EP0792928B1 - Procédé de récupération d'aromates à partir d'essence de reforming - Google Patents
Procédé de récupération d'aromates à partir d'essence de reforming Download PDFInfo
- Publication number
- EP0792928B1 EP0792928B1 EP96120033A EP96120033A EP0792928B1 EP 0792928 B1 EP0792928 B1 EP 0792928B1 EP 96120033 A EP96120033 A EP 96120033A EP 96120033 A EP96120033 A EP 96120033A EP 0792928 B1 EP0792928 B1 EP 0792928B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- aromatics
- benzene
- hydrogenation
- extractive distillation
- distillation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G67/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only
- C10G67/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only
- C10G67/04—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only including solvent extraction as the refining step in the absence of hydrogen
- C10G67/0409—Extraction of unsaturated hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G21/00—Refining of hydrocarbon oils, in the absence of hydrogen, by extraction with selective solvents
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G7/00—Distillation of hydrocarbon oils
- C10G7/08—Azeotropic or extractive distillation
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Claims (6)
- Procédé pour l'obtention d'arômes purs à partir de reformat,
au cours duquel procédé, une étape de reformat est obtenue au cours d'une première étape du procédé à partir de reformat par distillation fractionnée avec un aromate d'un nombre de carbone sélectionné Cx ou à l'aide d'aromates de plusieurs nombres de carbone sélectionnés,
dans lequel l'étape de reformat est hydratée au cours d'une seconde étape du procédé de façon sélective avec du nickel ou du palladium sur un matériau support en tant que catalyseur d'hydratation et par conséquent, les conditions d'hydratation sont réglées de telle sorte que des non-aromates essentiellement soient notamment des oléfines, des dioléfines et des trioléfines, soient hydratées et par conséquent, les dioléfines et les trioléfines conjuguées soient hydratées, si possible, intégralement,
et au cours duquel procédé ensuite les produits hydratés de façon sélective contenant des aromates sont séparés au cours d'une troisième étape du procédé par distillation d'extraction et / ou par extraction liquide-liquide en des aromates et des non-aromates. - Procédé selon la revendication 1 dans lequel une étape de reformat est obtenue au cours d'une première étape du procédé, laquelle étape contient comme portion aromatique essentiellement du benzène.
- Procédé selon l'une quelconque des revendications 1 ou 2 au cours duquel la distillation extractive et / ou l'extraction liquide-liquide est réalisée à l'aide d'un solvant sélectif du groupe N-formylmorphine, N-méthylpyrrolidone, sulfolane, éthylène glycol ou de dérivés d'éthylène glycol.
- Procédé selon l'une quelconque des revendications 1 à 3, dans lequel une morpholine N-substituée comprenant 1 à 8 atomes de carbone est utilisée dans des substituants comme solvant sélectif.
- Procédé selon l'une quelconque des revendications 1 à 4, dans lequel les alcanes diols comprenant 2 à 5 atomes de carbone et / ou leurs éthers de mono et / ou dialkyle sont utilisés comme solvant sélectif.
