EP0570607A1 - Procédé pour l'application de laque et de teinture sur un substrat - Google Patents

Procédé pour l'application de laque et de teinture sur un substrat Download PDF

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Publication number
EP0570607A1
EP0570607A1 EP92108427A EP92108427A EP0570607A1 EP 0570607 A1 EP0570607 A1 EP 0570607A1 EP 92108427 A EP92108427 A EP 92108427A EP 92108427 A EP92108427 A EP 92108427A EP 0570607 A1 EP0570607 A1 EP 0570607A1
Authority
EP
European Patent Office
Prior art keywords
lacquer
substrate
color
carrier
partially crosslinked
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP92108427A
Other languages
German (de)
English (en)
Inventor
Maximilian P. Zaher
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SABIC Innovative Plastics BV
Original Assignee
GE Polymertrend GmbH
General Electric Plastics BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by GE Polymertrend GmbH, General Electric Plastics BV filed Critical GE Polymertrend GmbH
Priority to EP92108427A priority Critical patent/EP0570607A1/fr
Publication of EP0570607A1 publication Critical patent/EP0570607A1/fr
Withdrawn legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
    • B44C1/16—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like
    • B44C1/165—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like for decalcomanias; sheet material therefor
    • B44C1/17—Dry transfer
    • B44C1/1712—Decalcomanias applied under heat and pressure, e.g. provided with a heat activable adhesive
    • B44C1/1716—Decalcomanias provided with a particular decorative layer, e.g. specially adapted to allow the formation of a metallic or dyestuff layer on a substrate unsuitable for direct deposition
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M1/00—Inking and printing with a printer's forme
    • B41M1/26—Printing on other surfaces than ordinary paper
    • B41M1/30—Printing on other surfaces than ordinary paper on organic plastics, horn or similar materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/025—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet
    • B41M5/035—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet by sublimation or volatilisation of pre-printed design, e.g. sublistatic

