EP1565614B1 - Verfahren zur herstellung von superdickgriffigen lwc-papieren - Google Patents

Verfahren zur herstellung von superdickgriffigen lwc-papieren Download PDF

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Publication number
EP1565614B1
EP1565614B1 EP03811840A EP03811840A EP1565614B1 EP 1565614 B1 EP1565614 B1 EP 1565614B1 EP 03811840 A EP03811840 A EP 03811840A EP 03811840 A EP03811840 A EP 03811840A EP 1565614 B1 EP1565614 B1 EP 1565614B1
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Prior art keywords
pigment
coating
weight
paper
nip
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English (en)
French (fr)
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EP1565614A2 (de
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Bob c/o International Paper Company CHING
Xiao-Qin c/o International Paper Company WANG
J. Veverka Peter
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Verso Paper LLC
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International Paper Co
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    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H25/00—After-treatment of paper not provided for in groups D21H17/00 - D21H23/00
    • D21H25/08—Rearranging applied substances, e.g. metering, smoothing; Removing excess material
    • D21H25/12—Rearranging applied substances, e.g. metering, smoothing; Removing excess material with an essentially cylindrical body, e.g. roll or rod
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/38—Coatings with pigments characterised by the pigments
    • D21H19/42—Coatings with pigments characterised by the pigments at least partly organic
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/52—Cellulose; Derivatives thereof
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H23/00—Processes or apparatus for adding material to the pulp or to the paper
    • D21H23/02—Processes or apparatus for adding material to the pulp or to the paper characterised by the manner in which substances are added
    • D21H23/22—Addition to the formed paper
    • D21H23/32—Addition to the formed paper by contacting paper with an excess of material, e.g. from a reservoir or in a manner necessitating removal of applied excess material from the paper
    • D21H23/34—Knife or blade type coaters

Definitions

  • the present invention relates to a process of manufacturing a high bulk, low weight paper product having stiffness and opacity comparable to heavier weight sheets, the process consisting of using a high level of groundwood containing sheet, coating with specifically formulated coatings then passing the paper web through two extended-nip calenders, using one nip for each side of the paper.
  • U.S. Patent Nos. 6,287,424 , 6,332,953 , and 4,749,445 discloses a high gloss lightweight paper stock that is coated with a pigment composition including delaminated clay, calcined clay and titanium dioxide, wherein up to about 5 parts by weight of hollow core opacifying plastic pigment may be substituted for the titanium dioxide.
  • U.S. Patent No. 4,090,307 discloses a high gloss coated paper product comprising 70-95% calcium carbonate and from 5-30% by weight of a non-film forming polymeric pigment having particles sized within the range of from 0.05-0.30 ⁇ m (microns).
  • the finishing operation may be a calendering process, in which the paper web is passed between the nips formed between or more pairs of rolls and the surface of the web is thereby flattened to form a smooth surface. Simultaneously, the thickness, or caliper, of the paper web is reduced and the web is densified. Bulk is inversely related to density, therefore when the density is increased the bulk of the finished paper product will be reduced. Further attempts to make lightweight (10.19-18.14 kg) (24-40 pounds) high bulk coated paper have been made utilizing on-line hot soft calender, on-line supercalender, or off-line supercalender at reduced loading and nip number. See, for example, U.S. Patent Nos.
  • US-A-5,400,707 discloses a hot soft nip calender apparatus for a paper mill including at least one heated calender roller and a finishing belt which is moved in proximity to the heated calender roller by a plurality of drive rollers and at least one pressure roller.
  • US-A-5,283,129 relates to a light weight coated paper prepared with an aqueous coating formulation comprising delaminated clay, calcined clay, whitening pigment, starch binder, starch cross-linking agent, lubricant and water at a pH of about 8 to 8.5.
  • WO 01/98 585 discloses a calendering method for precalendering where a paper web is guided through a calenderig nip formed between two surfaces, where in the nip heat is conducted on the surface of the web to be calendered and pressure is exerted thereon within a fixed length in the travel direction of the web.
  • the present invention provides a process of making a 0.0444 kg/m 2 (30 pounds/3300 square feet) super high bulk, lightweight coated (LWC) paper having high stiffness, opacity and brightness that may be used as a "low end" offset paper, which process consists of using high level of groundwood containing sheet, blade coating with specifically formulated coatings, followed by calendering with two extended-nip calenders, one calender for each side of paper.
  • LWC lightweight coated
  • the extended-nip calendered paper of the present invention exhibits better brightness and opacity, and equivalent or better printing performance, specifically in the print gloss performance, than supercalendered counterparts.
  • the significantly higher bulk resulting from the use of two extended-nip calenders is largely due to better bulk preservation of the extended-nip calender, that is, under an equivalent loading using two extended-nip calenders gives lower nip intensity than supercalender and hot soft calender.
  • an object of the invention is to provide a process for making a super high bulk, offset lightweight coated paper, comprising the steps of:
  • Another object of the Invention is to provide a process for making a 0.0444kg/m 2 (30 pounds/3300 square feet) super high bulk, No. 5 offset lightweight coated paper.
  • Another object is to provide a furnish comprising at least 40% mechanical pulp, preferably 60% mechanical pulp, wherein the mechanical pulp portion comprises an equal blend of thermal mechanical pulp (TMP) and a conventional stone groundwood pulp, and wherein the remaining makeup is Kraft.
