EP1173063A1 - Stärkung des wachstums von nutz- und zierpflanzen gegen unerwünschten pilzbefall im oberirdischen pflanzenbereich - Google Patents

Stärkung des wachstums von nutz- und zierpflanzen gegen unerwünschten pilzbefall im oberirdischen pflanzenbereich

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Publication number
EP1173063A1
EP1173063A1 EP00922640A EP00922640A EP1173063A1 EP 1173063 A1 EP1173063 A1 EP 1173063A1 EP 00922640 A EP00922640 A EP 00922640A EP 00922640 A EP00922640 A EP 00922640A EP 1173063 A1 EP1173063 A1 EP 1173063A1
Authority
EP
European Patent Office
Prior art keywords
component
plant
compounds
components
component mixtures
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP00922640A
Other languages
German (de)
English (en)
French (fr)
Inventor
Bettina Kopp-Holtwiesche
Doris Bell
Stephan Von Tapavicza
Johann Friedrich Fues
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Personal Care and Nutrition GmbH
Original Assignee
Cognis Deutschland GmbH and Co KG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Cognis Deutschland GmbH and Co KG filed Critical Cognis Deutschland GmbH and Co KG
Publication of EP1173063A1 publication Critical patent/EP1173063A1/de
Withdrawn legal-status Critical Current

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Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds

