EP1340823B1 - Procede de soufflage d'oxygene de convertisseur et lance de soufflage vers le haut pour soufflage d'oxygene de convertisseur - Google Patents

Procede de soufflage d'oxygene de convertisseur et lance de soufflage vers le haut pour soufflage d'oxygene de convertisseur Download PDF

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Publication number
EP1340823B1
EP1340823B1 EP01996630A EP01996630A EP1340823B1 EP 1340823 B1 EP1340823 B1 EP 1340823B1 EP 01996630 A EP01996630 A EP 01996630A EP 01996630 A EP01996630 A EP 01996630A EP 1340823 B1 EP1340823 B1 EP 1340823B1
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Prior art keywords
oxygen
nozzle
flow
rate
kpa
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German (de)
English (en)
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EP1340823A4 (fr
EP1340823A1 (fr
Inventor
Ikuhiro NKK CORPORATION SUMI
Yoshiteru NKK CORPORATION KIKUCHI
Ryo NKK CORPORATION KAWABATA
Atsushi NKK CORPORATION WATANABE
Shinichi NKK CORPORATION AKAI
Satoshi NKK CORPORATION KOHIRA
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JFE Steel Corp
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JFE Steel Corp
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    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C5/00—Manufacture of carbon-steel, e.g. plain mild steel, medium carbon steel or cast steel or stainless steel
    • C21C5/28—Manufacture of steel in the converter
    • C21C5/30—Regulating or controlling the blowing
    • C21C5/32—Blowing from above
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C5/00—Manufacture of carbon-steel, e.g. plain mild steel, medium carbon steel or cast steel or stainless steel
    • C21C5/28—Manufacture of steel in the converter
    • C21C5/42—Constructional features of converters
    • C21C5/46—Details or accessories
    • C21C5/4606—Lances or injectors

Definitions

  • the present invention relates to a method for blowing oxygen in a converter to refine a molten iron.
  • the oxygen is supplied from a divergent nozzle, known as Laval nozzle, installed on a tip of the top-blown lance into the converter as a supersonic or a subsonic jet.
  • Laval nozzle a divergent nozzle
  • a shape of the Laval nozzle is designed generally depending on the refining conditions in a high carbon region from the beginning to the middle of the blow process in which comparatively much oxygen is supplied to prevent a decline of efficiency of reactions such as the decarburization reaction.
  • oxygen-flow-rate the amount of the supplied oxygen is referred to as "oxygen-flow-rate.
  • JP-A-6-228624 discloses the blow method in which the shape of the top-blown lance is optimized, and the oxygen-flow-rate and the lance-height are controlled within a proper range adapted for the shape of the Laval nozzle.
  • the oxygen-flow-rate is reduced to restrain the oxidization of the iron and improve the oxygen efficiency for the decarburization.
  • the oxygen-flow-rate greatly deflects downward from an optimum flow value of the Laval nozzle, therefore maximum effect of the Laval nozzle cannot be obtained, and the oxygen jet is attenuated unnecessarily, resulting in the decline of the efficiency of the decarburization in the end of the blow, as indicated in increased T.Fe in the slag.
  • the oxygen-flow-rate must be controlled in extremely low order in the end of the blow in order to improve a hitting accuracy of the composition at the endpoint of the blow, an excessively low order of the rate extremely reduces dynamic pressure of the oxygen jet and causes rapid oxidization of the iron, therefore the oxygen-flow-rate has its limit in reduction.
  • the T.Fe is a total value of the iron content in all of the iron oxides including FeO and Fe 2 O 3 in the slag.
  • Japanese unexamined patent publication No.10-30110 discloses the oxygen blowing method which employs the top-blown lances having an exit diameter from 0.85D to 0.94D in the high carbon region and the exit diameter from 0.96D to 1.15D in the low carbon region respectively, to an optimum expansion exit diameter D of the Laval nozzle determined from the throat diameter of the Laval nozzle and the oxygen-flow-rate.
  • the Publication also describes that even when the same Laval nozzle is used, the exit diameter can be adjusted satisfying the above described range to the optimum expansion exit diameter D by altering the oxygen-flow-rate and a back pressure of the Laval nozzle P.
  • the present invention provides an oxygen blowing method in a converter, which uses a top-blown lance having a Laval nozzle installed at the tip of the top-blown lance.
  • the Laval nozzle has a back pressure of the nozzle Po(kPa) satisfying the following formula with respect to the oxygen-flow-rate Fhs(Nm 3 /hr) per hole of the Laval nozzle, determined from the oxygen-flow-rate Fs(Nm 3 /hr) in a high carbon region as a peak of the decarburization, and a throat diameter Dt(mm).
  • Po Fhs / 0.00465 ⁇ D ⁇ t 2
  • An exit diameter De of the Laval nozzle satisfies the following formula with respect to the back pressure of the nozzle Po(kPa), an ambient pressure Pe(kPa), and the throat diameter Dt(mm).
  • the exit diameter De of the Laval nozzle satisfies the following formula with respect to the back pressure of the nozzle Po(kPa), the ambient pressure Pe(kPa), and the throat diameter Dt(mm).
  • the exit diameter De of the Laval nozzle satisfies the following formula with respect to the back pressure of the nozzle Po(kPa), the ambient pressure Pe(kPa), and the throat diameter Dt(mm). 0.15 ⁇ D ⁇ t 2 / Pe / Po 5 / 7 ⁇ Pe / Po 2 / 7 1 / 2 ⁇ D ⁇ e 2 ⁇ 0.18 ⁇ D ⁇ t 2 / Pe / Po 5 / 7 ⁇ Pe / Po 2 / 7 1 / 2
  • the top-blown lance has multiple Laval nozzles, and at least one of those Laval nozzles is required to satisfy conditions of the following two formulas.
