EP1471997A1 - Verfahren zum speichern, zur aufnahme und abgabe von gasen unter verwendung neuartiger gerüstmaterialien - Google Patents
Verfahren zum speichern, zur aufnahme und abgabe von gasen unter verwendung neuartiger gerüstmaterialienInfo
- Publication number
- EP1471997A1 EP1471997A1 EP02806650A EP02806650A EP1471997A1 EP 1471997 A1 EP1471997 A1 EP 1471997A1 EP 02806650 A EP02806650 A EP 02806650A EP 02806650 A EP02806650 A EP 02806650A EP 1471997 A1 EP1471997 A1 EP 1471997A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- storing
- dispensing
- receiving
- gas
- hydrogen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
- H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
- H01M8/065—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants by dissolution of metals or alloys; by dehydriding metallic substances
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
- B01J20/26—Synthetic macromolecular compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
- B01J20/223—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material containing metals, e.g. organo-metallic compounds, coordination complexes
- B01J20/226—Coordination polymers, e.g. metal-organic frameworks [MOF], zeolitic imidazolate frameworks [ZIF]
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/0005—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes
- C01B3/001—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes characterised by the uptaking medium; Treatment thereof
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C11/00—Use of gas-solvents or gas-sorbents in vessels
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C11/00—Use of gas-solvents or gas-sorbents in vessels
- F17C11/005—Use of gas-solvents or gas-sorbents in vessels for hydrogen
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C11/00—Use of gas-solvents or gas-sorbents in vessels
- F17C11/007—Use of gas-solvents or gas-sorbents in vessels for hydrocarbon gases, such as methane or natural gas, propane, butane or mixtures thereof [LPG]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/40—Capture or disposal of greenhouse gases of CO2
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/32—Hydrogen storage
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S502/00—Catalyst, solid sorbent, or support therefor: product or process of making
- Y10S502/526—Sorbent for fluid storage, other than an alloy for hydrogen storage
Definitions
- the present invention relates to the technical field of storage of gases including methane and hydrogen, and more particularly to the technology of fuel cells.
- the invention relates in particular to a process in which an organometallic framework comprising pores and at least one metal ion and at least one bidentate organic compound, which is preferably bound as a coordination compound to said metal ion, for receiving, storing or dispensing, or for receiving and for storing, or for receiving and dispensing, or for storing and dispensing, or for receiving, for storing and dispensing at least one gas.
- the present invention relates to a device comprising the material described above.
- Fuel cell technology is one of the core technologies of the 21st century, for example, in stationary applications such as power plants, as well as in mobile applications such as cars, buses, trucks, and portable devices such as mobile phones, laptops, etc. and so-called "auxiliary power units” (APU), such as those used for power supply in power plants.
- APU auxiliary power units
- the reason for this is the increased efficiency of fuel cells compared to normal internal combustion engines.
- fuel cells produce significantly less pollutant emissions.
- organometallic complexes for storing gaseous C t to C 4 carbohydrates is disclosed in EP-A 0 727 608.
- the complexes disclosed there are difficult to synthesize.
- the storage capacity of the materials described is low, if not too low, for industrial applications.
- the present invention relates to a method of recording, storing or dispensing, or receiving and storing, or receiving and dispensing, or storing and dispensing, or picking , is provided for storing and dispensing at least one gas, characterized in that the gas is taken or stored or dispensed, or recorded and stored, or recorded and dispensed, or stored and dispensed or picked up, stored and dispensed using a medium containing an organometallic framework material comprising pores and at least one metal ion, and at least one at least bidentate organic compound bonded to said metal ion, preferably via a coordination compound.
- the present invention further relates to a device for receiving, storing or dispensing, or for receiving and storing, or for receiving and dispensing, or for storing and dispensing, or for receiving, for storing and dispensing of at least one gas; preferably, this is a fuel cell comprising an organometallic framework material as defined herein.
- the present invention relates to the use of a medium comprising an organometallic framework material which contains pores and at least one metal ion and furthermore at least one at least bidentate organic compound, this organic compound being bound to the said metal ion, preferably via a coordination compound.