Definitions

  • Spray products rich in silicon are used preventively in organic farming to protect against fungal leaf diseases, see p. see, for example, the publication Heyland, General Plant Cultivation, published by Eugen Ulmer, 7th edition, page 384, in book form. These preparations offer double protection. Due to the high pH value of the usual spray preparations, the fungal spores cannot establish themselves on the leaf. In addition, part of the silicon is absorbed through the sheet and incorporated into plant tissue. This results in a higher mechanical strength, which offers increased resistance to penetrating fungal spores. To promote the wetting of the plant parts to be treated, the use of wetting agents such as plant protection soap is recommended in the aqueous spray liquors. However, there is the problem that the spray preparations do not adhere to the leaf surface for a sufficiently long time and are washed off by rainwater or rainwater.
  • the teaching of this earlier application provides for two forms of application of the specified mixture of valuable substances, which can also be combined with one another: the mixtures can, on the one hand, be introduced into the soil in aqueous preparation form and / or applied to the aerial part of the plant.
  • the result of this measure shows an unexpected plant-strengthening and / or plant-sanitizing action against the infestation of the plants, in particular by phytopathogenic fungi.
  • fungal populations from the mycorrhiza area which promote plant growth, and thus from the area of the down-to-earth mushroom populations associated with the plant roots are not disturbed.
  • EP 0 230 598 describes the use of alkyl glycoside compounds as an active ingredient combating harmful organisms in agents for protecting useful and ornamental plants.
  • the APG compounds described here which in particular also include corresponding APG ethoxylates, can be applied to the aerial part of the plant in the form of aqueous spray liquors.
  • the APG components can be used as such, but also their combinations with other active ingredients from the groups of insecticides, fungicides, virucides, acaricides and other agents or substances from the field of crop promotion. In this context, it is pointed out that not only can the individual effects be added, but also a synergistic increase in activity.
  • the technical teaching of the invention described below is based on the approach of combining the knowledge known per se for the treatment of the aerial plant part with in particular water-soluble and / or water-swellable silicon compounds for the treatment and / or defense against phytopathogenic fungal attack with elements of plant strengthening, how they revelation of the aforementioned earlier application acc. DE 198 30 889.2.
  • the teaching of the invention also wants to make use of elements that are the subject of the likewise older and not previously published application according to. DE 197 48884.6 of the applicant, which will be discussed in more detail below.
  • the subject matter of the invention in a first embodiment is multicomponent mixtures for preventive and / or acute strengthening of useful and / or ornamental plants against pathogen attack, in particular from the field of pathogenic fungi, but also against other harmful effects such as dry stress or mechanical stress, e.g. Containing hail, by applying the mixture of valuable substances in an aqueous preparation to the aerial part of the plant
  • multi-component mixtures of the specified type which additionally contain, as component (d), compounds of P and / or N which have at least some lipophilic radicals.
  • Another embodiment of the teaching according to the invention relates to the use of the multicomponent mixtures described above for preventive and / or acute plant strengthening against harmful effects, in particular for combating and / or warding off fungal attack, by applying homogenized aqueous preparations of the active compound mixtures from components to (a), (b) and (c) on the aerial part of the plant, preferably combined with simultaneous and / or delayed application of component (s) to (d).
  • the effect of the silicon-based applied A portion of the active ingredient mixture according to the invention occurs immediately and at short notice. At least a substantial weakening of a possibly already existing microorganism population from phytopathogenic fungal infection takes place.
  • the still adhering organically based portions of the combination of recyclable materials according to the invention can now bring their plant-strengthening and pollutant-restricting function to an increased extent to advantage.
  • the new technical teaching which is now concerned, on the one hand provides for the joint use of the water-soluble and / or water-swellable and thereby plant-available compounds of silicon together with the components of (a) and (c).
  • the use of the at least partially lipophilic radicals of the compounds of P and / or N - component (d) according to the invention - is a preferred but not a mandatory measure.
  • the teaching according to the invention sees the combination of the organophilic components as (c) in combination with the ecologically compatible wetting agents of the O / W type as (a) with the water-soluble and / or water-swellable and thereby plant-available compounds of silicon as (b) in front.
  • Suitable water-soluble silicon compounds are, in particular, the alkali silicates and here in turn preferably the sodium and / or potassium silicates, which are also referred to as water glasses. Also suitable are alkali metal silicates, but also silica sols and the resulting silica gels, as are known from the relevant prior art of soil preparation for promoting plant growth.
  • alkali metal silicates but also silica sols and the resulting silica gels, as are known from the relevant prior art of soil preparation for promoting plant growth.
  • the chemical identification of water-soluble silicate compounds and in particular sodium and / or potassium water glasses can be found, for example, in the publication H. Weldes "Properties of Soluble Silicates" in INDUSTRIAL AND ENGINEERING CHEMISTRY, VOL. 61 NO. 4 April 1969, pages 29 ff, in particular Tables III and IV, loc. Cit., Page 31.
  • the additional range of silicon according to the invention for stabilizing and promoting plant growth is, however, not limited to the previously mentioned silicon components of inorganic origin. It is known that selected plants are capable of enriching the silicon content in the aerial plants. Examples of this are nettles and / or horsetail. Accordingly, the teaching according to the invention provides that, in addition to or instead of the inorganic silicon sources, corresponding plant-available silicon sources of plant origin are also used, residues and / or extracts of the plant groups mentioned being considered in particular and can be applied to the plant as part of the teaching according to the invention.
