EP1666822A1 - Installation pour la séparation cryogénique d'un mélange gazeux en particulier d'air - Google Patents

Installation pour la séparation cryogénique d'un mélange gazeux en particulier d'air Download PDF

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Publication number
EP1666822A1
EP1666822A1 EP04028681A EP04028681A EP1666822A1 EP 1666822 A1 EP1666822 A1 EP 1666822A1 EP 04028681 A EP04028681 A EP 04028681A EP 04028681 A EP04028681 A EP 04028681A EP 1666822 A1 EP1666822 A1 EP 1666822A1
Authority
EP
European Patent Office
Prior art keywords
direct contact
cooler
feed mixture
heat exchanger
cryogenic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP04028681A
Other languages
German (de)
English (en)
Inventor
Andreas Brox
Markus Huppenberger
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Linde GmbH
Original Assignee
Linde GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Linde GmbH filed Critical Linde GmbH
Priority to EP04028681A priority Critical patent/EP1666822A1/fr
Priority to EP04028683A priority patent/EP1666823A1/fr
Priority to PL05024947T priority patent/PL1672301T3/pl
Priority to EP05024947.3A priority patent/EP1672301B1/fr
Priority to US11/292,282 priority patent/US7516626B2/en
Priority to CA2528735A priority patent/CA2528735C/fr
Priority to RU2005137481/06A priority patent/RU2382963C2/ru
Priority to CN200510128991A priority patent/CN100575838C/zh
Publication of EP1666822A1 publication Critical patent/EP1666822A1/fr
Withdrawn legal-status Critical Current

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04763Start-up or control of the process; Details of the apparatus used
    • F25J3/04866Construction and layout of air fractionation equipments, e.g. valves, machines
    • F25J3/0489Modularity and arrangement of parts of the air fractionation unit, in particular of the cold box, e.g. pre-fabrication, assembling and erection, dimensions, horizontal layout "plot"
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04151Purification and (pre-)cooling of the feed air; recuperative heat-exchange with product streams
    • F25J3/04157Afterstage cooling and so-called "pre-cooling" of the feed air upstream the air purification unit and main heat exchange line
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04151Purification and (pre-)cooling of the feed air; recuperative heat-exchange with product streams
    • F25J3/04187Cooling of the purified feed air by recuperative heat-exchange; Heat-exchange with product streams
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04763Start-up or control of the process; Details of the apparatus used
    • F25J3/04866Construction and layout of air fractionation equipments, e.g. valves, machines
    • F25J3/04951Arrangements of multiple air fractionation units or multiple equipments fulfilling the same process step, e.g. multiple trains in a network
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2205/00Processes or apparatus using other separation and/or other processing means
    • F25J2205/30Processes or apparatus using other separation and/or other processing means using a washing, e.g. "scrubbing" or bubble column for purification purposes
    • F25J2205/32Processes or apparatus using other separation and/or other processing means using a washing, e.g. "scrubbing" or bubble column for purification purposes as direct contact cooling tower to produce a cooled gas stream, e.g. direct contact after cooler [DCAC]
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2205/00Processes or apparatus using other separation and/or other processing means
    • F25J2205/30Processes or apparatus using other separation and/or other processing means using a washing, e.g. "scrubbing" or bubble column for purification purposes
    • F25J2205/34Processes or apparatus using other separation and/or other processing means using a washing, e.g. "scrubbing" or bubble column for purification purposes as evaporative cooling tower to produce chilled water, e.g. evaporative water chiller [EWC]
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2290/00Other details not covered by groups F25J2200/00 - F25J2280/00
    • F25J2290/12Particular process parameters like pressure, temperature, ratios
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2290/00Other details not covered by groups F25J2200/00 - F25J2280/00
    • F25J2290/32Details on header or distribution passages of heat exchangers, e.g. of reboiler-condenser or plate heat exchangers
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S62/00Refrigeration
    • Y10S62/902Apparatus
    • Y10S62/903Heat exchange structure

