EP0931333B1 - Herstellverfahren für eine hoch-epsilon-dielektrische oder ferroelektrische schicht - Google Patents
Herstellverfahren für eine hoch-epsilon-dielektrische oder ferroelektrische schicht Download PDFInfo
- Publication number
- EP0931333B1 EP0931333B1 EP97910214A EP97910214A EP0931333B1 EP 0931333 B1 EP0931333 B1 EP 0931333B1 EP 97910214 A EP97910214 A EP 97910214A EP 97910214 A EP97910214 A EP 97910214A EP 0931333 B1 EP0931333 B1 EP 0931333B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- temperature
- layer
- dielectric
- oxygen
- coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title claims abstract description 22
- 238000004519 manufacturing process Methods 0.000 title claims description 15
- 239000011248 coating agent Substances 0.000 title abstract 4
- 238000000576 coating method Methods 0.000 title abstract 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000001301 oxygen Substances 0.000 claims abstract description 15
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 15
- 230000015654 memory Effects 0.000 claims abstract description 10
- 239000012298 atmosphere Substances 0.000 claims abstract description 9
- 238000004544 sputter deposition Methods 0.000 claims abstract description 6
- 239000003990 capacitor Substances 0.000 claims description 9
- 239000000758 substrate Substances 0.000 claims description 7
- 241001484259 Lacuna Species 0.000 claims 1
- 230000003750 conditioning effect Effects 0.000 claims 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims 1
- 230000004888 barrier function Effects 0.000 abstract description 11
- 230000003647 oxidation Effects 0.000 abstract description 6
- 238000007254 oxidation reaction Methods 0.000 abstract description 6
- 229910052454 barium strontium titanate Inorganic materials 0.000 description 13
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 6
- 239000000463 material Substances 0.000 description 4
- 239000012299 nitrogen atmosphere Substances 0.000 description 4
- 238000009792 diffusion process Methods 0.000 description 3
- 238000009413 insulation Methods 0.000 description 3
- 229910052697 platinum Inorganic materials 0.000 description 3
- 238000005496 tempering Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 238000000137 annealing Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229910000510 noble metal Inorganic materials 0.000 description 2
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 2
- 229920005591 polysilicon Polymers 0.000 description 2
- 239000004065 semiconductor Substances 0.000 description 2
- VEALVRVVWBQVSL-UHFFFAOYSA-N strontium titanate Chemical compound [Sr+2].[O-][Ti]([O-])=O VEALVRVVWBQVSL-UHFFFAOYSA-N 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910052721 tungsten Inorganic materials 0.000 description 2
- 239000010937 tungsten Substances 0.000 description 2
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000005137 deposition process Methods 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- HFGPZNIAWCZYJU-UHFFFAOYSA-N lead zirconate titanate Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Ti+4].[Zr+4].[Pb+2] HFGPZNIAWCZYJU-UHFFFAOYSA-N 0.000 description 1
- 238000002488 metal-organic chemical vapour deposition Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000010287 polarization Effects 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- -1 tungsten nitride Chemical class 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/31—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
- H01L21/3205—Deposition of non-insulating-, e.g. conductive- or resistive-, layers on insulating layers; After-treatment of these layers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02107—Forming insulating materials on a substrate
- H01L21/02109—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates
- H01L21/02112—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer
- H01L21/02172—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer the material containing at least one metal element, e.g. metal oxides, metal nitrides, metal oxynitrides or metal carbides
- H01L21/02197—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer the material containing at least one metal element, e.g. metal oxides, metal nitrides, metal oxynitrides or metal carbides the material having a perovskite structure, e.g. BaTiO3
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02107—Forming insulating materials on a substrate
- H01L21/02225—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer
- H01L21/0226—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a deposition process
- H01L21/02263—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a deposition process deposition from the gas or vapour phase
- H01L21/02266—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a deposition process deposition from the gas or vapour phase deposition by physical ablation of a target, e.g. sputtering, reactive sputtering, physical vapour deposition or pulsed laser deposition
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/31—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
- H01L21/314—Inorganic layers
- H01L21/316—Inorganic layers composed of oxides or glassy oxides or oxide based glass
- H01L21/31691—Inorganic layers composed of oxides or glassy oxides or oxide based glass with perovskite structure
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10B—ELECTRONIC MEMORY DEVICES
- H10B53/00—Ferroelectric RAM [FeRAM] devices comprising ferroelectric memory capacitors
Definitions
- the invention relates to a manufacturing method for a high ⁇ dielectric or ferroelectric layer on one Substrate that is especially used to manufacture an integrated Semiconductor memory is used.
