EP0615008A1 - Gekräuselte Acrylfasern, sowie Thixotropiermittel und diese enthaltende Zusammensetzungen - Google Patents
Gekräuselte Acrylfasern, sowie Thixotropiermittel und diese enthaltende Zusammensetzungen Download PDFInfo
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- EP0615008A1 EP0615008A1 EP94103729A EP94103729A EP0615008A1 EP 0615008 A1 EP0615008 A1 EP 0615008A1 EP 94103729 A EP94103729 A EP 94103729A EP 94103729 A EP94103729 A EP 94103729A EP 0615008 A1 EP0615008 A1 EP 0615008A1
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- fibers
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- fiber
- crimped
- acrylic fibers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
- D01F9/08—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
- D01F9/12—Carbon filaments; Apparatus specially adapted for the manufacture thereof
- D01F9/14—Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments
- D01F9/20—Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments from polyaddition, polycondensation or polymerisation products
- D01F9/21—Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments from polyaddition, polycondensation or polymerisation products from macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D01F9/22—Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments from polyaddition, polycondensation or polymerisation products from macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyacrylonitriles
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/10—Materials in mouldable or extrudable form for sealing or packing joints or covers
- C09K3/1025—Materials in mouldable or extrudable form for sealing or packing joints or covers characterised by non-chemical features of one or more of its constituents
- C09K3/1028—Fibres
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/02—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D01F6/18—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polymers of unsaturated nitriles, e.g. polyacrylonitrile, polyvinylidene cyanide
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2200/00—Chemical nature of materials in mouldable or extrudable form for sealing or packing joints or covers
- C09K2200/02—Inorganic compounds
- C09K2200/0239—Oxides, hydroxides, carbonates
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2200/00—Chemical nature of materials in mouldable or extrudable form for sealing or packing joints or covers
- C09K2200/04—Non-macromolecular organic compounds
- C09K2200/0447—Fats, fatty oils, higher fatty acids or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2200/00—Chemical nature of materials in mouldable or extrudable form for sealing or packing joints or covers
- C09K2200/06—Macromolecular organic compounds, e.g. prepolymers
- C09K2200/068—Containing also other elements than carbon, oxygen or nitrogen in the polymer main chain
- C09K2200/0682—Containing sulfur
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2904—Staple length fiber
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2922—Nonlinear [e.g., crimped, coiled, etc.]
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
- Y10T428/2964—Artificial fiber or filament
- Y10T428/2967—Synthetic resin or polymer
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2973—Particular cross section
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/298—Physical dimension
Definitions
- the invention relates to crimped acrylic fibers thixotropic agents and compositions and especially to the use of crimped acrylic fibers as thixotropes.
- Fibers have been added to organic and inorganic matrices to improve the viscosity and the handling characteristics of the mix and the toughness of the cured or solidified product. Fibers provide a combination of viscosity control and reinforcement, whereas particulate and chemical additives only improve viscosity. Asbestos fibers and other inorganic fibers, such as ceramic, glass, and the like, have been used in various resin systems to prepare sealants, mastics, putties and adhesive formulations. Health hazards in the use of asbestos are well known.
- inorganic fibers because of their intrinsic brittleness, can fracture during mixing to create a higher percentage of very short fibers, and these result in variability and loss of performance as fiber thixotropes, because short, broken fibers generally do not provide maximum reinforcement and viscosity enhancement.
- the inorganic thixotropes have been supplanted to a significant extent by polymeric fibers, especially by fibrillated polyolefin and polyaramid fibers.
- Fibrillation is a means of texturizing which comprises stretching a fiber or film to fully or partially orient it and then breaking it transversely apart or mechanically abrading it to provide an interlaced fibrous structure.
- Such fibers induce high viscosities, but they are difficult to disperse in resins, and tend to result in inhomogeneous mixtures. Additionally, their adhesion to the cured resin is generally poor unless special surface treatments are carried out on the fibrillated fibers.
