EP1211941B1 - Selektive herbizide auf basis eines substituierten phenylsulfonylaminocarbonyltriazolinons und safenern - Google Patents
Selektive herbizide auf basis eines substituierten phenylsulfonylaminocarbonyltriazolinons und safenern Download PDFInfo
- Publication number
- EP1211941B1 EP1211941B1 EP00962323A EP00962323A EP1211941B1 EP 1211941 B1 EP1211941 B1 EP 1211941B1 EP 00962323 A EP00962323 A EP 00962323A EP 00962323 A EP00962323 A EP 00962323A EP 1211941 B1 EP1211941 B1 EP 1211941B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- methyl
- compound
- dichloro
- formula
- dihydro
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 150000001875 compounds Chemical class 0.000 claims abstract description 35
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- -1 compound diethyl 1-(2,4-dichlorophenyl)-4,5-dihydro-5-methyl-1H-pyrazole-3,5-dicarboxylate Chemical class 0.000 claims description 10
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- 125000002877 alkyl aryl group Chemical group 0.000 description 1
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- SOIFLUNRINLCBN-UHFFFAOYSA-N ammonium thiocyanate Chemical compound [NH4+].[S-]C#N SOIFLUNRINLCBN-UHFFFAOYSA-N 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 229960000892 attapulgite Drugs 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 150000008422 chlorobenzenes Chemical class 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- JQVDAXLFBXTEQA-UHFFFAOYSA-N dibutylamine Chemical compound CCCCNCCCC JQVDAXLFBXTEQA-UHFFFAOYSA-N 0.000 description 1
- JQVDAXLFBXTEQA-UHFFFAOYSA-O dibutylazanium Chemical compound CCCC[NH2+]CCCC JQVDAXLFBXTEQA-UHFFFAOYSA-O 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- HPNMFZURTQLUMO-UHFFFAOYSA-O diethylammonium Chemical compound CC[NH2+]CC HPNMFZURTQLUMO-UHFFFAOYSA-O 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000010459 dolomite Substances 0.000 description 1
- 229910000514 dolomite Inorganic materials 0.000 description 1
- 238000010410 dusting Methods 0.000 description 1
- 238000005538 encapsulation Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- QUSNBJAOOMFDIB-UHFFFAOYSA-O ethylaminium Chemical compound CC[NH3+] QUSNBJAOOMFDIB-UHFFFAOYSA-O 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 239000003102 growth factor Substances 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000000787 lecithin Substances 0.000 description 1
- 235000010445 lecithin Nutrition 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical class [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 239000004579 marble Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- OBYVIBDTOCAXSN-UHFFFAOYSA-N n-butan-2-ylbutan-2-amine Chemical compound CCC(C)NC(C)CC OBYVIBDTOCAXSN-UHFFFAOYSA-N 0.000 description 1
- 229940042880 natural phospholipid Drugs 0.000 description 1
- 239000005645 nematicide Substances 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 229910052625 palygorskite Inorganic materials 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 150000003904 phospholipids Chemical class 0.000 description 1
- 239000001007 phthalocyanine dye Substances 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 235000012015 potatoes Nutrition 0.000 description 1
- 239000003531 protein hydrolysate Substances 0.000 description 1
- 239000008262 pumice Substances 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 229910052624 sepiolite Inorganic materials 0.000 description 1
- 235000019355 sepiolite Nutrition 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- YBRBMKDOPFTVDT-UHFFFAOYSA-N tert-butylamine Chemical compound CC(C)(C)N YBRBMKDOPFTVDT-UHFFFAOYSA-N 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 230000009261 transgenic effect Effects 0.000 description 1
- IMFACGCPASFAPR-UHFFFAOYSA-O tributylazanium Chemical compound CCCC[NH+](CCCC)CCCC IMFACGCPASFAPR-UHFFFAOYSA-O 0.000 description 1
- ZMANZCXQSJIPKH-UHFFFAOYSA-O triethylammonium ion Chemical compound CC[NH+](CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-O 0.000 description 1
- WCZKTXKOKMXREO-UHFFFAOYSA-N triethylsulfanium Chemical class CC[S+](CC)CC WCZKTXKOKMXREO-UHFFFAOYSA-N 0.000 description 1
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 1
- NRZWQKGABZFFKE-UHFFFAOYSA-N trimethylsulfonium Chemical compound C[S+](C)C NRZWQKGABZFFKE-UHFFFAOYSA-N 0.000 description 1
- YFTHZRPMJXBUME-UHFFFAOYSA-N tripropylamine Chemical compound CCCN(CCC)CCC YFTHZRPMJXBUME-UHFFFAOYSA-N 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/38—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< where at least one nitrogen atom is part of a heterocyclic ring; Thio analogues thereof
Definitions
- the invention relates to novel selective herbicidal active ingredient combinations which are 2- (2-methoxycarbonyl-phenylsulfonylaminocarbonyl) -4-methyl-5-propoxy-2,4-dihydro-3H-1,2,4-triazol-3-one and / or its salts, in particular its sodium salt, on the one hand and at least one crop plant compatibility-improving compound on the other hand, and with particular success for selective weed control can be used in various crops.
