EP0884954A1 - Siliermittel - Google Patents
SiliermittelInfo
- Publication number
- EP0884954A1 EP0884954A1 EP97905121A EP97905121A EP0884954A1 EP 0884954 A1 EP0884954 A1 EP 0884954A1 EP 97905121 A EP97905121 A EP 97905121A EP 97905121 A EP97905121 A EP 97905121A EP 0884954 A1 EP0884954 A1 EP 0884954A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- silage
- ensiling
- bacteria
- acid
- inhibitors
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 241000894006 Bacteria Species 0.000 claims abstract description 35
- 239000003112 inhibitor Substances 0.000 claims abstract description 25
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 19
- 230000000696 methanogenic effect Effects 0.000 claims abstract description 15
- 239000004460 silage Substances 0.000 claims description 53
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims description 30
- 239000000654 additive Substances 0.000 claims description 16
- 235000014655 lactic acid Nutrition 0.000 claims description 15
- 239000004310 lactic acid Substances 0.000 claims description 15
- 230000000996 additive effect Effects 0.000 claims description 13
- 238000000855 fermentation Methods 0.000 claims description 13
- 230000004151 fermentation Effects 0.000 claims description 13
- 238000006731 degradation reaction Methods 0.000 claims description 9
- 150000003839 salts Chemical class 0.000 claims description 9
- 239000002253 acid Substances 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 8
- 230000008569 process Effects 0.000 claims description 6
- 239000004459 forage Substances 0.000 claims description 5
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 150000007524 organic acids Chemical class 0.000 claims description 4
- 235000005985 organic acids Nutrition 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims description 4
- 241000194036 Lactococcus Species 0.000 claims description 3
- 241000192132 Leuconostoc Species 0.000 claims description 3
- 229930191564 Monensin Natural products 0.000 claims description 3
- GAOZTHIDHYLHMS-UHFFFAOYSA-N Monensin A Natural products O1C(CC)(C2C(CC(O2)C2C(CC(C)C(O)(CO)O2)C)C)CCC1C(O1)(C)CCC21CC(O)C(C)C(C(C)C(OC)C(C)C(O)=O)O2 GAOZTHIDHYLHMS-UHFFFAOYSA-N 0.000 claims description 3
- 229960005358 monensin Drugs 0.000 claims description 3
- GAOZTHIDHYLHMS-KEOBGNEYSA-N monensin A Chemical compound C([C@@](O1)(C)[C@H]2CC[C@@](O2)(CC)[C@H]2[C@H](C[C@@H](O2)[C@@H]2[C@H](C[C@@H](C)[C@](O)(CO)O2)C)C)C[C@@]21C[C@H](O)[C@@H](C)[C@@H]([C@@H](C)[C@@H](OC)[C@H](C)C(O)=O)O2 GAOZTHIDHYLHMS-KEOBGNEYSA-N 0.000 claims description 3
- 241000193798 Aerococcus Species 0.000 claims description 2
- 239000005711 Benzoic acid Substances 0.000 claims description 2
- 241000206594 Carnobacterium Species 0.000 claims description 2
- 241000192001 Pediococcus Species 0.000 claims description 2
- 241000191940 Staphylococcus Species 0.000 claims description 2
- 241000194017 Streptococcus Species 0.000 claims description 2
- 235000010233 benzoic acid Nutrition 0.000 claims description 2
- 150000003628 tricarboxylic acids Chemical class 0.000 claims description 2
- 125000001931 aliphatic group Chemical group 0.000 claims 1
- 238000002360 preparation method Methods 0.000 claims 1
- 235000002639 sodium chloride Nutrition 0.000 description 10
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 8
- 241001112696 Clostridia Species 0.000 description 7
- 241000196324 Embryophyta Species 0.000 description 7
- 244000025254 Cannabis sativa Species 0.000 description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Chemical class CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 6
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 6
- 235000000346 sugar Nutrition 0.000 description 6
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical class [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 5
- 244000005700 microbiome Species 0.000 description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical class [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 4
- 239000004280 Sodium formate Substances 0.000 description 4
- 150000007513 acids Chemical class 0.000 description 4
- 235000014633 carbohydrates Nutrition 0.000 description 4
- 150000001720 carbohydrates Chemical class 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000011780 sodium chloride Chemical class 0.000 description 4
- HLBBKKJFGFRGMU-UHFFFAOYSA-M sodium formate Chemical compound [Na+].[O-]C=O HLBBKKJFGFRGMU-UHFFFAOYSA-M 0.000 description 4
- 235000019254 sodium formate Nutrition 0.000 description 4
