EP0658317A2 - Article à fumer formant un cylindre - Google Patents

Article à fumer formant un cylindre Download PDF

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Publication number
EP0658317A2
EP0658317A2 EP94115638A EP94115638A EP0658317A2 EP 0658317 A2 EP0658317 A2 EP 0658317A2 EP 94115638 A EP94115638 A EP 94115638A EP 94115638 A EP94115638 A EP 94115638A EP 0658317 A2 EP0658317 A2 EP 0658317A2
Authority
EP
European Patent Office
Prior art keywords
tobacco
weight
product according
smoking product
smoking
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP94115638A
Other languages
German (de)
English (en)
Other versions
EP0658317A3 (fr
EP0658317B1 (fr
Inventor
Peter Walter Kossmehl
Edgar Mentzel
Henning Dr. Seidel
Wolfgang Wildenau
Hans Noe
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
HF and PhF Reemtsma GmbH and Co
Original Assignee
HF and PhF Reemtsma GmbH and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE4334222A external-priority patent/DE4334222C3/de
Application filed by HF and PhF Reemtsma GmbH and Co filed Critical HF and PhF Reemtsma GmbH and Co
Publication of EP0658317A2 publication Critical patent/EP0658317A2/fr
Publication of EP0658317A3 publication Critical patent/EP0658317A3/fr
Application granted granted Critical
Publication of EP0658317B1 publication Critical patent/EP0658317B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24BMANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
    • A24B15/00Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
    • A24B15/10Chemical features of tobacco products or tobacco substitutes
    • A24B15/12Chemical features of tobacco products or tobacco substitutes of reconstituted tobacco
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24BMANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
    • A24B15/00Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
    • A24B15/10Chemical features of tobacco products or tobacco substitutes
    • A24B15/12Chemical features of tobacco products or tobacco substitutes of reconstituted tobacco
    • A24B15/14Chemical features of tobacco products or tobacco substitutes of reconstituted tobacco made of tobacco and a binding agent not derived from tobacco
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D1/00Cigars; Cigarettes
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D1/00Cigars; Cigarettes
    • A24D1/02Cigars; Cigarettes with special covers