  • multicomponent combinations of the type described which are formed in the preparation form of homogenized aqueous concentrates are preferred.
  • these are very finely divided aqueous organic suspensions with a closed aqueous phase and a very finely divided organic phase.
  • these concentrates can be worked up to the spray liquors required in practical use and can be applied simply in a manner known per se.
  • the selection of the individual components for (a) to (d) and their concentration in the multi-component mixture is controlled by the effects desired and to be taken into account in practical use.
  • the silicon components for (b) are selected according to their type and quantity in such a way that undesirable secondary harmful effects - for example due to excessive alkalinity - are excluded in practical use.
  • particularly water-soluble silicon compounds of the type of sodium and / or potassium water glasses are particularly proven agents in practice for combating phytopathogenic fungi on the leaf surface which are present in concentrations in aqueous spray liquors in the range of 0.1% by weight of the silicon compound can generally be discharged without hesitation.
  • the organic portions and here in particular the components of (a) and (c) are selected such that, in the intended use, the all-over covering of the outer surface of the plant with the lipophilic phase or phases of (c) and (d) becomes possible.
  • An important requirement here is that, in particular by choosing suitable substances or combinations of substances, the oil phase (s) spread sufficiently at application temperatures or at least for a limited period of time - e.g. under sunlight - is ensured.
  • the wetting agents or surfactants mentioned here belong in particular to the classes of anionic surfactants and / or nonionic surfactants.
  • An important prerequisite is their ecological compatibility and thus, in particular, sufficient biodegradability in the substrate. Rapidly and completely biodegradable surfactant compounds from the class of nonionic surfactants are a preferred class of the auxiliary substances mentioned here.
  • Suitable anionic surfactants are, for example, soaps, but also biodegradable alkyl sulfates, especially fatty alcohol sulfates.
  • Petrochemical-based surfactants which are difficult or only incompletely degradable, for example alkylbenzene sulfonate or alkyl ether sulfates, are less suitable.
  • Suitable representatives can be the partial esters of phosphoric acid with fatty alcohols, and in particular corresponding partial esters with straight-chain fatty alcohols, preferably of natural origin and thus an even carbon number.
  • Appropriate esters of shorter-chain fatty alcohols for example those with 6 to 10, are suitable here, for example C atoms in the fatty alcohol molecule.
  • alkyl phosphates with longer fatty alcohol residues with, for example, 12 to 24 carbon atoms are also fundamentally suitable. The same applies - albeit less preferred - to the comparable fatty alcohol ether phosphates.
  • Biodegradable surfactants of substance class (a) which are particularly preferred according to the invention are corresponding compounds of at least predominantly nonionic character, which are furthermore preferably at least predominantly of natural substance-based origin and have preferred HLB values in the range from 10 to 18.
  • component (a) at least partially and in particular at least predominantly alkyl (oligo) glucoside compounds whose alkyl radical is derived at least predominantly from straight-chain fatty alcohols.
  • component (a) at least partially and in particular at least predominantly alkyl (oligo) glucoside compounds whose alkyl radical is derived at least predominantly from straight-chain fatty alcohols.
  • Compounds of this type - also referred to as APG components or compounds according to current usage - are surfactant auxiliaries for a wide range of uses. A number of factors are important for their practical use on a large industrial scale today: APG-based wetting agents can be known to be completely based on natural substances.
  • reaction products by reacting fatty alcohols with glucose, oligoglucose or - with simultaneous degradation of the chain length - with polyglycosides such as starch as reaction products of the general formula RO- (G) x , in which R contains a primary, preferably straight-chain and aliphatic hydrocarbon radical means at least 6 carbon atoms, preferably with 8 to 24 carbon atoms and in particular 8 to 18 carbon atoms, and G stands for a glycose unit with 5 or 6 carbon atoms, preferably for glucose.
  • R contains a primary, preferably straight-chain and aliphatic hydrocarbon radical means at least 6 carbon atoms, preferably with 8 to 24 carbon atoms and in particular 8 to 18 carbon atoms
  • G stands for a glycose unit with 5 or 6 carbon atoms, preferably for glucose.
  • the degree of oligomerization x - and thus the DP value - which indicates the distribution of monoglycosides and oligoglycosides is usually a value between 1 and 10 in the surfactant class concerned here and is, for example, in the range from about 1.2 to 5, preferably in Range of about 1, 2 to 4 and in particular in the range of 1, 2 to 2.
  • APG compounds of the type concerned here see for example the publication by Hill published in book form et. al. "Alkyl Polyglycosides", VCH-Verlagsgeselischaft mbH, Weinheim, 1997.
  • Re (c) "Lipophilic hydrocarbon residues with fat structure organic compounds"
  • the C source essential for organotrophic growth according to the invention are the lipophilic hydrocarbon residues with fat structure present in this component and thus the comparatively increased concentration of the energy-supplying C-H groups.
  • these hydrocarbon residues with a fat structure can be saturated and / or at least partially olefinically unsaturated. Further considerations regarding the physico-chemical nature of this component, which will be dealt with in the following, can also be decisive here.
  • Preferred components for (c) are oil-soluble, however biologically compatible organic compounds with fat residues of the type specified, which have at least 6 C atoms and in particular at least 8 C atoms.
  • the use of appropriate components based on straight-chain hydrocarbon residues or KW compounds is preferred.
  • Corresponding components that are at least predominantly based on natural substances are of particular importance.
  • Particularly important representatives of the substance class for (c) mentioned here are corresponding hydrocarbon compounds which are at least partially functionalized with oxygen as a hetero atom.
  • Typical examples of components of this type are fatty alcohols and / or fatty acids or their derivatives and / or salts.
