EP0884954A1 - Siliermittel - Google Patents

Siliermittel

Info

Publication number
EP0884954A1
EP0884954A1 EP97905121A EP97905121A EP0884954A1 EP 0884954 A1 EP0884954 A1 EP 0884954A1 EP 97905121 A EP97905121 A EP 97905121A EP 97905121 A EP97905121 A EP 97905121A EP 0884954 A1 EP0884954 A1 EP 0884954A1
Authority
EP
European Patent Office
Prior art keywords
silage
ensiling
bacteria
acid
inhibitors
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP97905121A
Other languages
German (de)
English (en)
French (fr)
Inventor
Bruno Käsler
Günter Gaus
Hans Müschen
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Publication of EP0884954A1 publication Critical patent/EP0884954A1/de
Withdrawn legal-status Critical Current

Links

Classifications

    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23KFODDER
    • A23K30/00Processes specially adapted for preservation of materials in order to produce animal feeding-stuffs
    • A23K30/10Processes specially adapted for preservation of materials in order to produce animal feeding-stuffs of green fodder
    • A23K30/15Processes specially adapted for preservation of materials in order to produce animal feeding-stuffs of green fodder using chemicals or microorganisms for ensilaging

Definitions

  • the invention relates to a ensiling agent containing an effective amount of at least one inhibitor of methanogenic bacteria.
  • the invention also relates to a process for the production of the silage additive and its use for the silageing of green fodder and the prevention of aerobic and anaerobic digestion processes in the fermentation feed.
  • silage is of exceptional economic importance in animal nutrition.
  • a number of additives and processes for improving the fermentation process and for improving the silage quality are known.
  • the currently valid list describes the tested by the German Agricultural Society (DLG) silage additives the use of salts of formic acid and propionic acid, nitrite compounds, sorbic acid, formaldehyde-generating compounds and sugar-containing ⁇ materials such as molasses.
  • DLG German Agricultural Society
  • DE-A 39 16 563 describes the addition of lactic acid-producing bacteria to improve the silage quality.
  • the use of effective silage additives reduces feed losses due to nutrient degradation and prevents partial or complete spreading due to incorrect fermentation.
  • Important parameters for good ensiling are e.g. the buffer capacity of the forage plants, the content of the plants in antimicrobial secondary substances, the acid and osmotolerance of the naturally occurring and produced lactic acid bacteria, the metabolic performance of the natural epiphyte population, the presence of a sufficient amount of fermentable carbohydrates and anaerobic conditions in the feedstock.
  • Clostridia are well-known feed and food spoilers.
  • Clostridia can be suppressed by adding nitrite. Where the nitrite administration is problematic from a toxicological point of view.
  • silages suffer a constant loss in weight and quality due to the respiration of sugar and starch through these undesirable microorganisms. This leads to considerable economic damage.
  • the object was therefore to prevent the development of butyric acid-forming bacteria (clostridia) in the silage without the abovementioned disadvantages and thus to specifically suppress anaerobic degradation processes in the silage.
  • the subject of the invention is a silage agent containing an effective amount of at least one inhibitor of methanogenic bacteria.
  • the invention also relates to a method for producing the ensiling agent and its use for ensiling green fodder and preventing aerobic and anaerobic degradation processes in the fermentation feed.
  • Inhibitors of methanogenic bacteria suitable for the silage additive according to the invention are all substances which selectively inhibit the growth of methaneogenic bacteria.
  • Archaea are, for example, the following families and genera Methanobacteriacae, Methanobacterium, Methanobrevibacter, Methanospaera; Methanothermaceae, Methanotherumus; Methanococcaceae, Methanococcus; Methanosarcinaceae, Halomethanococcus, Methanococcoides, Methanohalobium, Methanohalophilus, Methanolobus, Methanosarcina, Methanosaeta; Methanomicrobiaceae, Methanoculleus, Methanogenium, Methanolacinia, Methanomicrobiuum, Methanoplanus, Methanospirilum; Methanocorpuscülaceae to understand Methanocorpusculum.
  • Inhibitors of methanogenic bacteria are, for example, antibiotics such as puromycin and / or bacitracin, bacteriocins and / or methanogenesis inhibitors such as bromethanesulfonic acid and / or monensin.
  • Methanogenesis inhibitors are preferably used as inhibitors, very particularly preferably bromoethanesulfonic acid and / or monensin.
  • the inhibitors can be used alone to ensilage green fodder and prevent anaerobic degradation processes in fermentation feed or in combination with other silage aids, lactic acid produce the bacteria and / or auxiliaries for ensiling green feed and prevent aerobic and anaerobic degradation processes in fermentation feed.
  • the inhibitors of methanogenic bacteria can advantageously be used in an amount of 0.001 to 10 kg, in particular 0.05 to 8 kg, most preferably 0.1 to 5 kg.