Definitions

  • the invention relates to a rod-shaped smoking product with a strand-shaped core made from shredded smoking tobacco, which is surrounded by a jacket made of tobacco foils produced by a paper manufacturing process.
  • Such a smoking product is known, for example, from EP-A-0 495 567, the tobacco foil, which is also referred to as a sheet of reconstituted tobacco, having been produced by a paper production process in accordance with US-A-4,182,349.
  • stems of the tobacco plant, tobacco ribs and other tobacco components that cannot be used in cigarette production, in particular very fine fractions but also tobacco leaves, are defibrated and mixed or washed out with, for example, heated water or other aqueous liquids of certain temperatures, after which the sieve device is used to filter them the water-containing extract extract is withdrawn;
  • the cellulose constituents are optionally repeated after further intermediate stages such as homogenization Sieving or cleaning, together with fillers and other additives, are added to the sieve of a paper production device after further intermediate stages.
  • the concentrated tobacco extract is applied to the raw film thus obtained and this is processed into the final tobacco film.
  • tobacco foils produced according to such an extract process have so far been used in small chunks for stretching smoking tobacco in cigarettes or cigarillos, primarily using the fines and ribs which are unsuitable for cigarette manufacture as a smokable material.
  • tobacco foils of this type were used as cover sheets for cigarillos because of their uniform structure and better mechanical properties.
  • tobacco foils as a binder or cover sheet for smoking products is problematic for many reasons, because the tobacco foils are inadequate in terms of sensors due to the tobacco starting material and / or because of the darker color they are not appealing to the consumer. Numerous attempts have been made to overcome these disadvantages, for example by enzymatically processing the extract. Such measures have so far been unsuccessful and have also resulted in products that do not meet legal requirements. In addition, there were considerable difficulties with the required properties of such tobacco films with regard to their tear resistance, their water resistance or saliva resistance or very generally with regard to their smoking properties, such as porosity, burning behavior, ash content and in particular with regard to the smoke aroma familiar from the consumer.
  • the tobacco film is obtained essentially from ribs and fine fractions by the extraction paper process, the extract obtained by this paper production process being reduced in order to reduce secondary smoke, only in a limited amount, namely not more than 20% by weight .% (based on the weight of the tobacco foil) should be applied again.
  • the taste quality or aroma of such a product leaves something to be desired.
  • the invention is based on the object of proposing a novel smoking product of the type mentioned at the outset which once satisfies the typical flavor expected by the smoker, which until now could not be achieved by tobacco wrapped smoke products, and which on the other hand improves the quality of the secondary smoke.
  • a smoke product encased in this way is proposed, in which the casing formed from tobacco foils is designed with regard to the physical characteristics of the foil so that the smoke product can be produced economically on conventional cigarette or cigarillo production systems and thus meet the requirements with regard to tensile strength and elongation such jacket production fulfilled, with the glow rate and porosity allow control of the smoke supply.
  • a smoking product which is designed according to the main claim, particularly preferred embodiments being set out in the subclaims.
  • the use of smoking products as novel plug-in cigarillos is also proposed.
  • the tobacco foils for the cover sheet ie the outer wrapping of the rod-shaped smoke product
  • the tobacco wrapper of the topsheet is fed or returned considerably more tobacco extract than the binder.
  • tobacco foil In total, the jacket of the rod-shaped smoking product consisting of two layers contains a tobacco extract amount of more than 20% by weight, based on the dry substance.
  • the tobacco film produced by the paper manufacturing process according to TF-1 consists of 75 to 100% by weight essentially of (a) tobacco cellulose and (b) tobacco extract consisting of tobacco components.
  • the tobacco cellulose is obtained from a shredded leaf or cut tobacco mixture, from tobacco greens (scrap), from tobacco stems and from tobacco stem material, the aroma-intensive components, namely the leaf tobacco mixture and the tobacco greens having a particle size of about 1 to 5 and preferably 1 , 5 to 4 mm on the one hand and the components which are more determining for the cellulose content, namely tobacco rib material on the other hand, are present in a weight ratio of 1: 1.1 to 1: 5.
  • the tobacco extract is made from a shredded leaf or cut tobacco mixture and received tobacco rib material.
  • the tobacco films up to 20% by weight and preferably 8 to 14% by weight of foreign cellulose such as softwood, hemp or flax cellulose are used to produce the tobacco films. If the tobacco cellulose comes wholly or partly from tobacco stalks, the proportion of foreign cellulose can be reduced accordingly without impairing the physical properties of the tobacco film.
