EP1053291A1 - Procede de gazeification de matieres organiques et de melanges de substances - Google Patents
Procede de gazeification de matieres organiques et de melanges de substancesInfo
- Publication number
- EP1053291A1 EP1053291A1 EP98966829A EP98966829A EP1053291A1 EP 1053291 A1 EP1053291 A1 EP 1053291A1 EP 98966829 A EP98966829 A EP 98966829A EP 98966829 A EP98966829 A EP 98966829A EP 1053291 A1 EP1053291 A1 EP 1053291A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- pyrolysis
- heat transfer
- furnace
- transfer medium
- gases
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims abstract description 42
- 239000000126 substance Substances 0.000 title claims abstract description 31
- 239000000203 mixture Substances 0.000 title claims abstract description 20
- 238000000197 pyrolysis Methods 0.000 claims abstract description 132
- 239000007789 gas Substances 0.000 claims abstract description 98
- 238000006243 chemical reaction Methods 0.000 claims abstract description 47
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000007787 solid Substances 0.000 claims abstract description 14
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 37
- 239000003054 catalyst Substances 0.000 claims description 21
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 12
- 238000002309 gasification Methods 0.000 claims description 8
- 229910052759 nickel Inorganic materials 0.000 claims description 7
- 239000000376 reactant Substances 0.000 claims description 6
- 229910000514 dolomite Inorganic materials 0.000 claims description 4
- 239000010459 dolomite Substances 0.000 claims description 4
- -1 nickel aluminate Chemical class 0.000 claims description 4
- 229910000831 Steel Inorganic materials 0.000 claims description 3
- 239000000567 combustion gas Substances 0.000 claims description 3
- 229910052593 corundum Inorganic materials 0.000 claims description 3
- 239000010431 corundum Substances 0.000 claims description 3
- 229910000480 nickel oxide Inorganic materials 0.000 claims description 3
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 claims description 3
- 239000004576 sand Substances 0.000 claims description 3
- 239000010959 steel Substances 0.000 claims description 3
- 229910021532 Calcite Inorganic materials 0.000 claims description 2
- 239000011149 active material Substances 0.000 claims description 2
- 239000000919 ceramic Substances 0.000 claims description 2
- 229910052878 cordierite Inorganic materials 0.000 claims description 2
- JSKIRARMQDRGJZ-UHFFFAOYSA-N dimagnesium dioxido-bis[(1-oxido-3-oxo-2,4,6,8,9-pentaoxa-1,3-disila-5,7-dialuminabicyclo[3.3.1]nonan-7-yl)oxy]silane Chemical compound [Mg++].[Mg++].[O-][Si]([O-])(O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2)O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2 JSKIRARMQDRGJZ-UHFFFAOYSA-N 0.000 claims description 2
- 239000007769 metal material Substances 0.000 claims description 2
- 238000000465 moulding Methods 0.000 claims description 2
- 239000011044 quartzite Substances 0.000 claims description 2
- 229910052596 spinel Inorganic materials 0.000 claims description 2
- 239000011029 spinel Substances 0.000 claims description 2
- 229910000323 aluminium silicate Inorganic materials 0.000 claims 1
- 239000003153 chemical reaction reagent Substances 0.000 claims 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims 1
