EP0993876B1 - Procédé d'application d'un décor coloré sur un substrat - Google Patents

Procédé d'application d'un décor coloré sur un substrat Download PDF

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Publication number
EP0993876B1
EP0993876B1 EP19980119331 EP98119331A EP0993876B1 EP 0993876 B1 EP0993876 B1 EP 0993876B1 EP 19980119331 EP19980119331 EP 19980119331 EP 98119331 A EP98119331 A EP 98119331A EP 0993876 B1 EP0993876 B1 EP 0993876B1
Authority
EP
European Patent Office
Prior art keywords
substrate
coating film
coloured decoration
decoration
gas jet
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP19980119331
Other languages
German (de)
English (en)
Other versions
EP0993876A1 (fr
Inventor
Thomas Dr. Walter
Maximilian Zaher
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bush Industries Inc
Original Assignee
Bush Industries Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bush Industries Inc filed Critical Bush Industries Inc
Priority to EP19980119331 priority Critical patent/EP0993876B1/fr
Priority to ES98119331T priority patent/ES2213248T3/es
Priority to DE59810918T priority patent/DE59810918D1/de
Publication of EP0993876A1 publication Critical patent/EP0993876A1/fr
Application granted granted Critical
Publication of EP0993876B1 publication Critical patent/EP0993876B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
    • B44C1/16—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like
    • B44C1/165—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like for decalcomanias; sheet material therefor
    • B44C1/17—Dry transfer
    • B44C1/1733—Decalcomanias applied under pressure only, e.g. provided with a pressure sensitive adhesive
    • B44C1/1745—Decalcomanias applied under pressure only, e.g. provided with a pressure sensitive adhesive using an intermediate support
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00—Processes for applying liquids or other fluent materials
    • B05D1/28—Processes for applying liquids or other fluent materials performed by transfer from the surfaces of elements carrying the liquid or other fluent material, e.g. brushes, pads, rollers
    • B05D1/286—Processes for applying liquids or other fluent materials performed by transfer from the surfaces of elements carrying the liquid or other fluent material, e.g. brushes, pads, rollers using a temporary backing to which the coating has been applied