- Substituted phenylsulfonylaminocarbonyl-triazolinones are effective herbicides known (see, for example, EP-A 507 171). The effect of these compounds and / or their Compatibility with crops, however, is not under all conditions quite satisfactory.
- the salts of the compound of formula (I) are preferably the sodium, potassium, ammonium, Methylammonium, ethylammonium, n- or i-propylammonium, n-, i-, s- or t-butylammonium, dimethylammonium, diethylammonium, di-n-propylammonium, Di-i-propylammonium, di-n-butyl-ammonium, di-i-butylammonium, Di-s-butylammonium, trimethylammonium, triethylammonium, tripropylammonium, Tributylammonium, trimethylsulfonium and triethylsulfonium salts.
- the crop plants are all plants and plant cultivars including transgenic plants and plant varieties.
- the advantageous effect of the crop plant compatibility of the active compound combinations according to the invention is particularly strong at certain concentration ratios pronounced.
- the weight ratios of the active ingredients in the drug combinations be varied in relatively large areas.
- 1 part by weight of active substance of formula (I) or its salts 0.001 to 1000 Parts by weight, preferably 0.01 to 100 parts by weight and more preferably 0.1 to 10 parts by weight of one of the above mentioned under (b), the crops compatibility improving compound.
- the active compounds or active substance combinations can be converted into the customary formulations such as solutions, emulsions, wettable powders, suspensions, powders, Dusts, pastes, soluble powders, granules, suspension emulsion concentrates, Active substance-impregnated natural and synthetic substances as well as ultra-fine encapsulation in polymeric substances.
- formulations are prepared in a known manner, for. B. by mixing the active ingredients with extenders, ie liquid solvents and / or solid carriers, optionally using surface-active agents, ie Emulsifiers and / or dispersants and / or foam-forming agents.
- extenders ie liquid solvents and / or solid carriers
- surface-active agents ie Emulsifiers and / or dispersants and / or foam-forming agents.
- organic solvents be used as auxiliary solvent.
- aromatics such as xylene, toluene, or alkylnaphthalenes
- chlorinated aromatics and chlorinated aliphatic hydrocarbons such as chlorobenzenes, Chloroethylene or methylene chloride
- aliphatic hydrocarbons such as cyclohexane or paraffins, e.g.
- Petroleum fractions mineral and vegetable oils, alcohols, such as Butanol or glycol and their ethers and esters, ketones such as acetone, Methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents, such as dimethylformamide and dimethyl sulfoxide, as well as water.
- alcohols such as Butanol or glycol and their ethers and esters
- ketones such as acetone, Methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone
- strongly polar solvents such as dimethylformamide and dimethyl sulfoxide, as well as water.