  • Suitable fatty alcohol or fatty acid derivatives are their esters, ethers and / or amides.
  • particular importance is attached to the fatty alcohols and the esters of fatty acids with monofunctional and / or polyfunctional alcohols.
  • the term “fatty acid esters” includes both the voile esters and the partial esters when using multifunctional alcohols.
  • Fatty alcohols, partial esters of in particular lower polyfunctional alcohols - for example glycerol - and fatty acids and in particular their mixtures fulfill this task.
  • they are the C suppliers desired according to the invention for stimulating and increasing the growth of microorganisms and thus optimal representatives for the components of (c) in the sense of the definition according to the invention.
  • aqueous APG concentrates with defoamers / foam brakes on an alcohol basis and / or on the basis of partial esters of fatty acids and polyhydric alcohols, especially glycerol, can lead to the formation of gels which are no longer flowable.
  • limited amounts of lower mono- and / or polyfunctional alcohols e.g. by adding limited amounts of ethanol and / or glycerin to the gel-like thickened material concentrate, it will then be possible to ensure the flowability and pourability again even in the area of room temperature.
  • mixture component (c) The valuable substances or mixtures of substances to be used in the specific individual case as mixture component (c) are thus determined in preferred embodiments not only by considerations for optimizing this component as a carbon supplier for the growth of microorganisms. Secondary effects such as low foam of the aqueous multicomponent mixture, homogenization of the lipophilic components together with wetting agents of the O / W type in the aqueous phase-containing multicomponent mixture and applicability in the sense of dilution with further water and subsequent application by pouring and / or spraying can be decisive.
  • DE 19701127 deals in particular with these aspects.
  • the subject matter of this publication is hereby expressly made the subject of the present disclosure of the invention.
  • Suitable components are here, for example, olefinically unsaturated C ⁇ 2 - 2 - fatty alcohols of natural origin, more particularly at least predominantly C16 / 18 fatty alcohols with a high degree of olefinic double bonds and solidification ranges equal to / less than 20 ° C, preferably equal to / less than 10 to 15 ° C.
  • Preferred multicomponent mixtures for this constituent (c) in the sense of the definition according to the invention are mixtures of fatty alcohols with partial esters of saturated and in particular at least partially olefinically unsaturated fatty acids with polyfunctional alcohols with 2 to 6 C atoms and in particular 3 to 5 C atoms.
  • glycerol partial esters of fatty acids of natural origin can be important mixture components for blending with corresponding fatty alcohols, preferred embodiments being about equal amounts of fatty alcohol and fatty acid partial esters or corresponding substance mixtures with a multiple of the partial ester, based on the fatty alcohol.
  • Suitable mixtures of fatty alcohol to fatty acid partial glyceride are, for example, in the range from about 1: 1 to 1:10, preferably 1: 1 to 1: 5 and in particular from about 1: 1 to 1: 3 parts by weight.
  • fatty acid partial esters can also be used alone as component ⁇ ) to (c).
  • Further preferred components for (c) are, for example, soaps, but also biodegradable alkyl sulfates, in particular fatty alcohol sulfates.
  • the use of soaps is particularly preferred.
  • the soaps are generally known compounds, with potassium soaps of fatty acids having 6 to 18 and preferably 8 to 14 carbon atoms being preferred in the context of the present technical teaching.
  • the teaching of the invention provides for preferably additionally using selected valuable substances or mixtures of valuable substances which contain phosphorus and / or nitrogen. Components that are carriers of these two elements can be preferred representatives of this class of substances.
  • this valuable component (s) to (d) can take place simultaneously and in connection with the application of the valuable materials to (c) and the ecologically compatible wetting agents used to (a).
  • oil-soluble compounds of P and / or N are used as component (d) which has at least some lipophilic residues.
  • Particularly preferred representatives of these auxiliaries are therefore the phospholipids described in DE 44 37 313 and / or their derivatives as essential representatives of these components to (d).
  • the subject matter of the disclosure of this DE 44 37 313 is hereby also expressly made the subject of the disclosure within the framework of the teaching according to the invention, so that essential aspects are only emphasized below in part. It is already pointed out in this publication that the effect of the added phospholipids on the microbial soil flora manifests itself, inter alia, in the fact that organic compounds and plant residues present in the soil are broken down more quickly, with an increase in soil bacteria.
  • the lipophilic and flowable components for (c) are now preferably provided as carbon suppliers for the growth of microorganisms.
  • Lipophilic molecular parts of the components acc. (d) associate with the lipophilic residues of the hydrocarbon type from the C suppliers to (c) in the sense of the teaching according to the invention.
  • the microorganism strains of the diverse populations, which promote healthy plant growth, are mobilized and strengthened in an unforeseeable way.
  • Preferred components for material class (d) are esters of phosphoric acid with 1- and / or polyhydric alcohols, which have lipophilic residues in their molecular structure.
  • Suitable phosphoric acid esters in this sense are accordingly partial esters of fatty alcohols, which enter the required lipophilic portion into the phosphoric acid ester molecule via the hydrocarbon residue of the fatty alcohol.
  • Partial esters of phosphoric acid with straight-chain fatty alcohols which have preferably been prepared at least to a substantial extent using C 6 -oo fatty alcohols and / or their lower ethoxylates, can be particularly suitable here.
  • the phosphoric acid esters of higher fatty alcohols with, for example, 12 to 24 carbon atoms are also suitable, with particular importance being attached to olefinically unsaturated fatty alcohol residues.
  • Particularly preferred phosphoric acid esters for the subclass (d) are phospholipids and phospholipid derivatives. As is known, these are amphiphilic substances that are obtained from plant or animal cells. Preferred phospholipids in the sense of the teaching according to the invention are corresponding compounds of plant origin or phospholipid derivatives obtained therefrom. A particularly preferred representative of this class of substances for (b) are Glycerophospholip.de, which are usually also referred to as lecithin. The sphingophospholipids are less preferred.
