EP1511812A1 - Concentres pigmentaires - Google Patents
Concentres pigmentairesInfo
- Publication number
- EP1511812A1 EP1511812A1 EP03755099A EP03755099A EP1511812A1 EP 1511812 A1 EP1511812 A1 EP 1511812A1 EP 03755099 A EP03755099 A EP 03755099A EP 03755099 A EP03755099 A EP 03755099A EP 1511812 A1 EP1511812 A1 EP 1511812A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- derived
- units
- pigment
- methylstyrene
- pigment concentrates
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0041—Optical brightening agents, organic pigments
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
- C08K3/013—Fillers, pigments or reinforcing additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/006—Preparation of organic pigments
- C09B67/0063—Preparation of organic pigments of organic pigments with only macromolecular substances
Definitions
- the filter pressure that builds up when the pigment-containing melt is filtered and colohmetric measurement data can be used as a measure of the quality of the dispersion.
- DE 42 36 337 A1 describes the use of polymers of acrylic acid -C 2 -C 22 alkyl esters as dispersing agents for solids in organic media.
- DE 195 16 387 A1 claims dispersants for pigment concentrates consisting of a largely amorphous poly- ⁇ -olefin, a polyolefin wax, a crystalline polyolefin and a polyacrylic ester.
- pigment concentrates which contain copolymers consisting of a), b) and c).
- the ⁇ -olefins are preferably in the chain length range Ci 8 - to C ⁇ o-
- the pigment concentrates particularly preferably contain 5 to 40% by weight of copolymer, 20 to 50% by weight of pigment and 10 to 50% by weight of polyolefin.
- Suitable ⁇ -olefins are those with a chain length of 12 to 60, preferably 18 to 60, particularly preferably 26 to 60 carbon atoms. Both chain-pure olefins and olefin mixtures can be used, e.g. incurred in the known manufacturing processes as distillation cuts or distillation residues.
- Technical ⁇ -olefin mixtures especially those with a longer chain length, can contain, in addition to 1-alkenes, more or less high amounts of internal and lateral olefinic double bonds (vinylene and vinylidene groups), and also proportions of saturated non-olefinic hydrocarbons.
- the copolymers are prepared in a manner known per se by copolymerizing the monomers in the presence of free radical initiators. Corresponding procedures are described, for example, in DE 41 39 601 A1. All pigments that are used for coloring plastics are suitable for the production of the pigment concentrate. Examples can be found in relevant standard works such as Herbst, Hunger, Industrielle organic Pigments, 2nd ed. 1995, pages 4-11. Both inorganic and organic pigments can be used. Carbon black, titanium dioxide, zinc oxide and iron oxides may be mentioned as examples of inorganic pigments. Examples of organic pigments are azo, quinacridone and phthalocyanine pigments.
- the pigment concentrate it has proven useful to first premix the solid individual components in suitable mixing units.
- Copolyamate and optionally waxes can be used in coarse to fine-particle or micronized form, for example with average particle sizes (d50 values)> 4 ⁇ m.
- the actual pigment dispersion is then carried out by melting and kneading the premix in a kneader or extruder. Examples
- Acid and saponification numbers or dropping points were determined in accordance with DIN standards 53402, 53401 and 51801.
- the melt viscosities were measured using a rotary viscometer in accordance with the M-Ill 8 standard of the German Society for Fat Science.
- the copolymers listed in Table 1 were ground ( ⁇ 2 mm) and in a Henschel mixer with the pigment and with polypropylene plastic mixed (room temperature, 600 rpm, 10 min). The mixture was then processed into granules in a twin-screw extruder (Berstorff ZE 25x40 D).
