EP0582613A1 - Composition moulee solide utilisable comme produit de nettoyage et/ou produit desodorisant - Google Patents

Composition moulee solide utilisable comme produit de nettoyage et/ou produit desodorisant

Info

Publication number
EP0582613A1
EP0582613A1 EP19920909250 EP92909250A EP0582613A1 EP 0582613 A1 EP0582613 A1 EP 0582613A1 EP 19920909250 EP19920909250 EP 19920909250 EP 92909250 A EP92909250 A EP 92909250A EP 0582613 A1 EP0582613 A1 EP 0582613A1
Authority
EP
European Patent Office
Prior art keywords
weight
composition according
alkyl
behenic acid
group
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
EP19920909250
Other languages
German (de)
English (en)
Inventor
Jean-Christophe Ferrando
Henri Mazier
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SC Johnson and Son Inc
Original Assignee
SC Johnson and Son Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SC Johnson and Son Inc filed Critical SC Johnson and Son Inc
Publication of EP0582613A1 publication Critical patent/EP0582613A1/fr
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D10/00—Compositions of detergents, not provided for by one single preceding group
    • C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
    • C11D10/042—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on anionic surface-active compounds and soap
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00—Disinfection, sterilisation or deodorisation of air
    • A61L9/01—Deodorant compositions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00—Disinfection, sterilisation or deodorisation of air
    • A61L9/015—Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone
    • A61L9/04—Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone using substances evaporated in the air without heating
    • A61L9/05—Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone using substances evaporated in the air without heating specially adapted to be released by contact with a liquid, e.g. for toilets
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D10/00—Compositions of detergents, not provided for by one single preceding group
    • C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
    • C11D10/045—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on non-ionic surface-active compounds and soap
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0047—Detergents in the form of bars or tablets
    • C11D17/0056—Lavatory cleansing blocks
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0068—Deodorant compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00—Compositions of detergents based essentially on soap
    • C11D9/007—Soaps or soap mixtures with well defined chain length
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/04—Carboxylic acids or salts thereof
    • C11D1/10—Amino carboxylic acids; Imino carboxylic acids; Fatty acid condensates thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/123—Sulfonic acids or sulfuric acid esters; Salts thereof derived from carboxylic acids, e.g. sulfosuccinates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/126—Acylisethionates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29—Sulfates of polyoxyalkylene ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/90—Betaines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/92—Sulfobetaines ; Sulfitobetaines

