EP1742736B1 - Additif de zsm-5 - Google Patents

Additif de zsm-5 Download PDF

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Publication number
EP1742736B1
EP1742736B1 EP05738637.7A EP05738637A EP1742736B1 EP 1742736 B1 EP1742736 B1 EP 1742736B1 EP 05738637 A EP05738637 A EP 05738637A EP 1742736 B1 EP1742736 B1 EP 1742736B1
Authority
EP
European Patent Office
Prior art keywords
weight
alumina
catalyst
slurry
kaolin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Not-in-force
Application number
EP05738637.7A
Other languages
German (de)
English (en)
Other versions
EP1742736A1 (fr
Inventor
Gary M. Smith
Barry K. Speronello
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Corp
Original Assignee
BASF Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF Corp filed Critical BASF Corp
Publication of EP1742736A1 publication Critical patent/EP1742736A1/fr
Application granted granted Critical
Publication of EP1742736B1 publication Critical patent/EP1742736B1/fr
Not-in-force legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
    • C10G11/04—Oxides
    • C10G11/05—Crystalline alumino-silicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/14—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts
    • C10G11/18—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts according to the "fluidised-bed" technique
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/20—C2-C4 olefins

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Claims (8)

  1. Catalyseur comprenant (a) au moins 30 % en poids d'une zéolite à taille intermédiaire des pores, (b) 3 à 15 % en poids de phosphore, mesuré en termes de P2O5, (c) 15 à 45 % en poids de kaolin, (d) 3 à 25 % en poids d'un constituant non réactif ayant une surface spécifique BET inférieure à 50 m2/g et une masse volumique supérieure à 2,8 g/cm3, ledit constituant non réactif étant l'alumine alpha, et (e) 2 à 20 % en poids d'une alumine réactive.
  2. Catalyseur selon la revendication 1 dans lequel ladite zéolite (a) est ZSM-5 présente en quantités d'au moins 40 % en poids.
  3. Catalyseur selon la revendication 1 dans lequel les alumines ajoutées (d) et (e) sont présentes en une quantité supérieure à 10 % en poids.
  4. Procédé pour la préparation d'un catalyseur comprenant (a) la préparation d'une bouillie aqueuse comprenant une zéolite à taille intermédiaire des pores, un constituant non réactif ayant une surface spécifique BET inférieure à 50 m2/g et une masse volumique supérieure à 2,8 g/cm3, ledit constituant non réactif étant l'alumine alpha, et une alumine réactive, (b) le mélange de ladite bouillie (a) avec une bouillie aqueuse de kaolin hydraté contenant au moins 50 % en poids de matières solides, (c) l'injection d'acide phosphorique dans la bouillie mélangée (b) au voisinage ou au niveau d'un sécheur par pulvérisation et (d) le séchage par pulvérisation et la calcination de la bouillie résultante pour produire une matière particulaire contenant au moins 30 % en poids de ladite zéolite, 3 à 15 % en poids de P2O5, 3 à 25 % en poids dudit constituant non réactif, 2 à 20 % en poids de ladite alumine réactive et 15 à 50 % en poids de kaolin hydraté.
  5. Procédé selon la revendication 4 dans lequel la zéolite est ZSM-5 et est présente en quantité d'au moins 40 % du poids total de la matière particulaire.
  6. Procédé pour la réaction chimique et catalytique d'une charge d'hydrocarbures comprenant la mise en contact de la charge dans des conditions de réaction catalytique avec un catalyseur comprenant (a) au moins 30 % en poids d'une zéolite à taille intermédiaire des pores, (b) 3 à 15 % en poids de phosphore, mesuré en termes de P2O5, (c) 15 à 45 % en poids de kaolin, (d) 3 à 25 % en poids d'un constituant non réactif ayant une surface spécifique BET inférieure à 50 m2/g et une masse volumique supérieure à 2,8 g/cm3, ledit constituant non réactif étant l'alumine alpha, et (e) 2 à 20 % en poids d'une alumine réactive.
  7. Procédé selon la revendication 6 dans lequel les alumines ajoutées (d) et (e) sont présentes dans ledit catalyseur en une quantité supérieure à 10 % en poids.
  8. Procédé selon la revendication 6 comprenant en outre la récupération d'éthylène et/ou de propylène à partir dudit procédé.
EP05738637.7A 2004-04-29 2005-04-19 Additif de zsm-5 Not-in-force EP1742736B1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US56645204P 2004-04-29 2004-04-29
US11/093,256 US7375048B2 (en) 2004-04-29 2005-03-29 ZSM-5 additive
PCT/US2005/013516 WO2005110597A1 (fr) 2004-04-29 2005-04-19 Additif de zsm-5