  • TMP thermal mechanical pulp
  • a further object of the present invention is to provide a process for making a super high bulk, offset lightweight coated paper, wherein the coating formulation is preferably applied using a blade coater or a metering size press.
  • Another object of the invention is to provide a process for making a super high bulk, offset lightweight coated paper, wherein the coating formulation consists of (i) a hollow plastic pigment; (ii) a kaolin pigment; (iii) a calcined kaolin clay; (iv) a titanium dioxide (TiO 2 ) pigment; (v) a synthetic latex binder, and (vi) a synthetic thickener (or a co-binder including carboxymethylcellulose (CMC) or acrylic acid based or associative based thickeners.
  • the coating formulation consists of (i) a hollow plastic pigment; (ii) a kaolin pigment; (iii) a calcined kaolin clay; (iv) a titanium dioxide (TiO 2 ) pigment; (v) a synthetic latex binder, and (vi) a synthetic thickener (or a co-binder including carboxymethylcellulose (CMC) or acrylic acid based or associative based thickeners.
  • Another object is to provide a coating formulation wherein said hollow plastic pigment, in an amount of at least about 2% by weight, and preferably 3 to 5% by weight of the total amount of pigments.
  • Another object is to provide a coating formulation wherein said kaolin pigment is at least about 70% by weight, preferably 80-100% by weight of the total amount of pigment, and has a fine particle size distribution characterized by at least 85% of said particles are less than 2 microns and at least 50% of said particles are less than 0.5 ⁇ m (microns), based upon particle count using a Sedigraph particle size analyzer, and wherein said kaolin pigment has a platy morphology characterized as both fine and coarse particles having a shape factor greater than 15, preferably 20-27.
  • Another object is to provide a coating formulation wherein said calcined kaolin is at least about 5% by weight of the total amount of pigment.
  • Another object is to provide a coating formulation wherein said TiO 2 , In an amount of at least about 2% by weight and preferably 3 to 5% by weight of the total amount of pigment.
  • Another object is to provide a coating formulation wherein said synthetic latex is in a concentration of at least about 12 or more parts by weight of the total amount of pigment.
  • Another object is to provide a coating formulation wherein said synthetic thickener is in a concentration of at least about 0.05 or more parts by weight of the total amount pigment.
  • Another object is to provide a coating formulation which coating may also comprise precipitated calcium carbonate (PCC) or ground calcium carbonate (GCC).
  • PCC precipitated calcium carbonate
  • GCC ground calcium carbonate
  • Another object of the present invention is to provide a coating having a weight of at least 0.00293 kg/m 2 (2.0 pounds per 3300 square feet) preferably 0.00293 to 0.0889 kg/m 2 (2.0 to 60 pounds per 3300 square feet) and most preferably 0.00391 to 0.0083 kg/m 2 (2.5 to 5.5 pounds. per 3300 square feet) per side onto each surface of said web to form a coated web having a moisture content prior to calendering of at least 5.5%, preferably 6.5-8.0%, and most preferably 7.0%, the coating comprising a fine, platy kaolin pigment, a latex binder, and a thickener, said coated web having a caliper greater than 66,04 ⁇ m (2.6 mils).
  • Another object of the present invention is to provide a process for making a super high bulk, offset lightweight coated paper, while preserving significantly more of the original bulk than traditional supercalender or hot soft calenders, the calendering step is carried out using two extended-nip calenders, wherein the calender is preferably a shoe nip calender (SNC), said shoe nip width being in the range of from about 40 mm to about 80 mm, and calendering temperature controlled at about 422 K (300°F) to about 444.0 K (430°F) and nip loading at 303.6-428.6 kg per cm (1700-2400 pli).
  • SNC shoe nip calender
  • Another object of the present invention is to provide a process for making a super high bulk offset lightweight coated paper, wherein the finished coated paper has a basis weight of 0.0415 to 0.05615 kg/m 2 (28 to 38 pounds per 3300 square feet) and exhibits a 75° TAPPI gloss of 35% or above and a caliper of at least 54.61 ⁇ m (2.15 mils).
  • Another object of the present invention is to provide a process for making a super high bulk, offset lightweight coated paper wherein the LWC gives a 17-27% higher caliper than that of a supercalendered 0.0444 kg/m 2 (30 pounds/3300 square feet) LWC and has improved brightness, opacity and printing gloss.
  • Another object of the present invention is to provide a process for making a super high bulk, offset lightweight coated paper, wherein said extended-nip, shoe calender produces a No. 5 LWC offset sheet with up to 22% bulk improvement relative to its supercalendered counterparts, while providing better brightness and opacity, as well as providing comparable or better printing performance.
  • the process of the Invention produces a low weight paper product having a relatively high bulk, therefore producing a thicker sheet of reduced density or compaction, while maintaining the benefits of higher stiffness and opacity that are comparable to that of a heavier weight sheet
  • a basepaper is produced with a high level of mechanical pulp.
  • the process further comprises a coating formulation composed of a pigmentation containing (i) hollow plastic pigments in an amount of at least 2% by weight of the total amount of pigments (ii) platy or fine particle engineered kaolin in an amount of at least 70% by weight of the total amount of pigment, (III) TiO 2 in an amount of at least 2% by weight of the total amount of pigment, and (iv) calcined clay in an amount of at least 10% of the total amount of pigment.