- 239000011819 refractory material Substances 0.000 claims 1
- 238000011144 upstream manufacturing Methods 0.000 claims 1
- 238000010304 firing Methods 0.000 abstract description 9
- 239000000571 coke Substances 0.000 description 16
- 239000000463 material Substances 0.000 description 14
- 239000002956 ash Substances 0.000 description 10
- 239000002023 wood Substances 0.000 description 10
- 239000003610 charcoal Substances 0.000 description 8
- 229910001868 water Inorganic materials 0.000 description 8
- 238000004140 cleaning Methods 0.000 description 6
- 239000007858 starting material Substances 0.000 description 6
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 5
- 238000002485 combustion reaction Methods 0.000 description 5
- 230000008878 coupling Effects 0.000 description 5
- 238000010168 coupling process Methods 0.000 description 5
- 238000005859 coupling reaction Methods 0.000 description 5
- 238000001816 cooling Methods 0.000 description 4
- 238000005336 cracking Methods 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 239000011269 tar Substances 0.000 description 4
- 235000002918 Fraxinus excelsior Nutrition 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 239000003546 flue gas Substances 0.000 description 3
- 239000002918 waste heat Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229910002091 carbon monoxide Inorganic materials 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 230000020169 heat generation Effects 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000002028 Biomass Substances 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 241000237858 Gastropoda Species 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000011800 void material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B49/00—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated
- C10B49/16—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with moving solid heat-carriers in divided form
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B57/00—Other carbonising or coking processes; Features of destructive distillation processes in general
- C10B57/18—Modifying the properties of the distillation gases in the oven
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
- C10K3/02—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Combustion & Propulsion (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Processing Of Solid Wastes (AREA)
- Industrial Gases (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Gasification And Melting Of Waste (AREA)
Abstract
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19755693 | 1997-12-16 | ||
DE19755693A DE19755693C1 (de) | 1997-12-16 | 1997-12-16 | Verfahren zur Vergasung von organischen Stoffen und Stoffgemischen |
PCT/EP1998/008217 WO1999031197A1 (fr) | 1997-12-16 | 1998-12-15 | Procede de gazeification de matieres organiques et de melanges de substances |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1053291A1 true EP1053291A1 (fr) | 2000-11-22 |
EP1053291B1 EP1053291B1 (fr) | 2003-07-09 |
Family
ID=7851970
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP98966829A Expired - Lifetime EP1053291B1 (fr) | 1997-12-16 | 1998-12-15 | Procede de gazeification de matieres organiques et de melanges de substances |
Country Status (11)
Country | Link |
---|---|
EP (1) | EP1053291B1 (fr) |
JP (1) | JP2002508433A (fr) |
AT (1) | ATE244746T1 (fr) |
AU (1) | AU2513399A (fr) |