  • Inorganic silage auxiliaries are, for example, calcium carbonate, magnesium carbonate, cobalt carbonate, sodium trium sulfate, ammonium sulfate, manganese sulfate, cobalt sulfate. Iron, zinc and / or copper sulfate, sodium metabisulfite, orthophosphoric acid, sodium nitrate, sodium nitrite, sodium chloride, potassium chloride, calcium phosphate, calcium silicate, diatomaceous earth, mineral acids such as hydrochloric acid and / or sulfuric acid. To be favoured, calcium carbonate, magnesium carbonate, cobalt carbonate, sodium trium sulfate, ammonium sulfate, manganese sulfate, cobalt sulfate. Iron, zinc and / or copper sulfate, sodium metabisulfite, orthophosphoric acid, sodium nitrate, sodium nitrite, sodium chloride, potassium chloride, calcium phosphate, calcium silicate,
  • Organic silage auxiliaries are, for example, formaldehyde, paraformaldehyde, hexamethylenetetramine, organic acids and / or their agriculturally useful salts, without being restricted to these.
  • Alphatic C 1 -C 7 -mono-, di-, tricarboxylic acids, benzoic acid and / or their agriculturally useful salts such as, for example, formic acid, acetic acid, glycolic acid, propionic acid, lactic acid, valeric acid, caproic acid, heptylic acid, acrylic acid, are preferably Maleic acid, fumaric acid, citric acid, sorbic acid are used.
  • Particularly preferred acids and / or their agriculturally useful salts are citric acid, formic acid and / or propionic acid.
  • Particularly preferred salts are calcium formate, sodium formate, sodium propionate and / or calcium propionate.
  • Salts of the abovementioned acids which can be used in agriculture are salts of such bases which do not adversely affect the ensiling effect.
  • Particularly suitable basic salts are those of the alkali metals, preferably the sodium and potassium salts, those of the alkaline earth metals, preferably calcium, magnesium and / or barium salts and the transition metals, preferably manganese, copper, Zinc, cobalt and / or iron salts and the ammonium salts.
  • the silage auxiliaries can be added to the silage agent individually or in combination.
  • Suitable MSB are advantageously those of the genera Lactobacillus, Lactococcus, Streptococcus, Leuconostoc, Carnobacterium, Staphylococcus, Aerococcus and / or Pediococcus.
  • Microorganisms of the genus Lactococcus, Lactobacillus and / or Leuconostoc are particularly suitable.
  • the genus and species Lactobacillus plantarum is particularly suitable.
  • the bacteria can be used in liquid, frozen or lyphilized form. Before use, they can be mounted on a carrier and / or mixed and / or granulated with further auxiliaries.
  • Suitable carriers are e.g. Calcium carbonate, bran, semolina, granulated sugar, bone meal, bolus, talcum, stearates of alkaline earths, table salt, rock salt or other minerals suitable for feeding.
  • a carrier make sure that the bacteria are not damaged. Single strains of bacteria or combinations of different strains can be used.
  • Auxiliaries in the sense of the invention are growth-promoting substances for microorganisms, such as products containing fermentable carbohydrates, for example molasses, boiled potatoes, grain red, dried whey, green meal, dry pulp, sugar. Starch or wood hydrolyzates.
  • enzymes which break down cellulolytic, amylolytic and / or other carbohydrates or nitrogen in bound form for example urea or ammonium compounds such as ammonium sulfate, also has a growth-promoting effect.
  • the silage material from fermentation feed that can be used according to the invention is not subject to any particular restriction. All easily silable feeds are suitable (slightly withered grass and other other forage plants with more than 3% sugar content in the fresh mass, withered grass> 30% dry matter, withered leguminous plants> 35% dry matter, silage maize and corncob products> 25% dry matter, whole plant cereals, moist cereals and damp maize, pressed pulp), moderately difficult to silage feed (Grass 20 to 25% dry matter, legumes 25 to 30% dry matter and other fodder plants with sugar contents of 1.5 to 3% in the fresh matter) or difficult to ensilage (grass ⁇ 20% dry matter or legumes ⁇ 20% dry matter with less as 1.5% sugar in the fresh mass as well as grass or legumes, the withering of which failed).
  • the silage preferably has a moisture content of at least 50%, more preferably from 60 to 90% (corresponding to 40 to 10% dry matter).
  • the ensiling agent according to the invention is the silage in a
  • the silage additive can be delivered to the farmer as individual components or as a finished mixture. In this case it is advantageous to use the components in such a way that an adverse mutual influence of the components is excluded. This can be achieved, for example, by micronization. It is advantageously added to the material to be ensiled in the form of a spreadable mixture of the components. However, it can also be added separately to the silage.
  • the ensiling agent is applied either by hand, an applicator or a metering device during chopping and / or during or after the green fodder has been stored.
  • Alfalfa was ensiled with a dry matter content of 19% and 4 g of silage additive per kg of silage was added in all examples.
  • Batch 1 (Table I) shows the control without the addition of ensiling agents.
  • Run 2 shows the effect of herkömmli ⁇ chen silage additive of 50 wt -.% Sodium propionate and 50 wt -.% Of sodium formate.
  • Table I ensiling of alfalfa
  • Batch 3 shows the dry weight losses with a silage additive consisting of 45% by weight sodium propionate, 50% by weight sodium formate and 5% by weight bromoethanesulfonic acid as a methanogenesis inhibitor.
  • Table I shows the mean values from three independent experiments each.
  • methanogenesis inhibitors significantly reduces the weight loss of the silage material.

