EP0920486B1 - Assouplissant textile aqueux a haut potentiel zeta - Google Patents

Assouplissant textile aqueux a haut potentiel zeta Download PDF

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Publication number
EP0920486B1
EP0920486B1 EP97927127A EP97927127A EP0920486B1 EP 0920486 B1 EP0920486 B1 EP 0920486B1 EP 97927127 A EP97927127 A EP 97927127A EP 97927127 A EP97927127 A EP 97927127A EP 0920486 B1 EP0920486 B1 EP 0920486B1
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EP
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Prior art keywords
fatty
weight
carbon atoms
fatty acids
fabric softeners
Prior art date
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EP97927127A
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German (de)
English (en)
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EP0920486A2 (fr
EP0920486B2 (fr
Inventor
Ansgar Behler
Anneliese Wilsch-Irrgang
Theodor Völkel
Bernhard Guckenbiehl
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Cognis IP Management GmbH
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Cognis Deutschland GmbH and Co KG
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2006—Monohydric alcohols
    • C11D3/201—Monohydric alcohols linear
    • C11D3/2013—Monohydric alcohols linear fatty or with at least 8 carbon atoms in the alkyl chain
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/645—Mixtures of compounds all of which are cationic
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/835—Mixtures of non-ionic with cationic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/001—Softening compositions
    • C11D3/0015—Softening compositions liquid
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/42—Amino alcohols or amino ethers
    • C11D1/44—Ethers of polyoxyalkylenes with amino alcohols; Condensation products of epoxyalkanes with amines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
    • C11D1/525—Carboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain two or more hydroxy groups per alkyl group, e.g. R3 being a reducing sugar rest
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/62—Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/662—Carbohydrates or derivatives
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/667—Neutral esters, e.g. sorbitan esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols

