EP0806299A2 - Matériau d'enregistrement pour le procédé d'impression par jet d'encre - Google Patents

Matériau d'enregistrement pour le procédé d'impression par jet d'encre Download PDF

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Publication number
EP0806299A2
EP0806299A2 EP97106976A EP97106976A EP0806299A2 EP 0806299 A2 EP0806299 A2 EP 0806299A2 EP 97106976 A EP97106976 A EP 97106976A EP 97106976 A EP97106976 A EP 97106976A EP 0806299 A2 EP0806299 A2 EP 0806299A2
Authority
EP
European Patent Office
Prior art keywords
recording material
ink
material according
weight
layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP97106976A
Other languages
German (de)
English (en)
Other versions
EP0806299A3 (fr
EP0806299B1 (fr
Inventor
Gerhard Dr. Dipl.-Ing. Dransmann
Horst Dipl.-Ing. Westfal
Claudia Dr. Dipl.-Chem. Jünger
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Felix Schoeller Jr Foto und Spezialpapiere GmbH
Original Assignee
Felix Schoeller Jr Foto und Spezialpapiere GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Felix Schoeller Jr Foto und Spezialpapiere GmbH filed Critical Felix Schoeller Jr Foto und Spezialpapiere GmbH
Publication of EP0806299A2 publication Critical patent/EP0806299A2/fr
Publication of EP0806299A3 publication Critical patent/EP0806299A3/fr
Application granted granted Critical
Publication of EP0806299B1 publication Critical patent/EP0806299B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52Macromolecular coatings
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/502Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording characterised by structural details, e.g. multilayer materials
    • B41M5/506Intermediate layers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/502Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording characterised by structural details, e.g. multilayer materials
    • B41M5/508Supports
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52Macromolecular coatings
    • B41M5/5218Macromolecular coatings characterised by inorganic additives, e.g. pigments, clays
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52Macromolecular coatings
    • B41M5/5245Macromolecular coatings characterised by the use of polymers containing cationic or anionic groups, e.g. mordants
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52Macromolecular coatings
    • B41M5/5254Macromolecular coatings characterised by the use of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds, e.g. vinyl polymers
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24802Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24802Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
    • Y10T428/24893Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] including particulate material
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24942Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/25Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
    • Y10T428/256Heavy metal or aluminum or compound thereof

