EP0774016A1 - Procede de phosphatage sans rin age final - Google Patents
Procede de phosphatage sans rin age finalInfo
- Publication number
- EP0774016A1 EP0774016A1 EP95932747A EP95932747A EP0774016A1 EP 0774016 A1 EP0774016 A1 EP 0774016A1 EP 95932747 A EP95932747 A EP 95932747A EP 95932747 A EP95932747 A EP 95932747A EP 0774016 A1 EP0774016 A1 EP 0774016A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- range
- acid
- phosphating
- phosphating solution
- zinc
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims abstract description 51
- 239000002253 acid Substances 0.000 claims abstract description 38
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims abstract description 33
- 229910052751 metal Inorganic materials 0.000 claims abstract description 15
- 239000002184 metal Substances 0.000 claims abstract description 15
- 230000002378 acidificating effect Effects 0.000 claims abstract description 7
- PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910001437 manganese ion Inorganic materials 0.000 claims abstract description 5
- 239000011701 zinc Substances 0.000 claims description 53
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 36
- 239000011572 manganese Substances 0.000 claims description 29
- 229910019142 PO4 Inorganic materials 0.000 claims description 28
- 239000010452 phosphate Substances 0.000 claims description 28
- 229910052725 zinc Inorganic materials 0.000 claims description 24
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 22
- 229910001335 Galvanized steel Inorganic materials 0.000 claims description 17
- 239000008397 galvanized steel Substances 0.000 claims description 17
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims description 15
- 239000007788 liquid Substances 0.000 claims description 15
- 229910000831 Steel Inorganic materials 0.000 claims description 13
- 229910021645 metal ion Inorganic materials 0.000 claims description 13
- 239000010959 steel Substances 0.000 claims description 13
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 11
- 239000011975 tartaric acid Substances 0.000 claims description 11
- 235000002906 tartaric acid Nutrition 0.000 claims description 11
- 239000013543 active substance Substances 0.000 claims description 10
- 238000001035 drying Methods 0.000 claims description 9
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical class OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 7
- 125000004432 carbon atom Chemical group C* 0.000 claims description 7
- 239000007888 film coating Substances 0.000 claims description 7
- 238000009501 film coating Methods 0.000 claims description 7
- 229910052759 nickel Inorganic materials 0.000 claims description 7
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 6
- 229910045601 alloy Inorganic materials 0.000 claims description 6
- 239000000956 alloy Substances 0.000 claims description 6
- 229910052782 aluminium Inorganic materials 0.000 claims description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 6
- 238000007664 blowing Methods 0.000 claims description 4
- 229910052791 calcium Inorganic materials 0.000 claims description 4
- 229910052749 magnesium Inorganic materials 0.000 claims description 4
- 229910052748 manganese Inorganic materials 0.000 claims description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 3
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 3
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 3
- 229910052802 copper Inorganic materials 0.000 claims description 3
- 239000010949 copper Substances 0.000 claims description 3
- 229910052742 iron Inorganic materials 0.000 claims description 3
- 239000007789 gas Substances 0.000 claims description 2
- 230000005855 radiation Effects 0.000 claims description 2
- 239000000470 constituent Substances 0.000 claims 2
- 239000011260 aqueous acid Substances 0.000 claims 1
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 claims 1
- 239000000758 substrate Substances 0.000 abstract description 3
- 239000000243 solution Substances 0.000 description 66
- 235000021317 phosphate Nutrition 0.000 description 24
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 14
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
- 239000000126 substance Substances 0.000 description 10
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 238000000576 coating method Methods 0.000 description 7
- 238000005260 corrosion Methods 0.000 description 7
- 230000007797 corrosion Effects 0.000 description 7
- 238000010422 painting Methods 0.000 description 7
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 description 6
- 230000004913 activation Effects 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 6
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 6
- 239000011248 coating agent Substances 0.000 description 5
- 238000010276 construction Methods 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 239000003973 paint Substances 0.000 description 5
- XTEGARKTQYYJKE-UHFFFAOYSA-M Chlorate Chemical compound [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- 229910017052 cobalt Inorganic materials 0.000 description 4
- 239000010941 cobalt Substances 0.000 description 4
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 238000005303 weighing Methods 0.000 description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 3
- 230000002349 favourable effect Effects 0.000 description 3
- 239000004922 lacquer Substances 0.000 description 3
