EP0939161B2 - Färbeverfahren für Textilmaterialien mit Indigo und Vorrichtung zum Ausführen des Färbeverfahrens - Google Patents
Färbeverfahren für Textilmaterialien mit Indigo und Vorrichtung zum Ausführen des Färbeverfahrens Download PDFInfo
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- EP0939161B2 EP0939161B2 EP98630005A EP98630005A EP0939161B2 EP 0939161 B2 EP0939161 B2 EP 0939161B2 EP 98630005 A EP98630005 A EP 98630005A EP 98630005 A EP98630005 A EP 98630005A EP 0939161 B2 EP0939161 B2 EP 0939161B2
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/22—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using vat dyestuffs including indigo
- D06P1/228—Indigo
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B21/00—Successive treatments of textile materials by liquids, gases or vapours
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B3/00—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
- D06B3/10—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics
- D06B3/12—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics in zig-zag manner over series of guiding means
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B3/00—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
- D06B3/10—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics
- D06B3/18—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics combined with squeezing, e.g. in padding machines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/227—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/244—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons
- D06M15/256—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons containing fluorine
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
- D06M15/277—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof containing fluorine
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M7/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made of other substances with subsequent freeing of the treated goods from the treating medium, e.g. swelling, e.g. polyolefins
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/40—Reduced friction resistance, lubricant properties; Sizing compositions
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
- Y10S8/916—Natural fiber dyeing
- Y10S8/918—Cellulose textile
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
- Y10S8/93—Pretreatment before dyeing
- Y10S8/931—Washing or bleaching
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
- Y10S8/932—Specific manipulative continuous dyeing
Definitions
- the present invention relates to a process for dyeing a textile material with indigo according to the preamble of claim 1 and an installation for carrying out the method according to the preamble of claim 8.
- an indigo-dyed textile yarn is produced, which then makes it possible to prepare a fabric called denim fabric with which articles such as blue jeans are made, for example.
- Indigo is one of the oldest known dyes and has been used for centuries to tint textiles such as cotton.
- the patent EP-B-0 692 042 discloses a process for dyeing a cellulose-containing textile material with indigo in which an aqueous solution of leucoindigo prepared by catalytic hydrogenation is used and converted to the pigment form by air oxidation after its rise on the textile material.
- the U.S. Patent No. 4,283,198 discloses a continuous process for dyeing cellulosic fibers with indigo where the fibers are passed through a quenching tank train containing a liquor bath comprising leuco-indigo, sodium hydrosulfite and sodium hydroxide.
- the US-A-3,457,022 describes a process for dyeing cotton fibers with indigo where indigo is applied at a temperature between 65 ° C and 80 ° C on the yarns and then indigo is applied at temperatures below 40 ° C .
- the indigo tinted blue jeans have the disadvantage that they fade when washed.
- the industry has developed processes and facilities to follow this fashion, where the fabric has been accentuated and faded by facilitating fading of the yarn. of chain.
- the manner in which the dye was used facilitated the washing and aging. But any mode is ephemeral and lasts only one time.
- the object of the present invention is the production of a denim fabric which is resistant to wear and discoloration by washing and with the fabric according to the present invention, there is no longer any concern for the washing waters used and the corrosive detergents employed. washing.
- indigo is practically insoluble in water and can not be used as such for dyeing. It must be used first in a soluble form and then the dye is generated in an insoluble form in the fiber or yarn.
- the operations usually carried out for dyeing the yarn in indigo blue are modified, by adding additional operations, both at the bath level and at the stage of oxidation and mercerization beforehand, in order to facilitate the capacity of the yarn. absorption and impregnation of the wire.
- the yarn is then vaporized under conditions of defined temperature and pressure, before being washed and then mercerized again.
- the second phase of the process is to form around the now dyed wire, an insulation to make it insensitive to washing, and it is then ready to be used.
- the neutral wire must first be made by successive passages in acidic baths.
- the yarn is then completely dried before being immersed in a bath which will definitively fix the indigo and which will give it the desired characteristics.
- the yarn obtained by the methods known in the art consists of a white core core, i.e. untinted and externally impregnated with indigo dye.
- the wire With the method according to the invention, the wire will be constituted by a much thinner central white core and the indigo penetrate much deeper into the outer part so that it will be tinted much deeper. Ideally the yarn will be tinted from side to side by indigo.