- Suitable solid carriers are: For example, ammonium salts and ground natural minerals, such as kaolins, clays, talc, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth and synthetic minerals, such as finely divided silica, alumina and silicates, as solid carriers for granules in question: eg broken and fractionated natural rocks such Calcite, marble, pumice, sepiolite, dolomite and synthetic granules of inorganic and organic flours and granules of organic material such as sawdust, coconut shells, corn cobs and tobacco stalks; suitable emulsifiers and / or foam formers are: for example nonionic and anionic emulsifiers, such as polyoxyethylene fatty acid esters, polyoxyethylene fatty alcohol ethers, for example alkylaryl polyglycol ethers, alkylsulfonates, alkyl sulfates, arylsulfonates and protein hydro
- adhesives such as carboxymethylcellulose, natural and synthetic powdery, granular or latex-shaped polymers are used, such as Gum arabic, polyvinyl alcohol, polyvinyl acetate, as well as natural phospholipids, such as cephalins and lecithins and synthetic phospholipids.
- Other additives can be mineral and vegetable oils.
- Dyes such as inorganic pigments, e.g. Iron oxide, titanium oxide, ferrocyan blue and organic dyes such as alizarin, azo and metal phthalocyanine dyes and trace nutrients such as salts of iron, manganese, boron, copper, cobalt, Molybdenum and zinc are used.
- inorganic pigments e.g. Iron oxide, titanium oxide, ferrocyan blue and organic dyes such as alizarin, azo and metal phthalocyanine dyes and trace nutrients such as salts of iron, manganese, boron, copper, cobalt, Molybdenum and zinc are used.
- the formulations generally contain between 0.1 and 95 percent by weight of active substances, including safening agents, preferably between 0.5 and 90%.
- the active compound combinations according to the invention are generally in the form of Ready-made formulations applied.
- the new drug combinations can be used as such or in their formulations continue to be used in combination with other known herbicides, in turn, finished formulations or tank mixes are possible. Also one Mixture with other known active substances, such as fungicides, insecticides, acaricides, Nematicides, bird repellants, growth factors, plant nutrients and soil conditioners is possible. For certain purposes, In particular, postemergence, it may also be advantageous in the Formulations as further additives plant-compatible mineral or vegetable oils (e.g., the commercial preparation "Oleo® DuPont 11E") or ammonium salts such as. Ammonium sulfate or ammonium thiocyanate.
- plant-compatible mineral or vegetable oils e.g., the commercial preparation "Oleo® DuPont 11E”
- ammonium salts such as. Ammonium sulfate or ammonium thiocyanate.
- the new drug combinations can be used as such, in the form of their formulations or the use forms prepared therefrom by further dilution, such as Ready-to-use solutions, suspensions, emulsions, powders, pastes and granules be applied.
- the application is done in the usual way, e.g. by pouring, Spraying, spraying, dusting or spreading.
- the application rates of the active compound combinations according to the invention can be described in varied within a certain range; they hang u.a. from the weather and from the Soil factors. In general, the application rates are between 0.05 and 5 kg per ha, preferably between 0.05 and 2 kg per ha, more preferably between 0.1 and 1.0 kg per ha.
- the active compound combinations according to the invention can before and after emergence the plants are applied, ie in the pre-emergence and post-emergence procedure.
