EP0911384A2 - Lubrifiant pour convoyeurs - Google Patents
Lubrifiant pour convoyeurs Download PDFInfo
- Publication number
- EP0911384A2 EP0911384A2 EP98119747A EP98119747A EP0911384A2 EP 0911384 A2 EP0911384 A2 EP 0911384A2 EP 98119747 A EP98119747 A EP 98119747A EP 98119747 A EP98119747 A EP 98119747A EP 0911384 A2 EP0911384 A2 EP 0911384A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- acid
- substituted
- lubricant
- chain
- unsubstituted
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M105/00—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
- C10M105/56—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing nitrogen
- C10M105/68—Amides; Imides
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M129/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
- C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
- C10M129/26—Carboxylic acids; Salts thereof
- C10M129/28—Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M129/30—Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having 7 or less carbon atoms
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M133/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen
- C10M133/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of less than 30 atoms
- C10M133/04—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M133/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
- C10M133/08—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups
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- C10M133/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen
- C10M133/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of less than 30 atoms
- C10M133/16—Amides; Imides
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M145/00—Lubricating compositions characterised by the additive being a macromolecular compound containing oxygen
- C10M145/18—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M145/24—Polyethers
- C10M145/26—Polyoxyalkylenes
- C10M145/36—Polyoxyalkylenes etherified
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- C10M149/00—Lubricating compositions characterised by the additive being a macromolecular compound containing nitrogen
- C10M149/12—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
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- C10M173/00—Lubricating compositions containing more than 10% water
- C10M173/02—Lubricating compositions containing more than 10% water not containing mineral or fatty oils
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- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/02—Water
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- C10M2201/08—Inorganic acids or salts thereof
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- C10M2201/081—Inorganic acids or salts thereof containing halogen
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- C10M2201/085—Phosphorus oxides, acids or salts
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- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
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- C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
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- C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/022—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms containing at least two hydroxy groups
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- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/04—Ethers; Acetals; Ortho-esters; Ortho-carbonates
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- C10M2207/122—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms monocarboxylic
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
- C10M2223/042—Metal salts thereof
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2225/00—Organic macromolecular compounds containing phosphorus as ingredients in lubricant compositions
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2225/00—Organic macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2225/02—Macromolecular compounds from phosphorus-containg monomers, obtained by reactions involving only carbon-to-carbon unsaturated bonds
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/30—Refrigerators lubricants or compressors lubricants
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/32—Wires, ropes or cables lubricants
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/34—Lubricating-sealants
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/36—Release agents or mold release agents
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/38—Conveyors or chain belts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/40—Generators or electric motors in oil or gas winning field
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/42—Flashing oils or marking oils
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/44—Super vacuum or supercritical use
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/50—Medical uses
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2050/00—Form in which the lubricant is applied to the material being lubricated
- C10N2050/01—Emulsions, colloids, or micelles
Definitions
- the present invention relates to a lubricant based on secondary Amines and / or amides and, if appropriate, customary diluents or Auxiliaries or additives.
- the invention further relates to the use such lubricant as a chain lubricant especially in the food industry.
- the lubricants according to the invention are used in particular for lubricating, cleaning and disinfecting automatic chain and Belt lubrication systems that are used when filling foodstuffs, preferably beverages, in glass and plastic bottles, cans, glasses, barrels, beverage containers, Paper, cardboard containers and the like can be used.
- conveyor belts especially bottle conveyor belts emotional.
- Such conveyor belts generally exist Made of stainless steel and with a chain lubricant, which is also belt lubricant is called, lubricated.
- Belt lubricants of different compositions are known e.g. based on soaps (salts of fatty acids), based on carboxylated note surfactants (Ether carboxylic acids), amine-based, i.e. with primary, secondary, tertiary Amines and combinations thereof, the amines also being present as salts can.
- Belt lubricants are also based on diamines, in particular Dipropionamines, as well as based on phosphated alkanol ethoxylates.