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
Abstract
L'invention concerne des concentrés pigmentaires pour la coloration de plastiques thermoplastiques. Ces concentrés pigmentaires sont caractérisés en ce qu'ils contiennent des copolymères constitués a) d'unités dérivées d' alpha -oléfines de la longueur de chaîne C12-C6o et éventuellement b) d'unités dérivées d'un acide carboxylique de formule CH2=CR<1>-COOH et/ou c) d'unités dérivées d'un ester d'acide carboxylique de formule CH2=CR<1>-COOR<2> et/ou d) d'unités dérivées de styrène, 3-méthylstyrène, 4-méthylstyrène ou alpha -méthylstyrène, R<1> représentant un atome d'hydrogène ou un groupe méthyle et R<2> représentant un reste alkyle linéaire ou ramifié ayant 1 à 6 atomes de carbone.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10223402 | 2002-05-25 | ||
DE10223402A DE10223402A1 (de) | 2002-05-25 | 2002-05-25 | Pigmentkonzentrate |
PCT/EP2003/004967 WO2003099938A1 (fr) | 2002-05-25 | 2003-05-13 | Concentres pigmentaires |
Publications (1)
Publication Number | Publication Date |
---|---|
EP1511812A1 true EP1511812A1 (fr) | 2005-03-09 |
Family
ID=29557310
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP03755099A Withdrawn EP1511812A1 (fr) | 2002-05-25 | 2003-05-13 | Concentres pigmentaires |
Country Status (5)
Country | Link |
---|---|
US (1) | US20060074176A1 (fr) |
EP (1) | EP1511812A1 (fr) |
JP (1) | JP2005534727A (fr) |
DE (1) | DE10223402A1 (fr) |
WO (1) | WO2003099938A1 (fr) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2008130894A1 (fr) * | 2007-04-16 | 2008-10-30 | Designer Molecules, Inc. | Préparations à base de maléimide et d'acrylate durcissables à basse température et procédés d'utilisation correspondant |
DE102009034914A1 (de) | 2009-07-28 | 2011-02-03 | Clariant International Limited | Pigmentkonzentrate |
JP6108782B2 (ja) * | 2012-11-19 | 2017-04-05 | アイ‐コンポロジー株式会社 | 添加剤マスターバッチ |
US9637652B2 (en) * | 2013-03-15 | 2017-05-02 | Xerox Corporation | Systems and methods for manufacturing pigmented radiation curable inks for ink-based digital printing |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4230501A (en) * | 1978-07-31 | 1980-10-28 | Cities Service Company | Pigments dispersible in plastics |
DE4139601C2 (de) * | 1991-11-30 | 1994-09-08 | Hoechst Ag | Copolymerisate und ihre Verwendung als Gleit- und Trennmittel für die Verarbeitung thermoplastischer Kunststoffe |
DE4341395A1 (de) * | 1993-12-04 | 1995-06-08 | Hoechst Ag | Vinylchloridpolymer-Formmasse |
DE19516387A1 (de) * | 1995-05-04 | 1996-11-07 | Huels Chemische Werke Ag | Dispergiermittel für Pigmentkonzentrate |
-
2002
- 2002-05-25 DE DE10223402A patent/DE10223402A1/de not_active Withdrawn
-
2003
- 2003-05-13 EP EP03755099A patent/EP1511812A1/fr not_active Withdrawn
- 2003-05-13 WO PCT/EP2003/004967 patent/WO2003099938A1/fr active Application Filing
- 2003-05-13 US US10/515,401 patent/US20060074176A1/en not_active Abandoned
- 2003-05-13 JP JP2004508184A patent/JP2005534727A/ja active Pending
Non-Patent Citations (1)
Title |
---|
See references of WO03099938A1 * |
Also Published As
Publication number | Publication date |
---|---|
WO2003099938A1 (fr) | 2003-12-04 |
JP2005534727A (ja) | 2005-11-17 |
US20060074176A1 (en) | 2006-04-06 |
DE10223402A1 (de) | 2003-12-18 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
17P | Request for examination filed |
Effective date: 20041227 |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LI LU MC NL PT RO SE SI SK TR |
|
RBV | Designated contracting states (corrected) |
Designated state(s): DE ES FR GB IT NL |
|
RAP1 | Party data changed (applicant data changed or rights of an application transferred) |
Owner name: CLARIANT PRODUKTE (DEUTSCHLAND) GMBH |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION HAS BEEN WITHDRAWN |
|
18W | Application withdrawn |
Effective date: 20090821 |