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Zoology (AREA)
  • Microbiology (AREA)
  • Animal Husbandry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Fodder In General (AREA)
  • Medicines Containing Material From Animals Or Micro-Organisms (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
EP97905121A 1996-03-04 1997-02-28 Siliermittel Withdrawn EP0884954A1 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE19608263 1996-03-04
DE19608263A DE19608263A1 (de) 1996-03-04 1996-03-04 Siliermittel
PCT/EP1997/000983 WO1997032487A1 (de) 1996-03-04 1997-02-28 Siliermittel

Publications (1)

Publication Number Publication Date
EP0884954A1 true EP0884954A1 (de) 1998-12-23

Family

ID=7787145

Family Applications (1)

Application Number Title Priority Date Filing Date
EP97905121A Withdrawn EP0884954A1 (de) 1996-03-04 1997-02-28 Siliermittel

Country Status (13)

Country Link
EP (1) EP0884954A1 (cs)
AU (1) AU712872B2 (cs)
CA (1) CA2248007A1 (cs)
CZ (1) CZ275698A3 (cs)
DE (1) DE19608263A1 (cs)
HU (1) HUP9901816A3 (cs)
IL (1) IL125252A0 (cs)
MX (1) MX9806176A (cs)
NO (1) NO984043L (cs)
PL (1) PL328860A1 (cs)
SK (1) SK116898A3 (cs)
WO (1) WO1997032487A1 (cs)
ZA (1) ZA971807B (cs)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10105347A1 (de) * 2001-02-05 2002-08-22 Nutrinova Gmbh Sorbinsäurepräparat enthaltend Probiotika als Futtermittelzusatz in der Nutztieraufzucht
DE10110431A1 (de) * 2001-03-05 2002-09-19 Nutrinova Gmbh Bacteriocinhaltiges Sorbinsäurepräparat als Futtermittelzusatz in der Nutztieraufzucht
PL2312955T3 (pl) * 2008-07-21 2016-04-29 Erber Ag Sposób traktowania kiszonki paszowej i dodatek do kiszonki paszowej

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2940857A (en) * 1958-12-19 1960-06-14 Purdue Research Foundation Preservation of silage
DE1234504B (de) * 1960-09-03 1967-02-16 Biehl & Co Gaerfuttermittelbereitung
US4423224A (en) * 1980-09-08 1983-12-27 Sds Biotech Corporation 4-Me-1-(2-(1H-tetrazol-5-yl)ethyl)benzene sulfonate and N-2-(1H-tetrazol-5-yl)ethyl methanesulfonamide
US4764510A (en) * 1986-04-11 1988-08-16 Eli Lilly And Company Antibiotic A42125 and process for its production
DE69313655T2 (de) * 1992-10-22 1998-04-02 Bio-Technical Resources Lp, Manitowoc, Wis. Anthraquinon-inhibierung der methanherstellung durch methanogene bakterien
GB9512106D0 (en) * 1995-06-14 1995-08-09 Norsk Naeringsmiddelforskning Animal feed

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO9732487A1 *

Also Published As

Publication number Publication date
IL125252A0 (en) 1999-03-12
HUP9901816A3 (en) 2000-03-28
AU712872B2 (en) 1999-11-18
DE19608263A1 (de) 1997-09-11
WO1997032487A1 (de) 1997-09-12
SK116898A3 (en) 1999-01-11
CZ275698A3 (cs) 1999-02-17
PL328860A1 (en) 1999-03-01
CA2248007A1 (en) 1997-09-12
MX9806176A (es) 1998-10-31
AU1878797A (en) 1997-09-22
HUP9901816A2 (hu) 1999-09-28
ZA971807B (en) 1998-09-03
NO984043L (no) 1998-11-03
NO984043D0 (no) 1998-09-03

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