EP0771239B1 - Verfahren zum induktiven aufheizen eines feuerfesten formteils sowie ein entsprechendes formteil hierfür - Google Patents
Verfahren zum induktiven aufheizen eines feuerfesten formteils sowie ein entsprechendes formteil hierfür Download PDFInfo
- Publication number
- EP0771239B1 EP0771239B1 EP96914880A EP96914880A EP0771239B1 EP 0771239 B1 EP0771239 B1 EP 0771239B1 EP 96914880 A EP96914880 A EP 96914880A EP 96914880 A EP96914880 A EP 96914880A EP 0771239 B1 EP0771239 B1 EP 0771239B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- shaped member
- electrically insulating
- molten metal
- electrically conductive
- conductive layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Images
Classifications
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B6/00—Heating by electric, magnetic or electromagnetic fields
- H05B6/02—Induction heating
- H05B6/10—Induction heating apparatus, other than furnaces, for specific applications
- H05B6/14—Tools, e.g. nozzles, rollers, calenders
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D41/00—Casting melt-holding vessels, e.g. ladles, tundishes, cups or the like
- B22D41/50—Pouring-nozzles
- B22D41/60—Pouring-nozzles with heating or cooling means
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
- B22D11/06—Continuous casting of metals, i.e. casting in indefinite lengths into moulds with travelling walls, e.g. with rolls, plates, belts, caterpillars
- B22D11/0637—Accessories therefor
- B22D11/0665—Accessories therefor for treating the casting surfaces, e.g. calibrating, cleaning, dressing, preheating
- B22D11/0671—Accessories therefor for treating the casting surfaces, e.g. calibrating, cleaning, dressing, preheating for heating or drying
Definitions
- the invention relates to an inductively heatable refractory Molding.
- Such a molded part is in EP-A-0 503 237 described.
- This molding consists of shells, from which at least one can be heated inductively.
- the outer Shell has a slot. Measures for inductive Heating from outside in the longitudinal direction of the molding Areas of the inductor are not provided.
- FR-A-2 670 697 there is an inductively heatable duct with several slits in the longitudinal direction described.
- the inductor extends over the entire length of the duct to be heated.
- EP-A-0 593 383 there is a twin roll caster with boundary plates shown by special inductors are heated.
- From US-A-5 198 017 is an inductively heatable Pourer known for a melt vessel.
- the pouring spout carries several longitudinal tubes.
- From US-PS 3 435 992 is a pouring sleeve for the continuous pouring of liquid metal, in particular Steel, known which, before contacting the liquid metal is heated inductively.
- the in the U.S. Pat. No. 3,435,992 has a pouring sleeve electrically conductive insert in the one essentially non-electrically conductive refractory material molded pouring sleeve.
- the electrically conductive Insert which preferably consists of a graphite part, by a current of suitable frequency in the range of 3 to 50 kHz can be heated.
- the electrically conductive use induction energy on and heats up the heat generated by heat conduction to the actual, from the non-electrically conductive Refractory material formed pouring sleeve is transferred.
- FR 2 609 914 A1 shows a pouring sleeve, the The outer part can be heated inductively. Are in the outer part several pipes forming the pouring opening are used. Here, too, is generated by the induction energy Heat through heat conduction on the actual pouring opening forming pipes.
- a disadvantage of the prior art shown here is that the induction heat is not direct, but only by heat conduction on the entire refractory part is transmitted. This is especially the case Case when the molded part is not completely removed from the inductor device is enclosed, but from this more or less "protrudes”. Often this is not too avoid, because of space or construction reasons none other solution is possible. In such a case it will fireproof molding heated very unevenly, which too Stress cracks, etc.
- the molding according to the invention is quick and uniform inductively heatable, also in the area of electromagnetic Subfields.
- the inductor device can thus in an uncritical and constructively favorable area of the molded part can be placed and still the complete Molding be heated evenly inductively.
- the molded part a ceramic immersion pouring tube for the introduction of Metal melt, in a melt sump, especially in a mold for the production of thin slabs or strips.
- the immersion nozzle extends into the mold and dives, if the mold after casting with molten metal is filled with its lower area in the mold powder covered metal swamp.