Definitions

  • the invention relates to a method for applying a color decoration on a substrate using a carrier with so-called "Release” properties.
  • the following are considered as material for the substrates: Glass, metal, ceramic materials, plastics, wood, Wood materials, textiles and leather.
  • Carriers with "release” properties are known as such (cf. EP 0 573 676 A1).
  • a flat carrier with “release” properties certain papers are particularly considered or also plastic films that glisten on their surface or are prepared that applied under certain conditions Layers of paint or varnish in the manner of a "Peeling off” (like a decal) can be transferred to a substrate are.
  • Carrier with "release” property plastic films such as in particular Polyester films, which have a suitable release layer to achieve the "Release” (Abpell) property.
  • the present invention aims to provide a method of application a color decor on a substrate of the aforementioned Kind so that a primer of the substrate with very good adhesive and masking effect is achieved.
  • the process is to deliver decorated substrates (objects), which show a very good visual impression of the decoration, in particular a deep effect of the coloring, good adhesion the applied layers of paint or varnish with each other and also a high scratch and abrasion resistance of the color decoration covering lacquer layer.
  • the heating of the upper lacquer layer with a Hot gas jet carried out at least in one direction has a dimension (width) that is small compared to the dimension the color decor and the lacquer layer, the lacquer or the Adhesive layer in this direction.
  • the color decor are preferred in all variants of the invention diffusible disperse dyes used, i.e. the color decor has such disperse dyes.
  • the hot gas jet is in the form of a hot gas knife passed over the top layer of paint, in such a way that the temperature of the hot gas jet and a relative movement between the hot gas jet and the substrate are controlled so that essentially only warms the top layer of paint effectively becomes.
  • the paint is a primer paint.
  • the partial crosslinking of the lacquer according to step c) of the first variant the invention is preferably carried out with UV radiation.
  • the hot gas jet on a Temperature at which it causes or at least promotes that dye of the color decoration in the one above it Lacquer layer diffuses.
  • the Dye molecules diffuse different distances, each by molecular weight, in the paint above, what the affects the visual impression of the decoration.
  • the adhesion of the layers to each other and also the mechanical Properties of the applied lacquer and dye layers can according to a further preferred embodiment the invention are promoted in that the hot gas jet the shape of a knife when hitting the top layer of lacquer and has a line over the top layer of lacquer becomes.
  • this technique can be used to precisely target Temperature increase for a certain period of time up to one certain depth of the layers can be achieved without the underlying paint or adhesive layer to the same temperature is increased like the top layer of lacquer on the substrate.
  • a preferred embodiment of the invention is quality the lacquered decoration especially in the edge area promoted in that the linear hot gas jet (in particular Hot air jet) is guided so that it affects the affected Edge or the edge of the substrate with the ones lying on it Edge covering paint and varnish layers detected, so z. B. with a right-angled edge on both surfaces equally acts.
  • the linear hot gas jet in particular Hot air jet
  • Figure 1 shows a carrier 10 with "release” properties.
  • the illustrated embodiment is a polyester film.
  • a color decor 12 is printed on the carrier 10, e.g. B. with Rotary printing or digital printing.
  • the available ones Printing techniques as such are known to those skilled in the art.
  • a first lacquer layer 14 is applied to the color decor 12.
  • a lacquer is chosen which is used as the base lacquer is suitable for the substrate that is ultimately to be decorated, thus the surface structure of the substrate in the desired Way so that good adhesion of all applied Paint and color layers on the substrate is reached '.
  • the paint layer can be transparent or colored.
  • the lacquer layer applied to the bottom of the substrate prefers a base color for the decor above his. If e.g. the decor should be walnut-like, the Basic color of one of the lacquer layers or both lacquer layers be brown.
  • the lacquer layers, especially the lower layer of lacquer on the substrate which promotes adhesion Has properties.
  • the base coat of paint can also be used with regard to the application weight so that unevenness, Cracks, holes etc. in the substrate can be compensated.
  • the base lacquer layer can have adhesive properties, in particular, the base lacquer layer as a whole can be trade a glue.
  • Acrylic lacquer polyurethane lacquer, Polyester paint and the like.
  • water-soluble paints used preferably no paints with Solvent.
  • the paint 14 applied to the color decor 12 is a so-called. Partially crosslinked.
  • a "partial networking" means that the paint has not yet been completely crosslinked will, but only partially, so that later a complete one Networking is made possible.
