EP0823489B2 - Produit pour construction soudée en alliage AlMgMn à tenue à la corrosion améliorée - Google Patents
Produit pour construction soudée en alliage AlMgMn à tenue à la corrosion améliorée Download PDFInfo
- Publication number
- EP0823489B2 EP0823489B2 EP97420125A EP97420125A EP0823489B2 EP 0823489 B2 EP0823489 B2 EP 0823489B2 EP 97420125 A EP97420125 A EP 97420125A EP 97420125 A EP97420125 A EP 97420125A EP 0823489 B2 EP0823489 B2 EP 0823489B2
- Authority
- EP
- European Patent Office
- Prior art keywords
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- product according
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- size
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- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/04—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
- C22F1/047—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon of alloys with magnesium as the next major constituent
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
- C22C21/06—Alloys based on aluminium with magnesium as the next major constituent
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
- C22C21/06—Alloys based on aluminium with magnesium as the next major constituent
- C22C21/08—Alloys based on aluminium with magnesium as the next major constituent with silicon
Definitions
- the thermally affected zone around the weld joint is in the annealed state (state O), with less mechanical characteristics, which does not allow to exploit fully, in welded constructions, the mechanical characteristics. of the material.
- the certification and control bodies generally recommend that only the mechanical characteristics in state O be taken into account when sizing a structure.
- German patent DE 2443443 (Siemens AG) claims a weldable aluminum alloy machine component containing, inter alia, 3.5 to 4.9% Mg and 0.5 to 1.5% Mn. No information is given the mechanical characteristics or the corrosion resistance of this product.
- the European patent EP 0015799 (aines et Chantiers de Bretagne) discloses a weldable alloy containing among others 3.5 to 4.5% magnesium and 0.2 to 0.7% manganese for the manufacture of tubes for cryogenic application. This application does not pose the problem of thermal sensitization to corrosion, and the document does not mention the mechanical characteristics or other properties of use of the product.
- the US patent US 3502448 (Aluminum Company of America) discloses an alloy containing, inter alia, 4 to 5.5% magnesium, 0.2 to 0.7% manganese, which conducts, by cold rolling, to thin sheets and thin strips to the manufacture of beverage can lids, provided that the relationship between the contents of Mg and Mn is consistent with a certain algebraic relationship.
- This patent does not concern the field of welded mechanical engineering either.
- the problem to which the present invention attempts to respond is therefore to provide rolled, drawn or drawn AlMgMn alloy products having, after welding, improved corrosion resistance and better resistance to the sensitizing effect of exposure to temperature. , while retaining good mechanical properties after welding, good resistance to fatigue and can be developed at the lowest cost.
- the subject of the invention is thus an AlMgMn alloy product for welded mechanical construction of composition (% by weight): 5.0 ⁇ Mg ⁇ 6.5 0.2 ⁇ Mn ⁇ 1.0 Fe ⁇ 0.8 0.05 ⁇ Si ⁇ 0.6 0.2 ⁇ Zn ⁇ 1.3 optionally Cr at a content ⁇ 0.15 and / or one or more of the elements Cu, Ti, Ag, Zr, V, at a content ⁇ 0.3 each, the unavoidable impurities ⁇ 0.05 each and ⁇ 0.15 at total, remains aluminum, wherein the number of Mg 2 Si particles of size between 0.5 and 5 ⁇ m is between 150 and 2000 per mm 2 , and preferably between 300 and 1500 per mm 2 .
- the eutectic phases Mg 2 Si the eutectic phases AlFeMnSi, the eutectic phases Al 6 (Mn, Fe) and AlFeCr, and the manganese dispersoids, of sub-micron size, which are found in the grain.
- the number of "large" particles should represent only a small part of the total particles (size> 0.5 ⁇ m), typically less than 25%, and preferably , less than 20%.
- the surface fraction of Mg 2 Si particles also measured by image analysis from optical microscopy, must be less than 1%, and preferably 0.8%.
- Manganese improves the tensile strength and decreases the tendency of the metal to recrystallize, which is known to those skilled in the art. Below 0.2%, the present invention is of no industrial interest because the resistance to the pull is too weak. Above 1%, elongation at break, tenacity and fatigue resistance become too low for the intended applications.