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical class [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 4
- JXKPEJDQGNYQSM-UHFFFAOYSA-M sodium propionate Chemical compound [Na+].CCC([O-])=O JXKPEJDQGNYQSM-UHFFFAOYSA-M 0.000 description 4
- 235000010334 sodium propionate Nutrition 0.000 description 4
- 239000004324 sodium propionate Substances 0.000 description 4
- 229960003212 sodium propionate Drugs 0.000 description 4
- 230000004580 weight loss Effects 0.000 description 4
- GMPYNOTVKNXELU-UHFFFAOYSA-N 1-bromoethanesulfonic acid Chemical compound CC(Br)S(O)(=O)=O GMPYNOTVKNXELU-UHFFFAOYSA-N 0.000 description 3
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical class COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 235000013339 cereals Nutrition 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- -1 for example Chemical class 0.000 description 3
- 235000019253 formic acid Nutrition 0.000 description 3
- 235000021374 legumes Nutrition 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 235000019260 propionic acid Nutrition 0.000 description 3
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical class O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 102000004190 Enzymes Human genes 0.000 description 2
- 108090000790 Enzymes Proteins 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 241000186660 Lactobacillus Species 0.000 description 2
- 240000004658 Medicago sativa Species 0.000 description 2
- 235000017587 Medicago sativa ssp. sativa Nutrition 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical class OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 240000008042 Zea mays Species 0.000 description 2
- 235000016383 Zea mays subsp huehuetenangensis Nutrition 0.000 description 2
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 2
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 2
- 235000011130 ammonium sulphate Nutrition 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical class C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 description 2
- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 description 2
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 229940039696 lactobacillus Drugs 0.000 description 2
- 235000009973 maize Nutrition 0.000 description 2
- 239000011707 mineral Chemical class 0.000 description 2
- 235000010755 mineral Nutrition 0.000 description 2
- 235000013379 molasses Nutrition 0.000 description 2
- 235000015097 nutrients Nutrition 0.000 description 2
- 239000001103 potassium chloride Chemical class 0.000 description 2
- 235000011164 potassium chloride Nutrition 0.000 description 2
- RXWNCPJZOCPEPQ-NVWDDTSBSA-N puromycin Chemical compound C1=CC(OC)=CC=C1C[C@H](N)C(=O)N[C@H]1[C@@H](O)[C@H](N2C3=NC=NC(=C3N=C2)N(C)C)O[C@@H]1CO RXWNCPJZOCPEPQ-NVWDDTSBSA-N 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical class [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 description 2
- 235000010262 sodium metabisulphite Nutrition 0.000 description 2
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical class [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 2
- 235000010288 sodium nitrite Nutrition 0.000 description 2
- 239000004334 sorbic acid Chemical class 0.000 description 2
- 235000010199 sorbic acid Nutrition 0.000 description 2
- 229940075582 sorbic acid Drugs 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 241000203069 Archaea Species 0.000 description 1
- 108010001478 Bacitracin Proteins 0.000 description 1
- 108010062877 Bacteriocins Proteins 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- CBOCVOKPQGJKKJ-UHFFFAOYSA-L Calcium formate Chemical compound [Ca+2].[O-]C=O.[O-]C=O CBOCVOKPQGJKKJ-UHFFFAOYSA-L 0.000 description 1
- BCZXFFBUYPCTSJ-UHFFFAOYSA-L Calcium propionate Chemical compound [Ca+2].CCC([O-])=O.CCC([O-])=O BCZXFFBUYPCTSJ-UHFFFAOYSA-L 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 239000005909 Kieselgur Chemical class 0.000 description 1
- 240000006024 Lactobacillus plantarum Species 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 241000202974 Methanobacterium Species 0.000 description 1
- 241000202987 Methanobrevibacter Species 0.000 description 1
- 241000203357 Methanococcaceae Species 0.000 description 1
- 241000204999 Methanococcoides Species 0.000 description 1
- 241000203353 Methanococcus Species 0.000 description 1
- 241000203400 Methanocorpusculum Species 0.000 description 1
- 241000193751 Methanoculleus Species 0.000 description 1
- 241000203390 Methanogenium Species 0.000 description 1
