EP0920486B1 - Assouplissant textile aqueux a haut potentiel zeta - Google Patents

Assouplissant textile aqueux a haut potentiel zeta Download PDF

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Publication number
EP0920486B1
EP0920486B1 EP97927127A EP97927127A EP0920486B1 EP 0920486 B1 EP0920486 B1 EP 0920486B1 EP 97927127 A EP97927127 A EP 97927127A EP 97927127 A EP97927127 A EP 97927127A EP 0920486 B1 EP0920486 B1 EP 0920486B1
Authority
EP
European Patent Office
Prior art keywords
fatty
weight
carbon atoms
fatty acids
fabric softeners
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP97927127A
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German (de)
English (en)
Other versions
EP0920486A2 (fr
EP0920486B2 (fr
Inventor
Ansgar Behler
Anneliese Wilsch-Irrgang
Theodor Völkel
Bernhard Guckenbiehl
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Cognis IP Management GmbH
Original Assignee
Cognis Deutschland GmbH and Co KG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=7796957&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=EP0920486(B1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Cognis Deutschland GmbH and Co KG filed Critical Cognis Deutschland GmbH and Co KG
Publication of EP0920486A2 publication Critical patent/EP0920486A2/fr
Publication of EP0920486B1 publication Critical patent/EP0920486B1/fr
Application granted granted Critical
Publication of EP0920486B2 publication Critical patent/EP0920486B2/fr
Anticipated expiration legal-status Critical
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Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2003Alcohols; Phenols
    • C11D3/2006Monohydric alcohols
    • C11D3/201Monohydric alcohols linear
    • C11D3/2013Monohydric alcohols linear fatty or with at least 8 carbon atoms in the alkyl chain
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38Cationic compounds
    • C11D1/645Mixtures of compounds all of which are cationic
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/835Mixtures of non-ionic with cationic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005Other compounding ingredients characterised by their effect
    • C11D3/001Softening compositions
    • C11D3/0015Softening compositions liquid
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38Cationic compounds
    • C11D1/42Amino alcohols or amino ethers
    • C11D1/44Ethers of polyoxyalkylenes with amino alcohols; Condensation products of epoxyalkanes with amines
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38Cationic compounds
    • C11D1/52Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
    • C11D1/525Carboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain two or more hydroxy groups per alkyl group, e.g. R3 being a reducing sugar rest
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38Cationic compounds
    • C11D1/62Quaternary ammonium compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/662Carbohydrates or derivatives
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/667Neutral esters, e.g. sorbitan esters
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/72Ethers of polyoxyalkylene glycols

Claims (8)