Definitions

  • the invention relates to a recording material for the ink jet printing process (ink jet printing process).
  • the color printing technology associated with the general spread of electronic media has become very important in recent years.
  • the aim of this technology is to adapt the image quality of the color printouts to the level of silver salt photography.
  • thermo dye transfer system thermal dye transfer system
  • ink jet process Ink-Jet
  • electrophotography electrophotography
  • droplets of a recording liquid are applied to the surface of the recording material using various techniques.
  • a recording liquid ink
  • an ink jet is ejected from the nozzle, which dissolves into microscopic drops due to the surface tension.
  • the drops are charged electrically and placed on the base or deflected into a reservoir by means of downstream deflection plates which are controlled by the digital signals.
  • the image signal triggers a mechanical impulse that ejects the drop.
  • the first drop-on-demand printers used the piezoelectric Effect to cause the drops to be ejected.
  • the method is largely replaced by thermal ink jet, also called bubble jet.
  • the image signal activates a heating element, which creates a vapor bubble in the aqueous ink.
  • the resulting vapor pressure expels the drop.
  • the recording material (image receiving material) used for such recording systems generally consists of a support and an ink-receiving layer and, if appropriate, further auxiliary layers.
  • a polyester resin, diacetate or paper can be used as the carrier.
  • the ink-receiving layers are mostly hydrophilic coatings which are particularly well suited for the absorption of aqueous inks.
  • the ink-receiving layers usually consist of a pigment / binder mixture.
  • the pigments serve to retain the dyes from the recording liquid on the surface of the sheet.
  • Natural or synthetic polymers are used as binders, for example gelatin, starch, pectin, casein, carboxymethyl cellulose, polyvinyl alcohol, polyvinyl pyrrolidone and the like.
  • cationic substances are often used in the ink receiving layer to fix the ink dyes.
  • recording materials the backing of which is paper, and the ink-receiving layer contains a water-soluble binder, tend to have such problems as insufficient water resistance or cockle of the material.
  • a recording material is known from Japanese Patent Application Laid-Open No. 61-041585, which has a polyvinyl alcohol / polyvinylpyrrolidone mixture and, in addition to the above-mentioned lack of water resistance, is characterized by poor wet rub resistance.
  • a recording material is known from Japanese laid-open publication JP 06-297831, which has a porous layer with a pseudoboehmite / polyvinyl alcohol mixture. This enables fast drying times.
  • a disadvantage is the high layer application quantity (35-45 g / m 2 ) required here for rapid absorption of even large amounts of ink.
  • the object of the present invention is therefore to provide a recording material which does not have the disadvantages mentioned above, in particular has very good water resistance, very high resolution and color density.
  • a recording material comprising a support and a receiving layer, an upper layer being arranged on the receiving layer and containing an inorganic pigment which has fine pores and has cationic charge centers.
  • Aluminum oxides, pyrrogenic aluminum hydroxides and aluminum oxide hydrates are particularly well suited for this purpose, but in particular the ⁇ -aluminum oxide monohydrate or the metahydroxide ⁇ -AlO (OH) (boehmite) with a pore radius distribution between 10 to 35 ⁇ .
  • a finely divided silica such as pyrrogenic silica can be used in the top layer.
  • the amount of finely divided silica can vary between 30 and 70% by weight, based on the total amount of the pigment.
  • a polyvinyl alcohol is used as a binder in the top layer.
  • a partially saponified polyvinyl alcohol with a degree of saponification between 70 and 90 mol% is particularly suitable.
  • Cationically modified binders such as, for example, a cationic polyvinyl alcohol or cationically modified starch, are also very suitable.
  • other water-soluble polymers can also be used as binders.
  • the amount of the binder can be 20 to 90% by weight. The quantitative range is preferably 40 to 90% by weight, but in particular 50 to 80% by weight (based on the dried layer).
  • the quantitative ratio of inorganic pigment and / or filler particles to binder can be 1: 0.4 to 1: 100, but in particular 1: 2 to 1: 100.
  • the top layer additionally contains at least one cationic polymer such as, for example, a cationically modified polyvinyl alcohol, a cationically modified starch, a cationically modified polystyrene, a cationically modified polyvinylpyrrolidone and similar polymers. Quaternary, hydroxy or amino functional acrylate homo- and / or acrylate copolymers are particularly suitable.
  • the amount of the cationic polymer is 1 to 30% by weight, in particular 5 to 20% by weight, based on the dried one Layer.
  • the top layer may contain an additional cationic dye-fixing agent, for example a quaternary polyammonium salt from the group of polyvinylbenzyltrimethyl, polydiallyldimethyl, polymethacryloxyethyldimethylhydroxyethyl, polyhydroxypropyldimethylammonium chlorides.
  • an additional cationic dye-fixing agent for example a quaternary polyammonium salt from the group of polyvinylbenzyltrimethyl, polydiallyldimethyl, polymethacryloxyethyldimethylhydroxyethyl, polyhydroxypropyldimethylammonium chlorides.
  • other dye-fixing agents such as cationic cationic polyamines, cationic polyacrylamides, cationic polyethyleneimines can also be used.
  • the amount of the dye-fixing agent can be up to 5% by weight, in particular from 0.5 to 3% by weight.
  • the ink-receiving layer can contain binders, color-fixing compounds, hardening agents and other auxiliaries.
  • binders polyvinyl alcohol, modified polyvinyl alcohol, cationically modified polystyrene, carboxymethyl cellulose, polyvinyl pyrrolidone, polyvinyl acetate, starch, gelatin or mixtures thereof can be used as binders.
  • gelatin is used in the ink-receiving layer.