- 241000204639 Methanohalobium Species 0.000 description 1
- 241000203006 Methanohalophilus Species 0.000 description 1
- 241000586167 Methanolacinia Species 0.000 description 1
- 241000205017 Methanolobus Species 0.000 description 1
- 241000203393 Methanomicrobiaceae Species 0.000 description 1
- 241000204679 Methanoplanus Species 0.000 description 1
- 241000205276 Methanosarcina Species 0.000 description 1
- 241000205277 Methanosarcinaceae Species 0.000 description 1
- 241000202999 Methanothermaceae Species 0.000 description 1
- 241000205011 Methanothrix Species 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- 229930040373 Paraformaldehyde Natural products 0.000 description 1
- 241000209049 Poa pratensis Species 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical class O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 244000061456 Solanum tuberosum Species 0.000 description 1
- 235000002595 Solanum tuberosum Nutrition 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 239000005862 Whey Substances 0.000 description 1
- 102000007544 Whey Proteins Human genes 0.000 description 1
- 108010046377 Whey Proteins Proteins 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 150000003868 ammonium compounds Chemical class 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 229940044197 ammonium sulfate Drugs 0.000 description 1
- 230000003625 amylolytic effect Effects 0.000 description 1
- 235000019728 animal nutrition Nutrition 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 229940088710 antibiotic agent Drugs 0.000 description 1
- JPNZKPRONVOMLL-UHFFFAOYSA-N azane;octadecanoic acid Chemical class [NH4+].CCCCCCCCCCCCCCCCCC([O-])=O JPNZKPRONVOMLL-UHFFFAOYSA-N 0.000 description 1
- 229960003071 bacitracin Drugs 0.000 description 1
- 229930184125 bacitracin Natural products 0.000 description 1
- CLKOFPXJLQSYAH-ABRJDSQDSA-N bacitracin A Chemical compound C1SC([C@@H](N)[C@@H](C)CC)=N[C@@H]1C(=O)N[C@@H](CC(C)C)C(=O)N[C@H](CCC(O)=O)C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H]1C(=O)N[C@H](CCCN)C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@H](CC=2C=CC=CC=2)C(=O)N[C@@H](CC=2N=CNC=2)C(=O)N[C@H](CC(O)=O)C(=O)N[C@@H](CC(N)=O)C(=O)NCCCC1 CLKOFPXJLQSYAH-ABRJDSQDSA-N 0.000 description 1
- 159000000009 barium salts Chemical class 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229940036811 bone meal Drugs 0.000 description 1
- 239000002374 bone meal Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 239000004281 calcium formate Substances 0.000 description 1
- 235000019255 calcium formate Nutrition 0.000 description 1
- 229940044172 calcium formate Drugs 0.000 description 1
- 239000001506 calcium phosphate Chemical class 0.000 description 1
- 229910000389 calcium phosphate Inorganic materials 0.000 description 1
- 235000011010 calcium phosphates Nutrition 0.000 description 1
- 235000010331 calcium propionate Nutrition 0.000 description 1
- 239000004330 calcium propionate Substances 0.000 description 1
- 239000000378 calcium silicate Chemical class 0.000 description 1
- 229910052918 calcium silicate Inorganic materials 0.000 description 1
- 235000012241 calcium silicate Nutrition 0.000 description 1
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical class [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 229910021446 cobalt carbonate Inorganic materials 0.000 description 1
- 229910000361 cobalt sulfate Inorganic materials 0.000 description 1
- 229940044175 cobalt sulfate Drugs 0.000 description 1
- KTVIXTQDYHMGHF-UHFFFAOYSA-L cobalt(2+) sulfate Chemical compound [Co+2].[O-]S([O-])(=O)=O KTVIXTQDYHMGHF-UHFFFAOYSA-L 0.000 description 1
- ZOTKGJBKKKVBJZ-UHFFFAOYSA-L cobalt(2+);carbonate Chemical compound [Co+2].[O-]C([O-])=O ZOTKGJBKKKVBJZ-UHFFFAOYSA-L 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 229910000365 copper sulfate Inorganic materials 0.000 description 1
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical class [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 1
- 230000001461 cytolytic effect Effects 0.000 description 1
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- 235000013305 food Nutrition 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 235000021552 granulated sugar Nutrition 0.000 description 1
- MNWFXJYAOYHMED-UHFFFAOYSA-N heptanoic acid Chemical compound CCCCCCC(O)=O MNWFXJYAOYHMED-UHFFFAOYSA-N 0.000 description 1
- 235000010299 hexamethylene tetramine Nutrition 0.000 description 1