- Procédé selon l'une quelconque des revendications 1 à 5, dans lequel les aromates purs sont séparés par distillation par le solvant sélectif au terme de la distillation extractive et / ou par extraction liquide-liquide.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19603901 | 1996-02-03 | ||
DE19603901A DE19603901A1 (de) | 1996-02-03 | 1996-02-03 | Verfahren zur Gewinnung von Reinaromaten aus Reformatbenzin und Vorrichtung zur Durchführung des Verfahrens |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0792928A2 EP0792928A2 (fr) | 1997-09-03 |
EP0792928A3 EP0792928A3 (fr) | 1998-04-01 |
EP0792928B1 true EP0792928B1 (fr) | 2004-03-17 |
Family
ID=7784424
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP96120033A Expired - Lifetime EP0792928B1 (fr) | 1996-02-03 | 1996-12-13 | Procédé de récupération d'aromates à partir d'essence de reforming |
Country Status (10)
Country | Link |
---|---|
US (1) | US6124514A (fr) |
EP (1) | EP0792928B1 (fr) |
JP (1) | JP4514839B2 (fr) |
KR (1) | KR970061835A (fr) |
AT (1) | ATE262020T1 (fr) |
CA (1) | CA2196585A1 (fr) |
CZ (1) | CZ25097A3 (fr) |
DE (2) | DE19603901A1 (fr) |
ES (1) | ES2217298T3 (fr) |
PL (1) | PL318211A1 (fr) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2010102712A2 (fr) | 2009-03-11 | 2010-09-16 | Uhde Gmbh | Procédé de préparation de composés aromatiques purs a partir de fractions d'hydrocarbure renfermant des composés aromatiques |
WO2011082993A1 (fr) | 2009-12-15 | 2011-07-14 | Basf Se | Procédé d'hydrogénation en phase gazeuse d'un courant d'hydrocarbures qui contient des composants polymérisables dans des conditions réactionnelles de l'hydrogénation en phase gazeuse |
DE102010051396A1 (de) | 2010-11-16 | 2012-05-16 | Thyssenkrupp Uhde Gmbh | Verfahren zur Entfernung schwersiedender Kohlenwasserstoffe aus Lösungsmittelströmen |
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US6469223B2 (en) * | 2000-01-04 | 2002-10-22 | Fina Technology, Inc. | Selective hydrogenation of dienes |
US6551502B1 (en) * | 2000-02-11 | 2003-04-22 | Gtc Technology Corporation | Process of removing sulfur compounds from gasoline |
US7838708B2 (en) | 2001-06-20 | 2010-11-23 | Grt, Inc. | Hydrocarbon conversion process improvements |
DE10150556A1 (de) | 2001-10-15 | 2003-04-17 | Basf Ag | Verfahren zur katalytischen Hydrierung |
US7158925B2 (en) * | 2002-04-18 | 2007-01-02 | International Business Machines Corporation | Facilitating simulation of a model within a distributed environment |
WO2007055690A1 (fr) * | 2005-11-10 | 2007-05-18 | Uop Llc | Procede d’hydrogenation selective d’olefines |
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US20060100469A1 (en) | 2004-04-16 | 2006-05-11 | Waycuilis John J | Process for converting gaseous alkanes to olefins and liquid hydrocarbons |
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US7462434B2 (en) * | 2005-12-21 | 2008-12-09 | Xerox Corporation | Imaging member with low surface energy polymer in anti-curl back coating layer |
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US7754404B2 (en) * | 2005-12-27 | 2010-07-13 | Xerox Corporation | Imaging member |
US7517624B2 (en) * | 2005-12-27 | 2009-04-14 | Xerox Corporation | Imaging member |
AP2012006510A0 (en) | 2006-02-03 | 2012-10-31 | Grt Inc | Continuous process for converting natural gas to liquid hydrocarbons |
EA013629B1 (ru) | 2006-02-03 | 2010-06-30 | ДжиАрТи, ИНК. | Способ отделения легких газов от галогенов |