  • Binders include 14-20 parts by weight of total pigment bi-modal particle size distribution styrene butadiene (PSD SB) latex or SB latex with Acronitrile modification.
  • Co-binders include CMC, acrylic acid based, or associative based thickeners.
  • the coating formulation is applied using blade coater or a metering size press at coat weights ranged from about 0.00391 to 0.0083 kg/m 2 (2.5 to 5.5 pounds/3300 square feet).
  • the process of the present invention further comprises a calendering step, which is done using two extended-nip calendars, with one nip per side, in which the coated side of the paper faces the thermal rolls with temperature ranged from 433.2 K (320° F) to 488.7 K (420°F). Line loadings are ranged from about 260-464.3 kg per cm (1400-2600 PLI). Sheet moisture prior to calendering is controlled at about or above 6.5%. The resulting paper exhibits better brightness and opacity than supercalendered counterparts. Printing performance is equivalent or better than supercalendered counterparts, specifically in print gloss performance.
  • the LWC paper manufactured using the process of the present invention, would start with a waterborned furnish having a high percentage of mechanical pulp with the remaining makeup is Kraft.
  • the mechanical pulp is generally about at least 40%, usually in the 40% to 80% range, and preferably in the range of 60% to 80%.
  • the mechanical pulp portion comprises an equal blend of thermal mechanical pulp and conventional stone groundwood pulp.
  • the remaining composition is Kraft Mechanical pulp gives a well-formed base.
  • mechanical pulp may include stone ground wood (SGW), thermal mechanical pulp (TMP), and chemi-thermal mechanical pulp (CTMP).
  • Sample furnish formulations are: (1) 30% TMP/30% SGW/40% softwood Kraft (SWK) and (2) 60% TMP/10% PGW 30% SWK.
  • SWK is not considered a mechanical pulp. Another example might be 55%-65%CTMP/35%-45% SWK.
  • a paper sheet is created from the above furnish using conventional papermaking equipment
  • the paper sheet then moves into the press section wherein it can be conventionally pressed.
  • the web is then sent through the dryer section and dried to a moisture con- .. tent of below 6% and preferably to 4% or less.
  • the paper may then be coated on or off the papermaking machine with the coating formulation of the present invention.
  • a coating formulation is applied before finishing.
  • the coating formulation according to the present invention comprises (i) a hollow plastic pigment; (ii) a kaolin pigment; (iii) a calcined kaolin clay; (iv) a titanium dioxide (TiO 2 ) pigment; (v) a synthetic latex binder, and (vi) a synthetic thickener (or a co-binder including carboxymethylcellulose or acrylic acid based or associative based thickeners.
  • the coating formulation may also comprise precipitated calcium carbonate (PCC) or ground calcium carbonate (GCC)
  • the hollow plastic pigment is in an amount of at least 2% by weight, and preferably about 3-5% by weight of the total amount of pigments.
  • Suitable hollow plastic pigments include ROPAQUE HP-1055 ® , supplied commercially by ROHMNOVA 2990 Gilchrist Road, Akron, Ohio 44305.
  • the kaolin pigment is at least about 70% by weight, and preferably 80-100% by weight of the total amount of pigment, and is preferably engineered with a fine particle size and very platy morphology.
  • the kaolin pigment has a fine particle size distribution characterized in that at least 85% of the particles are less than 2 ⁇ m (micron) and at least 50% of the particles are about less than 0.5 ⁇ m (microns) based upon particle count using a Sedigraph particle size analyzer.
  • the kaolin has a platy morphology characterized as both fine and coarse particles having a shape factor greater than 15, preferably about 20 to 27, Shape factor was calculated based on the method described by Sven Lohmander, "Aspect Ratios Of Pigment Particles. Determined By Different Methods," Nordic Pulp And Paper Research, Vol. 15, No.3/2000, pg. 221 .
  • Suitable kaolin pigments include CONTOUR 1500 ® , supplied commercially by lmerys, Rt-1, Dry branch, Georgia 31020.
  • the calcined kaolin clay is at least 5% by weight of the total amount of pigment.
  • Suitable calcined pigments include ANSILEX 93 ® , supplied by Engelhard, 101 Wood Avenue, Iselin, New Jersey 08830.
  • the TiO 2 pigment is in an amount of at least 2% by weight and preferably about 3-5% by weight of the total amount of pigment Suitable TiO 2 pigments include RPS VANTAGE ® , supplied by Dupont.
  • the synthetic latex binder is at a concentration of at least about 12 or more parts by weight of the total amount of pigment Suitable synthetic latex binders include STYRONAL 4681 ® , supplied commercially by BASF, 11501 Steele Creek Road, Charlotte, North Carolina 28273.
  • the synthetic thickener is at a concentration of at least about 0.05 parts or more by weight of the total amount of pigment (or a co-binder including carboxymethylcellulose (CMC) or acrylic acid based or associative based thickeners).
  • Suitable synthetic thickeners include STEROCOLL FD ® , supplied commercially by BASF.