- 239000004310 lactic acid Substances 0.000 description 3
- 235000014655 lactic acid Nutrition 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- 239000010936 titanium Substances 0.000 description 3
- 229910052719 titanium Inorganic materials 0.000 description 3
- HWTDMFJYBAURQR-UHFFFAOYSA-N 80-82-0 Chemical compound OS(=O)(=O)C1=CC=CC=C1[N+]([O-])=O HWTDMFJYBAURQR-UHFFFAOYSA-N 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- 229910002651 NO3 Inorganic materials 0.000 description 2
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 2
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- 230000003213 activating effect Effects 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 229910052796 boron Inorganic materials 0.000 description 2
- 230000001680 brushing effect Effects 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 238000004070 electrodeposition Methods 0.000 description 2
- 150000002222 fluorine compounds Chemical class 0.000 description 2
- 230000008595 infiltration Effects 0.000 description 2
- 238000001764 infiltration Methods 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 229910001463 metal phosphate Inorganic materials 0.000 description 2
- 230000001603 reducing effect Effects 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- PUZPDOWCWNUUKD-UHFFFAOYSA-M sodium fluoride Chemical compound [F-].[Na+] PUZPDOWCWNUUKD-UHFFFAOYSA-M 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- JUWGUJSXVOBPHP-UHFFFAOYSA-B titanium(4+);tetraphosphate Chemical class [Ti+4].[Ti+4].[Ti+4].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O JUWGUJSXVOBPHP-UHFFFAOYSA-B 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 229910052845 zircon Inorganic materials 0.000 description 2
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 230000001464 adherent effect Effects 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- KRVSOGSZCMJSLX-UHFFFAOYSA-L chromic acid Substances O[Cr](O)(=O)=O KRVSOGSZCMJSLX-UHFFFAOYSA-L 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000010622 cold drawing Methods 0.000 description 1
- 239000010960 cold rolled steel Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229910001431 copper ion Inorganic materials 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 125000001153 fluoro group Chemical group F* 0.000 description 1
- 239000013505 freshwater Substances 0.000 description 1
- AWJWCTOOIBYHON-UHFFFAOYSA-N furo[3,4-b]pyrazine-5,7-dione Chemical compound C1=CN=C2C(=O)OC(=O)C2=N1 AWJWCTOOIBYHON-UHFFFAOYSA-N 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 239000011775 sodium fluoride Substances 0.000 description 1
- 235000013024 sodium fluoride Nutrition 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
- 238000004846 x-ray emission Methods 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/07—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
- C23C22/08—Orthophosphates
- C23C22/18—Orthophosphates containing manganese cations
- C23C22/182—Orthophosphates containing manganese cations containing also zinc cations
- C23C22/184—Orthophosphates containing manganese cations containing also zinc cations containing also nickel cations
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/07—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
- C23C22/08—Orthophosphates
- C23C22/12—Orthophosphates containing zinc cations
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/07—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
- C23C22/08—Orthophosphates
- C23C22/12—Orthophosphates containing zinc cations
- C23C22/17—Orthophosphates containing zinc cations containing also organic acids
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/07—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
- C23C22/08—Orthophosphates
- C23C22/18—Orthophosphates containing manganese cations
- C23C22/182—Orthophosphates containing manganese cations containing also zinc cations
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/34—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides
- C23C22/36—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides containing also phosphates
- C23C22/362—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides containing also phosphates containing also zinc cations
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/34—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides
- C23C22/36—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides containing also phosphates
- C23C22/364—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides containing also phosphates containing also manganese cations
- C23C22/365—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides containing also phosphates containing also manganese cations containing also zinc and nickel cations
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/73—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals characterised by the process
- C23C22/76—Applying the liquid by spraying
Definitions
- the invention relates to a phosphating solution and a method for phosphating surfaces made of steel, zinc, aluminum or their alloys in each case. It is particularly suitable for the phosphating of electrolytically galvanized or hot-dip galvanized steel.
- the phosphating solutions are not rinsed off with water in the sense of a so-called "no-rinse process" after the intended duration of action on the surfaces, but dried directly.