US7527906B2 (en) * | 2006-06-20 | 2009-05-05 | Xerox Corporation | Imaging member having adjustable friction anticurl back coating |
US7790943B2 (en) * | 2006-06-27 | 2010-09-07 | Amt International, Inc. | Integrated process for removing benzene from gasoline and producing cyclohexane |
US7767373B2 (en) * | 2006-08-23 | 2010-08-03 | Xerox Corporation | Imaging member having high molecular weight binder |
WO2008148113A1 (fr) | 2007-05-24 | 2008-12-04 | Grt, Inc. | Réacteur à zones comprenant la capture et la libération réversibles d'halogénure d'hydrogène |
CA2705036C (fr) * | 2007-11-09 | 2017-07-04 | Ranfeng Ding | Systeme et procede de recombinaison d'hydrocarbure catalytique pour produire une essence de haute qualite |
KR100894400B1 (ko) * | 2007-11-29 | 2009-04-20 | 주식회사 엘지화학 | 벤젠 회수 유닛 에너지 효율 개선 방법 |
US7998646B2 (en) * | 2008-04-07 | 2011-08-16 | Xerox Corporation | Low friction electrostatographic imaging member |
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US8084173B2 (en) * | 2008-04-07 | 2011-12-27 | Xerox Corporation | Low friction electrostatographic imaging member |
US8282810B2 (en) | 2008-06-13 | 2012-10-09 | Marathon Gtf Technology, Ltd. | Bromine-based method and system for converting gaseous alkanes to liquid hydrocarbons using electrolysis for bromine recovery |
CA2730934C (fr) | 2008-07-18 | 2017-07-04 | Grt, Inc. | Processus continu pour une conversion de gaz naturel en hydrocarbures liquides |
US8173341B2 (en) * | 2009-05-01 | 2012-05-08 | Xerox Corporation | Flexible imaging members without anticurl layer |
US8124305B2 (en) * | 2009-05-01 | 2012-02-28 | Xerox Corporation | Flexible imaging members without anticurl layer |
US8168356B2 (en) | 2009-05-01 | 2012-05-01 | Xerox Corporation | Structurally simplified flexible imaging members |
US20100297544A1 (en) | 2009-05-22 | 2010-11-25 | Xerox Corporation | Flexible imaging members having a plasticized imaging layer |
US8003285B2 (en) | 2009-08-31 | 2011-08-23 | Xerox Corporation | Flexible imaging member belts |
US8241825B2 (en) | 2009-08-31 | 2012-08-14 | Xerox Corporation | Flexible imaging member belts |
US8367884B2 (en) | 2010-03-02 | 2013-02-05 | Marathon Gtf Technology, Ltd. | Processes and systems for the staged synthesis of alkyl bromides |
US8198495B2 (en) | 2010-03-02 | 2012-06-12 | Marathon Gtf Technology, Ltd. | Processes and systems for the staged synthesis of alkyl bromides |
US8232030B2 (en) | 2010-03-17 | 2012-07-31 | Xerox Corporation | Curl-free imaging members with a slippery surface |
US8343700B2 (en) | 2010-04-16 | 2013-01-01 | Xerox Corporation | Imaging members having stress/strain free layers |
US8470505B2 (en) | 2010-06-10 | 2013-06-25 | Xerox Corporation | Imaging members having improved imaging layers |
US8394560B2 (en) | 2010-06-25 | 2013-03-12 | Xerox Corporation | Imaging members having an enhanced charge blocking layer |
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US8815050B2 (en) | 2011-03-22 | 2014-08-26 | Marathon Gtf Technology, Ltd. | Processes and systems for drying liquid bromine |
US8436220B2 (en) | 2011-06-10 | 2013-05-07 | Marathon Gtf Technology, Ltd. | Processes and systems for demethanization of brominated hydrocarbons |
US8829256B2 (en) | 2011-06-30 | 2014-09-09 | Gtc Technology Us, Llc | Processes and systems for fractionation of brominated hydrocarbons in the conversion of natural gas to liquid hydrocarbons |