  • a pork rind gelatin with a gel strength of 200 to 300 bloom (measured according to BS 757, 1975) has proven to be particularly advantageous, but a bovine bone gelatin can also be used.
  • a further binder in another embodiment of the invention, up to 20% by weight (based on the total binder) of a further binder can additionally be present.
  • the additional binder is a modified polyvinyl alcohol, carboxymethyl cellulose or polyvinyl pyrrolidone. Particularly good results are achieved if, in addition to the binder and the dye-fixing agents which can be used in an amount of up to 5% by weight Means additionally a cationic polymer is used.
  • the cationic polymer can be a quaternary, hydroxy or amino functional acrylate homo- and / or acrylate copolymer. However, other cationic polymers such as a cationic polystyrene or a cationically modified starch can also be used.
  • the quantitative ratio cat. Polymer / binder in the receiving layer is 1: 2 to 1:20.
  • a plastic film (film) or preferably an uncoated or coated base paper can be used as the carrier.
  • Paper that is coated on both sides with synthetic resin and has a weight per unit area of 50 to 250 g / m 2 is particularly suitable.
  • Polyolefins or polyester, for example, can be used as the synthetic resin.
  • the application amount of the synthetic resin coating, which may also contain pigments, dyes and other auxiliaries, is at least 5 g / m 2 .
  • a polyethylene-coated paper is used.
  • a coated base paper, in particular a barite-coated paper, is also suitable as a carrier.
  • the back of the recording material can also have a functional layer, for example an anticurl and / or antistatic layer.
  • Both the ink absorption and the top layer are applied from an aqueous dispersion (coating composition) and dried.
  • the coating composition can be applied to the carrier using all customary application and metering methods, such as, for example, roller application, engraving or nipping methods and air brushes or roller doctor metering.
  • the application amount of the ink-receiving layer is 1.0 to 20 g / m 2 , preferably 8 to 14 g / m 2 .
  • the application amount of the top layer is 0.5 to 5.0 g / m 2 , preferably 1.0 to 4.0 g / m 2 .
  • Tables 1 and 2 below show some of the many possible embodiments of the invention: Table 1 Components of the ink-receiving layer A A1 A2 A3 A4 A5 A6 A7 Gelatin, 264 Bloom 91.8 81.8 73.6 73.4 82.6 - - Polyvinyl alcohol, degree of saponification: 98 mol% - - 8.2 - 9.2 31.6 41.0 Polyvinylpyrrolidone, Molgew .: 630,000 daltons - - - 18.4 - 31.6 41.0 Vinyl acetate / butyl acrylate cop. - - - - - 31.6 - Aminomethyl methacrylate 5.0 15.0 15.0 5.0 5.0 - 15.0 quat.
  • the quantities are expressed in% by weight and relate to dried layers.
  • the front side of a base paper neutrally sized with alkyl ketene dimer and coated on both sides with polyethylene 1) of 80 g / m 2 basis weight was first coated with an ink absorption layer according to A1 (Tab. 1) and then with an upper layer according to B1, B2, B6, B7 and B8 ( Tab. 2).
  • corresponding aqueous coating compositions were first prepared, which were then applied to the substrate to be coated using a roller doctor blade and dried.
  • the order weights were: 1) The front of the base paper was covered with an LDPE ( low-density polyethylene ”) coated (19 g / m 2 ).
  • the back of the base paper was coated with a mixture of LDPE and HDPE (high-density polyethylene).
  • the application weight was 20 g / m 2 .
  • the recording material obtained was in a so-called. Thermal Jet "process printed and then analyzed.
  • the front of the base paper from Example 1 was first provided with an ink-receiving layer in accordance with A2 (Table 1) and then with an upper layer in accordance with B2, B6 and B8 (Table 2).
  • the order weights were: Ink receiving layer 12 g / m 2
  • a base paper provided with a baryta layer on the front (basis weight: 80 g / m 2 ) was first provided with an ink absorption layer in accordance with A7 and then with an upper layer in accordance with B9.
  • the barite layer contained 85% by weight of BaSO 4 and 15% by weight of gelatin.
  • test conditions were as in Example 1.
  • the base paper from Example 1 was coated with an ink absorption layer according to A2 (12 g / m 2 ) and then provided with an upper layer according to B6 (4 g / m 2 ), but without boehmite with a narrow pore radius distribution, instead with aluminum hydroxide with a pore radius distribution of 28 to 1000 ⁇ (V1a) and 20 to 140 ⁇ (V1b).
  • the base paper from Example 1 was only coated with an ink receiving layer in accordance with A2 and A6 without and with the addition of aluminum hydroxide.
  • the quantities are expressed in% by weight and relate to dried layers.
  • the recording material obtained in the comparative examples was in a so-called. Thermal Jet "process printed and then analyzed. The results are summarized in Table 4.
  • the recording material was printed using an HP Deskjet 550 C ink jet printer from Hewlett Packard, which works on the bubble jet principle (thermal jet).
  • the density measurements were made using a Original Reflection Densitometer SOS-45 "carried out. The measurements were carried out for the basic colors cyan, magenta, yellow and black.
  • the recording material was immersed in water to investigate the water resistance.
  • the density (%) remaining in a 25 ° C water bath after 60 s is used as a measure of the water stability.
  • the gloss values were measured using the RL3 laboratory reflectometer from Dr. Long according to DIN 67530.
  • the drying behavior of the recording material is determined as follows:
  • a bar is printed on a sheet of paper with black ink (pure black) and placed on paper after a waiting time of 120 seconds (20 sheets).
  • the color transfer is taken as a measure of drying.
  • the drying time can be ⁇ 120, 120-240 and> 240 seconds.
  • the recording materials produced according to the invention are distinguished by better water resistance, shorter drying times and better bleed behavior. Even if the water resistance and drying times of the papers produced according to V1a and V1b are also good, the bleed behavior is unsatisfactory. With regard to the gloss, too, the values in Example 2.2 are higher than in the corresponding Comparative Examples V1a and V1b.

