EP1051880B1 - Vis transporteuse chauffante - Google Patents
Vis transporteuse chauffante Download PDFInfo
- Publication number
- EP1051880B1 EP1051880B1 EP99901663A EP99901663A EP1051880B1 EP 1051880 B1 EP1051880 B1 EP 1051880B1 EP 99901663 A EP99901663 A EP 99901663A EP 99901663 A EP99901663 A EP 99901663A EP 1051880 B1 EP1051880 B1 EP 1051880B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- transfer member
- shaft
- transfer
- helical portion
- insulating material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Images
Classifications
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B3/00—Ohmic-resistance heating
- H05B3/40—Heating elements having the shape of rods or tubes
Definitions
- the present invention relates to a device for transfer and heat treatment of divided solids such as powdery materials.
- Transfer and processing devices thermal commonly used in industry include a transfer member and a heating treatment means thermal.
- the transfer is a vibrating tubular envelope receiving the divided solids.
- the heat treatment is then ensured by heating the tubular casing.
- Such devices are difficult to implement and are relatively expensive.
- a second type of device comprising at least one transfer member having an axis longitudinal and a helical part, mounted to rotate around its longitudinal axis in a tubular envelope and connected to an output shaft of a drive motor in rotation in accordance with the preamble of claim 1.
- the heating means is then constituted either by the envelope (then formed of a double envelope to make circulate a heat transfer fluid, or externally equipped heating resistors), either by a tube, around from which the propeller winds, said tube being traversed by a fluid brought to a high temperature.
- heating means consists of the envelope is for example illustrated by document US-A-3 589 834.
- This document describes a mixing device for food products, including a brewing member received in an enclosure intended to contain the products to mix and process, and a heating process thermal.
- the brewing member includes a tree around from which a propeller is wound, including an outer surface supports a heating tape (see figures 4 to 6), which heating tape includes electrically conductive wire zigzag embedded in a thin layer of material dielectric.
- the heating means consists of a hollow tube traversed by a fluid brought to a high temperature is for example illustrated by the document WO-A-92/19372.
- This document describes a transfer device comprising two transfer members formed by a shaft hollow around which a propeller winds, and heating resistors are arranged inside each hollow shaft to provide heating for the entire transfer member.
- the object of the invention is to remedy the drawbacks mentioned above by designing a more efficient device.
- a device for transferring and heat treatment of divided solids of the aforementioned type in which at least the helical part of the organ of transfer is formed in its mass of a material electrically conductive, and the transfer device includes means for connection to a power source in electrical energy to constitute itself the heating medium, in accordance with the characterizing part of claim 1.
- the heating means consists of the transfer organ in contact with which the divided solids are mostly brought during their transfer.
- the all or almost all of the divided solids will therefore heat directly in contact with the heating medium, and without parking against the heating surface.
- the heating of the divided solids is thus achieved so uniform and the browning problems are practically deleted.
- the structure of the device is simple, so that its manufacturing cost remains low.
- the part helical transfer member includes a flat ribbon wound in a helix.
- the part helical is formed by a helix winding around a tree, the tree then being made of insulating material or formed less on its outer surface of an electrically material driver.
- the electrically conductive material is a metal such as stainless steel.
- the tubular envelope is made of electrically insulating material. Thanks to this measure the risk of short circuits entered the organ transfer and the tubular casing are eliminated, same as the risk of electric shock to people by contact with the tubular casing. Device security is thus reinforced.
- the tubular envelope is covered at least partially of an internal lining of friction of insulating material to form a support for the helical part.
- the friction lining supports the helical part so as to prevent the helical part flexes during product transfer.
- the friction lining electrically insulates the helical part of the tubular casing, which can then be made of a conductive material. The risks of short circuits are then limited.
- the device comprises a coupling seal made of electrically insulating material connecting the transfer member to the output shaft of the engine.
- the motor is thus isolated from the organ of transfer. The security of the device is thus still improved.
- the transfer and heat treatment according to the invention comprises a tubular casing 1, open at the top, comprising, at its respective ends, a conduit inlet and outlet duct for the product to be transferred (not shown here).