- 239000004312 hexamethylene tetramine Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 159000000014 iron salts Chemical class 0.000 description 1
- 229910000358 iron sulfate Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 229940099596 manganese sulfate Drugs 0.000 description 1
- 239000011702 manganese sulphate Substances 0.000 description 1
- 235000007079 manganese sulphate Nutrition 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 description 1
- 235000012054 meals Nutrition 0.000 description 1
- 230000002503 metabolic effect Effects 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 150000002826 nitrites Chemical class 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000020477 pH reduction Effects 0.000 description 1
- 229920002866 paraformaldehyde Polymers 0.000 description 1
- 235000011007 phosphoric acid Nutrition 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 235000012015 potatoes Nutrition 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 229950010131 puromycin Drugs 0.000 description 1
- 230000029058 respiratory gaseous exchange Effects 0.000 description 1
- 235000015424 sodium Nutrition 0.000 description 1
- 229940001584 sodium metabisulfite Drugs 0.000 description 1
- 239000004296 sodium metabisulphite Substances 0.000 description 1
- 239000004317 sodium nitrate Chemical class 0.000 description 1
- 235000010344 sodium nitrate Nutrition 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 230000002110 toxicologic effect Effects 0.000 description 1
- 231100000027 toxicology Toxicity 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical class [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
- 241001148471 unidentified anaerobic bacterium Species 0.000 description 1
- 229940005605 valeric acid Drugs 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 229910000368 zinc sulfate Inorganic materials 0.000 description 1
- 229960001763 zinc sulfate Drugs 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23K—FODDER
- A23K30/00—Processes specially adapted for preservation of materials in order to produce animal feeding-stuffs
- A23K30/10—Processes specially adapted for preservation of materials in order to produce animal feeding-stuffs of green fodder
- A23K30/15—Processes specially adapted for preservation of materials in order to produce animal feeding-stuffs of green fodder using chemicals or microorganisms for ensilaging
Definitions
- the invention relates to a ensiling agent containing an effective amount of at least one inhibitor of methanogenic bacteria.
- the invention also relates to a process for the production of the silage additive and its use for the silageing of green fodder and the prevention of aerobic and anaerobic digestion processes in the fermentation feed.
- silage is of exceptional economic importance in animal nutrition.
- a number of additives and processes for improving the fermentation process and for improving the silage quality are known.
- the currently valid list describes the tested by the German Agricultural Society (DLG) silage additives the use of salts of formic acid and propionic acid, nitrite compounds, sorbic acid, formaldehyde-generating compounds and sugar-containing ⁇ materials such as molasses.
- DLG German Agricultural Society
- DE-A 39 16 563 describes the addition of lactic acid-producing bacteria to improve the silage quality.
- the use of effective silage additives reduces feed losses due to nutrient degradation and prevents partial or complete spreading due to incorrect fermentation.
- Important parameters for good ensiling are e.g. the buffer capacity of the forage plants, the content of the plants in antimicrobial secondary substances, the acid and osmotolerance of the naturally occurring and produced lactic acid bacteria, the metabolic performance of the natural epiphyte population, the presence of a sufficient amount of fermentable carbohydrates and anaerobic conditions in the feedstock.
- Clostridia are well-known feed and food spoilers.
- Clostridia can be suppressed by adding nitrite. Where the nitrite administration is problematic from a toxicological point of view.
- silages suffer a constant loss in weight and quality due to the respiration of sugar and starch through these undesirable microorganisms. This leads to considerable economic damage.
- the object was therefore to prevent the development of butyric acid-forming bacteria (clostridia) in the silage without the abovementioned disadvantages and thus to specifically suppress anaerobic degradation processes in the silage.