  • Po Fhs / 0.00465 ⁇ D ⁇ t 2 D ⁇ e 2 ⁇ 0.23 ⁇ D ⁇ t 2 / Pe / Po 5 / 7 ⁇ 1 - Pe / Po 2 / 7 1 / 2
  • Po Fhs / 0.00465 ⁇ D ⁇ t 2 D ⁇ e 2 ⁇ 0.185 ⁇ D ⁇ t 2 / Pe / Po 5 / 7 ⁇ 1 - Pe / Po 2 / 7 1 / 2
  • the oxygen blowing is carried out at the amount of the slag of less than 50kg per ton of the molten steel. More preferably, the amount is less than 30kg per ton of the molten steel.
  • the Laval nozzle has the back pressure of the nozzle Poo(kPa), satisfying the following formula with respect to the oxygen-flow-rate Fh M (Nm 3 /hr) per hole of the Laval nozzle determined from the oxygen-flow-rate F M (Nm 3 /hr) in the low carbon region in the end of the blow, and the throat diameter Dt (mm).
  • Poo F ⁇ h M / 0.00465 ⁇ D ⁇ t 2
  • the exit diameter De has a ratio (De/Deo) of 1.10 or less to the optimum exit diameter De o (mm) which is given from the back pressure Poo(kPa), the ambient pressure Pe(kPa). and the throat diameter Dt(mm) according to the following formula.
  • D ⁇ e o 2 0.259 ⁇ D ⁇ t 2 / Pe / Po 5 / 7 ⁇ 1 - Pe / Po 2 / 7 1 / 2
  • this invention provides the oxygen blowing method that blows using the top-blown lance having the Laval nozzle installed on its tip.
  • the Laval nozzle has the back pressure of the nozzle Poo(kPa) satisfying the following formula with respect to the oxygen-flow-rate Fh M (Nm 3 /hr) per hole of the Laval nozzle determined from the oxygen-flow-rate F M (Nm 3 /hr) in the low carbon region in the end of the blow, and the throat diameter Dt(mm).
  • Poo F ⁇ h M / 0.00465 ⁇ D ⁇ t 2
  • the exit diameter De of the Laval nozzle has the ratio (De/Deo) of 0.95 or less to the optimum exit diameter De o (mm) which is given from the back pressure Poo(kPa), the ambient pressure Pe(kPa), and the throat diameter Dt(mm) according to the following formula.
  • D ⁇ e o 2 0.259 ⁇ D ⁇ t 2 / Pe / Po 5 / 7 ⁇ 1 - Pe / Po 2 / 7 1 / 2
  • the top-blown lance has the multiple Laval nozzles, and at least one of those Laval nozzles is required to satisfy the conditions of the following two formulas.
  • the oxygen blowing is done at the amount of the slag of less than 50kg per ton of the molten steel. More preferably, the amount is less than 30kg per ton of the molten steel.
  • the present invention provides a top-blown lance for blowing oxygen having the Laval nozzle installed on its tip.
  • the Laval nozzle has the back pressure of the nozzle Po(kPa) satisfying the following formula with respect to the oxygen-flow-rate Fhs(Nm 3 /hr) per hole of the Laval nozzle determined from the oxygen-flow-rate Fs(Nm 3 /hr) in the high carbon region as the peak of the decarburization, and the throat diameter Dt(mm).
  • Po Fhs / 0.00465 ⁇ D ⁇ t 2
  • the exit diameter De of the Laval nozzle satisfies the following formula with respect to the back pressure of the nozzle Po(kPa), the ambient pressure Pe(kPa), and the throat diameter Dt(mm).
  • the Laval nozzle has the back pressure of the nozzle Poo(kPa) satisfying the following formula with respect to the oxygen-flow-rate Fh M (Nm 3 /hr) per hole of the Laval nozzle determined from the oxygen-flow-rate F M (Nm 3 /hr) in the low carbon region in the end of the blow, and the throat diameter Dt(mm).
  • Poo F ⁇ h M / 0.00465 ⁇ D ⁇ t 2
  • the exit diameter De of the Laval nozzle has the ratio (De/Deo) of 0.95 or less to the optimum exit diameter De o (mm) which is given from the back pressure of the nozzle Poo(kPa), the ambient pressure Pe(kPa), and the throat diameter Dt(mm) according to the following formula.
  • D ⁇ e o 2 0.259 ⁇ D ⁇ t 2 / Pe / Po 5 / 7 ⁇ 1 - Pe / Po 2 / 7 1 / 2
  • the inventors attained to the knowledge that the difficulties in prior art can be solved by using the Laval nozzle having the extremely smaller exit diameter De than the size De designed based on the conditions at the high oxygen-flow-rate in the high carbon region in the peak of the decarburization.
  • results of study will be described.
  • Behavior in converter during the oxygen blowing is divided roughly into the behavior in the high carbon region (C>0.6mass%) and the behavior in the low carbon region (C ⁇ 0.6mass%) due to difference of their reaction behavior.
  • a limiting factor of the reaction is the oxygen-flow-rate, and the blow is done at the high oxygen-flow-rate.
  • the limiting factor is changed from the oxygen-flow-rate to the carbon-migration-rate, and the oxygen is also consumed partially in the oxidization of the iron, therefore the oxygen-flow-rate is reduced to restrain the iron oxidization and improve the oxygen efficiency for the decarburization.