Definitions

  • the invention relates to a method for applying a color decoration on or into a substrate, a lacquer layer being used.
  • the invention also relates to the application of a lacquer layer as such to a substrate.
  • substrates made of plastic and wood or wood-based materials as well as mixtures of such substances come into consideration here.
  • ceramic materials, glasses and the like can also be used as the substrate.
  • a method for applying a colored decoration to a substrate made of polyethylene in which heating takes place to 120 to 185 ° C., a sublimation print being carried out from an ink carrier onto the substrate.
  • the heating is carried out with infrared radiation, which is radiated through the substrate onto the ink carrier, ie the ink carrier is heated on its side facing the substrate by means of IR radiation.
  • the ink carrier is designed to be reflective to the IR radiation on its surface not covered with dyes, so that this radiation is absorbed only where paint is applied.
  • Also known from DE-A-24 38 723 is a method in which dyes are transferred to a substrate in such a way that a color support is placed on the substrate and the color is transferred to the substrate by heating the support with infrared radiation by means of sublimation printing.
  • GB-A-1 107 401 describes a process for colored printing on plastics, in which the plastics are heated to 175 to 180 ° C. in a heated glycerol bath. The surface of the plastic is gelled.
  • EP 0 098 506 A2 discloses a method and a device for generating permanent images on substrates, in which a support with dye is arranged between the substrate and a heated matrix, which has raised sections, the shape of which corresponds to the image to be transmitted . After the transfer of the dyes to the substrate has taken place by means of this heated matrix, the substrate is heated so that the dye diffuses from an ink into the substrate.
  • GB 2 127 747 A1 describes a transfer printing process in which the transfer printing partners are positioned by means of electrostatic charging.
  • an ink carrier also called auxiliary carrier
  • printed images decors
  • the color carrier can in particular consist of paper.
  • Printing takes place, for example, by means of offset or rotary printing processes.
  • the print images are transferred by sublimation from the ink carrier to the textile to be colored (so-called transfer printing).
  • the printing inks mentioned are produced from sublimable disperse dyes using binders and oxidation additives.
  • the printed ink carriers also called transfer papers
  • the printed ink carriers are placed with the color-printed side on the textile side to be printed and heated by means of a printing plate heated to 170 to 220 ° C. (using the cycle method).
  • the temperature of approx. 170 to 220 ° C reaches the dyes, they sublime into the textiles made of synthetic fibers.
  • EP-A 0 014 615 Another known method (EP-A 0 014 615), which is primarily intended for decorating eyeglass frames, is carried out in such a way that an eyeglass frame with its surface to be decorated is placed on a base with each working cycle, which is arranged within a vacuum chamber and can be moved up and down by means of a piston-cylinder unit.
  • the vacuum chamber has a side opening for inserting the eyeglass frame, which can be closed with a door.
  • the vacuum chamber On its upper side, the vacuum chamber has a horizontal, stationary frame which delimits a slot with a frame which is also arranged above it and is horizontal but can be moved up and down.
  • a carrier film is passed through the slot, which is rolled off a reel and is provided on the underside with the decor that is to be applied to the spectacle frame.
  • the decor has, for example, been applied to the carrier film as a multicolor print or as a decal and consists of colors which can be sublimed at a temperature below the destruction temperature of the carrier film.
  • the upper frame is lowered so that it clamps the carrier film between itself and the lower frame and the vacuum chamber is thereby sealed and can be evacuated.
  • the carrier film is heated to the sublimation temperature of the decoration by means of a heating device arranged above the upper frame and then the spectacle frame is moved upwards by means of its base which can be raised and lowered within the vacuum chamber and on which it has been placed, and is pressed against the carrier film.
  • the vacuum causes the carrier film to nestle tightly against the surfaces to be decorated on the front and in lateral areas of the spectacle frame. This state is maintained for a period of time which is sufficient for a transition of the colors forming the decor away from the carrier film into the structure of the material of the spectacle frame.
  • the vacuum is then released, the spectacle frame is lowered and thereby separated from the carrier film and finally removed from the vacuum chamber.
  • the carrier film is greatly stretched in individual areas so that it nestles sufficiently against the spectacle frame. It is inevitable that the decor will be distorted in the particularly stretched areas of the carrier film.
  • the distortions can be compensated to a certain extent by applying an appropriately corrected decor to the carrier film from the outset.
  • distortions in objects such as spectacle frames, whose surfaces to be decorated are relatively narrow are hardly noticeable. It is different with objects that are to be decorated over a large area. In the case of such objects, disruptive distortions of the decor cannot always be avoided if the decor has been applied by the known method.
  • the size of the surface to be decorated increases, the risk that the decor will be adversely affected by air pockets.
  • the objects for example tin cans
  • a coating system which applies a layer of dye-affine, migration-preventing plastic to the outside of the objects.
  • the coated objects are fed to a labeling machine, in which decor carriers in the form of printed banderoles are removed from a stack or endless strips, placed around one object each and fixed with an adhesive strip, glue line, electrostatic field or the like.
  • the objects are then heated, for example by means of hot air, to a temperature of 200 ° to 350 ° C., preferably 250 ° to 300 ° C.
  • a device for printing a textile web with sublimable dye is known, which is fed on a carrier film.
  • the device has a drivable, from the inside heated drum, around the bottom of the carrier film with the radially outwardly facing layer of dye and over it the textile web to be printed and over this an endless pressure belt made of metal mesh guided over rollers.
  • the region of the drum that is wrapped in this way can be covered by a hood, within which a negative pressure is maintained. In this way, when the ink is sublimed, gas released is sucked through the textile web to be printed and the pressure belt made of metal mesh lying thereon.
  • the pressing forces exerted by the pressure belt on the textile web are generated exclusively by the mechanical tension of the pressure belt and somewhat reduced by the negative pressure inside the hood.