- the subject of the invention is a silage agent containing an effective amount of at least one inhibitor of methanogenic bacteria.
- the invention also relates to a method for producing the ensiling agent and its use for ensiling green fodder and preventing aerobic and anaerobic degradation processes in the fermentation feed.
- Inhibitors of methanogenic bacteria suitable for the silage additive according to the invention are all substances which selectively inhibit the growth of methaneogenic bacteria.
- Archaea are, for example, the following families and genera Methanobacteriacae, Methanobacterium, Methanobrevibacter, Methanospaera; Methanothermaceae, Methanotherumus; Methanococcaceae, Methanococcus; Methanosarcinaceae, Halomethanococcus, Methanococcoides, Methanohalobium, Methanohalophilus, Methanolobus, Methanosarcina, Methanosaeta; Methanomicrobiaceae, Methanoculleus, Methanogenium, Methanolacinia, Methanomicrobiuum, Methanoplanus, Methanospirilum; Methanocorpuscülaceae to understand Methanocorpusculum.
- Inhibitors of methanogenic bacteria are, for example, antibiotics such as puromycin and / or bacitracin, bacteriocins and / or methanogenesis inhibitors such as bromethanesulfonic acid and / or monensin.
- Methanogenesis inhibitors are preferably used as inhibitors, very particularly preferably bromoethanesulfonic acid and / or monensin.
- the inhibitors can be used alone to ensilage green fodder and prevent anaerobic degradation processes in fermentation feed or in combination with other silage aids, lactic acid produce the bacteria and / or auxiliaries for ensiling green feed and prevent aerobic and anaerobic degradation processes in fermentation feed.
- the inhibitors of methanogenic bacteria can advantageously be used in an amount of 0.001 to 10 kg, in particular 0.05 to 8 kg, most preferably 0.1 to 5 kg.
- Inorganic silage auxiliaries are, for example, calcium carbonate, magnesium carbonate, cobalt carbonate, sodium trium sulfate, ammonium sulfate, manganese sulfate, cobalt sulfate. Iron, zinc and / or copper sulfate, sodium metabisulfite, orthophosphoric acid, sodium nitrate, sodium nitrite, sodium chloride, potassium chloride, calcium phosphate, calcium silicate, diatomaceous earth, mineral acids such as hydrochloric acid and / or sulfuric acid. To be favoured, calcium carbonate, magnesium carbonate, cobalt carbonate, sodium trium sulfate, ammonium sulfate, manganese sulfate, cobalt sulfate. Iron, zinc and / or copper sulfate, sodium metabisulfite, orthophosphoric acid, sodium nitrate, sodium nitrite, sodium chloride, potassium chloride, calcium phosphate, calcium silicate,
- Organic silage auxiliaries are, for example, formaldehyde, paraformaldehyde, hexamethylenetetramine, organic acids and / or their agriculturally useful salts, without being restricted to these.
- Alphatic C 1 -C 7 -mono-, di-, tricarboxylic acids, benzoic acid and / or their agriculturally useful salts such as, for example, formic acid, acetic acid, glycolic acid, propionic acid, lactic acid, valeric acid, caproic acid, heptylic acid, acrylic acid, are preferably Maleic acid, fumaric acid, citric acid, sorbic acid are used.
- Particularly preferred acids and / or their agriculturally useful salts are citric acid, formic acid and / or propionic acid.
- Particularly preferred salts are calcium formate, sodium formate, sodium propionate and / or calcium propionate.
- Salts of the abovementioned acids which can be used in agriculture are salts of such bases which do not adversely affect the ensiling effect.
- Particularly suitable basic salts are those of the alkali metals, preferably the sodium and potassium salts, those of the alkaline earth metals, preferably calcium, magnesium and / or barium salts and the transition metals, preferably manganese, copper, Zinc, cobalt and / or iron salts and the ammonium salts.
- the silage auxiliaries can be added to the silage agent individually or in combination.
- Suitable MSB are advantageously those of the genera Lactobacillus, Lactococcus, Streptococcus, Leuconostoc, Carnobacterium, Staphylococcus, Aerococcus and / or Pediococcus.
- Microorganisms of the genus Lactococcus, Lactobacillus and / or Leuconostoc are particularly suitable.