- the dip tube also in the area surrounded by the mold, the existing ones in particular with thin slabs and immersion pipes Risk of bridging between the immersion pouring tube and the mold wall avoided.
- the mold powder can be melted in a targeted manner be, which means the reproducibility of this process or the quality of the product produced is improved. Likewise, the danger of Cloggings reduced.
- the molded part is a ceramic feed channel for the application of molten metal on a Conveyor belt.
- a molded part according to the invention which in particular for the introduction or Giving up molten metal essentially has the following features:
- the molded part consisting of an electrically conductive layer is in Longitudinal direction with a continuous, uninterrupted, electrical insulated longitudinal slot.
- This electrically insulating longitudinal slot is advantageously with an electrically insulating, refractory ceramic Material filled out.
- the interior area enclosed by the molded part, through which the molten metal is introduced or abandoned is with one of the Molten metal facing, electrically insulating, refractory ceramic Provide inner layer.
- the remaining areas of the molded part, which are in use either immerse in the melt sump or when giving up the Metal melt on a cooled conveyor belt with the metal melt in Contact are made with an electrically insulating, refractory ceramic Layer.
- a molded part according to the invention has another in an intermediate region electrically insulating longitudinal slot.
- This longitudinal slot connects at least two in this intermediate area almost all over Circumference of the molded part, deflecting the electromagnetic field, electrically insulating cross slots.
- the molded part is in Longitudinal direction divided by an electrically insulated partition.
- This Partition can be in the continuous, electrically insulating longitudinal slot and the electrically insulating longitudinal slot or slots in the intermediate area be anchored.
- This partition can also be used as a flow divider, for example be formed in a dip tube or serve the mechanical To increase the stability of the immersion nozzle or a feed channel.
- the molded part is a lateral boundary plate, as one particularly for a device for continuous pouring of molten metal between casting rolls, one so-called twin-roll caster required.
- the molded part according to the invention permits the inductor device not having to assemble directly at the place of action and still have an early one Solidification of molten metal in the gussets towards the casting rolls avoid.
- Such a molded part is a geometrically open structure with in Longitudinal side boundaries.
- the molded part consists of an electrically conductive layer or has one such on. It is on the side facing the molten metal with a provided electrically insulating layer and points in the intermediate area at least one further electrically insulating longitudinal slot, which in Distance at least two, in this intermediate area almost over the entire Width of the molded part, interrupting the electromagnetic field Cross slots connects.
- Such a configuration of the molded part allows Heating also in the area of the electromagnetic secondary field.
- the slots in the Intermediate area intersecting longitudinal slots, creating a targeted Redirection of eddy currents into the secondary electromagnetic field or secondary electromagnetic fields is effected.
- the electrically conductive materials have a specific electrical resistance ⁇ 1000 ohm mm 2 / m, preferably 200 ohm mm 2 / m. Experiments have shown that such materials have good coupling behavior. Particularly good results have been achieved with a carbon-bound, graphite-containing aluminum oxide material. For the electrically insulating slots and the electrically insulating inner and / or outer layer, electrically non-conductive, refractory materials, such as zirconium oxide, come into consideration.
- Figure 1 shows a molded part (1), for example a refractory ceramic Immersion pouring tube for introducing molten metal into a mold or refractory ceramic feed channel for the application of molten metal a conveyor belt.
- the molded part (1) is one Surround inductor device (2), the main electromagnetic field (A) generated.
- the main electromagnetic field (A) generated.
- an electromagnetic secondary field (B) in the Area (4 and 5) is essentially an electrically conductive layer (6) assembled molded part (1) in the longitudinal direction with a continuous, electrically isolating longitudinal slot (7) and the other Slits (10, 11) in the intermediate area (4).
- the in the intermediate area (4) almost around the entire circumference of the molded part (1) running, electrically insulating transverse slots (11) are through a also electrically insulating longitudinal slot (10) connected to each other.
- the inductor device (2) generates an electromagnetic secondary field (B) in the areas (4, 5), whereby it for inductive heating of the molded part (1) also in the areas (4, 5) is coming.
