EP1663899A1 - Procede pour produire un liant hydraulique et un element de construction, utilisation de ces derniers et dispositif correspondant - Google Patents
Procede pour produire un liant hydraulique et un element de construction, utilisation de ces derniers et dispositif correspondantInfo
- Publication number
- EP1663899A1 EP1663899A1 EP04764896A EP04764896A EP1663899A1 EP 1663899 A1 EP1663899 A1 EP 1663899A1 EP 04764896 A EP04764896 A EP 04764896A EP 04764896 A EP04764896 A EP 04764896A EP 1663899 A1 EP1663899 A1 EP 1663899A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- mixture
- binder
- sand
- fine
- particles
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000000034 method Methods 0.000 title claims abstract description 70
- 239000011230 binding agent Substances 0.000 title claims abstract description 61
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 26
- 239000000203 mixture Substances 0.000 claims abstract description 65
- 239000002245 particle Substances 0.000 claims abstract description 42
- 230000008569 process Effects 0.000 claims abstract description 23
- 239000012190 activator Substances 0.000 claims abstract description 16
- 239000000463 material Substances 0.000 claims abstract description 11
- 230000003993 interaction Effects 0.000 claims abstract description 7
- 230000035939 shock Effects 0.000 claims abstract description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 73
- 239000004576 sand Substances 0.000 claims description 59
- 239000002893 slag Substances 0.000 claims description 34
- 239000004927 clay Substances 0.000 claims description 32
- 239000004567 concrete Substances 0.000 claims description 32
- 229920000867 polyelectrolyte Polymers 0.000 claims description 31
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 26
- 239000007789 gas Substances 0.000 claims description 21
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims description 19
- 235000011941 Tilia x europaea Nutrition 0.000 claims description 19
- 239000004571 lime Substances 0.000 claims description 19
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 16
- 239000010881 fly ash Substances 0.000 claims description 16
- 239000000126 substance Substances 0.000 claims description 16
- 239000004094 surface-active agent Substances 0.000 claims description 13
- 239000000654 additive Substances 0.000 claims description 12
- 229920000642 polymer Polymers 0.000 claims description 12
- 229910052782 aluminium Inorganic materials 0.000 claims description 11
- 239000004604 Blowing Agent Substances 0.000 claims description 10
- 238000001035 drying Methods 0.000 claims description 10
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 9
- 238000004056 waste incineration Methods 0.000 claims description 9
- 239000011449 brick Substances 0.000 claims description 8
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical class [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims description 8
- 229920001577 copolymer Polymers 0.000 claims description 8
- 239000010791 domestic waste Substances 0.000 claims description 8
- 235000011116 calcium hydroxide Nutrition 0.000 claims description 7
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical class [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 6
- 230000008859 change Effects 0.000 claims description 6
- 238000002485 combustion reaction Methods 0.000 claims description 6
- 239000011734 sodium Substances 0.000 claims description 6
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 5
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 5
- 150000007513 acids Chemical class 0.000 claims description 5
- 239000011575 calcium Substances 0.000 claims description 5
- 229910052791 calcium Inorganic materials 0.000 claims description 5
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical class [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- 239000004058 oil shale Substances 0.000 claims description 5
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 5
- 239000000377 silicon dioxide Substances 0.000 claims description 5
- 229920001909 styrene-acrylic polymer Polymers 0.000 claims description 5
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims description 5
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 4
- 239000010426 asphalt Substances 0.000 claims description 4
- VTYYLEPIZMXCLO-UHFFFAOYSA-L calcium carbonate Substances [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 4
- 235000012255 calcium oxide Nutrition 0.000 claims description 4
- XFWJKVMFIVXPKK-UHFFFAOYSA-N calcium;oxido(oxo)alumane Chemical compound [Ca+2].[O-][Al]=O.[O-][Al]=O XFWJKVMFIVXPKK-UHFFFAOYSA-N 0.000 claims description 4
- 239000003093 cationic surfactant Substances 0.000 claims description 4
- 239000000839 emulsion Substances 0.000 claims description 4
- 238000000227 grinding Methods 0.000 claims description 4
- 159000000001 potassium salts Chemical class 0.000 claims description 4
- 235000012239 silicon dioxide Nutrition 0.000 claims description 4
- 229910052708 sodium Inorganic materials 0.000 claims description 4
- 229910021532 Calcite Inorganic materials 0.000 claims description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 3
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 claims description 3
- 239000002956 ash Substances 0.000 claims description 3
- -1 calcium aluminates Chemical class 0.000 claims description 3
- 229910052593 corundum Inorganic materials 0.000 claims description 3
- 239000010431 corundum Substances 0.000 claims description 3
- 239000010459 dolomite Substances 0.000 claims description 3
- 229910000514 dolomite Inorganic materials 0.000 claims description 3
- 239000000428 dust Substances 0.000 claims description 3
- 238000011068 loading method Methods 0.000 claims description 3
- KVOIJEARBNBHHP-UHFFFAOYSA-N potassium;oxido(oxo)alumane Chemical compound [K+].[O-][Al]=O KVOIJEARBNBHHP-UHFFFAOYSA-N 0.000 claims description 3
- 239000000344 soap Substances 0.000 claims description 3
- 229910001388 sodium aluminate Inorganic materials 0.000 claims description 3
- 230000000996 additive effect Effects 0.000 claims description 2
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical class [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 2
- 235000010216 calcium carbonate Nutrition 0.000 claims description 2
- 239000005018 casein Substances 0.000 claims description 2
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 claims description 2
- 235000021240 caseins Nutrition 0.000 claims description 2
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 2
- 239000000194 fatty acid Substances 0.000 claims description 2