- auxiliaries and additives solvents, Complexing agents, threshold-active substances, hydrotropes, urea, Biocides, special organic acids etc. can be used for a wide range of belt lubricants formulate.
- Typical tape lubricant formulations contain at least one alkyl diamine or its salt, excess acids and at least one ether carboxylic acid.
- DE-PS 36 31 953 describes a method for lubricating and cleaning Bottle conveyor belts, with a lubricant neutralized with acetic acid Mixture of primary fatty amines is used, which is also ethoxylated Fatty alcohols, ethoxylated fatty amines or ethoxylated nonylphenol, triethanolamine, May contain isopropanol and water.
- DE-OS 39 05 584 also relates to lubricants based on amines, the salts of secondary and / or tertiary amines being used.
- the acetate is preferably used as the anion of the amines.
- the use of ether carboxylic acids is not taught in this reference.
- U.S. Patent 5,062,978 discloses the use of alkyl diamines and organic Acids in aqueous lubricant solutions disclosed.
- WO 92/13050 discloses lubricant compositions, the diamine acetate contain.
- these compositions can be an alcohol or also include a nonionic surfactant.
- a lubricant for bottle conveyor belts which has a combination of different components, as well as a method for lubricating bottle conveyor belts and the use of the lubricant in the food industry, especially in the beverage industry, is described in DE-PS 42 44 536.
- the lubricants used for bottle conveyor belts according to DE 42 44 536 contain at least one alkyl diamine or its salt, which is formed by reaction with at least one organic acid, and, if appropriate, unreacted organic acids and at least one ether carboxylic acid.
- the ether carboxylic acids used have the general formula H 2n + 1 C n - (OC 2 H 4 ) x -O- (CH 2 ) y -COOH, where n is a number between 10 and 20, preferably between 12 and 18 and particularly preferably represents between 16 and 18, x represents a number between 1 and 20, preferably between 5 and 15 and particularly preferably between 7 and 10 and, wherein y represents a number between 0 and 5, preferably 1.
- the alkyl (C 16 -C 18 ) polyethylene glycol ether (9 EO) acetic acid is particularly preferably used.
- these lubricants also have alkyl polyethylene glycol ethers.
- Preferred examples of these compounds are alkyl (C 13 ) polyethylene glycol ethers with the following degrees of ethoxylation: 2-13 mol EO, 10-16 mol EO, 5-6 mol EO, 12 mol EO, in particular alkyl (C 13 ) polyethylene glycol ether (12 mol EO) .
- the lubricants described have a plurality of alkyl polyethylene glycol ethers.
- the lubricants are made on an aqueous basis, i.e. the lubricants contain about 60 to 90 wt .-% water.
- a preferred lubricant has the following compositions: (% By weight) Lactic acid (80%) 2-10 N-oleyl-1,3-diaminopropane 3-15 N-lauryl-1,3-diaminopropane 0.5-4.5 Alkyl (C 16 -C 18 ) polyethylene glycol ether (9EO) acetic acid 0.5-4.5 Alkyl (C 13 ) polyethylene glycol ether (6 mol EO) 0.5-3.0 Alkyl (C 13 ) polyethylene glycol ether (12 mol EO) 0.5-3.0 Rest of water (distilled, softened)
- the lubricant composition can also contain auxiliaries and / or additives contain.
- Solubilizers such as Alcohols, polyalcohols, ethers or polyethers, in particular isopropanol, butylglycol, Butyl diglycol or ethylene glycol ether.
- the amount of to use Solubilizer generally depends on the amine used.
- the pH value of the ready-to-use lubricants is preferably between about 6.5 and 7.0.
- the object of the invention was now to provide a new lubricant preparation, in particular as a chain lubricant, to provide the disadvantages of above-mentioned prior art, i.e. such lubricants should have a good coefficient of friction, i.e. an excellent lubricating effect, a low foaming behavior, a good cleaning effect and a good one Have microbicidal activity.