- the tubular casing 1 is here made of an electrically insulating material such as plastic material.
- the envelope tubular 1 arranged with an open sky, the envelope tubular 1 could also be arranged in the form of a complete cylinder (closed sky).
- a transfer body generally designated in 2 is mounted in the tubular casing 1 to turn around of its longitudinal axis 3.
- the transfer member 2 has a form part helical 4 formed by a flat ribbon, here of section rectangular, wrapped around a tree 5 and held spaced from it by 6 spacers distributed along of the tree 5.
- the helical part 4 is made in its mass in a material electrically conductive, for example stainless steel.
- the shaft 5 is here made of insulating material and is mounted to pivot in the tubular casing 1 by through two end portions 7 and 8 made of electrically conductive material and received in bearings not visible in Figures 1 and 2.
- the helical part 4 is electrically connected to the portions ends 7 and 8 by plates 9 of conductive material integral with the end portions 7 and 8.
- the end portion 7 is associated with a drum 10 of electrically conductive material on which rub coals 11 of electric current supply connected by conductive wires to a power source in electrical energy (not shown)
- the portion end 8 is itself associated with a drum, not shown, made of electrically conductive material on which rub rubbing evacuation coals Electric power.
- the shaft 5 is made of material electrically conductive but be isolated from the portions ends 7 and 8 and the helical part 4.
- the power source will be sized in particular according to the dimensional characteristics and electrical resistance of the transfer member.
- the voltage delivered, continuously or in alternative will be less than 100 volts for reasons of security.
- Means of connection to the power source could be, instead of coals, conductive rings, or conductive brushes rubbing on the outer surface of the drums, or even a swivel connection fitting mounted on one end of the transfer member 2.
- the drum 10 is connected to a drive motor in rotation 12 by means of a coupling joint 13.
- the coupling joint 13 is preferably made of insulating material.
- the coupling seal 13 can thus ensure, in addition to an insulation function of the motor of the transfer member, a catch-up function misalignments between the output shaft and the end of the transfer member and / or a function elastic damping.
- drum 10 and the coupling assembly the engine is housed in a compartment isolated from the tubular casing 1. Safety of the device is thus optimal.
- the transfer member 2 is driven in rotation by the motor 12.
- An electric current, brought from the power source via coals 11, drum 10, end portion 7 and plate 9, is led to the helical part 4 of the transfer member 2 which it traverses, causing thus its heating by Joule effect.
- the divided solids to be treated are introduced in the tubular casing 1 by the inlet duct (here on the motor side) and are driven by the helical part 4 to the outlet pipe (at the opposite end). Simultaneously, the divided solids are heated during along their transfer in direct contact with the surface external of the helical part 4. Due to the rotation of the helical part 4 and of the induced movements of the divided solids, divided solids will mostly be brought into contact with the helical part heated for their transfer. The heating of the divided solids is thus very efficient and uniform for all or almost all divided solids.
- the device according to the second embodiment is identical to the device of the first mode of previously described embodiment, except for the helical part 4 which is here self-supporting (none support shaft is not provided).
- the structure of the organ of transfer is then particularly simple and is more particularly suitable for transfers on reduced distances.
- the filling of friction 14 will be placed opposite the middle part of the helical part which is the area of the part helical with the largest arrow in case sagging.
- the friction lining 14 is advantageously made of an insulating material such as polytetrafluoroethylene, which allows on the one hand to isolate electrically the helical part 4 of the envelope tubular 1 which can then be made of a material conductor, and secondly to have a trim of friction having a low coefficient of friction.
- the material used may also be ceramic or mica.
- the flat ribbon forming the helical part 4 will have a rounded section, without sharp edges, like a oval section.
- the transfer member 2 of the device comprises a tubular shaft 5 having the longitudinal axis 3.
- a propeller 4 of the Archimedes screw type wraps around the tubular shaft 5.
- tubular shaft 5 and the propeller 4 are in this case made of a single piece of material electrically conductive, here stainless steel. Propeller 4 can also be reported on tree 5.