Definitions

  • the present invention relates to aqueous dispersions, the fatty substances and emulsifiers contain, as a fabric softener, which is characterized by a high positive zeta potential Mark dispersion.
  • Textile treatment agents that have a softening effect on laundry are well known. They are usually used in the last rinse of a machine wash and give the laundry a pleasant, soft feel, as it is a distinctive one Have sorption capacity on a wide variety of fiber surfaces. The occupancy the fiber with the long-chain molecules leads to a sliding effect between the fibers and thus prevents the water or dry rigidity required for the hard grip of the fabric responsible for.
  • a possible adsorption mechanism for drawing up softening Materials consist in the electrostatic attraction between the e.g. by Alkaline wash negatively charged fiber surface and positively charged plasticizer particles.
  • Statements about the size and the sign of the surface charge can be obtained by measuring the so-called zeta potential, which is the galvanic voltage at the diffuse electrochemical double layer at the phase boundary between the surface of a solid, for example a dispersed plasticizer, and a liquid, for example the washing liquor.
  • zeta potential is the galvanic voltage at the diffuse electrochemical double layer at the phase boundary between the surface of a solid, for example a dispersed plasticizer, and a liquid, for example the washing liquor.
  • Water-insoluble quaternaries are usually used as fabric softening agents
  • Ammonium compounds containing two long chain alkyl or alkenyl radicals are used. Commonly used compounds are ditallow dimethyl ammonium chloride or distearyl dimethyl ammonium chloride. Because such connections are ecologically questionable apply, increasingly used di-fatty acid trialkanolamine salts by reaction a trialkanolamine with technical fatty acids and subsequent quaternization are obtained, such as methyl-N- (2-hydroxyethyl) -N, N-di (tallow acyloxyethyl) ammonium methosulfate.
  • fabric softeners are offered in the form of aqueous dispersions.
  • the problem arises that the viscosity of the dispersion increases with an increasing proportion of active substance, which makes handling by the consumer more difficult, and furthermore the stability of such products is insufficient.
  • EP 043 622 B1 proposed an aqueous stable dispersion which contains 8 to 22% by weight of a water-insoluble cationic fabric softener, and a viscosity-regulating system containing 0.5 to 6% by weight C 10-24 hydrocarbons, C 10-24 fatty acids or C 10-24 fatty acid esters from fatty acids with short-chain alcohols or C 10-24 fatty alcohols and 0.05 to 1% by weight of a water-soluble cationic polymer.
  • the addition of polymers for viscosity control often leads to reduced performance of the fabric softener. Agents without polymeric viscosity regulators are described in DE 36 02 089 C2.
  • the compositions contain a fatty alcohol with 10 to 24 carbon atoms, the weight ratio between cationic softeners to fatty alcohols being between 3.5: 1 and 6: 1.
  • Ethoxylated amines are used as emulsifiers.
  • Solid agents are known from German patent application 42 32 448 A1 which contain quaternary difatty acid trialkanolamine ester salts and a hydroxy compound selected from the group of fatty alcohols, fatty alcohol polyglycol ethers, polyol fatty acid partial esters and carbohydrates and which are suitable for the preparation of liquid, aqueous plasticizer compositions (with 1 to 50% by weight). -% active substance).
  • the weight ratio between quaternary esteramine salt and hydroxy compound should be between 9: 1 and 1: 1.
  • a disadvantage of these agents is that relatively large amounts of ecologically unsatisfactory nitrogen-containing compounds are still used.
  • EP 497 769 A2 proposes acidic, aqueous fabric softeners which contain pentaerythritol esters as a softening component in amounts between 1 and 25% by weight and 0.1 to 10% by weight of a nonionic emulsifier and are therefore ecologically harmless.
  • the invention therefore relates to fabric softeners in the form of an aqueous dispersion a finish component, the finish component, based on the weight of the fabric softener, from 0.5 to 20% by weight of at least one nonionic Fat and 0.2 to 10 wt .-% of a water-soluble and / or water-insoluble cationic Emulsifier and 0 to 10 wt .-% of a nonionic emulsifier, wherein the weight ratio between fat and emulsifiers between 10: 1 and 0.5: 1 and the proviso that the zeta potential of the aqueous dispersion at a pH of 7 and a temperature of 25 ° C is at least + 30 mV.
  • zeta potential is a common method for characterizing solid / liquid dispersions (RJ Hunter, Zeta Potential in Colloid Science, pages 150 to 162, Academic Press, New York 1981).
  • Dispersed particles can become electrically charged, for example by adsorption of ions on their surface.
  • an electrical double layer forms on the surface of these electrically charged particles, which is firmly bonded to the particles and causes an apparent increase in volume.
  • This solid layer is enveloped by a movable and diffuse ion layer.
  • the potential ⁇ 0 on the particle surface now drops linearly within the solid ion layer with the thickness ⁇ to the value ⁇ ⁇ in order to decrease exponentially to the value 0 in the diffuse layer.