Definitions

  • the invention relates to a product for producing a product by cryogenic separation of a gas mixture, in particular air, with a feed gas compressor for compressing the feed mixture, with a direct contact cooler for precooling the feed mixture, with a cleaning device for cleaning the pre-cooled feed mixture, with a low temperature part, the main heat exchanger for Cooling of the purified feed mixture to about dew point and a distillation column for cryogenic separation of the cooled feed mixture, and having a coolant circuit for supplying coolant for the direct contact cooler, wherein the coolant circuit has an evaporative cooler for cooling coolant in direct heat exchange with a gas stream from the low temperature part.
  • cryogenic temperature is meant here basically any temperature which is below the ambient temperature, but preferably a temperature of 200 K or less, most preferably 150 K or less, for example 100 K or less.
  • a direct contact cooler In a "direct contact cooler” the feed mixture is brought into direct heat exchange with a coolant, for example water, and thereby cooled. It is used in particular for removing heat of compression, which has arisen in a feed gas compressor, which is usually connected upstream.
  • a coolant for example water
  • a subsequent "cleaning device” is usually designed as an adsorption device and in particular has at least two switchable container, which are operated cyclically. It serves to separate unwanted components, for example those which can freeze out in the low-temperature part.
  • the feed mixture is first cooled to about dew point temperature and then decomposed in a distillation column system.
  • the low-temperature part thus contains one or more heat exchangers and one or more distillation columns.
  • the product is withdrawn in gas or liquid form.
  • the cryogenic part is usually thermally insulated by being enclosed by one or more cold boxes.
  • the “main heat exchanger” serves to heat the gaseous product (s) in indirect heat exchange with at least one feed mixture stream.
  • Direct contact coolers are often operated with coolant circuits in which at least a portion of the withdrawn from the direct contact cooler, heated coolant is cooled and returned to the direct contact cooler.
  • evaporative cooler dry gas is brought into direct countercurrent with coolant.
  • the coolant evaporates partially and is thereby cooled.
  • the dry gas is often available as a residual product in cryogenic plants, for example as impure residual nitrogen in an air separation plant.
  • direct contact coolers and evaporative coolers are arranged as a unit or at least as immediately adjacent units because of their functional relationship.
  • the invention has for its object to further optimize the arrangement of the components of a cryogenic separation plant to achieve a particularly high efficiency of the system.
  • the ratio of the distance between evaporative cooler and direct contact cooler to the distance between the evaporative cooler and the main heat exchanger is at least 0.5, in particular at least 1.0.
  • the evaporative cooler 15 is arranged comparatively close to the main heat exchanger. Although this means higher costs for the coolant piping; However, the line for the gas flow from the low-temperature part can be made very short. In the context of the invention has been found that this arrangement leads to a total of comparatively low investment costs costs. In particular, the effort for the pipelines and the associated steel construction costs is reduced. This is partly due to the very high cross section (for example 1 to 2 m) of the gas line to the evaporative cooler.
  • Atmospheric air is sucked in as "feed mixture” via an inlet filter 1 and fed via feed pipes 51, 52, 53, 54 to other plant components.
  • the filtered air 51 is compressed in a main air compressor, which in the example is the "feed gas compressor.”
  • the compressed air 52 flows into a direct contact cooler 3 where it is cooled in direct heat exchange with cooling water flowing over a cooling water piping 61.
  • the cooled air 53 is further passed into a purifier 4 having a pair of molecular sieve adsorbers 5, 6.
  • the purified air 54 continues to flow to the cryogenic part 7.
  • the low-temperature part may consist of a single cold box, in which all cryogenic apparatuses are arranged, in particular the one or more heat exchangers and the distillation column (s), or from a variety of separate cold boxes.
  • a cylindrical rectification box 9 contains the distillation columns 9a, here a double column with high-pressure and low-pressure column and a main capacitor arranged therebetween.
  • the remaining cold parts, in particular the main heat exchanger 8a are housed in a cuboid heat exchanger box 8.
  • the two cold boxes 8, 9 insulate the respective cold parts of the apparatus against heat from the environment.
  • a transition section 10 also belongs to the low-temperature part. He is also surrounded by a coldbox; Alternatively, located in the transition section 10 piping and fittings are thermally insulated by means of a correspondingly smaller cold box.
  • the main heat exchanger is designed as exclusively recuperative heat exchanger, so not as a switchable heat exchanger (Revex). It consists, for example, of one block or a plurality of flow-connected blocks.
  • the block or blocks are preferably designed as aluminum plate heat exchangers.