  1. Assouplissant pour textile sous la forme d'une dispersion aqueuse d'un composant d'ensimage.
    caractérisé en ce que
    le composant d'ensimage, par rapport au poids de l'assouplissant pour textiles, se compose de 0,5 à 20 % en poids d'au moins un corps gras non ionique et de 0,2 à 10 % en poids d'un émulsiflant cationique soluble dans l'eau et/ou Insoluble dans l'eau, et de 0 à 10 % en poids d'un émulsifiant non ionique, le rapport pondéral entre le corps gras et l'émulsiflant se situant entre 10:1 et 0,5:1, et sous réserve que le potentiel zêta de la dispersion aqueuse à un pH de 7 et à une température de 25°C s'élève au moins à +30 mV.
  2. Assouplissant pour textile selon la revendication 1,
    caractérisé en ce que
    le corps gras non ionique Insoluble dans l'eau est choisi dans le groupe des esters d'acides gras provenant d'acides gras comportant de 12 à 22 atomes de carbone avec des alcools mono- ou polyvalents comportant de 1 à 22 atomes de carbone, ainsi que d'acides gras et d'alcools gras comportant de 12 à 22 atomes de carbone et de mélanges de ces substances.
  3. Assouplissant pour textile selon l'une des revendications 1 ou 2,
    caractérisé en ce que
    le solide est un mono- ou diester d'acides gras avec le pentaélythritol, un monoester et un diester d'acides gras en C12 à C18 avec la glycérine, ou un monoester d'acides gras en C12 à C18 avec des alcools gras en C12 à C18.
  4. Assouplissant pour textile selon l'une des revendications 1 à 3,
    caractérisé en ce que
    l'émulsifiant cationique insoluble dans l'eau est choisi dans le groupe des composés d'ammonium quaternaire de formules (I) et (II)
    Figure 00170001
    dans lesquelles R représente un radical alkyle acyclique comportant de 12 à 24 atomes de carbone, R1 représente un radical alkyle ou hydroxyalkyle en C1 à C4 saturé, R2 est ou bien identique à R ou bien à R1. et COR3 représente un radical acyle aliphatique comportant de 12 à 22 atomes de carbone avec 0, 1, 2 ou 3 doubles liaisons, et R4 représente H ou OH. n prenant les valeurs 1, 2 ou 3 et X représentant un ion halogénure, méthosulfate, méthophosphate ou phosphate, ainsi que les mélanges de ces composés.
  5. Assouplissant pour textile selon l'une des revendications 1 à 4,
    caractérisé en ce que
    l'émulsifiant non ionique est choisi dans le groupe des acides gras alcoxylés comportant de 12 à 22 atomes de carbone, des esters d'acides gras alcoxylés provenant d'acides gras comportant de 12 à 22 atomes de carbone avec des alcools comportant de 1 à 10 atomes de carbone, d'alcools gras alcoxylés comportant de 12 à 22 atomes de carbone, les composés alcoxylés présentant des valeurs d'équilibre hydrophile-lipophile comprises entre 3 et 20, ainsi que d'amides d'acides gras et de monoacanolamides dérivés d'acides gras en C12 à C22 avec des amines ou des alcanolamines comportant de 1 à 9 atomes de carbone, ainsi que d'alkylglycosides ou de glucamides.
  6. Assouplissant pour textiles selon l'une des revendications 1 à 5,
    caractérisé en ce que
    la dispersion aqueuse à pH = 7 et à une température de 25°C présente un potentiel zêta d'au moins +40 mV.
  7. Assouplissant pour textiles selon l'une des revendications 1 à 6,
    caractérisé en ce que
    la dispersion aqueuse à pH 8 et à une température de 25°C présente un potentiel zêta d'au moins + 25 mV.
  8. Assouplissant pour textiles selon l'une des revendications 1 à 6,
    caractérisé en ce que
    le rapport pondéral entre la matière grasse et l'émulsifiant se situe entre 1:1 et 8:1, de préférence entre 2:1 et 6:1.
EP97927127A 1996-06-14 1997-06-04 Assouplissant textile aqueux a haut potentiel zeta Expired - Lifetime EP0920486B2 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE19623764A DE19623764A1 (de) 1996-06-14 1996-06-14 Wäßriges Wäscheweichspülmittel mit hohem Zeta-Potential
DE19623764 1996-06-14
PCT/EP1997/002892 WO1997047716A2 (fr) 1996-06-14 1997-06-04 Assouplissant textile aqueux a haut potentiel zeta

Publications (3)

Publication Number Publication Date
EP0920486A2 EP0920486A2 (fr) 1999-06-09
EP0920486B1 true EP0920486B1 (fr) 2002-01-16
EP0920486B2 EP0920486B2 (fr) 2004-10-13

Family

ID=7796957

Family Applications (1)

Application Number Title Priority Date Filing Date
EP97927127A Expired - Lifetime EP0920486B2 (fr) 1996-06-14 1997-06-04 Assouplissant textile aqueux a haut potentiel zeta

Country Status (5)

Country Link
EP (1) EP0920486B2 (fr)
AT (1) ATE212050T1 (fr)
DE (2) DE19623764A1 (fr)
ES (1) ES2171950T5 (fr)
WO (1) WO1997047716A2 (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8232239B2 (en) 2010-03-09 2012-07-31 Ecolab Usa Inc. Liquid concentrated fabric softener composition
US8673838B2 (en) 2011-06-22 2014-03-18 Ecolab Usa Inc. Solid concentrated fabric softener composition
US9150819B2 (en) 2007-06-15 2015-10-06 Ecolab Usa Inc. Solid fabric conditioner composition and method of use