- a prewashing step is first carried out by passing the wire F originating from a starting roll on which it is wound through a prewashing installation 1 constituted by two or more tanks 2 containing a prewash solution 10,15.
- the wire is guided by rollers 3 and 4 in the first tank 2 containing the prewash solution, and then, coming out of this solution, it passes between two pressure rollers 5 to remove the excess liquid and then, guided by the roll 6, plunges back into the prewash solution.
- the wire passes between two pressure rollers 7.
- the guide rollers 8 and 9 the wire is immersed in the prewash solution 15 in the second tank 2.
- the wire will move in the second tank in a path identical to that of the first tank passing successively between the two pressure rollers 12, below the guide roller 11 and between the pressure rollers 13.
- the prewash solution contains a soaking product such as FINBIL AS (produced by Bozzetto) (trade designation) which is a phosphoric ester derivative of fatty alcohol. It is used in the aqueous solution in a concentration of 5 to 8 gr / liter. This prewash bath is used to impregnate the wire to promote the subsequent penetration of indigo.
- a soaking product such as FINBIL AS (produced by Bozzetto) (trade designation) which is a phosphoric ester derivative of fatty alcohol. It is used in the aqueous solution in a concentration of 5 to 8 gr / liter. This prewash bath is used to impregnate the wire to promote the subsequent penetration of indigo.
- the actual dyeing of the yarn is carried out by means of the dyeing plant 30 shown in FIG. figure 2 .
- the dyebaths contain a reduced indigo solution containing 3 to 5% indigo powder, sodium hydrosulphite in an amount corresponding to 2/3 of the amount of indigo and caustic soda. Baumé en a quantity corresponding to twice the amount of indigo.
- the wires pass through the baths at a speed of 20 to 60 m / minute depending on the type and quality of the wire.
- the example shown in the figure 2 has 8 tanks but it goes without saying that the operation can be repeated 2, 3 or more times by using two, three or more sets of 8 tanks to obtain an increasing penetration of the indigo in the thread.
- the washing and pre-wetting thereof is carried out using the installation 40 described in FIG. Fig. 3 .
- the wire is successively passed through the tanks 41 to 45 by guiding it by means of the rollers 46, 47 and 48.
- the tank 41 contains water and in the tanks 42, 43 and 44, acetic acid is introduced. (CH 3 -COOH) at 50% so that the tank 42 contains a proportion of 20 cc / l, the tank 43 contains 10 cc / l and the tank 44 contains 5 cc / l.
- the tank 45 again contains water, the final pH being between 6 and 7, preferably 6.7.
- the wire is pre-wiped by passing it around the rollers 50 as can be seen in FIG. figure 3 .
- the indigo dye is sized on the yarn to increase the resistance to washing and rubbing of the fabrics that will be subsequently prepared by passing the yarn through the installation. sizing 60 described in the figure 4 .
- the wire passes into a tank 62 containing a mixture of resins 63 and is guided through the tank by means of the guide rollers 64 and the pressure rollers 61.
- the wire is dried using the installation 70 shown in FIG. figure 5 passing the yarns around the rollers 71. This drying is done at a temperature between 150-180 ° C.
- the method according to the invention can be implemented with various types of son, for example cotton, cotton and nylon, cotton and polyester etc ....