Landscapes

  • Ink Jet Recording Methods And Recording Media Thereof (AREA)
  • Ink Jet (AREA)
  • Paper (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Particle Formation And Scattering Control In Inkjet Printers (AREA)
EP97106976A 1996-05-09 1997-04-26 Matériau d'enregistrement pour le procédé d'impression par jet d'encre Expired - Lifetime EP0806299B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19618607A DE19618607C2 (de) 1996-05-09 1996-05-09 Aufzeichnungsmaterial für Tintenstrahl-Druckverfahren
DE19618607 1996-05-09

Publications (3)

Publication Number Publication Date
EP0806299A2 true EP0806299A2 (fr) 1997-11-12
EP0806299A3 EP0806299A3 (fr) 1998-04-08
EP0806299B1 EP0806299B1 (fr) 2001-10-31

Family

ID=7793782

Family Applications (1)

Application Number Title Priority Date Filing Date
EP97106976A Expired - Lifetime EP0806299B1 (fr) 1996-05-09 1997-04-26 Matériau d'enregistrement pour le procédé d'impression par jet d'encre

Country Status (8)

Country Link
US (1) US5911855A (fr)
EP (1) EP0806299B1 (fr)
JP (1) JP4024902B2 (fr)
AT (1) ATE207816T1 (fr)
DE (2) DE19618607C2 (fr)
DK (1) DK0806299T3 (fr)
ES (1) ES2166931T3 (fr)
PT (1) PT806299E (fr)

