EP0671432A1 - Feuille perforable par pression pour couvertures de supports d'articles ayant securité de manipulation - Google Patents

Feuille perforable par pression pour couvertures de supports d'articles ayant securité de manipulation Download PDF

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Publication number
EP0671432A1
EP0671432A1 EP19950107067 EP95107067A EP0671432A1 EP 0671432 A1 EP0671432 A1 EP 0671432A1 EP 19950107067 EP19950107067 EP 19950107067 EP 95107067 A EP95107067 A EP 95107067A EP 0671432 A1 EP0671432 A1 EP 0671432A1
Authority
EP
European Patent Office
Prior art keywords
push
film according
film
approximately
filler
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP19950107067
Other languages
German (de)
English (en)
Inventor
Jürgen Schnäbele
Norwin Schmidt
Henning Lüdemann
Anton Wolfsberger
Jürgen Emig
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
PCD Polymere GmbH
BP Chemicals Plastec GmbH
Original Assignee
PCD Polymere GmbH
BP Chemicals Plastec GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by PCD Polymere GmbH, BP Chemicals Plastec GmbH filed Critical PCD Polymere GmbH
Priority to EP19990114241 priority Critical patent/EP0962485A1/fr
Publication of EP0671432A1 publication Critical patent/EP0671432A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D75/00Packages comprising articles or materials partially or wholly enclosed in strips, sheets, blanks, tubes, or webs of flexible sheet material, e.g. in folded wrappers
    • B65D75/28Articles or materials wholly enclosed in composite wrappers, i.e. wrappers formed by associating or interconnecting two or more sheets or blanks
    • B65D75/30Articles or materials enclosed between two opposed sheets or blanks having their margins united, e.g. by pressure-sensitive adhesive, crimping, heat-sealing, or welding
    • B65D75/32Articles or materials enclosed between two opposed sheets or blanks having their margins united, e.g. by pressure-sensitive adhesive, crimping, heat-sealing, or welding one or both sheets or blanks being recessed to accommodate contents
    • B65D75/325Articles or materials enclosed between two opposed sheets or blanks having their margins united, e.g. by pressure-sensitive adhesive, crimping, heat-sealing, or welding one or both sheets or blanks being recessed to accommodate contents one sheet being recessed, and the other being a flat not- rigid sheet, e.g. puncturable or peelable foil
    • B65D75/326Articles or materials enclosed between two opposed sheets or blanks having their margins united, e.g. by pressure-sensitive adhesive, crimping, heat-sealing, or welding one or both sheets or blanks being recessed to accommodate contents one sheet being recessed, and the other being a flat not- rigid sheet, e.g. puncturable or peelable foil and forming one compartment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D65/00Wrappers or flexible covers; Packaging materials of special type or form
    • B65D65/38Packaging materials of special type or form
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D75/00Packages comprising articles or materials partially or wholly enclosed in strips, sheets, blanks, tubes, or webs of flexible sheet material, e.g. in folded wrappers
    • B65D75/28Articles or materials wholly enclosed in composite wrappers, i.e. wrappers formed by associating or interconnecting two or more sheets or blanks
    • B65D75/30Articles or materials enclosed between two opposed sheets or blanks having their margins united, e.g. by pressure-sensitive adhesive, crimping, heat-sealing, or welding
    • B65D75/32Articles or materials enclosed between two opposed sheets or blanks having their margins united, e.g. by pressure-sensitive adhesive, crimping, heat-sealing, or welding one or both sheets or blanks being recessed to accommodate contents
    • B65D75/325Articles or materials enclosed between two opposed sheets or blanks having their margins united, e.g. by pressure-sensitive adhesive, crimping, heat-sealing, or welding one or both sheets or blanks being recessed to accommodate contents one sheet being recessed, and the other being a flat not- rigid sheet, e.g. puncturable or peelable foil
    • B65D75/327Articles or materials enclosed between two opposed sheets or blanks having their margins united, e.g. by pressure-sensitive adhesive, crimping, heat-sealing, or welding one or both sheets or blanks being recessed to accommodate contents one sheet being recessed, and the other being a flat not- rigid sheet, e.g. puncturable or peelable foil and forming several compartments
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/13Hollow or container type article [e.g., tube, vase, etc.]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/25Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/25Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
    • Y10T428/252Glass or ceramic [i.e., fired or glazed clay, cement, etc.] [porcelain, quartz, etc.]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/25Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
    • Y10T428/254Polymeric or resinous material
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31786Of polyester [e.g., alkyd, etc.]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31855Of addition polymer from unsaturated monomers
    • Y10T428/31909Next to second addition polymer from unsaturated monomers