- the transfer member 2 is intended, as previously, to be mounted rotating in an envelope tubular, preferably of material electrically insulator, by means of bearings receiving the ends of the tubular shaft 5, and to be connected by collecting means, such as drums on which rub coals associated with a food source electric.
- the cross section of the tubular shaft 5 is determined to be less than that of the cross section, in this case rectangular, of the propeller 4 so that the current brought to one end of the shaft 5 preferably passes throughout the mass propeller 4. Any other way to increase the resistance of the shaft compared to that of the propeller can of course be used.
- FIG. 6 we may use two transfer members 2 arranged side by side side by side in a common tubular envelope 1 delimiting troughs. It is thus possible to increase considerably the exchange surfaces for the same length of transfer.
- the transfer members 2 are here spaced one on the other but could alternatively be nested.
- the trees 5 are shown here full but may well heard to be tubular.
- the transfer members 2 are electrically connected to each other so that the electric current flows along these two organs.
- a friction pad may be provided in all embodiments described above, this lining extending over all or part of the tubular casing.
Landscapes
- Screw Conveyors (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Processing Of Solid Wastes (AREA)
- Fish Paste Products (AREA)
- Resistance Heating (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
- Forging (AREA)
- Tunnel Furnaces (AREA)
- General Induction Heating (AREA)
- Seal Device For Vehicle (AREA)
Description
- la figure 1 est une vue partielle en perspective, du côté du moteur d'entraínement, d'un dispositif de transfert et de traitement thermique selon un premier mode de réalisation,
- la figure 2 est une vue analogue à la figure 1, d'un côté opposé au moteur, de l'organe de transfert du dispositif selon le premier mode de réalisation,
- la figure 3 est une vue partielle en perspective avec écorché d'un dispositif de transfert et de traitement thermique selon un deuxième mode de réalisation,
- la figure 4 est une vue partielle en coupe transversale d'une variante du deuxième mode de réalisation,
- la figure 5 est une vue en perspective de l'organe de transfert d'un dispositif selon un troisième mode de réalisation,
- la figure 6 est une vue en coupe transversale d'une variante du troisième mode de réalisation.
Claims (10)
- Dispositif de transfert et de traitement thermique de solides divisés, comprenant au moins un organe de transfert (2) ayant un axe longitudinal (3) et une partie hélicoïdale (4), monté pour tourner autour de son axe longitudinal dans une enveloppe tubulaire (1) et relié à un arbre de sortie d'un moteur d'entraínement en rotation, le dispositif comprenant en outre un moyen chauffant de traitement thermique, caractérisé en ce qu'au moins la partie hélicoïdale (4) de l'organe de transfert (2) est formée dans sa masse d'un matériau électriquement conducteur, et en ce que l'organe de transfert (2) comprend des moyens de connexion (11) à une source d'alimentation en énergie électrique pour constituer lui-même le moyen chauffant.
- Dispositif selon la revendication 1, caractérisé en ce que la partie hélicoïdale (4) de l'organe de transfert (2) comprend un ruban plat enroulé en hélice.
- Dispositif selon la revendication 2, caractérisé en ce que le ruban plat (4) présente une section arrondie.
- Dispositif selon la revendication 2, caractérisé en ce que la partie hélicoïdale est formée d'une hélice (4) s'enroulant autour d'un arbre (5).
- Dispositif selon la revendication 4, caractérisé en ce que l'arbre (5) est en matériau électriquement isolant.
- Dispositif selon la revendication 4, caractérisé en ce que l'arbre (5) est formé au moins sur sa surface extérieure d'un matériau électriquement conducteur.
- Dispositif selon l'une quelconque des revendications précédentes, caractérisé en ce que le matériau électriquement conducteur est un métal tel que l'acier inoxydable.
- Dispositif selon l'une quelconque des revendications précédentes, caractérisé en ce que l'enveloppe tubulaire (1) est constituée d'un matériau isolant électriquement
- Dispositif selon l'une des revendications précédentes, caractérisé en ce que l'enveloppe tubulaire (1) est recouverte au moins partiellement d'une garniture interne de frottement (14) en matériau isolant pour former un appui pour la partie hélicoïdale (4).