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1998056592A1 (fr) * 1997-06-13 1998-12-17 Ppg Industries Ohio, Inc. Composition de revetement et support d'impression
US6074761A (en) * 1997-06-13 2000-06-13 Ppg Industries Ohio, Inc. Inkjet printing media
EP1048480A1 (fr) * 1999-04-30 2000-11-02 Felix Schoeller jr Foto- und Spezialpapiere GmbH & Co. KG Matériau pour l'impression par jet d'encre contenant des couches de pigmentées
US6183844B1 (en) 1998-12-16 2001-02-06 Hewlett-Packard Company Inkjet printing medium comprising multiple coatings
EP1120281A1 (fr) * 2000-01-28 2001-08-01 Oji Paper Company Limited Matériau d'enregistrement à jet d' encre
EP1138513A1 (fr) * 2000-03-30 2001-10-04 Nippon Paper Industries Co., Ltd. Feuille multicouche réceptrice de colorants pour l'impression à jet d'encre
WO2002053391A1 (fr) 2000-12-28 2002-07-11 Fuji Photo Film B.V. Support d'enregistrement de jets d'encre
WO2003016068A1 (fr) 2001-08-15 2003-02-27 Fuji Photo Film B.V. Support d'enregistrement a jet d'encre
WO2004050379A1 (fr) 2002-12-04 2004-06-17 Fuji Photo Film B.V. Support d'enregistrement a jet d'encre
WO2004054813A1 (fr) 2002-12-13 2004-07-01 Fuji Photo Film B.V. Support d'impression a jet d'encre
WO2005032834A1 (fr) 2003-10-03 2005-04-14 Fuji Photo Film B.V. Support de reproduction
WO2005032835A1 (fr) 2003-10-03 2005-04-14 Fuji Photo Film B.V. Support d'impression
EP1738918A1 (fr) 2005-06-29 2007-01-03 Mitsubishi HiTec Paper Flensburg GmbH Matériau pour l'enregistrement par jet d'encre
EP1226965B2 (fr) 2001-01-26 2010-12-08 Eastman Kodak Company Elément pour l'impression au jet d'encre et procédé d'impression
EP2617580A1 (fr) 2012-01-17 2013-07-24 Mitsubishi HiTec Paper Europe GmbH Matériau d'enregistrement à jet d'encre
WO2013186367A1 (fr) * 2012-06-15 2013-12-19 Schoeller Technocell Gmbh & Co. Kg Couche de réception pour procédés d'impression numériques comprenant de la cellulose nanofibrillée

Families Citing this family (27)