Publications (2)

Publication Number Publication Date
EP1742736A1 EP1742736A1 (fr) 2007-01-17
EP1742736B1 true EP1742736B1 (fr) 2018-06-20

Family

ID=34966495

Family Applications (1)

Application Number Title Priority Date Filing Date
EP05738637.7A Not-in-force EP1742736B1 (fr) 2004-04-29 2005-04-19 Additif de zsm-5

Country Status (11)

Country Link
US (4) US7375048B2 (fr)
EP (1) EP1742736B1 (fr)
JP (1) JP4951504B2 (fr)
KR (1) KR101121494B1 (fr)
CN (1) CN1950146B (fr)
AU (1) AU2005243748A1 (fr)
BR (1) BRPI0510432B1 (fr)
CA (1) CA2564306C (fr)
MX (1) MXPA06012453A (fr)
TW (1) TW200603886A (fr)
WO (1) WO2005110597A1 (fr)

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CN102744097B (zh) * 2011-04-20 2014-11-26 中国石油化工股份有限公司 低磨耗流化床催化剂及制备方法
KR20140079357A (ko) 2011-07-21 2014-06-26 릴라이언스 인더스트리즈 리미티드 유동상 촉매 분해(fcc) 촉매 첨가제 및 그 제조 방법
US9227181B2 (en) * 2011-09-13 2016-01-05 Basf Corporation Catalyst to increase propylene yields from a fluid catalytic cracking unit
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US9522392B2 (en) 2013-03-15 2016-12-20 Inaeris Technologies, Llc Phosphorous promotion of zeolite-containing catalysts
US20150045208A1 (en) * 2013-08-09 2015-02-12 Kior, Inc. Catalysts For Thermo-Catalytic Conversion Of Biomass, And Methods Of Making and Using
WO2015081122A2 (fr) 2013-11-27 2015-06-04 Siluria Technologies, Inc. Réacteurs et systèmes destinés au couplage oxydatif du méthane
CN106068323B (zh) 2014-01-08 2019-09-06 希路瑞亚技术公司 乙烯成液体的系统和方法
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WO2016087956A1 (fr) * 2014-12-06 2016-06-09 Reliance Industries Limited Composition d'additif de catalyseur de fcc stable de façon hydrothermale
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WO2017015597A1 (fr) 2015-07-23 2017-01-26 Albemarle Corporation Additif de catalyseur fcc et liant
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Also Published As

Publication number Publication date
JP4951504B2 (ja) 2012-06-13
KR20070010070A (ko) 2007-01-19
EP1742736A1 (fr) 2007-01-17
MXPA06012453A (es) 2007-01-17
US7547653B2 (en) 2009-06-16
AU2005243748A1 (en) 2005-11-24
CA2564306C (fr) 2013-10-29
US7585804B2 (en) 2009-09-08
CN1950146A (zh) 2007-04-18
US20050241995A1 (en) 2005-11-03
KR101121494B1 (ko) 2012-02-28
CA2564306A1 (fr) 2005-11-24
US20080161180A1 (en) 2008-07-03
CN1950146B (zh) 2011-02-16
US20090023971A1 (en) 2009-01-22
BRPI0510432A (pt) 2007-10-30
TW200603886A (en) 2006-02-01
BRPI0510432B1 (pt) 2016-06-21
US7375048B2 (en) 2008-05-20
WO2005110597A1 (fr) 2005-11-24
US20080161625A1 (en) 2008-07-03
US7547813B2 (en) 2009-06-16
JP2007534485A (ja) 2007-11-29

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