  • thermoplastic films fuse or become so soft that the ink carriers (paper, etc.) used in transfer printing stick or damage the surfaces of the films so that the product did not meet the aesthetic requirements.
  • the migration resistance of the dyes required for good image reproduction was also not achieved.
  • thermosetting films and lacquers FR-A-2 230 794, DE-A 24 24 949, GB-A-1 517 832).
  • thermoplastic films and sheets which are thermoformed into three-dimensional bodies, e.g. Components for interior fittings, furniture parts (especially fronts), household appliances, office machines, lighting fixtures, car molded parts, etc., can be molded, there has long been a need for a way to provide good quality thermoplastic substrates with colored decorations.
  • EP 0 014 901 describes an attempt to achieve constant, traceable and stable transfer printing results in that the molecular weights of the sublimable disperse dyes, the temperatures used and the composition and nature of the plastic substrates are specified in more detail. It has come to the conclusion that heating to temperatures of 220 ° C. and more is required for the application of the transfer printing process to plastics. This excludes a large number of thermoplastic materials. The process remained limited to certain thermosetting plastic coatings and certain substrates made of inorganic materials.
  • the prior art also teaches as a prejudice that the molecular weight of the dyes used is important in sublimation printing.
  • the aforementioned EP 0 014 901 teaches the use of high molecular weight disperse dyes with molecular weights between 300 and 1000, in particular with a view to the required resistance to migration.
  • German patents 37 08 855 and 39 04 424 already mentioned at the beginning bring progress in that they sublimation printing from the use of heated printing plates or heated cylinders and instead suggest heating with heat radiation (infrared radiation). This prior art does not go into details of the materials used or of the sublimation temperatures.
  • EP-A-0 455 849 describes a method for applying and introducing dyes onto or into a plastic substrate, in which infrared radiation is directed inhomogeneously depending on the color distribution of the decoration onto a color support, so that the colors are sublimated - Transfer be transferred to the substrate.
  • Sublimation printing is complex and very sensitive to compliance with the process parameters if good results are to be achieved.
  • the invention has for its object to provide a method according to which a color decor with good qualitative results can be applied to a substrate in a simple manner.
  • the product should meet high demands with regard to its aesthetic and mechanical properties.
  • release means that the carrier is designed or prepared on its surface in such a way that under certain conditions it releases applied layers of paint or lacquer layers to another substrate. In other words: under certain conditions, color decorations or lacquers applied to a carrier with “release” properties can be “peeled off” from this carrier and transferred to another substrate.
  • a plastic material preferably a thermoplastic, whose colored decoration still caused problems in the prior art is particularly suitable as the substrate. Wooden surfaces or surfaces of wooden materials can also serve as the substrate.
  • the transfer of the partially crosslinked lacquer and, if appropriate, the color decoration from the carrier to the substrate is carried out under pressure and elevated temperature by means of a calender, which in particular has at least one roller made of elastic material. Large production capacities are possible with relatively little effort.
  • the substrate and the carrier are preferably guided synchronously through the calender.
  • Papers or plastic films are particularly suitable as carriers with "release” properties.
  • the first lacquer layer consists of a clear lacquer and the second lacquer layer consists of a white colored lacquer . This gives a very attractive visual impression with a high mechanical quality of the surface.
  • the invention also teaches how substrates can be colored or painted in the area of their edges. Both the surface of the substrate and the edges of the substrate are decorated or painted in a single step. A silicone cloth (or a cloth with similar elastic properties) is used for this purpose, which is pulled over the substrate by means of vacuum in such a way that it clamps the carrier between itself and the substrate surface, the edge surfaces of the substrate also being detected.
  • the invention also includes the use of the disclosed objects and materials for the purposes indicated.
  • Carriers with "release” properties are known as such, for example from ceramic technology, in order to apply color decors in the manner of "decals" to a substrate.
  • FIG. 1 shows a first variant of the method according to the invention.
  • a color decor is first applied to a carrier 10 with a “release” property.
  • This application of the color decor can be done in a conventional manner, e.g. by offset printing and the like.
  • lacquer 14 is applied over the color decor.
  • the dye is a diffusible disperse dye, especially low to medium molecular weight.
  • acrylic lacquer polyurethane lacquer, polyester lacquer and the like are used as lacquers.
  • water-soluble paints are used, but not paints with solvents.
  • lacquer is partially crosslinked.
  • the term "partially crosslinked" means that the lacquer is not yet fully crosslinked, but only partially, so that complete crosslinking is still possible later.
  • the crosslinking of lacquers is also known per se to the person skilled in the art. Networking can e.g. be carried out at elevated temperatures, in particular by means of infrared radiators. So-called hardeners are generally used for crosslinking. Different hardeners are available, which require different cross-linking temperatures. In particular, hardeners exist which already carry out partial crosslinking at relatively low temperatures, while the crosslinking of the lacquer takes place only at relatively high temperatures.
  • the lacquer 14 and the color decoration 12 are transferred from the carrier 10 to the substrate 16 to be ultimately decorated according to FIG.
  • the transfer is described in more detail below with reference to FIG. 5. For example, it can be done using a so-called calender.
  • the lacquer layer 14 comes to lie on the bottom of the substrate 16, while the color decor 12 is on the outside (FIG. 1b).
  • the partial crosslinking of the lacquer has the advantage that the lacquer 14 including the color decoration 12 can be transferred to the substrate 16 in a simple manner.
  • the paint binds the paint, i.e. the paint sticks to the paint.
  • the paint itself is easily removable from the carrier 10.