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Coloring (AREA)
- Treatment Of Fiber Materials (AREA)
Claims (16)
- Färbeverfahren eines Textilstoffs mit Indigo, dadurch gekennzeichnet, dass es die folgenden Schritte umfasst:a. Vorwaschen eines Garns F, indem man dieses durch eine Vorwaschanlage (1) laufen lässt, die aus zwei oder mehreren Bottichen (2) besteht, die eine Vorwaschlösung (10, 15) enthalten;b. anschließendes Färben des Garns, indem man es durch eine Färbeanlage (30) laufen lässt,c. Waschen und Vorabstreifen des Garns, indem man es durch eine Wasch- und Vorabstreifanlage (40) laufen lässt, die eine Reihe von Bottichen (41, 42, 43, 44 und 45) umfasst, wobei der erste Bottich (41) Wasser enthält, die Bottiche (42, 43 und 44) Essigsäure enthalten und der Bottich (45) Wasser enthält, sodass der pH im letzten Bottich zwischen 6 und 7 liegt und man das Garn am Ausgang des Bottichs (45) vorabstreift, indem man es zwischen den Rollen (50) durchlaufen lässt;d. Beschichten der Indigofärbung auf dem Garn, indem man es durch eine Beschichtungsanlage (60) laufen lässt, die einen Bottich (62) umfasst, der ein Gemisch aus Harzen enthält, um einen durchsichtigen Film auf den Garnfasern zu bilden;e. Trocknen des Garns, indem man es durch eine Trockenanlage (70) laufen lässt, die aus Rollen (71) besteht;f. Aufnehmen des Kettgarns, indem man es auf die Trommel (72) aufwickelt,dadurch gekennzeichnet, dass man den Schritt b) zum Färben des Garn umsetzt, indem man es durch eine Färbeanlage (30) laufen lässt, die aus einer Reihe von acht Bottichen (35) besteht, die jeder eine Lösung aus reduziertem Indigo enthalten, und beim Übergang von einem Bottich (35) auf den anderen das Garn einer Oxidation durch Exposition mit Luft aussetzt, die den reduzierten Indigo in Indigo umwandelt, der das Garn durch Imprägnieren färbt, wobei die Oxidation durch Exposition mit der Luft so durchgeführt wird, dass man beim aufeinander folgenden Durchlaufen vom ersten Bottich (35) bis zum achten Bottich, nacheinander Folgendes erhält, wenn man der Oxidation zwischen dem ersten Bottich (35) und dem zweiten den Wert x gibt:Zwischen dem 1. und dem 2. Bottich den Oxidationswert = xZwischen dem 2. und dem 3. Bottich den Oxidationswert = 2xZwischen dem 3. und dem 4. Bottich den Oxidationswert = 3xZwischen dem 4. und dem 5. Bottich den Oxidationswert = 4xZwischen dem 5. und dem 6. Bottich den Oxidationswert = 5xZwischen dem 6. und dem 7. Bottich den Oxidationswert = 6xZwischen dem 7. und dem 8. Bottich den Oxidationswert = 7xNach dem 8. Bottich Oxidationswert = 8x
- Verfahren nach Anspruch 1, dadurch gekennzeichnet, dass man im Laufe des Schritts a) eine Vorwaschlösung verwendet, die ein Fettalkohol-Phosphoresterderivat, wie zum Beispiel FINBIL AS enthält.
- Verfahren nach Anspruch 1, dadurch gekennzeichnet, dass das Farbbad in den Bottichen (35) eine Lösung aus reduziertem Indigo umfasst, die 3 bis 5 % Indigo in Pulverform, Natriumhydrosulfit in einer Menge, die 2/3 der Menge Indigo entspricht, und Ätznatron 36 Baumé in einer Menge enthält, die dem Doppelten der Menge Indigo entspricht.
- Verfahren nach Anspruch 1, dadurch gekennzeichnet, dass beim Schritt c) die Essigsäurelösung im Bottich (42) durch Hinzufügen von 50 %-iger Essigsäure in den Bottich (42) in einer Menge von 20 cm3/l erzielt wird, wobei man die Essigsäurelösung im Bottich (43) durch Hinzufügen von 50 %-iger Essigsäure in den Bottich (43) in einer Menge von 10 cm3/l erzielt, und die Essigsäurelösung im Bottich (44) durch Hinzufügen von 50 %-iger Essigsäure in den Bottich (44) in einer Menge von 5 cm3/l erzielt.
- Verfahren nach Anspruch 1, dadurch gekennzeichnet, dass das Gemisch aus Harzen während des Schritts d) ein Gemisch umfasst aus:10 bis 50 g/l Polyalkylamin-Quartärsalz10 bis 50 g/l Fluorkohlenstoffharz10 bis 200 g/l Acrylharz1 bis 20 g/l autokatalysiertes Polysiloxan10 bis 200 g/l Polyurethanharz
- Verfahren nach Anspruch 1, dadurch gekennzeichnet, dass der Schritt b) mehrere Male unter Verwendung von 16, 24 Farbbottichen (35) an Stelle von acht wiederholt werden kann.
- Verfahren nach Anspruch 1, dadurch gekennzeichnet, dass die Garne mit einer Geschwindigkeit von 20 bis 60 m/Minute durch die Farbbäder laufen.