  • the coating formulation may also comprise PCC or GCC. Supplied commercially by Minerals Technologies, Inc., 9 Highland Avenue, Bethlehem, Pennsylvania 18017 and Omya, 61 Main Street, Proctor, Vermont 05765.
  • the coating formulation may be prepared by mixing together the various ingredients in a one-tank make down or by pre-mixing then combining separate ingredients. The mixture is generally agitated to homogenize the ingredients. The resulting formulation may be of a viscosity ranging from about 17 Pa.s (1000 cPs) to about 1.5 Pa.s (1500 cPs) measured by a Brookfield viscometer at 100 rpm.
  • the solids content of the coating formulation when it is used, for example, in a blade coater may desirably be as high as from about 53% to about 55% by weight; however, because the plastic pigment is typically added to the formulation in the form of an aqueous dispersion having a low solids content, the solids content of the coating formulation is more usually in the range of about 49% to about 51% by weight.
  • a sample coating formulation is:
  • the coating formulation should be applied at a weight of about 0.00293 to 0.00879 kg/m 2 (2.0 to 6.0 pounds/3300 square feet) and preferably 0.00391 to 0.0083 kg/m 2 (2.5 to 5.5 pounds/3300 square feet).
  • the coating formulation is generally, but need not be, applied to both sided of the paper web.
  • the coating formulation can be applied with any conventional type blade coating as shown in U.S. Pat. Nos. 4,250,211 and 4,512,279 , and/or a fountain type coater shown in US Pat. No. 5,436,030 and/or a double bladed coater as shown in US Pat. No. 5,112,653 , the teachings of which patents are incorporated herein by reference.
  • the coating formulation can be applied using a metering size press, such as the Metso's Optisizer.
  • a metering size press such as the Metso's Optisizer.
  • blade or blade coater as used herein, unless specifically stated, is understood to include such other equivalent metering techniques.
  • the doctor blade shown in US Pat. No. 4,780,336 has been advantageously used to provide low coat weight
  • the coating formulation is applied using a blade coater, in a substantially uniform thickness over the surface of the base stock.
  • the coating process is carried out off-line or in-line.
  • the coated web Prior to calendering, the coated web has a moisture content greater than 5.5%, preferably 6.5%, most preferably 7.0%.
  • the coated paper can then be calendered, using two extended-nip calenders, preferably using a shoe nip calender (SNC), that comprises a heated roll and a soft shoe backing, as shown in U.S. Patent Nos. 6,332,953 , 6,465,074 and 6,213,009 the teachings of which patents are incorporated herein by reference.
  • SNC shoe nip calender
  • the nip is formed between a cylindrical press roll and an arcuate pressure shoe.
  • the latter has a cylindrically concave surface having a radius of curvature close to that of the cylindrical press roll.
  • a nip which can be five to ten times longer in the machine direction than one formed between press rolls, is formed. This increases the so-called dwell time of the cellulosic fibrous web in the long nip while maintaining an adequate level of pressure per square inch of pressing force.
  • the use of a shoe nip calender preserves significantly more of the original bulk than traditional supercalender or hot soft calenders.
  • the coated paper passes through the two calendering nips, with each side of paper facing a heated roll and treated with one of said calender nips; each calendering nip being formed by a calender roll having a surface temperature of at least 422 K (300° F) and a backing shoe having a width of at least 30 mm, the nip providing loading of at least 178.6 kg per cm (1000 pounds per linear inch); the calendered paper having a caliper preservation greater than 75%.
  • B1 and B1/hi-mechanical basepaper The effect of five 32 g/m 2 basepaper was examined using the following types of basepaper: B1, B1/hi-mechanical, B4 and two hot soft pre-calendered basepaper (B1/precalendering and B1/hi-mechanical/precalendering).
  • B4 basepaper is similar to B1 basepaper, except that the B4 has less addition of wet-end starch in the sheet
  • Precalendering basepaper has smoother surfaces than non-precalendered basepaper, but its caliper is reduced.
  • Table 1 shows that by increasing TMP content from 30% to 60% the total mechanical pulp content increases from 60% to 70%, while still maintaining good paper maChine runnability.
  • Table 2 shows that by increasing the amount of mechanical pulp from 60% to 70% the caliper increases from 2.85 to 3.03, while roughness and porosity are slightly increased.
  • the "control" coating is a typical No.5 lightweight coating, consisting of: 79% standard delaminated kaolin with 80% less than 2 ⁇ m (micron) and a median particle size of 0.75 ⁇ m (microns) using a Sedigraph particle size analyzer, 7 % of 93% brightness calcined kaolin, 7.5% TiO 2 ; 6.5% of a hollow plastic pigment; 8 parts starch; and 12 parts styrene butadiene (SB) latex at 50.7% coating solids.
  • SB styrene butadiene
  • Coating A consists of 86% fine platy kaolin with 90% less than 2 ⁇ m (microns) and a median particle size of 0.5 ⁇ m (microns) using a Sedigraph particle size analyzer, 5.5% of a hollow plastic pigment; 14 parts latex containing styrene butadiene with acronitrile monomer (SBAn); and 0.25 part of synthetic thickener at 53.9% solids.