- the object is achieved by the lubricant according to the invention 1, the at least one secondary amine of formula I and / or at least one Salt of such an amine and / or at least one amide of the formula II and / or III or their salts.
- the lubricants according to the invention do not show that Disadvantages associated with the lubricants based on primary fatty amines are. This is all the more unexpected than even small amounts of the secondary Amines according to formula I or their salts have an excellent lubricating effect have.
- the lubricant was also based at least one amide of the formula II and / or the formula III even in small amounts Quantities, i.e. at 50 to 100 ppm has an excellent sliding effect.
- the compounds of the formulas I, II and III or their salts can either alone or in combination with one another in the lubricant according to the invention available.
- the amide of the formula II is 9-octadecenamid-N '- [3 [(3'-aminopropyl) amino] propyl] alias3-oleylamino-3'-aminodropropamine (CAS No. 36254-28-1) and the amide of the formula III 9-octadecenamid-N, N-bis (3-aminopropyl) (CAS No. 138249-75-9).
- the lubricant according to the invention can in the form of a paste and a melting range of 25 to 40 ° C. exhibit.
- Aminopolyglycol ethers are offered by various manufacturers, e.g. Marlazin types from HippoECHST AG, genamine types from HOECHST AG; Ethomeen brands by AKZO. They are mainly used as emulsifiers and as corrosion inhibitors used. However, these commercial products mainly exist (in some cases exclusively) from tertiary amines. The formation of the Secondary isomers are avoided by appropriate measures as far as possible prevented because they are for the known industrial applications of this Group of products undesirable or less powerful than the corresponding ones are tertiary aminopolyglycol ethers.
- AKZO called ETHOMEEN S / 12
- ETHOMEEN S / 12 a very important product from the Gamme the fatty amine ethoxylates, clearly as "oleylalkyldi (2-hydroxyethyl) amine” (a tertiary amine), CAS no. 25307-17-9.
- the proportion of primary and secondary amines therein expressly with ⁇ 3% specified.
- EP 0 372 628 B1 mentions tertiary fatty amine polyglycol ethers as suitable additives (Dispersants) in belt lubricants.
- the corresponding secondary aminopolyglycol ethers are not mentioned.
- the examples are intended to show the performance of the secondary amines of the invention general formula I (Examples 1 to 3) or the amides of the invention Formulas II and / or III (Examples 5 to 7) compared to the performance of commercial ones Formulations in different constellations (comparative examples 1 to 6) show.
- the tests were carried out with both softened water (examples of A series, 3 ° dH) as well as with hard water (examples of the B series, 18 ° dH).
- the coefficient of friction coefficient " ⁇ " is measured as the quotient of the Pressure [g] to the weight of the bottles [3600 g] calculated.
- the examples according to the invention therefore show that amines of the general Formula I and / or amides of the general formulas II and III already in concentrations A sufficient effect of only 50 ppm with optimal foaming behavior exhibit.
- the amines or amides according to the invention are also Insensitive to water hardness, both in terms of effectiveness and solubility and foaming behavior.