- fibrillated polymeric fibers adapted for use as physical thixotropes are: KEVLAR®, and ULTRATHIX®, poly para-phenyleneterephtalimide, and PULPLUSTM, linear polyethylene, both products of the Du Pont Company, Wilmington, DE, USA. Also commercially available are polyethylene fibers sold under the tradenames SHORT STUFF® and FYBREL® by Minifibers, Inc., Johnson City, TN, USA.
- KEVLAR® aramid pulped fibers in the range of from about 0.1 to 5.0 % by weight, for viscosity control in poly(vinyl chloride) plastisols, in silicones, in epoxy resins, and in polyurethanes is described in Research Disclosure No. 29676, April 1987.
- Acrylic fibers e.g., fibers of a co-polymer containing acrylonitrile in a quantity more than 85 wt-%, have good extensibility, which prevents their fragmentation during mixing, and they adhere well to most resin systems because of the polar nitrile groups present in the molecule. These attributes make them desirable materials to consider for use where viscosity enhancement in resin systems is needed while maintaining or increasing the strength of the resulting resin-fiber composite.
- Modacrylic fibers with more than 35 wt% and generally less than 85 wt% acrylonitrile in the copolymer provide also good extensibility, resistance to fragmentation during mixing and good adhesion to most resin systems, while also providing other attractive attributes such as fire retardancy. Consequently, they also are desirable materials for the present purpose.
- Fiber aspect ratio is defined as the ratio of the fiber length to its diameter (L/D). If fiber aspect ratios are above 20, the patent states that the fibers will bend and scratch the rollers used to process the paint. Typically, the disclosure continues, the concentration of the fibers in such paints are disclosed to be about 20% by weight. High fiber concentrations in the mix are permitted when L/D is 20 or less. However, where L/D values are larger, the viscosity greatly increases.
- the fibers are not texturized, but special stretching techniques (at least 8 times stretch) and annealing techniques (heating at 150-200°C, while stretched, then allowing the fibers to relax) are used in the manufacture of such acrylic fibers to make them strong reinforcing agents.
- Such heat treatments result in tenacities higher than 50 cN/tex and initial moduli greater than 1000 cN/tex, and these values are typical of fibers twice as strong and twice as stiff as would suffice in the typical fibrous thixotropes.
- East German Patent Publication, DD-A1-279491 describes the use of acrylic fibers as physical thixotropes in resin systems.
- the diameter of the fibers is not specified, but the count number is given as 0.05 to 1.0 Tex, with specific examples of 0.52 Tex and 0.12 Tex. This, for the examples, corresponds to a diameter in the range of 23.8 to 11.4 micrometers.
- the cut length of the fibers in the claims is greater than 0.1 mm and less than 10 mm.
- the aspect ratio of the fibers used in the examples in the East German Patent Publication ranges from 42 to 263.
- the fibers of the East German Patent are not texturized, e.g., they are unlike the pulps and fibrillated fibers, mentioned above.
- the East German Patent DD 279491 states that the fibers should not be agglomerated in order to facilitate incorporation into the resin system.
- Example IX In US-A-4,866,109 are described cut acrylic fibers and their use to reinforce materials such as plastics, rubbers, paints, cement, tar, petroleum residues, polymeric materials and paints. No mention is made of their use as physical thixotropes.
- the citation does disclose in Example IX that the fibers have a natural crimp of 3% resulting from normal processing conditions.
- Example IX of the patent is described to produce an unsatisfactory gasket sheet.
- crimp as used herein, is meant the A.S.T.M.
- fibrous organic thixotropes are known to be suitable replacements for inorganic thixotropes, like asbestos, and they generally comprise pulped polyolefin fibers, pulped aramid fibers, and unpulped heat-modified or chemically modified acrylic fibers.
- Pulped, or otherwise texturized acrylic fibers having more than the normal 3% crimp have not been described as physical thixotropes, and especially no acrylic fiber thixotropes having a special form of texturizing known in the textile art as crimped fibers, have been described for use as thixotropes.