  • the lacquer When removing the lacquer from the carrier, ie when transferring the lacquer layer 14 and the color layer 12 to the substrate 16, essentially all of the color must be taken along. Problems arise here: none should cross-link the paint Diffuse color into the carrier 10. Therefore, the lacquer must be chosen so that its cross-linking temperature is lower than the softening temperature of the carrier 10 if a plastic material is used for the carrier 10. On the other hand, good coatings have the property that relatively high temperatures are used for crosslinking. However, such high temperatures cause problems with the diffusion of the color into the carrier.
  • low temperatures and high temperatures refer to the materials and supports used, that is to say in particular the softening temperature of the support and the diffusion properties of the paint.
  • the complete crosslinking of the lacquer (as well as the partial crosslinking beforehand) is preferably carried out by means of infrared heating. So-called impregnation of the substrate 16 takes place in such a way that the lacquer penetrates relatively far into the substrate. For example, it was measured that the lacquer (and also the dye molecules) penetrate 250 ⁇ m into a plastic substrate, whereas the penetration depth for a wooden substrate is approximately 80 ⁇ m. This impregnation of the substrate is highly desirable because it improves both the aesthetic properties of the decor and the mechanical stability of the surface.
  • Fig. 2 shows a modification of the previously described embodiment.
  • the variant according to FIG. 2 relates to a pure lacquer application on a substrate, in particular made of wood or a wooden material.
  • the prior art with regard to the application of lacquer to wood is extremely complex and requires a large number of process steps. If wet varnish is applied to wood, then when the varnish is cross-linked, so-called wood hair gets up, which is why complex sanding and multi-layered varnish application are required. It is also necessary to first saturate the wood with a filler so that too much varnish is not used.
  • a lacquer layer 14 is first applied to a carrier 10 with a “release” property.
  • the paint 14 is then partially crosslinked in the manner described above and then the paint 14 is transferred to the substrate 16 (here made of wood or a wood material), as described in more detail below is.
  • the transfer can be carried out with a calender, in particular using rubberized pressure rollers.
  • the process described above for applying lacquer to wood can be repeated, i.e. several layers can be applied one above the other in the manner described to further improve the result.
  • Diffusible dyes are used to dye the lacquer, ie dyes that are able to diffuse into the plastic substrate (cf. EP-A 0 455 849). Dyes with molecular weights less than or equal to 800 are preferably used. 3 to 5 g of dye per liter of varnish give good results.
  • UV-crosslinking lacquers are used, and also no lacquers that can be hardened by an electron beam.
  • the partial crosslinking and also the full crosslinking of the paints is preferably carried out by infrared radiation or hot air.
  • a first lacquer layer 14a is first applied to a carrier 10 with "release” property, which is first subjected to partial crosslinking. Then a color decor 12 is applied to the lacquer layer 14a and over the Color decor 12 is then applied a second lacquer layer 14b, which is then also subjected to partial crosslinking.
  • FIG. 4 describes a modification of the exemplary embodiment according to FIG. 1, in which a lacquer layer 14 is first applied to a carrier 10 with a “release” property, which is then subjected to partial crosslinking.
  • the color decor is then applied to the partially crosslinked lacquer layer 14 in the manner described above.
  • the carrier 10 there is a transfer from the carrier 10 to the substrate 16, the lacquer layer 14 then at the top, i.e. comes to lie over the color layer 12.
  • the lacquer on the substrate 16 is then fully crosslinked.
  • the method described above with reference to FIG. 3 can be modified in such a way that a clear lacquer is first applied to the carrier 10 with "release” property and partially crosslinked.
  • the color decor is then printed over the partially crosslinked clear lacquer layer and a lacquer is then applied over the color decor, which is then also partially crosslinked.
  • the top coat of paint mentioned above is colored white. After the partial crosslinking of the two lacquer layers, the transfer to the substrate then takes place, so that the white lacquer layer comes to rest on the substrate. Then all layers of paint are fully cross-linked and a high-quality product with great depth and good mechanical properties of the surface is created.
  • a plastic web 16 (or also a wood-containing film, veneer, etc.) is unwound as a substrate from a substrate unwinding roll 18a and, after the method has been carried out, is wound up on the other side on a substrate unwinding roll 18b.
  • the substrate 16 to be painted or decorated in color is fed to a calender 22 via a feed belt 20a.
  • the calender here has two rollers 22a, 22b which are rubberized on their surface in order to have a high elasticity.
  • the pressing force is indicated by the arrow F.
  • the carrier 10 with the “release” property is unwound from a carrier unwinding roll 24a, passed through the calender 22 and then wound up again onto a carrier winding roll 24b after transfer of the color decoration or varnish onto the substrate.
  • the lacquer and possibly the color decor are thus arranged on the side of the carrier 10 which faces the substrate 16 in the calender 22.
  • the calender generates the required pressure and also the temperatures required for the transfer. As such, this is known in calendering technology.
  • the rollers can be tempered directly.
  • preheating devices 26a, 26b On the input side of the calender 22 there is preheating by means of preheating devices 26a, 26b. These preheating devices cause the above-mentioned partial crosslinking of the paints before they enter the calender 22.
  • the paint is fully crosslinked by means of the main heating devices 28a, 28b on the output side (that is to say the movement from left to right in FIG. As shown, the heating devices (including the preheating) are arranged above and below (on both sides) of the substrate 16. The finished product is then wound up on the take-up roll 18b and is suitable for further processing.
  • the edge surface of the substrate 16 can also be decorated or painted.
  • the substrate 16 is placed on a table 30 which has a multiplicity of holes which can be connected to a vacuum source. This creates a suction effect on the table 30 (cf. EP-A 0 455 849).
  • the carrier 10 with "release” property is placed on the substrate 16 in such a way that the edge surfaces of the substrate (in addition to the actual surface of the substrate) can also be covered.
  • a silicone cloth 32 is then placed over the carrier 10 and the silicon cloth 32 is then sucked in such a way that the entire carrier 10 is pressed firmly and completely against the substrate 16 even in the area of the edge surfaces.
  • temperature is generated in the desired manner and the color layers or lacquer layers are transferred from the carrier 10 to the substrate 16, analogously to the technique described above.