- the iron content does not have much influence in the context of the present invention; it should be less than 0.8% to avoid the formation of primary phases during casting, while for high manganese contents, it is preferable that it does not exceed 0.4%.
- Examples 1 and 2 and Example 3 (resulting in a microstructure outside the invention) correspond to composition 1.
- Examples 7 and 8, and Example 9 (resulting in a microstructure outside the invention) correspond to composition 3.
- the number, the surface fraction and the size distribution of eutectic precipitates Mg 2 Si and AlFeMnSi were measured by image analysis.
- samples were prepared by an automatic continuous butt MIG welding shipyard company, with a 45 ° symmetrical chamfer with respect to the vertical to a thickness of 6 mm, with wire alloying 5183. The welding was carried out parallel to the rolling direction.
Landscapes
- Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Organic Chemistry (AREA)
- Metallurgy (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Metal Rolling (AREA)
- Arc Welding In General (AREA)
- Laminated Bodies (AREA)
- Heat Treatment Of Steel (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR9610085A FR2752244B1 (fr) | 1996-08-06 | 1996-08-06 | Produit pour construction soudee en alliage almgmn a tenue a la corrosion amelioree |
FR9610085 | 1996-08-06 |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0823489A1 EP0823489A1 (fr) | 1998-02-11 |
EP0823489B1 EP0823489B1 (fr) | 2000-11-02 |
EP0823489B2 true EP0823489B2 (fr) | 2007-08-22 |
Family
ID=9494970
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP97420125A Expired - Lifetime EP0823489B2 (fr) | 1996-08-06 | 1997-07-23 | Produit pour construction soudée en alliage AlMgMn à tenue à la corrosion améliorée |
Country Status (8)
Country | Link |
---|---|
US (1) | US5908518A (es) |
EP (1) | EP0823489B2 (es) |
JP (1) | JPH1088270A (es) |
AU (1) | AU709909C (es) |
DE (2) | DE823489T1 (es) |
DK (1) | DK0823489T4 (es) |
ES (1) | ES2152073T5 (es) |
FR (1) | FR2752244B1 (es) |
Families Citing this family (29)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0799900A1 (en) | 1996-04-04 | 1997-10-08 | Hoogovens Aluminium Walzprodukte GmbH | High strength aluminium-magnesium alloy material for large welded structures |
US6416884B1 (en) * | 1997-10-03 | 2002-07-09 | Corus Aluminium Walzprodukte Gmbh | Aluminium-magnesium weld filler alloy |
US20030145912A1 (en) * | 1998-02-20 | 2003-08-07 | Haszler Alfred Johann Peter | Formable, high strength aluminium-magnesium alloy material for application in welded structures |
BR9914953A (pt) * | 1998-10-30 | 2001-07-24 | Corus Aluminium Walzprod Gmbh | Painel de alumìnio composto |
JP4554088B2 (ja) * | 1999-05-04 | 2010-09-29 | アレリス、アルミナム、コブレンツ、ゲゼルシャフト、ミット、ベシュレンクテル、ハフツング | 耐剥離性アルミニウム−マグネシウム合金 |
DE10231437B4 (de) * | 2001-08-10 | 2019-08-22 | Corus Aluminium N.V. | Verfahren zur Herstellung eines Aluminiumknetlegierungsprodukts |
DE10231422A1 (de) * | 2001-08-13 | 2003-02-27 | Corus Aluminium Nv | Aluminium-Magnesium-Legierungserzeugnis |
FR2837499B1 (fr) * | 2002-03-22 | 2004-05-21 | Pechiney Rhenalu | PRODUITS EN ALLIAGES Al-Mg POUR CONSTRUCTION SOUDEE |