  • the dynamic pressure of the oxygen jet at the surface of the molten pool must be lowered, while the high oxygen-flow-rate is maintained in order to reduce the scatter of the iron and the dust.
  • the geometry and the trajectory of the oxygen jet must be kept in constant conditions as much as possible.
  • the dynamic pressure of the oxygen jet is significantly reduced, therefore the decline of the oxygen efficiency for the decarburization or increase of the oxidization of the iron is brought about if as it is.
  • the dynamic pressure of the oxygen jet at the surface of the bath is kept in the high order as much as possible
  • there is a limit in increasing the dynamic pressure of the oxygen jet by means of lowering of the lance-height because the means causes wear of the tip of the top-blown lance due to radiation from the bath surface and the metal adhesion to the lance due to the scatter of the iron from the surface to be increased significantly.
  • the measures must be practiced without alteration of the operating conditions such as the lance-height as much as possible.
  • the ambient pressure Pe is that outside of the Laval nozzle, in other words, the ambient gas pressure within the converter.
  • formula (1) and formula (5) are relational expressions formable in the Laval nozzle, and well known as the formulas used in the design of the Laval nozzle.
  • K in the formula (5) is a constant.
  • the ratio (F/Po) is controlled in the operation such that the constant K generally lies in a range from 0.24 to 0.28.
  • the oxygen jet expands substantially optimumly, and energy of the oxygen jet itself is maximum. Therefore, the energy of the oxygen jet reaching the bath surface is also maximum, leading to increase of the scatter of the iron and the dust.
  • the oxygen-flow-rate is reduced gradually as described before, however, if such conventional Laval nozzle is used, since.the nozzle is designed based on the high oxygen-flow-rate in the high carbon region, excessively low oxygen-flow-rate causes the oxygen jet to be attenuated intensively, the blow falls to be extremely unstable due to the decline of the reaction efficiency for the decarburization or the oxidization of the iron, and the hitting accuracy of the composition of the molten pool in the end of the blow declines drastically.
  • the inventors studied the behavior in the oxygen blowing in the peak of the decarburization and the end of the blow using the Laval nozzle of which exit diameter De is different from the conventional De, while throat diameter Dt is equal to the conventional Dt.
  • the exit diameter De is determined as bellow. That is, the back pressure of the nozzle Po was given from the oxygen-flow-rate Fh s in the high carbon region and the throat diameter Dt according to the formula (1), and when the exit diameter De was given from the obtained back pressure of the nozzle Po, the ambient pressure Pe, and the throat diameter Dt according to the formula (5), the constant K was varied differently from 0.15 to 0.26, then the exit diameter De was determined. As the constant K becomes smaller below 0.26, the exit diameter De becomes smaller, and the oxygen jet within the Laval nozzle expands insufficiently. It is noted that the used converters are those shown in the practical examples as described later.
  • Fig.1 shows the results of the study on relations between the dust generation rate and the amount of the metal adhesion in the peak of the decarburization, and the constant K, in the blows.
  • the constant K is about 0.23 or less, the dust generation rate is in low order together with the amount of the metal adhesion. That is, it was known that the dust generation rate and the amount of the metal adhesion are reduced together by establishing the exit diameter De in the range according to the following formula (2). If the constant K is 0.185 and below, the dust generation rate and the amount of the metal adhesion are further reduced. Most preferably, the constant K is in the range from 0.15 to 0.18.
  • the energy of the oxygen jet must be increased while the oxygen-flow-rate is suppressed, in order to reduce the T.Fe and accelerate and/or stabilize the refining reaction.
  • the Laval nozzle of which exit diameter De is established to be small compared with the theoretical value given from the oxygen-flow-rate in the high carbon region as the peak of the decarburization, or designed assuming that the constant K is lower than 0.259, is used, while the oxygen jet expands insufficiently in the peak of the decarburization as the exit diameter De is smaller, the jet necessarily approaches the optimum expansion jet flow at the low oxygen-flow-rate in the end of the blow, the energy of the oxygen jet increases without any particular means, and the reduction of the T.Fe and acceleration and/or stabilization of the refining reaction can be achieved by the effect for improvement of the refining reaction due to the increased oxygen jet energy.
  • the optimum expansion jet flow can be obtained at the oxygen-flow-rate in the end of the blow.
  • the back pressure of the nozzle Poo (kPa) is given from the oxygen-flow-rate Fh M (Nm 3 /hr) per hole of the Laval nozzle in the end of the blow process in the blow concerned and the predetermined throat diameter Dt(mm) of the Laval nozzle according to the following formula (3)
  • the optimum exit diameter De o (mm) in the end of the blow is given using the the back pressure of the nozzle Poo(kPa), the throat diameter Dt(mm), and the ambient pressure Pe kPa) according to the following formula (4)
  • the obtained optimum exit diameter De o is agreed with the exit diameter De of the Laval nozzle concerned.
  • Fig.2 is a view showing the ratio of the exit diameter of the used nozzle De to the optimum exit diameter De o calculated from the conditions in the end of the blow in the practical operation as a horizontal axis and the T.Fe at the endpoint of the blow along a vertical axis.
  • the ratio of the exit diameter of the used nozzle De to the calculated optimum exit diameter De o (De/De o ) ranges not more than 1.10 the T.Fe can be suppressed low compared with the conventional level.
  • the significant effect in the reduction of the T.Fe, or a preferable effect was obtained in the range of the De/De o from 0.90 to 1.05.
  • the effect for the attenuation of the oxygen jet in the peak of the decarburization is necessarily increased, in addition, the effect on the decarburization reaction in the end can be kept in that range, and the effect for the attenuation of the jet flow can be obtained in some degree, therefore the metal adhesion to the lance was restrained in extremely low order over the whole region in the blow, as well as the effect for the reduction of the T.Fe.