Definitions

  • the invention relates to a push-through film for tamper-proof covering of product carriers, as is known, for example, from a large number of so-called blister packs.
  • Such known films for blister covers have hitherto consisted of aluminum foils, plastic-coated aluminum foils up to pure transparent or opaque plastic foils. These foils form the counterpart to the goods carrier or the so-called lower part of the packaging, which in turn can be formed from a variety of materials, for example from a stable layer of cardboard, a plastic or aluminum shell adapted to the shape of the goods or the like.
  • foils as cover for such packaging, either aluminum foils were used, as is the case in particular with the packaging of pharmaceutical products, such as tablets, ampoules or capsules, or a removal option was provided in the lower part of the packaging .
  • the object of the present invention is to provide a film for tamper-proof covers of product carriers, which can be produced from plastic and yet shows the known push-through properties of aluminum foil covers.
  • the film is an unstretched film with a plastic matrix which comprises the latter polyolefins, polyester, polystyrene or styrene copolymers and contains a particulate filler in an amount of 20 to 60% by weight, where the filler has an average particle size (measured over the largest dimension of the particle) of approx. 5 ⁇ m to approx. 100 ⁇ m and is selected so that the puncture resistance of the film is below a limit of approx. 200 N / mm (measured at a 150 ⁇ m thick film, measuring method according to DIN 53 373) is reduced.
  • This limit applies to approximately 150 ⁇ m thick foils. For significantly thinner or thicker foils, the corresponding limit values can be derived from these values. With the specified limit, it is possible to push pressure-insensitive goods through the cover film of the goods carrier, even if with some effort. In the case of more sensitive products, a lower limit value for the puncture resistance is preferably chosen, and this value is then preferably around 100 to around 200 N / mm. Lower puncture resistance may be advisable in individual cases where very pressure-sensitive goods are packed. However, it should be noted that, of course, with the reduction in puncture resistance, the protective effect of the packaging against damage to the goods themselves also decreases, so that in many cases an optimum can be seen in the previously specified numerical range from approximately 100 to approximately 200 N / mm is.
  • the so-called tear resistance determines the amount of force required to tear open a film once it has been pierced and thus release the product.
  • This property can also be influenced by the choice of the filler and its proportion in the plastic matrix, a tear strength of less than 30 N (measurement method according to DIN 53363) preferably being sought here.
  • This numerical value applies in particular to approximately 150 ⁇ m thick films, but can essentially also be applied to much thinner or thicker films.
  • a value for the tear propagation resistance which is acceptable for the handling, in particular also of pressure-sensitive goods, is between approx. 2 to 12 N, whereby again it should be noted that of course much lower values are possible, but with regard to the protection of the goods by the Any reduction limits are set.
  • a preferred range for tear resistance is in the range of 3 to 4 N.
  • the film according to the invention contains the filler as a homogeneous admixture to an already fully polymerized plastic material.
  • the filler is therefore not - as is known in connection with filler-reinforced plastics - dispersed in the polymerization reaction mixture of monomer and / or prepolymer and incorporated into the plastic matrix during the curing of the reaction mixture.
  • filler-reinforced plastics dispersed in the polymerization reaction mixture of monomer and / or prepolymer and incorporated into the plastic matrix during the curing of the reaction mixture.
  • fillers are available for the film fillers. These can be selected from inorganic and / or organic substances.
  • the organic substances are e.g. halogenated hydrocarbon polymers, in particular PTFE, polyether sulfones, which like the PTFE have a fixed point of> 300 ° C, and thermosetting plastics.
  • PTFE halogenated hydrocarbon polymers
  • polyether sulfones which like the PTFE have a fixed point of> 300 ° C
  • thermosetting plastics thermosetting plastics.
  • the substance can be selected from the series of silicas, in particular in the form of glass or quartz, silicates, in particular in the form of talc, titanates, TiO2, aluminum oxide, kaolin, calcium carbonates, in particular in the form of chalk, magnesite , MgO, iron oxides, silicon carbides, silicon nitrides, barium sulfate or the like.
  • the goods to be packaged and their sensitivity to one or the other additive to the polymer matrix will always have to be taken into account.
  • the shape of the filler particles will most likely be granular, but platelet-shaped, fibrous or rod-shaped filler particles are also possible as filler particles both as an essentially uniform shape or in a mixture with other shapes.
  • the choice of particle size is of course not insignificantly determined by the film layer thickness to be produced. It will therefore be important to ensure that the average expansion of the particles is at a clear distance from the film thickness to be produced. Average particle sizes between 20 ⁇ m and 60 ⁇ m are preferred, in particular with film thicknesses from 80 ⁇ m to 100 ⁇ m.