- Anlage zum Durchführen des Färbeverfahrens nach den Ansprüchen 1-5, die Folgendes umfasst:a) eine Vorwaschanlage (1);b) eine Färbeanlage (30);c) eine Wasch- und Vorabstreifanlage (40);d) eine Beschichtungsanlage (60);e) eine Trockenanlage (70);dadurch gekennzeichnet, dass diese Färbeanlage (30) eine Reihe von 8 Bottichen (35) umfasst, die ein Bad aus reduziertem Indigo enthalten, eine Reihe von Rollen (31, 32, 33, 34, 36 und 37), die jedem Bottich zugewiesen sind, wobei die Rollen (36) zwischen den Bottichen (35) so angeordnet sind, dass es eine Rolle (36) zwischen dem ersten und dem zweiten Bottich (35), zwei Rollen (36) zwischen dem zweiten und dem dritten Bottich, drei Rollen (36) zwischen dem dritten und dem vierten Bottich (35) gibt, und so weiter bis zum achten Bottich (35), und dass es nach diesem auch acht Rollen (36) gibt, wobei diese Anordnung der Rollen (36) es erlaubt, die Dauer der Exposition des Garns mit der freien Luft allmählich zu steigern, um dieses Garn so zu oxidieren, dass man nacheinander Folgendes erhält, wenn man der Oxidation zwischen dem ersten Bottich (35) und dem zweiten den Wert x zuweist:Zwischen dem 1. und dem 2. Bottich den Oxidationswert = xZwischen dem 2. und dem 3. Bottich den Oxidationswert = 2xZwischen dem 3. und dem 4. Bottich den Oxidationswert = 3xZwischen dem 4. und dem 5. Bottich den Oxidationswert = 4xZwischen dem 5. und dem 6. Bottich den Oxidationswert = 5xZwischen dem 6. und dem 7. Bottich den Oxidationswert = 6xZwischen dem 7. und dem 8. Bottich den Oxidationswert = 7xNach dem 8. Bottich Oxidationswert = 8x
- Anlage nach Anspruch 8, dadurch gekennzeichnet, dass die Vorwaschanlage Folgendes umfasst:zwei oder mehr Bottiche (2), die eine Vorwaschlösung (10, 15) enthalten, eine Führungsrolle (3), um das Garn in die Vorwaschlösung (10) zu führen, eine Führungsrolle (4), um das Garn zwischen zwei Druckrollen (5) zu lenken, die das Garn zu einer Führungsrolle (6) führen, zwei Druckrollen (7) zum Abstreifen des Überschusses an Flüssigkeit, eine Führungsrolle (8), die das Garn in die Waschflüssigkeit (15) in dem zweiten Bottich (2) lenkt, eine Führungsrolle (9), die das Garn zu zwei Druckrollen (12) lenkt, eine Führungsrolle (11), die das Garn wieder in die Vorwaschlösung (15) führt, und zwei Druckrollen (13), die das Garn am Ausgang des zweiten Bottichs (2) abstreifen.
- Anlage nach Anspruch 8, dadurch gekennzeichnet, dass die Wasch- und Vorabstreifanlage (40) eine Reihe von Bottichen (41, 42, 43, 44 und 45) und Rollen (46, 47 und 48) umfasst, die jedem Bottich zugewiesen sind, wobei der erste Bottich (41) Wasser enthält, die Bottiche (42, 43 und 44) Essigsäure enthalten und der Bottich (45) Wasser enthält, sodass der pH im letzten Bottich zwischen 6 und 7 liegt und sich am Ausgang des Bottichs (45) eine Reihe von Rollen (50) zum Trocknen des Garns befindet.
- Anlage nach Anspruch 8, dadurch gekennzeichnet, dass die Beschichtungsanlage (60) einen Bottich (62) umfasst, der ein Gemisch aus Harzen enthält.
- Anlage nach Anspruch 8, dadurch gekennzeichnet, dass man im Laufe des Schritts a) eine Vorwaschlösung verwendet, die ein Fettalkohol-Phosphoresterderivat, wie zum Beispiel FINBIL AS enthält.
- Anlage nach Anspruch 8, dadurch gekennzeichnet, dass das Farbbad in den Bottichen (35) eine Lösung aus reduziertem Indigo umfasst, die 3 bis 5 % reduzierten Indigo in Pulverform, Natriumhydrosulfit in einer Menge, die 2/3 der Menge Indigo entspricht, sowie Ätznatron 36 Baumé in einer Menge enthält, die dem Doppelten der Menge Indigo entspricht.
