EP0863200A3 - Detergent compositions in tablet form - Google Patents

Detergent compositions in tablet form Download PDF

Info

Publication number
EP0863200A3
EP0863200A3 EP98103426A EP98103426A EP0863200A3 EP 0863200 A3 EP0863200 A3 EP 0863200A3 EP 98103426 A EP98103426 A EP 98103426A EP 98103426 A EP98103426 A EP 98103426A EP 0863200 A3 EP0863200 A3 EP 0863200A3
Authority
EP
European Patent Office
Prior art keywords
weight
detergent compositions
detergent
tablets
tablet form
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP98103426A
Other languages
German (de)
French (fr)
Other versions
EP0863200A2 (en
Inventor
Michael Feist
Hans-Friedrich Kruse
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Publication of EP0863200A2 publication Critical patent/EP0863200A2/en
Publication of EP0863200A3 publication Critical patent/EP0863200A3/en
Withdrawn legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/83Mixtures of non-ionic with anionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0047Detergents in the form of bars or tablets
    • C11D17/0065Solid detergents containing builders
    • C11D17/0073Tablets
    • C11D17/0086Laundry tablets
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/08Silicates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2075Carboxylic acids-salts thereof
    • C11D3/2086Hydroxy carboxylic acids-salts thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • C11D3/3703Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3707Polyethers, e.g. polyalkyleneoxides
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • C11D3/3746Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3757(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
    • C11D3/3761(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in solid compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/146Sulfuric acid esters
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38Cationic compounds
    • C11D1/52Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
    • C11D1/525Carboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain two or more hydroxy groups per alkyl group, e.g. R3 being a reducing sugar rest
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/662Carbohydrates or derivatives

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

Die Erfindung betrifft ein Verfahren zur Herstellung von Waschmittelformkörpern, die Tenside, Gerüststoffe sowie optional andere Waschmittelbestandteile enthalten. Zur Herstellung der Formkörper werden teilchenförmige Waschmittelzusammensetzungen, die 5 bis 20 Gew.-% eines übertrockneten amorphen Silikats, 0,5 bis 10 Gew.-% Polyethylenglycol und 1 bis 15 Gew.-% Wasser oder wäßrige Lösungen, jeweils bezogen auf das Gewicht des entstehenden Formkörpers, enthalten, unter Druck verpreßt. Das erfindungsgemäße Verfahren liefert bei niedrigen Preßdrucken Tabletten mit hoher Bruchfestigkeit und Lagerstabilität, die zusätzlich ein hervorragendes Auflöseverhalten zeigen.The invention relates to a method for producing detergent tablets, the Contain surfactants, builders and optionally other detergent ingredients. For the production the moldings are particulate detergent compositions, the 5th up to 20% by weight of an over-dried amorphous silicate, 0.5 to 10% by weight of polyethylene glycol and 1 to 15% by weight of water or aqueous solutions, based in each case on the Weight of the resulting molded body, contained, pressed under pressure. The invention The process provides tablets with high breaking strength at low compression pressures and storage stability, which also show excellent dissolution behavior.

EP98103426A 1997-03-07 1998-02-27 Detergent compositions in tablet form Withdrawn EP0863200A3 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19709411 1997-03-07
DE19709411A DE19709411A1 (en) 1997-03-07 1997-03-07 Detergent tablets

Publications (2)

Publication Number Publication Date
EP0863200A2 EP0863200A2 (en) 1998-09-09
EP0863200A3 true EP0863200A3 (en) 1999-09-15

Family

ID=7822592

Family Applications (1)

Application Number Title Priority Date Filing Date
EP98103426A Withdrawn EP0863200A3 (en) 1997-03-07 1998-02-27 Detergent compositions in tablet form

Country Status (3)

Country Link
US (1) US6329335B1 (en)
EP (1) EP0863200A3 (en)
DE (1) DE19709411A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8338357B2 (en) 2006-01-21 2012-12-25 Reckitt Benckiser N.V. Multiple dosing ware washing article