- 229930195729 fatty acid Natural products 0.000 claims description 2
- 150000004665 fatty acids Chemical class 0.000 claims description 2
- 239000001301 oxygen Substances 0.000 claims description 2
- 229910052760 oxygen Inorganic materials 0.000 claims description 2
- 229920006395 saturated elastomer Polymers 0.000 claims description 2
- 229910052645 tectosilicate Inorganic materials 0.000 claims description 2
- 238000011144 upstream manufacturing Methods 0.000 claims description 2
- 238000009825 accumulation Methods 0.000 claims 3
- 239000003245 coal Substances 0.000 claims 2
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims 2
- RHZUVFJBSILHOK-UHFFFAOYSA-N anthracen-1-ylmethanolate Chemical compound C1=CC=C2C=C3C(C[O-])=CC=CC3=CC2=C1 RHZUVFJBSILHOK-UHFFFAOYSA-N 0.000 claims 1
- 239000003830 anthracite Substances 0.000 claims 1
- 239000012530 fluid Substances 0.000 claims 1
- 230000005484 gravity Effects 0.000 claims 1
- 239000003077 lignite Substances 0.000 claims 1
- 239000011347 resin Substances 0.000 claims 1
- 229920005989 resin Polymers 0.000 claims 1
- 230000001960 triggered effect Effects 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 abstract description 5
- 230000004075 alteration Effects 0.000 abstract 1
- 238000007142 ring opening reaction Methods 0.000 abstract 1
- 239000004568 cement Substances 0.000 description 22
- 239000000047 product Substances 0.000 description 12
- 239000002689 soil Substances 0.000 description 10
- 241000196324 Embryophyta Species 0.000 description 8
- 239000011398 Portland cement Substances 0.000 description 7
- 238000005452 bending Methods 0.000 description 7
- 239000011148 porous material Substances 0.000 description 7
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 6
- 239000000920 calcium hydroxide Substances 0.000 description 6
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- 239000004575 stone Substances 0.000 description 6
- 229910000831 Steel Inorganic materials 0.000 description 5
- 239000010959 steel Substances 0.000 description 5
- 230000008901 benefit Effects 0.000 description 4
- 238000009826 distribution Methods 0.000 description 4
- 239000004572 hydraulic lime Substances 0.000 description 4
- 229920002401 polyacrylamide Polymers 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
- 238000005054 agglomeration Methods 0.000 description 3
- 230000002776 aggregation Effects 0.000 description 3
- 239000004566 building material Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 238000013467 fragmentation Methods 0.000 description 3
- 238000006062 fragmentation reaction Methods 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 239000011133 lead Substances 0.000 description 3
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 238000003825 pressing Methods 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 239000002699 waste material Substances 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 229910000805 Pig iron Inorganic materials 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 230000004913 activation Effects 0.000 description 2
- 239000013543 active substance Substances 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000009435 building construction Methods 0.000 description 2
- 239000000292 calcium oxide Substances 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical class [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 230000001419 dependent effect Effects 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- IQDGSYLLQPDQDV-UHFFFAOYSA-N dimethylazanium;chloride Chemical compound Cl.CNC IQDGSYLLQPDQDV-UHFFFAOYSA-N 0.000 description 2
- 230000008030 elimination Effects 0.000 description 2
- 238000003379 elimination reaction Methods 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 238000004880 explosion Methods 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 239000010419 fine particle Substances 0.000 description 2
- 238000009415 formwork Methods 0.000 description 2
- 239000010440 gypsum Substances 0.000 description 2
- 229910052602 gypsum Inorganic materials 0.000 description 2
- 239000011396 hydraulic cement Substances 0.000 description 2
- 239000002440 industrial waste Substances 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 229920000831 ionic polymer Polymers 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 230000002427 irreversible effect Effects 0.000 description 2
- 239000000395 magnesium oxide Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 235000010755 mineral Nutrition 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- AOHJOMMDDJHIJH-UHFFFAOYSA-N propylenediamine Chemical compound CC(N)CN AOHJOMMDDJHIJH-UHFFFAOYSA-N 0.000 description 2
- 239000011435 rock Substances 0.000 description 2
- 229910052814 silicon oxide Inorganic materials 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 230000008961 swelling Effects 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 241000648001 Anolis alumina Species 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229910001341 Crude steel Inorganic materials 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 235000002918 Fraxinus excelsior Nutrition 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 235000019738 Limestone Nutrition 0.000 description 1
- 229920000388 Polyphosphate Polymers 0.000 description 1
- 239000006004 Quartz sand Substances 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
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- 238000007605 air drying Methods 0.000 description 1
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- 229940037003 alum Drugs 0.000 description 1
- 229910052925 anhydrite Inorganic materials 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 235000011132 calcium sulphate Nutrition 0.000 description 1
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- 229940113118 carrageenan Drugs 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 230000001413 cellular effect Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 239000000567 combustion gas Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000001687 destabilization Effects 0.000 description 1
- 230000000368 destabilizing effect Effects 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
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- 150000002170 ethers Chemical class 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
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- 239000000835 fiber Substances 0.000 description 1
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- 125000000524 functional group Chemical group 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