  • These effects were obtained not always by establishing the exit diameter De to be within the range according to the formula (2), and only establishing the De/De o to be not more than 0.95.
  • the oxygen blowing in the converter when the amount of the slag is small within the converter, the percentage of the molten pool that is covered by the slag decreases, and the amount of the dust and the scatter of the iron in the high carbon region increases.
  • the aforementioned oxygen blowing method can restrain the amount of the dust and the scatter of the iron.
  • the effects can be obtained in a wide control range. Therefore, the effects can be brought out more significantly by applying the above oxygen blowing method to the blow where the amount of the slag within the converter is less than 50kg, and desirably less than 30kg, per ton of the molten steel.
  • the present invention is made based on the above knowledge, and the oxygen blowing method in the converter according to the embodiment 1-1 is characterized in that; employing the top-blown lance having the Laval nozzle installed on its tip; determining the back pressure of the nozzle Po(kPa) satisfying the above formula (1) with respect to the oxygen-flow-rate Fh s (Nm 3 /hr) per hole of the Laval nozzle determined from the oxygen-flow-rate F s (Nm 3 /hr) in the high carbon region as the peak of the decarburization and the throat diameter Dt(mm) of the Laval nozzle, in the oxygen blowing method blowing at various different oxygen-flow-rate depending on a carbon concentration of the molten pool; and blowing using the top-blown lance provided with the Laval nozzle having the exit diameter De(mm) obtained from the back pressure of the nozzle Po(kPa), the ambient pressure Pe(kPa), and the throat diameter Dt(mm) according to the above formula (2)
  • the oxygen blowing method in the converter according to the embodiment 1-2 is characterized in that; the exit diameter De further lies in the range that the ratio to the optimum exit diameter De o (mm) (De/De o ) is not more than 1.10 in the embodiment 1-1; the De o being obtained from the back pressure of the nozzle Poo(kPa) satisfying the above formula (3) with respect to the oxygen-flow-rate Fh M (Nm 3 /hr) per hole of the Laval nozzle determined from the oxygen-flow-rate F M (Nm 3 /hr) in the low carbon region in the end of the blow and the throat diameter Dt(mm), the ambient pressure Pe(kPa), and the throat diameter Dt(mm) according to the above formula (4).
  • the oxygen blowing method in the converter according to the embodiment 1-3 is characterized in that; in the oxygen blowing method which employs the top-blown lance having the Laval nozzle installed on its tip and blows at various different oxygen-flow-rates depending on the carbon concentration of the molten pool, the blow is done using the top-blown lance provided with the Laval nozzle having the exit diameter De(mm), which lies in the range that the ratio to the optimum exit diameter De o (mm) (De/De o ) is not more than 0.95, the De o being obtained from the back pressure of the nozzle Poo(kPa), the ambient pressure Pe(kPa), and the throat diameter Dt(mm) according to the above formula (4); the Poo being determined such that it satisfies the above formula (3) with respect to the oxygen-flow-rate Fh M (Nm 3 /hr) per hole of the Laval nozzle determined from the oxygen-flow-rate F M ((Nm 3 /hr) in the low carbon region in the end of the blow
  • the oxygen blowing method in the converter according to the invention of the embodiment 1-4 is characterized in that; in either of the embodiment 1-1 through the embodiment 1-3, the top-blown lance has the multiple Laval nozzles, and at least one of those Laval nozzles satisfies the above conditions.
  • the oxygen blowing method in the converter according to the embodiment 1-5 is characterized in that; in either of the embodiment 1-1 through the embodiment 1-4, the amount of the slag within the converter is less than 50kg per ton of the molten steel.
  • the back pressures of the nozzle P, Po, Poo(kPa) and the ambient pressure Pe are those expressed in an absolute pressure (that is the pressure expressed regarding a vacuum state as a reference assuming the state is zero-pressure).
  • Fig.3 is the schematic sectional view of the Laval nozzle used in this invention, and as shown in Fig.3, the Laval nozzle 2 is composed of two cones comprising a portion having a reducing section and the portion having an enlarging section, the portion having a reducing section is referred to as a reduction portion 3, the portion having an enlarging section is referred to as a skirt portion 5, and the narrowest region as the region transferred from the reduction portion 3 to the skirt portion 5 is referred to as the throat 4, with a single or multiple Laval nozzle or nozzles 2 being installed in a copper Lance nozzle 1.
  • the lance nozzle 1 is connected to the lower end of the lance body (not shown) by welding and the like to form the top-blown lance (not shown).
  • the oxygen which has passed through the inside of the lance body, is passed through the reduction portion 3, the throat 4, and the skirt portion 5 in order, and supplied into the converter as the ultrasonic or subsonic jet.
  • Dt is the throat diameter
  • De is the exit diameter
  • a spreading angle ⁇ of the skirt portion 5 is generally ten or less degrees.
  • the reduction portion 3 and the skirt portion 5 are shown as the cones in the Laval nozzle 2 in Fig.3, however, the reduction portion 3 and the skirt portion 5 are not always required to be cone for the Laval nozzle, and may be formed with a type of curved surface of which bore varies curvedly, in addition, the reduction portion 3 may possibly be a straight tubular type having the equal bore to that of the throat 4.
  • This invention determines the shape of such formed Laval nozzle 2 according to the following procedures prior to the blow.
  • the oxygen-flow-rate Fh s (Nm 3 /hr) in the single Laval nozzle 2 is given from the oxygen-flow-rate F s (Nm 3 /hr) fed through the top-blown lance in the high carbon region in the peak of the decarburization.