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Publication number Priority date Publication date Assignee Title
US5681380A (en) 1995-06-05 1997-10-28 Kimberly-Clark Worldwide, Inc. Ink for ink jet printers
US6524379B2 (en) 1997-08-15 2003-02-25 Kimberly-Clark Worldwide, Inc. Colorants, colorant stabilizers, ink compositions, and improved methods of making the same
CA2298468A1 (fr) 1998-06-03 1999-12-09 John Gavin Macdonald Nouveaux photoamorceurs et applications
KR100591999B1 (ko) 1998-06-03 2006-06-22 킴벌리-클라크 월드와이드, 인크. 마이크로에멀젼 기술에 의해 제조된 네오나노플라스트 및잉크젯 프린팅용 잉크
WO2000004104A1 (fr) 1998-07-20 2000-01-27 Kimberly-Clark Worldwide, Inc. Compositions a jet d'encre ameliorees
EP1117698B1 (fr) 1998-09-28 2006-04-19 Kimberly-Clark Worldwide, Inc. Nouveaux photoamorceurs et leurs utilisations
EP1144512B1 (fr) 1999-01-19 2003-04-23 Kimberly-Clark Worldwide, Inc. Nouveaux colorants,stabilisateurs de colorants, compositions d'encre, et leur procedes de preparation ameliores
US6331056B1 (en) 1999-02-25 2001-12-18 Kimberly-Clark Worldwide, Inc. Printing apparatus and applications therefor
US6294698B1 (en) 1999-04-16 2001-09-25 Kimberly-Clark Worldwide, Inc. Photoinitiators and applications therefor
US6368395B1 (en) 1999-05-24 2002-04-09 Kimberly-Clark Worldwide, Inc. Subphthalocyanine colorants, ink compositions, and method of making the same
US6887559B1 (en) * 1999-10-01 2005-05-03 Cabot Corporation Recording medium
GB9930177D0 (en) * 1999-12-22 2000-02-09 Clariant Int Ltd Improvements in or relating to organic compounds
DE10022529A1 (de) * 2000-05-09 2001-11-15 Emtec Magnetics Gmbh Pigmenthaltiges Aufzeichnungsmaterial
JP3733283B2 (ja) * 2000-09-07 2006-01-11 キヤノン株式会社 インクジェット用記録媒体とその製造方法およびそれを用いたインクジェット記録方式による画像形成方法
DE10103716C5 (de) * 2001-01-26 2005-11-17 Felix Schoeller Jr. Foto- Und Spezialpapiere Gmbh & Co. Kg Poröses Tintenstrahlaufzeichnungsmaterial
DE10117504A1 (de) * 2001-04-07 2002-10-17 Degussa Injekt-Tinte
DE10138631A1 (de) * 2001-08-13 2003-02-27 Basf Ag Verfahren zur Herstellung von beschichtetem Papier mit hoher Weiße
US6843177B2 (en) 2001-09-14 2005-01-18 Fine Arts Group Llc Methods and materials for producing an image, and articles comprising materials for producing an image
US6979481B2 (en) * 2002-08-19 2005-12-27 Mohawk Paper Mills, Inc. Microporous photo glossy inkjet recording media
DE102005034827B3 (de) 2005-07-26 2007-03-01 Kanzan Spezialpapiere Gmbh Tintenstrahlaufzeichnungsmaterial
WO2008016303A1 (fr) * 2006-08-04 2008-02-07 Fujifilm Manufacturing Europe B.V. Membrane poreuse et support d'enregistrement comportant une telle membrane
EP2051860A1 (fr) * 2006-08-04 2009-04-29 Fuji Film Manufacturing Europe B.V. Membranes poreuses et support d'enregistrement les renfermant
WO2008016302A1 (fr) * 2006-08-04 2008-02-07 Fujifilm Manufacturing Europe B.V. Compositions pour membranes poreuses et supports d'enregistrement
AU2008337508B2 (en) 2007-12-17 2012-03-15 Technocell Dekor Gmbh & Co. Kg Compressible decorative paper impregnating agent which can be printed by the inkjet method
CN102991173A (zh) * 2012-12-27 2013-03-27 天津海华科技发展有限公司 一种环保医用激光打印胶片
CN102991175A (zh) * 2012-12-27 2013-03-27 天津海华科技发展有限公司 一种环保医用喷墨打印胶片
JP6152279B2 (ja) * 2013-02-19 2017-06-21 三菱製紙株式会社 化粧シート用原紙およびそれを用いた化粧シートおよび化粧板