Definitions

  • the present invention relates to a novel solid cast composition, usable notably as cleaning and/or deodorizing product, and to its preparation process.
  • the invention is particularly applicable to the production of devices for the automatic cleaning of toilets, such as for example W.C. blocks or containers designed to be immersed in the flushing tank, or to the production of air fresheners.
  • a W.C. block is a product which, after each flushing of the bowl, ensures the cleaning and deodorizing of toilet bowls.
  • This product is generally constituted of a solid active block placed and held inside the bowl, for example in a perforated cage-like container equipped with a hook.
  • these blocks have a duration of use corresponding to about 400-600 flushes.
  • the main properties required for these products are a good stability in time and under heat. Moreover, they are required to have a relatively high melting point (generally higher than
  • perfumes when incorporated in a proportion higher than 15% by weight, soften up the compositions obtained by extrusion and render them unsuitable for use.
  • the cast products (with or without dichloro- benzene) which contain more than 15% by weight of perfume have a melting point which is too low and incompatible with the severe storage conditions which are normally encountered.
  • the solution proposed by the present invention to solve said technical problem consists in a solid cast composition characterized in that it comprises 3 to 15% by weight of at least a behenic acid soap.
  • soaps which are excellent structuring agents, confer to the solid cast compositions, high melting points which can be corrected or reduced by addition of solvent.
  • the "conventional" fatty acid soaps containing between 12 and 18 carbon atoms considerably reduce the stability of the foam produced in the bowl, because of their insoluble nature.
  • soaps are generally used as foam-suppressing agents in washing powders.
  • fatty acid soaps containing between 12 and 18 carbon atoms cause an important reduction of the wearing time compared with blocks containing paradichlorobenzene; they also cause staining of the bowl during use.
  • the benehic acid salts contained in the solid compositions according to the invention are generally obtained by saponification of the behenic acid.
  • the behenic (or n-docosa ⁇ oic) acid is a saturated aliphatic fatty acid containing 22 carbon atoms, naturally found in colza and mustard oils, in carnauba wax and in animal sphingolipids.
  • behenic acid is in fact constituted by a mixture of pure behenic acid and other fatty acids in lesser quantity, such as for example the palmitic, stearic, arachidic and lignoceric acids.
  • behenic acid pure or taken from a raw material for example a colza extract. It is, however, important for such raw material to contain the highest possible proportion of behenic acid, at least 80 to 90% by weight.
  • Suitable saponifying agents according to the invention include, in general, all basic agents reacting with behenic acid. These agents can be used in pure form or in solution, alone or mixed.
  • alkaline metal hydroxides such as sodium hydroxide and potassium hydroxide
  • alkanolamines such as monoethanolamine, diethanolami ⁇ e, triethanolamine
  • alkanamines as well as alkaline or alkaline-earth carbonates and silicates.
  • Said saponifying agents will be used in equimolar quantity with respect to behenic acid.
  • the preferred ones are sodium hydroxide, potassium hydroxide and alkanolamines which give harder products than the other saponifying agents.
  • a solid cast composition according to the invention further comprises : - up to 70% by weight, and preferably 15 to 50% of at least one non-ionic surfactant;
  • non-ionic agents suitable for use according to the invention are generally ethoxylated fatty alcohols with an alkyl chain of hydrophobic nature and a polyoxyethylated chain of hydrophylic nature.
  • the hydrophobic alkyl part may be straight or branched, of natural or synthetic origin and it can contain for example 8 to 18 carbon atoms.
  • the hydrophilic polyoxyethylated part can contain 5 to 100 moieties of ethylene oxide.
  • non-ionic surfactants can be in liquid, paste or solid form, and they are generally used pure or in solution.
  • the non-ionic surfactant used will be an ethoxylated fatty alcohol of which the straight or branched alkyl part contains 8 to 15 carbon atoms and of which the polyoxyethylated part is composed of 5 to 35 moieties of ethylene oxide. It has indeed been found that such products give a solid composition with a very high cleaning and foaming power.
  • anionic or amphoteric surfactant any one of the conventional amphoteric or anionic surfactants, as well as mixtures thereof.
  • Suitable anionic surfactants include : alkyl benzene sulfonates, 0t-olefi ⁇ sulfonates, paraffin sulfonates, alkyl ether sulfates, alkyl sulfates, fatty acid sarcosinates, fatty acid methyl laurates, fatty acid isethionates, dialkyl sulfoccinates; these compounds being for example in sodium salt form.
  • Suitable amphoteric surfactants include alkylbetaines, alkylhydrosulfobetains. All these surfactants may be in liquid, solid or gel form, and will be used either pure or in solution.
  • Any conventional organic solvent can be used according to the present invention if they are compatible with the other constituents of the composition and with the conditions of production.
  • said solvents must have a flash point higher than 90°C.
  • Suitable solvents include:
  • glycols such as for example propylene glycol, dipropylene glycol, hexylene glycol;
  • glycol ethers such as for example diethylene glycol methyl ether, diethylene glycol ethyl ether, diethyleieglycol n-butyl ether, tripropylene glycol methyl ether.
  • All said solvents are liquid at room temperature, with the exception of the polyethylene glycols of molecular mass higher than 1000 of which the melting point varies between 25 and 55°C.
  • Suitable perfumes and dyes according to the present invention include all the compounds known in that application, provided that they are stable in basic medium (pH between 9 and 11).
  • additives adapted to confer additional properties to these compositions, may be advantageously incorporated to the solid compositions according to the invention.
  • bactericidal agents may be added to said compositions, such as for example formaldehyde or phenol derivatives, in order to confer a disinfectant effect thereto.
  • Antitartar or sequestering agents may also be added to said compositions, such as for example phosphonates, certain polycarboxylic polymers or tetra-acetic ethylenediamine acid.
  • the solid cast compositions according to the invention can be obtained by conventional processes which include melting under stirring of the different constituents and casting of the resulting molten mixture in cooling molds.
  • the present invention further relates to the use of behenic acid in the preparation of a solid cast composition particularly usable as cleaning and/or deodorizing product.
  • PEG 600 polyethyleneglycol
  • the ethoxylated fatty alcohol is then added and the temperature of the mixture is brought to 70°C under stirring.
  • the lauryl ether sulfate is added, also under stirring, and the temperature of the resulting mixture is brought to 80°C.
  • the behenic acid is added under stirring while keeping the temperature at 80°C, until complete melting of the acid.
  • the perfume and dye are then added, and the final mixture is kept for about half-an-hour, under moderate stirring, at between 75 and 80°C, until complete homogenizing.
  • the final mixture then obtained is brought, from the production vat, to an automatic measuring device, via pipes thermo- regulated at 80°C.
  • This device then delivers into aluminium molds, calibrat ⁇ ed quantities of the mixture, generally between 20 and lOOg, corresponding to the weight of the finished product.
  • the molten mixture is rapidly cooled and solidified inside the molds, giving solid blocks.
  • the solidification phenomenon can be speeded up by subjecting the molds, after filling, to a stream of cold air.
  • behenic acid salt is formed in situ, during the melting operation.
  • a solid composition containing stearic acid instead of behenic acid was prepared according to the method described in Example 1.
  • the ethoxylated fatty alcohol used is a product containing an alkyl radical with 14 carbon atoms and an ethoxylated chain including 12 moieties of ethylene oxide.
  • the lauryl ether sulfate used is a fluid gel, with an active material content of 70%.
  • Example 2 which contains stearic acid has a relatively low melting point and rather poor foaming and wearing performances, and it stains the bowl through wear.
  • ethoxylated fatty alcohol used in these examples contains an alkyl radical with 12 carbon atoms and an ethoxylated chain containing 20 moieties of ethylene oxide.
  • paraffin sulfonate used is a fluid gel with an active material content of 60%.
  • composition according to the invention having the formula indicated in Table 1 above is prepared by the method described in Example 1.
  • the surfactants used in this example are the same as those used in Examples 1 and 2.
  • compositions can contain a very high proportion of perfume, and the obtained products can be considered as room deodorizers.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Epidemiology (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Detergent Compositions (AREA)