  • Coating B consists of 76% a coarse platy delaminated kaolin with 60% less than 2 ⁇ m (microns) and a median particle size of 1.6 ⁇ m (microns); 10% of 93% brightness calcined kaolin; 8.5% of TiO 2 5.5% of a hollow plastic pigment; 12 parts SBAn latex; and 0.25 part of synthetic thickener at 51.1 % solids.
  • Coating C consists of 86% fine engineered kaolin with 99% less than 2 ⁇ m (microns) and a median particle size of 0.21 ⁇ m (microns); 8.5% of TiO 2 ; 5.5% of a hollow plastic pigment; 16 part of SBAn latex; and 0.25 part of synthetic thickener, at 55.6% solids.
  • the coatings as described Table 3 below, were applied on the basepapers shown in Tables 1 and 2.
  • the coat weights were targeted at 5.7 g/m 2 on the wire side of paper and 4.9 g/m 2 on the felt side of paper.
  • the wire side was coated first and followed by felt side.
  • the basepapers were coated at 10.66 m/s (2100 fpm).
  • the final coated sheet moisture content was controlled at 5.5-6.0%.
  • Table 1 Basepaper Properties B1 Std B1/hi-mechanical Furnish 40 Kraft, 30 TMP, 30 GWD 30 Kraft, 60 TMP, 10 GWD Other Furnish 18 Coated Broke, 5 Return Broke 5 Coated Broke, 5 Return Broke Rawstock Ash (%) 5.7 3.1 Porosity(s) 21 23.7 Smoothness (SU) Top/Wire 235/292 245/299 Formation 29.9 31.3 Opacity (%) 75.8 75.2 Table 2 - Basestock Comparisons Basestock Caliper ( ⁇ m) (mils) Gurley Porosity(s) Mean/S.D.
  • the above-coated papers were calendered at 15.24 m/s (3000 fpm) using the Optidwell shoe-nip calender, manufactured by Metso Paper Inc.
  • the calendering process was done one-nip-per-side with the wire side calendered first and followed by felt side.
  • the thermal roll temperature for the first nip was 443.8 K (350°F) and 70 mm nip width the 2nd nip was 477.6 K (400°F) and 70 mm nip width.
  • the loading for the 1st and the 2nd nips was 410.7 kg per cm (2300 pli).
  • the papers coated with the "control” coating were also calendered using a conventional supercalender at 5.08 m/s (1000 fpm).
  • the supercalendering roll temperature was at 360,9 K (190° F) and nip loading was adjusted so that a 45% sheet gloss can be obtained with the B1 basepaper sample.
  • the same supercalendering conditions were also used with the B4 basepaper that was coated with the "control" coating.
  • Samples made with the B1 and B4 basepaper coated with the "control” coating and calendered in a supercalender showed 45.72-46.48 ⁇ m (1.80-1.83mils) caliper, in line with that of commercial products made with the same basepaper and coated with the "control” coating.
  • the same samples calendered in a shoe nip calender showed significantly higher caliper (55.37-55.88 ⁇ m) (2.18-2.20 mils), which is approximately a 22% improvement.
  • the 13.61 kg (30-pounds) SNC coated samples prepared with the B1/hi-mechanical basepapers have the highest caliper, equal to or marginally better than that of a typical 18.14 kg (40 pounds) LWC product.
  • the 13.61 kg (30-pounds) SNC coated samples prepared with the precalendered papers have lower caliper than their uncalendered counterparts, but are still in a range of typical 16.33-17.24 kg (36-38 pounds) LWC products.
  • the 13.61 kg (30-pounds) SNC coated samples prepared with the B1 basepaper have caliper close to a typical 18.14 kg (40 pounds) LWC sheet.
  • the 13.61 kg (30-pounds) SNC coated samples prepared with the B4 basepaper have slightly lower caliper than those prepared with the B1 basepaper, but are comparable to a typical 17.24 kg (38 pounds) LWC sheet.
  • samples that were coated with coating B consisting of a coarse platy kaolin and a calcined kaolin, have improved caliper.
  • the 13.61 kg (30-pounds) SNC papers regardless of whether they are made with precalendered basepaper or not, have significantly improved caliper, that is, caliper is 17-27% higher than that of a supercalendered counterparts (13.61 kg) (30 pounds).
  • the main contributor of the significantly better caliper is the superior bulk preservation of the shoe calender.
  • increasing initial bulk of the paper along with the use of the shoe calender can produce the highest final caliper.
  • Figure 1 shows that the samples that were calendered using a shoe-nip calender and that were coated with the "control" coating exhibited about 22% higher caliper than their supercalendered counterparts.
  • the effect of coating formulation on bulk was relatively small with only the samples that were coated with coating B producing a marginally higher bulk.
  • basepaper on bulk was largely expected, that is, pre calendered basepaper produced a lower caliper and a higher mechanical pulp containing basepaper produced a higher bulk.
  • B1/hi-mechanical basepaper gave the highest bulk, arid followed by B1 basepaper, B4 basepaper, B1/hi-mechanical/precalendering basepaper, and then B1/precalendering basepaper,
  • Figure 2 shows that the shoe-calendered papers coated with the "control” coating exhibited about 1.1-3.1 points higher brightness than their supercalendered counterparts. Substituting the "control" coating with coating A produced 0.2-0.6 points higher brightness. Samples that were coated with coating B produced comparable brightness. Samples that were coated with coating C produced 0.3-0.5 points lower brightness. Increasing the mechanical pulp in the basepaper reduced brightness. Precalendering basepapers gave comparable or slightly better brightness than their non-precalendering counterparts. Overall, superior brightness was obtained with the samples that use B1, B1/precalendering, or B1/hi-mechanical/precalendering basepapers and that were coated with either coating A or coating B.