- the molded part (1) which essentially consists of the electrical conductive layer (6), compared to that with molten metal Provide exposed surfaces with electrically insulating layers (8, 9).
- These electrically insulating layers also include the end faces of the Molded part (1) insofar as they can be subjected to molten metal.
- the electrically insulating inner layer (8) extends over all inner surfaces of the molded part (1).
- the electrically insulating Outer layer (9) extends at least over the surface of the schematically illustrated melt sump.
- the slots (7, 10, 11) are usually with an electrically insulating, ceramic material backfilled.
- FIG. 2 shows a mold (1) used as a dip tube (16) shown.
- a distributor vessel (18) is used as a dip tube (16) formed molded part (1) metal melt introduced into a mold (12).
- the molded part (1) is over a schematically shown inductor device (2) heated inductively.
- the molded part (1) is also sensitive to thermal shock when cast on Danger of bridging, as is the case especially with thin slab casting exists, through the possibility of inductive heating of the molded part (1) in Area of the bath level reduced during the pouring process.
- Figure 3 shows an arrangement analogous to Figure 2, wherein the molten metal is not in a mold, but is placed on a conveyor (13).
- the molded part (1) designed as a feed channel (17) does not submerge or only to a very small extent in the molten metal. Accordingly, an electrically insulating outer layer (9) can be made narrower.
- FIG. 4 schematically shows a twin roll caster with a boundary plate (15) shown for lateral limitation.
- the limiting plate (15) also heat inductively in the lower area. With this measure it can unwanted freezing of molten metal in the gussets, which from the Casting rolls and the or the boundary plates are formed, and what to destruction of the casting rolls or poor strip quality, be avoided.
- Figure 5 shows a boundary plate (15) according to the invention, which in essentially of an electrically conductive slotted layer (6) and a electrically insulating inner layer (8).
- the whole plate is preferably covered with an electrically insulating layer (9).
- FIG 6 is a development of the molded part shown in Figure 1 (1) reproduced. This development includes the electrically conductive layer (6) interrupted by the electrically insulating longitudinal and transverse slots (10 and 11).
- the inductor device (2) is used for inductive coupling in area (3) and due to the special design in the intermediate area (4) a course of the eddy currents outlined in area (5).
Landscapes
- Mechanical Engineering (AREA)
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Electromagnetism (AREA)
- General Induction Heating (AREA)
- Continuous Casting (AREA)
- Moulds For Moulding Plastics Or The Like (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
- Heating, Cooling, Or Curing Plastics Or The Like In General (AREA)
- Resistance Heating (AREA)
- Mounting, Exchange, And Manufacturing Of Dies (AREA)
- Ceramic Products (AREA)
- Prostheses (AREA)
- Heat Treatment Of Articles (AREA)
Description
- Figur 1
- ein feuerfestes Formteil mit rechteckigem Querschnitt einschließlich einer Induktorvorrichtung,
- Figur 2
- schematisch ein Tauchgießrohr, welches Metallschmelze aus einem Verteilergefäß in eine Kokille einleitet,
- Figur 3
- schematisch einen Zufuhrkanal, durch welchen aus einem Verteilergefäß Metallschmelze auf eine Fördervorrichtung aufgegeben wird
- Figur 4
- eine seitliche Begrenzungsplatte an einem Twin-roll-caster,
- Figur 5
- eine Ansicht X gemäß Figur 4,
- Figur 6
- die Abwicklung der elektrisch leitfähigen Schicht gemäß Figur 1.