  • the networking of paints is that Known to those skilled in the art. Networking can e.g. B. with increased Temperatures, especially using infrared radiators be performed. Networking is promoted by so-called hardeners. In the illustrated embodiment, the achievement a subsequent good primer of the to be decorated Substrate and good adhesion of the layers the partial crosslinking of the first lacquer layer 14 with UV radiation 16.
  • the system prepared in this way becomes a carrier 10, color decor layer 12 lying thereon and lying thereon partially cross-linked first lacquer layer 14 on a to be decorated Substrate 18 laid around the lacquer layer 14 and the color decor 12 to transfer to the substrate 18.
  • the paint layer is there 14 directly below on the substrate 18, as shown in FIG. 2 is.
  • the transmission takes place with the one explained at the beginning "Release" technique.
  • the first lacquer layer 14 serves as a primer of the substrate 18.
  • a second lacquer layer 20 is applied.
  • Paint layer 20 can use the types of paint mentioned above find, especially a transparent lacquer or a (light) white colored lacquer.
  • the top coat layer 20 is chosen to be relatively thick, in particular in the range from 40 to 120 ⁇ m, particularly preferably in the range from 60 to 100 ⁇ m. These strengths of the lacquer layer 20 are important for the diffusion of the dye molecules described below.
  • the paint curing is carried out so that essentially both Lacquer layers 14, 20 are fully hardened.
  • the paints can also in aqueous, solvent-based or in 100% form the paint can be applied.
  • Hot air knife used. It is a Hot air jet coming from a nozzle 24 directly onto the top one Lacquer layer 20 is applied. For this purpose, hot air 26 flows through The nozzle 24.
  • the Hot air jet "knife-shaped", d. H. it has the shape of a line, which is perpendicular to the plane of the drawing and is preferred across the entire width of the paint and dye layers as well of the substrate 18 extends.
  • Such a "hot air knife” can corresponding to arrow 28 relative to substrate 18 with those lying thereon Paint and dye layers are moved.
  • Such a "hot air knife" 24, 26 can be used here Process can be used in various ways.
  • First the hot air knife can serve to transfer the Color decorations 12 with the partially crosslinked lacquer layer 14 from the carrier 10 onto the substrate 18 (i.e. the transition from FIG. 1 to FIG 2) to promote.
  • the hot air knife can first of all be used in this process, the support 10 lying on top with the underlying ones Paint and varnish layers 12, 14 against the substrate 18 be pressed. Strokes the hot air knife over the carrier 10, there is a full-area, even system and the partially networked Lacquer is pressed against the substrate 10 and its adhesive effect promoted on the substrate. This makes peeling easier ("Peeling") of the carrier 10.
  • the hot air knife 24, 26 after the electron beam hardening the layers of paint 14, 20.
  • the hot air knife can the temperature of the upper layer of lacquer 20 and the underlying Dye layer 12 can be increased briefly in such a way that a clear temperature gradient from top to bottom is given, d. H. the top lacquer layer 20 is hotter than that bottom paint layer 14. This causes the dye molecules diffuse from the color decor layer 12 into the upper lacquer layer 20.
  • diffusible disperse dyes that depends Color and thus the diffusion rate of the dye in usually depends on the molecular weight. Roughly said z. B.
  • yellow Colors have a typical molecular weight of 200 to 300, red of 250 to 350, blue from 300 to 400 and black from 350 to 500. This has the consequence that in the thermal diffusion described above the light dyes, such as yellow, continue to diffuse than the darker dyes, such as B. blue or black. hereby becomes a 3-dimensional depth effect of the color decoration reached.
  • the above strengths for the top lacquer layer 20 enable this depth effect due to different diffusion distances of the individual dye molecules.
  • the hot air knife mentioned is particularly suitable for this process, because it's a short-term very targeted temperature increase with the temperature gradient mentioned.
  • the temperature the hot air 26 and the speed of the relative movement between nozzle 24 and substrate 18 with those lying thereon Lacquer and dye layers are adjusted so that the above explained effect is achieved.
  • the locally limited Hot air knife enables a brief temperature increase with temperature gradients without immediately being complete even distribution of heating occurs, d. H. without a uniform temperature distribution in the paint and Dye layers sets before the targeted described above Diffusion of the dye molecules into the top layer of lacquer 20 is essentially achieved.
  • the nozzle 24 is shaped so that the hot air jet in the form of an elongated line on the top layer of lacquer 20 hits. This enables in particular a good quality decoration of the substrate 18 in the particularly critical edge area 30.
  • the line-shaped hot air jet (the "Hot air knife") guided obliquely over the edge area 30, see above that a uniform pressure and temperature influence on both edge surfaces is given by the gas jet. It can too several hot air knives at different angles at the same time be used.
  • Figure 3 shows a modification of the embodiment described above of the invention, being instead of the first a layer of glue now lying on the substrate 14a is used.
  • glue can e.g. B.
  • Glue on water or solvent base can be used.