  • opacity is also highly dependent on the type of basepaper.
  • the uncalendered basepapers (B1 and B4) specifically those with higher mechanical pulp content, produce a higher opacity.
  • Samples coated with either coating A or coating B (both consisting of platy kaolin) have similar opacity and both give higher opacity than the samples that were coated with coating C or sample that were coated with the "control" coating.
  • the opacity of the SNC samples is significantly better than the commercial samples (13.61 kg) (30 pounds) and the industry samples (14.51-18.14 kg) (32-40 pounds).
  • Figure 3 shows that the shoe-calendered papers that were coated With the "control” coating exhibited about 2.0-2.5 points higher opacity than their supercalendered counterparts.
  • Substituting the "control" coating with either coating A or coating B on basepapers (Including B1, B1/precalendering, B1/hi-mechanical, and B1/hi-mechanical/precalendering basepapers), produced about 1 point higher opacity than samples that were coated with coating C, which produced about 1 point lower opacity.
  • Precalendering bases produced 0.1-0.8 points lower opacity than their non-precalendering counterparts.
  • Samples coated with the "control" coating that were finished in a SNC have a significantly lower gloss than those that were finished in a supercalender. In fact, the SNC samples only have 31-33% gloss, significantly lower than 13.61 kg (30 pounds) commercial samples. Further, the gloss performance of the starch-containing "control" coating is poorer than the non-starch-containing coatings A, B, and C. The only samples that were able to reach 40% gloss were those that were coated with either coating A or coating C. In general, the smoother surfaces and lower porosity of B4 and precalendered basepapers gave improved sheet gloss. Samples that were prepared with B4 basepaper and coated with coating C had the highest gloss (50%).
  • Figure 4 shows that the shoe-calendered papers coated with the "control” coating exhibited about 15-20 points lower paper gloss than their supercalendered counterparts. Substituting the "control" coating with coating A produced about 9-12 point higher paper gloss; substituting with coating B, produced about 2-5 points higher paper gloss; and substituting with coating C, produced about 12-17 points higher paper gloss. Precalendering produced 2-5 points higher sheet gloss. Overall, papers coated with coating C have higher gloss than those coated with coating A, and papers coated with coating B have the lowest paper gloss.
  • Samples that were coated with the "control" coating, and that were finished in a SNC have poorer Parker Print Surf (PPS), or rougher surfaces, than those that were finished in a supercalender.
  • PPS Parker Print Surf
  • the PPS performance is not only depending on calendering method, but also on types of basepaper and coating. For example, a rougher basepaper like the B1 basepaper, gives poorer PPS than a smoother basepaper like the B4 paperpaer. For the same reason, precalendering which improved the smoothness of the basepaper also improves the PPS compared to uncalendered basepapers.
  • the coatings A and B consisting of platy kaolin, give better PPS than coating C consisting of fine-engineered kaolin.
  • SNC samples give poorer PPS than commercial samples (13.61 kg) (30 pounds) as well as average industry samples (14.51-18.14 kg) (32-40 pounds).
  • Figure 5 shows that the shoe-calendered papers coated with the "control” coating exhibited about 0.1-0.9 points higher PPS than their supercalendered counter-parts.
  • Substituting the "control" coating with coating A reduced PPS by about 0.1-0.6 points.
  • Substituting with coating B reduced PPS by about 0.1-0.4 points.
  • Substituting the "control” coating with coating C gave 0.2-0.3 points higher PPS. Precalendering reduced PPS by 0.1-0.5 points.
  • All basepapers coated with either coating A or coating B gave commercially acceptable PPS, that is, 1.6-1.9 ⁇ m (microns).
  • the print gloss is measured on a four-color black area using a RIT web offset press print signature.
  • SNC samples In general exhibit comparable or better print gloss than 13.61 kg (30 pounds) commercial sheets. Among all SNC samples, the samples that were prepared with the B4 basepaper and were coated with coating A exhibited the highest print gloss.
  • the shoe-calendered papers coated with the "control” coating exhibited about 7 points lower print gloss than their supercalendered counterparts. Substituting the "control" coating with coating A gave 10-12 points higher print gloss; 4-8 points higher with coating B; and 4-10 points higher with the coating C. Precalendering produced 1-5 points higher print gloss. Overall, the shoe-calendered papers that are coated with either coating A, B, or C gave at least comparable print gloss to commercial sheets.