Families Citing this family (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19841146A1 (en) * 1998-09-09 2000-03-16 Henkel Kgaa Detergent tablets with binders
DE19845602A1 (en) * 1998-10-05 2000-04-06 Henkel Kgaa Detergent tab pack for dishwashers
DE19850984A1 (en) * 1998-11-05 2000-05-11 Henkel Kgaa Shape-optimized detergent tablets
DE19902425A1 (en) * 1999-01-22 2000-07-27 Henkel Kgaa Compressed laundry and other detergent tablets, useful for laundry, in dishwasher, for cleaning hard surface or as bleach, water softening or stain removal tablets, are made from granulate with higher than equilibrium water content
DE19903289A1 (en) * 1999-01-28 2000-08-03 Henkel Kgaa Abrasion-resistant detergent tablets with a high non-ionic surfactant content
DE19908025A1 (en) * 1999-02-25 2000-08-31 Henkel Kgaa Process for the production of rapidly disintegrating detergent tablets
US6846794B1 (en) * 1999-03-05 2005-01-25 The Procter & Gamble Company Production process for detergent tablet
DE19910819A1 (en) * 1999-03-11 2000-09-14 Henkel Kgaa Detergent tablets with surfactant-bleach-builder combination
DE19919444B4 (en) * 1999-04-29 2016-06-30 Henkel Ag & Co. Kgaa Detergent tablets with binder compound, process for its preparation and use of binder compounds
DE19930771A1 (en) * 1999-07-03 2001-01-04 Henkel Kgaa Process for the production of detergent tablets
DE19932569A1 (en) * 1999-07-13 2001-01-18 Henkel Kgaa Detergent tablets, in particular for machine dishwashing
GB9918087D0 (en) * 1999-08-02 1999-10-06 Mcbride Robert Ltd Detergent tablets
DE19937428A1 (en) * 1999-08-07 2001-02-08 Henkel Kgaa Detergent tablets
DE19953792A1 (en) * 1999-11-09 2001-05-17 Cognis Deutschland Gmbh Detergent tablets
WO2002033036A1 (en) * 2000-10-18 2002-04-25 Unilever N.V. Cleaning compositions
DE10352961A1 (en) * 2003-11-13 2005-06-23 Henkel Kgaa Shock-resistant tablet
FR2865214B1 (en) * 2004-01-15 2007-11-23 Eurotab DETERGENT TABLET FOR LAUNDRY WASHING, HIGH SURFACTANT
DE102004020009A1 (en) * 2004-04-21 2005-11-10 Henkel Kgaa Washing/cleaning agent molded article, useful as e.g. detergent tablets or water softener tablets, comprises dirt-removable cellulose derivative obtained by alkylation and hydroxyalkylation of cellulose
EP1976421B1 (en) 2006-01-21 2017-06-21 Reckitt Benckiser Finish B.V. An article for use in a ware washing machine
DE102006016578A1 (en) * 2006-04-06 2007-10-11 Henkel Kgaa Solid textile softening composition with a water-soluble polymer
GB0621572D0 (en) 2006-10-30 2006-12-06 Reckitt Benckiser Nv Multi-dosing detergent delivery device
US8338352B2 (en) * 2007-05-07 2012-12-25 Ecolab Usa Inc. Solidification matrix
GB0710229D0 (en) 2007-05-30 2007-07-11 Reckitt Benckiser Nv Detergent dosing device
US8759269B2 (en) * 2007-07-02 2014-06-24 Ecolab Usa Inc. Solidification matrix including a salt of a straight chain saturated mono-, di-, and tri- carboxylic acid
CN101687156B (en) * 2007-07-03 2013-08-07 巴斯夫欧洲公司 Process for producing a free-flowing and storage-stable solid comprising essentially alpha-alanine-N,N-diacetic acid and/or one or more derivatives of alpha-alanine-N,N-diacetic acid
US8198228B2 (en) * 2008-01-04 2012-06-12 Ecolab Usa Inc. Solidification matrix using an aminocarboxylate
DE102008020275A1 (en) 2008-04-22 2009-10-29 Henkel Ag & Co. Kgaa Cleaning agent shaped body from pressed particulate material, useful e.g. for cleaning utensils in a household dishwasher, comprises zinc-containing cogranulate comprising zinc compounds and carrier material from group of builders
DE102008020274A1 (en) 2008-04-22 2009-10-29 Henkel Ag & Co. Kgaa Preparing a cleaning agent tablet, useful for cleaning or washing e.g. moldings, comprises compressing a particulate premix containing zinc-containing granulates and other ingredients
US8530403B2 (en) * 2009-11-20 2013-09-10 Ecolab Usa Inc. Solidification matrix using a maleic-containing terpolymer binding agent
US20110124547A1 (en) * 2009-11-23 2011-05-26 Ecolab Inc. Solidification matrix using a sulfonated/carboxylated polymer binding agent