  • foreign cellulose such as softwood, hemp or flax cellulose
  • the tobacco material required to produce the tobacco foil consists of a high-quality cut tobacco mixture, for example a mixture of Virginia tobacco, Burley tobacco, Orient tobacco and blowing ribs from Virginia -Tobacco exists.
  • the proportion of tobacco rib material required to produce the tobacco film is somewhat higher, which is necessary in view of the physical properties of the tobacco cellulose.
  • the ratio of leaf or cut tobacco mixture to tobacco stem or tobacco stem material should not exceed a value of 1: 5, since otherwise the flavor-determined smoking properties of the tobacco foil are adversely affected. If necessary, however, this can be compensated for by adding tobacco flavors during the last step of the film production process.
  • the extract is applied to the cellulose material obtained in this process in an amount of more than 20% by weight of the tobacco foil. If the extract contains an increased proportion of a lamina tobacco extract, the aroma components required for the final smoking product are enriched.
  • This tobacco film manufactured according to another paper manufacturing process consists essentially of lamina tobacco material with regard to its tobacco content. Based on the tobacco film, this is crushed in an amount of 75 to 80% by weight together with 10 to 20% by weight of long-fiber foreign cellulose and, when the cold-water-soluble tobacco extracts are almost completely circulated in the wire section of a paper production plant, is obtained as raw film on this.
  • the usual additives that are still required, such as binders, fillers and the agents influencing the burn-off, as well as flavorings, can be added in an amount of up to 15% by weight both when the raw film is produced and later when it is conditioned.
  • the tobacco film in its taste-relevant tobacco mixture composition corresponds to the composition of the leaf or cut tobacco mixture of the tobacco inlay or the core of the rod-shaped smoking product. This is on the one hand, to achieve the desired taste - preferably "American blend" - necessary, on the other hand, with regard to a simple, inexpensive manufacture of the rod-shaped smoke product, an advantage overall, since both the casing and the core can be produced with the same tobacco mixture.
  • the tobacco mixture composition of the tobacco film can be changed from the mixture composition of the tobacco.
  • binders such as methyl cellulose, dextrins, pectins, alginates, starch, gums, amylose, carboxymethyl cellulose, honey, corn syrup or other polysaccharides can be used as additives.
  • Calcium carbonate or titanium dioxide for example, can be used as filler.
  • Flavorings that can be used later are tobacco flavors or extracts from tobacco mixtures, for example by an on-line loading of the tobacco foils, which are manufactured per se, by means of the loading device from Kaymich (GB) (Kaymich applicator model FDU3 SYSM).
  • the flavoring is preferably carried out in alcoholic solution, preferably on the inside of the tobacco foils, in order to avoid undesirable optical effects, over the entire surface or in longitudinal strips.
  • This subsequent film flavoring can be carried out both with the tobacco film according to TF-1 and with the tobacco film according to TF-2.
  • Table I Technical data of the tobacco films TF-1 and TF-2 general area preferably Elongation in% according to DIN 53112 1 - 1.4 1.15 - 1.3 Porosity according to DIN ISO 2965 in Coresta units 30-200 80-120 Basis weight according to DIN 53104 in g / m2 35-70 45-55 Humidity according to DIN 10252 in% 8-15 8-12 Breaking load according to DIN 53112 in g each 2.54 cm wide at least 1000 1350 - 1600
  • the strand-shaped core of shredded smoking tobacco is coated with only one tobacco foil obtained by the TF-1 process.
  • the jacket placed around the strand-shaped core consists of one or more layers of tobacco film, both of which have been obtained by the TF-1 process or both by the TF-2 process, although it is preferred to use one layer and in particular to produce the outer layer or cover sheet by the TF-1 process, while the inner layer or cover sheet has been obtained by the TF-2 process.
  • the cover sheet that is to say the outermost layer of the jacket formed around the strand-shaped core, is usually arranged in a spiral, while the binder sheet, that is to say the innermost layer of the jacket formed around the strand-shaped core, has an adhesive seam in the axial direction.
  • this smoking product should generally have the technical data listed in Table II below: Table II general area preferably Diameter in mm 6 - 9 7.8 - 8.1 length in mm 50-250 55-75 Mass glow rate in mg / min 50-70 60 Packing density of the filling tobacco (core) in mg / cm3 190-270 210-240
  • the cutting width of the inlay or filling tobacco preferably has the following values: Average of the mix 2.2 mm Virginia 2.2 mm Orient 2.5 mm Burley 2.0 mm
  • the pH of the tobacco foil measured in an aqueous slurry is 7.0.
  • the casing or jacket of the smoke product according to the invention can have an end porosity which is greater than 30 and less than 1,000 Coresta units.
  • This product can be smoked like a normal cigarillo, but can also be inserted into a conventional cigarette filter sleeve and then smoked.