- Anlage nach Anspruch 8, dadurch gekennzeichnet, dass die Essigsäurelösung im Schritt c) im Bottich (42) erzielt wird, indem 50 %-ige Essigsäure in den Bottich (42) in einer Menge von 20 cm3/l hinzugefügt wird, die Essigsäurelösung im Bottich (43) erzielt wird, indem 50 %-ige Essigsäure in den Bottich (43) in einer Menge von 10 cm3/l hinzugefügt wird, und die Essigsäurelösung im Bottich (44) erzielt wird, indem 50 %-ige Essigsäure in den Bottich (44) in einer Menge von 5 cm3/l hinzugefügt wird.
- Anlage nach Anspruch 8, dadurch gekennzeichnet, dass das Gemisch aus Harzen im Laufe des Schritts d) ein Gemisch aus Folgendem umfasst:10 bis 50 g/l Polyalkylamin-Quartärsalz10 bis 50 g/l Fluorkohlenstoffharz10 bis 200 g/l Acrylharz1 bis 20 g/l autokatalysiertes Polysiloxan10 bis 200 g/l Polyurethanharz
- Anlage nach Anspruch 8, dadurch gekennzeichnet, dass der Schritt b) mehrmals durchgeführt werden kann, indem man 16, 24 Farbbottiche (35) an Stelle von acht verwendet.
Priority Applications (8)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT98630005T ATE264423T1 (de) | 1998-02-26 | 1998-02-26 | Färbeverfahren für textilmaterialien mit indigo und vorrichtung zum ausführen des färbeverfahrens |
ES98630005T ES2218792T5 (es) | 1998-02-26 | 1998-02-26 | Procedimiento de teñido de una materia textil con indigo, e instalacion para la aplicacion del procedimiento. |
EP98630005A EP0939161B2 (de) | 1998-02-26 | 1998-02-26 | Färbeverfahren für Textilmaterialien mit Indigo und Vorrichtung zum Ausführen des Färbeverfahrens |
PT98630005T PT939161E (pt) | 1998-02-26 | 1998-02-26 | Processo de tintura de um material textil com anil e instalacao para realizar o processo |
DK98630005T DK0939161T3 (da) | 1998-02-26 | 1998-02-26 | Fremgangsmåde til farvning af tekstilstoffer med indigo og indretning til udförelse af fremgangsmåden |
DE69823161T DE69823161T2 (de) | 1998-02-26 | 1998-02-26 | Färbeverfahren für Textilmaterialien mit Indigo und Vorrichtung zum Ausführen des Färbeverfahrens |
SI9830663T SI0939161T1 (en) | 1998-02-26 | 1998-02-26 | Process for dyeing of textile materials with indigo and installation for carrying out the method |
US09/334,549 US6123741A (en) | 1998-02-26 | 1999-06-16 | Process for dyeing a textile material with indigo and arrangement for conducting the process |
Applications Claiming Priority (1)
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EP98630005A EP0939161B2 (de) | 1998-02-26 | 1998-02-26 | Färbeverfahren für Textilmaterialien mit Indigo und Vorrichtung zum Ausführen des Färbeverfahrens |
Publications (3)
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EP0939161A1 EP0939161A1 (de) | 1999-09-01 |
EP0939161B1 EP0939161B1 (de) | 2004-04-14 |
EP0939161B2 true EP0939161B2 (de) | 2009-04-01 |
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EP98630005A Expired - Lifetime EP0939161B2 (de) | 1998-02-26 | 1998-02-26 | Färbeverfahren für Textilmaterialien mit Indigo und Vorrichtung zum Ausführen des Färbeverfahrens |
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US (1) | US6123741A (de) |
EP (1) | EP0939161B2 (de) |
AT (1) | ATE264423T1 (de) |
DE (1) | DE69823161T2 (de) |
DK (1) | DK0939161T3 (de) |
ES (1) | ES2218792T5 (de) |
PT (1) | PT939161E (de) |
SI (1) | SI0939161T1 (de) |
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DE19915439A1 (de) * | 1999-04-07 | 2000-10-12 | Cognis Deutschland Gmbh | Verfahren zur Stabilisierung von gefärbtem Textilgut gegen Vergilben |
