur les têtes mélangeuses (13) sous forme de buses rotatives.
- Dispositif selon l'une des revendications 19 à 21, caractérisé en ce que sur chacune des têtes mélangeuses (13) est formé un dispositif de démêlage rotatif (14) avec lequel le matériau fibreux transporté peut être localement démêlé dans la zone autour des têtes mélangeuses (13).
- Dispositif selon la revendication 22, caractérisé en ce que la ou toutes les buses (15) sont intégrées dans le dispositif de démêlage rotatif (14).
- Dispositif selon la revendication 22 ou 23, caractérisé en ce que le dispositif de démêlage rotatif est un composant rotatif (14) ayant une longueur circonférentielle qui est plus grande que la longueur étirée des plus longues fibres comprises par le matériau fibreux à imprégner.
- Dispositif selon la revendication 23 ou 24, caractérisé en ce que la ou toutes les buses (15) sont formées au moyen d'ouvertures dans le dispositif de démêlage ou le composant rotatif.
- Dispositif selon l'une des revendications 19 à 25, caractérisé en ce que le dispositif de transport et de dosage (10) présente des outils d'entraînement (9) qui sont montés sur un arbre (8) disposé dans la chambre de travail (6) et qui peuvent tourner avec l'arbre (8) pour transporter le matériau fibreux introduit de l'entrée (3) vers la sortie (12).
- Dispositif selon la revendication 26, caractérisé en ce que l'arbre (8) présente une longueur circonférentielle qui est plus grande que la longueur étirée des plus longues fibres comprises par le matériau fibreux à imprégner.
- Dispositif selon l'une des revendications 19 à 27, caractérisé par un dispositif de séchage placé en aval de la chambre de travail (6) pour sécher le matériau fibreux traité.
- Dispositif selon l'une des revendications 19 à 28, caractérisé en ce que la chambre de travail (6) est formée dans un tambour mélangeur (7).
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE502005004288T DE502005004288D1 (de) | 2005-06-27 | 2005-06-27 | Verfahren und Vorrichtung zum Imprägnieren eines Fasermaterials |
EP05013783A EP1749918B1 (fr) | 2005-06-27 | 2005-06-27 | Procédé et dispositif d'imprégnation d'un matériaux fibreux |
AT05013783T ATE397114T1 (de) | 2005-06-27 | 2005-06-27 | Verfahren und vorrichtung zum imprägnieren eines fasermaterials |
PCT/DE2006/001093 WO2007000147A1 (fr) | 2005-06-27 | 2006-06-26 | Procede et dispositif d'impregnation d'un materiau fibreux |
DE112006002353T DE112006002353A5 (de) | 2005-06-27 | 2006-06-26 | Verfahren und Vorrichtung zum Imprägnieren eines Fasermaterials |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP05013783A EP1749918B1 (fr) | 2005-06-27 | 2005-06-27 | Procédé et dispositif d'imprégnation d'un matériaux fibreux |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1749918A1 EP1749918A1 (fr) | 2007-02-07 |
EP1749918B1 true EP1749918B1 (fr) | 2008-05-28 |
Family
ID=35207602
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP05013783A Not-in-force EP1749918B1 (fr) | 2005-06-27 | 2005-06-27 | Procédé et dispositif d'imprégnation d'un matériaux fibreux |
Country Status (4)
Country | Link |
---|---|
EP (1) | EP1749918B1 (fr) |
AT (1) | ATE397114T1 (fr) |
DE (2) | DE502005004288D1 (fr) |
WO (1) | WO2007000147A1 (fr) |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3393537A (en) * | 1965-12-06 | 1968-07-23 | Unisearch Ltd | Apparatus for the treatment of fibre assemblies with fluids |
GB1217759A (en) * | 1967-12-27 | 1970-12-31 | Vepa Ag | Device for the treatment with liquid of loose fibrous material |
DE1760583A1 (de) * | 1968-06-07 | 1971-12-23 | Vepa Ag | Vorrichtung zum kontinuierlichen Behandeln,insbesondere Faerben,von losem Fasermaterial |
US4372002A (en) * | 1980-10-17 | 1983-02-08 | Small Eugene D | Cotton treating process |
US4485644A (en) * | 1983-02-07 | 1984-12-04 | Beu-Tex Corporation | Apparatus for continuously treating staple length textile fibrous materials |
DE4339078C2 (de) | 1993-11-16 | 1996-11-28 | Alchimea Naturwaren Gmbh | Verfahren zur Verbesserung der Flammbeständigkeit von faserigen Materialien unter gleichzeitiger Verbesserung der Beständigkeit gegen Pilz-, Schädlings- und Bakterienbefall |
DE19829277A1 (de) | 1998-06-30 | 2000-01-05 | Fraunhofer Ges Forschung | Baubiologisch unbedenkliche Flamm- und Pilzschutzmittel für Baustoffe aus nachwachsenden Rohstoffen |
-
2005
- 2005-06-27 AT AT05013783T patent/ATE397114T1/de not_active IP Right Cessation
- 2005-06-27 DE DE502005004288T patent/DE502005004288D1/de not_active Expired - Fee Related
- 2005-06-27 EP EP05013783A patent/EP1749918B1/fr not_active Not-in-force
-
2006
- 2006-06-26 WO PCT/DE2006/001093 patent/WO2007000147A1/fr active Application Filing
- 2006-06-26 DE DE112006002353T patent/DE112006002353A5/de not_active Withdrawn
Also Published As
Publication number | Publication date |
---|---|
DE502005004288D1 (de) | 2008-07-10 |
WO2007000147A1 (fr) | 2007-01-04 |
ATE397114T1 (de) | 2008-06-15 |
EP1749918A1 (fr) | 2007-02-07 |
DE112006002353A5 (de) | 2008-06-05 |
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