- the method is therefore particularly suitable for use in continuously running strip treatment plants.
- the phosphating of metals pursues the goal of producing firmly adherent metal phosphate layers on the metal surface, which in themselves improve the corrosion resistance and, in conjunction with lacquers and other organic coatings, contribute to a substantial increase in lacquer adhesion and resistance to infiltration Corrosion stress contribute.
- Such phosphating processes have been known for a long time.
- low-zinc phosphating processes in particular have recently been preferred, in which the phosphating solutions contain comparatively low contents of zinc ions of e.g. B. 0.5 to 2 g / 1.
- phosphate solutions which contain 1.0 to 6.0 g / 1 zinc and 8 to 25 g / 1 phosphate.
- Other optional components are nickel, cobalt, manganese, magnesium and calcium in amounts of 0.5 to 5.0 g / 1 each, iron (II) in amounts of up to 2 g / 1 and copper in amounts of 3 to 50 mg / 1 .
- DE-C-2739066 describes a phosphate process in which water rinsing is undesirable from an environmental and cost point of view can be dispensed with.
- the surfaces are brought into contact with a phosphating solution at a temperature of 50 to 75 ° C. for a period of 1 to 5 seconds, which contains 0.1 to 5 g / 1 zinc, 1 to 10 parts by weight of nickel and / or cobalt per part by weight of zinc, 5 to 50 g / 1 phosphate and 0.5 to 5 g / 1 hydrogen peroxide as accelerator.
- a phosphating solution at a temperature of 50 to 75 ° C. for a period of 1 to 5 seconds, which contains 0.1 to 5 g / 1 zinc, 1 to 10 parts by weight of nickel and / or cobalt per part by weight of zinc, 5 to 50 g / 1 phosphate and 0.5 to 5 g / 1 hydrogen peroxide as accelerator.
- phosphating solutions with a zinc content of more than 5 g / l
- EP-B-141 341 also describes a phosphating process in which rinsing with water is dispensed with. This method was developed in particular for stationary structures such as bridges or the like. Accordingly, treatment is carried out with a solution which contains 1 to 5% by weight of zinc, 1 to 20% by weight of phosphoric acid, 0.01 to 0.5% by weight of cobalt and / or nickel and 0.02 to 1.5 Contains wt .-% of an accelerator. After the application of the phosphating solution, which can be carried out, for example, by wiping, brushing, brushing, rolling up or spraying on, the solution is left to act for an unspecified time, during which the solution reacts or only partially reacts. In both cases, you can rinse after exposure.
- the phosphating solution described above has high contents of zinc and phosphate.
- Phosphating solutions in similar concentration ranges are also known for depositing phosphate layers on metal parts which are to be subjected to cold mechanical shaping, for example by drawing or pressing.
- the relatively thick phosphate layers which separate out here and which can be impregnated with oil to increase their effectiveness act as lubricants. medium and reduce the friction between tool and workpiece. They are usually not suitable as pretreatment before painting, since the paint adhesion on the thick phosphate layers is only poor under mechanical stress.
- a phosphate solution which can be used to form phosphate layers on steel strip or wire as a lubricant before cold drawing or other deformations, is described, for example, in DE-B-2552 122. Accordingly, solutions are used which contain zinc in an amount of 5 to 100 g / 1 and phosphate in an amount of 10 to 150 g / 1 and nitrate acting as an accelerator in an amount of 10 to 80 g / 1. The phosphating solution is brought into contact with the surface for a period of 5 to 15 seconds and then rinsed off with water.
- the object of the invention is to provide phosphating processes and phosphating solutions which are intended for use in continuously running belt systems and in which washing of the treated surfaces with water can be dispensed with.
- the invention relates to a method for phosphating surfaces made of steel, zinc, aluminum or their alloys in each case by treatment with acidic, zinc and phosphate-containing solutions and drying the solutions without intermediate rinsing, characterized in that the surfaces be brought into contact with a phosphating solution which
- the phosphating solution contains and has a pH in the range of 1 to 4. Zinc concentrations between 5 and 25 g / 1 are preferable because of the increased process reliability. If the requirements for the corrosion protection effect are not too high, for example for use in the household appliance sector, it is sufficient to use zinc as the only layer-forming cation. For improved corrosion protection, as is required, for example, for use in vehicle construction, it is preferred to use a phosphating process in which the phosphating solution additionally contains 2 to 25 g / 1 manganese ions, preferably 5 to 25 g / 1 . In addition or instead of this, the phosphating solution can contain further components to optimize the properties of the phosphate layer for the intended use of the pretreated material.