DE602004005529T2 (de) * | 2003-05-20 | 2007-10-25 | Aleris Aluminum Duffel Bvba | Schmiedealuminiumlegierung |
JP4534573B2 (ja) * | 2004-04-23 | 2010-09-01 | 日本軽金属株式会社 | 高温高速成形性に優れたAl‐Mg合金板およびその製造方法 |
US7494043B2 (en) * | 2004-10-15 | 2009-02-24 | Aleris Aluminum Koblenz Gmbh | Method for constructing a welded construction utilizing an Al-Mg-Mn weld filler alloy |
ATE524571T2 (de) * | 2005-08-16 | 2011-09-15 | Aleris Aluminum Koblenz Gmbh | Hochfeste schweissbare al-mg-legierung |
CA2797446C (en) * | 2010-04-26 | 2020-07-14 | Sapa Ab | Damage tolerant aluminium material having a layered microstructure |
CN101880802B (zh) * | 2010-07-30 | 2013-06-19 | 浙江巨科铝业有限公司 | 汽车车身板用Al-Mg系高镁铝合金及其制造方法 |
EP3266891B1 (en) * | 2013-03-29 | 2019-08-14 | Furukawa Electric Co. Ltd. | Aluminum alloy conductor, aluminum alloy stranded wire, coated wire, wire harness and manufacturing method of aluminum alloy conductor |
CN103757572A (zh) * | 2013-10-29 | 2014-04-30 | 佛山市三水凤铝铝业有限公司 | 一种6xxx系铝合金的时效工艺 |
US20150132181A1 (en) * | 2013-11-11 | 2015-05-14 | Stephen L. Anderson | Aluminum welding filler metal, casting and wrought metal alloy |
CN103774067A (zh) * | 2014-02-26 | 2014-05-07 | 常州大学 | 一种提高6000系铝合金晶间腐蚀抗力的双级时效方法 |
CN103981404B (zh) * | 2014-05-04 | 2017-02-22 | 南安市国高建材科技有限公司 | 一种耐蚀、易加工铝合金板材、制造方法及其应用 |
CN104195390A (zh) * | 2014-09-23 | 2014-12-10 | 中南大学 | 一种高强耐蚀耐热易成型Al-Mg合金 |
CN106834823B (zh) * | 2016-12-22 | 2018-07-03 | 中电科技(武汉)电子信息发展有限责任公司 | 一种铝合金带材 |
CN106834826B (zh) * | 2016-12-22 | 2018-07-03 | 中电科技(武汉)电子信息发展有限责任公司 | 一种铝合金带材及其制造方法 |
JP7401307B2 (ja) | 2017-03-08 | 2023-12-19 | ナノアル エルエルシー | 高性能5000系アルミニウム合金 |
JP6886861B2 (ja) * | 2017-05-29 | 2021-06-16 | 三菱造船株式会社 | アルミニウム合金の溶接方法 |
CN108161273A (zh) * | 2018-03-06 | 2018-06-15 | 东北大学 | 一种Al-Mg-Zn-Mn铝合金焊丝及其制备方法 |
CN110551928A (zh) * | 2019-09-17 | 2019-12-10 | 新疆众和股份有限公司 | 一种5654铝合金焊丝线坯的生产方法 |
RU2735846C1 (ru) * | 2019-12-27 | 2020-11-09 | Общество с ограниченной ответственностью "Объединенная Компания РУСАЛ Инженерно-технологический центр" | Сплав на основе алюминия |
CN112708810B (zh) * | 2020-12-17 | 2021-10-22 | 华南理工大学 | 一种高Fe含量的挤压铸造再生铝镁合金及其制备方法 |
CN115233051B (zh) * | 2022-09-20 | 2023-01-24 | 中铝材料应用研究院有限公司 | 一种船舶用高强耐蚀铝合金板材的制备方法 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5181969A (en) † | 1990-06-11 | 1993-01-26 | Sky Aluminum Co., Ltd. | Rolled aluminum alloy adapted for superplastic forming and method for making |
WO1996026299A1 (fr) † | 1995-02-24 | 1996-08-29 | Pechiney Rhenalu | PRODUIT POUR CONSTRUCTION SOUDEE EN ALLIAGE AlMgMn A RESISTANCE MECANIQUE AMELIOREE |
EP0769564A1 (fr) † | 1995-10-18 | 1997-04-23 | Pechiney Rhenalu | Alliages AlMg pour constructions soudées à caractéristiques mécaniques améliorées |
EP0892858B1 (en) † | 1996-04-04 | 2000-11-02 | Corus Aluminium Walzprodukte GmbH | Aluminium-magnesium alloy plate or extrusion |
Family Cites Families (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3502448A (en) * | 1967-12-07 | 1970-03-24 | Aluminum Co Of America | Aluminum alloy sheet |
US4108688A (en) * | 1976-09-30 | 1978-08-22 | Kaiser Aluminum & Chemical Corporation | Cast aluminum plate and method therefor |