- the genus and species Lactobacillus plantarum is particularly suitable.
- the bacteria can be used in liquid, frozen or lyphilized form. Before use, they can be mounted on a carrier and / or mixed and / or granulated with further auxiliaries.
- Suitable carriers are e.g. Calcium carbonate, bran, semolina, granulated sugar, bone meal, bolus, talcum, stearates of alkaline earths, table salt, rock salt or other minerals suitable for feeding.
- a carrier make sure that the bacteria are not damaged. Single strains of bacteria or combinations of different strains can be used.
- Auxiliaries in the sense of the invention are growth-promoting substances for microorganisms, such as products containing fermentable carbohydrates, for example molasses, boiled potatoes, grain red, dried whey, green meal, dry pulp, sugar. Starch or wood hydrolyzates.
- enzymes which break down cellulolytic, amylolytic and / or other carbohydrates or nitrogen in bound form for example urea or ammonium compounds such as ammonium sulfate, also has a growth-promoting effect.
- the silage material from fermentation feed that can be used according to the invention is not subject to any particular restriction. All easily silable feeds are suitable (slightly withered grass and other other forage plants with more than 3% sugar content in the fresh mass, withered grass> 30% dry matter, withered leguminous plants> 35% dry matter, silage maize and corncob products> 25% dry matter, whole plant cereals, moist cereals and damp maize, pressed pulp), moderately difficult to silage feed (Grass 20 to 25% dry matter, legumes 25 to 30% dry matter and other fodder plants with sugar contents of 1.5 to 3% in the fresh matter) or difficult to ensilage (grass ⁇ 20% dry matter or legumes ⁇ 20% dry matter with less as 1.5% sugar in the fresh mass as well as grass or legumes, the withering of which failed).
- the silage preferably has a moisture content of at least 50%, more preferably from 60 to 90% (corresponding to 40 to 10% dry matter).
- the ensiling agent according to the invention is the silage in a
- the silage additive can be delivered to the farmer as individual components or as a finished mixture. In this case it is advantageous to use the components in such a way that an adverse mutual influence of the components is excluded. This can be achieved, for example, by micronization. It is advantageously added to the material to be ensiled in the form of a spreadable mixture of the components. However, it can also be added separately to the silage.
- the ensiling agent is applied either by hand, an applicator or a metering device during chopping and / or during or after the green fodder has been stored.
- Alfalfa was ensiled with a dry matter content of 19% and 4 g of silage additive per kg of silage was added in all examples.
- Batch 1 (Table I) shows the control without the addition of ensiling agents.
- Run 2 shows the effect of herkömmli ⁇ chen silage additive of 50 wt -.% Sodium propionate and 50 wt -.% Of sodium formate.
- Table I ensiling of alfalfa
- Batch 3 shows the dry weight losses with a silage additive consisting of 45% by weight sodium propionate, 50% by weight sodium formate and 5% by weight bromoethanesulfonic acid as a methanogenesis inhibitor.
- Table I shows the mean values from three independent experiments each.
- methanogenesis inhibitors significantly reduces the weight loss of the silage material.