- the phosphating solution can also contain one or more divalent metal ions in amounts of 0.1 to 15 g / 1 each included, these additional metal ions are preferably selected from nickel, cobalt, calcium and magnesium.
- the phosphating solution can contain iron in amounts of 0.01 to 5 g / 1 and / or 3 to 200 mg / 1 copper ions.
- fluoride in free or complex-bound form for example as fluorocomplexes of boron, silicon, titanium or zircon, can have a favorable effect on the layer formation. This is the case in particular in the phosphating of hot-dip galvanized steel.
- the effective fluoride limits are between 0.01 and 5 g / 1.
- the phosphating solutions tend to be unstable. They can be stabilized by adding 0.1 to 100 g / 1 of a chelating hydroxycarboxylic acid with 3 to 6 carbon atoms. Examples of such hydroxycarboxylic acids are lactic acid and in particular citric acid and tartaric acid.
- the free acid content of the phosphating solution is preferably in the range from 0 to 100 points.
- the free acid score is determined by titrating 10 ml of the phosphating solution with 0.1 N sodium hydroxide solution up to a pH of 3.6. The consumption of sodium hydroxide solution in ml indicates the free acid score.
- the score of free acid is therefore 0.
- the score of free acid is therefore 0.
- the free acid score is then negative and is equated with the negative sign of consumption of hydrochloric acid in ml.
- the total acid content is determined by titrating 10 ml of the phosphating solution with 0.1N sodium hydroxide solution up to a pH of 8.5.
- the consumption of 0.1 n sodium hydroxide solution in ml gives the total acid score.
- the total acid is preferably in the range from 40 to 400 points.
- the ratio of free acid to total acid is preferably adjusted so that it is in the range from 1: 4 to 1:20.
- Phosphating solutions which have a temperature in the range from 15 to 80 ° C., in particular in the range from 20 to 40 ° C., are preferably used.
- the active substance content of the phosphating solutions should be in the range from about 5.5 to about 35% by weight.
- the active substance content is defined as the sum of the metal ions, phosphoric acid and optionally other components mentioned above.
- the process is particularly designed for phosphating running metal strips in strip treatment plants, such as those found in steel mills.
- a liquid film coating of 2 to 10 ml of phosphating solution per metal surface is preferably applied to the surfaces.
- the optimal value of the liquid film layer depends on the active substance content of the Phosphating solution and on the other hand from the plant-specific exposure time of the phosphating solution.
- layer weights of the phosphate layers in the range of about 0.3 to about 3 g / m 2 are obtained with liquid film coatings of about 6 ml / m 2, as used as the basis for a subsequent painting is desirable.
- the higher the concentration of the phosphating solution the lower the liquid film coating.
- the application of the phosphating solution to the surface and the setting of the desired liquid film overlay can be carried out by different methods. For example, it is possible to spray the phosphating solution onto the surface in such a way that the desired liquid film coating is obtained. A higher level of procedural safety is achieved, however, if the liquid film layer is specifically adjusted after the phosphating solution has been sprayed on, for example by blowing off with compressed air or preferably by squeezing rollers. Instead of spraying on, the phosphating solution can also be applied to the surface by application rollers, the desired liquid film coating being able to be set directly. Such application rollers are known for the surface treatment of metal strips, for example under the name "chem-coater" or "roll-coater".
- the method can be carried out in such a way that the surfaces are immersed in the phosphating solution.
- Metal strips can, for example, be passed through the phosphating solution, the desired liquid film layer being set on the surface after leaving the phosphating solution, which can be done, for example, by blowing with air or preferably with squeezing rollers.
- the optimal process parameters depend on the specific material properties of the surfaces to be treated.
- Example It has been found that, when treating surfaces of running belts made of hot-dip galvanized steel, optimum phosphating results are obtained when the phosphating solution has an active substance content in the range from 5.5 to 35% by weight.