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- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
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- 238000005342 ion exchange Methods 0.000 description 1
- 125000003010 ionic group Chemical group 0.000 description 1
- 239000006028 limestone Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 125000005608 naphthenic acid group Chemical class 0.000 description 1
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- 231100000719 pollutant Toxicity 0.000 description 1
- 239000001205 polyphosphate Substances 0.000 description 1
- 235000011176 polyphosphates Nutrition 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 235000018102 proteins Nutrition 0.000 description 1
- 108090000623 proteins and genes Chemical group 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 150000003222 pyridines Chemical class 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
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- 230000001105 regulatory effect Effects 0.000 description 1
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- 239000011701 zinc Substances 0.000 description 1
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- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical group [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/26—Bituminous materials, e.g. tar, pitch
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B18/00—Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B18/04—Waste materials; Refuse
- C04B18/14—Waste materials; Refuse from metallurgical processes
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B18/00—Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B18/04—Waste materials; Refuse
- C04B18/06—Combustion residues, e.g. purification products of smoke, fumes or exhaust gases
- C04B18/08—Flue dust, i.e. fly ash
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/021—Ash cements, e.g. fly ash cements ; Cements based on incineration residues, e.g. alkali-activated slags from waste incineration ; Kiln dust cements
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/10—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on aluminium oxide
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/28—Fire resistance, i.e. materials resistant to accidental fires or high temperatures
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Definitions
- the invention relates to a method for producing a hydraulic binder on an inorganic basis according to the preamble of claim 1 and a component and a gas concrete block.
- the invention also includes a device for carrying out the method and the use of the binder on the one hand and of polyelectrolytes on the other.
- Concrete is one of the most important building materials and usually consists of a mixture of mineral components - such as sand, gravel or quarry stones - and cement as a binder; the latter sets with the addition of water and creates a kind of conglomerate rock.
- the most important hydraulic binder for concrete is Portland cement (PZ), which consists of a finely ground mixture of PZ clinker and calcium sulfates - such as gypsum or anhydrite. After mixing with water, it hardens both in air and under water and maintains its strength even under water.
- Raw materials containing lime and clay - such as limestone, clay, lime marl and clay marl - are mixed with one another in such a way that the raw material mixture in addition to silica (S ⁇ ), alumina (Al 2 0 3 ) and iron oxide (Fe 2 0 3 ) contains between 75 and 79% by weight of lime (CaC0 3 ) from the clay content.
- the Geraisch is finely ground and then usually heated in rotary kilns with upstream preheating systems of various types until sintering.
- the Portland cement clinker resulting from this process is then subjected to fine grinding subjected and by admixing additives such as gypsum or the like. processed into Portland cement.
- cements include, for example, the metallurgical cements - Eisenportlandzement and Hocbiofenzement -, the trass cement and the oil shale cement, which contain various other aggregates for the Portland cement clinker (DIN 1164).
- Special cements not standardized as cement may include a. Alumina cement, deep drilling cement and swelling cement.
- the high-quality cements CEM * 42.5 and CEM 52.5 differ from normal cement CEM 32.5 in that they have a different composition and a higher fineness of grinding, which results in faster hardening - not setting - and on standardized test specimens after 28 Days gives the compressive strengths indicated by the numbers.
- the higher initial strengths of the high-quality cements enable the formwork to be stripped earlier and therefore to be built more quickly.
- fly ash is used as an additive in the manufacture of concrete; Fly ash is a product that is extracted from the exhaust gas from industrial furnaces or waste incineration plants by means of filter systems, which is carried as combustion residue in the combustion gases, mechanically entrained or condensed from the vapor state when it cools down.
- calcined ashes and fly ash - for example from industrial furnaces in the paper industry - or slag sands are used.
- the latter distort when the glowing red-hot blast furnace slag flowing from the slag tapping of the blast furnace is moved into moving water.
- CEM international term for cement
- the aim of the invention is to improve the usability of latent hydraulic binders - in particular those based on fly ash, calcined ash or blastfurnace slag and burnt oil shale - for practical use in the construction sector and, in particular, to enable faster hardening.
- the product is ground by high mechanical loading of the batch in an activator, which among other things results in an increase in the surface area.
- the globular structures of a fly ash are changed in such a way that an amorphous structure is created.
- This structure benefits the setting process by interlocking the individual particles and increases the strength values, especially the compressive and bending tensile strengths.
- the newly created reactive areas of the mixture subsequently increase the total specific surface area of the particles or grains - also called the Blain value.
- the surface enlargement through the fine grinding on the one hand and the transfer of the particle structures into reactive areas on the other hand result in an overall increase in the Blain value of 8 to 24 times compared to a Portland cement.
- shock waves continue in the particles, which lead to the fragmentation of the particles into amorphous structures and to disturbances of the lattice structure within the particles.