- Dispositif selon l'une quelconque des revendications précédentes, caractérisé en ce qu'il comprend un joint d'accouplement (13) en matériau électriquement isolant reliant l'organe de transfert (2) à l'arbre de sortie du moteur (12).
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9801046 | 1998-01-30 | ||
| FR9801046A FR2774545B1 (fr) | 1998-01-30 | 1998-01-30 | Dispositif de transfert et de traitement thermique de solides divises |
| PCT/FR1999/000188 WO1999039549A1 (fr) | 1998-01-30 | 1999-01-29 | Vis transporteuse chauffante |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP1051880A1 EP1051880A1 (fr) | 2000-11-15 |
| EP1051880B1 true EP1051880B1 (fr) | 2003-07-02 |
Family
ID=9522376
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP99901663A Expired - Lifetime EP1051880B1 (fr) | 1998-01-30 | 1999-01-29 | Vis transporteuse chauffante |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US6375345B1 (fr) |
| EP (1) | EP1051880B1 (fr) |
| JP (1) | JP3455518B2 (fr) |
| CN (1) | CN1144504C (fr) |
| AT (1) | ATE244497T1 (fr) |
| AU (1) | AU2169099A (fr) |
| CA (1) | CA2319031C (fr) |
| DE (1) | DE69909245T2 (fr) |
| ES (1) | ES2203064T3 (fr) |
| FR (1) | FR2774545B1 (fr) |
| WO (1) | WO1999039549A1 (fr) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2023237230A1 (fr) | 2022-06-08 | 2023-12-14 | Knauf Gips Kg | Extrudeuse pour la production d'articles moulés en gypse, procédé de fabrication d'articles à base de gypse et articles à base de gypse |
| EP4751790A1 (fr) * | 2024-10-31 | 2026-06-03 | Meci Tech, Sociedad Limitada | Système d'extraction d'eau et/ou de solvant et procédé d'extraction d'eau et/ou de solvant utilisant un tel système |
Families Citing this family (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2840676B1 (fr) | 2002-06-05 | 2005-01-28 | E T I A Evaluation Technologiq | Procede de traitement thermique en continu de solides divises, et dispositif de mise en oeuvre dudit procede |
| FR2888724B1 (fr) * | 2005-07-20 | 2007-09-28 | Panzani Soc Par Actions Simpli | Procede de traitement de graines cereales entieres decortiquees, et dispositif de mise en oeuvre dudit procede |
| FR2892888B1 (fr) * | 2005-10-27 | 2008-01-04 | E T I A Evaluation Technologiq | Dispositif de traitement de solides divises |
| FR2945294B1 (fr) * | 2009-05-07 | 2012-04-20 | Olivier Lepez | Procede et installation de densification energetique d'un produit sous forme de solides divises, en vue de l'obtention d'huiles pyrolytiques a vocation energetique |
| FR2955029B1 (fr) * | 2010-01-08 | 2012-03-30 | E T I A Evaluation Technologique Ingenierie Et Applic | Procede de traitement de produits sous forme de solides divises en vue de leur debacterisation thermique, et installation de mise en oeuvre dudit procede |
| US9486774B2 (en) | 2011-03-23 | 2016-11-08 | Institut De Recherche Et De Developpement En Agroenvironnement Inc. (Irda) | System and process for thermochemical treatment of matter containing organic compounds |
| CN102424251A (zh) * | 2011-08-17 | 2012-04-25 | 无锡市彩云机械设备有限公司 | 一种空心绞龙叶片 |
| FR2995986A1 (fr) * | 2012-09-21 | 2014-03-28 | E T I A Evaluation Technologique Ingenierie Et Applic | Dispositif de traitement thermique d'un produit |