  • Adhesion promoters of this type are usually used in the production of filled plastics, but in which the particular strength of the material is used.
  • the aim is, of course, to ensure that the filler particles are distributed as evenly as possible in the plastic matrix and also maintained during the production process, so that auxiliary agents are preferably added; which improve the dispersibility of the filler particles in the matrix.
  • Low-melting organic substances which have great wetting ability for the filler are particularly suitable as dispersing agents.
  • Specific examples are low molecular weight polyolefin waxes.
  • the dispersing aids are preferably applied to the filler particles before they are mixed, in particular kneaded, with the granules of the matrix plastic.
  • the thickness of the film is preferably selected from 20 ⁇ m to approximately 600 ⁇ m, which on the one hand ensures sufficient stability of the film to protect the packaged goods and on the other hand keeps the forces necessary for opening the packaging within the predetermined limit, at least within it Pressure-sensitive goods can still be easily removed from the packaging by pushing through the cover film by the average buyer.
  • the film In particular in the packaging of pharmaceuticals, it is often desirable for the film to be essentially impermeable to water and steam.
  • Preferred polyolefins are seen in polypropylenes.
  • the reason for this is the particularly good physical properties of polypropylene, such as a barrier effect for water vapor, transparency, etc.
  • the average molecular weight of the polymers in the plastic matrix is preferably selected in the range from approximately 10,000 to approximately 300,000.
  • the normal seal strength may be sufficient to solve the above problem.
  • the sealing strength is too low in direct contact of the film with the lower part, the need for an additional sealing layer on the film surface may arise.
  • the film is constructed in two or more layers, the two or more layers of the film preferably being produced in a coextruded manner.
  • an outer film layer is designed as a sealing layer. This can, on the one hand, serve to improve the adhesion of the cover film to the goods carrier and, on the other hand, can have a special property for certain applications, such as e.g. a special water vapor impermeability, etc.
  • the film according to the invention is particularly suitable for producing a packaging with a lower part, which may be adapted in shape to the goods to be packaged, as a goods carrier and an upper part from the film according to the invention and already described above.
  • the lower part and the upper part are preferably produced using the same type of plastic, so that a pure product is obtained.
  • Such sorted products are particularly easy to recycle and reusable for the same purpose, which is an optimum in the packaging cycle.
  • a particularly preferred use of the films according to the invention is in the packaging of pharmaceuticals, which are in particular in ampoule, capsule or tablet form.
  • a polymer granulate is mixed with the filler components and then extruded or calendered.
  • the mixing in particular the homogenization, can be carried out by kneading using known processes, in particular twin-screw compounding.
  • twin-screw compounding can also be mixed with one another in a dry mixing process.
  • the filler particles should always be treated with dispersing aids before they are mixed with the matrix plastic.
  • the compound is melted in the extruder, at melt temperatures of approx. 220 ° C and more and at a melt pressure of up to 250 bar.
  • the melt is preferably cooled using a chill roll at 20 ° C. to approx. 40 ° C., but other cooling processes, possibly composed with a surface treatment with corona discharge, are also possible.
  • the foils are then cut and wrapped.
  • polypropylene such as Block copolymers or random copolymers
  • Block copolymers such as Block copolymers or random copolymers
  • the proportion of the fillers in the total film weight is preferably from 25 to 55% by weight. Below a filler content of 20% by weight, there is regularly no longer sufficient embrittlement of the plastic with the associated reduction in puncture resistance and tear resistance. With proportions well over 60% by weight, film production is difficult and the physical strength values are then often no longer sufficient for the typical uses.
  • the polypropylene-based foil according to the invention is also rewound for reasons of recrystallization. (The duration of post-crystallization is typically 4 to 10 days.)
  • a puncture resistance of 162 N / mm and a tear strength of 3.2 N were measured on this film.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Composite Materials (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Wrappers (AREA)
  • Laminated Bodies (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Packages (AREA)
  • Packaging For Recording Disks (AREA)
  • Casting Or Compression Moulding Of Plastics Or The Like (AREA)
  • Cartons (AREA)
EP19950107067 1992-10-28 1993-08-18 Feuille perforable par pression pour couvertures de supports d'articles ayant securité de manipulation Withdrawn EP0671432A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP19990114241 EP0962485A1 (fr) 1992-10-28 1993-08-18 Feuille perforable par pression pour couvertures de supports d'articles ayant une sécurité de manipulation