Claims (9)

  1. Procédé pour appliquer un décor en couleur (12) sur un substrat (18), comprenant les étapes suivantes :
    a) application d'un décor en couleur (12) sur un support surfacique (10) à propriété de détachement ;
    b) application d'une laque (14) sur le décor en couleur (12) posé sur le support (10) ;
    c) réticulation partielle de la laque appliquée (14) ;
    d) transmission de la laque réticulée partiellement (14) conjointement avec le décor en couleur (12), depuis le support (10) jusque sur le substrat (18), de sorte que la laque (14) est posée sous le décor en couleur (12) sur le substrat (18) et le support (10) est enlevé du décor en couleur (12) ;
    e) application d'une couche de laque supérieure (20) sur le décor en couleur (12) transmis sur le substrat (18) ; et
    f) durcissement intégral de la laque (14) et de la couche de laque (20) ;
    caractérisé en ce que :
    g) un durcissement par faisceau électronique (22) est exécuté pour durcir la couche de laque supérieure (20) ; et
    h) un réchauffement de la couche de laque supérieure (20) est exécuté avec un jet de gaz chaud (26) qui possède au moins dans une direction une dimension (largeur) qui est petite en comparaison à la dimension du décor en couleur (12) et de la couche de laque supérieure (20).
  2. Procédé pour appliquer un décor en couleur (12) sur un substrat (18), comprenant les étapes suivantes :
    a) application d'un décor en couleur (12) sur un support surfacique (10) à propriété de détachement ;
    b) application d'une couche de colle (14a) sur le décor en couleur (12) posé sur le support (10) ;
    c) séchage ou séchage au moins partiel de la couche de colle appliquée (14a) ;
    d) transmission du décor en couleur (12) avec la couche de colle (14a), séchée ou séchée partiellement, depuis le support (10) jusque sur le substrat (18), de sorte que la couche de colle (14a) est posée sous le décor en couleur (12) sur le substrat (18), et le support (10) est enlevé du décor en couleur (12) ;
    e) application d'une couche de laque supérieure (20a) sur le décor en couleur (12) transmis sur le substrat (18) ; et
    f) durcissement de la couche de laque supérieure (20a) et activation de la couche de colle (14a) pour obtenir un collage intégral avec le substrat (18) ;
    caractérisé en ce que :
    g) un durcissement par faisceau électronique (22) est exécuté pour durcir la couche de laque supérieure (20a) ; et
    h) un réchauffement de la couche de laque supérieure (20a) est exécuté avec un jet de gaz chaud (26) qui possède au moins dans une direction une dimension (largeur) qui est petite en comparaison à la dimension du décor en couleur (12) et de la couche de laque supérieure (20a) dans cette direction.
  3. Procédé selon l'une ou l'autre des revendications 1 et 2, caractérisé en ce qu'un mouvement relatif (28) est exécuté entre le jet de gaz chaud (26) et le substrat (18).
  4. Procédé selon la revendication 1, caractérisé en ce que la laque (14) est une laque d'apprêt.
  5. Procédé selon la revendication 1, caractérisé en ce que la réticulation partielle de l'étape c) est exécutée avec des rayons ultraviolets.
  6. Procédé selon l'une ou l'autre des revendications 1 et 2, caractérisé en ce que le jet de gaz chaud (26) est échauffé à une température à laquelle il provoque, ou du moins favorise, la diffusion du colorant du décor en couleur (12) dans la couche de laque supérieure (20, 20a).
  7. Procédé selon la revendication 6, caractérisé en ce que la température du jet de gaz chaud (26) et un mouvement relatif (28) entre le jet de gaz chaud (26) et le substrat (18) sont ainsi commandés que sensiblement seule la couche de laque supérieure (20, 20a) est échauffée avec efficacité.
  8. Procédé selon la revendication 7, caractérisé en ce que le jet de gaz chaud (26) atteint au moins une bordure du substrat (18) avec les couches de laque et de peinture (12, 14, 20, 20a), appliquées sur le substrat et recouvrant la bordure.
  9. Procédé selon la revendication 8, caractérisé en ce que le jet de gaz chaud (26) a la forme d'une lame lors qu'il atteint la couche de laque supérieure (20, 20a) et est guidé en forme de lignes sur la couche de laque supérieure (20, 20a).
EP19980119331 1998-10-13 1998-10-13 Procédé d'application d'un décor coloré sur un substrat Expired - Lifetime EP0993876B1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
EP19980119331 EP0993876B1 (fr) 1998-10-13 1998-10-13 Procédé d'application d'un décor coloré sur un substrat
ES98119331T ES2213248T3 (es) 1998-10-13 1998-10-13 Procedimiento para aplicar una decoracion de color sobre un sustrato.
DE59810918T DE59810918D1 (de) 1998-10-13 1998-10-13 Verfahren zum Aufbringen eines Farbdekors auf ein Substrat

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP19980119331 EP0993876B1 (fr) 1998-10-13 1998-10-13 Procédé d'application d'un décor coloré sur un substrat

Publications (2)

Publication Number Publication Date
EP0993876A1 EP0993876A1 (fr) 2000-04-19
EP0993876B1 true EP0993876B1 (fr) 2004-03-03

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EP19980119331 Expired - Lifetime EP0993876B1 (fr) 1998-10-13 1998-10-13 Procédé d'application d'un décor coloré sur un substrat

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EP (1) EP0993876B1 (fr)
DE (1) DE59810918D1 (fr)
ES (1) ES2213248T3 (fr)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7709070B2 (en) 2001-12-20 2010-05-04 The Procter & Gamble Company Articles and methods for applying color on surfaces
US7727289B2 (en) 2005-06-07 2010-06-01 S.C. Johnson & Son, Inc. Composition for application to a surface
US7727607B2 (en) 2003-06-09 2010-06-01 The Procter & Gamble Company Multi-layer dry paint decorative laminate having discoloration prevention barrier
US7763083B2 (en) 2005-06-07 2010-07-27 S.C. Johnson & Son, Inc. Composition for application to a surface
US7842363B2 (en) 2003-02-14 2010-11-30 The Procter & Gamble Company Differential release system for a self-wound multilayer dry paint decorative laminate having a pressure sensitive adhesive
US7897228B2 (en) 2001-12-20 2011-03-01 The Procter & Gamble Company Articles and methods for applying color on surfaces
US8061269B2 (en) 2008-05-14 2011-11-22 S.C. Johnson & Son, Inc. Multilayer stencils for applying a design to a surface
US8557758B2 (en) 2005-06-07 2013-10-15 S.C. Johnson & Son, Inc. Devices for applying a colorant to a surface