- High- ⁇ -dielectric and ferroelectric substances are becoming increasingly important in the manufacture of integrated circuits. They are used, for example, as a capacitor dielectric in integrated memories because, due to their high dielectric constant ( ⁇ r of a few hundred), they reduce the space required for the storage capacitor and, because of the different polarization directions of the ferroelectric, they enable the construction of a non-volatile memory (FRAM) (no loss of information in the event of supply voltage failure and no constant refresh).
- FRAM non-volatile memory
- BST barium strontium titanate
- ST strontium titanate
- PZT lead zirconium titanate
- SBT SrBi 2 Ta 2 O 9
- SBTN SrBi 2 Ta 2-x Nb x O 9
- a noble metal such as platinum or ruthenium is then used as the material for the first electrode, since the conductive materials such as polysilicon or aluminum that are usually used as the electrode material oxidize under these conditions.
- a process is known from the article by A. Yuuki et al, IEDM 95, Technical Digest, page 115, in which the crystallization of a BST film produced in a CVD process takes place by annealing in N 2 .
- a layer produced in this way has high leakage currents.
- the object of the invention is therefore a manufacturing method for a high ⁇ dielectric layer or a ferroelectric layer with a reduced Specify temperature load. This task is accomplished by the Features of claim 1 solved.
- FIG. 1 As an example of an application of the method, a cell of a DRAM memory with a capacitor (stacked cell) arranged above the selection transistor is shown.
- the FIG shows a silicon substrate 1 with a MOS transistor arranged therein, which comprises two doped regions 3, 4 and a gate 5 insulated on the substrate. Inactive areas of the circuit are covered with insulation 2.
- An insulation layer 6 covers the transistor, a connection 7 to the doped region 3 and a connection to the doped region 4 lying outside the plane of the drawing being provided.
- the connection 7 can for example consist of polysilicon or tungsten, with which a contact hole etched into the insulation layer 6 is filled.
- a diffusion barrier 9 made of tungsten nitride (or also WTiN, TiN, TaN or the like) is applied with a thickness of 30 nm, so that at least the entire exposed surface of the connection 7 is covered.
- a first electrode 8 is then applied, for example by sputtering or MOCVD of a platinum layer, and structured appropriately.
- the barrier can also be arranged on the electrode 8, or the electrode can be formed from the barrier material.
- the arrangement thus far completed represents a carrier 1-9 for the high- ⁇ -dielectric or ferroelectric layer.
- a BST layer is now applied to the carrier or this electrode 8 as a capacitor dielectric 10.
- a 3-stage process in which in the first step the BST is sputtered on at a substrate temperature of up to 350 ° C, the layer thickness is about 10 - 200 nm.
- the substrate and the BST layer deposited thereon are only removed during the Sputtering heated to the temperature T 1 .
- the BST that is separated out is not yet crystalline or has a very small grain size.
- the BST is crystallized in a second step in an RTP process in a nitrogen atmosphere.
- the temperature is about 700 ° C., the time period is about 60 seconds. Oxidation of the barrier 9 is prevented by the nitrogen atmosphere.
- This is followed by the third step, which is decisive for the functioning of the BST layer, namely about 3 minutes.
- FIG 2 shows the temperature-time diagram of the in FIG described manufacturing process.