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE4236450 1992-10-28
DE4236450A DE4236450A1 (de) 1992-10-28 1992-10-28 Folie für manipulationssichere Abdeckungen von Warenträgern
EP19930919084 EP0662098B1 (fr) 1992-10-28 1993-08-18 Emballage ayant une feuille de recouvrement pour le maintien d'objets sur des supports

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
EP93919084.9 Division 1993-08-18

Related Child Applications (1)

Application Number Title Priority Date Filing Date
EP19990114241 Division EP0962485A1 (fr) 1992-10-28 1993-08-18 Feuille perforable par pression pour couvertures de supports d'articles ayant une sécurité de manipulation

Publications (1)

Publication Number Publication Date
EP0671432A1 true EP0671432A1 (fr) 1995-09-13

Family

ID=6471592

Family Applications (3)

Application Number Title Priority Date Filing Date
EP19990114241 Withdrawn EP0962485A1 (fr) 1992-10-28 1993-08-18 Feuille perforable par pression pour couvertures de supports d'articles ayant une sécurité de manipulation
EP19950107067 Withdrawn EP0671432A1 (fr) 1992-10-28 1993-08-18 Feuille perforable par pression pour couvertures de supports d'articles ayant securité de manipulation
EP19930919084 Expired - Lifetime EP0662098B1 (fr) 1992-10-28 1993-08-18 Emballage ayant une feuille de recouvrement pour le maintien d'objets sur des supports

Family Applications Before (1)

Application Number Title Priority Date Filing Date
EP19990114241 Withdrawn EP0962485A1 (fr) 1992-10-28 1993-08-18 Feuille perforable par pression pour couvertures de supports d'articles ayant une sécurité de manipulation

Family Applications After (1)

Application Number Title Priority Date Filing Date
EP19930919084 Expired - Lifetime EP0662098B1 (fr) 1992-10-28 1993-08-18 Emballage ayant une feuille de recouvrement pour le maintien d'objets sur des supports

Country Status (16)

Country Link
US (1) US5932338A (fr)
EP (3) EP0962485A1 (fr)
JP (1) JP2815704B2 (fr)
AT (1) ATE148483T1 (fr)
CA (1) CA2146649C (fr)
CZ (1) CZ100795A3 (fr)
DE (3) DE4236450A1 (fr)
DK (1) DK0662098T3 (fr)
ES (1) ES2098771T3 (fr)
GR (1) GR3022432T3 (fr)
HU (1) HU214848B (fr)
NO (1) NO311433B1 (fr)
PL (1) PL308548A1 (fr)
SI (1) SI9300557A (fr)
SK (1) SK282070B6 (fr)
WO (1) WO1994010229A1 (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0959020A1 (fr) * 1998-05-20 1999-11-24 Alusuisse Technology & Management AG Emballage permettant la sécurité lors de manipulations
WO2006037425A1 (fr) * 2004-09-30 2006-04-13 Lts Lohmann Therapie-Systeme Ag Emballage non refermable pour produits dangereux pour la sante et procede pour le produire

Families Citing this family (18)