KR100528359B1 (ko) * | 2000-02-21 | 2005-11-16 | 프랑스와 지르보 | 인독실을 사용하여 직물 재료를 인디고로 염색하는 방법및 그 방법을 이용하기 위한 시스템 |
KR20030070382A (ko) * | 2002-02-25 | 2003-08-30 | 김성수 | 쪽을 이용한 천연 염색사의 염색방법 |
US20050150058A1 (en) * | 2003-07-18 | 2005-07-14 | Wroblowski Hans G. | Method of and device for coloring textiles |
US6997962B2 (en) * | 2004-02-18 | 2006-02-14 | Melvin Alpert | Method for dyeing cotton with indigo |
US7235110B2 (en) * | 2004-02-18 | 2007-06-26 | Melvin Alpert | Method for dyeing fabric materials with indigo, other vat dyes, and sulfur dyes |
ITMI20041553A1 (it) * | 2004-07-29 | 2004-10-29 | Master Sas Di Ronchi Francesco & C | Dispositivo e procedimenti di tintura con indaco e altri coloranti |
WO2006041480A1 (en) * | 2004-10-07 | 2006-04-20 | Melvin Alpert | Method for dyeing cotton with indigo |
DE102005020165A1 (de) * | 2005-04-30 | 2006-11-02 | Mageba-Textilmaschinen Gmbh & Co. Ohg | Tauch-Quetschwalzwerk-Vorrichtung |
US8038726B2 (en) * | 2006-09-29 | 2011-10-18 | Standard Textile Co., Inc. | In-line system for processing textile material |
TR200800218A2 (tr) * | 2008-01-11 | 2008-12-22 | Gap Güneydoğu Teksti̇l Sanayi̇ Ve Ti̇caret Anoni̇m Şi̇rketi̇ | Çözgü üzerine fınıshıng maddelerinin aplikasyonu. |
CN102758323A (zh) * | 2011-04-28 | 2012-10-31 | 孚日集团股份有限公司 | 连续轧染巾被织物前处理专用给液装置 |
CN102965985A (zh) * | 2012-12-12 | 2013-03-13 | 江苏富邦纺织有限公司 | 一种全棉织物的还原染料染色工艺 |
US10982381B2 (en) | 2014-10-06 | 2021-04-20 | Natural Fiber Welding, Inc. | Methods, processes, and apparatuses for producing welded substrates |
US10011931B2 (en) | 2014-10-06 | 2018-07-03 | Natural Fiber Welding, Inc. | Methods, processes, and apparatuses for producing dyed and welded substrates |
CN104452360A (zh) * | 2014-12-19 | 2015-03-25 | 苏州市吴中区郭巷旭宇羊毛衫加工场 | 一种纱线染色工艺 |
CN105401463B (zh) * | 2015-11-04 | 2017-11-14 | 浙江理工大学 | 一种棉纤维的靛蓝染料一次染深色方法 |
CN114657730A (zh) | 2016-03-25 | 2022-06-24 | 天然纤维焊接股份有限公司 | 用于生产焊接基质的方法、工艺和设备 |
US11085133B2 (en) | 2016-05-03 | 2021-08-10 | Natural Fiber Welding, Inc. | Methods, processes, and apparatuses for producing dyed and welded substrates |
ITUA20163921A1 (it) * | 2016-05-30 | 2017-11-30 | Mayer Textilmaschf | Apparecchiatura multifunzionale per la tintura in continuo di catene di ordito per tessuti. |
CN106592136B (zh) * | 2016-12-15 | 2018-10-02 | 嘉兴万源时装有限公司 | 一种布料的染色装置及染色方法 |
WO2020234897A1 (en) * | 2019-05-17 | 2020-11-26 | Arvind Limited | Process for dyeing yarns and system thereof |
CN112210932B (zh) * | 2020-11-16 | 2021-05-14 | 肇庆市高要区姿采袜业有限公司 | 一种基于电磁吸附技术的纺织节水染色机 |
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- 1998-02-26 SI SI9830663T patent/SI0939161T1/xx unknown
- 1998-02-26 PT PT98630005T patent/PT939161E/pt unknown
- 1998-02-26 DE DE69823161T patent/DE69823161T2/de not_active Expired - Lifetime
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Also Published As
Publication number | Publication date |
---|---|
PT939161E (pt) | 2004-08-31 |
ATE264423T1 (de) | 2004-04-15 |
ES2218792T5 (es) | 2009-07-06 |
ES2218792T3 (es) | 2004-11-16 |
DE69823161T2 (de) | 2004-08-26 |
DE69823161D1 (de) | 2004-05-19 |
US6123741A (en) | 2000-09-26 |
DK0939161T3 (da) | 2004-07-12 |
SI0939161T1 (en) | 2004-12-31 |
EP0939161A1 (de) | 1999-09-01 |
EP0939161B1 (de) | 2004-04-14 |
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