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EP0298424A2 (fr) * 1987-07-07 1989-01-11 Asahi Glass Company Ltd. Milieu support pour une matière colorante
EP0331125A2 (fr) * 1988-03-04 1989-09-06 Canon Kabushiki Kaisha Matériau d'enregistrement et méthode d'enregistrement à jet d'encre l'utilisant
EP0450540A1 (fr) * 1990-04-02 1991-10-09 Canon Kabushiki Kaisha Support d'impression par jet d'encre et méthode l'utilisant
EP0732219A2 (fr) * 1995-03-15 1996-09-18 Canon Kabushiki Kaisha Elément d'impression et procédé d'impression à jet d'encre de même que procédé de formation d'images les utilisant
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US5880196A (en) * 1997-06-13 1999-03-09 Ppg Industries, Inc. Inkjet printing media
US6074761A (en) * 1997-06-13 2000-06-13 Ppg Industries Ohio, Inc. Inkjet printing media
US6340725B1 (en) 1997-06-13 2002-01-22 Hewlett-Packard Company Inkjet printing media
WO1998056592A1 (fr) * 1997-06-13 1998-12-17 Ppg Industries Ohio, Inc. Composition de revetement et support d'impression
US6183844B1 (en) 1998-12-16 2001-02-06 Hewlett-Packard Company Inkjet printing medium comprising multiple coatings
EP1048480A1 (fr) * 1999-04-30 2000-11-02 Felix Schoeller jr Foto- und Spezialpapiere GmbH & Co. KG Matériau pour l'impression par jet d'encre contenant des couches de pigmentées
US6502935B1 (en) 1999-04-30 2003-01-07 Felix Schoeller Jr. Foto-Und Spezialpapiere Gmbh & Co. Kg Ink-jet recording material comprising pigment layers
EP1120281A1 (fr) * 2000-01-28 2001-08-01 Oji Paper Company Limited Matériau d'enregistrement à jet d' encre
EP1138513A1 (fr) * 2000-03-30 2001-10-04 Nippon Paper Industries Co., Ltd. Feuille multicouche réceptrice de colorants pour l'impression à jet d'encre
WO2002053391A1 (fr) 2000-12-28 2002-07-11 Fuji Photo Film B.V. Support d'enregistrement de jets d'encre
EP1226965B2 (fr) 2001-01-26 2010-12-08 Eastman Kodak Company Elément pour l'impression au jet d'encre et procédé d'impression
WO2003016068A1 (fr) 2001-08-15 2003-02-27 Fuji Photo Film B.V. Support d'enregistrement a jet d'encre
WO2004050379A1 (fr) 2002-12-04 2004-06-17 Fuji Photo Film B.V. Support d'enregistrement a jet d'encre
WO2004054813A1 (fr) 2002-12-13 2004-07-01 Fuji Photo Film B.V. Support d'impression a jet d'encre
WO2005032834A1 (fr) 2003-10-03 2005-04-14 Fuji Photo Film B.V. Support de reproduction
WO2005032835A1 (fr) 2003-10-03 2005-04-14 Fuji Photo Film B.V. Support d'impression
EP1738918A1 (fr) 2005-06-29 2007-01-03 Mitsubishi HiTec Paper Flensburg GmbH Matériau pour l'enregistrement par jet d'encre
US8377521B2 (en) 2005-06-29 2013-02-19 Mitsubishi Hitec Paper Flensburgh Gmbh Ink jet recording material
EP2617580A1 (fr) 2012-01-17 2013-07-24 Mitsubishi HiTec Paper Europe GmbH Matériau d'enregistrement à jet d'encre
WO2013186367A1 (fr) * 2012-06-15 2013-12-19 Schoeller Technocell Gmbh & Co. Kg Couche de réception pour procédés d'impression numériques comprenant de la cellulose nanofibrillée
CN104379358A (zh) * 2012-06-15 2015-02-25 舍尔勒尔电子元件两合公司 用于数字印刷法的带有纳米纤丝化纤维素的接收层

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DE59705136D1 (de) 2001-12-06
PT806299E (pt) 2002-04-29
ES2166931T3 (es) 2002-05-01
EP0806299A3 (fr) 1998-04-08
US5911855A (en) 1999-06-15
DK0806299T3 (da) 2002-02-18
JPH10100532A (ja) 1998-04-21
JP4024902B2 (ja) 2007-12-19
DE19618607C2 (de) 1999-07-08
ATE207816T1 (de) 2001-11-15
DE19618607A1 (de) 1997-11-20
EP0806299B1 (fr) 2001-10-31

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