- the preferred pH is in the range from 1.0 to 2.2 and the weight ratio of the sum of the divalent metal ions to phosphate is preferably set in the range from 1: 5 to 1: 6.
- the presence of free or complex-bound fluoride in the phosphating solution has a favorable effect on the layer formation.
- Fluoride concentrations in the range of 0.5 to 1.5 g / 1 are particularly effective.
- Free fluoride is preferably used in the form of hydrofluoric acid, complex fluorides are preferably used as fluoro acids of boron, silicon, titanium and / or zircon.
- alkali fluoride or acidic alkali fluorides such as HF2 to provide free fluoride is also possible.
- the bath stability can be improved by adding about 1 to 10% by weight of a chelating hydroxycarboxylic acid having 3 to 6 carbon atoms, for example by means of lactic acid and preferably citric acid and / or tartaric acid.
- accelerators that is to say substances which promote the formation of layers due to their oxidizing or reducing action, is not necessary in particular in the treatment of galvanized steel. However, they can be advantageous if the formation of certain crystal shapes is desired.
- Suitable accelerators are the compounds known in the relevant prior art, in particular nitrate, nitrite, chlorate, nitrobenzenesulfonic acid or hydrogen peroxide.
- Hydroxylamine can be used as a rather reducing accelerator. Hydrogen peroxide and hydroxylamine can be used as such, the other accelerators mentioned as free acids or in the form of salts soluble in the phosphating solution.
- the liquid film remaining on the surface after the application of the phosphating solution is not rinsed off but dried.
- the surfaces are preferably heated to a temperature between 50 and 120 ° C., in particular between 60 and 90 ° C.
- the treated steel strip can be passed through a drying oven set to the appropriate temperature.
- the drying can also be carried out by blowing the surfaces with hot gases, preferably with air and / or by the action of infrared radiation. Since the acidic phosphating solution can react chemically with the metal surface as long as it is still liquid, the effective exposure time is given by the time between the first contact of the surface with the phosphating solution and the complete drying of the liquid film on the surface, i.e. the End of drying. This time period is preferably in the range between approximately 3 and approximately 60 seconds.
- phosphate layers with a layer weight in the range from 0.3 to 3 g / m 2 are produced on the surfaces.
- Layer weights in this area are particularly desirable as the basis for subsequent painting, since this means that the two requirements of corrosion protection and paint adhesion are met to a particular extent at the same time.
- layers are obtained which do not provide any reflections in X-ray diffraction studies, that is to say can be described as X-ray amorphous, or layers in which more or less pronounced reflections of Hopeit can be observed.
- the metal sheets pre-phosphated by the process according to the invention can be used in particular in the manufacture of vehicles. It is the rule here that the vehicle bodies according to the assembly is phosphated again and then painted, for which cathodic electrocoating is currently customary. In these cases, the material pre-phosphated by the process according to the invention is transported to the further processor in the unpainted state. To improve the temporary corrosion protection during storage and transport, the phosphated material can also be oiled. This will make subsequent forming operations easier at the same time. Post-phosphating the assembled bodies after alkaline cleaning is possible without any problems.
- the phosphating according to the invention can also be immediately followed by a coil coating with an organic film or a lacquer.
- coil-coating is common for this process. In this way, coil-coated material is currently preferred for the construction of household appliances such as refrigerators and washing machines and for architectural applications.
- the invention relates to an aqueous acidic phosphating solution containing zinc and manganese for phosphating surfaces made of steel, zinc, aluminum or their alloys, characterized in that they
- the phosphating solution can contain one or more of the components specified above in the description of the method.
- the conditions mentioned above also apply to the contents of Zn, Mn and possibly other metal ions, free acid and total acid, which are preferably to be set, as well as the preferred ratio of free acid to total acid.
- steel sheets of the quality ST 1405, steel sheets electrolytically galvanized on both sides (ZE) with a zinc coating of 7.5 ⁇ m each and hot-dip galvanized steel sheets (Z) with a zinc coating of about 10 ⁇ m were used.
- the sheets each had the dimensions 10 cm x 20 cm.
- a commercially available mildly alkaline cleaner Rosinline R 1250 I, Henkel KGaA, Düsseldorf.
- the no-rinse treatment was simulated by pouring the treatment solution in a paint spinner (model 4302 from Lau GmbH) and at 550 rpm. was thrown out.