US4412870A (en) * | 1980-12-23 | 1983-11-01 | Aluminum Company Of America | Wrought aluminum base alloy products having refined intermetallic phases and method |
US4659396A (en) * | 1984-07-30 | 1987-04-21 | Aluminum Company Of America | Metal working method |
JPS61199056A (ja) * | 1985-02-27 | 1986-09-03 | Mitsui Alum Kogyo Kk | アルミニウム合金鋳物の製造方法 |
GB8524077D0 (en) * | 1985-09-30 | 1985-11-06 | Alcan Int Ltd | Al-mg-si extrusion alloy |
US5244516A (en) * | 1988-10-18 | 1993-09-14 | Kabushiki Kaisha Kobe Seiko Sho | Aluminum alloy plate for discs with improved platability and process for producing the same |
CA2054193C (en) * | 1990-03-09 | 1998-12-22 | Yoshihito Inabayashi | Brazing sheet comprising an a1-mg-si alloy brazing material |
DE4015741A1 (de) * | 1990-05-16 | 1991-11-21 | Metallgesellschaft Ag | Verfahren zur herstellung von mg(pfeil abwaerts)2(pfeil abwaerts)si enthaltenden legierungen |
JPH0621310B2 (ja) * | 1990-06-26 | 1994-03-23 | 住友軽金属工業株式会社 | 高導電性Al―Mg―Si系合金管の製造方法 |
JPH04202747A (ja) * | 1990-11-30 | 1992-07-23 | Sky Alum Co Ltd | 成形加工用アルミニウム合金板の製造方法 |
JPH04202748A (ja) * | 1990-11-30 | 1992-07-23 | Sky Alum Co Ltd | 成形加工用アルミニウム合金板の製造方法 |
US5240522A (en) * | 1991-03-29 | 1993-08-31 | Sumitomo Light Metal Industries, Ltd. | Method of producing hardened aluminum alloy sheets having superior thermal stability |
JPH07112625B2 (ja) * | 1991-04-04 | 1995-12-06 | 日本電装株式会社 | アルミニウムの真空ろう付方法および真空ろう付炉と、真空ろう付用アルミニウムブレージングシート |
JP2818721B2 (ja) * | 1992-11-12 | 1998-10-30 | 川崎製鉄株式会社 | ボディーシート用アルミニウム合金板の製造方法とこれにより得られるアルミニウム合金板 |
US5667602A (en) * | 1995-03-31 | 1997-09-16 | Aluminum Company Of America | Alloy for cast components |
-
1996
- 1996-08-06 FR FR9610085A patent/FR2752244B1/fr not_active Expired - Fee Related
-
1997
- 1997-07-23 DE DE0823489T patent/DE823489T1/de active Pending
- 1997-07-23 ES ES97420125T patent/ES2152073T5/es not_active Expired - Lifetime
- 1997-07-23 DK DK97420125T patent/DK0823489T4/da active
- 1997-07-23 DE DE69703420T patent/DE69703420T3/de not_active Expired - Lifetime
- 1997-07-23 EP EP97420125A patent/EP0823489B2/fr not_active Expired - Lifetime
- 1997-07-25 US US08/899,691 patent/US5908518A/en not_active Expired - Lifetime
- 1997-08-06 AU AU33201/97A patent/AU709909C/en not_active Expired
- 1997-08-06 JP JP9244535A patent/JPH1088270A/ja active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5181969A (en) † | 1990-06-11 | 1993-01-26 | Sky Aluminum Co., Ltd. | Rolled aluminum alloy adapted for superplastic forming and method for making |
WO1996026299A1 (fr) † | 1995-02-24 | 1996-08-29 | Pechiney Rhenalu | PRODUIT POUR CONSTRUCTION SOUDEE EN ALLIAGE AlMgMn A RESISTANCE MECANIQUE AMELIOREE |
EP0769564A1 (fr) † | 1995-10-18 | 1997-04-23 | Pechiney Rhenalu | Alliages AlMg pour constructions soudées à caractéristiques mécaniques améliorées |
EP0892858B1 (en) † | 1996-04-04 | 2000-11-02 | Corus Aluminium Walzprodukte GmbH | Aluminium-magnesium alloy plate or extrusion |
Non-Patent Citations (16)
Title |
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"Aluminium Standards, Data and Design. Wrought Products", AustralianAluminium Council limited, Australie, 1ère édition, février 1994, page 5.13 † |