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Claims (10)

  1. Verfahren zum Herstellen eines LWC-Papiers mit hohem spezifischen Volumen, umfassend die Schritte:
    (a) Erzeugen eines Faserstoffs, umfassend mechanische Pulpe und chemische Pulpe;
    (b) Bilden einer Papierbahn aus dem Faserstoff;
    (c) Entfernen von Wasser von der Bahn;
    (d) Aufbringen einer Beschichtung mit einem Gewicht von mindestens 0,00293 kg/m2 (2,0 Pfund pro 3300 Quadratfuß) pro Seite auf jede Oberfläche der Bahn, um eine beschichtete Bahn mit einem Feuchtigkeitsgehalt von mehr als 5,5 % und einer Dicke von mehr als 66,04 µm (2,6 mils) zu bilden;
    (e) Laufenlassen der beschichteten Bahn durch zwei Breitspalt-Kalander, wobei jede Seite des Papiers einer erwärmten Walze gegenüber liegt und mit einer der Kalanderspalten behandelt wird, und
    wobei jede Kalandrier-Spalte gebildet ist durch eine Kalanderwalze mit einer Oberflächentemperatur von mindestens 422K (300°F) und einem Stützschuh mit einer Breite von mindestens 30 mm, wobei die Spalte eine Beladung von mindestens 178,6 kg/cm (1000 Pfund pro linearem Inch) bereitstellt, und wodurch das kalandrierte Papier eine Dickenerhaltung von mehr als 75% aufweist.
  2. Verfahren nach Anspruch 1, wobei die Beschichtung ein flaches Kaolin als ein Pigment umfasst.
  3. Verfahren nach Anspruch 2, wobei das Kaolinpigment eine Größenverteilung der feinen Teilchen besitzt, die dadurch gekennzeichnet ist, dass mindestens 85% der Teilchen kleiner sind als 2 µm (Mikron) und mindestens 50% der Teilchen kleiner sind als 0,5 µm (Mikron), basierend auf einer Teilchenzählung unter Verwenden eines Sedigraph-Teilchengrößenanalysators.
  4. Verfahren nach Anspruch 2, wobei das Kaolinpigment eine flache Morphologie besitzt, dadurch gekennzeichnet, dass sowohl feine als auch grobe Teilchen einen Formfaktor von größer als 15 besitzen.
  5. Verfahren nach Anspruch 2, wobei das Kaolinpigment eine flache Morphologie besitzt, gekennzeichnet dadurch, dass sowohl feine als auch grobe Teilchen einen Formfaktor von ungefähr 20 bis 27 besitzen.
  6. Verfahren nach Anspruch 1, wobei die Beschichtung umfasst ein hohles Plastikpigment; ein Kaolinpigment; einen kalzinierten Kaolinton; ein Titandioxidpigment; ein synthetisches Latexbindemittel; und ein synthetisches Verdickungsmittel, oder ein Co-Bindemittel, einschließlich aus auf Carboxymethylcellulose oder Acrylsäure basierenden oder assoziativ basierenden Verdickungsmitteln.
  7. Verfahren nach Anspruch 1, wobei der Kalander ein Schuhspalt-Kalander ist, wobei die Schuhspalten-Breite im Bereich von ungefähr 40 mm bis ungefähr 80 mm liegt, und die Kalandrier-Temperatur mindestens 422K (300°F) beträgt und die Spaltenbeladung bei 303,6- 428,6 kg pro cm (1700-2400 pli) liegt.
  8. Verfahren zum Herstellen eines Offset-LWC-Papiers mit extra hohem spezifischen Volumen, umfassend
    (a) Erzeugen eines Faserstoffs, umfassend mindestens 40% mechanische Pulpe;
    (b) Bilden einer Papierbahn aus dem Faserstoff;
    (c) Entfernen von Wasser aus der Bahn;
    (d) Aufbringen einer Beschichtung unter Verwenden einer Rakelstreichmaschine an einem Beschichter bei Beschichtungsgewichten von mindestens 0,00293 kg/m2 (2,0 Pfund pro 3300 Quadratfuß) pro Seite auf jede Oberfläche der Bahn, um eine beschichtete Bahn mit einem Feuchtigkeitsgehalt von mindestens 5,5% zu bilden; und
    (e) Laufenlassen der beschichteten Bahn durch zwei Breitspalt-Kalander, wobei jede Seite des Papiers einer erwärmten Rolle gegenüberliegt und mit einer der Kalander-Spalten behandelt wird; wobei jede Kalandrier-Spalte durch eine Kalanderwalze gebildet wird mit einer Oberflächentemperatur von mindestens 422K (300°F) und einem Stützschuh-Spalt mit einer Breite von mindestens 30 mm, wobei der Spalt eine Beladung von mindestens 178,6 kg pro cm (1000 Pfund pro linearem Inch (pli)) bereitstellt und wodurch das kalandrierte Papier eine Dickenerhaltung von mehr als 75% aufweist,
    wobei die Beschichtung umfasst:
    (i) ein hohles Plastikpigment, in einer Menge von mindestens ungefähr 2 Gewichtsprozent der Gesamtmenge des Pigments;
    (ii) Kaolinpigment in einer Menge von mindestens ungefähr 70 Gewichtsprozent der gesamten Menge des Pigmentes, wobei das Kaolinpigment eine Größenverteilung der feinen Teilchen besitzt, gekennzeichnet dadurch, dass mindestens 85% der Teilchen kleiner sind als 2 µm (Mikron) und mindestens 50% der Teilchen kleiner sind als 0,5 µm (Mikron), und eine flache Morphologie besitzt, gekennzeichnet dadurch, dass sowohl feine als auch grobe Teilchen einen Formfaktor von mehr als 15, bevorzugt 20 bis 27 besitzen;
    (iii) Titandioxid in einer Menge von mindestens ungefähr 2 Gewichtsprozent der gesamten Menge des Pigments;
    (iv) kalziniertes Kaolin in einer Menge von mindestens 5 Gewichtsprozent der gesamten Menge des Pigments;
    (v) synthetisches Latex in einer Konzentration von mindestens ungefähr 12 oder mehr Gewichtsteilen der gesamten Menge des Pigments;
    (vi) ein synthetisches Verdickungsmittel in einer Konzentration von mindestens ungefähr 0,05 oder mehr Gewichtsteilen der gesamten Menge des Pigments, und wobei das fertige beschichtete Papier ein Basisgewicht von 0,0415 bis 0,05615 kg/m2 (28 bis 38 Pfund pro 33 Quadratfuß) besitzt, einen 75°-TAPPI-Glanz von 35% oder darüber zeigt, eine Dicke von mindestens 54,61 µm (2,15 mils) besitzt, eine 17-27% höhere Dicke ergibt, eine Verbesserung bis zu 22% spezifischem Volumen relativ zu einem superkalandrierten 0,0444 kg/m2 (30 Pfund/3300 Quadratfuß) LWC besitzt, und einen/eine verbesserten Weißgehalt, Opazität und Druckglanz besitzt.