Landscapes
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Manufacturing & Machinery (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Computer Hardware Design (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Materials Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Optics & Photonics (AREA)
- Semiconductor Memories (AREA)
- Semiconductor Integrated Circuits (AREA)
- Non-Volatile Memory (AREA)
Abstract
Description
- FIG 1
- zeigt eine Speicherzelle einer integrierten Halbleiterschaltung, bei der das Verfahren eingesetzt werden kann,
- FIG 2
- zeigt ein Temperatur-Zeit-Diagramm eines Ausführungsbeispieles der Erfindung.
Claims (6)
- Herstellverfahren für eine hoch-ε-dielektrische oder eine ferroelektrische Schicht (10) auf einem Träger (1 bis 9) mit folgenden Schritten:1) Aufsputtern der Schicht (10) bei einer niedrigen Temperatur T1, die unter 500°C liegt,2) Durchführen eines RTP-Schritts in einer inerten Atmosphäre bei einer Temperatur T2, die im Bereich 500 - 900°C liegt,3) Temperung der Schicht (10) in einer sauerstoffhaltigen Atmosphäre bei einer Temperatur T3, die im Bereich 200 - 600°C liegt.
- Herstellverfahren nach Anspruch 1, bei dem die Temperatur T2 im Bereich von 600 bis 800°C liegt.
- Herstellverfahren nach einem der Ansprüche 1 bis 2, bei dem die Temperatur T3 im Bereich von 300 bis 500°C liegt.
- Herstellverfahren nach einem der Ansprüche 1 bis 3, bei dem der zweite Schritt einer stickstoffhaltigen Atmosphäre durchgeführt wird.
- Herstellverfahren nach einem der Ansprüche 1 bis 4, bei dem die Atmosphäre im dritten Schritt aus Sauerstoff oder Luft besteht und die Zeitdauer 1 bis 15 min. beträgt.
- Verwendung des Verfahrens nach einem der Ansprüche 1 bis 5 bei der Herstellung eines Kondensatordielektrikums in einer integrierten Speicherzelle.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19640241 | 1996-09-30 | ||
DE19640241A DE19640241C1 (de) | 1996-09-30 | 1996-09-30 | Herstellverfahren für eine hoch-epsilon-dielektrische oder ferroelektrische Schicht und Verwendung des Verfahrens |
PCT/DE1997/002131 WO1998014993A1 (de) | 1996-09-30 | 1997-09-19 | HERSTELLVERFAHREN FÜR EINE HOCH-ε-DIELEKTRISCHE ODER FERROELEKTRISCHE SCHICHT |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0931333A1 EP0931333A1 (de) | 1999-07-28 |
EP0931333B1 true EP0931333B1 (de) | 2002-11-27 |
Family
ID=7807401
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP97910214A Expired - Lifetime EP0931333B1 (de) | 1996-09-30 | 1997-09-19 | Herstellverfahren für eine hoch-epsilon-dielektrische oder ferroelektrische schicht |
Country Status (8)
Country | Link |
---|---|
US (1) | US6346424B1 (de) |
EP (1) | EP0931333B1 (de) |
JP (1) | JP3416150B2 (de) |
KR (1) | KR100325439B1 (de) |
CN (1) | CN1111903C (de) |
DE (2) | DE19640241C1 (de) |
TW (1) | TW442921B (de) |
WO (1) | WO1998014993A1 (de) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TW404021B (en) * | 1998-04-09 | 2000-09-01 | Hitachi Ltd | Semiconductor memory device and manufacturing method thereof |
US6495412B1 (en) | 1998-09-11 | 2002-12-17 | Fujitsu Limited | Semiconductor device having a ferroelectric capacitor and a fabrication process thereof |