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1363342A (en) * 1962-05-03 1964-06-12 Colgate Palmolive Co Method for applying a colored coating to a detergent bar and resulting product
GB989683A (en) * 1961-04-03 1965-04-22 Colgate Palmolive Co Detergent tablets and processes for manufacturing them
DE1467564A1 (en) * 1962-07-30 1969-10-09 Colgate Palmolive Co Process for the production of detergent tablets
DE2036673A1 (en) * 1969-07-28 1971-02-11 Gaiser. Conrad Jerome, Reno. Nev (V St A ) Detergent preparation containing amorphous sodium silicate and methods for washing fabrics
DE1617093A1 (en) * 1963-11-26 1971-02-25 Fmc Corp Process for the manufacture of detergent tablets
EP0522766A2 (en) * 1991-07-01 1993-01-13 Unilever Plc Detergent compositions in tablet form
DE4400024A1 (en) * 1994-01-03 1995-07-06 Henkel Kgaa Silicate builders and their use in detergents and cleaning agents as well as multi-component mixtures for use in this field
DE4404279A1 (en) * 1994-02-10 1995-08-17 Henkel Kgaa Tablet with builder substances
EP0711828A2 (en) * 1994-11-14 1996-05-15 Unilever Plc Detergent compositions
DE19601840A1 (en) * 1996-01-19 1997-07-24 Henkel Kgaa Process for the preparation of detergent tablets