Claims (12)
- Feuerfestes elektrisch leitendes oder eine elektrisch leitfähige Schicht(6) aufweisendes, induktiv beheizbares Formteil mit wenigstens einem elektrisch isolierenden Längsschlitz(7), das in einem Bereich(3) von einem elektromagnetischen Hauptfeld(A) eines Induktors(2) beaufschlagt ist,
dadurch gekennzeichnet,
daß das Formteil(1) oder seine elektrisch leitfähige Schicht(6) in einem an den genannten Bereich(3) in Längsrichtung anschließenden Zwischenbereich(4) elektrisch isolierende Querschlitze(11) aufweist, die nahezu um den gesamten Umfang oder über nahezu die gesamte Breite des Formteils(1) verlaufen, derart, daß die im Bereich (3) des Formteils indurierten Wirbelströme um diesen Zwischenbereich (4) herum in einen hierauf folgenden Bereich (5) des Formteils gelenkt werden. - Formteil nach Anspruch 1,
dadurch gekennzeichnet,
daß das Formteil(1) ein keramisches Tauchgießrohr(16) für das Einleiten von Metallschmelze in einen Schmelzensumpf, insbesondere in einer Kokille(12), ist. - Formteil nach Anspruch 1,
dadurch gekennzeichnet,
daß das Formteil(1) ein keramischer Zufuhrkanal(17) für die Aufgabe von Metallschmelze auf eine Fördervorrichtung (13), insbesondere ein Transportband, ist. - Formteil nach einem der Ansprüche 1 bis 3,
dadurch gekennzeichnet,
daß das Formteil(1) eine elektrisch leitfähige Schicht(6) mit einem in Längsrichtung durchgehenden, elektrisch isolierenden Längsschlitz(7) sowie eine der Metallschmelze zugewandte elektrisch isolierende Innenschicht(8) aufweist, daß das Formteil(1) an einem auch außen mit Metallschmelze in Berührung stehenden Bereich(5) eine elektrisch isolierende Außenschicht(9) aufweist, so daß die elektrisch leitfähige Schicht(6) nicht in Kontakt mit Metallschmelze kommt, und daß das Formteil(1) in dem Zwischenbereich(4) mindestens einen weiteren, elektrisch isolierenden Längsschlitz(10) aufweist, welcher mindestens zwei in diesem Zwischenbereich(4) nahezu um den gesamten Umfang des Formteils(1) verlaufende, elektrisch isolierende Querschlitze(11) verbindet. - Formteil nach Anspruch 4,
dadurch gekennzeichnet,
daß es durch eine elektrisch isolierte Trennwand(14) in Längsrichtung geteilt ist. - Formteil nach Anspruch 1,
dadurch gekennzeichnet,
daß das Formteil(1) eine Begrenzungsplatte(15) für eine Vorrichtung zum kontinuierlichen Vergießen von Metallschmelze ist. - Formteil nach Anspruch 6,
dadurch gekennzeichnet,
daß das Formteil(1) eine elektrisch leitfähige Schicht(6) sowie eine der Metallschmelze zugewandte, elektrisch isolierende Innenschicht(8) aufweist, daß das Formteil(1) in einem Zwischenbereich(4) mindestens einen weiteren, elektrisch isolierenden Längsschlitz(10) aufweist, welcher mindestens zwei in diesem Zwischenbereich(4) nahezu über die gesamte Breite des Formteils(1) verlaufende, elektrisch isolierende Querschlitze(11) verbindet. - Formteil nach einem der Ansprüche 4, 5 oder 7,
dadurch gekennzeichnet,
daß die Schlitze(10,11) in dem Zwischenbereich(4) sich kreuzende Schlitze sind. - Formteil nach einem der Ansprüche 4, 5, 7 oder 8,
dadurch gekennzeichnet,
daß weitere Schlitze zur Umlenkung der elektrischen Wirbelströme vorhanden sind. - Formteil nach einem der Ansprüche 4, 5 oder 7 bis 9,
dadurch gekennzeichnet,
daß die Abwicklung der elektrisch leitfähigen Schicht(6) eine in sich geschlossene Fläche bildet, derart, daß sich dort elektrische Wirbelströme ausbilden können. - Formteil nach einem der Ansprüche 4, 5 oder 7 bis 10,