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Polymers & Plastics (AREA)
- Zoology (AREA)
- Microbiology (AREA)
- Animal Husbandry (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Fodder In General (AREA)
- Medicines Containing Material From Animals Or Micro-Organisms (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19608263 | 1996-03-04 | ||
| DE19608263A DE19608263A1 (de) | 1996-03-04 | 1996-03-04 | Siliermittel |
| PCT/EP1997/000983 WO1997032487A1 (de) | 1996-03-04 | 1997-02-28 | Siliermittel |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP0884954A1 true EP0884954A1 (de) | 1998-12-23 |
Family
ID=7787145
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP97905121A Withdrawn EP0884954A1 (de) | 1996-03-04 | 1997-02-28 | Siliermittel |
Country Status (13)
| Country | Link |
|---|---|
| EP (1) | EP0884954A1 (cs) |
| AU (1) | AU712872B2 (cs) |
| CA (1) | CA2248007A1 (cs) |
| CZ (1) | CZ275698A3 (cs) |
| DE (1) | DE19608263A1 (cs) |
| HU (1) | HUP9901816A3 (cs) |
| IL (1) | IL125252A0 (cs) |
| MX (1) | MX9806176A (cs) |
| NO (1) | NO984043L (cs) |
| PL (1) | PL328860A1 (cs) |
| SK (1) | SK116898A3 (cs) |
| WO (1) | WO1997032487A1 (cs) |
| ZA (1) | ZA971807B (cs) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10105347A1 (de) * | 2001-02-05 | 2002-08-22 | Nutrinova Gmbh | Sorbinsäurepräparat enthaltend Probiotika als Futtermittelzusatz in der Nutztieraufzucht |
| DE10110431A1 (de) * | 2001-03-05 | 2002-09-19 | Nutrinova Gmbh | Bacteriocinhaltiges Sorbinsäurepräparat als Futtermittelzusatz in der Nutztieraufzucht |
| PL2312955T3 (pl) * | 2008-07-21 | 2016-04-29 | Erber Ag | Sposób traktowania kiszonki paszowej i dodatek do kiszonki paszowej |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2940857A (en) * | 1958-12-19 | 1960-06-14 | Purdue Research Foundation | Preservation of silage |
| DE1234504B (de) * | 1960-09-03 | 1967-02-16 | Biehl & Co | Gaerfuttermittelbereitung |
| US4423224A (en) * | 1980-09-08 | 1983-12-27 | Sds Biotech Corporation | 4-Me-1-(2-(1H-tetrazol-5-yl)ethyl)benzene sulfonate and N-2-(1H-tetrazol-5-yl)ethyl methanesulfonamide |
| US4764510A (en) * | 1986-04-11 | 1988-08-16 | Eli Lilly And Company | Antibiotic A42125 and process for its production |
| DE69313655T2 (de) * | 1992-10-22 | 1998-04-02 | Bio-Technical Resources Lp, Manitowoc, Wis. | Anthraquinon-inhibierung der methanherstellung durch methanogene bakterien |
| GB9512106D0 (en) * | 1995-06-14 | 1995-08-09 | Norsk Naeringsmiddelforskning | Animal feed |
-
1996
- 1996-03-04 DE DE19608263A patent/DE19608263A1/de not_active Withdrawn
-
1997
- 1997-02-28 CZ CZ982756A patent/CZ275698A3/cs unknown
- 1997-02-28 IL IL12525297A patent/IL125252A0/xx unknown
- 1997-02-28 HU HU9901816A patent/HUP9901816A3/hu unknown
- 1997-02-28 EP EP97905121A patent/EP0884954A1/de not_active Withdrawn
- 1997-02-28 AU AU18787/97A patent/AU712872B2/en not_active Ceased
- 1997-02-28 CA CA002248007A patent/CA2248007A1/en not_active Abandoned
- 1997-02-28 WO PCT/EP1997/000983 patent/WO1997032487A1/de not_active Ceased
- 1997-02-28 SK SK1168-98A patent/SK116898A3/sk unknown
- 1997-02-28 PL PL97328860A patent/PL328860A1/xx unknown
- 1997-03-03 ZA ZA971807A patent/ZA971807B/xx unknown
-
1998
- 1998-07-31 MX MX9806176A patent/MX9806176A/es unknown
- 1998-09-03 NO NO984043A patent/NO984043L/no unknown
Non-Patent Citations (1)
| Title |
|---|
| See references of WO9732487A1 * |
Also Published As
| Publication number | Publication date |
|---|---|
| IL125252A0 (en) | 1999-03-12 |
| HUP9901816A3 (en) | 2000-03-28 |
| AU712872B2 (en) | 1999-11-18 |
| DE19608263A1 (de) | 1997-09-11 |
| WO1997032487A1 (de) | 1997-09-12 |
| SK116898A3 (en) | 1999-01-11 |
| CZ275698A3 (cs) | 1999-02-17 |
| PL328860A1 (en) | 1999-03-01 |
| CA2248007A1 (en) | 1997-09-12 |
| MX9806176A (es) | 1998-10-31 |
| AU1878797A (en) | 1997-09-22 |
| HUP9901816A2 (hu) | 1999-09-28 |
| ZA971807B (en) | 1998-09-03 |
| NO984043L (no) | 1998-11-03 |
| NO984043D0 (no) | 1998-09-03 |
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