- the layer weight was determined as a parameter for the phosphate layer obtained. Two different methods were used for this: When determining the layer weight by weighing, the sheet was weighed before the coating was carried out, after which the phosphating solution was applied and dried and the coated sheet was weighed again. The layer coverage in g / m2 was calculated from the difference in weight. When determining the layer weight by detaching, the phosphated sheets were weighed, the phosphate layer was removed by detaching with 0.5% by weight chromic acid solution, and the sheets were weighed again. The mass of the removed layer g / m 2 was determined from the difference in weight.
- the layer weight determined by detachment is generally higher than that determined by weighing, since part of the metal surface is converted into metal phosphate by the phosphating becomes. This part is not included in the determination of the layer weight by weighing, but is also removed when the layer is detached.
- Table 1 contains phosphating baths for electrolytically galvanized steel and the layer coatings obtained, table 2 corresponding examples for the treatment of hot-dip galvanized steel.
- phosphating solutions are suitable, which lead to layer weights in the range of 1 to 3 g / m2.
- Zinc as oxide, manganese and nickel as carbonate and fluoride as sodium fluoride were used in the exemplary treatment baths.
- the baths contained no components other than water.
- the layer composition was determined by means of EDX (X-ray emission) (in% by weight): Zn 7.5, Mn 2.2, P 7.5, AI 0.3, rest: can be taken up as oxygen.
- EDX X-ray emission
- Example bath composition active pH free total layer no. Substance acid acid weight *) [g / 1] [% by weight] [points] [points] [g / m 2 ]
- bath-active pH free total layer For example, bath-active pH free total layer
- the sheet was phosphated for 5 seconds by immersion in an activating bath based on titanium phosphate (Fixodine R 950, Henkel KGaA, 0.3% batch) before phosphating. salted water) activated and dried for 2 minutes at 75 ° C.
- bath composition active pH free total layer For example, bath composition active pH free total layer
- Example bath composition active pH free total layer no.
- bath combination active pH layer For example, bath combination active pH layer
- bath combination active pH layer For example, bath combination active pH layer
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- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Chemical Treatment Of Metals (AREA)
- Saccharide Compounds (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE4433946A DE4433946A1 (de) | 1994-09-23 | 1994-09-23 | Phosphatierverfahren ohne Nachspülung |
| DE4433946 | 1994-09-23 | ||
| PCT/EP1995/003619 WO1996009422A1 (fr) | 1994-09-23 | 1995-09-14 | Procede de phosphatage sans rinçage final |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP0774016A1 true EP0774016A1 (fr) | 1997-05-21 |
| EP0774016B1 EP0774016B1 (fr) | 1999-07-28 |
Family
ID=6528963
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP95932747A Expired - Lifetime EP0774016B1 (fr) | 1994-09-23 | 1995-09-14 | Procede de phosphatage sans rin age final |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US5976272A (fr) |
| EP (1) | EP0774016B1 (fr) |
| JP (1) | JPH10505881A (fr) |
| KR (1) | KR100347405B1 (fr) |
| AT (1) | ATE182632T1 (fr) |
| CA (1) | CA2200893A1 (fr) |
| DE (2) | DE4433946A1 (fr) |
| ES (1) | ES2135090T3 (fr) |
| WO (1) | WO1996009422A1 (fr) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2001066826A1 (fr) * | 2000-03-07 | 2001-09-13 | Chemetall Gmbh | Procede de phosphatation utilisation des pieces en metal ainsi phosphatees |