Aluminium Today, 23 octobre 1998, p.23 † |
ASM Specialty Handbook "Aluminum and Aluminum Alloys", édité par J.R. Davis, ASM International, 3ème édition, mai 1994, pp. 60-61, 675-678 † |
DNV, "Rules for Classification of SHIPS, NEWBUILDINGS", Partie 2, Chapitre 3, Welding, janvier 1996, Det Norske Veritas, Norvège, pp. 13-14 † |
G. J. Marshall et al., "The effect of Fe and Si on the micro- structure and properties of AA5182 alloy sheet", Light Metals 1996, Proceedings du Symposium International sur les Métaux Légers, 1996, Montréal, Quebec, Canada25-29 août 1996, pp. 257-267 † |
G.J. Marshall et al., "The effect of silicon on the microstructure and properties of AA5182 alloy sheet", Aluminum Alloys, 4ème Conférence Internationale sur les Alliages d'Aluminium, Atlanta, Georgia, USA, 11-16 septembre 1994, pp. 330-337 † |
G.J. Marshall, "Microstructural control during processing of aluminium canning alloys", Materials Science Forum Vols. 217-222, 1996, pp. 19- 30 † |
H. E. Exner, "Analysis of Grain- and Particle-Size Distributions in Metallic Materials", International Metallurgical Review, Vol. 17, 1972, pp. 25 -42 † |
H. S. Campbell, "Superior Stress Corrosion Resistance of Wrought Aluminium-Magnesium Alloys Containing 1% Zinc", Spring Residential Conference, Loughbourough, UK, Mars 1983, pp. 82-100 † |
John E. Hatch, "Aluminum Properties and Physical Metallurgy", American Society for Metals, Metals Park, Ohio, USA, 5ème édition, janvier 1993,pp. 232-233 † |
Liste des désignations internationales d'alliages enregistrés, "Registration Record of International Alloy Designations and Chemical Composition Limits for Wrought Aluminum und Wrought Aluminum Alloys", The Aluminum Association, avril 1991, pp. 2-17 † |
Norme allemande LN 9073 de septembre 1991, 9 pages † |
Official Journal of the European Communities, No. C104/84-C104/91, 13 septembre 1974, 8 pages † |
P. Band and J.G. Harris, "Rolling of aluminium alloy plate", and "Discussion on rolling operations", Metals Technology, juillet-août 1975, pp. 287-293, 303-305. † |
P. Vachet, "Utilisation de l'Aluminium et de ses Alliages aux Basses Températures", Revue de Metallurgie, février 1964, pp. 173-180 † |
S.C. Flood et al., "The influence of extreme variations in casting parameters and iron & silicon compositions on can-end stock (AA-5182)", Light Metals 1995, Proceedings des sessions techniques de la 124ème Rencontre Annuellede TMS, Las Vegas, Nevada, USA, 12-16 février 1995, pp. 1127-1135 † |
Also Published As
Publication number | Publication date |
---|---|
DK0823489T4 (da) | 2008-08-18 |
EP0823489B1 (fr) | 2000-11-02 |
DE823489T1 (de) | 1998-07-16 |
DK0823489T3 (da) | 2001-01-29 |
EP0823489A1 (fr) | 1998-02-11 |
FR2752244A1 (fr) | 1998-02-13 |
FR2752244B1 (fr) | 1998-09-18 |
JPH1088270A (ja) | 1998-04-07 |
AU3320197A (en) | 1998-02-12 |
US5908518A (en) | 1999-06-01 |
ES2152073T5 (es) | 2008-03-16 |
AU709909B2 (en) | 1999-09-09 |
ES2152073T3 (es) | 2001-01-16 |
DE69703420T2 (de) | 2001-05-10 |
DE69703420T3 (de) | 2008-04-10 |
DE69703420D1 (de) | 2000-12-07 |
AU709909C (en) | 2006-07-13 |
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