- An activator is used as the device for producing this hydraulic binder.
- This device enables the parameters necessary for activation to be reached at high speeds of the rotating tools up to 250m / sec.
- the control of the material feed, the air supply, the process heat and the material discharge are of great importance.
- the design of the tools for the mechanochemical as well as tribomechanical effects is of particular importance.
- the activator essentially consists of a rotor and a stator, which are held on a machine platform.
- the arrangement of the axis is vertical. It is driven by an electric motor using a V-belt on the rotor shaft to which the rotor is assigned.
- the speed of the rotor is infinitely variable via a frequency converter.
- the tools are exchangeable and adjustable.
- the products to be activated are fed into the interior of the activator from a silo from above through a metering device by means of a rotary valve.
- a rotary valve In an annular space or gap released by the rotor and stator, the batch is conveyed downward in a spiral, the air being held in counterflow by the dwell time of the product in this annular space. Also causes this air flow is the removal of excess heat.
- the individual particles are thrown outwards against the stator by a pulse - caused by the rotor tools.
- the tools of both the rotor and the stator are permanently coated with a layer of the mixture, so that the particles collide with one another or primarily with this layer.
- This mutual exposure and the effects achieved thereby - such as plastic deformation, resilience, fragmentation, friction - cause a fundamental change in the physical characteristics of the particles.
- the mass of the tools contributes significantly to supporting both the momentum and the momentum interruption and the resulting interactions such as reflections between the tools.
- the chemical composition of the mixtures that can be activated is of a similar order of magnitude to that of the cements.
- the product manufactured is mainly based on the basis of siliceous fly ash, blastfurnace slag and waste incineration slag.
- This main component is added with additives - such as calcium oxides, calcium oxides, calcium carbonates and aluminum hydroxide - under oxidative conditions in the activator.
- additives - such as calcium oxides, calcium oxides, calcium carbonates and aluminum hydroxide - under oxidative conditions in the activator.
- the supply of oxygen is ensured by air fed into the activator from below.
- the required proportion of admixture for a hardening time comparable to conventional concrete is in the range of 0.2 to 30 percent by weight with calcium aluminate.
- the admixtures for sodium aluminate or potassium aluminate are 0.1 to 20 percent by weight.
- the stated weight percentages relate to the finished binder mixture.
- Mixtures of calcium aluminate, sodium aluminate or potassium aluminate can, of course, also be used, in which the amount of the respective admixtures is determined in such a way that the ranges of the admixtures specified above are not exceeded.
- Type A (a) Characteristics • Slow setting based on strength class 32.5 N (> 32.5 N / mm 2 standard strength after 28 days); • compressive strength after 7 days> 16 N / mm 2 ; • E-module is given with the strength class; «High bending tensile strength.
- Type B (a) character! Stika • Medium-fast setting based on strength class 32.5 R (> 32.5 N / mm 2 standard strength after 28 days); »Compressive strength after 2 Tg> 10 N / mm 2 .
- Type C (c) Characteristics • Fast setting based on strength class 42.5 R (> 42.5 N / mm 2 standard strength after 28 days); • Compressive strength after 2 Tg> 20 N / mm 2 .
- these binders can be used in various areas.
- cationic surfactants it is achieved that after the curing phase, the component produced is waterproof after about 28 days; water is no longer absorbed by the structure of the component.
- the possible uses include to be seen in the areas of hydraulic engineering, landfill construction, soil remediation, disposal of contaminated sites, etc.
- this binder can be used in the area of thermally stable building materials such as in the lining of furnaces, converters, etc.
- thermally stable building materials such as in the lining of furnaces, converters, etc.
- the binder in the manufacture of aerated concrete. It has been shown here that when aluminum powder (less than 70 micrometers) is added, a closed-pore structure is formed, which corresponds to classic products in terms of strength values, densities, etc.
- the scope of the invention also includes a method for producing components such as bricks, plates or molded parts for building construction and civil engineering, which should be inexpensive to carry out; the components produced in this way should prove to be resistant to tensile and compressive loads and to weather.
- a mixture of the same proportions of clay with particle sizes below 100 ⁇ m, fine sand with particle sizes from 100 ⁇ m to 2 mm and sand with particle sizes over 2 mm is mixed in a mixer with polyelectrolytes - preferably polymers or copolymers based of acrylamide - and a hydraulic binder mixed, introduced into molds and pressed at a pressure of at least 40 N / mm 2 .
- This process is particularly easy to carry out, since on the one hand only low demands are made on the equipment and on the other hand the required proportioning components are easily and cheaply available.
- Clay is understood to mean that portion of the soil whose grain sizes are below 100 ⁇ m, fine sand that portion with particle sizes of 100 ⁇ m - 2 mm and as sand that part with grain sizes over 2 mm. These parts of clay, fine sand and sand are abundant in soils, although the proportions of clay, fine sand and sand obtained by removing the soil can of course differ in their proportions from the required composition. European soils have a high clay and gravel content, so that sand must be added in this case.
- the necessary hydraulic binders such as cement, highly hydraulic lime, hydrated lime or fine lime, are also available in abundance and cheaply.
- the choice of the respective binder and its required admixing amount depend in particular on the exact grain size distribution and moisture of the prepared mixture.