- crimping above 3% e.g., 30 - 50%, alone, will increase the viscosity of a polysulfide resin containing 2% by weight of the respective fibers by a factor ranging from 1.25 to 2.2; crimping above 3% , e.g., 30 - 50%, alone will reduce the vertical slump of a polysulfide resin composition containing 1.25% by weight of the respective fibers by a factor of 0.1 to 0.5; and crimping above 3%, e.g., 30 -50%, alone will increase the resin yield stress in a rheometer by a factor of 2 to 8 and decrease the tendency of resin to separate from the fiber, i.e., dewet, by a factor of 3 to 6, (based on comparing Examples 5-6 and 5A and 6A).
- microdenier acrylic fibers i.e., fibers with a tex less than 0.11 (denier less than 1.0), and having greater than 3% crimp to act as a physical thixotrope in adhesives, sealants, coatings, building materials, and the like while maintaining satisfactory mixing, processing and surface characteristics.
- the working examples hereinafter will show that the fibers act as physical thixotropes by forming an interlocking matrix in the substrate fluid when at rest and orienting parallel to the direction of shear when flowing.
- the fibers can be unfibrillated or in the form of a pulp.
- the comparative examples will demonstrate that the fibers provide excellent rheological properties because of crimping to greater than 3%, all other variables being constant. Extensibility (elongation) of elastomeric materials is also increased compared to other fibrous thixotropes. Because of the good UV resistance and low moisture absorption of the fibers, they are well suited for outdoor applications. Also, because of their good hydrocarbon and other chemical resistance they are well suited as fuel tank and chemical tank sealant components.
- the thixotropic effect of the fibers can be controlled by changing the fiber architecture, including fiber length and diameter.
- the thixotropic effect of the fibers can be defined in terms of the fiber aspect ratio and the volume fraction, when the aspect ratio exceeds a critical minimum.
- crimped, microdenier acrylic fibers with a small diameter, a minimum length in the range of 0.5-3 mm, a minimum aspect ratio (L/D) in the 20-50 range, having greater than 3%, prefeably greater than 5%, and most preferably, greater than 10% crimp, and adapted to act as a physical thixotrope e.g. in adhesives, sealants, coatings, building materials and the like.
- thixotropic agents produced from crimped fibers of a polymer containing acrylonitrile in a quantity more than 35 wt%, and especially more than 85 wt%, the fibers having a fiber diameter less than 100 ⁇ m, a fiber length greater than 0.5 mm, a minimum aspect ratio in the range of 20-50, and being crimped to greater than 3%, preferably greater than 5%, and most preferably, greater than 10% so as
- compositions comprising
- the invention contemplates texturized fibers as defined above wherein the acrylic fibers are non-fibrillated; those comprised of a polymer containing acrylonitrile in a quantity more than 35 wt%; those having an average diameter in the range of about 2-15 micrometers and a crimp of greater than 10%; and those having an aspect ratio (L/D) of greater than about 100.
- compositions as defined above wherein the resin comprises a curable resin selected from a polyester, a polyacrylate, a phenolic, a silicone, a polyurethane, natural or synthetic latex or rubber, a polyimide, a polyepoxide, a polysulfide, or a combination of any of the foregoing; those wherein the concentration of the physical thixotrope is from about 0.05 to about 10.0 parts by weight per 100 parts by weight of (a) and (b) combined; preferably those wherein the concentration of the physical thixotrope is from about 0.5 to about 5.0 parts by weight per 100 parts by weight of (a) and (b) combined.
- a curable resin selected from a polyester, a polyacrylate, a phenolic, a silicone, a polyurethane, natural or synthetic latex or rubber, a polyimide, a polyepoxide, a polysulfide, or a combination of any of the foregoing; those wherein the concentration of the physical
- acrylic fibers include fibers obtained by the wet-spinning or dry-spinning of homopolymers of acrylonitrile, of copolymers containing at least 85% by weight of acrylonitrile, the residue being an ethylenically unsaturated comonomer copolymerizable with acrylonitrile, or blends of polymers wherein the total content of polymerized acrylonitrile is higher than 70 % by weight.