  • the potential difference between the inner solid ion layer ⁇ ⁇ and the point within the diffuse ion layer at which the potential has decreased to 1 / e • ⁇ ⁇ is called the zeta potential.
  • the rate of migration is measured depending on the size of the patient to be examined Particles either by means of light microscopic observation or, in particular for smaller particles, using laser correlation spectroscopy (W. Demtröder, laser spectroscopy: Basics and techniques, 2nd edition, Springer-Verlag, Berlin 1991, chapter 12.7 to 12.7.2).
  • the high positive zeta potential of the dispersions leads to the dispersed particles completely on the negatively charged fibers and by the full Wrapping the fibers with hydrophobic, long-chain alkyl residues is a good thing softening effect is achieved.
  • Means are particularly suitable that have a wide pH range as it is in the wash liquor, the highest possible zeta potential exhibit.
  • Dispersions according to the invention which are not particularly preferred only have a zeta potential of at least + 30 mV at a pH of 7, but the even at a pH of 8, which is often reached in the wash liquor during the wash cycle will show at least a zeta potential of + 25 mV (temperature 25 each ° C).
  • Dispersions whose zeta potential at a temperature of 25 ° C and a pH of 7 show at least + 40 mV.
  • the dispersions according to the invention contain at least one fatty substance in amounts between 0.5 and 20 wt .-%, preferably between 2 and 12 wt .-% and in particular between 4 and 6 wt .-%, based on the total amount of the agent, and the cationic Emulsifier in amounts between 0.2 and 10 wt .-%, preferably between 0.3 and 8 wt .-%, in particular between 0.4 and 6 wt .-% and optionally a nonionic Emulsifier in amounts up to 10% by weight.
  • the weight ratio between fat and emulsifier is between 10: 1 and 0.5: 1 and the amounts of the ingredients are adjusted so that the zeta potential of the dispersion at one pH of 7 and 25 ° C is at least + 30 mV. Only then is it possible that in sufficient Put a lot of softening substances on the textile fibers to get a to achieve a good softening effect.
  • Particularly preferred dispersions have a weight ratio between fat and emulsifiers between 1: 1 and 8: 1, and especially between 2: 1 and 6: 1.
  • fatty substances are understood to mean solid fats, fatty alcohols, waxes and hydrocarbons at normal temperature (20 ° C.). These include, for example, hardened fats and oils of animal and vegetable origin, as well as non-cyclic, branched and unbranched hydrocarbons with 12 to 30 carbon atoms. Examples of such compounds are tetradecane, hexadecane, octadecane and octadecene.
  • the fatty substances are preferably selected from the group of the fatty acid esters of fatty acids with 12 to 22 carbon atoms with mono- or polyhydric alcohols with 1 to 22 carbon atoms, as well as fatty acids or fatty alcohols with 12 to 22 carbon atoms and mixtures of these substances.
  • monoesters or diesters of fatty acids with pentaerythritol monoesters and diesters of C 12-18 fatty acids with glycerol or monoesters of C 12-18 fatty acids with C 12-18 fatty alcohols are preferred.
  • Examples of such compounds are lauric, myristic, palmitic or stearic acid as well as methyl and ethyl esters of these acids.
  • Examples of preferred fatty substances are technical pentaerythritol distearic acid esters or glycerol monostearic acid esters as well technical fatty alcohols.
  • Cationic emulsifiers in the context of the present application are understood to mean compounds which are selected from the group of the quaternary ammonium compounds of the formulas (I) and (II), where R is an acyclic alkyl radical having 12 to 24 carbon atoms, R 1 is a saturated C 1 -C 4 alkyl or hydroxyalkyl radical, R 2 is either R or R 1 and COR 3 is an aliphatic acyl radical having 12 to 22 carbon atoms 0, 1, 2 or 3 double bonds and R 4 is H or OH, where n is 1, 2 or 3 and X is either a halide, methosulfate, metophosphate or phosphate ion, and mixtures of these compounds. Compounds which contain alkyl radicals having 16 to 18 carbon atoms are particularly preferred.
  • Examples of cationic surfactants of the formula (I) are didecyldimethylammonium chloride, Ditallow dimethyl ammonium chloride or dihexadecyl ammonium chloride.
  • Examples of connections of the formula (II) are methyl-N- (2-hydroxyethyl) -N, N-di (tallow acyl-oxyethyl) ammonium methosulfate, Bis (palmitoyl) ethyl hydroxyethyl methyl ammonium methosulfate or methyl N, N-bis (acyloxyethyl) -N- (2-hydroxyethyl) ammonium methosulfate.
  • connections of the formulas (I) and (II) can also be short-chain, water-soluble, quaternary ammonium compounds are used, such as trihydroxyethyl methyl ammonium methosulfate or cetyl trimethyl ammonium chloride.
  • protonated alkylamine compounds have the softening effect, as well as the non-quaternized, protonated Precursors of the cationic emulsifiers are suitable.
  • the unsaturated alkyl chains have, the Acly phenomenon are preferred, the corresponding fatty acids one Iodine number between 5 and 25, preferably between 10 and 25 and in particular between 15 and 20 and which have a cis / trans isomer ratio (in% by weight) of 30:70, preferably have greater than 50:50 and in particular greater than 70:30.