Family Cites Families (74)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1120819A (en) * 1977-06-01 1982-03-30 Jurgen W.K. Gromer Detergent tablet
JPS58217598A (en) 1982-06-10 1983-12-17 日本油脂株式会社 Detergent composition
DE3315950A1 (en) * 1983-05-02 1984-11-15 Henkel KGaA, 4000 Düsseldorf METHOD FOR PRODUCING DETERGENT TABLETS
CA1238917A (en) 1984-01-31 1988-07-05 Vivian B. Valenty Detergent builder
US4524009A (en) 1984-01-31 1985-06-18 A. E. Staley Manufacturing Company Detergent builder
US4639325A (en) 1984-10-24 1987-01-27 A. E. Staley Manufacturing Company Detergent builder
DE3541146A1 (en) * 1985-11-21 1987-05-27 Henkel Kgaa MULTILAYERED DETERGENT TABLETS FOR MACHINE DISHWASHER
FR2597473B1 (en) 1986-01-30 1988-08-12 Roquette Freres PROCESS FOR THE OXIDATION OF DI-, TRI-, OLIGO- AND POLYSACCHARIDES TO POLYHYDROXYCARBOXYLIC ACIDS, CATALYST IMPLEMENTED AND PRODUCTS THUS OBTAINED.
GB8629837D0 (en) 1986-12-13 1987-01-21 Interox Chemicals Ltd Bleach activation
DE3706036A1 (en) 1987-02-25 1988-09-08 Basf Ag POLYACETALS, METHOD FOR THE PRODUCTION THEREOF FROM DIALDEHYDES AND POLYOLCARBONIC ACIDS AND USE OF THE POLYACETALS
GB8908416D0 (en) 1989-04-13 1989-06-01 Unilever Plc Bleach activation
DE3914131A1 (en) 1989-04-28 1990-10-31 Henkel Kgaa USE OF CALCINATED HYDROTALCITES AS CATALYSTS FOR ETHOXYLATION OR PROPOXYLATION OF FATTY ACID ESTERS
JPH03157067A (en) 1989-11-01 1991-07-05 Yuzo Tsuruta Switching device for video camera lighting
GB9003741D0 (en) 1990-02-19 1990-04-18 Unilever Plc Bleach activation
US5047163A (en) 1990-03-16 1991-09-10 Lever Brothers Company, Division Of Conopco, Inc. Activation of bleach precursors with sulfonimines
US5041232A (en) 1990-03-16 1991-08-20 Lever Brothers Company, Division Of Conopco, Inc. Sulfonimines as bleach catalysts
DE69125310T2 (en) 1990-05-21 1997-07-03 Unilever Nv Bleach activation
IT1249883B (en) 1990-08-13 1995-03-30 Ferruzzi Ricerca & Tec CALCIUM SEQUESTRING AGENTS BASED ON OXIDIZED CARBOHYDRATES AND THEIR USE AS BUILDER FOR DETERGENTS
US5133892A (en) * 1990-10-17 1992-07-28 Lever Brothers Company, Division Of Conopco, Inc. Machine dishwashing detergent tablets
IT1245063B (en) 1991-04-12 1994-09-13 Ferruzzi Ricerca & Tec PROCEDURE FOR OXIDATION OF CARBOHYDRATES
ATE155165T1 (en) 1991-07-31 1997-07-15 Ausimont Spa METHOD FOR INCREASING THE BLEACHING EFFECTIVENESS OF AN INORGANIC PER SALT
DE4134914A1 (en) 1991-10-23 1993-04-29 Henkel Kgaa DETERGENT AND CLEANING AGENT WITH SELECTED BUILDER SYSTEMS
IT1252682B (en) * 1991-11-13 1995-06-23 Vomm Impianti & Processi Srl PRODUCT IN HIGH SPECIFIC WEIGHT GRANULES, PARTICULARLY AS A POWDER DETERGENT ADDITIVE AND METHOD FOR ITS OBTAINING
ATE166362T1 (en) 1991-11-14 1998-06-15 Procter & Gamble C6/C2-C3 OXIDIZED STARCH AS A DETERGENT INGREDIENT
GB9127060D0 (en) 1991-12-20 1992-02-19 Unilever Plc Bleach activation
CA2085642A1 (en) 1991-12-20 1993-06-21 Ronald Hage Bleach activation
DE4221381C1 (en) 1992-07-02 1994-02-10 Stockhausen Chem Fab Gmbh Graft copolymers of unsaturated monomers and sugars, process for their preparation and their use
DE4203184C3 (en) 1992-02-05 1996-11-21 Weidmueller Interface Protective conductor terminal
DE69202239T2 (en) 1992-02-06 1996-01-18 Caribonum Ltd Ribbon cartridge.
DE4203923A1 (en) 1992-02-11 1993-08-12 Henkel Kgaa METHOD FOR PRODUCING POLYCARBOXYLATES ON A POLYSACCHARIDE BASE
JPH05339896A (en) 1992-06-03 1993-12-21 Arakawa Chem Ind Co Ltd Paper sizing agent and paper sizing
DE4300772C2 (en) 1993-01-14 1997-03-27 Stockhausen Chem Fab Gmbh Water-soluble, biodegradable copolymers based on unsaturated mono- and dicarboxylic acids, process for their preparation and their use
DE4303320C2 (en) 1993-02-05 1995-12-21 Degussa Detergent composition having improved soil carrying power, process for its preparation and use of a suitable polycarboxylate therefor
CN1065563C (en) 1993-05-20 2001-05-09 普罗格特-甘布尔公司 Bleaching compounds comprising N-acyl caprolactam for use in hand-wash or other low-water cleaning systems
AU6949094A (en) 1993-05-20 1994-12-20 Procter & Gamble Company, The Bleaching compounds comprising substituted benzoyl caprolactam bleach activators
JP3347734B2 (en) 1993-05-20 2002-11-20 ザ、プロクター、エンド、ギャンブル、カンパニー Bleach composition comprising N-acylcaprolactam activator