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EP92108427A 1992-05-19 1992-05-19 Procédé pour l'application de laque et de teinture sur un substrat Withdrawn EP0570607A1 (fr)

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Application Number Priority Date Filing Date Title
EP92108427A EP0570607A1 (fr) 1992-05-19 1992-05-19 Procédé pour l'application de laque et de teinture sur un substrat

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Application Number Priority Date Filing Date Title
EP92108427A EP0570607A1 (fr) 1992-05-19 1992-05-19 Procédé pour l'application de laque et de teinture sur un substrat

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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4421554C1 (de) * 1994-06-20 1995-10-19 Osmetric Entwicklungs Und Prod Verfahren zum Beschichten thermoplastischer Kunststoffe und Verfahren zum Herstellen geformter Gegenstände aus diesen Kunststoffen
DE4421558A1 (de) * 1994-06-20 1995-12-21 Osmetric Entwicklungs Und Prod Verfahren zum Beschichten von Metallsubstraten sowie Verfahren zum Herstellen geformter beschichteter Metallerzeugnisse
DE4421559A1 (de) * 1994-06-20 1995-12-21 Osmetric Entwicklungs Und Prod Verfahren zum Herstellen eines beschichteten und mit einer Struktur, Textur oder Maserung versehenen Subtrats
EP1053793A1 (fr) * 1999-05-17 2000-11-22 Argotec Lacksysteme GmbH Procédé pour l'application d' une peinture et d'un décor sur un objet et procédé et dispositif pour appliquer une peinture, un décor et un adhésif sur un film
DE10154732A1 (de) * 2001-11-09 2003-05-22 Wipak Walsrode Gmbh & Co Kg Farbdekorübertragungssystem
FR2842456A1 (fr) * 2002-07-22 2004-01-23 Bourgogne Grasset Procede de marquage par tampographie et sublimation et encres de tampographie sublimables
WO2006054188A1 (fr) * 2004-11-17 2006-05-26 Illinois Tool Works Inc. Etiquette imprimee par transfert a chaud avec sechage uv, procede de creation et d’utilisation
US8507616B2 (en) 2010-06-29 2013-08-13 Illinois Tool Works Inc. Halo-free heat transfer label with pigmented adhesive
EP2674298A1 (fr) 2012-06-12 2013-12-18 Veka AG Cylindre destiné à chauffer un support décoratif ou une feuille