  • the high carbon region in the peak of the decarburization is the range that the carbon concentration in the molten pool is over 0.6mass%
  • the oxygen-flow-rate F s is the rate in case the carbon region lies in this range
  • the oxygen-flow-rate is varied in the range that the carbon concentration is over 0.6mass%
  • the rate is regarded to be any one of the varied oxygen-flow-rates.
  • a typical value or weighted mean value of those oxygen-flow-rates can be regarded to be the rate Fs.
  • the back pressure of the nozzle Po(kPa) is determined from the oxygen-flow-rate Fh s (Nm 3 /hr) and the throat diameter Dt(mm) of the Laval nozzle 2 according to the aforementioned formula (1).
  • the back pressure of the nozzle Po is the oxygen pressure within the lance body, or the pressure on an inlet side of the Laval nozzle 2.
  • the throat diameter Dt(mm) is determined from the oxygen-flow-rate Fh s (Nm 3 /hr) and the back pressure of the nozzle Po(kPa).
  • the exit diameter De(mm) is given using the back pressure of the nozzle Po(kPa), the ambient pressure Pe(kPa), and the throat diameter Dt(mm) determined in this manner according to the aforementioned formula (2).
  • the minimum value of the exit diameter De is not expressed in the formula (3), since the Laval nozzle 2 cannot keep its shape when the exit diameter De is smaller than the throat diameter Dt, the exit diameter De is established to be any one of values within the range according to the formula (2) under the condition that the De is more than or equal to the throat diameter Dt.
  • the ambient pressure Pe is the atmospheric pressure generally in the oxygen blowing.
  • the exit diameter De it is preferable that following points are further considered to be determined. That is, it is preferable that the oxygen-flow-rate Fh M (Nm 3 /hr) per Laval nozzle is given from the oxygen-flow-rate F M (Nm 3 /hr) in the low carbon region in the end of the blow, the back pressure of the nozzle Poo(kPa) in the end of the blow is determined from the oxygen-flow-rate Fh M (Nm 3 /hr) and the previously determined throat diameter Dt(mm) of the Laval nozzle according to the aforementioned formula (3), then the optimum exit diameter De o (mm) in the end of the blow is given using the back pressure of the nozzle Poo(kPa), the ambient pressure Pe(kPa), and the throat diameter Dt(mm) according to the aforementioned formula (4), and the exit diameter De is determined within the range such that the ratio to the obtained optimum exit diameter De o (De/ De o ) is not more than 1.10.
  • the exit diameter De when the exit diameter De is determined within the range that the ratio (De/De o ) is not more than 0.95, in the general oxygen blowing in which the oxygen-flow-rate in the high carbon region is intentionally differed from the oxygen-flow-rate in the low carbon region, the exit diameter De satisfies the range according to the formula (2), therefore the range of the exit diameter De is not required to be positively determined. That is, when the ratio (De/ De o ) is not more than 0.95, the exit diameter De can be determined from the oxygen-flow-rate F M (Nm 3 /hr) in the low carbon region in the end of the blow.
  • the lance nozzle 1 having the Laval nozzle 2 of which shape is determined in this manner is fabricated, and then connected to the lower end of the lance body to form the top-blown lance.
  • the lance nozzle 1 has the multiple Laval nozzles 2, only a part of those Laval nozzles 2 possibly has the shape determined as above. However, in this case, the intended effects are somewhat reduced.
  • this top-blown lance is used to blow oxygen onto the molten iron, produced in a blast furnace and the like, in the converter.
  • the blow is done at the predetermined oxygen-flow-rate F s , otherwise at any high oxygen-flow-rate corresponding to the refining reaction without regard to the oxygen-flow-rate F s when the oxygen-flow-rate is altered variously.
  • the blow is done at the reduced oxygen-flow-rate in order to improve the oxygen efficiency for the decarburization, in this case, the blow is preferably done under such conditions of the oxygen-flow-rate and the back pressure of the nozzle P that the ratio (De/De o ) to the optimum exit diameter De o determined according to the formula (4) is 1.10 or less.
  • the high and low carbon regions are not strictly classified at 0.6mass% of the carbon concentration of the molten pool as a border, and the blow may be done even if the oxygen-flow-rate is reduced from the range of the carbon concentration of the molten pool over 0.6mass%, or conversely even if the high oxygen-flow-rate is kept to the range of the carbon concentration below 0.6mass%, for example about 0.4mass% of the carbon concentration.
  • the refining method according to this invention can work more by applying the method to the blow where the amount of the slag within the converter is less than 50kg, and desirably less than 30kg, per ton of the molten steel.
  • the flow jet velocity during the high oxygen-flow-rate region in the high carbon region can be reduced, the oxygen jet energy is enabled to be kept in low order, the scatter of the iron and the dust can be reduced, and the jet flow velocity of the oxygen jet in the end of the blow can be optimized, or value of the dynamic pressure of the oxygen jet in the end of the blow can be increased close to the theoretical value, and then the oxidization of the iron can be restrained. Consequently, the yield of iron can be improved as a whole of the blow, and a stabilized operation is achieved.
  • the used molten iron is that to which desulfurization and dephosphorization was applied with the pretreatment equipment for the molten iron as pre-converter process.
  • Lime-based flux was added into the converter to generate the small amount of the slag (less than 50kg per ton of the molten steel).
  • argon or nitrogen was blown in about 10Nm 3 per minute for agitating the molten pool.