US8877413B2 (en) | 2011-08-23 | 2014-11-04 | Xerox Corporation | Flexible imaging members comprising improved ground strip |
US8802908B2 (en) | 2011-10-21 | 2014-08-12 | Marathon Gtf Technology, Ltd. | Processes and systems for separate, parallel methane and higher alkanes' bromination |
US9193641B2 (en) | 2011-12-16 | 2015-11-24 | Gtc Technology Us, Llc | Processes and systems for conversion of alkyl bromides to higher molecular weight hydrocarbons in circulating catalyst reactor-regenerator systems |
EP2882830B1 (fr) * | 2012-08-09 | 2018-01-03 | Council of Scientific & Industrial Research | Procédé de fabrication d'essence à faible teneur en benzène par récupération de benzène à pureté élevée à partir de fraction d'essence de craquage non traitée contenant des peroxydes organiques |
CN103160310A (zh) * | 2013-03-15 | 2013-06-19 | 西南石油大学 | 一种萃取分离芳烃所用的复合溶剂及其萃取方法 |
US9046798B2 (en) | 2013-08-16 | 2015-06-02 | Xerox Corporation | Imaging members having electrically and mechanically tuned imaging layers |
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US9075327B2 (en) | 2013-09-20 | 2015-07-07 | Xerox Corporation | Imaging members and methods for making the same |
KR102300823B1 (ko) * | 2017-12-29 | 2021-09-09 | 한화솔루션 주식회사 | 수소화 반응용 촉매 및 이의 제조방법 |
US11802248B2 (en) * | 2020-09-07 | 2023-10-31 | Sk Innovation Co., Ltd. | Process for reducing unsaturated hydrocarbons in aromatic fraction through selective hydrogenation |
Family Cites Families (24)
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US2084471A (en) * | 1933-10-18 | 1937-06-22 | Standard Oil Dev Co | Process of treating lubricating oils with selective solvents |
US2960548A (en) * | 1958-09-19 | 1960-11-15 | Pure Oil Co | Extraction of aromatics from hydrocarbon fractions |
US3044950A (en) * | 1958-12-15 | 1962-07-17 | Gulf Research Development Co | Process for upgrading catalytically cracked gasoline |
NL134185C (fr) * | 1960-07-07 | |||
NL262671A (fr) * | 1961-03-22 | |||
US3221078A (en) * | 1961-07-06 | 1965-11-30 | Engelhard Ind Inc | Selective hydrogenation of olefins in dripolene |
US3514395A (en) * | 1968-05-29 | 1970-05-26 | Sun Oil Co | Process for producing a high aromatic,low color,uv stable process oil |
BE792747A (fr) * | 1971-12-14 | 1973-03-30 | Metallgesellschaft Ag | Procede et catalyseur d'hydrogenation, applicable notamment pour obtenir des produits aromatiques tres purs |
GB1400884A (en) * | 1972-03-13 | 1975-07-16 | Ici Ltd | Treatment of the feedstock for a aromatic hydrocarbon extraction process |
FR2213335B1 (fr) * | 1973-01-10 | 1976-04-23 | Inst Francais Du Petrole | |
US3865716A (en) * | 1973-09-13 | 1975-02-11 | Exxon Research Engineering Co | Process for the selective hydrogenation of olefins |
US4503267A (en) * | 1983-10-24 | 1985-03-05 | Union Camp Corporation | Extraction of phenolics from hydrocarbons |
US4781820A (en) * | 1985-07-05 | 1988-11-01 | Union Carbide Corporation | Aromatic extraction process using mixed polyalkylene glycols/glycol ether solvents |
US5202520A (en) * | 1989-03-09 | 1993-04-13 | Uop | Method for aromatic hydrocarbon recovery |
US5139651A (en) * | 1989-09-18 | 1992-08-18 | Uop | Aromatic extraction process using mixed polyalkylene glycol/glycol ether solvents |
DE3942950A1 (de) * | 1989-12-23 | 1991-06-27 | Krupp Koppers Gmbh | Verfahren zur gleichzeitigen gewinnung von reinem benzol und reinem tuluol |