DE4317519A1 (en) 1993-05-26 1994-12-01 Henkel Kgaa Production of polysaccharide-based polycarboxylates
DE4319578A1 (en) 1993-06-14 1994-12-15 Henkel Kgaa Detergent containing amino acids and / or their salts
US5405413A (en) 1993-06-24 1995-04-11 The Procter & Gamble Co. Bleaching compounds comprising acyl valerolactam bleach activators
JPH08502715A (en) * 1993-08-23 1996-03-26 ピー キュー コーポレーション Amorphous alkali metal silicate, method and application
NL194919C (en) 1993-09-07 2003-07-04 Tno Process for oxidizing carbohydrates.
WO1995007331A1 (en) 1993-09-09 1995-03-16 The Procter & Gamble Company Liquid detergents with n-alkoxy or n-aryloxy polyhydroxy fatty acid amide surfactants
NL9301905A (en) 1993-11-04 1995-06-01 Inst Voor Agrotech Onderzoek Method for oxidizing carbohydrates.
DE4338922A1 (en) 1993-11-15 1995-05-18 Degussa Activators for inorganic peroxygen compounds
ES2133710T3 (en) 1993-11-25 1999-09-16 Warwick Int Group WHITENING COMPOSITIONS.
US5534196A (en) 1993-12-23 1996-07-09 The Procter & Gamble Co. Process for making lactam bleach activator containing particles
DE4402051A1 (en) 1994-01-25 1995-07-27 Henkel Kgaa Builder for detergents or cleaners
DE4402851A1 (en) 1994-01-31 1995-08-03 Henkel Kgaa Fluid bed oxidation process for the production of polysaccharide-based polycarboxylates
DE4406592A1 (en) * 1994-03-01 1995-09-07 Henkel Kgaa Improved multi-substance mixtures based on water-soluble alkali silicate compounds and their use, in particular for use as builders in detergents and cleaners
CA2187169A1 (en) 1994-04-07 1995-10-19 Gerard Marcel Abel Baillely Bleach compositions comprising metal-containing bleach catalysts
DE4415362A1 (en) * 1994-05-02 1995-11-09 Henkel Kgaa Process for the production of silicate builder granules with increased bulk density
DE4416438A1 (en) 1994-05-10 1995-11-16 Basf Ag Mononuclear or multinuclear metal complexes and their use as bleaching and oxidation catalysts
DE4417734A1 (en) 1994-05-20 1995-11-23 Degussa Polycarboxylates
ES2132687T3 (en) * 1994-07-04 1999-08-16 Unilever Nv WASHING COMPOSITION AND PROCEDURE.
DE69533149T2 (en) 1994-07-21 2005-08-25 Ciba Specialty Chemicals Holding Inc. Bleaching composition for tissue
DE4429550A1 (en) * 1994-08-19 1996-02-22 Henkel Kgaa Process for the production of detergent tablets
GB9419091D0 (en) 1994-09-22 1994-11-09 Cerestar Holding Bv Process for decreasing the build up of inorganic incrustations on textiles and detergent composition used in such process
GB9422924D0 (en) 1994-11-14 1995-01-04 Unilever Plc Detergent compositions
GB9422895D0 (en) 1994-11-14 1995-01-04 Unilever Plc Detergent compositions
DE4443177A1 (en) 1994-12-05 1996-06-13 Henkel Kgaa Activator mixtures for inorganic per compounds
DE69628784T2 (en) * 1995-04-12 2004-02-12 Cleantabs A/S Bleach tablets
GB2303635A (en) * 1995-07-25 1997-02-26 Procter & Gamble Detergent compositions in compacted solid form
DE19529905A1 (en) 1995-08-15 1997-02-20 Henkel Kgaa Activator complexes for peroxygen compounds
DE19536082A1 (en) 1995-09-28 1997-04-03 Henkel Kgaa Use of transition metal complex as activator for peroxy cpd.
DE19540086A1 (en) 1995-10-27 1997-04-30 Henkel Kgaa Use of polymeric aminodicarboxylic acids in detergents
DE19600018A1 (en) 1996-01-03 1997-07-10 Henkel Kgaa Detergent with certain oxidized oligosaccharides
DE19605688A1 (en) 1996-02-16 1997-08-21 Henkel Kgaa Transition metal complexes as activators for peroxygen compounds
DE19613103A1 (en) 1996-04-01 1997-10-02 Henkel Kgaa Systems containing transition metal complexes as activators for peroxygen compounds
DE19620411A1 (en) 1996-04-01 1997-10-02 Henkel Kgaa Transition metal amine complexes as activators for peroxygen compounds
DE19616770A1 (en) 1996-04-26 1997-11-06 Henkel Kgaa Acyl lactams as bleach activators for detergents and cleaning agents
DE19616693A1 (en) 1996-04-26 1997-11-06 Henkel Kgaa Enol esters as bleach activators for detergents and cleaning agents
DE19616767A1 (en) 1996-04-26 1997-11-06 Henkel Kgaa Bleach activators for detergents and cleaning agents
DE19616769A1 (en) 1996-04-26 1997-11-06 Henkel Kgaa Acylacetals as bleach activators for detergents and cleaning agents
DE19620267A1 (en) 1996-05-20 1997-11-27 Henkel Kgaa Catalytically active activator complexes with N¶4¶ ligands for peroxygen compounds