  • the used top-blown lance is of a 5 holes-nozzle type with the five Laval nozzles installed therein, the throat diameter Dt of the Laval nozzle was established to be 55.0mm, and the exit diameter De was determined from the oxygen-flow-rate Fs of 60000Nm 3 /hr in the peak of the decarburization ranging from the beginning to the middle of the blow.
  • the back pressure of the nozzle Po was determined to be 853kPa (8.7kgf/cm 2 ) from the conditions that the oxygen-flow-rate Fh s was 12000Nm 3 /hr and the throat diameter Dt was 55.0mm according to the formula (1), and the exit diameter De was determined to be 61.5mm from the conditions that the back pressure of the nozzle Po was 853kPa, the ambient pressure was 101kPa (the atmospheric pressure), and the throat diameter Dt was 55.0mm according to the formula (5) assuming the constant k was 0.184. And then, the 5 holes-Laval nozzles were all formed like this.
  • the optimum back pressure of the nozzle Po that is, the back pressure of the nozzle Po which brings the ideal expansion, was given from the conditions that the throat diameter Dt was 55.0mm, the exit diameter De was 61.5mm, and the ambient pressure was 101kPa according to the formula (5) assuming the constant k was 0.259.
  • the optimum back pressure of the nozzle Po was 428kPa (4.4kgf/cm 2 ).
  • the oxygen was fed from the top-blown lance inserted within the converter under the conditions that the oxygen-flow-rate F s was 60000Nm 3 /hr and the back pressure of the nozzle Po was 853kPa in the range from the beginning to the middle of the blow process as the peak of the decarburization, and the blow was done under the back pressure of the nozzle P of 428kPa in the end of the blow where the carbon concentration of the molten pool was 0.6mass% or less.
  • the ratio of the exit diameter De to the optimum exit diameter De o (De/ De o ) is 1.0 in the end of the blow.
  • the oxygen-flow-rate F M in the end of the blow was about 30000Nm 3 /hr under the back pressure of the nozzle P of 428kPa.
  • the amount of the dust in the offgas was measured using the dry type dust-measuring device during the blow. Moreover, the slag within the converter was sampled when the blow was completed, and the T.Fe in the slag was examined. From the results of the blows over 100 heats, the amount of the dust was 8kg per ton of the molten steel in the blow using the lance, and the T.Fe in the slag was 13mass% when the blow was stopped at the carbon content of 0.05mass%.
  • the molten iron, to which the pretreatment for the molten iron had been applied was blown with the 5 holes-nozzles type top-blown lance under the same conditions as those in the practical example 1.
  • the exit diameter De was altered.
  • the back pressure of the nozzle Po was determined to be 853kPa (8.7kgf/cm 2 ) according to the formula (1) from the conditions that the oxygen-flow-rate Fh s in the peak of the decarburization ranging from the beginning to the middle of the blow was 12000Nm 3 /hr and the throat diameter Dt was 55.0mm, then the exit diameter De was established to be 58.2mm according to the formula (5) assuming the constant K was 0.165 from the conditions that the back pressure of the nozzle Po was 853kPa, the ambient pressure was 101kPa (the atmospheric pressure), and the throat diameter Dt was 55.0mm. And then, all of the 5 holes-Laval nozzles were formed like this.
  • the oxygen-flow-rate F M in the end of the blow was established to be about 30000Nm 3 /hr as with the example 1. Since the optimum exit diameter De o is given to be 61.5mm from the practical example 1, the ratio of the exit diameter De to the optimum exit diameter De o (De/De o ) is 0.95.
  • the oxygen was fed through the top-blown lance inserted within the converter under the conditions that the oxygen-flow-rate F was 60000Nm 3 /hr and the back pressure of the nozzle P was 853kPa in the range from the beginning to the middle of the blow as the peak of the decarburization, and the blow was done under the back pressure of the nozzle P of 428kPa in the end of the blow where the carbon concentration of the molten pool became 0.6mass% or less.
  • the amount of the dust in the offgas was measured using the dry type dust-measuring device during the blow. Moreover, the slag within the converter was sampled when the blow was completed, and the T.Fe in the slag was examined. From the results of the blows over 100 heats, the amount of the dust was 7kg per ton of the molten steel in the blow using this lance, and the T.Fe in the slag was 14mass% when the blow was stopped at the carbon content of 0.05mass%, and thus the significant effect for the dust reduction was found with substantially remaining the effect for the reduction of the T.Fe. Moreover, it was observed that the metal adhesion to the lance was extremely low in this occasion.
  • the molten iron, to which the pretreatment for molten iron had been applied was blown with the 5 holes-nozzle type top-blown lance under the same conditions as those in the practical example 1 except for the amount of the slag.
  • the lime-based flux was added into the converter to generate the small amount of the slag (less than 30kg per ton of the molten steel).
  • the shape of the Laval nozzle was determined from the oxygen-flow-rate F M in the end of the blow.
  • the exit diameter De of the Laval nozzle was determined under the conditions that the oxygen-flow-rate in the end of the blow was 30000Nm 3 /hr, the throat diameter Dt of the Laval nozzle was 56.0mm, and the ratio of the exit diameter De to the optimum exit diameter De o (De/De o ) was 0.95 or less.
  • the exit diameter De was established such that the ratio to the optimum exit diameter De o (De/De o ) was 0.94, and the exit diameter De was established to be 58.4mm. All of the 5 holes-Laval nozzles were formed like this.
  • the oxygen was fed under the conditions that the oxygen-flow-rate F s was 60000Nm 3 /hr in the range from the beginning to the middle of the blow as the peak of the decarburization, and the blow was done under the conditions that the oxygen-flow-rate F M was 30000Nm 3 /hr and the back pressure of the nozzle P was 411kPa in the end of the blow where the carbon concentration of the molten pool was 0.6mass% or less.