- modifiedacrylic fibers which are copolymers comprising from 35 to 85 % by weight of polymerized acrylonitrile.
- the fibers can be "normal" modulus or "high” modulus fibers, the former generally having a modulus as measured by ASTM Test Method D3822 in the range of 6,900 to 55,200 bar(100,000 to 800,000 psi (0.1 to 0.8 msi)), and the latter having a modulus in the range of 55,200 to 276,000 (800,000 psi to 4,000,000 psi (0.8 to 4 msi)).
- the molecular weight of the polymers is not particularly critical, and can range from about 10,000 to about 500,000, preferably >100,000, on the M W basis.
- the polymers can be surface finished, using conventional sizing agents or they can be unfinished. Thermally stable i.e., pre-oxidized, acrylic fibers can be used. A variety of shaped cross-sections, i.e., non-round fibers, can be used without departing from advantages of the invention.
- texturized when used with acrylic fibers herein and in the appended claims is intended to include all known processes to produce fibers for textured yarns, including, but not limited to, taking partially or fully drawn monocomponent or bicomponent filaments or tows and processing them into the desired texture e.g., by coiling, curling, crimping and waving. Methods for such texturizing techniques are described in detail in reference texts, among which is mentioned, "Textiles: Fiber to Fabric", B.P. Corbman, New York, McGraw-Hill, Inc., Fifth Edition, 1975, pages 73-90.
- a preferred texturizing technique for producing the acrylic fibers used in the present invention is "crimping", which provides an accordionlike characteristic to the yarn.
- crimps are those produced by a stuffer box in which the thermoplastic acrylic yarn is stuffed into a container and heat-set in the crimped condition thereby forming a random zigzag crimp.
- gear method crimps are put into thermoplastic tow or yarn by employing the teeth on heated gear wheels. As the yarn is passed between the wheels, it is crimped into a jagged fashion in conformation to the gears and is heat-set.
- the fiber tow is fed into a crimping zone four times faster than it emerges, causing the fiber to be compressed in its length and thereby becoming crimped.
- Jet crimping can also be used, in which yarn is guided into contact with high velocity air jets, heated and set.
- Machines which can be used to process acrylic fibers in tow form by heat-stretching, breaking, and crimping are available commercially, e.g., the Tow Stapler, manufactured and sold by Turbo Machine Company.
- Crimping apparatus and processes are described in the art, US-A-2,575,839, showing stuffing boxes and US-A-2,917,784, showing crimping wet stretched tow.
- Crimping can also be produced by exposing to heat and/or moisture specially prepared bicomponent fibers with differential shrinkage in the components. Cutting the acrylonitrile-containing fibers is carried out with well-known equipment and by well-known procedures which are standard in the synthetic fiber industry; see for Example the disclosure in the above-mentioned US-A-4,866,109.
- the fiber diameter is required to be small, i.e., less than 100, and preferably less than 40, micrometers. Especially preferably the fibers will have an average diameter in the range of about 2-15 micrometers. It is necessary that the fibers have a minimum length in the range of 0.3-3 millimeters, and a maximum length of about 6 millimeters. When the fiber diameter and length exceeds these limits, dispersion into the resin can become difficult, and reinforcing effects can be adversely affected.
- a most important characteristic is the aspect ratio, length divided by diameter (L/D). It has been found that aspect ratios must be no less than about 20-50, and preferably substantially higher, 100, and even up to 200. Higher than about 200, however, generally limits the volume of fibers that can be used.
- the aspect ratio can be increased by using the smaller diameter fibers, or longer fibers with the larger diameter fibers. If the aspect ratio falls below 20-50, the viscosity increase becomes unacceptably small.