- the medium is used for recording or storing or recording, storing or dispensing, or recording and storing, or recording and dispensing, or storing and dispensing, or recording, storing and dispensing at least one gas, in stationary applications, in mobile applications and in mobile applications with portable devices, preferably in power plants, cars, trucks, buses, mobile phones and laptops.
- the invention further relates to the use of the apparatus as described herein for powering power plants, and for powering cars, trucks, buses, cell phones and laptops.
- the organometallic framework material containing pores consists of at least at least one metal ion and at least one bidentate organic compound, said bidentate organic compound being attached to the said metal ion is attached, preferably via a coordination compound.
- Such materials are known and described per se, for example in US 5,648,508, EP-A-0 709 253, J. Sol. State Chem., 152 (2000) p. 3-20, Nature 402 (1999), p. 276 et seq., Topics in Catalysis 9 (1999), pp. 105-111, Science 291 (2001), pp. 1021- 23rd An inexpensive process for the production of these materials is described in DE 10111230.0. The relevant content of the above-described publications is hereby fully incorporated in the present application.
- the organometallic frameworks used in the present invention contain pores, especially micropores and / or mesopores, with micropores defined as pores having a diameter of 2 nm or less.
- Mesopores are defined as pores having a diameter greater than 2 nm and up to 50 nm, as defined in Pure Applied Chem. 45, p. 71 et seq., Especially p. 79 (1976).
- the presence of micro- and / or mesopores can be checked by sorption measurements, with the help of which the capacity of the organometallic frameworks can be measured in terms of nitrogen at 77 K, in accordance with DIN 66131 and DIN 66134. An I-shaped course of Isotherms indicates the presence of micropores.
- the specific surface area is preferably more than 5 m Ig, more preferably more than 20 m Ig, more preferably more than 50 m 2 / g, even more preferably more than 500 m 2 / g, wherein the specific surface area may be greater than 2000 m Ig.
- the metal ions of the elements of groups Ia, Ha, Ula, JVa to Villa and Ib to VIb of the periodic table of the elements are to be mentioned in particular.
- suitable metal ions of these elements are: Mg 2+ , Ca 2+ , Sr 2+ , Ba 2+ , Sc 3+ , Y 3+ , Ti 4+ , Zr 4+ , Hf ", V 4+ , V 3+ , V 2+ , Nb 3+ , Ta 3+ , Cr 3+ , Mo 3+ , W 3+ , Mn 3+ , Mn 2+ , Re 3+ , Re 2+ , Fe 3+ , Fe 2+ , Ru 3+ , Ru 2+ , Os 3+ , Os 2+ , Co 3+ , Co 2+ , Rh 2+ , Rh + , Ir 2+ , Ir + , Ni 2+ , Ni + , Pd 2+ , Pd + , Pt 2+ , Pt + , Cu 2+ , Cu + , Ag + , Au + , Zn 2+ , Cd 2+ , Hg 2+ , Al 3+ , V
- the at least bidentate organic compound which must be able to coordinate with the metal ion, in principle all compounds are conceivable which can be used for this purpose and which fulfill the abovementioned conditions, in particular which are at least bidentate.
- the organic compound must have at least two centers which are capable of coordinating with the metal ions, especially with the metals of the groups indicated above.
- the at least bidentate organic compounds mention should be made of the following compounds, which compounds include:
- an alkyl group substructure having 1 to 10 carbon atoms i) an aryl group substructure having 1 to 5 phenyl rings, iii) an alkyl or arylamine substructure consisting of alkyl groups having 1 to 10 carbon atoms or aryl groups having 1 to 5 phenyl rings,
- said substructures having bound thereto at least one at least bidentate functional group "X" covalently attached to the substructure said compound is attached, and wherein the group X is selected from the group consisting of
- substituted or unsubstituted, mono- or polynuclear aromatic di-, tri- or tetracarboxylic acids and also substituted or unsubstituted aromatic, at least one heteroatom-containing di-, tri- and tetracarboxylic acids which comprise one or more nuclei.