BG (1) | BG104615A (fr) |
CA (1) | CA2314094A1 (fr) |
DE (2) | DE19755693C1 (fr) |
HU (1) | HUP0101001A3 (fr) |
PL (1) | PL341225A1 (fr) |
TR (1) | TR200001777T2 (fr) |
WO (1) | WO1999031197A1 (fr) |
Families Citing this family (28)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19930071C2 (de) * | 1999-06-30 | 2001-09-27 | Wolfgang Krumm | Verfahren und Vorrichtung zur Pyrolyse und Vergasung von organischen Stoffen und Stoffgemischen |
DE19945771C1 (de) * | 1999-09-24 | 2001-02-22 | Muehlen Gmbh & Co Kg Dr | Verfahren zur Vergasung von organischen Stoffen und Stoffgemischen |
DE19946381C2 (de) * | 1999-09-28 | 2001-09-06 | Zsw | Verfahren und Vorrichtung zur Erzeugung eines kohlendioxidarmen, wasserstoffreichen Gases oder eines konditionierten Synthesegases und Verwendung derselben |
DE19956560C2 (de) * | 1999-11-24 | 2003-05-22 | Bodo Wolf | Verfahren zur Erzeugung von erneuerbaren Brenn- und Kraftstoffen |
DE10033453B4 (de) * | 2000-07-10 | 2006-11-02 | Herhof Verwaltungsgesellschaft Mbh | Verfahren und Vorrichtung zur Verwertung von Stoffen und Stoffgemischen, die organische Bestandteile enthalten |
DE10055360B4 (de) * | 2000-11-08 | 2004-07-29 | Mühlen, Heinz-Jürgen, Dr.rer.Nat. | Verfahren zur Vergasung von flüssigen bis pastösen organischen Stoffen und Stoffgemischen |
EP1399527B1 (fr) * | 2001-06-27 | 2013-02-20 | Herhof Verwaltungsgesellschaft mbH | Procede et dispositif pour pyrolyser et gazeifier des melanges de matieres a composants organiques |
DE10228100B4 (de) * | 2001-06-27 | 2008-04-03 | Herhof Verwaltungsgesellschaft Mbh | Verfahren und Vorrichtung zur Pyrolyse und Vergasung von Stoffgemischen, die organische Bestandteile enthalten |
JP2005247930A (ja) * | 2004-03-02 | 2005-09-15 | Takuma Co Ltd | ガス化システム、発電システム、ガス化方法および発電方法 |
DE102005005859B3 (de) * | 2005-02-09 | 2006-09-28 | Peter Oehler | Verfahren und Vorrichtung zur thermischen Behandlung von Biomasse |
JP2006225483A (ja) * | 2005-02-16 | 2006-08-31 | Nippon Steel Corp | バイオマスの炭化方法 |
JP4682027B2 (ja) * | 2005-11-25 | 2011-05-11 | 株式会社キンセイ産業 | 燃料ガス発生装置 |
JP2007169534A (ja) * | 2005-12-26 | 2007-07-05 | Ube Machinery Corporation Ltd | バイオマス炭化装置 |
DE102007005799B4 (de) * | 2006-10-18 | 2018-01-25 | Heinz-Jürgen Mühlen | Verfahren zur Erzeugung eines wasserstoffreichen Produktgases |
DE102007062413B3 (de) * | 2007-12-20 | 2009-09-10 | Conera Process Solutions Gmbh | Verfahren und Vorrichtung zur Wiederaufbereitung von CO2-haltigen Abgasen |
DE102007062414B4 (de) | 2007-12-20 | 2009-12-24 | Ecoloop Gmbh | Autothermes Verfahren zur kontinuierlichen Vergasung von kohlenstoffreichen Substanzen |
GR20080100647A (el) * | 2008-10-06 | 2010-05-13 | Διονυσιος Χαραλαμπους Χοϊδας | Συσκευη θερμικης αποδομησης ενυδρων ανθρακουχων συμπυκνωματων |
EP2233551B1 (fr) | 2009-03-26 | 2012-02-01 | Marold, Freimut Joachim | Procédé et dispositif de gazage de matériaux organiques |
RU2011153516A (ru) | 2009-05-28 | 2013-07-10 | ТАННХОЙЗЕР ГЁЛЬ Айпи АГ | Процесс получения энергии из органических материалов и/или биомассы |
JP5512200B2 (ja) * | 2009-09-01 | 2014-06-04 | 新日鉄住金エンジニアリング株式会社 | 高効率乾留炉およびガス化剤の調整方法 |
EP2655552A1 (fr) * | 2010-12-20 | 2013-10-30 | Thannhaueser Goel IP AG | Procédé de pyrolyse d'une matière d'alimentation organique |
JP5756231B2 (ja) | 2012-05-18 | 2015-07-29 | 株式会社ジャパンブルーエナジー | バイオマスのガス化装置 |
DE102012025478A1 (de) | 2012-12-29 | 2014-07-03 | Robert Völkl | Verfahren und Vorrichtung zur Verwertung kohlenstoffhaltiger Asche |