dadurch gekennzeichnet,
daß die elektrisch leitfähige Schicht(6) einen spezifischen elektrischen Widerstand <1000 Ohm mm2/m, vorzugsweise <200 Ohm mm2/m aufweist. - Formteil nach einem der Ansprüche 4, 5 oder 7 bis 11,
dadurch gekennzeichnet,
daß die elektrisch leitfähige Schicht(6) aus kohlenstoffhaltigen, feuerfesten Werkstoffen, insbesondere kohlenstoffgebundenem, graphithaltigem Al2O3 besteht, und daß die elektrisch isolierende Innen- und/oder Außenschicht (8,9) aus elektrisch nichtleitfähigen, feuerfesten Werkstoffen, insbesondere ZrO2, besteht.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19515230 | 1995-04-28 | ||
DE19515230A DE19515230C2 (de) | 1995-04-28 | 1995-04-28 | Verfahren zum induktiven Aufheizen eines feuerfesten Formteils sowie ein entsprechendes Formteil |
PCT/EP1996/001477 WO1996033829A1 (de) | 1995-04-28 | 1996-04-04 | Verfahren zum induktiven aufheizen eines feuerfesten formteils sowie ein entsprechendes formteil hierfür |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0771239A1 EP0771239A1 (de) | 1997-05-07 |
EP0771239B1 true EP0771239B1 (de) | 1999-07-28 |
Family
ID=7760345
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP96914880A Expired - Lifetime EP0771239B1 (de) | 1995-04-28 | 1996-04-04 | Verfahren zum induktiven aufheizen eines feuerfesten formteils sowie ein entsprechendes formteil hierfür |
Country Status (17)
Country | Link |
---|---|
US (2) | US5901776A (de) |
EP (1) | EP0771239B1 (de) |
JP (1) | JPH10502579A (de) |
KR (1) | KR970703210A (de) |
CN (1) | CN1152268A (de) |
AT (1) | ATE182496T1 (de) |
AU (1) | AU712223B2 (de) |
BR (1) | BR9605800A (de) |
CA (1) | CA2187450A1 (de) |
CZ (1) | CZ289837B6 (de) |
DE (2) | DE19515230C2 (de) |
ES (1) | ES2136992T3 (de) |
FI (1) | FI965232A (de) |
IN (1) | IN188124B (de) |
MX (1) | MX9700260A (de) |
WO (1) | WO1996033829A1 (de) |
ZA (1) | ZA963064B (de) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19644345A1 (de) * | 1996-10-25 | 1998-04-30 | Didier Werke Ag | Verfahren, Vorrichtung und Verschlußglied zum Angießen von flüssigen Schmelzen |
SE512691C2 (sv) | 1998-03-02 | 2000-05-02 | Abb Ab | Anordning för gjutning av metall |
DE19843087A1 (de) * | 1998-09-21 | 2000-03-23 | Didier Werke Ag | Induktor zur Erzeugung eines elektromagnetischen Wechselfeldes |
DE20014593U1 (de) | 2000-08-23 | 2000-12-14 | Didier-Werke Ag, 65189 Wiesbaden | Ausgusseinrichtung eines Schmelzegefäßes |
US8050939B2 (en) * | 2005-02-11 | 2011-11-01 | Avaya Inc. | Methods and systems for use in the provision of services in an institutional setting such as a healthcare facility |
JP4746412B2 (ja) * | 2005-11-21 | 2011-08-10 | 新日本製鐵株式会社 | 連続鋳造方法 |
US9873151B2 (en) * | 2014-09-26 | 2018-01-23 | Crucible Intellectual Property, Llc | Horizontal skull melt shot sleeve |
CN109932383B (zh) * | 2018-11-22 | 2024-06-04 | 康姆罗拉有限公司 | 一种耐火陶瓷过滤器装置 |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3435992A (en) * | 1966-03-11 | 1969-04-01 | Tisdale Co Inc | Pouring nozzle for continuous casting liquid metal or ordinary steel |
FR2609914B1 (fr) * | 1987-01-26 | 1990-04-13 | Aubert & Duval Acieries | Busette composite de coulee de metal liquide, notamment pour appareil d'atomisation du metal |
US4784209A (en) * | 1987-08-06 | 1988-11-15 | Bethlehem Steel Corporation | Continuous casting apparatus |