| JP6307789B2 (ja) * | 2013-01-07 | 2018-04-11 | 東レ株式会社 | 糖液の製造装置及び糖液の製造方法 |
| JP5547320B1 (ja) * | 2013-03-19 | 2014-07-09 | 第一施設工業株式会社 | 搬送装置 |
| FR3020353B1 (fr) | 2014-04-24 | 2016-05-27 | E T I A - Evaluation Tech Ingenierie Et Applications | Dispositif de traitement thermique a vis comprenant une bande electriquement isolante |
| RU2561620C1 (ru) * | 2014-06-10 | 2015-08-27 | Евгений Сергеевич Ляховский | Трубчатый электронагреватель |
| CN104129608A (zh) * | 2014-07-15 | 2014-11-05 | 湖州大周高分子材料有限公司 | 粉料传输加热装置及传输加热方法 |
| FR3037130B1 (fr) * | 2015-06-05 | 2017-06-16 | Lepez Conseils Finance Innovations Lcfi | Four de craquage |
| JP6834960B2 (ja) * | 2015-08-26 | 2021-02-24 | 株式会社サタケ | 過熱蒸気殺菌装置 |
| WO2017131517A1 (fr) | 2016-01-28 | 2017-08-03 | Next Renewable Group B.V. | Procédé de production de combustible gazeux, matériau de départ et serre |
| CA3039727C (fr) * | 2016-10-18 | 2021-07-20 | E.T.I.A. - Evaluation Technologique, Ingenierie Et Applications | Dispositif de production de dihydrogene, procede de production de dihydrogene a partir d'un tel dispositif et utilisation d'un tel dispositif |
| GB201803905D0 (en) * | 2018-03-12 | 2018-04-25 | British American Tobacco Investments Ltd | Methods for treating tobacco, material, apparatus for treating tobacco material, treated tobacco material and uses thereof |
| FR3081977A1 (fr) * | 2018-05-31 | 2019-12-06 | E.T.I.A. - Evaluation Technologique, Ingenierie Et Applications | Dispositif de traitement thermique a revetement rapporte, revetement et procede correspondants |
| FR3081978B1 (fr) * | 2018-06-01 | 2022-01-07 | E T I A Evaluation Tech Ingenierie Et Applications | Dispositif de traitement thermique a enveloppe refractaire |
| GB201811370D0 (en) * | 2018-07-11 | 2018-08-29 | British American Tobacco Investments Ltd | Methods of treating cut stem tobacco material |
| CN109250404A (zh) * | 2018-10-29 | 2019-01-22 | 天津大学 | 一种安装在余热锅炉下方的耐高温螺旋输送机 |
| FR3101699B1 (fr) * | 2019-10-08 | 2021-09-10 | E T I A Evaluation Tech Ingenierie Et Applications | Dispositif de traitement thermique d’un produit comprenant au moins un élément chauffant et procédé correspondant |
| DE102020121017A1 (de) | 2020-08-10 | 2022-02-10 | Techni Grau Solutions Ltd. | Wärmebehandlungsverfahren zur Wärmebehandlung von festen Lebens- oder Futtermitteln und Wärmebehandlungsvorrichtung zur Durchführung des Verfahrens |
| CN117139344B (zh) * | 2023-09-12 | 2024-04-09 | 四川云华川科技有限公司 | 一种生活垃圾连续化多层热解反应釜 |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE563690C (de) * | 1930-10-19 | 1932-11-10 | I G Farbenindustrie Akt Ges | Ruehrwerksbehaelter mit elektrisch beheiztem Ruehrwerk |
| US2690890A (en) * | 1949-02-25 | 1954-10-05 | Wind Turbine Company | Deicing system for airfoil structures |
| US3109913A (en) * | 1960-09-02 | 1963-11-05 | Jr John E Galajda | Electrically heated mixing device |
| DE1925918A1 (de) * | 1968-05-25 | 1969-12-04 | Wynn Edward Donald | Heizluefter |
| US3589834A (en) * | 1969-04-04 | 1971-06-29 | Dynamics Corp America | Helical blade mixer with heating device |
