EP0792928B1 - Procédé de récupération d'aromates à partir d'essence de reforming - Google Patents

Procédé de récupération d'aromates à partir d'essence de reforming Download PDF

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Publication number
EP0792928B1
EP0792928B1 EP96120033A EP96120033A EP0792928B1 EP 0792928 B1 EP0792928 B1 EP 0792928B1 EP 96120033 A EP96120033 A EP 96120033A EP 96120033 A EP96120033 A EP 96120033A EP 0792928 B1 EP0792928 B1 EP 0792928B1
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EP
European Patent Office
Prior art keywords
aromatics
benzene
hydrogenation
extractive distillation
distillation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP96120033A
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German (de)
English (en)
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EP0792928A2 (fr
EP0792928A3 (fr
Inventor
Gerd Emmrich
Hans-Christoph Schneider
Helmut Dr. Gehrke
Bernard Dr. Firnhaber
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BASF SE
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BASF SE
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Publication of EP0792928A2 publication Critical patent/EP0792928A2/fr
Publication of EP0792928A3 publication Critical patent/EP0792928A3/fr
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Publication of EP0792928B1 publication Critical patent/EP0792928B1/fr
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G67/00Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only
    • C10G67/02Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only
    • C10G67/04Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only including solvent extraction as the refining step in the absence of hydrogen
    • C10G67/0409Extraction of unsaturated hydrocarbons
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G21/00Refining of hydrocarbon oils, in the absence of hydrogen, by extraction with selective solvents
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G7/00Distillation of hydrocarbon oils
    • C10G7/08Azeotropic or extractive distillation

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Claims (6)

  1. Procédé pour l'obtention d'arômes purs à partir de reformat,
    au cours duquel procédé, une étape de reformat est obtenue au cours d'une première étape du procédé à partir de reformat par distillation fractionnée avec un aromate d'un nombre de carbone sélectionné Cx ou à l'aide d'aromates de plusieurs nombres de carbone sélectionnés,
    dans lequel l'étape de reformat est hydratée au cours d'une seconde étape du procédé de façon sélective avec du nickel ou du palladium sur un matériau support en tant que catalyseur d'hydratation et par conséquent, les conditions d'hydratation sont réglées de telle sorte que des non-aromates essentiellement soient notamment des oléfines, des dioléfines et des trioléfines, soient hydratées et par conséquent, les dioléfines et les trioléfines conjuguées soient hydratées, si possible, intégralement,
    et au cours duquel procédé ensuite les produits hydratés de façon sélective contenant des aromates sont séparés au cours d'une troisième étape du procédé par distillation d'extraction et / ou par extraction liquide-liquide en des aromates et des non-aromates.
  2. Procédé selon la revendication 1 dans lequel une étape de reformat est obtenue au cours d'une première étape du procédé, laquelle étape contient comme portion aromatique essentiellement du benzène.
  3. Procédé selon l'une quelconque des revendications 1 ou 2 au cours duquel la distillation extractive et / ou l'extraction liquide-liquide est réalisée à l'aide d'un solvant sélectif du groupe N-formylmorphine, N-méthylpyrrolidone, sulfolane, éthylène glycol ou de dérivés d'éthylène glycol.
  4. Procédé selon l'une quelconque des revendications 1 à 3, dans lequel une morpholine N-substituée comprenant 1 à 8 atomes de carbone est utilisée dans des substituants comme solvant sélectif.
  5. Procédé selon l'une quelconque des revendications 1 à 4, dans lequel les alcanes diols comprenant 2 à 5 atomes de carbone et / ou leurs éthers de mono et / ou dialkyle sont utilisés comme solvant sélectif.
  6. Procédé selon l'une quelconque des revendications 1 à 5, dans lequel les aromates purs sont séparés par distillation par le solvant sélectif au terme de la distillation extractive et / ou par extraction liquide-liquide.
EP96120033A 1996-02-03 1996-12-13 Procédé de récupération d'aromates à partir d'essence de reforming Expired - Lifetime EP0792928B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19603901 1996-02-03
DE19603901A DE19603901A1 (de) 1996-02-03 1996-02-03 Verfahren zur Gewinnung von Reinaromaten aus Reformatbenzin und Vorrichtung zur Durchführung des Verfahrens

Publications (3)

Publication Number Publication Date
EP0792928A2 EP0792928A2 (fr) 1997-09-03
EP0792928A3 EP0792928A3 (fr) 1998-04-01
EP0792928B1 true EP0792928B1 (fr) 2004-03-17

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EP96120033A Expired - Lifetime EP0792928B1 (fr) 1996-02-03 1996-12-13 Procédé de récupération d'aromates à partir d'essence de reforming

Country Status (10)

Country Link
US (1) US6124514A (fr)
EP (1) EP0792928B1 (fr)
JP (1) JP4514839B2 (fr)
KR (1) KR970061835A (fr)
AT (1) ATE262020T1 (fr)
CA (1) CA2196585A1 (fr)
CZ (1) CZ25097A3 (fr)
DE (2) DE19603901A1 (fr)
ES (1) ES2217298T3 (fr)
PL (1) PL318211A1 (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010102712A2 (fr) 2009-03-11 2010-09-16 Uhde Gmbh Procédé de préparation de composés aromatiques purs a partir de fractions d'hydrocarbure renfermant des composés aromatiques
WO2011082993A1 (fr) 2009-12-15 2011-07-14 Basf Se Procédé d'hydrogénation en phase gazeuse d'un courant d'hydrocarbures qui contient des composants polymérisables dans des conditions réactionnelles de l'hydrogénation en phase gazeuse
DE102010051396A1 (de) 2010-11-16 2012-05-16 Thyssenkrupp Uhde Gmbh Verfahren zur Entfernung schwersiedender Kohlenwasserstoffe aus Lösungsmittelströmen

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Cited By (5)

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Publication number Priority date Publication date Assignee Title
WO2010102712A2 (fr) 2009-03-11 2010-09-16 Uhde Gmbh Procédé de préparation de composés aromatiques purs a partir de fractions d'hydrocarbure renfermant des composés aromatiques
DE102009012265A1 (de) 2009-03-11 2010-09-23 Uhde Gmbh Verfahren zur Gewinnung von Reinaromaten aus aromatenhaltigen Kohlenwasserstofffraktionen
WO2011082993A1 (fr) 2009-12-15 2011-07-14 Basf Se Procédé d'hydrogénation en phase gazeuse d'un courant d'hydrocarbures qui contient des composants polymérisables dans des conditions réactionnelles de l'hydrogénation en phase gazeuse
DE102010051396A1 (de) 2010-11-16 2012-05-16 Thyssenkrupp Uhde Gmbh Verfahren zur Entfernung schwersiedender Kohlenwasserstoffe aus Lösungsmittelströmen
WO2012065703A1 (fr) 2010-11-16 2012-05-24 Thyssenkrupp Uhde Gmbh Procédé pour l'élimination d'hydrocarbures à point d'ébullition élevé de courants de solvants

Also Published As

Publication number Publication date
PL318211A1 (en) 1997-08-04
ES2217298T3 (es) 2004-11-01
CZ25097A3 (en) 1997-08-13
CA2196585A1 (fr) 1997-08-04
KR970061835A (ko) 1997-09-12
ATE262020T1 (de) 2004-04-15
EP0792928A2 (fr) 1997-09-03
EP0792928A3 (fr) 1998-04-01
JPH09309846A (ja) 1997-12-02
US6124514A (en) 2000-09-26
DE19603901A1 (de) 1997-08-07
JP4514839B2 (ja) 2010-07-28
DE59610939D1 (de) 2004-04-22

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