  9. Beschichtetes Papierblatt umfassend:
    ein Basispapier, gebildet aus einem Faserstoff, wobei der Faserstoff eine Mischung von mechanischer Pulpe und chemischer Pulpe umfasst; und
    einer Beschichtung mit einem Gewicht von mindestens 0,00293 kg/m2 (2,0 Pfund pro 3300 Quadratfuß) pro Seite auf jeder Oberfläche des Basispapiers,
    wobei die Beschichtung umfasst
    eines oder mehrere Pigmente oder Töne oder einen oder mehrere Bindemittel, wobei mindestens eines der Pigmente ein flaches Kaolinpigment mit einer Größenverteilung der feinen Teilchen besitzt, die dadurch gekennzeichnet ist, dass mindestens 85% der Teilchen kleiner sind als 2 µm (Mikron) und mindestens 50% der Teilchen kleiner sind als 0,5 µm (Mikron), basierend auf einer Teilchenzählung unter Verwenden eines Sedigraph-Teilchengrößenanalysators, und mit einer flachen Morphologie, gekennzeichnet dadurch, dass sowohl die feinen als auch die groben Teilchen einen Formfaktor von größer als 15 besitzen.
  10. Beschichtetes Papierblatt nach Anspruch 9, wobei die Beschichtung umfasst:
    (i) ein hohles Plastikpigment, in einer Menge von mindestens ungefähr 2 Gewichtsprozent der Gesamtmenge des Pigments;
    (ii) Kaolinpigment in einer Menge von mindestens ungefähr 70 Gewichtsprozent der gesamten Menge des Pigmentes, wobei das Kaolinpigment eine Größenverteilung der feinen Teichen besitzt, gekennzeichnet dadurch, dass mindestens 85% der Teilchen kleiner sind als 2 µm (Mikron) und das mindestens 50% der Teilchen kleiner sind als 0,5 µm (Mikron) und eine flache Morphologie besitzt, gekennzeichnet dadurch, dass sowohl feine als auch grobe Teilchen einen Formfaktor von größer als 15, bevorzugt 20 bis 27 besitzen;
    (iii)Titandioxid in einer Menge von mindestens ungefähr 2 Gewichtsprozent der Gesamtmenge des Pigments;
    (iv) kalziniertes Kaolin in einer Menge von mindestens 5 Gewichtsprozent der Gesamtmenge des Pigments;
    (v) synthetisches Latex in einer Konzentration von mindestens ungefähr 12 oder mehr Gewichtsteilen der Gesamtmenge des Pigments;
    (vi) ein synthetisches Verdickungsmittel in einer Konzentration von mindestensungefähr 0,05 oder mehr Gewichtsteilen der Gesamtmenge des Pigmentes;
    und wobei das fertige beschichtete Papier ein Basisgewicht von 0,0415 bis 0,05615 kg/m2 (28 bis 38 Pfund pro 3300 Quadratfuß) besitzt, einen 75° TAPPI-Glanz von 35% oder mehr, eine Dicke von mindestens 54,61 µm (2,15 mils) besitzt, eine um 17 bis 27% höhere Dicke ergibt, bis zu 22% Verbesserung des spezifischen Volumens relativ zu einem superkalandrierten 0,0444 kg/m2 (30 Pfund/3300 Quadratfuß) LWC besitzt, und einen/eine verbesserten Weißglanz, Opazität und Druckglanz besitzt.
EP03811840A 2002-11-26 2003-11-25 Verfahren zur herstellung von superdickgriffigen lwc-papieren Expired - Lifetime EP1565614B1 (de)

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ATE366338T1 (de) 2007-07-15
WO2004048692A3 (en) 2004-07-29
US20040099391A1 (en) 2004-05-27
CN1723317A (zh) 2006-01-18
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EP1565614A2 (de) 2005-08-24
JP2006507420A (ja) 2006-03-02
DE60314771D1 (de) 2007-08-16
CA2503966A1 (en) 2004-06-10
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