JPH01205858A (ja) * | 1988-02-10 | 1989-08-18 | Daido Steel Co Ltd | 連続鋳造用侵漬ノズル |
JPH01217883A (ja) * | 1988-02-25 | 1989-08-31 | Jiyuuou:Kk | 誘導加熱コイル用ボビン |
DE3923550C2 (de) * | 1989-07-15 | 1997-10-23 | Ald Vacuum Techn Gmbh | Verfahren und Dauerform zum Formgießen von elektrisch leitenden Werkstoffen |
FR2670697B1 (fr) * | 1990-12-24 | 1993-03-12 | Pont A Mousson | Chenal pour la mise en óoeuvre d'un procede de coulee sous pression d'un alliage metallique. |
DE4108153A1 (de) * | 1991-03-14 | 1992-09-17 | Didier Werke Ag | Feuerfestes formteil und dessen verwendung |
DE4125916A1 (de) * | 1991-08-05 | 1993-02-11 | Didier Werke Ag | Verfahren zum induktiven aufheizen von keramischen formteilen |
US5160532A (en) * | 1991-10-21 | 1992-11-03 | General Electric Company | Direct processing of electroslag refined metal |
US5198017A (en) * | 1992-02-11 | 1993-03-30 | General Electric Company | Apparatus and process for controlling the flow of a metal stream |
FR2696960B1 (fr) * | 1992-10-16 | 1994-11-25 | Usinor Sacilor | Dispositif de coulée continue entre cylindres de produits métalliques minces. |
-
1995
- 1995-04-28 DE DE19515230A patent/DE19515230C2/de not_active Expired - Fee Related
-
1996
- 1996-04-03 IN IN612CA1996 patent/IN188124B/en unknown
- 1996-04-04 WO PCT/EP1996/001477 patent/WO1996033829A1/de active IP Right Grant
- 1996-04-04 CA CA002187450A patent/CA2187450A1/en not_active Abandoned
- 1996-04-04 US US08/722,171 patent/US5901776A/en not_active Expired - Fee Related
- 1996-04-04 DE DE59602533T patent/DE59602533D1/de not_active Expired - Fee Related
- 1996-04-04 KR KR1019960706760A patent/KR970703210A/ko not_active Application Discontinuation
- 1996-04-04 CZ CZ19963757A patent/CZ289837B6/cs not_active IP Right Cessation
- 1996-04-04 ES ES96914880T patent/ES2136992T3/es not_active Expired - Lifetime
- 1996-04-04 JP JP8532123A patent/JPH10502579A/ja active Pending
- 1996-04-04 BR BR9605800A patent/BR9605800A/pt not_active Application Discontinuation
- 1996-04-04 MX MX9700260A patent/MX9700260A/es unknown
- 1996-04-04 AU AU70703/96A patent/AU712223B2/en not_active Ceased
- 1996-04-04 CN CN96190382A patent/CN1152268A/zh active Pending
- 1996-04-04 EP EP96914880A patent/EP0771239B1/de not_active Expired - Lifetime
- 1996-04-04 AT AT96914880T patent/ATE182496T1/de active
- 1996-04-17 ZA ZA963064A patent/ZA963064B/xx unknown
- 1996-12-27 FI FI965232A patent/FI965232A/fi unknown
-
1999
- 1999-02-24 US US09/256,105 patent/US6148903A/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
CZ289837B6 (cs) | 2002-04-17 |
JPH10502579A (ja) | 1998-03-10 |
US6148903A (en) | 2000-11-21 |
AU7070396A (en) | 1996-11-18 |
WO1996033829A1 (de) | 1996-10-31 |
MX9700260A (es) | 1997-05-31 |
DE19515230C2 (de) | 1997-06-19 |
US5901776A (en) | 1999-05-11 |
CA2187450A1 (en) | 1996-10-29 |
EP0771239A1 (de) | 1997-05-07 |
AU712223B2 (en) | 1999-11-04 |
KR970703210A (ko) | 1997-07-03 |
ZA963064B (en) | 1996-10-24 |
FI965232A0 (fi) | 1996-12-27 |
CZ375796A3 (en) | 1997-05-14 |
CN1152268A (zh) | 1997-06-18 |
IN188124B (de) | 2002-08-24 |
DE19515230A1 (de) | 1996-11-07 |
FI965232A (fi) | 1996-12-27 |
ATE182496T1 (de) | 1999-08-15 |
DE59602533D1 (de) | 1999-09-02 |
BR9605800A (pt) | 1997-08-05 |
ES2136992T3 (es) | 1999-12-01 |
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