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Plural Heterocyclic Compounds (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19940860A DE19940860A1 (de) | 1999-08-27 | 1999-08-27 | Selektive Herbizide auf Basis eines substituierten Phenylsulfonyl aminocarbonyltriazolinons und Safenern II |
| DE19940860 | 1999-08-27 | ||
| PCT/EP2000/007982 WO2001015533A1 (de) | 1999-08-27 | 2000-08-16 | Selektive herbizide auf basis eines substituierten phenylsulfonylaminocarbonyltriazolinons und safenern |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP1211941A1 EP1211941A1 (de) | 2002-06-12 |
| EP1211941B1 true EP1211941B1 (de) | 2003-11-26 |
Family
ID=7919912
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP00962323A Expired - Lifetime EP1211941B1 (de) | 1999-08-27 | 2000-08-16 | Selektive herbizide auf basis eines substituierten phenylsulfonylaminocarbonyltriazolinons und safenern |
Country Status (20)
| Country | Link |
|---|---|
| US (1) | US6649565B1 (enExample) |
| EP (1) | EP1211941B1 (enExample) |
| JP (1) | JP2003508413A (enExample) |
| CN (1) | CN1198507C (enExample) |
| AR (1) | AR025397A1 (enExample) |
| AT (1) | ATE254849T1 (enExample) |
| AU (1) | AU771120B2 (enExample) |
| BR (1) | BR0013646A (enExample) |
| CA (1) | CA2382305A1 (enExample) |
| CZ (1) | CZ303831B6 (enExample) |
| DE (2) | DE19940860A1 (enExample) |
| DK (1) | DK1211941T3 (enExample) |
| ES (1) | ES2208423T3 (enExample) |
| HU (1) | HU230217B1 (enExample) |
| MX (1) | MXPA02002039A (enExample) |
| PL (1) | PL200541B1 (enExample) |
| RU (1) | RU2266648C2 (enExample) |
| UA (1) | UA73142C2 (enExample) |
| WO (1) | WO2001015533A1 (enExample) |
| ZA (1) | ZA200200593B (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CZ303831B6 (cs) * | 1999-08-27 | 2013-05-22 | Bayer Aktiengesellschaft | Herbicidní prostredek, jeho pouzití, zpusob jeho výroby a zpusob hubení plevelu |
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| DE10139465A1 (de) * | 2001-08-10 | 2003-02-20 | Bayer Cropscience Ag | Selektive Herbizide auf Basis von substituierten, cayclischen Ketoenolen und Safenern |
| DE10143083A1 (de) * | 2001-09-03 | 2003-03-20 | Bayer Cropscience Ag | Selektive Herbizide auf Basis von substituierten Arylsulfonylaminocarbonyltriazolinonen und Safenern |
| DE10146590A1 (de) * | 2001-09-21 | 2003-04-10 | Bayer Cropscience Ag | Selektive Herbizide auf Basis von substituierten Thien-3-yl-sulfonylamino(thio)carbonyl-triazolin(thi)onen und Safenern |
| DE10146591A1 (de) * | 2001-09-21 | 2003-04-10 | Bayer Cropscience Ag | Herbizide auf Basis von substituierten Thien-3-yl-sulfonylamino(thio)carbonyl-triazolin(thi)onen |
| DE102004010813A1 (de) | 2004-03-05 | 2005-11-10 | Bayer Cropscience Ag | Neue Herbizide auf Basis von substituierten Thien-3-yl-sulfonylamino(thio)carbonyltriazolin(thi)onen und 4-HPPD-Hemmstoffen |
| DE102004035136A1 (de) * | 2004-07-20 | 2006-02-16 | Bayer Cropscience Gmbh | Safening-Methode |
| CA2622071A1 (en) * | 2005-09-08 | 2007-03-15 | Bayer Cropscience Ag | Novel sulfonamide-containing solid formulations |
| US8940742B2 (en) | 2012-04-10 | 2015-01-27 | Infinity Pharmaceuticals, Inc. | Heterocyclic compounds and uses thereof |