Abstract

La présente invention se rapport à une composition moulée solide ne contenant pas de paradichlorobenzène, utilisable en particulier comme produit de nettoyage et/ou produit désodorisant. La préparation de la composition selon l'invention consiste à faire fondre les constituants sous agitation et à recueillir le mélange fondu résultant dans des moules de refroidissement. La composition comprend de 3 à 15 % en poids d'un savon d'acide de Ben obtenu par réaction d'un acide de Ben avec au moins un agent de saponification sélectionné dans le groupe comprenant des hydroxydes de métal alcalins, des alcanolamines, des alcanamines, des carbonates ou silicates alcalins ou alcalino-terreux.
EP19920909250 1991-04-29 1992-04-27 Composition moulee solide utilisable comme produit de nettoyage et/ou produit desodorisant Ceased EP0582613A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR9105268 1991-04-29
FR9105268A FR2675814B1 (fr) 1991-04-29 1991-04-29 Composition solide coulee, notamment utile comme produit de nettoyage et/ou desodorisant; son procede de fabrication.

Publications (1)

Publication Number Publication Date
EP0582613A1 true EP0582613A1 (fr) 1994-02-16

Family

ID=9412364

Family Applications (1)

Application Number Title Priority Date Filing Date
EP19920909250 Ceased EP0582613A1 (fr) 1991-04-29 1992-04-27 Composition moulee solide utilisable comme produit de nettoyage et/ou produit desodorisant

Country Status (6)

Country Link
EP (1) EP0582613A1 (fr)
JP (1) JPH06506964A (fr)
AU (1) AU659640B2 (fr)
CA (1) CA2108555A1 (fr)
FR (1) FR2675814B1 (fr)
WO (1) WO1992019712A1 (fr)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2287712A (en) * 1994-03-14 1995-09-27 Jeyes Group Plc Lavatory cleansing compositions
WO1996004362A1 (fr) * 1994-08-01 1996-02-15 Albemarle Corporation Produit d'entretien de cuvette de w-c
US5562850A (en) * 1995-07-26 1996-10-08 The Procter & Gamble Company Toilet bowl detergent system
DE775741T1 (de) * 1995-11-22 1999-05-20 Sara Lee De Nv Frischer/Reinigersystem für Toiletten
US5972864A (en) * 1997-02-14 1999-10-26 Lonza Inc. Bleaching and cleaning compositions containing fragrances
EP1156101A1 (fr) * 2000-05-19 2001-11-21 Deoflor S.p.A. Dispositif de nettoyage de cuvette de toilettes
US6987085B2 (en) 2003-06-13 2006-01-17 Kao Corporation Skin cleansing compositions
JP2013520416A (ja) * 2010-02-18 2013-06-06 シャネル パフュームズ ビューテ コンフォートソープクレンザー

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE551361A (fr) * 1955-10-27
US4149986A (en) * 1977-11-03 1979-04-17 Dickson David J Toilet bowl cleaner
JPS61185269A (ja) * 1985-02-14 1986-08-18 大洋香料株式会社 ゲル状芳香剤組成物

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO9219712A1 *

Also Published As

Publication number Publication date
FR2675814A1 (fr) 1992-10-30
AU659640B2 (en) 1995-05-25
JPH06506964A (ja) 1994-08-04
CA2108555A1 (fr) 1992-10-28
WO1992019712A1 (fr) 1992-11-12
FR2675814B1 (fr) 1994-02-04
AU1652592A (en) 1992-12-21

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