- the upper limit of the aspect ratio is quite high, and is reached only when the composition with resin has an unextrudably high viscosity, e.g., of the order of 20,000 Pa ⁇ s(200,000 poise). The best balance of properties seems to be achieved with fibers of 5 to 12 micrometer diameters and lengths between about 0.5 and 5 millimeters.
- the effective amount of the fibers to be used will vary widely, but in general it will be an amount which is within the range used in the prior art, which is typically from about 0.05 to about 10 parts by weight of fibers per 100 parts by weight of fibers and resin and/or resin and conventional additives combined, depending mostly on the resin system used, the desired viscosity, and the range of reinforcement desired. In general, however, an amount in the range of from about 0.5 to about 5.0 parts by weight of physical thixotrope per 100 parts by weight of fibers and resin system, combined, will be used, with the ideal amount being easily determined by those of ordinary skill in this art.
- the resin compositions can be prepared readily by simply mixing the thixotrope into the resin system with conventional mixers, such as ribbon blenders, vertical or horizontal blenders, Koneaders, helical mixers, Sigma mixers, Banbury mixers, two roll mills, single and twin screw extruder mixers and other known blenders.
- conventional mixers such as ribbon blenders, vertical or horizontal blenders, Koneaders, helical mixers, Sigma mixers, Banbury mixers, two roll mills, single and twin screw extruder mixers and other known blenders.
- the compositions can be applied to areas of ultimate use also in conventional ways well known to those skilled in the art, such as by brushing, spraying, pumping, injecting, and the like.
- the resin matrices can contain conventional additives in conventional amounts, such as pigments, dyes, fillers, heat stabilizers, antioxidants, plasticizers, lubricants, UV-stabilizers, flame retardant agents, processing aids, foaming agents, and the like in order to further improve the properties, including processability, of the resin composition.
- conventional additives such as pigments, dyes, fillers, heat stabilizers, antioxidants, plasticizers, lubricants, UV-stabilizers, flame retardant agents, processing aids, foaming agents, and the like in order to further improve the properties, including processability, of the resin composition.
- Unfibrillated acrylic fibers 1, 2 and 3 mm in length and 10 micrometers in diameter and a crimp of approximately 30% were added to 98 parts of LP 32 polysulfide resin to prepare mixtures (Examples 1, 2, and 3, respectively), each containing 2 parts by weight of fibers.
- An important parameter that characterizes the fibers is their aspect ratio, which is defined as the ratio of the length of the fiber to its diameter in identical units. In the present instance the aspect ratio of the fibers was 100, 200 and 300, respectively.
- Part A a resin package
- Part B a separate package
- Acrylic fibers having various aspect ratios and % crimp were mixed in the above mixture using first a Sigma Mixer and then a three roll paint mill to uniformly disperse the fibers and the other additives.
- concentration of the fibers in the mixture is expressed in parts by weight to 100 parts by weight resin (phr) and does not include the fillers.
- the sagging of sealant formulations when they are placed on a vertical surface was measured using A.S.T.M. D2202 Slump Test. In this test the sag of the sealant is measured in cm (inches) at 23°C and at 50°C after 30 minutes in a vertical position. In this test, the sealant formulation which contained no fibers sagged 10.16cm (4.0 inches) within 2 minutes, which is an excessive amount.
- the sample containing 1.25 phr of about 30% crimped fibers, 10 ⁇ m in diameter and cut to 3.2 mm lengths had a sag of only 0.508 cm (0.02 inches) at 23°C and 0.127cm (0.05 inches) at 50°C, which confirms it to be a non-sagging sealant.
- the respective sags were 0.508 cm (0.2 inches) and 0.635 cm (0.25 inches), showing that crimping enhances sag resistance, all other variables being constant.