- the grain size distribution of the processed batch not only the quantity distribution between clay, fine sand and sand content is of interest, but also the grain size distribution within each of these Groups.
- Basic properties of the prepared batch, such as its compressibility, can already be derived from this.
- fine lime or hydrated lime generally prove to be suitable as hydraulic binders for carrying out the method according to the invention, although in some cases highly hydraulic lime, cement and bituminous binders can also be used.
- a polyelectrolyte is a water-soluble ionic polymer that is anionic from polyacids - e.g. polycarboxylic acids - cationic from polybases - e.g. Polyvinylammonium chloride - is formed or is neutral (polyampholytes or polysalts).
- An example of natural polyelectrolytes are polysaccharides with ionic groups such as carrageenan, but also proteins and long-chain polyphosphates.
- polyacrylamides are preferably used as polyelectrolytes, that is to say compounds made from monomers based on acrylamide.
- mixtures of mono- and polymeric polyelectrolytes possibly together with solubilizers, emulsifiers and catalysts, and with admixtures of propylenediamine, dimethylammonium chloride or isopropyl alcohol.
- mixtures of cationic surfactants can also be introduced.
- the mixture of clay, fine sand and sand mixture, polyelectrolyte and hydraulic binder is subsequently introduced into molds and pressed at a pressure of at least 40 N / mm 2 .
- the choice of the pressing pressure influences the ultimate strength of the components, but usually a pressure of 40 - 120 N / mm 2 is sufficient.
- the polyelectrolyte is admixed with a preferred proportion of 0.001-2% by weight, based on the dry weight of the mixture of clay, fine sand and sand.
- a styrene-acrylic copoly should be added to the hydraulic binder before adding the hydraulic binder, which is particularly advantageous in wet and salty batches.
- the objectives of the invention are also achieved by the characterizing features of claim 22.
- This procedure is particularly advantageous for prepared batches that have low moisture and a high proportion of fine sand.
- the prepared mixture will be a bitumen emulsion as well as polyelectrolytes, "preferably polymers or copolymers based on acrylamide added.
- polyelectrolyte in a preferred proportion of 0.001-2% by weight, based on the dry weight of the mixture of clay, fine sand and sand.
- polyelectrolytes preferably polymers or copolymers based on acrylamide, for the production of structural elements such as bricks, plates or molded parts for building construction and civil engineering.
- Claim 36 discloses bricks and molded parts for civil engineering, which contain polyelectrolytes, preferably polymers or copolymers based on acrylamide.
- water-soluble ionic polymers are referred to here as polyelectrolytes, which are formed anionically from polyacids - for example polycarboxylic acids - cationically from polybases - for example polyvinylammonium chloride - or are neutral (polyampholytes or polysalts). It is also conceivable to use mixtures of mono- and polymeric polyelectrolytes, possibly together with solubilizers, emulsifiers and catalysts, and with admixtures of propylenediamine, dimethylammonium chloride or isopropyl alcohol.
- polymers have ionic dissociable groups that can be part of the polymer chain and the number of which is so large that the polymers are water-soluble in dissociated form.
- Polyacrylamide is preferably used in suspension form.
- polyelectrolytes In aqueous solution, polyelectrolytes have reactive groups that show a strong affinity for the surfaces of the colloids and fine particles of the fine-grain portion of the soil.
- the polyelectrolytes used in the invention can thus also be referred to as cross ⁇ surface-active substances.
- the potentials that are effective on the particle surface are decisive for the optimal effect of the polyelectrolyte. They are dependent on the particles themselves as well as on the environmental conditions, i.e. on the ionic strength of the mixture and the resulting properties, such as pH, electrical conductivity or hardness.
- the person skilled in the art will determine the polyelectrolyte with the corresponding ionogenicity which is suitable for the respective application.
- polyacrylamide for example, is suitable in most cases and has good strengthening properties.
- the polyelectrolyte is used here in a preferred proportion of 0.001-2% by weight, based on the dry weight of the mixture.
- the proportion will be based in particular on the ionogenicity of the polyelectrolyte used and on the fine-grain fraction of the batch.
- polyacrylamide 0.01% by weight has mostly proven to be sufficient.
- any necessary addition of water can be dosed by dilution with water.
- a styrene-acrylic copolymer for example an acrylic acid dispersion
- a bitumen emulsion is preferably added. But it is not out of the question that there will be one Mixture of a styrene-acrylic copolymer and a bitumen emulsion can prove to be advantageous.
- the hydraulic binder is added.
- fine lime or hydrated lime have proven to be suitable binders for carrying out the process according to the invention, and in cases where there is a large proportion of larger grain sizes, highly hydraulic lime, cement and bituminous binders can also be advantageous.
- the admixing amount of the respective binder is also based in particular on the moisture of the prepared batch, whereby efforts are made to achieve the so-called Proctor optimum, which is the degree of saturation of the batch at which the batch's optimum compressibility given is. Soils and the clay, fine sand and sand components obtained from them often have too high a moisture content, whereby water is extracted from the mixture when using fine lime, hydrated lime or highly hydraulic lime.
- the mixture consisting of clay, fine sand and sand mixture, polyelectrolyte and hydraulic binding agent or any necessary additives such as styrene-acrylic copolymers is then introduced into molds and pressed at a pressure of at least 40 N / mm 2 .