  • the back pressure of the nozzle P was about 823kPa (8.4kgf/cm 2 ) in the peak of the decarburization from the beginning to the middle of the blow where the oxygen-flow-rate F s was established to be 60000Nm 3 /hr.
  • the amount of the dust in the offgas was measured using the dry type dust-measuring device during the blow. Moreover, the slag within the converter was sampled when the blow was completed, and the T.Fe in the slag was examined. From the results of blows over 100 heats, the amount of the dust was 8kg per ton of the molten steel in the blow using this lance, in addition, the T.Fe in the slag was 14mass% when the blow was stopped at the carbon content of 0.05mass%, and thus the significant effect for the dust reduction was found with substantially remaining the effect for the T.Fe reduction. Moreover, it was observed that the metal adhesion to the lance was extremely low in this occasion.
  • the molten iron, to which the pretreatment for molten iron had been applied was blown with the 5 holes-nozzle type top-blown lance under the same conditions as those in the example 1.
  • the exit diameter De was established such that the optimum expansion can be obtained in the peak of the decarburization.
  • the exit diameter De was established to be 73.0mm according to the formula (5) assuming the constant k was 0.259 from the conditions that the back pressure of the nozzle Po was 853kPa(8.7kgf/cm 2 ), the ambient pressure Pe was 101kPa (the atmospheric pressure), and the throat diameter Dt was 55.0mm.
  • the blow was done with all of 5 holes Laval nozzles being formed like this, and the amount of the dust in the offgas was measured using the dry type dust-measuring device during the blow. Moreover, the slag within the converter was sampled when the blow was completed, and the T.Fe in the slag was examined. From the results of the blows over 100 heats, the amount of the dust was 14kg per ton of the molten steel in the blow using this lance, in addition, the T.Fe in the slag was 19mass% when the blow was stopped at the carbon content of 0.05mass%, that is, both effects for the dust reduction and the T.Fe reduction were low compared with those in the practical examples.

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Claims (12)

  1. Procédé pour souffler de l'oxygène dans un convertisseur, le procédé utilisant une lance à soufflage par le haut ayant une buse de Laval installée au bout de la lance à soufflage par le haut,
    caractérisé en ce que
    la buse de Laval a une contre-pression de la buse Po (kPa) satisfaisant à la formule suivante en fonction d'un débit d'oxygène Fhs (Nm3/h) par trou de la buse de Laval déterminé à partir du débit d'oxygène Fs (Nm3/h) dans une zone à haute teneur en carbone dans un pic de décarburation et en fonction d'un diamètre d'étranglement Dt (mm), Po = Fh s / 0 , 00465 ⋅ D ⁢ t 2
    Figure imgb0052
    la buse de Laval a un diamètre de sortie De satisfaisant à la formule suivante en fonction de la contre-pression de la buse Po (kPa), de la pression ambiante Pe (kPa), et dudit diamètre d'étranglement Dt (mm). D ⁢ e 2 ≦ 0 , 23 × D ⁢ t 2 / Pe / Po 5 / 7 × 1 - Pe / Po 2 / 7 1 / 2
    Figure imgb0053
  2. Procédé selon la revendication 1, caractérisé en ce que ledit diamètre de sortie De de la buse de Laval satisfait à la formule suivante en fonction de la contre-pression de la buse Po (kPa), de 1a pression ambiante Pe (kPa), et dudit diamètre d'étranglement Dt (mm). D ⁢ e 2 ≦ 0 , 185 × D ⁢ t 2 / Pe / Po 5 / 7 × 1 - Pe / Po 2 / 7 1 / 2
    Figure imgb0054
  3. Procédé selon la revendication 2, caractérisé en ce que ledit diamètre de sortie De de la buse de Laval satisfait à la formule suivante en fonction de la contre-pression de la buse Po (kPa), de la pression ambiante Pe (kPa), et dudit diamètre d'étranglement Dt (mm). 0 , 15 × D ⁢ t 2 / Pe / Po 5 / 7 × Pe / Po 2 / 7 1 / 2 ≦ D ⁢ e 2 ≦
    Figure imgb0055
     0 , 18 × D ⁢ t 2 / Pe / Po 5 / 7 × Pe / Po 2 / 7 1 / 2
    Figure imgb0056
  4. Procédé selon la revendication 1, caractérisé en ce que ladite lance à soufflage par le haut possède de multiples buses de Laval et au moins une de ces buses de Laval satisfait aux conditions des deux formules suivantes. Po = Fh s / 0 , 00465 ⋅ D ⁢ t 2
    Figure imgb0057
     D ⁢ e 2 ≦ 0 , 23 × D ⁢ t 2 / Pe / Po 5 / 7 × 1 - Pe / Po 2 / 7 1 / 2
    Figure imgb0058
  5. Procédé selon la revendication 4, dans lequel ladite lance à soufflage par le haut possède les multiples buses de Laval et au moins une de ces buses de Laval satisfait aux conditions des deux formules suivantes. Po = Fh s / 0 , 00465 ⋅ D ⁢ t 2
    Figure imgb0059
     D ⁢ e 2 ≦ 0 , 185 × D ⁢ t 2 / Pe / Po 5 / 7 × 1 - Pe / Po 2 / 7 1 / 2
    Figure imgb0060
  6. Procédé selon l'une quelconque des revendications 1 à 5, dans lequel le soufflage d'oxygène est effectué à une quantité de laitier inférieure à 50 kg par tonne d'acier fondu.