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0919608A1 (fr) * 1997-11-25 1999-06-02 The Procter & Gamble Company Utilisation d'un composé polyhydroxy-alkyl-amide d'acide gras comme agennet adoucissant
AU2769299A (en) * 1998-02-19 1999-09-06 Colgate-Palmolive Company, The Stable rinse cycle fabric softener composition with glycerol monostearate co-softener
US6057285A (en) * 1998-02-19 2000-05-02 Colgate-Palmolive Co. Stable rinse cycle fabric softener composition with GMS co-softener
GB0014891D0 (en) * 2000-06-16 2000-08-09 Unilever Plc Fabric softening compositions
US20020187911A1 (en) * 2001-03-05 2002-12-12 Goldschmist Chemical Company Viscosity and softening enhancement by low-solids rinse cycle fabric softeners based on quaternary ammonium compounds and amine ethoxylates
US7893014B2 (en) 2006-12-21 2011-02-22 Gregory Van Buskirk Fabric treatment for stain release
US10900168B2 (en) 2002-04-09 2021-01-26 Gregory van Buskirk Fabric treatment for stain repellency
US10822577B2 (en) 2002-04-09 2020-11-03 Gregory van Buskirk Fabric treatment method for stain release
GB0213263D0 (en) * 2002-06-10 2002-07-17 Unilever Plc Improvements relating to fabric detergent compositions
US8470756B2 (en) * 2009-03-17 2013-06-25 S.C. Johnson & Son, Inc. Eco-friendly laundry pretreatment compositions
US9688945B2 (en) 2014-11-21 2017-06-27 Ecolab Usa Inc. Compositions to boost fabric softener performance
US9725679B2 (en) 2014-11-21 2017-08-08 Ecolab Usa Inc. Compositions to boost fabric softener performance
US9506015B2 (en) 2014-11-21 2016-11-29 Ecolab Usa Inc. Compositions to boost fabric softener performance
WO2023105205A1 (fr) 2021-12-06 2023-06-15 Reckitt Benckiser Health Limited Composition de désinfection et d'adoucissement du linge

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2733493C2 (de) * 1976-05-17 1986-11-13 Henkel KGaA, 4000 Düsseldorf Glättemittel für Textilfasermaterial
GB1601359A (en) 1977-05-30 1981-10-28 Procter & Gamble Textile treating composition
GB1601360A (en) * 1977-07-12 1981-10-28 Procter & Gamble Textile treatment composition
US4320013A (en) 1980-06-10 1982-03-16 The Procter & Gamble Company Fabric conditioning compositions
JP2688719B2 (ja) * 1990-09-25 1997-12-10 ユシロ化学工業株式会社 繊維処理用油剤
NO300383B1 (no) * 1991-09-06 1997-05-20 Colgate Palmolive Co Softergentblanding
WO1994019439A1 (fr) 1993-02-25 1994-09-01 Unilever Plc Utilisation d'une composition assouplissante pour tissus
DE4437032A1 (de) * 1994-10-17 1996-04-18 Henkel Kgaa Textile Weichmacher-Konzentrate

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9150819B2 (en) 2007-06-15 2015-10-06 Ecolab Usa Inc. Solid fabric conditioner composition and method of use
US8232239B2 (en) 2010-03-09 2012-07-31 Ecolab Usa Inc. Liquid concentrated fabric softener composition
US8367601B2 (en) 2010-03-09 2013-02-05 Ecolab Usa Inc. Liquid concentrated fabric softener composition
US8673838B2 (en) 2011-06-22 2014-03-18 Ecolab Usa Inc. Solid concentrated fabric softener composition
US9388366B2 (en) 2011-06-22 2016-07-12 Ecolab Usa Inc. Solid concentrated fabric softener composition

Also Published As

Publication number Publication date
WO1997047716A3 (fr) 1998-03-05
WO1997047716A2 (fr) 1997-12-18
EP0920486A2 (fr) 1999-06-09
ATE212050T1 (de) 2002-02-15
ES2171950T3 (es) 2002-09-16
EP0920486B2 (fr) 2004-10-13
DE19623764A1 (de) 1997-12-18
ES2171950T5 (es) 2005-04-16
DE59706021D1 (de) 2002-02-21

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