- a particularly preferred ligand is terephthalic acid, and particularly preferred metal ions are the Co 2+ and Zn 2+ ions.
- the organometallic framework material as used in connection with the present invention may also contain one or more monodentate ligands, these monodentate ligands being derived in particular from the following substances:
- Alkylamines and their corresponding Alkylammoniumsalze containing straight-chain or branched or cyclic aliphatic groups, each having 1 to 20 carbon atoms (and their corresponding ammonium salts); b. Arylamines and their corresponding Arylammoniumsalze, having 1 to 5 phenyl rings; c. Alkylphosphonium salts containing unbranched, branched or cyclic aliphatic groups each having 1 to 20 carbon atoms; d. Arylphosphonium salts with 1 to 5 phenyl rings; e.
- alkyl organic acids and their corresponding alkylic organic anions containing unbranched, branched or cyclic aliphatic groups of 1 to 20 carbon atoms; f. arylic organic acids and their corresponding arylorganic
- G aliphatic alcohols having unbranched, branched or cyclic aliphatic groups and having 1 to 20 carbon atoms
- H Aryl alcohols having 1 to 5 phenyl rings
- i inorganic anions selected from the group comprising:
- Ammonia carbon dioxide, methane, oxygen, ethylene, hexane, benzene, toluene, xylene, chlorobenzene, nitrobenzene, naphthalene, thiophene, pyridine, acetone, 1-2-dichloroethane, methylene chloride, tetrahydrofuran, ethanolamine, triethylamine and trifluoromethylsulfonic acid.
- the solvents used are of particular importance for the preparation of these materials and are therefore also listed in the table below.
- the values of the cell parameters (angles ⁇ , ⁇ and ⁇ as well as the spaces a, b and c (in Angstrom)) were determined by X-ray diffractometry and correspond to the given space group.
- framework materials of the type described here which contain Zn 2+ as the metal ion and ligands derived from terephthalic acid as a bidentate compound.
- Such framework materials are also known as MOF-5 in the literature.
- Separation of the organic frameworks, particularly MOF-5, from the mother liquor after crystallization can be accomplished by any of the methods known to those skilled in the art.
- Such processes are, for example, solid-liquid separations such as centrifuging, extraction, filtration, membrane filtration, cross-flow filtration, flocculation using flocculants (nonionic, cationic and anionic additives) or the addition of substances which shift the pH, such as salts, acids or bases; further by flotation, spray drying or spray granulation, as well as by evaporation of the mother liquor at elevated temperatures and / or in vacuo and by concentration of the solid.
- flocculants nonionic, cationic and anionic additives
- the separated framework materials in particular MOF-5, can be compacted, extruded, coextruded, pressed, spun, foamed. Furthermore, they can be granulated according to the methods known from the processing of plastics. In general, the materials are used in the form of pellets or as thin layers or as thin plates in the sense of the present invention. However, the above methods allow the production of various more advanced geometries and physical embodiments necessary for the widespread applications of said materials in the context of the present invention, especially if they are to be used in portable or mobile applications.
- gases which are to be taken up and / or stored and / or discharged are to be mentioned in particular: hydrocarbons, alcohols, hydrogen, nitrogen, noble gases, CO, C0 2 , naturally occurring gases, synthesis gases, compounds which produce these gases and / or deliver, as well as mixtures of at least two of the aforementioned substances.
- gases which are to be taken up and / or stored and / or discharged
- hydrocarbons alcohols, hydrogen, nitrogen, noble gases, CO, C0 2
- naturally occurring gases gases
- synthesis gases compounds which produce these gases and / or deliver, as well as mixtures of at least two of the aforementioned substances.
- hydrogen mixtures containing hydrogen, substances which produce and supply hydrogen and a gas mixture which contain at least one hydrogen-producing and / or hydrogen-generating substance.
- the organometallic framework material is contacted with at least one substance which increases the capacity, said substance being selected from the group consisting of: solvents, complexes, metals, metal hydrides, alloys, as well as mixtures of at least two of the aforementioned substances.