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB989683A (en) * 1961-04-03 1965-04-22 Colgate Palmolive Co Detergent tablets and processes for manufacturing them
FR1363342A (en) * 1962-05-03 1964-06-12 Colgate Palmolive Co Method for applying a colored coating to a detergent bar and resulting product
DE1467564A1 (en) * 1962-07-30 1969-10-09 Colgate Palmolive Co Process for the production of detergent tablets
DE1617093A1 (en) * 1963-11-26 1971-02-25 Fmc Corp Process for the manufacture of detergent tablets
DE2036673A1 (en) * 1969-07-28 1971-02-11 Gaiser. Conrad Jerome, Reno. Nev (V St A ) Detergent preparation containing amorphous sodium silicate and methods for washing fabrics
EP0522766A2 (en) * 1991-07-01 1993-01-13 Unilever Plc Detergent compositions in tablet form
DE4400024A1 (en) * 1994-01-03 1995-07-06 Henkel Kgaa Silicate builders and their use in detergents and cleaning agents as well as multi-component mixtures for use in this field
DE4404279A1 (en) * 1994-02-10 1995-08-17 Henkel Kgaa Tablet with builder substances
EP0711828A2 (en) * 1994-11-14 1996-05-15 Unilever Plc Detergent compositions
DE19601840A1 (en) * 1996-01-19 1997-07-24 Henkel Kgaa Process for the preparation of detergent tablets

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8338357B2 (en) 2006-01-21 2012-12-25 Reckitt Benckiser N.V. Multiple dosing ware washing article

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US6329335B1 (en) 2001-12-11
DE19709411A1 (en) 1998-09-10
EP0863200A2 (en) 1998-09-09

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