  • diacylphospholip.de phosphatidylcholines, phosphatidylethanolamines, phosphatidylinositols, phosphatidylserines, phosphatidylglycerols, phosphatidylglycerol phosphates, diphosphatidylglycerol, N-acylphosphate idylethanolamine and phosphatidic acid amine.
  • the phosphatidylglycerides which are commercially available as vegetable or animal lecithins and zephalins, are technically accessible and available in large quantities.
  • compositions are obtained, for example, from oils such as corn oil or cottonseed oil or soybean oil.
  • Components according to the invention for subclass (d) can be enzymatically hydrolyzed glycerophospholipids (enzymatically hydrolyzed lecithin) which have a more hydrophilic character due to the elimination of a fatty acid ester. The only exceptions are products that have lost their phosphoric acid residue due to the enzymatic hydrolysis.
  • Preferred components for (d) are lecithin, lecithin hydrolyzates and / or chemically modified lecithins. These compounds can also be used in a mixture with other N-containing components, urea and / or urea derivatives in particular being preferred here. Further examples of such additional components are amino alcohols such as ethanolamine and related compounds.
  • the teaching according to the invention provides for a quantity matching of component (s) to (c) to the amounts of P introduced by the mixture component to (d).
  • the source of carbon (c) for the growth of microorganisms is used in such minimum amounts that - based on the phosphorus P introduced via the mixture component (d) - the weight ratio of C: P is at least in the range from about 5 to 10: 1 and preferably is at least about 20 to 25: 1.
  • Important lower limit values are 40: 1 and preferably in the range of at least 50: 1.
  • C: P weight ratios of about 100: 1 to 500: 1 or even more are within the scope of the teaching according to the invention.
  • the amount of component mixtures applied is adjusted so that weight ratios of P: N: C in the range of at least about 1:10: 10 to 1: 10: 100 are set.
  • water-diluted spray liquors are preferred whose contents of the individual components discussed here correspond approximately to the following quantitative ranges - represented as percentages by weight and based on the spray liquor used:
  • 0.01 to 0.1% by weight preferably amounts in the range of approximately 0.05% by weight
  • the corresponding potassium water glass content of the spray liquor preferred according to the invention is in the range from about 0.02 to 0.5% by weight.
  • C source acc. the definition of material class (c): 0.05 to 0.2% by weight, preferably 0.08 to 0.15% by weight.
  • Lecithin as a typical and preferred representative of component (s) for (d): 0.04 to 0.8% by weight.
  • the teaching according to the invention provides for the previously defined multicomponent mixtures according to the invention to be used simultaneously and / or with a time delay together with other, in particular synthetic, crop protection agents.
  • a combination with appropriate fungicides is particularly preferred here.
  • An essential element of the teaching according to the invention can be seen in this context in the following preferred additional teaching:
  • application quantities can be used up to a maximum of 50% to 75%, if necessary, make up a maximum of 20 or 30% of the usual amounts.
  • chitins and / or in particular chitosans are used in admixture with the components of (a), (b), (c) and optionally (d), then amounts of at least 0.05% by weight and in particular amounts of at least 0 are used , 1 to 1 wt .-% - each based on the anhydrous multicomponent mixture - used. It is crucial that even such small amounts of the chitin or chitosan-based components can have a substantial influence on the course of life processes in the soil and in the plant, in particular promoting the growth of healthy microorganism flora and thus plant growth and suppressing the growth of pests becomes.
  • auxiliaries from the field of plant strengthening can be added to the multicomponent mixtures described so far.
  • these antioxidants just like the previously mentioned additives based on chitin or chitosan - stimulate the plant's own immune system as so-called "elicitors", which increases the resistance of the plants treated in this way to the effects of damage.
  • 10-day-old bean seedlings (Phaseolus vulgaris) were separated in cultivation pots with a soil-sand mixture and sprayed with a surfactant potassium water glass solution as a plant-strengthening component.
  • chlorophyll fluorescence was measured 4, 24 and 48 hours after application of the stressor paraquat.
  • chlorophyll fluorescence was measured 24, 48, 72 and 120 hours after application of the botrytis stressor. All measurements were carried out with a fluorescence measuring device with exclusion of light at room temperature.
  • the chlorophyll fluorescence was determined as described in the specialist literature on plants which had been darkly adapted for 30 minutes (for example: (1) Koch, C, G. Noga, G. Strittmatter (1994): Photosynthetic electron transport is differentially affected during early stages of cultivar / Race specific interactions between potato and Phytophthora infestans. Planta 193: 551-557; (2). Schmitz, M., G. Noga (1998); alpha-tocopherol reduced environmental stress and improved fruit quality; Acta Hort. 466: 89-94, ISHS 1998).
  • the intensity of the fluorescence is regarded as a measure of the resistance of the plant, ie the higher the fluorescence, the stronger / healthier the plant.
  • the plants treated with stressor paraquat fluoresced less strongly than the plants not exposed to the stressor.
  • the plants treated with the test substance potassium water glass showed significantly higher fluorescence than the stressed plants. All tested doses of potassium water glass (0.2 to 5.0 g / m 2 ) led to similarly good fluorescence values as the undressed control.
  • the intensity of the fluorescence is taken as a measure of the resistance of the plant, i.e. the higher the fluorescence, the stronger / healthier the plant.
  • the plants treated with the biotic stressor Botrytis cinerea fluoresced less strongly than the plants not exposed to the stressor.
  • the plants treated with the test substance potassium water glass showed significantly higher fluorescence than the stressed plants (Tab. 2).
  • Examples 1 to 3 above show mixtures of water glass and the combination of potassium soaps with APG compounds.
  • Examples 4 to 5 show that the combination with further auxiliaries, here preferably the diglycerides and valuable substances of type (c), are also possible.
  • the diglycerin can act as an emulsion mediator and then, as here in Example 5, make the use of potassium soap unnecessary.