- Example 1 was repeated using DER 331 epoxy resin (Dow Chemical), and using the acrylic fiber used in Examples 4 and 4A*. In addition, acrylic fibers of 13 micrometers in diameter were used. Four compositions in all were prepared. Resistance to fiber-resin separation and dewetting was measured by measuring the drainage from a dollop weighing 8 grams, 2.54 cm (1 inch) in diameter after one-month's storage. The yield stress properties were measured in a Rheometrics RMS-605 mechanical spectrimeter under dynamic oscillation by extrapolation of the square root profile of viscosity/shear rate.
- Example 1 If the procedure of Example 1 is repeated, substituting fibrillated crimped fibers having about 30% crimp for the unfibrillated fibers, a polysulfide composition having its properties improved with the thixotropic fiber in accordance with this invention will be obtained.
- Example 1 If the procedure of Example 1 is repeated, substituting crimped fibers having about 30% crimp and a variety of lengths for the fibers having an average length of 3.2 mm and a uniform length distribution, a polysulfide composition having its properties improved with the thixotropic fiber in accordance with this invention will be obtained.
- Example 1 If the procedure of Example 1 is repeated, substituting crimped fibers having about 30% crimp and fiber diameters of 2, 3, and 5 ⁇ m for the fibers having a diameter of 10 ⁇ m, polysulfide compositions having their properties improved with the thixotropic fibers in accordance with this invention will be obtained.
- Example 1 If the procedure of Example 1 is repeated, substituting crimped modacrylic fibers (50 wt% acrylonitrile - 50 wt% vinyl chloride) having about 30% crimp, for the crimped acrylic fibers, polysulfide compositions having their properties improved with the thixotropic fibers in accordance with this invention will be obtained.
- crimped modacrylic fibers 50 wt% acrylonitrile - 50 wt% vinyl chloride
- Example 5 The 10 micrometer crimped fiber of Example 5 was washed in a solution of acetone and water to remove the normal fiber sizing, which was approximately 1% of the weight of the fiber.
- the drainage area test of Example 5 was performed on a composition of 1.5 parts fiber in 100 parts DER 331 epoxy resin. The drainage area was measured to be 0.516 cm2 (0.08 square inches) after one week storage. An identical composition containing unwashed, sized fibers drained 0.387 cm2 (0.06 square inches) in the same time period. The data indicate that removal of fiber sizing does not alter the effectiveness of the fiber thixotrope of the invention.
- a high modulus, high molecular weight acrylic fiber having a modulus of 207,000 bar (3.0 msi), a molecular weight (M K ) of 370,000, a crimp level of approximately 20%, a length of 3.2 mm and a diameter of 16 micrometers was evaluated in the drainage area test of Example 5 at a compositional level of 2.5 parts per hundred parts of DER 331 epoxy resin. The drainage area was found to be 0.774 cm2 (0.12 square inches) after one week storage, indicating high thixotropic efficiency.
- a stabilized, preoxidized acrylic fiber (PANOX B, a trademark) having a crimp level of approximately 10%, a length of 3.2 mm and a diameter of 13 micrometers was evaluated in the drainage area test of Example 5 at a compositional level of 2.4 parts per hundred parts of DER 331 epoxy resin.
- the drainage area was found to be 1.613 cm2 (0.25 square inches) after one week storage, indicating high thixotropic efficiency.
- fibers act as thixotropes by forming three dimensional networks in the resin.
- this threshold concentration is not absolute, it depends on fiber aspect ratio.
- the fiber aspect ratio satisfying this requirement is given by L/D > 4.6/V 1/2 It follows that to satisfy both conditions, the fiber aspect ratio is bounded by the relationship below: 3/V 3/2 > L/D > 4.6/V 1/2 At a given volume fraction the use of fiber aspect ratios between these limits can provide a wide range of mix viscosities.
- the tear strength of the cured sealant is important, higher fiber volume fraction and lower aspect ratios are preferred, whereas highly stretchable cured sealants require lower fiber volume fraction with high aspect ratios. In the latter case, achieving a high fiber aspect ratio using small diameter (microdenier) fibers is preferred to cutting long lengths in order to preserve the homogeniety of the mix.