| SG10201902074UA (en) | 2013-10-04 | 2019-04-29 | Infinity Pharmaceuticals Inc | Heterocyclic compounds and uses thereof |
| WO2015051241A1 (en) | 2013-10-04 | 2015-04-09 | Infinity Pharmaceuticals, Inc. | Heterocyclic compounds and uses thereof |
| CN113616656B (zh) | 2014-03-19 | 2023-02-17 | 无限药品股份有限公司 | 用于治疗PI3K-γ介导的障碍的杂环化合物 |
| WO2016054491A1 (en) | 2014-10-03 | 2016-04-07 | Infinity Pharmaceuticals, Inc. | Heterocyclic compounds and uses thereof |
| RS60906B1 (sr) | 2014-10-06 | 2020-11-30 | Vertex Pharma | Modulatori regulatora transmembranske provodljivosti za cističnu fibrozu |
| AU2016322552B2 (en) | 2015-09-14 | 2021-03-25 | Infinity Pharmaceuticals, Inc. | Solid forms of isoquinolinone derivatives, process of making, compositions comprising, and methods of using the same |
| WO2017161116A1 (en) | 2016-03-17 | 2017-09-21 | Infinity Pharmaceuticals, Inc. | Isotopologues of isoquinolinone and quinazolinone compounds and uses thereof as pi3k kinase inhibitors |
| PL3436446T3 (pl) | 2016-03-31 | 2023-09-11 | Vertex Pharmaceuticals Incorporated | Modulatory mukowiscydozowego przezbłonowego regulatora przewodnictwa |
| WO2017214269A1 (en) | 2016-06-08 | 2017-12-14 | Infinity Pharmaceuticals, Inc. | Heterocyclic compounds and uses thereof |
| HUE056716T2 (hu) | 2016-09-30 | 2022-03-28 | Vertex Pharma | Cisztás firbrózis transzmembrán konduktancia regulátor modulátora, gyógyszerészeti készítmények, kezelési eljárások, és eljárások a modulátor elõállítására |
| EP3812379A1 (en) | 2016-12-09 | 2021-04-28 | Vertex Pharmaceuticals Incorporated | Crystalline form of a n-(pyrazol-4-yl)sulfonyl-6-(pyrazol-1-yl)-2-(pyrrolidin-1-yl)pyridine-3-carboxamide for treating cystic fibrosis |
| AU2018279646B2 (en) | 2017-06-08 | 2023-04-06 | Vertex Pharmaceuticals Incorporated | Methods of treatment for cystic fibrosis |
| CA3069226A1 (en) | 2017-07-17 | 2019-01-24 | Vertex Pharmaceuticals Incorporated | Methods of treatment for cystic fibrosis |
| ES2912657T3 (es) | 2017-08-02 | 2022-05-26 | Vertex Pharma | Procesos para preparar compuestos de pirrolidina |
| AU2018351533B2 (en) | 2017-10-19 | 2023-02-02 | Vertex Pharmaceuticals Incorporated | Crystalline forms and compositions of CFTR modulators |
| JP7245834B2 (ja) | 2017-12-08 | 2023-03-24 | バーテックス ファーマシューティカルズ インコーポレイテッド | 嚢胞性線維症膜コンダクタンス制御因子のモジュレーターを作成するためのプロセス |
| TWI810243B (zh) | 2018-02-05 | 2023-08-01 | 美商維泰克斯製藥公司 | 用於治療囊腫纖化症之醫藥組合物 |
| US11414439B2 (en) | 2018-04-13 | 2022-08-16 | Vertex Pharmaceuticals Incorporated | Modulators of cystic fibrosis transmembrane conductance regulator, pharmaceutical compositions, methods of treatment, and process for making the modulator |
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| EP0112799A1 (de) | 1982-12-06 | 1984-07-04 | Ciba-Geigy Ag | Herbizides Mittel zur selektiven Unkrautbekämpfung in Getreide |
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| US5700758A (en) | 1989-11-30 | 1997-12-23 | Hoechst Aktiengesellschaft | Pyrazolines for protecting crop plants against herbicides |
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| DE19638887A1 (de) | 1996-09-23 | 1998-03-26 | Bayer Ag | Selektive Herbizide auf Basis von Arylsulfonylaminocarbonyltriazolinonen |