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US20040161564A1 (en) 2003-02-14 2004-08-19 Truog Keith L. Dry paint transfer laminate
DE10318542A1 (de) * 2003-04-24 2004-11-11 Aluminium Féron GmbH & Co. KG Verfahren zur Herstellung von mit einer einen Lack enthaltenden Schutzschicht versehenen flächigen Materialien und Transferfolie hierfür
CN1946571A (zh) * 2004-02-23 2007-04-11 德麦克兹有限责任公司 用于制造施用清漆和颜料到物体上的膜的设备和方法
CN1942253A (zh) * 2004-02-23 2007-04-04 德麦克兹有限责任公司 用于向膜上施用清漆的设备
CN1942329A (zh) * 2004-02-23 2007-04-04 德麦克兹有限责任公司 用于制造向物体上施用清漆和颜料的膜的设备和方法
EP1658905A1 (fr) 2004-11-22 2006-05-24 DeMaxZ AG Procédé et appareil pour appliquer une décoration sur un objet
US8846154B2 (en) 2005-06-07 2014-09-30 S.C. Johnson & Son, Inc. Carpet décor and setting solution compositions
EP2048001A1 (fr) 2007-10-11 2009-04-15 DeMaxZ AG Application d'un décor sur un objet à l'aide d'une feuille de collage, sur laquelle le décor a été préalablement appliqué selon le procédé de décollement
DE102010014381A1 (de) * 2010-04-01 2011-10-06 Karl Wörwag Lack- Und Farbenfabrik Gmbh & Co. Kg Substrate mit mehrfarbiger Lackierung und ihre Herstellung

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Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7897227B2 (en) 2001-12-20 2011-03-01 The Procter & Gamble Company Articles and methods for applying color on surfaces
US7897228B2 (en) 2001-12-20 2011-03-01 The Procter & Gamble Company Articles and methods for applying color on surfaces
US7709070B2 (en) 2001-12-20 2010-05-04 The Procter & Gamble Company Articles and methods for applying color on surfaces
US7842363B2 (en) 2003-02-14 2010-11-30 The Procter & Gamble Company Differential release system for a self-wound multilayer dry paint decorative laminate having a pressure sensitive adhesive
US7842364B2 (en) 2003-02-14 2010-11-30 The Procter & Gamble Company Differential release system for a self-wound multilayer dry paint decorative laminate having a pressure sensitive adhesive
US7846522B2 (en) 2003-02-14 2010-12-07 The Procter & Gamble Company Discoloration-resistant articles for applying color on surfaces and methods of reducing discoloration in articles for applying color on surfaces
US7727607B2 (en) 2003-06-09 2010-06-01 The Procter & Gamble Company Multi-layer dry paint decorative laminate having discoloration prevention barrier
US7763083B2 (en) 2005-06-07 2010-07-27 S.C. Johnson & Son, Inc. Composition for application to a surface
US7727289B2 (en) 2005-06-07 2010-06-01 S.C. Johnson & Son, Inc. Composition for application to a surface
US7947640B2 (en) 2005-06-07 2011-05-24 S.C. Johnson & Son, Inc. Method of neutralizing a stain on a surface
US8048517B2 (en) 2005-06-07 2011-11-01 S.C. Johnson & Son, Inc. Composition for application to a surface
US8557758B2 (en) 2005-06-07 2013-10-15 S.C. Johnson & Son, Inc. Devices for applying a colorant to a surface
US8061269B2 (en) 2008-05-14 2011-11-22 S.C. Johnson & Son, Inc. Multilayer stencils for applying a design to a surface
US8499689B2 (en) 2008-05-14 2013-08-06 S. C. Johnson & Son, Inc. Kit including multilayer stencil for applying a design to a surface

Also Published As

Publication number Publication date
EP0993876A1 (fr) 2000-04-19
ES2213248T3 (es) 2004-08-16
DE59810918D1 (de) 2004-04-08

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