- thermosetting resins comprising polyesters, polyacrylates, phenolics, silicones, polyurethanes, natural and synthetic rubber and lattices, polyimides, mixtures of any of them and the like can be used. All such obvious modifications are within the full intended scope of the appended claims.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Polymers & Plastics (AREA)
- Manufacturing & Machinery (AREA)
- Toxicology (AREA)
- Medicinal Chemistry (AREA)
- Sealing Material Composition (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Materials For Medical Uses (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Multicomponent Fibers (AREA)
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Artificial Filaments (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/030,953 US5362562A (en) | 1993-03-12 | 1993-03-12 | Crimped acrylic fibers having improved thixotropic performance |
US30953 | 1993-03-12 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0615008A1 true EP0615008A1 (de) | 1994-09-14 |
EP0615008B1 EP0615008B1 (de) | 1998-12-16 |
Family
ID=21856873
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP94103729A Expired - Lifetime EP0615008B1 (de) | 1993-03-12 | 1994-03-10 | Gekräuselte Acrylfasern, sowie Thixotropiermittel und diese enthaltende Zusammensetzungen |
Country Status (13)
Country | Link |
---|---|
US (2) | US5362562A (de) |
EP (1) | EP0615008B1 (de) |
JP (1) | JPH06299409A (de) |
KR (1) | KR940021782A (de) |
AT (1) | ATE174639T1 (de) |
AU (1) | AU669965B2 (de) |
BR (1) | BR9401129A (de) |
CA (1) | CA2118769A1 (de) |
DE (1) | DE69415191T2 (de) |
ES (1) | ES2124805T3 (de) |
FI (1) | FI941172A (de) |
NO (1) | NO940875L (de) |
TW (1) | TW253909B (de) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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WO2001009264A2 (de) * | 1999-08-02 | 2001-02-08 | Illbruck Gmbh | Abdichtmasse und verfahren zur herstellung einer abdichtung |
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ES2133626T3 (es) * | 1994-08-09 | 1999-09-16 | Sterling Chemicals Int | Material de friccion procesado en seco, metodo de fabricacion del mismo y mezcla seca. |
US5472995A (en) * | 1994-08-09 | 1995-12-05 | Cytec Technology Corp. | Asbestos-free gaskets and the like containing blends of organic fibrous and particulate components |
IN183563B (de) * | 1994-08-09 | 2000-02-12 | Sterling Chemicals Internat In | |
US5643359A (en) * | 1995-11-15 | 1997-07-01 | Dpd, Inc. | Dispersion of plant pulp in concrete and use thereof |
US5972499A (en) * | 1997-06-04 | 1999-10-26 | Sterling Chemicals International, Inc. | Antistatic fibers and methods for making the same |
US5985449A (en) * | 1997-10-08 | 1999-11-16 | Specialty Filaments | Crimped thermoplastic fibers for reinforcing concrete |
US6942726B2 (en) | 2002-08-23 | 2005-09-13 | Bki Holding Corporation | Cementitious material reinforced with chemically treated cellulose fiber |
CN100488910C (zh) | 2002-08-23 | 2009-05-20 | 博凯技术公司 | 用化学处理过的纤维素纤维增强的水泥质材料 |
CA2536780C (en) | 2003-08-29 | 2012-11-13 | Bki Holding Corporation | System for delivery of fibers into concrete |
US7223303B2 (en) * | 2004-08-26 | 2007-05-29 | Mitsubishi Materials Corporation | Silicon cleaning method for semiconductor materials and polycrystalline silicon chunk |
US20080228056A1 (en) | 2007-03-13 | 2008-09-18 | Michael Blomquist | Basal rate testing using frequent blood glucose input |