US6346892B1 (en) | 1999-05-07 | 2002-02-12 | Honeywell International Inc. | Method and apparatus for aircraft systems management |
US6451666B2 (en) * | 1999-12-27 | 2002-09-17 | Hyundai Electronics Industries Co., Ltd | Method for forming a lower electrode by using an electroplating method |
US6372518B1 (en) * | 2000-01-26 | 2002-04-16 | Matsushita Electric Industrial Co., Ltd. | Method using unreactive gas anneal and low temperature pretreatment for fabricating layered superlattice materials and making electronic devices including same |
DE10105673C2 (de) * | 2001-02-08 | 2003-04-17 | Infineon Technologies Ag | Verfahren zur Herstellung eines nach dem Stackprinzip aufgebauten integrierten ferroelektrischen Halbleiterspeichers oder eines DRAM-Halbleiters mit Hoch-epsilon-Material |
US20050084984A1 (en) * | 2003-10-02 | 2005-04-21 | Haoren Zhuang | Method for forming ferrocapacitors and FeRAM devices |
RU2671614C1 (ru) * | 2017-06-19 | 2018-11-02 | Федеральное государственное автономное образовательное учреждение высшего образования "Санкт-Петербургский государственный электротехнический университет "ЛЭТИ" им. В.И. Ульянова (Ленина) | Способ получения сегнетоэлектрических пленок Ba1-xSrx TiO3 |
RU2700901C1 (ru) * | 2019-02-07 | 2019-09-23 | Федеральное государственное автономное образовательное учреждение высшего образования "Санкт-Петербургский государственный электротехнический университет "ЛЭТИ" им. В.И. Ульянова (Ленина) | Способ получения сегнетоэлектрических пленок Βа1-хSrхTiO3 |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5063422A (en) * | 1988-06-20 | 1991-11-05 | At&T Bell Laboratories | Devices having shallow junctions |
JPH02208937A (ja) * | 1989-02-08 | 1990-08-20 | Seiko Epson Corp | 強誘電体膜の製造方法 |
KR940006708B1 (ko) * | 1989-01-26 | 1994-07-25 | 세이꼬 엡슨 가부시끼가이샤 | 반도체 장치의 제조 방법 |
KR950000156B1 (ko) * | 1989-02-08 | 1995-01-10 | 세이꼬 엡슨 가부시끼가이샤 | 반도체 장치 |
JP3119997B2 (ja) * | 1994-06-21 | 2000-12-25 | 松下電子工業株式会社 | 半導体装置の製造方法 |
-
1996
- 1996-09-30 DE DE19640241A patent/DE19640241C1/de not_active Expired - Fee Related
-
1997
- 1997-09-19 EP EP97910214A patent/EP0931333B1/de not_active Expired - Lifetime
- 1997-09-19 WO PCT/DE1997/002131 patent/WO1998014993A1/de active IP Right Grant
- 1997-09-19 KR KR1019997002372A patent/KR100325439B1/ko not_active IP Right Cessation
- 1997-09-19 DE DE59708837T patent/DE59708837D1/de not_active Expired - Lifetime
- 1997-09-19 JP JP51612098A patent/JP3416150B2/ja not_active Expired - Fee Related
- 1997-09-19 CN CN97198370A patent/CN1111903C/zh not_active Expired - Fee Related
- 1997-10-14 TW TW086114129A patent/TW442921B/zh not_active IP Right Cessation
-
1999
- 1999-03-30 US US09/282,094 patent/US6346424B1/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
DE19640241C1 (de) | 1998-04-16 |
US6346424B1 (en) | 2002-02-12 |
EP0931333A1 (de) | 1999-07-28 |
KR20010029534A (ko) | 2001-04-06 |
DE59708837D1 (de) | 2003-01-09 |
JP2000503725A (ja) | 2000-03-28 |
TW442921B (en) | 2001-06-23 |
JP3416150B2 (ja) | 2003-06-16 |
WO1998014993A1 (de) | 1998-04-09 |
CN1111903C (zh) | 2003-06-18 |
CN1231760A (zh) | 1999-10-13 |
KR100325439B1 (ko) | 2002-02-25 |
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