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4058644A (en) * 1974-12-04 1977-11-15 Devries Roy F Sublimation transfer and method
DE2740137A1 (de) * 1976-09-10 1978-03-16 Stork Brabant Bv Verfahren und vorrichtung fuer den vakuum-uebertragungsdruck
EP0033776A2 (fr) * 1980-02-07 1981-08-19 CP Components GmbH Kunststoff-Bauteile Procédé et dispositif de mise en couleur ou d'impression d'objets en forme de bande, en particulier de garnitures de ski, et objets d'une telle nature
EP0255572A1 (fr) * 1986-08-04 1988-02-10 Sika AG, vorm. Kaspar Winkler & Co. Adhésif et/ou agent d'étanchéité en un composant, stable au stockage et pompable jusqu'à 30 degrés C.
WO1992001572A1 (fr) * 1990-07-16 1992-02-06 Leonhard Kurz Gmbh & Co. Feuille a estamper a chaud pour la fixation d'une couche decorative sur un substrat

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4058644A (en) * 1974-12-04 1977-11-15 Devries Roy F Sublimation transfer and method
DE2740137A1 (de) * 1976-09-10 1978-03-16 Stork Brabant Bv Verfahren und vorrichtung fuer den vakuum-uebertragungsdruck
EP0033776A2 (fr) * 1980-02-07 1981-08-19 CP Components GmbH Kunststoff-Bauteile Procédé et dispositif de mise en couleur ou d'impression d'objets en forme de bande, en particulier de garnitures de ski, et objets d'une telle nature
EP0255572A1 (fr) * 1986-08-04 1988-02-10 Sika AG, vorm. Kaspar Winkler & Co. Adhésif et/ou agent d'étanchéité en un composant, stable au stockage et pompable jusqu'à 30 degrés C.
WO1992001572A1 (fr) * 1990-07-16 1992-02-06 Leonhard Kurz Gmbh & Co. Feuille a estamper a chaud pour la fixation d'une couche decorative sur un substrat

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4421554C1 (de) * 1994-06-20 1995-10-19 Osmetric Entwicklungs Und Prod Verfahren zum Beschichten thermoplastischer Kunststoffe und Verfahren zum Herstellen geformter Gegenstände aus diesen Kunststoffen
DE4421558A1 (de) * 1994-06-20 1995-12-21 Osmetric Entwicklungs Und Prod Verfahren zum Beschichten von Metallsubstraten sowie Verfahren zum Herstellen geformter beschichteter Metallerzeugnisse
DE4421559A1 (de) * 1994-06-20 1995-12-21 Osmetric Entwicklungs Und Prod Verfahren zum Herstellen eines beschichteten und mit einer Struktur, Textur oder Maserung versehenen Subtrats
DE4421559C2 (de) * 1994-06-20 1998-05-20 Osmetric Entwicklungs Und Prod Verfahren zum Herstellen einer Beschichtung, die eine Struktur aufweist, auf einem Substrat sowie Beschichtung
DE4421558C2 (de) * 1994-06-20 2000-02-03 Maximilian Zaher Verfahren zum Beschichten von Metallsubstraten und nach dem Verfahren beschichtete Metallerzeugnisse
EP1053793A1 (fr) * 1999-05-17 2000-11-22 Argotec Lacksysteme GmbH Procédé pour l'application d' une peinture et d'un décor sur un objet et procédé et dispositif pour appliquer une peinture, un décor et un adhésif sur un film
DE10154732A1 (de) * 2001-11-09 2003-05-22 Wipak Walsrode Gmbh & Co Kg Farbdekorübertragungssystem
FR2842456A1 (fr) * 2002-07-22 2004-01-23 Bourgogne Grasset Procede de marquage par tampographie et sublimation et encres de tampographie sublimables
WO2004009366A1 (fr) * 2002-07-22 2004-01-29 Gaming Partners International Procede de marquage par tampographie et sublimation et encres de tampographie sublimables.
US7063012B2 (en) 2002-07-22 2006-06-20 Gaming Partners International Method for marking by pad-printing and sublimation, and sublimable pad-printing inks
AU2003269040B2 (en) * 2002-07-22 2007-11-22 Gaming Partners International Method for ink pad and sublimation printing and sublimable tampographic inks
US7563834B2 (en) 2002-07-22 2009-07-21 Gaming Partners International Sublimable pad-printing inks
WO2006054188A1 (fr) * 2004-11-17 2006-05-26 Illinois Tool Works Inc. Etiquette imprimee par transfert a chaud avec sechage uv, procede de creation et d’utilisation
US8507616B2 (en) 2010-06-29 2013-08-13 Illinois Tool Works Inc. Halo-free heat transfer label with pigmented adhesive
EP2674298A1 (fr) 2012-06-12 2013-12-18 Veka AG Cylindre destiné à chauffer un support décoratif ou une feuille

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