US5225072A (en) * | 1990-08-03 | 1993-07-06 | Uop | Processes for the separation of aromatic hydrocarbons from a hydrocarbon mixture |
DE4101848A1 (de) * | 1991-01-23 | 1992-07-30 | Krupp Koppers Gmbh | Verfahren zur abtrennung von aromaten aus kohlenwasserstoffgemischen beliebigen aromatengehaltes |
US5336840A (en) * | 1991-02-20 | 1994-08-09 | Uop | Process for the separation of aromatic hydrocarbons with energy redistribution |
US5191152A (en) * | 1991-02-20 | 1993-03-02 | Uop | Process for the separation of aromatic hydrocarbons with energy redistribution |
US5310480A (en) * | 1991-10-31 | 1994-05-10 | Uop | Processes for the separation of aromatic hydrocarbons from a hydrocarbon mixture |
US5399244A (en) * | 1993-12-06 | 1995-03-21 | Glitsch, Inc. | Process to recover benzene from mixed hydrocarbons by extractive distillation |
US5685972A (en) * | 1995-07-14 | 1997-11-11 | Timken; Hye Kyung C. | Production of benzene, toluene, and xylene (BTX) from FCC naphtha |
FR2743080B1 (fr) * | 1995-12-27 | 1998-02-06 | Inst Francais Du Petrole | Procede de reduction selective de la teneur en benzene et en composes insatures legers d'une coupe d'hydrocarbures |
-
1996
- 1996-02-03 DE DE19603901A patent/DE19603901A1/de not_active Withdrawn
- 1996-12-13 EP EP96120033A patent/EP0792928B1/fr not_active Expired - Lifetime
- 1996-12-13 ES ES96120033T patent/ES2217298T3/es not_active Expired - Lifetime
- 1996-12-13 AT AT96120033T patent/ATE262020T1/de active
- 1996-12-13 DE DE59610939T patent/DE59610939D1/de not_active Expired - Lifetime
-
1997
- 1997-01-28 CZ CZ97250A patent/CZ25097A3/cs unknown
- 1997-01-30 PL PL97318211A patent/PL318211A1/xx unknown
- 1997-01-31 JP JP01929297A patent/JP4514839B2/ja not_active Expired - Fee Related
- 1997-01-31 KR KR1019970002925A patent/KR970061835A/ko not_active Application Discontinuation
- 1997-01-31 CA CA002196585A patent/CA2196585A1/fr not_active Abandoned
- 1997-01-31 US US08/791,893 patent/US6124514A/en not_active Expired - Lifetime
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2010102712A2 (fr) | 2009-03-11 | 2010-09-16 | Uhde Gmbh | Procédé de préparation de composés aromatiques purs a partir de fractions d'hydrocarbure renfermant des composés aromatiques |
DE102009012265A1 (de) | 2009-03-11 | 2010-09-23 | Uhde Gmbh | Verfahren zur Gewinnung von Reinaromaten aus aromatenhaltigen Kohlenwasserstofffraktionen |
WO2011082993A1 (fr) | 2009-12-15 | 2011-07-14 | Basf Se | Procédé d'hydrogénation en phase gazeuse d'un courant d'hydrocarbures qui contient des composants polymérisables dans des conditions réactionnelles de l'hydrogénation en phase gazeuse |
DE102010051396A1 (de) | 2010-11-16 | 2012-05-16 | Thyssenkrupp Uhde Gmbh | Verfahren zur Entfernung schwersiedender Kohlenwasserstoffe aus Lösungsmittelströmen |
WO2012065703A1 (fr) | 2010-11-16 | 2012-05-24 | Thyssenkrupp Uhde Gmbh | Procédé pour l'élimination d'hydrocarbures à point d'ébullition élevé de courants de solvants |
Also Published As
Publication number | Publication date |
---|---|
PL318211A1 (en) | 1997-08-04 |
ES2217298T3 (es) | 2004-11-01 |
CZ25097A3 (en) | 1997-08-13 |
CA2196585A1 (fr) | 1997-08-04 |
KR970061835A (ko) | 1997-09-12 |
ATE262020T1 (de) | 2004-04-15 |
EP0792928A2 (fr) | 1997-09-03 |
EP0792928A3 (fr) | 1998-04-01 |
JPH09309846A (ja) | 1997-12-02 |
US6124514A (en) | 2000-09-26 |
DE19603901A1 (de) | 1997-08-07 |
JP4514839B2 (ja) | 2010-07-28 |
DE59610939D1 (de) | 2004-04-22 |
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