| JP2007084868A (ja) * | 2005-09-21 | 2007-04-05 | Jfe Steel Kk | 冷延鋼板およびその製造方法 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19639597C2 (de) * | 1996-09-26 | 2000-01-20 | Henkel Kgaa | Verfahren zur Phosphatierung von laufenden Bändern aus kalt- oder warmgewalztem Stahl in schnellaufenden Bandanlagen |
| US6179934B1 (en) | 1997-01-24 | 2001-01-30 | Henkel Corporation | Aqueous phosphating composition and process for metal surfaces |
| JPH10204649A (ja) * | 1997-01-24 | 1998-08-04 | Nippon Parkerizing Co Ltd | 金属表面のりん酸塩処理水溶液及び処理方法 |
| US5968240A (en) * | 1997-08-19 | 1999-10-19 | Sermatech International Inc. | Phosphate bonding composition |
| DE19749508A1 (de) | 1997-11-08 | 1999-05-12 | Henkel Kgaa | Korrosionsschutz von verzinkten und legierungsverzinkten Stahlbändern |
| DE19844391C2 (de) | 1998-09-28 | 2003-01-09 | Chemetall Gmbh | Verfahren zur Vorbereitung von Werkstücken für die Kaltumformung |
| US6162508A (en) * | 1998-11-02 | 2000-12-19 | Nortel Networks Limited | Molybdenum phosphate based corrosion resistant conversion coatings |
| TW500827B (en) * | 1999-08-06 | 2002-09-01 | Sms Demag Ag | Process and installation for hot galvanizing of hot rolled steel strip |
| JP2001295063A (ja) * | 2000-04-10 | 2001-10-26 | Nippon Parkerizing Co Ltd | 非鉄金属材料およびめっき鋼板へのりん酸塩被膜の形成方法 |
| DE10110834B4 (de) * | 2001-03-06 | 2005-03-10 | Chemetall Gmbh | Verfahren zur Beschichtung von metallischen Oberflächen und Verwendung der derart beschichteten Substrate |
| DE10110833B4 (de) * | 2001-03-06 | 2005-03-24 | Chemetall Gmbh | Verfahren zum Aufbringen eines Phosphatüberzuges und Verwendung der derart phosphatierten Metallteile |
| US20020164425A1 (en) * | 2001-04-27 | 2002-11-07 | Rivard Douglas Charles | Method for treating iron based parts |
| CA2454029A1 (fr) * | 2002-12-24 | 2004-06-24 | Nippon Paint Co., Ltd. | Agent de revetement par conversion chimique et metal a surface traitee |
| DE102005023023B4 (de) * | 2005-05-19 | 2017-02-09 | Chemetall Gmbh | Verfahren zur Vorbereitung von metallischen Werkstücken zum Kaltumformen, mit dem Verfahren beschichtete Werkstücke und ihre Verwendung |
| US20080283152A1 (en) * | 2007-05-17 | 2008-11-20 | Jeffrey Allen Greene | Rinse conditioner bath for treating a substrate and associated method |
| BRPI0811201A2 (pt) * | 2007-06-07 | 2014-10-29 | Henkel Ag & Co Kgaa | Composição de matéria líquida útil para a formação de um revestimento de conversão de fosfato sobre um substrato metálico, processo para a produção de um revestimento de conversão de fosfato sobre um substrato metálico, e, artigo de fabricação. |
| KR101016915B1 (ko) * | 2007-11-28 | 2011-02-22 | 가부시키가이샤 고베 세이코쇼 | 표면 안정성이 우수한 알루미늄 합금재 및 그 제조 방법 |
| ES2731279T3 (es) * | 2013-03-06 | 2019-11-14 | Quaker Chem Corp | Recubrimiento de conversión a alta temperatura sobre sustratos de acero y de hierro |
| RU2692361C2 (ru) | 2014-06-27 | 2019-06-24 | Хенкель Аг Унд Ко. Кгаа | Твердый смазочный материал для оцинкованной стали |
| KR101769302B1 (ko) * | 2016-06-08 | 2017-08-18 | 현대자동차주식회사 | 망간 함량을 최적화시킨 인산염 피막 조성물 및 아연계 전기도금강판의 인산염 처리 방법 |
| US10465292B2 (en) | 2016-10-07 | 2019-11-05 | Goodrich Corporation | Anti-corrosion and/or passivation composition for metal-containing substrates and methods for making, enhancing, and applying the same |
| DE102017207591A1 (de) * | 2017-05-05 | 2018-11-08 | Federal-Mogul Nürnberg GmbH | Stahlkolben mit einer Phosphat-Schicht |
| WO2022232817A1 (fr) * | 2021-04-30 | 2022-11-03 | Ppg Industries Ohio, Inc. | Procédés de fabrication de couches de revêtement et substrats pourvus desdites couches de revêtement |