  • R 7 each independently represents a C 1-4 alkyl, alkenyl or hydroxyalkyl group
  • R 8 each independently represents a C 8-28 alkyl group
  • n is a number between 0 and 5.
  • nonionic emulsifiers are understood to mean compounds which come from the group of the alkoxylated fatty acids with 12 to 22 carbon atoms, the alkoxylated fatty acid esters from fatty acids with 12 to 22 carbon atoms with alcohols with 1 to 10 carbon atoms and the alkoxylated fatty alcohols with 12 to 22 carbon atoms , where the alkoxylated compounds have HLB values between 3 and 20, and fatty acid amides and monoalkanolamides from C 12 -C 22 fatty acids with amines or alkanolamines with 1 to 9 carbon atoms, and alkylglycosides or glucamides.
  • Alkoxylated compounds with an HLB value between 3 and 20, preferably between 8 and 14 are preferred.
  • nonionic emulsifiers according to the invention are C 12-18 fatty alcohols with 7 EO, cetyl / stearyl alcohol with 20 EO or fatty acid polyglycol esters.
  • the alkyl glycosides used are compounds of the general formula RO (G) x in which R denotes a primary straight-chain or methyl-branched, in particular methyl-branched aliphatic radical having 8 to 22, preferably 12 to 18, carbon atoms and G is the symbol, which stands for a glycose unit with 5 or 6 carbon atoms, preferably for glucose.
  • the degree of oligomerization x which indicates the distribution of monoglycosides and oligoglycosides, is any number between 1 and 10; x is preferably 1.2 to 1.4.
  • Fatty acid N-alkylglucamides such as are represented by the formula (IV) are preferably used as glucamides, where R 10 is hydrogen or an alkyl group and R 9 CO is the acyl radical of caproic acid, caprylic acid, capric acid, lauric acid, myristic acid, palmitic acid, palmoleic acid, stearic acid, isostearic acid, oleic acid, elaidic acid, petroselinic acid, linoleic acid, linolenic acid, arachic acid, gadoleic acid, gadoleic acid or erucic acid or its technical mixtures.
  • Fatty acid N-alkylglucamides of the formula (IV) which are obtained by reductive amination of glucose with methylamine and subsequent acylation with lauric acid or C 12/14 coconut fatty acid or a corresponding derivative are particularly preferred.
  • the agents according to the invention can also contain other substances common in fabric softeners. These include, for example, organic ones Solvents such as ethanol or isopropyl alcohol, fungicides, enzymes, for example Cellulase, dyes, optical brighteners, lecithin, UV absorbers, preservatives, soil repellents, pearlescent agents or fragrances. Furthermore, the funds Contain electrolytes, preferably sodium, magnesium or calcium chloride, as well as pH adjusting agents such as. organic and inorganic acids.
  • the dispersions according to the invention are prepared in a manner known per se, by mixing the ingredients with the necessary amount of water, then heated to a temperature of 60 ° C and 5 to 30 minutes in a high speed mixer mixed.
  • the aqueous white rinse dispersions thus obtained have one pH between 2 and 7, preferably between 3 and 6.
  • aqueous dispersions mentioned in Examples 1 to 8 were prepared by the corresponding fatty substances are presented with the emulsifiers and water and with good Mixing were heated to 80 ° C. After the raw materials were homogeneously dispersed the cationic emulsifier was added with thorough mixing. The dispersion was cooled to 30 ° C. with moderate stirring and then the rest Components, such as perfume oils metered in.
  • the determination of the grip effect was carried out on pre-washed terry towels, equipped with the agents to be examined and then in the room air were dried.
  • the test fabrics were placed in a glass drum with those to be examined Average (concentration 15 g / kg dry wash, water hardness 16 ° d, liquor ratio 1: 5) treated for 5 minutes, with the drum in reversing movements was transferred.
  • the cloths were evaluated by a test panel (5 people) in terms of grip.
  • the zeta potential was measured using a Malvern-Zetazisers® 3 in one Temperature of 25 ° C. The respective dispersion was used to determine the zeta potential diluted 1: 400 with 0.001 molar potassium chloride solution and then the pH value with Hydrochloric acid or sodium hydroxide set to the desired value. The values given represent mean values from 5 measurements.
  • the dispersions according to the invention had a small proportion of quaternary N-containing ones Connections, good gripping properties that match the performance of the market Plasticizers are comparable, which only contain cationic N-containing as a finishing component Contain salts.
  • the two examples 7 and 8 not according to the invention and a commercial plasticizer 9 based on a known quaternary esteramine salt examined.
  • 8 represents one Combination of a cationic and two nonionic emulsifiers without a fat substance according to the invention was added.
  • Example 10 shows that the combination of the ingredients according to the invention do not necessarily lead to dispersions with high Zeta potential leads.
  • the missing amounts are up to 100% by weight Water and minor other components (electrolytes, perfume oil, auxiliaries etc.) mean.