| DE2256671C2 (de) * | 1972-11-18 | 1973-12-20 | Werner & Pfleiderer, 7000 Stuttgart | Verfahren zum verschleißfesten Auskleiden von Extrudergehäusebohrungen und nach diesem Verfahren hergestellte Verschleißschutzauskleidung |
| US4090054A (en) * | 1976-10-12 | 1978-05-16 | Brown Boveri Corporation | Electrical preheating apparatus |
| GB2175815B (en) * | 1985-05-29 | 1988-03-02 | Electricity Council | Heating and mixing a fluid |
| JPS62234534A (ja) * | 1986-04-04 | 1987-10-14 | Mitsubishi Paper Mills Ltd | 撹拌装置及びそれを用いたゼラチン溶解方法 |
| IT1217923B (it) * | 1988-06-24 | 1990-03-30 | Ugolini Spa | Macchina perfezionata per la produzione di granita |
| GB2246821A (en) * | 1990-08-07 | 1992-02-12 | Electricity Ass Services Ltd | Heated rotor |
| GB9109814D0 (en) * | 1991-05-07 | 1991-06-26 | Christian Engineering | Apparatus for continuously mixing and heating flowable materials |
| GB2262693B (en) * | 1991-12-17 | 1995-06-07 | Electricity Ass Tech | Induction heater |
| DE4412536A1 (de) * | 1994-04-12 | 1995-10-19 | Kloeckner Humboldt Deutz Ag | Vorwärmschnecke |
| US5876117A (en) * | 1997-11-04 | 1999-03-02 | Yueh-Chiao Chen | Agitator |
| US6030112A (en) * | 1998-05-06 | 2000-02-29 | Milek; Robert C. | Slurry batcher mixer |
-
1998
- 1998-01-30 FR FR9801046A patent/FR2774545B1/fr not_active Expired - Fee Related
-
1999
- 1999-01-29 JP JP2000529878A patent/JP3455518B2/ja not_active Expired - Lifetime
- 1999-01-29 EP EP99901663A patent/EP1051880B1/fr not_active Expired - Lifetime
- 1999-01-29 CA CA002319031A patent/CA2319031C/fr not_active Expired - Lifetime
- 1999-01-29 CN CNB998024988A patent/CN1144504C/zh not_active Expired - Lifetime
- 1999-01-29 AT AT99901663T patent/ATE244497T1/de not_active IP Right Cessation
- 1999-01-29 ES ES99901663T patent/ES2203064T3/es not_active Expired - Lifetime
- 1999-01-29 AU AU21690/99A patent/AU2169099A/en not_active Abandoned
- 1999-01-29 US US09/582,214 patent/US6375345B1/en not_active Expired - Lifetime
- 1999-01-29 DE DE69909245T patent/DE69909245T2/de not_active Expired - Lifetime
- 1999-01-29 WO PCT/FR1999/000188 patent/WO1999039549A1/fr not_active Ceased
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2023237230A1 (fr) | 2022-06-08 | 2023-12-14 | Knauf Gips Kg | Extrudeuse pour la production d'articles moulés en gypse, procédé de fabrication d'articles à base de gypse et articles à base de gypse |
| EP4751790A1 (fr) * | 2024-10-31 | 2026-06-03 | Meci Tech, Sociedad Limitada | Système d'extraction d'eau et/ou de solvant et procédé d'extraction d'eau et/ou de solvant utilisant un tel système |
Also Published As
| Publication number | Publication date |
|---|---|
| DE69909245T2 (de) | 2004-04-15 |
| CA2319031A1 (fr) | 1999-08-05 |
| FR2774545B1 (fr) | 2003-05-30 |
| EP1051880A1 (fr) | 2000-11-15 |
| JP3455518B2 (ja) | 2003-10-14 |
| ATE244497T1 (de) | 2003-07-15 |
| FR2774545A1 (fr) | 1999-08-06 |
| US6375345B1 (en) | 2002-04-23 |
| DE69909245D1 (de) | 2003-08-07 |
| ES2203064T3 (es) | 2004-04-01 |
| CN1144504C (zh) | 2004-03-31 |
| AU2169099A (en) | 1999-08-16 |
| CN1289524A (zh) | 2001-03-28 |
| WO1999039549A1 (fr) | 1999-08-05 |
| JP2002501868A (ja) | 2002-01-22 |
| CA2319031C (fr) | 2007-06-12 |
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