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| US3819425A (en) * | 1972-10-18 | 1974-06-25 | Diamond Shamrock Corp | Composite coating adherent under shear condition |
| JPS50139039A (fr) * | 1974-04-26 | 1975-11-06 | ||
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| IT1065925B (it) * | 1976-09-03 | 1985-03-04 | Pirelli | Apparato per riunire tra di loro dei filamenti sottili |
| JPS5339945A (en) * | 1976-09-25 | 1978-04-12 | Nippon Packaging Kk | Surface treatment of zinc or zinc alloy |
| DE2905535A1 (de) * | 1979-02-14 | 1980-09-04 | Metallgesellschaft Ag | Verfahren zur oberflaechenbehandlung von metallen |
| US4316751A (en) * | 1980-04-14 | 1982-02-23 | Hooker Chemicals & Plastics Corp. | Electrical resistance coating for steel |
| DE3023479A1 (de) * | 1980-06-24 | 1982-01-14 | Metallgesellschaft Ag, 6000 Frankfurt | Phosphatierverfahren |
| GB2148950B (en) * | 1983-10-26 | 1987-02-04 | Pyrene Chemical Services Ltd | Phosphating composition and processes |
| DE3636390A1 (de) * | 1986-10-25 | 1988-04-28 | Metallgesellschaft Ag | Verfahren zur erzeugung von phosphatueberzuegen auf metallen |
| DE3800834A1 (de) * | 1988-01-14 | 1989-07-27 | Henkel Kgaa | Verfahren und mittel zum gleichzeitigen gleitschleifen, reinigen und passivieren metallischer werkstuecke |
| EP0327153B1 (fr) * | 1988-02-03 | 1993-08-04 | Metallgesellschaft Ag | Procédé pour former des couches de phosphates sur des métaux |
| GB9207725D0 (en) * | 1992-04-08 | 1992-05-27 | Brent Chemicals Int | Phosphating solution for metal substrates |
| DE4241134A1 (de) * | 1992-12-07 | 1994-06-09 | Henkel Kgaa | Verfahren zur Phosphatierung von Metalloberflächen |
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1994
- 1994-09-23 DE DE4433946A patent/DE4433946A1/de not_active Withdrawn
-
1995
- 1995-09-14 CA CA002200893A patent/CA2200893A1/fr not_active Abandoned
- 1995-09-14 EP EP95932747A patent/EP0774016B1/fr not_active Expired - Lifetime
- 1995-09-14 KR KR1019970701888A patent/KR100347405B1/ko not_active IP Right Cessation
- 1995-09-14 WO PCT/EP1995/003619 patent/WO1996009422A1/fr active IP Right Grant
- 1995-09-14 ES ES95932747T patent/ES2135090T3/es not_active Expired - Lifetime
- 1995-09-14 JP JP8510571A patent/JPH10505881A/ja active Pending
- 1995-09-14 AT AT95932747T patent/ATE182632T1/de not_active IP Right Cessation
- 1995-09-14 US US08/809,606 patent/US5976272A/en not_active Expired - Fee Related
- 1995-09-14 DE DE59506484T patent/DE59506484D1/de not_active Expired - Fee Related
Non-Patent Citations (1)
| Title |
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| See references of WO9609422A1 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2001066826A1 (fr) * | 2000-03-07 | 2001-09-13 | Chemetall Gmbh | Procede de phosphatation utilisation des pieces en metal ainsi phosphatees |
| US7208053B2 (en) | 2000-03-07 | 2007-04-24 | Chemetall Gmbh | Method for applying a phosphate covering and use of metal parts thus phospated |
| JP2007084868A (ja) * | 2005-09-21 | 2007-04-05 | Jfe Steel Kk | 冷延鋼板およびその製造方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| US5976272A (en) | 1999-11-02 |
| WO1996009422A1 (fr) | 1996-03-28 |
| ATE182632T1 (de) | 1999-08-15 |
| KR100347405B1 (ko) | 2002-12-05 |
| DE59506484D1 (de) | 1999-09-02 |
| DE4433946A1 (de) | 1996-03-28 |
| KR970706420A (ko) | 1997-11-03 |
| EP0774016B1 (fr) | 1999-07-28 |
| JPH10505881A (ja) | 1998-06-09 |
| ES2135090T3 (es) | 1999-10-16 |
| CA2200893A1 (fr) | 1996-03-28 |
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