  • the tobacco films of the jacket can also be produced in such a way that the porosity of the jacket formed from the cover sheet and the binder sheet is in a range from 10,000 to 30,000 Coresta units, that is to say has a very high porosity, so that this smoking product is suitable for is not smokable and can only be inserted and smoked as a plug-in cigarillo in customary known pods.
  • the rod-shaped smoke product according to the invention which can be smoked per se, can be produced in the length customary for cigarillos; it can with one Filter mouthpiece of the usual type, that is, also provided with a ventilated filter, which is preferably laser-perforated, which takes into account the trend towards the lights-cigarillo.
  • the rod-shaped smoke product according to the invention can also be produced in oversized lengths in order to be able to divide it up according to DE PS 42 06 507 depending on smoking habits; it can also be beveled at the end according to DE PS 41 07 027 in order to be able to use it better in corresponding sleeves.
  • a rod-shaped smoke product with a single-layer jacket as a cigarillo with a diameter of 8.0 mm and a strand length of 70 mm was produced.
  • the tobacco insert or the strand-shaped core consisted of a tobacco mixture with about 1.8% tobacco nicotine and a plug density of 210 mg / cm3, the average cutting width of the core tobacco of 60% by weight of the mixture being 2.2 mm.
  • the one-ply casing was a tobacco film glued in the axial direction, which had been obtained by the extraction paper process TF-1.
  • Table III cover sheet Porosity in Coresta units 103 Basis weight 47.7 g / m2 extract 27.5% by weight CaCO3 6.3% by weight TiO2 4.4% by weight Sodium acetate 1.6% by weight rib 33.3% by weight Lamina 14.2% by weight Foreign cellulose 12.7% by weight
  • a rod-shaped smoke product in the manner of a two-layer cigarillo with a diameter of 8.0 mm and a strand length of 70 mm was produced.
  • the tobacco insert (core) again consisted of a tobacco mixture with about 1.8% tobacco nicotine and a plug density of 210 mg / cm3, the average cutting width of 60% by weight of the mixture again being 2.2 mm.
  • Both the binder and cover sheet consisted of tobacco films obtained by the extraction paper process "TF-1"; the cover sheet was placed in a spiral at an angle of 30 ° around the binder.
  • the physical properties of the cover sheet corresponded to the tobacco film according to Example 1; the tobacco film used as a binder and its composition are listed in Table IV below: Table IV Folder Porosity in Coresta units 76 Basis weight 41.8 g / m2 extract 15.4% by weight CaC03 5.7% by weight Ti02 3.5% by weight Sodium acetate 2.0% by weight rib 42.9% by weight Lamina 16.7% by weight Foreign cellulose 13.8% by weight
  • a smoke product was produced analogously to Example 2, but the cover sheet and cover sheet were interchanged.
  • a smoke product was produced analogously to Example 2, but with a ventilated (18% filter ventilation) monoacetate filter of 20 mm length and a retention capacity of 36% (retention).
  • a smoking product was produced as in Example 2, but the binder was obtained by a paper production process without extract recycling according to TF-2 and had a porosity of 133 Coresta units and a weight of 52 g / m2.
  • the tobacco mixture consisted of 100% lamina tobacco. Based on its dry weight, the tobacco film also contained 75% by weight of laminate tobacco in addition to 10% by weight of long-fiber foreign cellulose CaCO 3: 8.0% by weight TiO2: 3.8% by weight Na acetate: 1.8% by weight Extract: 1.4% by weight
  • a smoke product was produced analogously to Example 2, wherein however, the cover sheet was produced with a different recipe according to TF-1; the individual values were: porosity 78 Coresta units Weight 48.2 g / m2 extract 29.3% by weight CaCO3 5.8% by weight TiO2 1.7% by weight Na acetate 2.2% by weight Foreign cellulose 15.0% by weight Ribs 27.6% by weight Virginia Lamina 18.4% by weight
  • a smoking product was produced analogously to Example 6, but the cover sheet was not produced from tobacco rib material and lamina, but using the appropriate amount, namely 46% by weight of tobacco stalks.
  • a smoking product was produced analogously to Example 6, but the tobacco rib fraction of 27.6% by weight was replaced by the same amount of tobacco stalks.
  • the smoking product is designed such that the outermost layer of the jacket is shaped as a filter-provided sleeve made of spirally wound and / or sheet-like tobacco foil, which is at least partially glued and has an axial overlap region, into which the tobacco foil is enveloped
  • the core of smoking tobacco can be inserted, the inner tobacco film possibly also consisting of several layers.
  • the outermost layer or the inner layer or tobacco foil can be highly porous, the respective other layer then being less porous; Mixed forms with regard to porosity can also be carried out as long as an overall smokable product is obtained.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Cigarettes, Filters, And Manufacturing Of Filters (AREA)
  • Manufacture Of Tobacco Products (AREA)
  • Artificial Filaments (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Paper (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Forging (AREA)
EP94115638A 1993-10-07 1994-10-05 Article à fumer formant un cylindre Expired - Lifetime EP0658317B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE4334222 1993-10-07
DE4334222A DE4334222C3 (de) 1993-10-07 1993-10-07 Stabförmiges Rauchprodukt