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DE4236450A1 (de) * 1992-10-28 1994-05-05 Bp Chemicals Plastec Gmbh Folie für manipulationssichere Abdeckungen von Warenträgern
DE4317326C1 (de) 1993-05-25 1994-09-01 Ver Kunststoffwerke Gmbh Durchdrückfolie für Durchdrückverpackung
DE4402038A1 (de) * 1994-01-25 1995-07-27 Borries Horst Von Durchdrückpackung
DE4414669C2 (de) * 1994-04-27 1996-04-04 Bp Chemicals Plastec Gmbh Verwendung eines Kunststoff-Materials zur Herstellung einer Folie für manipulationssichere Abdeckungen von Warenträgern
JP3898252B2 (ja) * 1996-06-10 2007-03-28 大日本印刷株式会社 包装体
WO1997010159A1 (fr) * 1995-09-13 1997-03-20 Dai Nippon Printing Co., Ltd. Emballage, son procede de fabrication et combinaison d'un dispositif d'emballage et d'une boite de stockage
DE19613960C5 (de) * 1996-04-09 2004-11-04 Borealis Gmbh Durchdrückfolie
DE19613959C2 (de) * 1996-04-09 2003-03-27 Bp Chemicals Plastec Gmbh Verpackung
DE19713685A1 (de) * 1997-04-03 1997-11-20 Karl Herbert Dr Ing Bauer Blisterstreifen zum Verpacken von Arzneimittel-Tabletten
US6086988A (en) * 1998-03-23 2000-07-11 Kloeckner Pentaplast Of America, Inc. Recyclable lidding material for push-through packaging
US6482074B1 (en) * 2000-12-04 2002-11-19 Taiwan Semiconductor Manufacturing Co., Ltd Apparatus and method for transferring a torque from a rotating hub frame to a hub shaft
GB0225621D0 (en) 2002-11-02 2002-12-11 Glaxo Group Ltd Medicament carrier
DE102004016791A1 (de) * 2004-04-06 2005-11-10 Clariant Gmbh Verwendung von Wachsen als Gleitmittel für gefüllte Kunststoffe
FR2869019B1 (fr) 2004-04-15 2007-11-30 Tergal Fibres Sa Articles d'emballage tels que bouteilles opaques et procede de fabrication de ces articles
US20060141241A1 (en) * 2004-12-23 2006-06-29 Carespodi Dennis L Peelable breakaway multi-layered structures and methods and compositions for making such structures
US20160257438A1 (en) 2015-03-04 2016-09-08 Tekni-Plex, Inc. Multi-layer web and process for forming scored lidding film for blister packages
DE102019101066A1 (de) 2019-01-16 2020-07-16 Huhtamaki Flexible Packaging Germany Gmbh & Co. Kg Recyclingfreundliche Durchdrückverpackung
EP4321337A1 (fr) 2022-08-10 2024-02-14 SÜDPACK Medica AG Film de couverture et feuille de fond pour emballage blister et emballage blister

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US8534461B2 (en) 2004-09-30 2013-09-17 Lts Lohmann Therapie-Systeme Ag Non-reclosable package for products prejudicial to health, as well as process for its production

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NO311433B1 (no) 2001-11-26
SK52795A3 (en) 1995-08-09
WO1994010229A1 (fr) 1994-05-11
PL308548A1 (en) 1995-08-21
JPH08502536A (ja) 1996-03-19
DE9320940U1 (de) 1995-06-14
HU214848B (hu) 1998-06-29
HUT70711A (en) 1995-10-30
SK282070B6 (sk) 2001-10-08
SI9300557A (en) 1994-06-30
NO951530L (no) 1995-04-21
JP2815704B2 (ja) 1998-10-27
US5932338A (en) 1999-08-03
ATE148483T1 (de) 1997-02-15
ES2098771T3 (es) 1997-05-01
CZ100795A3 (en) 1995-12-13
EP0662098B1 (fr) 1997-01-29
DE4236450A1 (de) 1994-05-05
GR3022432T3 (en) 1997-04-30
DE59305356D1 (de) 1997-03-13
DK0662098T3 (da) 1997-08-25
NO951530D0 (no) 1995-04-21
CA2146649A1 (fr) 1994-05-11
CA2146649C (fr) 2000-08-01
EP0662098A1 (fr) 1995-07-12

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