  7. Procédé selon la revendication 6, dans lequel le soufflage d'oxygène est effectué à la quantité de laitier inférieure à 30 kg par tonne d'acier fondu.
  8. Procédé selon l'une quelconque des revendications 1 à 7, caractérisé en ce que
    ladite buse de Laval a la contre-pression de la buse Poo (kPa) satisfaisant à la formule suivante en fonction du débit d'oxygène FhM (Nm3/h) par trou de la buse de Laval déterminée à partir du débit d'oxygène FM (Nm3/h) dans la zone à faible teneur en carbone à la fin du soufflage et en fonction dudit diamètre d'étranglement Dt (mm), Poo = F ⁢ h M / 0 , 00465 ⋅ D ⁢ t 2
    Figure imgb0061
    ledit diamètre de sortie De a un rapport (De / Deo) de 1,10 ou moins à un diamètre de sortie optimal Deo (mm) obtenu à partir de la contre-pression Poo (kPa), de la pression ambiante Pe (kPa), et dudit diamètre d'étranglement Dt (mm) selon la formule suivante. D ⁢ e o 2 = 0 , 259 × D ⁢ t 2 / Pe / Po 5 / 7 × 1 - Pe / Po 2 / 7 1 / 2
    Figure imgb0062
  9. Procédé pour souffler de l'oxygène dans un convertisseur, le procédé utilisant une lance à soufflage par le haut ayant une buse de Laval installée au bout de la lance à soufflage par le haut,
    caractérisé en ce que
    ladite buse de Laval a la contre-pression de la buse Poo (kPa) satisfaisant à la formule suivante en fonction du débit d'oxygène FhM (Nm3/h) par trou de la buse de Laval déterminée à partir du débit d'oxygène FM (Nm3/h) dans la zone à basse teneur en carbone à la fin du soufflage et en fonction du diamètre d'étranglement Dt (mm). Poo = F ⁢ h M / 0 , 00465 ⋅ D ⁢ t 2
    Figure imgb0063
    ledit diamètre de sortie De de la buse de Laval a le rapport (De / Deo) de 0,95 ou moins par rapport au diamètre de sortie optimal Deo (mm) obtenu à partir de la contre-pression Poo (kPa), de la pression ambiante Pe (kPa), et dudit diamètre d'étranglement Dt (mm) selon la formule suivante. D ⁢ e o 2 = 0 , 259 × D ⁢ t 2 / Pe / Po 5 / 7 × 1 - Pe / Po 2 / 7 1 / 2
    Figure imgb0064
  10. Procédé selon la revendication 9, caractérisé en ce que ladite lance à soufflage par le haut possède les multiples buses de Laval et au moins une de ces buses de Laval satisfait aux conditions des deux formules suivantes. Poo = F ⁢ h M / 0 , 00465 ⋅ D ⁢ t 2
    Figure imgb0065
     D ⁢ e o 2 = 0 , 259 × D ⁢ t 2 / Pe / Po 5 / 7 × 1 - Pe / Po 2 / 7 1 / 2
    Figure imgb0066
  11. Procédé selon la revendication 9, dans lequel le soufflage d'oxygène est effectué à la quantité de laitier inférieure à 50 kg par tonne d'acier fondu.
  12. Procédé selon la revendication 11, dans lequel le soufflage d'oxygène est effectué à la quantité de laitier inférieure à 30 kg par tonne d'acier fondu.
EP01996630A 2000-11-16 2001-11-15 Procede de soufflage d'oxygene de convertisseur et lance de soufflage vers le haut pour soufflage d'oxygene de convertisseur Expired - Lifetime EP1340823B1 (fr)

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JP2000349746 2000-11-16
JP2000349746 2000-11-16
JP2001302591A JP4273688B2 (ja) 2000-11-16 2001-09-28 転炉吹錬方法
JP2001302591 2001-09-28
PCT/JP2001/009971 WO2002040721A1 (fr) 2000-11-16 2001-11-15 Procede de soufflage d'oxygene de convertisseur et lance de soufflage vers le haut pour soufflage d'oxygene de convertisseur

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US20070052603A1 (en) * 2005-07-28 2007-03-08 Shesh Nyalamadugu Multiple loop RFID system
KR100813698B1 (ko) * 2006-10-12 2008-03-14 인하대학교 산학협력단 저온 분사 코팅용 초음속 노즐 및 이를 이용한 저온 분사코팅 방법
CN101597664B (zh) * 2009-06-18 2011-01-05 攀钢集团攀枝花钢铁研究院有限公司 一种氧气顶吹转炉炼钢的方法
CN101962728B (zh) * 2010-10-15 2013-05-01 刘东业 粒状镁铁水脱硫用喷枪
EP2796569B1 (fr) 2011-12-20 2017-08-02 JFE Steel Corporation Procédé de fabrication d'acier par convertisseur
CN102443681B (zh) * 2011-12-22 2013-08-14 刘东业 颗粒镁铁水脱硫喷枪
CN103707204B (zh) * 2013-12-10 2016-04-13 安徽工业大学 一种利用炼钢转炉渣对工件表面进行喷砂处理的方法
DE102015105307A1 (de) * 2015-04-08 2016-10-13 Sms Group Gmbh Konverter
JP6660044B2 (ja) 2017-12-22 2020-03-04 Ｊｆｅスチール株式会社 溶鉄の送酸精錬方法及び上吹きランス
TWI700373B (zh) * 2018-05-28 2020-08-01 日商日本製鐵股份有限公司 轉爐吹煉方法
CN113597472A (zh) * 2019-04-09 2021-11-02 杰富意钢铁株式会社 喷枪喷嘴

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