Publications (3)

Publication Number Publication Date
EP0658317A2 true EP0658317A2 (fr) 1995-06-21
EP0658317A3 EP0658317A3 (fr) 1995-08-23
EP0658317B1 EP0658317B1 (fr) 2000-08-16

Family

ID=6499640

Family Applications (1)

Application Number Title Priority Date Filing Date
EP94115638A Expired - Lifetime EP0658317B1 (fr) 1993-10-07 1994-10-05 Article à fumer formant un cylindre

Country Status (16)

Country Link
US (1) US5617881A (fr)
EP (1) EP0658317B1 (fr)
AT (1) ATE195405T1 (fr)
CA (1) CA2133785C (fr)
CZ (1) CZ289068B6 (fr)
DE (1) DE19512535A1 (fr)
EE (1) EE03145B1 (fr)
HR (1) HRP940578B1 (fr)
HU (2) HU9402892D0 (fr)
LT (1) LT3637B (fr)
LV (1) LV11097B (fr)
MD (1) MD1289C2 (fr)
PL (1) PL178311B1 (fr)
RU (1) RU2114538C1 (fr)
SI (1) SI9400378B (fr)
SK (1) SK282288B6 (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL1020285C2 (nl) * 2002-03-29 2003-09-30 Deli Htl Tabak Mij B V Werkwijze ter vervaardiging van een 'toploaded cigarette filler'. Werkwijze ter vervaardiging van een 'toploaded cigarette filler'.
CN103005658A (zh) * 2011-09-21 2013-04-03 湖北中烟工业有限责任公司 一种提高烟梗成浆质量的新工艺