- the choice of the pressing pressure influences the ultimate strength of the components, but usually a pressure of 40-120 N / mm 2 is sufficient.
- the components can be loaded after 50% drying.
- the scope of the invention also includes a method for producing a gas concrete block, in which a mixture of a hydraulic binder, a fine-grained component, water and a blowing agent is produced, poured into molds and dried.
- the mixture is poured into molds, and different formats and profiles can be cut in the semi-solid state.
- the high strength of the aerated concrete is achieved by steam curing in autoclaves at approx. 160-220 ° C and approx. 12-15 bar pressure after about four to eight hours. The hydrogen escapes and the pores formed fill with air.
- the gas concrete blocks manufactured in this way have comparatively low densities of up to around 400 kg / m 3 and, due to the pore structure and their air pockets, have good thermal insulation properties.
- household waste is comminuted, homogenized and prepared with calcium-containing additives such as dolomite, calcite, lime marl or marl as well as with aluminum oxide-containing additives such as corundum dust, clay marl or to produce the hydraulic binder used for this method according to the invention Clinker mixed and burned; then up to 40% by weight Framework silicates, for example tuff, are added, and the product obtained is ground to a grain size of less than 0.063 mm.
- Framework silicates for example tuff
- fine slag from waste incineration plants, metallurgical or steel slag is used as a fine-grained component and a surfactant is used as a blowing agent.
- Typical household waste usually contains 59-69% silicon oxide, 4.9-7.8% iron oxide, 5.1-6.3% aluminum oxide and 8.3-10.3% lime in% by weight and is therefore suitable for production an inorganic binder for concrete-like hardening masses.
- the binder can be produced in waste incineration plants that are run on special refuse-derived fuels (BRAM). These are 18% to 26% by weight of silicon oxide, 2% to 5% iron oxide, 4% to 12% aluminum oxide and 58% to 66% lime, and 2% to 5% magnesium oxide.
- BRAM refuse-derived fuels
- the combustion bed temperature is at least 950 ° C and the calorific value of the waste is at least 13MJ / kg. The latter circumstance ensures that practically no additional primary energy has to be added for combustion.
- calcium-containing industrial waste or calcium-containing rock such as dolomite, calcite, lime marl and the like. added that are readily available.
- additives industrial waste such as corundum dust, but also clay marl, clinker and the like can also be used. be used.
- fine slag from waste incineration plants MAA
- metallurgical slag or steelworks slag is used as the fine-grained component.
- These are the solid, non-combustible residues that arise in the course of combustion in industrial furnaces or incinerators.
- waste incineration slag When incinerating waste, slag still accounts for around 35% of the original weight of the waste. In addition to the iron-containing components, waste incineration slag also contains significantly smaller amounts of non-ferrous metals such as copper, nickel, lead, zinc or tin in varying amounts.
- Iron and steel slag can be broken down into blast furnace slag and steel works slag, whereby blast furnace slag is produced in the production of pig iron in the blast furnace and steel works slag in steel production in converters, in electric furnaces and Siemens Martin furnaces.
- Metallurgical slag is formed during the extraction of non-ferrous (NE) metals. According to the current state of the art, about 250 kg of blast furnace slag is produced per ton of pig iron and about 120 kg of steelworks per ton of crude steel. slag. This results in large amounts of slag that can be recycled.
- Blast furnace and steelworks slag differ in their chemical composition, but because of their main components calcium oxide, silicon dioxide, aluminum oxide and iron oxide they are both also suitable for use with the method according to the invention.
- a blowing agent such as a surfactant can also be used.
- This is understood to mean compounds that accumulate strongly from their solution at interfaces (eg water / oil) and thereby reduce the surface tension - in the case of liquid / gaseous systems, the surface tension.
- polar solvents such as alcohols, ethers, pyridines, alkylformamides, etc. are also surface-active
- the compounds used as surface-active substances in the context of the invention are those which have a lipophilic hydrocarbon radical and one, possibly also several, hydrophilic functional groups.
- - -COONa, -S0 3 Na, -0-S0 3 Na and the like - have; such substances are also referred to as surfactants or detergents.
- These can be water-soluble sodium or potassium salts of saturated and unsaturated higher fatty acids (also known as lye soap) or water-soluble sodium or potassium salts of the rosin rosin acids (also known as rosin soap), or water-soluble sodium or potassium salts of naphthenic acids - for example alkyl naphthalene sulfonic acid enriched on the casein basis.
- the surface-active Agents are added in an amount of 0.03 to 0.001% by weight, based on the mixture before drying.
- Drying can also be carried out without steam curing and without the production of high pressures; instead, air drying has proven to be sufficient.
- the maturing process until the gas concrete blocks can be processed takes about 3 to 7 days, with the final strength increasing as the drying time increases. This not only achieves high energy savings, but also enables the production of more complicated shapes due to the elimination of the steam autoclave. The risk of explosion associated with the use of aluminum powder is eliminated.
- the density of the gas concrete blocks produced according to the invention is between 650 and 1200 kg / cm 3 .