| AU719657B2 (en) | 1998-01-21 | 2000-05-11 | Syngenta Participations Ag | Herbicidal composition |
| AU3183199A (en) | 1998-05-14 | 1999-11-29 | E.I. Du Pont De Nemours And Company | Crop-safened herbicidal mixtures |
| DE19940860A1 (de) * | 1999-08-27 | 2001-03-01 | Bayer Ag | Selektive Herbizide auf Basis eines substituierten Phenylsulfonyl aminocarbonyltriazolinons und Safenern II |
-
1999
- 1999-08-27 DE DE19940860A patent/DE19940860A1/de not_active Withdrawn
-
2000
- 2000-08-16 JP JP2001519762A patent/JP2003508413A/ja not_active Withdrawn
- 2000-08-16 CN CNB008121613A patent/CN1198507C/zh not_active Expired - Fee Related
- 2000-08-16 WO PCT/EP2000/007982 patent/WO2001015533A1/de not_active Ceased
- 2000-08-16 ES ES00962323T patent/ES2208423T3/es not_active Expired - Lifetime
- 2000-08-16 UA UA2002032396A patent/UA73142C2/uk unknown
- 2000-08-16 DK DK00962323T patent/DK1211941T3/da active
- 2000-08-16 EP EP00962323A patent/EP1211941B1/de not_active Expired - Lifetime
- 2000-08-16 CA CA002382305A patent/CA2382305A1/en not_active Abandoned
- 2000-08-16 PL PL362853A patent/PL200541B1/pl unknown
- 2000-08-16 AT AT00962323T patent/ATE254849T1/de active
- 2000-08-16 US US10/069,350 patent/US6649565B1/en not_active Expired - Lifetime
- 2000-08-16 HU HU0301992A patent/HU230217B1/hu unknown
- 2000-08-16 DE DE50004584T patent/DE50004584D1/de not_active Expired - Lifetime
- 2000-08-16 AU AU74094/00A patent/AU771120B2/en not_active Ceased
- 2000-08-16 RU RU2002107796/04A patent/RU2266648C2/ru active
- 2000-08-16 BR BR0013646-8A patent/BR0013646A/pt not_active IP Right Cessation
- 2000-08-16 MX MXPA02002039A patent/MXPA02002039A/es active IP Right Grant
- 2000-08-16 CZ CZ20020650A patent/CZ303831B6/cs not_active IP Right Cessation
- 2000-08-25 AR ARP000104423A patent/AR025397A1/es active IP Right Grant
-
2002
- 2002-01-23 ZA ZA200200593A patent/ZA200200593B/xx unknown
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CZ303831B6 (cs) * | 1999-08-27 | 2013-05-22 | Bayer Aktiengesellschaft | Herbicidní prostredek, jeho pouzití, zpusob jeho výroby a zpusob hubení plevelu |
Also Published As
| Publication number | Publication date |
|---|---|
| DE50004584D1 (de) | 2004-01-08 |
| US6649565B1 (en) | 2003-11-18 |
| HUP0301992A3 (en) | 2005-11-28 |
| UA73142C2 (uk) | 2005-06-15 |
| BR0013646A (pt) | 2002-05-07 |
| DK1211941T3 (da) | 2004-04-05 |
| DE19940860A1 (de) | 2001-03-01 |
| AR025397A1 (es) | 2002-11-27 |
| AU7409400A (en) | 2001-03-26 |
| EP1211941A1 (de) | 2002-06-12 |
| JP2003508413A (ja) | 2003-03-04 |
| HUP0301992A2 (en) | 2003-09-29 |
| CZ303831B6 (cs) | 2013-05-22 |
| AU771120B2 (en) | 2004-03-11 |
| CN1198507C (zh) | 2005-04-27 |
| WO2001015533A1 (de) | 2001-03-08 |
| CZ2002650A3 (cs) | 2002-06-12 |
| ZA200200593B (en) | 2003-03-26 |
| ATE254849T1 (de) | 2003-12-15 |
| HU230217B1 (hu) | 2015-10-28 |
| CA2382305A1 (en) | 2001-03-08 |
| ES2208423T3 (es) | 2004-06-16 |
| PL362853A1 (en) | 2004-11-02 |
| CN1379622A (zh) | 2002-11-13 |
| PL200541B1 (pl) | 2009-01-30 |
| RU2266648C2 (ru) | 2005-12-27 |
| MXPA02002039A (es) | 2002-11-07 |
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