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Inorganic Chemistry (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Cultivation Of Plants (AREA)
EP00922640A 1999-04-26 2000-04-15 Stärkung des wachstums von nutz- und zierpflanzen gegen unerwünschten pilzbefall im oberirdischen pflanzenbereich Withdrawn EP1173063A1 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE19918693A DE19918693A1 (de) 1999-04-26 1999-04-26 Stärkung des Wachstums von Nutz- und Zierpflanzen gegen unerwünschten Pilzbefall im oberirdischen Pflanzenbereich
DE19918693 1999-04-26
PCT/EP2000/003440 WO2000064263A1 (de) 1999-04-26 2000-04-15 Stärkung des wachstums von nutz- und zierpflanzen gegen unerwünschten pilzbefall im oberirdischen pflanzenbereich

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EP1173063A1 true EP1173063A1 (de) 2002-01-23

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EP (1) EP1173063A1 (zh)
JP (1) JP2002542269A (zh)
CN (1) CN1352525A (zh)
AU (1) AU4295900A (zh)
BR (1) BR0010065A (zh)
CO (1) CO5211005A1 (zh)
DE (1) DE19918693A1 (zh)
GT (1) GT200000051A (zh)
TR (1) TR200102949T2 (zh)
WO (1) WO2000064263A1 (zh)

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CN108794176A (zh) * 2018-07-03 2018-11-13 王国华 一种草莓营养粉及其使用方法

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Publication number Priority date Publication date Assignee Title
CN108794176A (zh) * 2018-07-03 2018-11-13 王国华 一种草莓营养粉及其使用方法

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WO2000064263A1 (de) 2000-11-02
TR200102949T2 (tr) 2002-01-21
CO5211005A1 (es) 2002-10-30
CN1352525A (zh) 2002-06-05
AU4295900A (en) 2000-11-10
BR0010065A (pt) 2002-01-15
GT200000051A (es) 2001-10-17
DE19918693A1 (de) 2000-11-02
JP2002542269A (ja) 2002-12-10

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