- the compressive strengths and the bending tensile strengths are dependent on the density, the ratio between compressive strength and bending tensile strength being significantly greater than in the case of concrete, ie the existing bending tensile strength is comparatively high in relation to the compressive strength. This ensures that thermal insulation panels made from this material have excellent stability.
- this method according to the invention it is also possible to reinforce the gas concrete block produced in this way with fibers, for example based on coconut or plastic, whereby the bending tensile strength can be increased considerably. It is shown that in particular the use of fine slag instead of the fine sand usually used has extremely favorable effects on the strength of the gas concrete block produced by the method according to the invention.
- powdered aluminum can also be used in addition to the surfactant, which is aluminum from recycled materials. In this case too, the energy-intensive and complex steam autoclaving can be dispensed with.
- the powdered aluminum is added in an amount of 0.05 to 0.001% by weight, based on the mixture before drying.
- the amount of aluminum powder used will depend on the one hand on the amount of the surfactant used and on the other hand depend on which properties, in particular what density, the final gas concrete block should have.
- additional quantities of aluminum powder ensure that the pore structure turns out coarser after drying, which reduces the density of the gas concrete block.
- the average pore size depends on the average grain size of the aluminum powder used. It is obvious that depending on the mixing ratio and grain sizes of the aluminum powder used and the blowing agent, different properties of the final gas concrete block can be realized.
- This invention thus provides an extremely inexpensive method of manufacturing a gas concrete block that is extremely suitable for use as a high-quality, heat-insulating lightweight building material.
- Fig. 6 the side view of a tool part.
- a pile 10 of spherical components 12 is shown. Due to the high mechanical loading of this mixture in an activator described below, the product is ground, whereby u. a. an increase in the surface is achieved.
- the globular structures of a fly ash are changed in such a way that an amorphous structure is created. This structure favors the setting process by interlocking the individual particles 14 which have arisen after a comminution process and increases the strength values, in particular the compressive and bending tensile strengths.
- shock waves continue in the particles 12, which break them down into amorphous structures and disrupt the structures Lattice structure within the particles lead, as shown in FIG. 2.
- the comminution takes place in a so-called activator 20, which has a rotor 24 and a stator 30 on a machine platform 22, the top plate 32 of which is penetrated by a rotor shaft 26.
- the latter runs coaxially to the vertical axis A of the rotor 24.
- the rotor 24 is driven by an electric motor 36, which can be seen outside the stator wall 34, by means of a V-belt 38 on the rotor shaft 26.
- the speed of the rotor 24 is infinitely variable via a frequency converter, which cannot be seen.
- a metering device 42 is a cylindrical silo from which the pile 10 is fed to a metering device 42. Beneath this is a floor-level horizontal arm 45 of a conveyor 44 - in longitudinal section here Z-shaped - whose inclined central section 46 merges into a ridge arm 47 above the cover plate 32 of the stator 30. The latter is followed by a cellular wheel sluice 50 through which the material to be conveyed 10 is fed to the interior of the activator 20.
- the batch 10 is conveyed downward in a spiral in the annular space or annular gap 52, the dwell time of which can be regulated by counter-flowing air. This air flow also removes the excess heat.
- the individual particles 14 are thrown outwards against the stator 30 by a pulse - caused by the rotor tools 54 r .
- the tools 54 and 54 r of both the stator 20 and the rotor 24 are continuously coated with a layer of the mixture 10, so that the particles 14 collide with one another or primarily with this layer. This mutual action and the effects achieved thereby - such as plastic deformation, resilience, fragmentation, friction - cause a fundamental change in the physical properties of the particles 14.
- the mass of the layers 54, 54 r contributes significantly to both the momentum and the momentum interruption and the resulting interactions such as reflections between the figures 54, 54 r to support.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Environmental & Geological Engineering (AREA)
- Inorganic Chemistry (AREA)
- Civil Engineering (AREA)
- Combustion & Propulsion (AREA)
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- Processing Of Solid Wastes (AREA)
Abstract
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