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  • Chemical & Material Sciences (AREA)
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  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
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Claims (8)

  1. Assouplissant pour textile sous la forme d'une dispersion aqueuse d'un composant d'ensimage.
    caractérisé en ce que
    le composant d'ensimage, par rapport au poids de l'assouplissant pour textiles, se compose de 0,5 à 20 % en poids d'au moins un corps gras non ionique et de 0,2 à 10 % en poids d'un émulsiflant cationique soluble dans l'eau et/ou Insoluble dans l'eau, et de 0 à 10 % en poids d'un émulsifiant non ionique, le rapport pondéral entre le corps gras et l'émulsiflant se situant entre 10:1 et 0,5:1, et sous réserve que le potentiel zêta de la dispersion aqueuse à un pH de 7 et à une température de 25°C s'élève au moins à +30 mV.
  2. Assouplissant pour textile selon la revendication 1,
    caractérisé en ce que
    le corps gras non ionique Insoluble dans l'eau est choisi dans le groupe des esters d'acides gras provenant d'acides gras comportant de 12 à 22 atomes de carbone avec des alcools mono- ou polyvalents comportant de 1 à 22 atomes de carbone, ainsi que d'acides gras et d'alcools gras comportant de 12 à 22 atomes de carbone et de mélanges de ces substances.
  3. Assouplissant pour textile selon l'une des revendications 1 ou 2,
    caractérisé en ce que
    le solide est un mono- ou diester d'acides gras avec le pentaélythritol, un monoester et un diester d'acides gras en C12 à C18 avec la glycérine, ou un monoester d'acides gras en C12 à C18 avec des alcools gras en C12 à C18.
  4. Assouplissant pour textile selon l'une des revendications 1 à 3,
    caractérisé en ce que
    l'émulsifiant cationique insoluble dans l'eau est choisi dans le groupe des composés d'ammonium quaternaire de formules (I) et (II)
    Figure 00170001
    dans lesquelles R représente un radical alkyle acyclique comportant de 12 à 24 atomes de carbone, R1 représente un radical alkyle ou hydroxyalkyle en C1 à C4 saturé, R2 est ou bien identique à R ou bien à R1. et COR3 représente un radical acyle aliphatique comportant de 12 à 22 atomes de carbone avec 0, 1, 2 ou 3 doubles liaisons, et R4 représente H ou OH. n prenant les valeurs 1, 2 ou 3 et X représentant un ion halogénure, méthosulfate, méthophosphate ou phosphate, ainsi que les mélanges de ces composés.
  5. Assouplissant pour textile selon l'une des revendications 1 à 4,
    caractérisé en ce que
    l'émulsifiant non ionique est choisi dans le groupe des acides gras alcoxylés comportant de 12 à 22 atomes de carbone, des esters d'acides gras alcoxylés provenant d'acides gras comportant de 12 à 22 atomes de carbone avec des alcools comportant de 1 à 10 atomes de carbone, d'alcools gras alcoxylés comportant de 12 à 22 atomes de carbone, les composés alcoxylés présentant des valeurs d'équilibre hydrophile-lipophile comprises entre 3 et 20, ainsi que d'amides d'acides gras et de monoacanolamides dérivés d'acides gras en C12 à C22 avec des amines ou des alcanolamines comportant de 1 à 9 atomes de carbone, ainsi que d'alkylglycosides ou de glucamides.
  6. Assouplissant pour textiles selon l'une des revendications 1 à 5,
    caractérisé en ce que
    la dispersion aqueuse à pH = 7 et à une température de 25°C présente un potentiel zêta d'au moins +40 mV.
  7. Assouplissant pour textiles selon l'une des revendications 1 à 6,
    caractérisé en ce que
    la dispersion aqueuse à pH 8 et à une température de 25°C présente un potentiel zêta d'au moins + 25 mV.
  8. Assouplissant pour textiles selon l'une des revendications 1 à 6,
    caractérisé en ce que
    le rapport pondéral entre la matière grasse et l'émulsifiant se situe entre 1:1 et 8:1, de préférence entre 2:1 et 6:1.
EP97927127A 1996-06-14 1997-06-04 Assouplissant textile aqueux a haut potentiel zeta Expired - Lifetime EP0920486B2 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE19623764 1996-06-14
DE19623764A DE19623764A1 (de) 1996-06-14 1996-06-14 Wäßriges Wäscheweichspülmittel mit hohem Zeta-Potential
PCT/EP1997/002892 WO1997047716A2 (fr) 1996-06-14 1997-06-04 Assouplissant textile aqueux a haut potentiel zeta