CN103468322B (zh) * | 2013-07-25 | 2015-08-12 | 易高环保能源研究院有限公司 | 一种由固体有机物水蒸气气化制取富氢气体的方法 |
CN103438458A (zh) * | 2013-08-21 | 2013-12-11 | 陈开宇 | 新型垃圾焚烧炉 |
CN106085481A (zh) * | 2016-08-11 | 2016-11-09 | 北京神雾环境能源科技集团股份有限公司 | 一种煤热解反应器与气基竖炉联用系统及处理煤的方法 |
DE102017106347A1 (de) * | 2017-03-24 | 2018-09-27 | Universität Stuttgart | Verfahren und Vorrichtung zur allothermen Herstellung von Brenngasen |
DE102021134442B4 (de) | 2021-12-23 | 2023-07-06 | Concord Blue Patent Gmbh | Anlage zur Erzeugung eines Synthesegases und Verfahren zum Betreiben derselben |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE960892C (de) * | 1951-03-25 | 1957-03-28 | Ruhrgas Ag | Verfahren zur thermischen Behandlung feinkoerniger bis staubfoermiger, insbesondere backender Kohlen |
US4142867A (en) * | 1974-07-04 | 1979-03-06 | Karl Kiener | Apparatus for the production of combustible gas |
DE2537732C3 (de) * | 1975-08-25 | 1981-12-10 | Gosudarstvennyj naučno-issledovatel'skij energetičeskij institut imeni G.M. Kržižanovskogo, Moskva | Verfahren zur thermischen Verarbeitung von festen bituminösen Stoffen |
FR2426079A1 (fr) * | 1978-05-17 | 1979-12-14 | Charlier Etienne | Procede et installation pour la production de gaz pauvre combustible |
FR2535734B1 (fr) * | 1982-11-05 | 1986-08-08 | Tunzini Nessi Entreprises Equi | Procede de gazeification de produits ligno-cellulosiques et dispositif pour sa mise en oeuvre |
DE3611429A1 (de) * | 1985-02-15 | 1986-11-06 | SKF Steel Engineering AB, Hofors | Verfahren zur abfallzersetzung |
EP0271477A1 (fr) * | 1986-11-26 | 1988-06-15 | VOEST-ALPINE Aktiengesellschaft | Dispositif pour le dégazage et la gazéification de combustible solide |
IT1248156B (it) * | 1991-05-08 | 1995-01-05 | Daneco Danieli Ecologia Spa | Procedimento di conversione del combustibile derivato dai rifiuti (rdf) in gas combustibile. |
-
1997
- 1997-12-16 DE DE19755693A patent/DE19755693C1/de not_active Expired - Fee Related
-
1998
- 1998-12-15 AU AU25133/99A patent/AU2513399A/en not_active Abandoned
- 1998-12-15 DE DE59809004T patent/DE59809004D1/de not_active Expired - Fee Related
- 1998-12-15 WO PCT/EP1998/008217 patent/WO1999031197A1/fr active IP Right Grant
- 1998-12-15 CA CA002314094A patent/CA2314094A1/fr not_active Abandoned
- 1998-12-15 TR TR2000/01777T patent/TR200001777T2/xx unknown
- 1998-12-15 HU HU0101001A patent/HUP0101001A3/hu unknown
- 1998-12-15 JP JP2000539104A patent/JP2002508433A/ja active Pending
- 1998-12-15 PL PL98341225A patent/PL341225A1/xx unknown
- 1998-12-15 AT AT98966829T patent/ATE244746T1/de not_active IP Right Cessation
- 1998-12-15 EP EP98966829A patent/EP1053291B1/fr not_active Expired - Lifetime
-
2000
- 2000-07-14 BG BG104615A patent/BG104615A/xx unknown
Non-Patent Citations (1)
Title |
---|
See references of WO9931197A1 * |
Also Published As
Publication number | Publication date |
---|---|
HUP0101001A2 (hu) | 2001-09-28 |
ATE244746T1 (de) | 2003-07-15 |
WO1999031197A1 (fr) | 1999-06-24 |
BG104615A (en) | 2001-03-30 |
PL341225A1 (en) | 2001-03-26 |
EP1053291B1 (fr) | 2003-07-09 |
AU2513399A (en) | 1999-07-05 |
HUP0101001A3 (en) | 2002-10-28 |
DE19755693C1 (de) | 1999-07-29 |
DE59809004D1 (de) | 2003-08-14 |
TR200001777T2 (tr) | 2000-09-21 |
JP2002508433A (ja) | 2002-03-19 |
CA2314094A1 (fr) | 1999-06-24 |
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