- a substance which increases the capacity said substance being selected from the group consisting of: solvents, complexes, metals, metal hydrides, alloys, as well as mixtures of at least two of the aforementioned substances.
- the present invention relates to a device for receiving, storing or dispensing, or for receiving and storing, or for receiving and dispensing, or for storing and dispensing, or for receiving, for storing and dispensing at least one gas containing at least one organometallic framework material as defined in the present invention.
- Said device may contain the following further components:
- a container which receives the organometallic framework material; an inlet for removal or discharge which allows at least one gas to enter the device or from the device; a gas-tight pick-up mechanism capable of holding the gas under pressure within the container.
- the present invention further relates to a fuel cell which accommodates the storage medium comprising the at least one organometallic framework material as described in the present invention.
- the present invention also relates to the use of the medium comprising at least one organometallic framework material as described in the present invention for receiving, storing or dispensing, or for receiving and storing, or for receiving and dispensing, or for storing and dispensing, or for receiving, storing and dispensing at least one gas in the following applications: stationary, mobile, mobile, portable applications, preferably in power plants, cars, trucks, buses, cell phones, laptops, and use the device according to the present invention for supplying energy in power plants, cars, trucks, buses, mobile phones and laptops.
- the present invention also relates to a method of using the fuel cell comprising at least one organometallic framework material for supplying power to power plants, automobiles, trucks, buses, cell phones and laptops.
- FIG. 1 shows a powder X-ray diffractogram of the MOF-5 organic framework material as prepared according to Example 1.
- the horizontal x-axis denotes the scattering angle 2 ⁇ in degrees
- the vertical y-axis represents a scattering intensity in arbitrary units.
- Figure 2 shows the sorption isotherm with respect to argon from an MOF-5 material at 87K.
- the horizontal x-axis indicates the relative pressure P / P 0 and the vertical y-axis the adsorbed volume in cm 3 / g at standard conditions ,
- Fig. 3 shows the hydrogen absorption isotherm with respect to hydrogen of MOF-5 at 30 ° C.
- the horizontal x-axis indicates the hydrogen partial pressure in mbar, while the vertical y-axis indicates the adsorbed amount in mg / g adsorbent.
- the upper points connected by a line denote the framework material according to the invention, whereas the lower polyline represents the comparison material from Example 3.
- the crystallization was carried out at 150 ° C and took 20 hours.
- the orange solvent was then decanted from the yellow crystals, and the crystals were covered once more with 20 mm of dimethylformamide, which was decanted again. This procedure was repeated three times. Thereafter, 20 mm of chloroform was applied to the solid, which was then washed and decanted twice more with the said solvent.
- the sorption isotherm was determined using argon (at 87K, Micromeritics AS AP 2010) and shows a type I isotherm typical of microporous materials.
- a specific surface area of 3020 mm 2 / g is determined, calculated according to the Langmuir isotherm.
- Example 2 The ability of the material of Example 1 to absorb hydrogen was determined by using a magnetic suspension balance from Rubotherm Rezisionsmesstechnik GmbH, Bochum, in the following manner: The sample was weighed and introduced into the apparatus. After closing of the apparatus and the evacuation of the sample to a pressure of 10 "5 mbar, by using a Membranvorpumpe and a turbo molecular pump, the sample was heated under vacuum for 16 hours at 100 ° C.
- FIG. 1 shows that at a hydrogen pressure of about 150 mbar, the sample is capable of storing about 1% by weight of hydrogen relative to the total weight of the activated sample. By further increasing the pressure, the storage capacity can be increased even further.