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EP0920486A2 EP0920486A2 (fr) 1999-06-09
EP0920486B1 true EP0920486B1 (fr) 2002-01-16
EP0920486B2 EP0920486B2 (fr) 2004-10-13

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AT (1) ATE212050T1 (fr)
DE (2) DE19623764A1 (fr)
ES (1) ES2171950T5 (fr)
WO (1) WO1997047716A2 (fr)

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US8232239B2 (en) 2010-03-09 2012-07-31 Ecolab Usa Inc. Liquid concentrated fabric softener composition
US8673838B2 (en) 2011-06-22 2014-03-18 Ecolab Usa Inc. Solid concentrated fabric softener composition
US9150819B2 (en) 2007-06-15 2015-10-06 Ecolab Usa Inc. Solid fabric conditioner composition and method of use

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EP0919608A1 (fr) * 1997-11-25 1999-06-02 The Procter & Gamble Company Utilisation d'un composé polyhydroxy-alkyl-amide d'acide gras comme agennet adoucissant
JP2001525020A (ja) * 1998-02-19 2001-12-04 コルゲート・パーモリブ・カンパニー グリセロールモノステアレート補助柔軟剤を含む安定なすすぎ洗いサイクル布帛柔軟剤組成物
US6057285A (en) * 1998-02-19 2000-05-02 Colgate-Palmolive Co. Stable rinse cycle fabric softener composition with GMS co-softener
GB0014891D0 (en) * 2000-06-16 2000-08-09 Unilever Plc Fabric softening compositions
US20020187911A1 (en) * 2001-03-05 2002-12-12 Goldschmist Chemical Company Viscosity and softening enhancement by low-solids rinse cycle fabric softeners based on quaternary ammonium compounds and amine ethoxylates
US10900168B2 (en) 2002-04-09 2021-01-26 Gregory van Buskirk Fabric treatment for stain repellency
US7893014B2 (en) 2006-12-21 2011-02-22 Gregory Van Buskirk Fabric treatment for stain release
US10822577B2 (en) 2002-04-09 2020-11-03 Gregory van Buskirk Fabric treatment method for stain release
GB0213263D0 (en) * 2002-06-10 2002-07-17 Unilever Plc Improvements relating to fabric detergent compositions
US8470756B2 (en) * 2009-03-17 2013-06-25 S.C. Johnson & Son, Inc. Eco-friendly laundry pretreatment compositions
US9506015B2 (en) 2014-11-21 2016-11-29 Ecolab Usa Inc. Compositions to boost fabric softener performance
US9725679B2 (en) 2014-11-21 2017-08-08 Ecolab Usa Inc. Compositions to boost fabric softener performance
US9688945B2 (en) 2014-11-21 2017-06-27 Ecolab Usa Inc. Compositions to boost fabric softener performance
WO2023105205A1 (fr) 2021-12-06 2023-06-15 Reckitt Benckiser Health Limited Composition de désinfection et d'adoucissement du linge

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GB1601359A (en) † 1977-05-30 1981-10-28 Procter & Gamble Textile treating composition
GB1601360A (en) * 1977-07-12 1981-10-28 Procter & Gamble Textile treatment composition
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JP2688719B2 (ja) * 1990-09-25 1997-12-10 ユシロ化学工業株式会社 繊維処理用油剤
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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9150819B2 (en) 2007-06-15 2015-10-06 Ecolab Usa Inc. Solid fabric conditioner composition and method of use
US8232239B2 (en) 2010-03-09 2012-07-31 Ecolab Usa Inc. Liquid concentrated fabric softener composition
US8367601B2 (en) 2010-03-09 2013-02-05 Ecolab Usa Inc. Liquid concentrated fabric softener composition
US8673838B2 (en) 2011-06-22 2014-03-18 Ecolab Usa Inc. Solid concentrated fabric softener composition
US9388366B2 (en) 2011-06-22 2016-07-12 Ecolab Usa Inc. Solid concentrated fabric softener composition

Also Published As

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ES2171950T3 (es) 2002-09-16
EP0920486A2 (fr) 1999-06-09
ATE212050T1 (de) 2002-02-15
ES2171950T5 (es) 2005-04-16
WO1997047716A2 (fr) 1997-12-18
WO1997047716A3 (fr) 1998-03-05
DE59706021D1 (de) 2002-02-21
DE19623764A1 (de) 1997-12-18
EP0920486B2 (fr) 2004-10-13

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