  • Possible further heat exchangers, such as one or more subcooling countercurrents, may also be accommodated in the heat exchanger box; alternatively or additionally, one or more blocks of subcooling countercurrents may be arranged in the rectification box.
  • the form of the rectification box may differ from the exemplary embodiment; For example, it may be substantially cuboidal.
  • the main air compressor 2 is driven via a first shaft 11 by a drive means 12, which is designed as an electric motor, gas or steam turbine.
  • a booster 14 is provided for a portion of the purified air 54.
  • the inlet of the booster 14 is connected to the pipe 54 for the purified air.
  • the further compressed air in the booster 14 is passed through a further, not shown in the drawing pipe in the cryogenic part 7, in particular in the heat exchanger box 8.
  • the booster 14 is also driven by a further shaft 13 of the drive means 12.
  • the booster could be driven independently of the main air compressor, for example by a separate gas or steam turbine or by a separate electric motor.
  • the products of the low-temperature part 7 are discharged via exemplary product lines 105, 106, which open here into manifolds 107 and 108, respectively.
  • the manifolds 107, 108 are arranged on a pipe bridge 109 and can connect the device and possibly other identical or similar devices (strands) to a multi-strand system or lead to a tank farm and / or to an emergency supply device.
  • an evaporative cooler 15 For cooling water before its introduction into the direct contact cooler 3, an evaporative cooler 15 is used. In it, dry residual nitrogen from the low-temperature part is brought into direct heat and mass transfer with cooling water to be cooled. About the cooling water piping 61 cold cooling water is passed to the direct contact cooler. Warm cooling water is returned directly or indirectly to the evaporative cooler. The moist nitrogen from the evaporative cooler reaches the atmosphere.
  • the apparatus also includes utility piping 63, the location of which is schematically indicated in the drawing.
  • the equipment piping serves to transport steam, gas and / or cooling water and to dispose of condensate, cooling water, etc. It flows into resource headers (not shown), which can be arranged on the pipe bridge 109.
  • Resource and booster air tubing 63, 62 may be located on the floor (on sleepers) or on one or more pipe bridges.
  • the base surfaces of the direct contact cooler 3, the cleaning device 4 and the low-temperature part 7 have in the embodiment circular, rectangular or a complex shape. These bases are arranged in a line, for example on a main orientation axis 101. In addition, this line 101 extends through the base of the main air compressor 2. This results in a particularly short Eirisatzgasverrohrung 52/53/54. Also, the product lines 105, 106, which are arranged opposite the entrance of the insert line 54, have a particularly short length. They can even be so short that their own pipe bridge is not needed.
  • the rectangle 102 which encloses the bases of direct contact cooler 3, cleaning device 4 and low-temperature part 7, is approximately 1.7 times longer in the extent that extends vertically in the drawing than in the direction perpendicular thereto (horizontally in the drawing).
  • a factor of about 1.8 applies for the rectangle 103, which also encloses the base of the main air compressor and the apparatuses connected to it.
  • a short pipe bridge 109 and short lines 107, 108 of sufficient length for the product removal or the resource supply and removal; This is particularly advantageous in multi-strand systems. (Due to its schematic character, the drawing is not necessarily to scale in this respect either.)
  • direct contact coolers 3 and evaporative coolers 15 are arranged as a unit or at least as immediately adjacent units because of their functional relationship. In the embodiment, however, the evaporative cooler 15 is much closer to the low temperature part than the direct contact cooler.
  • the distance 104 between the evaporative cooler 15 and the main heat exchanger 8a is about one fifth of the distance between the direct contact cooler 3 and the low temperature part 7.
  • the residual nitrogen pipe between the main heat exchanger and the evaporative cooler 15 which is not shown in the drawing, only a relatively short Overcome route and can therefore be realized particularly cost effective; This saving is significant because of the very large cross-section of the residual nitrogen pipe.
  • the cooling water piping is longer, but has a much smaller cross-section and increases the cost of the apparatus only insignificantly.
  • Cryogenic air separation plants regularly have one or more expansion machines, which serve to generate cold by work-performing relaxation of one or more process streams and are usually designed as turbines.
  • the plant of the embodiment preferably has a turbine for work-performing expansion of a partial flow of the feed air or a product or intermediate product stream from the low-temperature decomposition. This turbine is seated in a turbine box 16, which is arranged in the embodiment at the transition section 10 between the heat exchanger box 8 and rectification box 9.
EP04028681A 2004-12-03 2004-12-03 Installation pour la séparation cryogénique d'un mélange gazeux en particulier d'air Withdrawn EP1666822A1 (fr)