Abstract
Description
Claims
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US61147 | 2002-02-01 | ||
US10/061,147 US6929679B2 (en) | 2002-02-01 | 2002-02-01 | Method of storing, uptaking, releasing of gases by novel framework materials |
PCT/EP2002/007250 WO2003064030A1 (de) | 2002-02-01 | 2002-07-01 | Verfahren zum speichern, zur aufnahme und abgabe von gasen unter verwendung neuartiger gerüstmaterialien |
Publications (1)
Publication Number | Publication Date |
---|---|
EP1471997A1 true EP1471997A1 (de) | 2004-11-03 |
Family
ID=22033917
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP02806650A Ceased EP1471997A1 (de) | 2002-02-01 | 2002-07-01 | Verfahren zum speichern, zur aufnahme und abgabe von gasen unter verwendung neuartiger gerüstmaterialien |
Country Status (11)
Country | Link |
---|---|
US (1) | US6929679B2 (de) |
EP (1) | EP1471997A1 (de) |
JP (1) | JP2005525218A (de) |
KR (1) | KR100856445B1 (de) |
CN (1) | CN1617761A (de) |
CA (1) | CA2391755C (de) |
DE (1) | DE20210139U1 (de) |
IS (1) | IS7375A (de) |
MX (1) | MXPA04007326A (de) |
TW (1) | TWI304279B (de) |
WO (1) | WO2003064030A1 (de) |
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CA2446020A1 (en) * | 2001-04-30 | 2002-11-07 | The Regents Of The University Of Michigan | Isoreticular metal-organic frameworks, process for forming the same, and systematic design of pore size and functionality therein, with application for gas storage |
US6893564B2 (en) * | 2002-05-30 | 2005-05-17 | Basf Aktiengesellschaft | Shaped bodies containing metal-organic frameworks |
EP1513612A2 (de) * | 2002-06-19 | 2005-03-16 | University Of Iowa Research Foundation | Gasspeichermaterialien und vorrichtung |
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DE602004027036D1 (de) * | 2003-05-09 | 2010-06-17 | Univ Michigan | MOFs mit einer hohen Oberfläche und Methode zu deren Herstellung |
US7191602B2 (en) * | 2003-06-16 | 2007-03-20 | The Regents Of The University Of California | Storage of H2 by absorption and/or mixture within a fluid medium |
US7309380B2 (en) * | 2003-06-30 | 2007-12-18 | Basf Aktiengesellschaft | Gas storage system |
US20050004404A1 (en) | 2003-07-03 | 2005-01-06 | Basf Akiengesellschaft | Process for the alkoxylation of monools in the presence of metallo-organic framework materials |
JP2005106113A (ja) * | 2003-09-29 | 2005-04-21 | Kurita Water Ind Ltd | 水素貯蔵方法 |
DE10355087A1 (de) | 2003-11-24 | 2005-06-09 | Basf Ag | Verfahren zur elektrochemischen Herstellung eines kristallinen porösen metallorganischen Gerüstmaterials |
EP1689762A4 (de) * | 2003-12-05 | 2009-08-05 | Univ Michigan | Metallorganische polyhedra |
JP2006083898A (ja) | 2004-09-14 | 2006-03-30 | Honda Motor Co Ltd | 水素貯蔵タンク |
US7887781B2 (en) * | 2004-09-23 | 2011-02-15 | GM Global Technology Operations LLC | Methods of storing hydrogen in hydrogen storage systems |
US7582798B2 (en) | 2004-10-22 | 2009-09-01 | The Regents Of The University Of Michigan | Covalently linked organic frameworks and polyhedra |
CN101090861A (zh) * | 2004-11-05 | 2007-12-19 | 通用汽车公司 | 支架硼氮烷-氢化锂储氢材料 |
US7524444B2 (en) * | 2004-11-09 | 2009-04-28 | Basf Aktiengesellschaft | Shaped bodies containing metal-organic frameworks |
DE102005000938A1 (de) * | 2005-01-07 | 2006-07-20 | Basf Ag | Adsorptive Gewinnung von Xenon aus Krypton-Xenon Gasgemischten |
JP2006218346A (ja) * | 2005-02-08 | 2006-08-24 | Honda Motor Co Ltd | 水素吸着材及びその製造方法 |
US7343747B2 (en) * | 2005-02-23 | 2008-03-18 | Basf Aktiengesellschaft | Metal-organic framework materials for gaseous hydrocarbon storage |
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MX2007012388A (es) | 2005-04-07 | 2008-03-11 | Univ Michigan | Adsorcion elevada de gas en una estructura metal-organica microporosa con sitios de metal abiertos. |
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