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AT0060903U AT7308U1 (de) | 2003-09-08 | 2003-09-08 | Verfahren zur herstellung von bauelementen für den hoch- und tiefbau |
DE102004025050 | 2004-05-18 | ||
AT0036604U AT8003U1 (de) | 2004-05-18 | 2004-05-18 | Verfahren zur herstellung eines gasbetonsteines |
PCT/EP2004/009953 WO2005037727A1 (fr) | 2003-09-08 | 2004-09-07 | Procede pour produire un liant hydraulique et un element de construction, utilisation de ces derniers et dispositif correspondant |
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EP1663899A1 true EP1663899A1 (fr) | 2006-06-07 |
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EP04764896A Withdrawn EP1663899A1 (fr) | 2003-09-08 | 2004-09-07 | Procede pour produire un liant hydraulique et un element de construction, utilisation de ces derniers et dispositif correspondant |
Country Status (7)
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EP (1) | EP1663899A1 (fr) |
JP (1) | JP2007505023A (fr) |
KR (1) | KR20070012310A (fr) |
AU (1) | AU2004281885A1 (fr) |
CA (1) | CA2538056A1 (fr) |
DE (1) | DE102004043614A1 (fr) |
WO (1) | WO2005037727A1 (fr) |
Cited By (1)
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CN108348967A (zh) * | 2015-09-03 | 2018-07-31 | 丹尼兹.格拉夫 | 用于拆解复合材料和混合物、尤其是固体混合物和炉渣的方法和装置 |
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DE102005020441A1 (de) * | 2005-04-29 | 2006-11-02 | Silver Cay Worldwide Corp. | Vorrichtung und Verfahren zum Behandeln von Verbundelementen |
DE102007048105A1 (de) * | 2007-10-05 | 2009-04-09 | Drache Umwelttechnik Gmbh | Verfahren zur Herstellung eines Feuerfestmaterials sowie Feuerfestmaterial |
CZ2008318A3 (cs) * | 2008-05-23 | 2010-04-07 | Faltus@Miloš | Zpusob výroby anorganických hydraulických pojiv |
CN102300826B (zh) | 2009-01-30 | 2015-02-18 | 全南大学校产学协力团 | 碱激活结合料、使用结合料的碱激活砂浆、混凝土制品和湿红粘土铺路材料 |
KR100942032B1 (ko) * | 2009-01-30 | 2010-02-11 | 전남대학교산학협력단 | 무시멘트 알칼리 활성결합재, 상기 결합재를 포함하는 무시멘트 알칼리 활성 모르터, 콘크리트 및 콘크리트 제품 |
JP2010095444A (ja) * | 2010-02-04 | 2010-04-30 | Nagoya Institute Of Technology | セラミックスの固化方法 |
EP2711347A1 (fr) * | 2012-09-21 | 2014-03-26 | HeidelbergCement AG | Procédé et moyen destinés à préparer des agrégats |
CA2920810C (fr) * | 2013-08-15 | 2022-10-18 | Sika Technology Ag | Agent entraineur d'air pour compositions de liant mineral |
CN104131628B (zh) * | 2014-07-24 | 2016-08-17 | 吴佰仲 | 一种防火芯板及其制备方法和防火装饰板 |
FR3071494B1 (fr) * | 2017-09-25 | 2022-07-15 | Sarp Ind | Procede de fabrication d'un materiau poreux a partir de machefers d'incineration |
WO2019170963A1 (fr) * | 2018-03-09 | 2019-09-12 | Betolar Oy | Composition de liant et mélange durcissable |
DE102020128894A1 (de) | 2020-11-03 | 2022-05-05 | Harald Kurkowski | Baustoff und Verfahren zum Herstellen eines derartigen Baustoffes |
DE102021127319A1 (de) * | 2021-10-21 | 2023-04-27 | pro CLIR GmbH | Verfahren zum Gewinnen einer wiederverwendbaren Gesteinskörnung aus Aschen von Hausmüllverbrennungsanlagen |
DE102022117825A1 (de) | 2022-07-17 | 2024-01-18 | Gesellschaft für innovative und nachhaltige Lösungen im Bauwesen UG (haftungsbeschränkt) | Verfahren zur Anwendung von definierten anorganischen feinsten festen Partikeln |
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FR67694E (fr) * | 1955-03-16 | 1958-03-17 | Masse dure cellulaire, résistante et légère, pouvant être utilisée pour la confection à froid des tuiles et des briques | |
GB1040442A (en) * | 1962-04-13 | 1966-08-24 | Gascon Ltd | Improvements relating to cementitious material |
AT256694B (de) * | 1963-04-11 | 1967-09-11 | Straa Kalkbruk Ab | Verfahren zur Herstellung eines aus einer Mischung von gemahlener Hochofenschlacke und gelöschtem Kalk bestehenden Bindemittels, insbesondere für Mörtel und Putzmörtel |
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-
2004
- 2004-09-07 KR KR20067006943A patent/KR20070012310A/ko not_active Application Discontinuation
- 2004-09-07 CA CA 2538056 patent/CA2538056A1/fr not_active Abandoned
- 2004-09-07 DE DE200410043614 patent/DE102004043614A1/de not_active Withdrawn
- 2004-09-07 JP JP2006525131A patent/JP2007505023A/ja active Pending
- 2004-09-07 WO PCT/EP2004/009953 patent/WO2005037727A1/fr active Application Filing
- 2004-09-07 EP EP04764896A patent/EP1663899A1/fr not_active Withdrawn
- 2004-09-07 AU AU2004281885A patent/AU2004281885A1/en not_active Abandoned
Non-Patent Citations (1)
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See references of WO2005037727A1 * |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108348967A (zh) * | 2015-09-03 | 2018-07-31 | 丹尼兹.格拉夫 | 用于拆解复合材料和混合物、尤其是固体混合物和炉渣的方法和装置 |
CN108348967B (zh) * | 2015-09-03 | 2021-09-14 | 丹尼兹.格拉夫 | 用于拆解复合材料和混合物、尤其是固体混合物和炉渣的方法和装置 |
Also Published As
Publication number | Publication date |
---|---|
KR20070012310A (ko) | 2007-01-25 |
WO2005037727A1 (fr) | 2005-04-28 |
DE102004043614A9 (de) | 2005-08-11 |
JP2007505023A (ja) | 2007-03-08 |
CA2538056A1 (fr) | 2005-04-28 |
AU2004281885A1 (en) | 2005-04-28 |
DE102004043614A1 (de) | 2005-04-21 |
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