Priority Applications (8)

Application Number Priority Date Filing Date Title
EP04028681A EP1666822A1 (fr) 2004-12-03 2004-12-03 Installation pour la séparation cryogénique d'un mélange gazeux en particulier d'air
EP04028683A EP1666823A1 (fr) 2004-12-03 2004-12-03 Installation pour la séparation cryogénique d'un mélange gazeux en particulier d'air
PL05024947T PL1672301T3 (pl) 2004-12-03 2005-11-15 Urządzenie do niskotemperaturowego rozkładu mieszanki gazowej, zwłaszcza powietrza
EP05024947.3A EP1672301B1 (fr) 2004-12-03 2005-11-15 Installation pour la séparation cryogénique d'un mélange gazeux en particulier d'air
US11/292,282 US7516626B2 (en) 2004-12-03 2005-12-02 Apparatus for the low-temperature separation of a gas mixture, in particular air
CA2528735A CA2528735C (fr) 2004-12-03 2005-12-02 Appareil de separation, a basse temperature, de melanges de gaz, particulierement de l'air
RU2005137481/06A RU2382963C2 (ru) 2004-12-03 2005-12-02 Установка для криогенного разделения смеси газов, в частности воздуха
CN200510128991A CN100575838C (zh) 2004-12-03 2005-12-05 用于低温分离气体混合物、特别是空气的设备

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP04028682 2004-12-03
EP04028681A EP1666822A1 (fr) 2004-12-03 2004-12-03 Installation pour la séparation cryogénique d'un mélange gazeux en particulier d'air
EP04028683A EP1666823A1 (fr) 2004-12-03 2004-12-03 Installation pour la séparation cryogénique d'un mélange gazeux en particulier d'air

Publications (1)

Publication Number Publication Date
EP1666822A1 true EP1666822A1 (fr) 2006-06-07

Family

ID=36565984

Family Applications (3)

Application Number Title Priority Date Filing Date
EP04028681A Withdrawn EP1666822A1 (fr) 2004-12-03 2004-12-03 Installation pour la séparation cryogénique d'un mélange gazeux en particulier d'air
EP04028683A Withdrawn EP1666823A1 (fr) 2004-12-03 2004-12-03 Installation pour la séparation cryogénique d'un mélange gazeux en particulier d'air
EP05024947.3A Not-in-force EP1672301B1 (fr) 2004-12-03 2005-11-15 Installation pour la séparation cryogénique d'un mélange gazeux en particulier d'air

Family Applications After (2)

Application Number Title Priority Date Filing Date
EP04028683A Withdrawn EP1666823A1 (fr) 2004-12-03 2004-12-03 Installation pour la séparation cryogénique d'un mélange gazeux en particulier d'air
EP05024947.3A Not-in-force EP1672301B1 (fr) 2004-12-03 2005-11-15 Installation pour la séparation cryogénique d'un mélange gazeux en particulier d'air

Country Status (6)

Country Link
US (1) US7516626B2 (fr)
EP (3) EP1666822A1 (fr)
CN (1) CN100575838C (fr)
CA (1) CA2528735C (fr)
PL (1) PL1672301T3 (fr)
RU (1) RU2382963C2 (fr)

Cited By (3)

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DE102007052136A1 (de) 2007-09-28 2009-04-02 Linde Aktiengesellschaft Verfahren zum Anfahren einer Tieftemperatur-Luftzerlegungsanlage und Tieftemperatur-Luftzerlegungsanlage
WO2012007691A2 (fr) 2010-07-13 2012-01-19 L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude Ensemble de refroidissement et appareil de separation d'air par distillation cryogenique comprenant un tel ensemble de refroidissement
CN105222524A (zh) * 2015-11-05 2016-01-06 天津市振津石油天然气工程有限公司 一种小型移动式天然气液化撬

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JP5913305B2 (ja) 2010-07-02 2016-04-27 エクソンモービル アップストリーム リサーチ カンパニー 低エミッション発電システム及び方法
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FR2962526B1 (fr) * 2010-07-09 2014-07-04 Air Liquide Appareil de refroidissement et d'epuration d'air destine a une unite de distillation cryogenique d'air
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CA2528735A1 (fr) 2006-06-03
CN1782644A (zh) 2006-06-07
CN100575838C (zh) 2009-12-30
CA2528735C (fr) 2013-08-06
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RU2005137481A (ru) 2007-06-20
US20060156759A1 (en) 2006-07-20

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