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19746675 | 1997-10-22 | ||
DE19746675 | 1997-10-22 | ||
DE19817751A DE19817751A1 (de) | 1997-10-22 | 1998-04-21 | Schmiermittel für Transportbänder |
DE19817751 | 1998-04-21 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0911384A2 true EP0911384A2 (fr) | 1999-04-28 |
EP0911384A3 EP0911384A3 (fr) | 1999-06-16 |
Family
ID=26041016
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP98119747A Withdrawn EP0911384A3 (fr) | 1997-10-22 | 1998-10-21 | Lubrifiant pour convoyeurs |
Country Status (1)
Country | Link |
---|---|
EP (1) | EP0911384A3 (fr) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2928649A1 (fr) * | 2008-03-12 | 2009-09-18 | Ceca Sa Sa | Lubrifiant pour chaine transporteuse de recipients |
EP2520166A1 (fr) * | 2011-05-04 | 2012-11-07 | Taminco | Nouveaux bisaminopropylamides et utilisations associées aux compositions agricoles et détergentes |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB657419A (en) * | 1939-05-20 | 1951-09-19 | Nopco Chem Co | Improvements relating to the production of fatty polyamides |
US3859378A (en) * | 1970-07-06 | 1975-01-07 | Sandoz Ag | Antistatic finishing of plastic molding materials |
US4002785A (en) * | 1973-02-27 | 1977-01-11 | Sandoz Ltd. | Organic compound |
DE4132364A1 (de) * | 1990-03-29 | 1993-04-01 | Okura Denki Co Ltd | Verfahren zur erzeugung von ausgeformten verbundwerkstoffkoerpern aus zement und synthetischen polymeren |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2704290B2 (ja) * | 1989-06-06 | 1998-01-26 | 第一工業製薬株式会社 | 油中水型乳化剤 |
-
1998
- 1998-10-21 EP EP98119747A patent/EP0911384A3/fr not_active Withdrawn
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB657419A (en) * | 1939-05-20 | 1951-09-19 | Nopco Chem Co | Improvements relating to the production of fatty polyamides |
US3859378A (en) * | 1970-07-06 | 1975-01-07 | Sandoz Ag | Antistatic finishing of plastic molding materials |
US4002785A (en) * | 1973-02-27 | 1977-01-11 | Sandoz Ltd. | Organic compound |
DE4132364A1 (de) * | 1990-03-29 | 1993-04-01 | Okura Denki Co Ltd | Verfahren zur erzeugung von ausgeformten verbundwerkstoffkoerpern aus zement und synthetischen polymeren |
Non-Patent Citations (1)
Title |
---|
DATABASE WPI Section Ch, Week 9109 Derwent Publications Ltd., London, GB; Class A97, AN 91-060803 XP002092492 & JP 03 008426 A (DAIICHI KOGYO SEIYAKU CO LTD), 16. Januar 1991 * |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2928649A1 (fr) * | 2008-03-12 | 2009-09-18 | Ceca Sa Sa | Lubrifiant pour chaine transporteuse de recipients |
WO2009122060A2 (fr) * | 2008-03-12 | 2009-10-08 | Ceca S.A. | Lubrifiant pour chaine transporteuse de recipients |
WO2009122060A3 (fr) * | 2008-03-12 | 2009-12-03 | Ceca S.A. | Lubrifiant pour chaine transporteuse de recipients |
EP2520166A1 (fr) * | 2011-05-04 | 2012-11-07 | Taminco | Nouveaux bisaminopropylamides et utilisations associées aux compositions agricoles et détergentes |
WO2012150343A1 (fr) * | 2011-05-04 | 2012-11-08 | Taminco | Nouvelles compositions agricoles et détergentes contenant un amide tertiaire en tant qu'adjuvant ou tensioactif |
CN103547151A (zh) * | 2011-05-04 | 2014-01-29 | 塔明克公司 | 含有叔酰胺作为助剂或作为表面活性剂的新农业和清洁剂组合物 |
US20140080708A1 (en) * | 2011-05-04 | 2014-03-20 | Taminco | Agricultural and detergent compositions containing a tertiary amide as adjuvant or as surfactant |
BE1021290B1 (nl) * | 2011-05-04 | 2015-10-22 | Taminco | Nieuwe landbouw- en detergentsamenstellingen die een tertiair amide bevatten als hulpstof of als oppervlakte-actieve stof |
CN103547151B (zh) * | 2011-05-04 | 2016-05-25 | 塔明克公司 | 含有叔酰胺作为助剂或作为表面活性剂的农业和清洁剂组合物 |
US9992994B2 (en) | 2011-05-04 | 2018-06-12 | Taminco Bvba | Agricultural and detergent compositions containing a tertiary amide as adjuvant or as surfactant |
Also Published As
Publication number | Publication date |
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EP0911384A3 (fr) | 1999-06-16 |
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