US7751907B2 (en) | 2007-05-24 | 2010-07-06 | Smiths Medical Asd, Inc. | Expert system for insulin pump therapy |
US8221345B2 (en) | 2007-05-30 | 2012-07-17 | Smiths Medical Asd, Inc. | Insulin pump based expert system |
US8882701B2 (en) | 2009-12-04 | 2014-11-11 | Smiths Medical Asd, Inc. | Advanced step therapy delivery for an ambulatory infusion pump and system |
BR112013015744B1 (pt) | 2010-12-02 | 2021-04-27 | Swimc Llc | Tinta arquitetônica e método de cobertura de defeitos em uma superfície de parede |
US10035924B2 (en) * | 2015-12-04 | 2018-07-31 | Dur-A-Flex, Inc. | Elimination of application streaks of coatings using short fibers |
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EP0235577A2 (de) * | 1986-01-31 | 1987-09-09 | Montefibre S.p.A. | Akrylfasern mit Fähigkeit zur Zerstreuung in viskosen organischen oder anorganischen Grundmassen |
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1993
- 1993-03-12 US US08/030,953 patent/US5362562A/en not_active Expired - Fee Related
-
1994
- 1994-02-17 TW TW083101289A patent/TW253909B/zh active
- 1994-03-09 JP JP6064365A patent/JPH06299409A/ja active Pending
- 1994-03-10 EP EP94103729A patent/EP0615008B1/de not_active Expired - Lifetime
- 1994-03-10 AT AT94103729T patent/ATE174639T1/de not_active IP Right Cessation
- 1994-03-10 DE DE69415191T patent/DE69415191T2/de not_active Expired - Fee Related
- 1994-03-10 ES ES94103729T patent/ES2124805T3/es not_active Expired - Lifetime
- 1994-03-10 CA CA002118769A patent/CA2118769A1/en not_active Abandoned
- 1994-03-11 KR KR1019940004943A patent/KR940021782A/ko active IP Right Grant
- 1994-03-11 AU AU57757/94A patent/AU669965B2/en not_active Ceased
- 1994-03-11 BR BR9401129A patent/BR9401129A/pt not_active Application Discontinuation
- 1994-03-11 FI FI941172A patent/FI941172A/fi unknown
- 1994-03-11 NO NO940875A patent/NO940875L/no unknown
- 1994-06-08 US US08/255,689 patent/US5385978A/en not_active Expired - Fee Related
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EP0053831A2 (de) * | 1980-12-10 | 1982-06-16 | Badische Corporation | Verfahren zur Herstellung verstärkter Materialien mit einem verbesserten Verstärkungsmaterial |
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EP0235577A2 (de) * | 1986-01-31 | 1987-09-09 | Montefibre S.p.A. | Akrylfasern mit Fähigkeit zur Zerstreuung in viskosen organischen oder anorganischen Grundmassen |
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WO2001009264A2 (de) * | 1999-08-02 | 2001-02-08 | Illbruck Gmbh | Abdichtmasse und verfahren zur herstellung einer abdichtung |
WO2001009264A3 (de) * | 1999-08-02 | 2001-08-09 | Illbruck Gmbh | Abdichtmasse und verfahren zur herstellung einer abdichtung |
Also Published As
Publication number | Publication date |
---|---|
ES2124805T3 (es) | 1999-02-16 |
ATE174639T1 (de) | 1999-01-15 |
AU669965B2 (en) | 1996-06-27 |
EP0615008B1 (de) | 1998-12-16 |
DE69415191T2 (de) | 1999-08-05 |
US5385978A (en) | 1995-01-31 |
CA2118769A1 (en) | 1994-09-13 |
FI941172A (fi) | 1994-09-13 |
BR9401129A (pt) | 1995-03-07 |
AU5775794A (en) | 1994-09-15 |
TW253909B (de) | 1995-08-11 |
KR940021782A (ko) | 1994-10-19 |
NO940875D0 (no) | 1994-03-11 |
US5362562A (en) | 1994-11-08 |
FI941172A0 (fi) | 1994-03-11 |
DE69415191D1 (de) | 1999-01-28 |
NO940875L (no) | 1994-09-13 |
JPH06299409A (ja) | 1994-10-25 |
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