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CN1321599C (zh) * 1999-07-28 2007-06-20 菲利普莫里斯生产公司 带有改进的填充料的吸烟品包装物
US8578944B2 (en) * 1999-12-07 2013-11-12 Blunt Wrap U.S.A., Inc. Method of making a tobacco product
US6722372B1 (en) 2000-07-20 2004-04-20 Brown & Williamson Tobacco Corporation Wrapper for smoking article
PT1449447E (pt) * 2001-11-05 2012-04-26 Japan Tobacco Inc Cigarro com baixa tendência à ignição
DE10304629B4 (de) * 2003-02-05 2008-10-30 British American Tobacco (Germany) Gmbh Druckkonditionierungsverfahren
US20120152265A1 (en) * 2010-12-17 2012-06-21 R.J. Reynolds Tobacco Company Tobacco-Derived Syrup Composition
GB201100218D0 (en) * 2011-01-07 2011-02-23 British American Tobacco Co Smoking article
CN103798949B (zh) * 2014-03-11 2016-02-24 云南瑞升烟草技术(集团)有限公司 一种用于重组烟叶的改性粒子制备方法
US20160073686A1 (en) * 2014-09-12 2016-03-17 R.J. Reynolds Tobacco Company Tobacco-derived filter element
HUE041357T2 (hu) 2014-09-30 2019-05-28 Philip Morris Products Sa Eljárás homogenizált dohány anyag elõállítására
US9950858B2 (en) 2015-01-16 2018-04-24 R.J. Reynolds Tobacco Company Tobacco-derived cellulose material and products formed thereof
HUE044510T2 (hu) * 2015-05-21 2019-10-28 Philip Morris Products Sa Eljárás induktív módon melegíthetõ dohányrudak elõállítására
MX2018002248A (es) 2015-08-28 2018-03-23 Philip Morris Products Sa Elementos tubulares mejorados para articulos para fumar.
GB201707761D0 (en) 2017-05-15 2017-06-28 British American Tobacco Investments Ltd Method of making a tobacco extract
GB201707767D0 (en) 2017-05-15 2017-06-28 British American Tobacco Investments Ltd Method of making a tobacco extract
GB201707758D0 (en) * 2017-05-15 2017-06-28 British American Tobacco Investments Ltd Ground tobacco composition
US11582997B2 (en) 2017-11-28 2023-02-21 Philip Morris Products S.A. Aerosol generating article having a mouthpiece with a modified structure
CN108978222B (zh) * 2018-07-11 2021-06-11 常州龙途新材料科技有限公司 可挥发香味且生物降解的复合纤维纱,及制备、用途工艺
EP3981262A4 (fr) * 2019-06-07 2023-02-08 Japan Tobacco Inc. Feuille de tabac, boudin de tabac et article à fumer
KR102605497B1 (ko) * 2021-04-29 2023-11-22 주식회사 케이티앤지 담배추출물시트, 이의 제조 방법 및 이를 포함하는 흡연물품
WO2024036779A1 (fr) * 2022-08-18 2024-02-22 云南中烟工业有限责任公司 Structure de papier à cigarette composite multicouche pour aromatisation facile et procédé de fabrication

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL1020285C2 (nl) * 2002-03-29 2003-09-30 Deli Htl Tabak Mij B V Werkwijze ter vervaardiging van een 'toploaded cigarette filler'. Werkwijze ter vervaardiging van een 'toploaded cigarette filler'.
WO2003082030A1 (fr) * 2002-03-29 2003-10-09 B.V. Deli-Htl Tabak Maatschappij Procede de fabrication de tripe de cigarette charge jusqu'a la tete
CN103005658A (zh) * 2011-09-21 2013-04-03 湖北中烟工业有限责任公司 一种提高烟梗成浆质量的新工艺
CN103005658B (zh) * 2011-09-21 2015-04-01 湖北中烟工业有限责任公司 一种提高烟梗成浆质量的工艺

Also Published As

Publication number Publication date
CA2133785C (fr) 2000-03-07
DE19512535A1 (de) 1996-10-10
SI9400378B (en) 2001-12-31
MD1289C2 (ro) 2000-10-31
HU9402892D0 (en) 1995-01-30
RU2114538C1 (ru) 1998-07-10
RU94039293A (ru) 1996-09-20
ATE195405T1 (de) 2000-09-15
EE03145B1 (et) 1999-02-15
EP0658317A3 (fr) 1995-08-23
LV11097A (lv) 1996-04-20
LTIP2044A (en) 1995-05-25
MD1289B2 (en) 1999-08-30
SI9400378A (en) 1995-04-30
HU214187B (hu) 1998-01-28
EP0658317B1 (fr) 2000-08-16
HU9402899D0 (en) 1995-01-30
SK122294A3 (en) 1995-04-12
CZ247994A3 (en) 1995-06-14
MD940381A (en) 1996-02-29
HRP940578B1 (en) 1999-10-31
HUT71854A (en) 1996-02-28
PL305350A1 (en) 1995-04-18
PL178311B1 (pl) 2000-04-28
CZ289068B6 (cs) 2001-10-17
CA2133785A1 (fr) 1995-04-08
US5617881A (en) 1997-04-08
LT3637B (en) 1996-01-25
HK1013606A1 (en) 1999-09-03
SK282288B6 (sk) 2002-01-07
HRP940578A2 (en) 1996-08-31
LV11097B (en) 1996-08-20

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